JPH02136853A - Silver halide color photosensitive material - Google Patents

Abstract

PURPOSE:To obtain a silver halide color photosensitive material providing picture images having high picture quality by constituting the silver halide color photosensitive material of adjacent layers succeedingly from a farthest side apart from a base body in an order as described hereunder: blue sensitive silver halide emulsion layer, red sensitive silver halide emulsion layer having high sensitivity, green sensitive silver halide emulsion layer having high sensitivity, green sensitive silver halide emulsion layer having low sensitivity, and red sensitive silver halide emulsion layer having low sensitivity. CONSTITUTION:A silver halide color photosensitive material is formed on a base body by forming succeedingly at least one blue sensitive silver halide emulsion layer, red sensitive silver halide emulsion layer having high sensitivity, green sensitive silver halide emulsion layer having high sensitivity, green sensitive silver halide emulsion layer having low sensitivity, and red sensitive silver halide emulsion layer having low sensitivity adjacently and in the described order from the farthest side from the base body. If necessary, nonsensitive layers may be interposed between the layers. Thus, a color photosensitive material having high sensitivity and providing a picture image having high picture quality which can be processed rapidly is obtd. on the base body.

Description

DETAILED DESCRIPTION OF THE INVENTION (Field of the Invention) The present invention relates to a color light-sensitive material for photographing with high sensitivity, and particularly to a color light-sensitive material for photographing that is suitable for rapid processing and has good storage stability.

(Prior Art) In recent years, with advances in the technology of photographic photosensitive materials, highly sensitive photosensitive materials have been released one after another. Expanding the range of photography by increasing the sensitivity of photosensitive materials, such as shooting without a strobe in a dark room, shooting with a high-speed shutter using a telephoto lens for sports photography, and shooting that requires long exposures such as astronomical photography. is an eternal theme for this industry.

Many efforts have been made to increase the sensitivity of photosensitive materials. Numerous studies have been conducted on the shape and composition of silver halide grains, methods of forming them, chemical sensitization, spectral sensitization, additives, coupler structures, etc., and several useful inventions have been made. The demands for sensitive light-sensitive materials are greater than the advances in technology, and unfortunately these methods alone were not sufficient.Therefore, other methods were developed to increase the size of silver halide emulsion grains in order to achieve higher sensitivity. It has become a common practice in the industry to produce highly sensitive photosensitive materials in combination with other techniques.

Increasing the size of the silver halide emulsion grains increases the sensitivity to a certain extent, but as long as the silver halide content is kept constant, the number of silver halide emulsion grains inevitably decreases, and therefore the development starting point increases. The major disadvantage is that the number is reduced and the graininess is greatly impaired. In order to compensate for this drawback, British Patent No. 923,045, Japanese Patent Publication No. 49-1
A photographic material having two or more emulsion layers having same-photochromic properties and different sensitivities, that is, different silver halide grain sizes, as described in JP-A No. 5495, JP-A-55-62
Methods using fast-reactive couplers such as those described in US Pat. No. 454, US Pat. No. 3,227.554,
Methods using so-called DIR couplers or DIR compounds, such as those described in U.S. Pat. No. 3,632,435, and couplers that produce mobile dyes, as described in British Patent No. 2,083,640. Method, JP-A-6
A method using silver halide having a high average silver iodide content is known, as described in Japanese Patent No. 0128443. Although each of these methods is an excellent invention with great effects, they are not sufficient technologies to meet the great demand for high sensitivity and high image quality. Therefore, in order to increase the grain size of the silver halide emulsion grains and at the same time increase the number of development initiation points as much as possible, high-sensitivity color negative light-sensitive materials are manufactured within a range that allows for various performances such as desilvering properties during bleach-fixing processing. Designs have been made to increase the content of silver halide emulsion grains.

On the other hand, it has been known to change the arrangement of the layers of a multilayer color photosensitive material in order to increase the sensitivity of the color photosensitive material or to achieve both high sensitivity and high image quality. For example, as in U.S. Pat. Also, as in U.S. Patent No. 4,184,876, the green sensitive layer and the red sensitive layer are made into one unit, and the green sensitive layer and the red sensitive layer are made into another unit. There are some that aim to increase the frequency range by placing the high-sensitivity unit outside the low-sensitivity unit. However, although these techniques have partially achieved their objectives, they still have some deficiencies, and many patents have been filed for the purpose of improving them. West German Patent No. 3,410,639 describes a technology that incorporates the high-sensitivity portion of the blue-sensing layer into a high-sensitivity unit.
, 411,966, European Patent No. 155814, No. 1
No. 24861, JP-A-59-177.552, JP-A-59180.556, etc. disclose a technique in which a high-sensitivity unit consisting of blue, green, and red sensitive layers is combined with other techniques.

