JPH02133680A - Suede-like sheet - Google Patents
Suede-like sheetInfo
- Publication number
- JPH02133680A JPH02133680A JP63288600A JP28860088A JPH02133680A JP H02133680 A JPH02133680 A JP H02133680A JP 63288600 A JP63288600 A JP 63288600A JP 28860088 A JP28860088 A JP 28860088A JP H02133680 A JPH02133680 A JP H02133680A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- fibers
- suede
- conductive
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 claims abstract description 58
- 229920001410 Microfiber Polymers 0.000 claims abstract description 23
- 239000004065 semiconductor Substances 0.000 claims abstract description 19
- 239000000758 substrate Substances 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims description 15
- 239000011347 resin Substances 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 12
- 239000002184 metal Substances 0.000 abstract description 9
- 229920000642 polymer Polymers 0.000 abstract description 9
- 239000000843 powder Substances 0.000 abstract description 9
- 229910052799 carbon Inorganic materials 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 4
- 229920001971 elastomer Polymers 0.000 abstract description 2
- 239000000806 elastomer Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 30
- 230000003068 static effect Effects 0.000 description 22
- 239000000463 material Substances 0.000 description 18
- 230000005611 electricity Effects 0.000 description 15
- 230000000694 effects Effects 0.000 description 14
- 239000002245 particle Substances 0.000 description 10
- 229920002635 polyurethane Polymers 0.000 description 9
- 239000004814 polyurethane Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 239000002131 composite material Substances 0.000 description 7
- 239000004020 conductor Substances 0.000 description 6
- 150000002009 diols Chemical class 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000008030 elimination Effects 0.000 description 5
- 238000003379 elimination reaction Methods 0.000 description 5
- 239000004745 nonwoven fabric Substances 0.000 description 5
- -1 ether diol Chemical class 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000006230 acetylene black Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012792 core layer Substances 0.000 description 2
- 238000005421 electrostatic potential Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 229920005570 flexible polymer Polymers 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000009981 jet dyeing Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000003658 microfiber Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000001007 puffing effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は柔軟で帯電防止性を有するスェード調シート、
とりわけ車両用内装シーi・に使用するlご適したスェ
ード調シートに関するものである。[Detailed Description of the Invention] <Industrial Application Field> The present invention provides a suede-like sheet that is flexible and has antistatic properties;
In particular, it relates to a suede-like sheet suitable for use in vehicle interior seats.
〈従来の技術〉
従来、自動車の運転操作後の降車の際に、静電気による
衝撃が発生する事は良く知られている。<Prior Art> It is well known that a shock due to static electricity occurs when getting out of a car after driving it.
これは、人体が車両内の内装材(例えば座席)と摩擦し
合うことにより人体が高電位に帯電し、これが導体に触
れた際に急に多量の静電気が一瞬の間に流れることによ
る、ずなはちスパーク放電現象である。This is because the human body is charged with a high potential when it rubs against the interior material (for example, seats) inside the vehicle, and when this contacts a conductor, a large amount of static electricity suddenly flows in an instant. This is a spark discharge phenomenon.
従来、繊維製品の帯電防止対策として導電性繊維を織り
込む手段が知られている。このものは、繊維製品に帯電
した静電気を導電性繊維に集TM、t、、これを該繊維
先端からコロナ放電により放出して繊維製品の帯電をな
くする機構を利用したものである。しかしながら、この
ような手段を用いても繊維製品のコロナ放電効果(集電
効果)は少なく、到底自動車の座席の表面材として満足
出来るものではなく、しかも導電性繊維自体の蓄電効果
(コンデ〕/サー効果)も極めて小さく、例えば、高電
位に帯電した人体等、他の物体との接触によりこの静電
気を該シートに逃がして除去することは殆ど期待出来な
い。BACKGROUND ART Conventionally, a method of weaving conductive fibers into textile products has been known as a measure to prevent static electricity. This device utilizes a mechanism that collects static electricity charged on a textile product onto conductive fibers and releases it from the tip of the fiber by corona discharge to eliminate the static electricity on the textile product. However, even if such means are used, the corona discharge effect (current collection effect) of the textile product is small, and it cannot be used as a surface material for automobile seats. The electrostatic charge (thermal effect) is also extremely small, and it is hardly expected that static electricity will be released to the sheet and removed by contact with another object, such as a human body charged to a high potential.
このため、除電効果を目的として、4電性繊維を混入し
た繊維シートの裏面に20%ないし5096のカーボン
微粒子を含有する導電バッキング剤層(表面抵抗1O8
0以下)を一体化し、該バッキング剤層をアースしたも
のが除電シートとして提案されている(実開昭60−4
01197号)5〈発明が解決しようとする課題〉
従来のユ・−トをカーシートの表面材として使用すると
き、シートと人体が当初から接触しているときは、シー
トおよび人体に帯電した静電気は常に導電繊維およびバ
ッキング材層をとおり車体に流れて除電されるために両
者の静電位は上からないが、人体かう・−トから離れる
と、シートと人体(衣服)との剥離、あるいは摩擦によ
って生じた人体は高電位に帯電し、シートと人体が再接
触したとき著しいスパーク放電を生じる事が認めらFす
る。これと同様の現象は、他の原因で高電位に帯電した
人体が同じシートに接触したときにも生ずる。このよう
な現象は高電位に帯電した人体が金属等の良導体に接触
するときのスパーク放電と同じである。したがって、m
I記シートは車両用の静電および除電シートとして必ず
り、もイ1効なものとは言えない。For this reason, for the purpose of static elimination effect, a conductive backing agent layer containing 20% to 5096 carbon fine particles (surface resistance 1O8
0 or less) and grounding the backing agent layer has been proposed as a static eliminating sheet (Utility Model Application No. 60-4).