Further, in US Pat. No. 4,129,446, the positional relationship between the high frequency unit and the yellow filter is described in No. 4.186.
No. 016 describes the connection relationship between a high sensitivity unit and a low sensitivity unit, No. 4,267.264 describes the relationship between a green sensitivity layer and a high sensitivity red sensitivity layer, and British Patent No. 1,560.965 describes the connection relationship between a high sensitivity unit and a low sensitivity unit. , US Pat. No. 4,186,011, an intermediate layer is defined.

However, although all of the above-mentioned three techniques and their improvement techniques have partially achieved their objectives, satisfactory performance has not been achieved. In particular, the image quality is insufficient, such as color reproduction, and the amount of coated silver is larger than in the conventional layer arrangement, and the image quality is likely to deteriorate if the photosensitive material is exposed to radiation during storage. there was.

(Objective of the Invention) The object of the present invention is firstly to provide a high-sensitivity color photosensitive material with high image quality, and secondly, to provide a color photosensitive material with high image quality and high sensitivity that can be rapidly processed. The third object is to provide a highly sensitive color photosensitive material in which deterioration in performance, such as an increase in fog, which occurs during storage after production is minimized.

(Means for Solving the Problems) An object of the present invention is to sequentially form at least one blue-sensitive silver halide emulsion layer, a high-sensitivity red-sensitive silver halide emulsion layer, and a high-sensitivity red-sensitive silver halide emulsion layer from the far side of the support. A green-sensitive silver halide emulsion layer with high sensitivity, a green-sensitive silver halide emulsion layer with low sensitivity, and a red-sensitive silver halide emulsion layer with low sensitivity are adjacent to each other, or with a non-light-sensitive layer interposed as necessary, This was achieved by the silver halide color light-sensitive material provided above.

In the present invention, at least one blue-sensitive silver halide emulsion layer (also referred to as "blue-sensitive emulsion layer") is provided, preferably two or three blue-sensitive silver halide layers having substantially the same color sensitivity. An emulsion layer is preferred. Here, substantially the same color sensitivity means that the sensitivity maximum is 400-500 nm.
This means that the spectral sensitivity distribution is the same or similar. When a plurality of blue-sensitive emulsion layers are provided, it is preferable that the blue-sensitive emulsion layer with relatively high sensitivity is provided on the side far from the support.

"High sensitivity" or "low sensitivity" with respect to the red-sensitive silver halide emulsion layer (hereinafter also referred to as "red-sensitive emulsion layer") and the green-sensitive silver halide emulsion layer (also referred to as "green-sensitive emulsion layer"). All stipulations are relative. These emulsion layers with relatively high sensitivity and relatively low sensitivity have a sensitivity difference of 0.1 to 1.0, preferably 0.2 to 0.7, depending on the common logarithm of exposure. preferable. Furthermore, as will be described later, the red-sensitive or green-sensitive emulsion layer with high sensitivity or low sensitivity may be further formed into two layers with different sensitivities, and the relative sensitivity difference in this case is the same as in the case of dividing into two layers. be.

Here, the sensitivities are different, for example, high, low, or high.

The three medium and low red or green sensitive emulsion layers have substantially the same color sensitivity. Substantially the same color sensitivity means that the sensitivity maximum of each emulsion layer is in the range of 600-700 nm and 500-600 nm, respectively, and the spectral sensitivity distribution is the same or similar. It means that

In the present invention, it is preferred that the blue-sensitive, green-sensitive and red-sensitive emulsion layers each contain at least one yellow, magenta and cyan coupler.

The present invention is preferably a negative color photosensitive material. For this reason, a transparent flexible support is used as the support.
It is preferable to use a photosensitive material for photographing having a relative photographic sensitivity of 320 to 6,400, which will be described later.

Specific examples of the arrangement order of each layer in the color photosensitive material of the present invention are listed below, but the present invention is not limited thereto.

fil Support, low sensitivity red-sensitive emulsion 71 (RL)
, medium-speed red-sensitive emulsion layer (RM), intermediate layer (IL), low-speed green-sensitive emulsion layer (OL), medium-speed green-sensitive emulsion layer (GM)
, high-sensitivity green-sensitive emulsion layer (GH), intermediate layer (IL)
, high sensitivity red sensitive emulsion layer (RH), yellow filter layer (YF), low sensitivity red sensitive emulsion layer (BL), medium sensitivity blue sensitive emulsion layer (BM), high sensitivity blue sensitive emulsion layer (BH), protective layer (PL) (2) Support, RL, RM, IL, GL,
GMrL, OH, IL, RH, YF, BL, BM.

BHPL (3) Support, RL, RM, IL, GL, GM.

IL, GH, 'y'F, RH, IL, BL, BM.

BH, P.L. (4) Support, RL, RM, IL, GL, GM.

IL, OH, IL, RH, IL, BL, BM.

BH, PL In (1) to (4) above, each emulsion layer with different color sensitivity has three different speed sensitivities, and is composed of M and H layers, but two layers, L and H. It may be.

There may be only one blue-sensitive layer. A layer that reflects light (Ref) is provided under the high-sensitivity layer, such as BL, BM,
A configuration such as Ref and BH may be adopted. A non-light-sensitive fine grain emulsion layer may be provided in a non-light-sensitive intermediate layer adjacent to the high-speed layer in order to accelerate the development of the high-speed layer. In the examples (1) to (4), the medium-sensitivity layer is arranged adjacent to the low-sensitivity layer, but it may also be arranged adjacent to the high-sensitivity layer. Intermediate N separating emulsion layers of the same color sensitivity (for example, GL in (2),
G.M.

The IL (IL, GH) may contain a compound (so-called scavenger) that captures the oxidized form of the developing agent. Alternatively, an emulsion may be added to this layer to form a four-layer structure. The protective layer PL may be IN, or may have two or more layers. It is preferable that the outermost layer contains a mantle agent. When oil droplets are included to adjust film physical properties, a structure of two or more layers is preferred, and the outermost layer preferably has a smaller oil droplet/binder (weight ratio) than the inner adjacent layer. An antihalation layer and, if necessary, an intermediate layer are usually included between the low-speed red-sensitive emulsion layer and the support.

For the protective layer and the various intermediate layers mentioned above,
No. 1-4374'8, No. 59-113438, No. 59
-113440, 61-20037, 61-2
Coupler and DIR compounds such as those described in No. 0038 may be included.

The color light-sensitive material of the present invention has blue-sensitive, green-sensitive, and red-sensitive silver halide emulsion layers, and among these, at least the green-sensitive layer and the red-sensitive layer have two different sensitivities. It is particularly preferred that each color-sensitive layer has a three-layer structure in order to improve the graininess of the green-sensitive or red-sensitive layer and, if necessary, the blue-sensitive layer. .

This technique is different from the three-layer structure described in Japanese Patent Publication No. 49-15,495, because a particularly excellent effect can be obtained by combining it with an inverted layer structure.

A non-light sensitive layer may be present between each light sensitive emulsion layer. This non-light sensitive layer may be present between two or more emulsion layers having the same color sensitivity. Furthermore, when photosensitive emulsion layers having different color sensitivities are adjacent to each other, it is preferable to provide a non-photosensitive layer between them. Such a non-photosensitive intermediate layer may also contain a scavenger substance for the oxidized color developing agent.

It is also preferable to provide a non-light-sensitive reflective layer under the light-sensitive emulsion layer to improve sensitivity, as described in JP-A-59-160.135. Although not necessarily required, the color photosensitive material of the present invention usually has a yellow color.
Contains a filter layer. The main purpose of this yellow filter layer is to block unnecessary blue sensitivity of the red-sensitive emulsion layer or the green-sensitive emulsion layer, and usually the yellow filter layer is the closest to the high-sensitivity red-sensitive silver halide emulsion layer and the support. Coated between sensitive silver halide emulsion layers. However, even if it is coated on the side close to the support adjacent to the highly sensitive red-sensitive silver halide emulsion layer, the effective sensitivity can be improved without substantially reducing color reproducibility. In this case, it is particularly preferable to use tabular grains for RH whose color sensitization sensitivity (minus blue sensitivity) is relatively higher than the intrinsic sensitivity (blue sensitivity).