No. 01197) 5 <Problems to be Solved by the Invention> When a conventional vehicle is used as a surface material for a car seat, if the seat and the human body are in contact from the beginning, static electricity charged on the seat and the human body The electrostatic potential between the two always flows through the conductive fibers and backing material layer to the car body and is removed, so the electrostatic potential between the two does not rise. The human body caused by this is charged to a high potential, and when the seat and the human body come into contact again, it is observed that a significant spark discharge occurs. A similar phenomenon also occurs when a human body charged to a high potential due to other causes comes into contact with the same sheet. This phenomenon is similar to spark discharge when a highly charged human body comes into contact with a good conductor such as metal. Therefore, m
The sheet described in I is not always effective as a static electricity eliminating sheet for vehicles.
本発明は、車両内で高電位に帯電した人体等の帯電体か
、該シートに接触する過程で、該帯電体の電位を接触前
にスパーク放電する電位以下に下げ、接触後は導電によ
って帯電体の除電を速やかに行うことができる機能を有
する車両用内装シト、特に自動車の座席の表面H用/〜
トであり、シート自体制電性を有するスェード調シー]
・を提供するものである。The present invention reduces the electric potential of a charged body such as a human body charged to a high potential in a vehicle to a level below the potential that causes a spark discharge before the contact occurs, and then charges the charged body by conduction during the process of contacting the sheet. Interior seats for vehicles that have the function of quickly eliminating static electricity from the body, especially for surface H of automobile seats/~
[Suede-like sheet with antistatic properties]
・It provides:
更に、本発明は車両用内装シートとして要求される制電
性および除電性を有1.ながら、しかも車両用座席の表
面材として要求される、十分な柔軟tiと高級感のある
、更に優美なライディング効果の有る外観を有するシー
トを提供寸−るものである。Furthermore, the present invention has anti-static and static-eliminating properties required for vehicle interior seats. However, the present invention provides a seat that has sufficient softness and a luxurious appearance required for a surface material of a vehicle seat, and has an appearance that provides a more elegant riding effect.
〈課題を解決するための手段〉
本発明は極細繊維および27′またほぞの束状繊維と弾
性樹脂からなる基体、該基体の一面が平均繊度0.3デ
ニール以下の極細繊維でなる立毛密度が104本/cm
2以上の繊維立毛を主体とする表面のスェード調シート
において、立毛104本当たり少なくとも1本の基体に
連通ずる電気抵抗が104〜10″Ω/cmである導電
性繊琲の立毛を存在させ、該スェード調シートの裏面に
、表面電気抵抗が108〜10”Ωの可撓性半導体層を
付与してなることを特徴とするスェード調シートである
。<Means for Solving the Problems> The present invention provides a substrate made of ultrafine fibers, 27' or tenon bundle fibers, and an elastic resin, and one surface of the substrate has a napped density of ultrafine fibers with an average fineness of 0.3 denier or less. 104 pieces/cm
In a suede-like sheet with a surface mainly composed of two or more raised fibers, at least one conductive fiber raised having an electrical resistance of 104 to 10''Ω/cm communicating with the substrate is present per 104 raised fibers, This suede-like sheet is characterized in that a flexible semiconductor layer having a surface electrical resistance of 108 to 10''Ω is provided on the back side of the suede-like sheet.
また、本発明は平均繊度0.3デニール以下の極細繊維
および/または極細繊維発生型繊維と電気抵抗が105
〜104Ωの極細繊紺または極細繊維発生型繊維を立毛
繊維104本当たり少なくとも1本となる量とを混繊し
て繊維絡合不織布を作り、(1)弾性樹脂を含有させた
後、極細繊維発生型繊維を処理して極細繊維または極細
繊維束とする、(2)極細繊維発生型繊維を処理して極
細繊維または極細繊維束とした後、弾性樹脂を含有させ
る、のいずれかの工程をへて基体とし、該基体の一面に
、表面の繊維立毛密度が104本/ c m ”以上に
なるまで立毛処理を施17て、繊維立毛を主体とする表
面のスェード調シートとし、次いでスェード調;−−1
−の裏面に、表面電気抵抗が104・−10”Ωの可撓
性重合体組成物を付与してなることを特徴とするスェー
ド調シートの製造法であるっ本発明に用いる極細繊維発
生型繊維は複数に分割可能な多成分繊維、海成分を抽出
除去可能な海島繊維で、弾性樹脂を含有させる前もしく
は弾性樹脂を含有させた後に極細化されるものである。Further, the present invention uses ultrafine fibers with an average fineness of 0.3 denier or less and/or ultrafine fiber-generated fibers with an electrical resistance of 105
A fiber-entangled nonwoven fabric is made by mixing ~104 Ω ultrafine navy blue or ultrafine fiber generation type fibers with an amount of at least 1 fiber per 104 napped fibers, (1) after containing an elastic resin, ultrafine fibers are mixed. (2) processing the generated fibers to form ultrafine fibers or ultrafine fiber bundles; (2) processing the generated fibers to form ultrafine fibers or ultrafine fiber bundles, and then incorporating an elastic resin into the process; This is used as a substrate, and one side of the substrate is subjected to a napping treatment 17 until the fiber napping density on the surface becomes 104 fibers/cm" or more to obtain a suede-like sheet with a surface mainly composed of napping fibers, and then a suede-like sheet is formed. ;--1
- A method for producing a suede-like sheet, characterized in that a flexible polymer composition having a surface electrical resistance of 104.-10"Ω is applied to the back side of the ultrafine fiber generating type used in the present invention. The fibers are multi-component fibers that can be divided into a plurality of parts, sea-island fibers from which the sea component can be extracted and removed, and are made into ultra-fine fibers before or after containing the elastic resin.
その中でスェード調シートとじてfI’Jな外観と柔軟
な触感を得るためには極細繊維の繊度は0.3デニール
以下、好ましくは0.1デニール以下のものを使用する
。Among them, in order to obtain a fI'J appearance and a soft touch when the suede-like sheet is assembled, the fineness of the ultrafine fibers is 0.3 denier or less, preferably 0.1 denier or less.
本発明に用いられる導電性繊維としては、カーボン、金
属などの導電性粉粒を記入したポリマーからなる繊維、
これら導電性粉粒を混入(7たポリマーと導電性粉粒を
実質的に含まないポリマーからなる複合繊維等が挙けら
れる。金属細線なども導電性繊維としであるが、これら
の繊維は一般に後述する電気抵抗が104Ω/cm未満
であり、電気抵抗の点でこれら導電性繊維は一般に本発
明に用いることができない。本発明において特に繊維素
材のl?I親上の審美性及び風合いを損なわないために
は、また本発明の目的の点でカーボン等の導電性粉粒を
含むポリマーが導電性粉粒を実質的に含まないポリマー
層により包囲されたような複合繊維が有用である。The conductive fibers used in the present invention include fibers made of polymers containing conductive powder particles of carbon, metal, etc.
Composite fibers made of polymers mixed with these conductive powder particles and polymers that do not substantially contain conductive powder particles are examples.Although thin metal wires are also examples of conductive fibers, these fibers are generally These conductive fibers generally cannot be used in the present invention due to their electrical resistance, which will be described later, being less than 104 Ω/cm. In order to avoid this, and for the purpose of the present invention, a composite fiber in which a polymer containing conductive particles such as carbon is surrounded by a polymer layer substantially free of conductive particles is useful.
また導電性繊維としては、電気抵抗が104Ω/cm以
下のものが集電による除電効果の点で好ましいが、10
″Ω7”cm未満になると電撃によるシヨツクを来すこ
ととなるため、本発明では104〜104Ω/cmの範
囲のものが用いられる。なJり前記したようなカーボン
、金属導電性粉粒を混入したポリマーからなる繊維ある
いは該ポリマーを含む複合繊維の場合でも導TM、汁粉
粒の添加量により電気抵抗値が大きく変化することとな
る。したがって電気抵抗値が上記範囲となるように導電
性粉粒が添加さitていることが必要である。In addition, as the conductive fiber, one having an electrical resistance of 104 Ω/cm or less is preferable from the viewpoint of static elimination effect by current collection, but 10 Ω/cm or less is preferable.
If it is less than 7"cm, a shock due to electric shock will occur, so in the present invention, a value in the range of 104 to 104 ohm/cm is used. Even in the case of fibers made of polymers mixed with carbon or metal conductive powder particles as described above, or composite fibers containing such polymers, the electrical resistance value changes greatly depending on the amount of conductive TM and powder particles added. . Therefore, it is necessary that conductive powder particles be added so that the electrical resistance value falls within the above range.
上記の極細繊維発生型繊維と導電性繊維を必要な一定長
に切断した後混綿する手法、もしくは切断する前に必要
な比率で各々の繊維束を集束し、必要があれば延伸、捲
縮、切断する方法によって向繊維を均一に混綿し、既存
の方法で3次元絡合不織布とする。The above-mentioned ultrafine fiber-generating fibers and conductive fibers are cut into required lengths and then mixed together, or the fiber bundles are bundled in the required ratio before cutting, and if necessary, stretched, crimped, The fibers are uniformly blended using a cutting method, and a three-dimensionally entangled nonwoven fabric is made using an existing method.