The photosensitive material of the present invention has a specific photographic sensitivity of 320 or more,
and the total amount of silver contained in the photosensitive material is 3.0~
It is preferably 13.0 g/mr. Specific photographic sensitivity 32
If it is less than 0, there is no need to adopt the layer structure as in the present invention.

Furthermore, if the amount of silver is 13 g/+d or more, bleaching takes time and it is difficult to shorten the desilvering process.

Specific photographic sensitivity is JISK that measures RSO sensitivity.
Photographic sensitivity obtained by a method according to 7614-1981, after exposing a photosensitive material for sensitometry,
It refers to the photographic sensitivity obtained by developing after 1 hour without leaving it for 5 days using Fuji Photo Film's negative processing prescription CN-16. The reason for shortening the number of days specified in the JIS test method is to obtain results quickly, and the development process is specified as specified by each company.

The details of the test method for measuring this specific photographic sensitivity can be found in Japanese Patent Application Laid-Open No. 1983-226650 (Japanese Patent Application No. 1983-226650).
Patent application 1986- claiming priority based on No. 201756
159115), page (4) [page 440] From the upper left column (
Page 6) [page 442] It is written in the upper right column.

Several methods are known for analyzing the silver content of photosensitive materials, and any method may be used. For example, elemental analysis using fluorescent X-rays is useful.

When the specific photographic sensitivity of the color photosensitive material of the present invention is lower than 320, the effect of the combination of the arrangement order of the layers of the multilayer color negative photosensitive material of the present invention and the amount of silver contained is not very effective. It is. Preferably it is 400 or more, more preferably 800 or more.

Any of silver bromide, silver iodobromide, silver iodochlorobromide, silver chlorobromide and silver chloride may be used as silver halide in the photographic emulsion layer of the silver halide photographic light-sensitive material of the present invention. A preferred silver halide is silver iodobromide containing up to 30 mole percent silver iodide. Particularly preferred is silver iodobromide containing from 2 mol % to 20 mol % silver iodide. In addition, in order to achieve both high sensitivity and high image quality, the average silver iodide content of silver halide in all emulsion layers must be 8 mol% or more, as described in JP-A-60-128,443. It is preferable to

It is known that graininess is significantly improved by increasing the average silver iodide content of silver halide, but if the silver iodide content exceeds a certain level, development speed may be delayed, desilvering, and fixing speed may be reduced. There are drawbacks such as delays.

However, in the present invention, even if the silver iodide content is increased, these drawbacks hardly become a problem, which is very preferable.

The silver halide grains used in the photographic emulsion layer of the silver halide photographic light-sensitive material of the present invention include a core consisting essentially of silver iodobromide containing 5 mol% or more of silver iodide, and a core consisting essentially of silver iodobromide containing 5 mol% or more of silver iodide; It is preferred to have a double structure constituted by a shell consisting essentially of silver iodobromide or silver bromide, the silver iodide content of which is lower than the silver iodide content of the core. The silver iodide content of the core is more preferably 10 mol% or more, and most preferably 20 mol% or more and 44 mol% or less.

The silver iodide content of the shell is preferably 5 mol % or less.

The core may contain silver iodide uniformly, or may have a multilayer structure consisting of phases having different silver iodide contents. In the latter case, the silver iodide content of the phase with the highest silver iodide content is 5 mol% or more, more preferably 10
% by mole or more, and the silver iodide content of the shell is lower than that of the highest silver iodide content phase of the core. or,
"Substantially composed of silver iodobromide" means that it is mainly composed of silver iodobromide, but may also contain up to about 1 mol% of other components (for example, silver chloride). do.

In a further preferred embodiment of the silver halide grains used in the photographic emulsion layer of the silver halide photographic light-sensitive material of the present invention, the silver halide grains have a diffraction angle (2θ) in the range of 38 to 42°, and the silver halide grains are When we obtain a curve of diffraction intensity versus diffraction angle for the (220) plane of In addition, the particles have a structure such that the diffraction intensity corresponding to the core portion is 1/10 to 3/1 of that of the shell portion. Particularly preferably, the diffraction intensity ratio is 115 to 3/'1, more preferably 1/3 to 3/1.