この不織布に含有せしめる弾性体はポリウレタンが好ま
しく用いられ、平均分子量700〜3000のポリエス
テルジオール、ポリエーテルジオール、ポリエステルエ
ーテルジオール、ポリラクトンジオール、ポリカーボネ
ートジA−ル、などから選ばれI:少なくとも1種のポ
リマージオール、芳香族ジイソシアネートおよび/また
は脂環族ジイソシアネートから選ばれた少なくとも1種
の有機ジイソシアネ−1・を主体に、必要に応じて他の
有機ジイソシアネートあるいは有機トリイソシア不−1
−を配合した有機ジイソシアネート、および低分子ジオ
ール、低分子ジアミ〉・、ヒドラジン、ヒドロキンアミ
ンなど活性水素原子2個有する化合物とを溶液重合法、
溶融重合法、塊状重合法なとによって重合して得たポリ
ニスデル系ポリウレタン、ポリエーテル系ポリウレタン
、ポリエステルポリエーテル系ポリウレタン、ポリラク
トン系ポリウレタン、ポリカーボネート系ポリウレタン
などであり、ポリウレタンは30°Cにおける溶融粘度
しv:l=0.5〜1.3の範囲のポリウレタンである
。この溶融粘度以外では本発明で[1的とする牛革や1
革のスェード調シートを構成するうえで好ましくない。The elastic material contained in this nonwoven fabric is preferably polyurethane, selected from polyester diol, polyether diol, polyester ether diol, polylactone diol, polycarbonate diol, etc. having an average molecular weight of 700 to 3000. Mainly contains at least one organic diisocyanate selected from polymer diols, aromatic diisocyanates, and/or alicyclic diisocyanates, and if necessary, other organic diisocyanates or organic triisocyanates.
An organic diisocyanate containing - and a compound having two active hydrogen atoms such as low-molecular diol, low-molecular diamide, hydrazine, hydroquinamine, etc. are combined using a solution polymerization method.
These include polynisder polyurethane, polyether polyurethane, polyester polyether polyurethane, polylactone polyurethane, polycarbonate polyurethane, etc. obtained by polymerization by melt polymerization method, bulk polymerization method, etc. Polyurethane has a melt viscosity at 30°C. v:l is a polyurethane in the range of 0.5 to 1.3. Other than this melt viscosity, in the present invention [1] cowhide and 1
It is undesirable when constructing a leather suede-like sheet.
このように極細戦線不織布に弾性樹脂を含有さゼた基体
の表面をパフィングして立毛を形成させルカ、スェード
m>−1−としてのライティング効果のある優美な外貌
と柔軟な触感を得るためには、先に述べた極細繊維の繊
度の他に立毛密度も大きく影響し、l〔〕4本/cm2
以上好ましくはlOS本/cm’以上とする。In this way, by puffing the surface of the base material containing elastic resin in ultra-fine front non-woven fabric to form raised pilings, in order to obtain an elegant appearance and soft touch with a lighting effect as suede m>-1-. In addition to the fineness of the ultrafine fibers mentioned above, the napped density also has a large influence;
The above is preferably 1OS lines/cm' or more.
また、このシートに十分な制電性能、除電性能を付与す
るためには先に述べた電気抵抗が105〜109Ω/a
mである導電性繊維がある程度の密度をも−1−〔裏面
の半導体層から基体を連通して表面に立毛を存在させる
必要がある。該立毛繊維は高電位に帯電した帯電体が接
近してくるとき接触する直ギjにシーI・に集電させて
コロプ放電により帯電体の電位をある程度下げる機能を
持つ。本発明でいう制電シートとじて必要な基体に連通
する導電性繊維の立毛密度は少なくとも極細繊維立毛密
度lO1本/cm2当たり1本以」−である。それ以下
では十分な集電及び放電効果は得られない。しかし、逆
に極細繊維の10倍以上の太さの導電性繊維密度が高く
なりすぎると、同効果は飽和となり著しい効果の向上は
認められないばかりか、触感は荒くなり発色性の著しく
異なる立毛が増えるためにシモフリ調の外観どなり好ま
しくない。In addition, in order to provide this sheet with sufficient antistatic performance and static elimination performance, the electrical resistance mentioned above must be 105 to 109 Ω/a.
It is necessary for the conductive fibers of m to have a certain density of -1-[to communicate the semiconductor layer on the back side with the substrate so that napped hairs are present on the surface. The napped fibers have the function of lowering the potential of the charged body to some extent by collapsing the charged body by collecting current in the straight line with which it comes into contact when a charged body charged at a high potential approaches. The napped density of the electrically conductive fibers that communicate with the necessary substrate as used in the antistatic sheet of the present invention is at least 1 per 10 ultrafine fibers/cm 2 . If it is less than that, sufficient current collection and discharge effects cannot be obtained. However, if the density of the conductive fibers, which are 10 times or more thicker than the microfibers, becomes too high, the same effect will become saturated and no significant improvement will be observed. This increases the appearance of a shimofuri style, which is undesirable.
また本発明でいう半導体層は、布帛層の裏面にバッキン
グ剤としてコートされるか、フィルム等として貼り合わ
されて形成される。該バッキング剤としては、通常のバ
ンキング樹脂またはゴムにカーボン、金属等の導電性微
粒子たは物質を微分散したものが用いられ、該フィルム
としても同様に導電性微粒子等が混入されたものが用い
られる。Further, the semiconductor layer referred to in the present invention is formed by coating the back surface of the fabric layer as a backing agent, or by bonding it together as a film or the like. As the backing agent, a material obtained by finely dispersing conductive fine particles or substances such as carbon or metal in ordinary banking resin or rubber is used, and as the film, a material in which conductive fine particles, etc. are mixed is used. It will be done.
該半導体層は表面抵抗が104〜1010Ωであること
が必要であり、10”Ω以上では帯電体との接触によっ
てその除電を行いに<<、またIO1IΩ以下になると
核層が導体に近くなり、帯電体の電位によってはシート
との間でスパーク放電を起こし好ましくない。該バッキ
ング剤は例えば通常のバッキング樹脂にカーボン粉粒を
一般に樹脂剤重量(固形分)の1.5〜15重量%混入
微分散することによって容易に得られる。またフィルム
の場合も同様に、導電性粉粒または物質の混入量を調節
することにより容易に得られる。The semiconductor layer needs to have a surface resistance of 104 to 1010 Ω; if it is 10”Ω or more, the static electricity is removed by contact with a charged body, and if it is less than IO1IΩ, the core layer becomes close to a conductor. Depending on the potential of the charged body, spark discharge may occur between the sheet and the sheet, which is undesirable.The backing agent is made by, for example, mixing carbon powder particles in a normal backing resin in an amount of 1.5 to 15% by weight based on the weight (solid content) of the resin. It can be easily obtained by dispersing it.Also, in the case of a film, it can also be easily obtained by adjusting the amount of conductive powder or substance mixed.
一般に、樹脂に導電性粉粒を添加すると、この樹脂況合
物から得られる樹脂層は柔軟性が半減し、座席用表面材
として用いるとラードの柔軟性が損なわれ、座り心地が
悪化する。このようなことを防ぐためには、樹脂層を発
泡コーティング法やメツシュ:1−ティング法(点状、
線状、網目状コーティ〉グを含む)により形成するのが
有効である。Generally, when conductive powder particles are added to a resin, the flexibility of the resin layer obtained from this resin mixture is halved, and when used as a seating surface material, the flexibility of the lard is impaired, resulting in poor seating comfort. In order to prevent this, the resin layer must be coated with a foam coating method or a mesh coating method (dotted,
It is effective to form the film with a linear or mesh coating.
本発明において導電性繊維と半導体層とが接触している
ことが必要であり、接触していない場合には、布帛層に
集電された静電気のコロナ放電能が低下すると同時に半
導体層への漏洩効果も減することとなる。また導電性繊
維の電気抵抗値は半導体層の表面抵抗値よりも低いこと
が、半導体層への漏洩効果の点で好ましい。In the present invention, it is necessary that the conductive fibers and the semiconductor layer are in contact with each other. If they are not in contact with each other, the corona discharge ability of the static electricity collected in the fabric layer decreases, and at the same time, leakage to the semiconductor layer occurs. The effect will also be reduced. Further, it is preferable that the electrical resistance value of the conductive fiber is lower than the surface resistance value of the semiconductor layer from the viewpoint of the leakage effect to the semiconductor layer.
さらに、本発明では帯電体から集電したシー1−の静電
気をアースにより除去するのが好ましく、このために前
記布帛層と半導体層からなるシートの裏面に表面抵抗1
04Ω以下の導電層を一体化することが望ましい。Further, in the present invention, it is preferable to remove the static electricity of the sheet 1- collected from the charged body by grounding, and for this purpose, a surface resistance 1 is provided on the back side of the sheet consisting of the fabric layer and the semiconductor layer.
It is desirable to integrate the conductive layer with a resistance of 0.4 Ω or less.
この導電層としては、導電性フィルム、導電性布帛、金
属シート、金属板等が用いられる。第1図は本発明によ
る制電、除TL機能を有する複合ソートの断面図であり
、図中、lは極細繊維、2は導電性繊維、3は基体層、
・1は半導体層、5は導電層を示す。As this conductive layer, a conductive film, a conductive cloth, a metal sheet, a metal plate, etc. are used. FIG. 1 is a cross-sectional view of a composite sort having antistatic and TL functions according to the present invention, in which l is an ultrafine fiber, 2 is a conductive fiber, 3 is a base layer,
- 1 indicates a semiconductor layer, and 5 indicates a conductive layer.