This double structure makes it possible to use a high iodine silver iodobromide emulsion without causing a delay in development speed, and achieves a photosensitive material with excellent grain consistency even with a small amount of coated silver. be able to.

The average grain size of the silver halide grains in a photographic emulsion (grain diameter for spherical or near-spherical grains).

In the case of cubic particles, the principal is the particle size, and the projected area is also expressed as an average. ) is not particularly important, but 0.05
The thickness is preferably 10 μm or more. The average size of silver halide grains in each emulsion layer with the highest sensitivity is 0.5
The range is preferably 0.6 μm or more, 2.
More preferably, the thickness is 5 μm or less.

The particle size distribution may be narrow or wide.

The silver halide grains in the photographic emulsion may have a regular crystalline structure such as a cube or a hexagonal, or may have a spherical or hexagonal shape.
It may have an irregular crystalline shape such as a plate shape, or it may have a composite shape of these crystalline shapes. It may also consist of a mixture of particles of various crystalline forms.

Further, it is preferable to use tabular grains having a high color sensitization efficiency using a sensitizing dye and having an aspect ratio of 5 or more.

Tabular grains are described in Fetographic Science and Engineering by Gutoff.

Photographic 5science and
Engineering)-, Volume 14, 248-25
7 pages (1970); U.S. Patent Nos. 4,434,226, 4,414,310, 4,433,048,
No. 4,439,520 and British Patent No. 2,112.
It can be easily prepared by the method described in No. 157 and the like.

The photographic emulsion used in the present invention is P, Glafkide.
Written by Chin+ie et Physique Pho
tographique (Pau1Monte1, 1967), Pho by G. F. Duffin
tographic Emulsion Chemises
try (The Focalpress, 1966
), V. L., Zelikn+an et al.
AuthorMaking and Coating Photo
Graphic Emulsion (The Foca
1 Press, 1964). That is, any of the acidic method, neutral method, ammonia method, etc. may be used, and the method for reacting the soluble root salt with the soluble halogen salt may be any one-sided mixing method, simultaneous mixing method, or a combination thereof. good.

It is also possible to use a method in which particles are formed in an excess of silver ions (so-called back-mixing method).

As one type of simultaneous mixing method, a method in which pl'1g in the liquid phase in which silver halide is produced can be kept constant, that is, a so-called Chondrald double jet method can also be used. According to this method, a silver halide emulsion having a regular crystal shape and a nearly uniform grain size can be obtained.

Two or more silver halide emulsions formed separately may be mixed and used in one emulsion layer.

The silver halide emulsion used in the present invention has a crystal plane defined by the Miller index (nnl) (n≧2, n is a natural number) on the outer surface as described in Japanese Patent Publication No. 486-9598. Silver halide grains are preferably used.

Also preferably used is a silver halide emulsion having a hollow conductive portion from the surface toward the inside, as described in JP-A-61-75337. Such a silver halide emulsion having a large specific surface area is more effective when combined with the present invention because it is easier to achieve sensitivity than an emulsion having the same volume, especially when color sensitized.

Also, JP-A-57-133540, JP-A No. 58-1085
Composite grains in which silver salts having different compositions are epitaxially grown on host grains as described in No. 26 or No. 59-162540 can be preferably used in the present invention. Since such particles exhibit photographic properties with high sensitivity and high contrast, they are preferably used in combination with the present invention.

Also, JP-A-61-14630 and JP-A-60-122
The silver halide emulsion grown in the presence of tetrazaindene as described in No. 935 has a high silver iodide content and excellent monodispersity, so it exhibits high sensitivity and excellent graininess. It is preferably used as a silver halide emulsion.

Also, as shown in Japanese Patent Application Laid-Open No. 58-126526,
Silver halide emulsions subjected to gold sulfur sensitization or gold selenium sensitization in the presence of a nitrogen-containing heterocyclic compound exhibit low fog and high sensitivity and are therefore preferably used as silver halide emulsions for use in the present invention.

Also, JP-A-59-149345 or JP-A No. 59-1
The slightly rounded cubic or tetradecahedral crystals described in No. 49344 are preferred as silver halide emulsions for use in the present invention because of their high sensitivity performance.