〈作 用〉
本発明の複合シートは、導電層にアースされて使用され
るが、このシート表面に高電位に帯電した人体等の帯電
体が接触しようとするとき、まず、接触直前に帯電帯の
静電気は繊維層の導電繊維に集電されコロナ放電により
帯電体の電位が下がり、また本発明のシーi・全体とし
ては導体でなく、徐々に静電気を流し一挙に放電しない
ため、スパークすることなく、帯電体とシート面が接触
したときは、導電体に比べて緩やかに帯電体の静電気が
シートの導電性繊維を通じて半導体層に流れ、ア・−ス
によって除電される。したがって高電位の帯電体が本発
明のラードに接触するときスパーク放電による電撃やノ
イズ等の静電気障害を招くことなく速やかに帯電体の除
電を行うことができる。<Function> The composite sheet of the present invention is used by being grounded to a conductive layer. When a charged body such as a human body charged at a high potential comes into contact with the surface of this sheet, first, immediately before contact, the charged body is The static electricity is collected by the conductive fibers of the fiber layer, and the potential of the charged body is lowered by corona discharge.Also, the material of the present invention is not a conductor as a whole, and because it gradually releases static electricity and does not discharge all at once, it does not cause sparks. Instead, when the charged body and the sheet surface come into contact, the static electricity of the charged body flows to the semiconductor layer through the conductive fibers of the sheet more slowly than that of the conductor, and is eliminated by the earth. Therefore, when a charged body with a high potential comes into contact with the lard of the present invention, the charge of the charged body can be quickly removed without causing electrostatic disturbances such as electric shock or noise due to spark discharge.
また帯電体の電位が低いときにはソートどの接触のみで
除電されることになる。Further, when the potential of the charged body is low, the charge is removed only by contact with the sorting member.
本発明によるシート自体は、導電性繊維が混入されてい
るため制電効果を有し、しかも前記除電機能により本発
明のシートに接触している物質に大きく帯電することは
ない。The sheet according to the present invention itself has an antistatic effect because conductive fibers are mixed therein, and furthermore, due to the static eliminating function, substances in contact with the sheet according to the present invention are not significantly charged.
以上の機能から、本発明のシートは、車両用の内装材と
して、たとえば座席の表面材、ドアライニング、インサ
イドパネル板等に使用できるが、特に自動車の座席の表
面材として擾れている。さらに、これら以外に、コンピ
ュータールームの椅子張り、ドアノブカバー、敷物、壁
材等として使用できる。Due to the above functions, the sheet of the present invention can be used as a vehicle interior material, such as a seat surface material, a door lining, an inside panel board, etc., but it is particularly used as a surface material for automobile seats. Furthermore, in addition to these, it can be used as upholstery in computer rooms, doorknob covers, rugs, wall materials, etc.
〈実施例〉 次に、本発明の実施態様を具体的な実施例で説明する。<Example> Next, embodiments of the present invention will be explained with specific examples.
なお実施例中の部および%はことわりのないかぎり重量
に関するものである。Note that parts and percentages in the examples are by weight unless otherwise specified.
実施例1
島成分としてポリエチレンテレフタレートヲ5θ部、海
成分と12で低密度ポリエチレン50部からなる太さ5
デニールの多成分繊維(A)190部とアセチレンブラ
ック26.5%を含む6−ナイロンがアセチレンブラッ
クを含まないポリエチし・ンテレフタレートにより包囲
された断面構造を有する太さ12.5デニールの複合導
電性繊維(I3)5部を混綿して作成した3次元絡合不
織布にボリデトラメチレンエーテルグリコール60部、
ポリカプロラクトン40部をソフトセグメントとするポ
リウレタン組成物のD M F溶液を含浸し、湿式凝固
した後、熱トルエン中にて繊維(A)の海成ケ)(ポリ
エチレン)を抽出除去し、繊維シート を 1得 tこ
。Example 1 Thickness 5 consisting of 5θ parts of polyethylene terephthalate as the island component, 12 parts of the sea component, and 50 parts of low density polyethylene.
A 12.5-denier conductive composite with a cross-sectional structure in which 190 parts of denier multicomponent fiber (A) and 6-nylon containing 26.5% acetylene black are surrounded by polyethylene terephthalate containing no acetylene black. 60 parts of bolidetramethylene ether glycol was added to a three-dimensional entangled nonwoven fabric made by blending 5 parts of synthetic fiber (I3).
After impregnating with a DMF solution of a polyurethane composition containing 40 parts of polycaprolactone as a soft segment and wet coagulating, the polyethylene of the fiber (A) is extracted and removed in hot toluene to obtain a fiber sheet. Get 1.
この繊維シートの表面をバフイ〉・グして極細繊維の立
毛を形成し、これを120°Cの高温高圧液流染色機で
染色した後、プランジングして、ライティング効果のあ
る優美な外観のスェード調シートを得た。極細繊維の立
毛密度は平均104本/am”、基体に連通ずる導電性
繊維(B)の立毛密度は平均25本/Cm2であった。The surface of this fiber sheet is buffed to form a napped layer of ultra-fine fibers, which is dyed in a high-temperature, high-pressure jet dyeing machine at 120°C, and then plunged to create an elegant appearance with a lighting effect. I got a suede style sheet. The average napped density of the ultrafine fibers was 104 pieces/am'', and the average napped density of the conductive fibers (B) communicating with the substrate was 25 pieces/cm2.
この立毛シーIの裏面にカーボン粉末を10%兄大した
バンキング材を塗布し、半導体層を形成し、スェード調
繊維シート(I)を得た。A banking material containing 10% larger carbon powder was applied to the back side of this raised sheet I to form a semiconductor layer, thereby obtaining a suede-like fiber sheet (I).
比較のために(1)のシートの半導体バッキングをしな
いサンプル(■)、更に(I)のシートの半導体バッキ
ングの代わりに表面抵抗104Ωの導体バンキング(バ
ッキング樹脂にカーボン粉末30%混入したもの)をし
たサンプル(III)を作成し、これらの除電性能を評
価した。結果は第1表の通りである。For comparison, a sample (■) of sheet (1) without semiconductor backing, and a conductor banking (30% carbon powder mixed in backing resin) with a surface resistance of 104 Ω instead of semiconductor backing of sheet (I) were used for comparison. Samples (III) were prepared, and their static elimination performance was evaluated. The results are shown in Table 1.
以下余tJ
第1表 放電球の接触による電位の減衰これらサンプル
(1)〜(III)を表面材として用いてそれぞれ自動
車用座席を作製しtユ。そして作製された座席を自動車
内にセットし、5℃−12%RHの温湿度条件下で、ポ
リエステルシャツにポリエステルズポ〉・をはいた人を
座席に座らせ、10秒間に腰を前後に10往復させて座
席と着衣とを摩擦させた。Table 1 Attenuation of electric potential due to contact with discharge lamp Automobile seats were prepared using these samples (1) to (III) as surface materials. Then, the manufactured seat was set in a car, and a person wearing a polyester shirt and a polyester jacket was seated in the seat under a temperature and humidity condition of 5°C - 12% RH, and the seat was moved back and forth for 10 seconds. I made it back and forth 10 times to create friction between the seat and my clothes.
サンプル(n)の場合は、座席から立ち上がり導電性物
(金属)に触れると大きな電撃ショックが発生した。ま
たサンプル(III)の場合は座席から立ち上がった際
に大きな電撃ショックが発生した。それに対してサンプ
ル(1)の場合には導電性物に触れた際にほんの僅かな
電撃を感じただけであった。In the case of sample (n), a large electric shock occurred when the patient stood up from his seat and touched a conductive object (metal). In the case of sample (III), a large electric shock occurred when the passenger stood up from the seat. In contrast, in the case of sample (1), only a slight electric shock was felt when touching the conductive object.
実施例2
実施例1のサンプル(1)の製法において、半導体層と
して、予め泡立てた樹脂液(カーボン粉末をlO重λ%
含む)を裏面に塗布して乾燥させたものを用いる以外は
サンプル(I)と同様に行ったシートを製造した。この
際の半導体層の気泡含宜皐は65体積%であった。まt
二手心体層の塗布量は95g/m”であった。このシー
トを表面材どする座席を作製したところ、制’tsよび
除電能に関しては前記サンプル(I)と同様に極めて優
tまたものであり、さらにシート自体も極めて柔軟であ
り、座席の表面材どしたときの座り心地は極めて良いも
のであった。Example 2 In the manufacturing method of sample (1) of Example 1, a pre-foamed resin liquid (carbon powder was added to lO weight λ%) as a semiconductor layer.
A sheet was manufactured in the same manner as Sample (I) except that a sheet containing a compound (including 100% polyester) was applied to the back surface and dried. At this time, the bubble content of the semiconductor layer was 65% by volume. Yes
The coating amount of the two-hand core layer was 95 g/m''. When a seat was fabricated using this sheet as a surface material, it showed extremely good control and static elimination ability, similar to sample (I). Furthermore, the seat itself was extremely flexible, and the seat surface material was extremely comfortable to sit on.
〈効果〉
本発明のスェード調シートは、帯電体の電位がシートど
の接触直前にスパーク放電を生ずることがない電位に下
げることができ、その後、速やかに帯電体から除電する
ことが出来る。<Effects> With the suede-like sheet of the present invention, the electric potential of the charged body can be lowered to a potential that does not cause spark discharge immediately before the sheet comes into contact with the sheet, and then the electric charge can be quickly removed from the charged body.
第1図は本発明のスェード調シートを用いた複合シート
の一例の断面模式図であり、第2図はシートの除N、性
能を測定するだめの装置の図である。FIG. 1 is a schematic cross-sectional view of an example of a composite sheet using the suede-like sheet of the present invention, and FIG. 2 is a diagram of an apparatus for measuring the N removal and performance of the sheet.
Claims (1)
らなる基体、該基体の一面が平均繊度0.3デニール以
下の極細繊維でなる立毛密度が10^4本/cm^2以
上の繊維立毛を主体とする表面のスエード調シートにお
いて、立毛10^4本当たり少なくとも1本の基体に連
通する電気抵抗が10^5〜10^9Ω/cmである導
電性繊維の立毛を存在させ、該スエード調シートの裏面
に、表面電気抵抗が10^6〜10^1^0Ωの可撓性
半導体層を付与してなることを特徴とするスエード調シ
ート。1) A base made of ultrafine fibers and/or their bundled fibers and an elastic resin; one side of the base is made of ultrafine fibers with an average fineness of 0.3 denier or less; a napped fiber with a napped density of 10^4 fibers/cm^2 or more; In a suede-like sheet with a surface mainly composed of, there is present at least one napped conductive fiber with an electrical resistance of 10^5 to 10^9 Ω/cm that communicates with the substrate for every 10^4 napped fibers, and the suede A suede-like sheet, characterized in that a flexible semiconductor layer having a surface electrical resistance of 10^6 to 10^1^0 Ω is provided on the back side of the suede-like sheet.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63288600A JPH07870B2 (en) | 1988-11-14 | 1988-11-14 | Suede-like seat |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63288600A JPH07870B2 (en) | 1988-11-14 | 1988-11-14 | Suede-like seat |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH02133680A true JPH02133680A (en) | 1990-05-22 |
JPH07870B2 JPH07870B2 (en) | 1995-01-11 |
Family
ID=17732341
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63288600A Expired - Fee Related JPH07870B2 (en) | 1988-11-14 | 1988-11-14 | Suede-like seat |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH07870B2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6373141B1 (en) * | 1996-06-10 | 2002-04-16 | Tessera, Inc. | Bondable compliant pads for packaging of a semiconductor chip and method therefor |
JP2007138310A (en) * | 2005-11-15 | 2007-06-07 | Kuraray Co Ltd | Flame-retardant leather-like sheet and process for imparting flame retardancy to leather-like sheet |
JP2020115169A (en) * | 2019-01-17 | 2020-07-30 | シャープ株式会社 | Image formation apparatus |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56115498U (en) * | 1980-02-01 | 1981-09-04 | ||
JPS59135024A (en) * | 1983-01-24 | 1984-08-03 | 三菱バ−リントン株式会社 | Tile carpet |
JPS60140698A (en) * | 1983-12-28 | 1985-07-25 | 旭化成ポリフレックス株式会社 | Charging preventive woven cloth and nonwoven cloth |
JPS6225146A (en) * | 1985-07-24 | 1987-02-03 | Suminoe Orimono Kk | Electrically conductive carpet-backing composition |
-
1988
- 1988-11-14 JP JP63288600A patent/JPH07870B2/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56115498U (en) * | 1980-02-01 | 1981-09-04 | ||
JPS59135024A (en) * | 1983-01-24 | 1984-08-03 | 三菱バ−リントン株式会社 | Tile carpet |
JPS60140698A (en) * | 1983-12-28 | 1985-07-25 | 旭化成ポリフレックス株式会社 | Charging preventive woven cloth and nonwoven cloth |
JPS6225146A (en) * | 1985-07-24 | 1987-02-03 | Suminoe Orimono Kk | Electrically conductive carpet-backing composition |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6373141B1 (en) * | 1996-06-10 | 2002-04-16 | Tessera, Inc. | Bondable compliant pads for packaging of a semiconductor chip and method therefor |
JP2007138310A (en) * | 2005-11-15 | 2007-06-07 | Kuraray Co Ltd | Flame-retardant leather-like sheet and process for imparting flame retardancy to leather-like sheet |
JP2020115169A (en) * | 2019-01-17 | 2020-07-30 | シャープ株式会社 | Image formation apparatus |
Also Published As
Publication number | Publication date |
---|---|
JPH07870B2 (en) | 1995-01-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4713531A (en) | Heating element for textiles | |
EP0125494A2 (en) | Entangled fibrous mat having good elasticity and production thereof | |
JPH0343389B2 (en) | ||
JP2023126471A (en) | conductive synthetic leather | |
US3462326A (en) | Method of making a leather-like microporous sheet material | |
JPH02133680A (en) | Suede-like sheet | |
US4269881A (en) | Anti-static mats and carpets | |
JP3366504B2 (en) | Flexible artificial nubuck leather and manufacturing method thereof | |
JP4633606B2 (en) | Flame-retardant leather-like sheet and method for flame-retardant processing of leather-like sheet | |
US3496056A (en) | Leather-like microporous sheet material | |
US3616023A (en) | Process for manufacturing suedelike sheet material | |
JP4884661B2 (en) | Artificial leather and method for producing the same | |
JP3141566B2 (en) | Antistatic brushed sheet | |
JP3215739B2 (en) | Brushing method of microfiber sheet | |
JP4014477B2 (en) | Flame-retardant leather-like sheet substrate and method for producing the same | |
JP3671733B2 (en) | Surface material for vehicle seat | |
JP4459705B2 (en) | Antistatic napping sheet | |
JPH08445B2 (en) | Composite material | |
JPS6132750Y2 (en) | ||
JP2002115183A (en) | Flame-retardant leather-like sheet substrate and method for producing the same | |
JP2538961Y2 (en) | Conductive carpet | |
JPS5940480Y2 (en) | Needle punch non-woven carpet | |
JP4498824B2 (en) | Leather-like sheet and method for producing the same | |
JP2006028683A (en) | Antistatic napped sheet | |
JP3162846B2 (en) | Nubuck sheet material and method for producing the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
LAPS | Cancellation because of no payment of annual fees |