In the process of silver halide grain formation or physical ripening, cadmium salts, zinc salts, lead salts, thallium salts, iridium salts or complex salts thereof, rhodium salts or complex salts thereof, iron salts or complex salts thereof, etc. may be allowed to coexist.

Among these, silver halide emulsions whose grains are formed in the coexistence of iridium are highly sensitive (Japanese Patent Publication No. 43-49
No. 35, Japanese Patent Publication No. 45-32738) is particularly preferred as the silver halide emulsion used in the present invention.

After the emulsion is precipitated or physically ripened, soluble salts are usually removed. For this purpose, the long-known Tardel water washing method, which involves gelling gelatin, may be used. Inorganic salts such as sodium sulfate, anionic surfactants, anionic polymers (e.g. polystyrene sulfonic acid), or gelatin derivatives (e.g. aliphatic acylated gelatin, aromatic acylated gelatin, aromatic carbamoylated gelatin, etc.) A flocculation method may also be used.

Silver halide emulsions are usually chemically sensitized.

For chemical sensitization, for example H, Fr1eser 11
74 “DieGrundlagender Photo
graphischen Prozesse mitS
ilber-halogeniden” (Akad
emischeVerlagsgesellchaft
, 1968), pages 675-734, can be used.

Namely, sulfur sensitization using active gelatin and sulfur-containing compounds that can react with silver (e.g., thiosulfates, thioureas, mercapto compounds, rhodanines); reducing substances (e.g., stannous salts); , amines, hydrazine derivatives, formamidine sulfinic acid, silane compounds); using noble metal compounds (e.g., complex salts of metals in group I of the periodic table such as gold complexes, Pt, Ir, Pd, etc.) Noble metal sensitization methods can be used alone or in combination.

Further, it is preferable to use a selenium sensitization method using a selenium-containing compound that can react with active gelatin or silver in combination with other sensitization methods because a highly sensitive emulsion can be obtained. This technology is described in U.S. Pat. No. 1,574,944;
No. 592, No. 1.623.499, Special Publication No. 52-38
No. 408, Japanese Patent Publication No. 57-22090, Japanese Patent Publication No. 59-1
No. 80536, US Pat. No. 4,565,778, Japanese Patent Application Laid-open No. 185329/1982, and Japanese Patent Application Laid-open No. 60450046.

The photographic emulsion used in the present invention is spectrally sensitized with methine dyes and other dyes, if necessary. The dyes used include cyanine dyes, merocyanine dyes, complex cyanine dyes, complex merocyanine dyes, holopolar cyanine dyes, hemicyanine dyes, styryl dyes and hemioxonol dyes. Particularly useful dyes are those belonging to the cyanine dyes, merocyanine dyes, and complex merocyanine dyes. Any of the nuclei commonly used for cyanine dyes can be used as the basic heterocyclic nucleus for these dyes. That is, pyrroline nucleus, oxazoline nucleus, thiazoline nucleus, pyrrole nucleus, oxazole nucleus, thiazole nucleus, selenazole nucleus, imidazole nucleus, tetrazole nucleus, pyridine nucleus, etc.; a nucleus in which an alicyclic hydrocarbon ring is fused to these nuclei; and these A nucleus in which an aromatic hydrocarbon ring is fused to the nucleus of Thiazole nuclei, quinoline nuclei, etc. can be applied. These nuclei may be substituted on carbon atoms.

Merocyanine dyes or complex merocyanine dyes include a core with a ketomethylene structure, such as a birapurin-5-one core, a thiohydantoin core, and a 2-thioxazolindin-
2,4-dione nucleus, thiazolidine-2,4-dione nucleus,
A 5- to 6-membered heterocyclic ring nucleus such as a rhodanine nucleus or a thiobarbyl nucleus can be applied.

Useful sensitizing dyes include, for example, German Patent No. 929.0
No. 80, U.S. Patent No. 2,231,658, U.S. Patent No. 2,493
, No. 748, No. 2.503.776, No. 2,519,
No. 001, No. 2,912,329, No. 3,656,9
No. 59, No. 3,672,897, No. 3,694,21
No. 7, No. 4,025,349, No. 4,046,572
No., British Patent No. 1.242,588, Special Publication No. 1977-14
Examples include those described in No. 030 and No. 52-24844.

These sensitizing dyes may be used alone or in combination, and combinations of sensitizing dyes are often used particularly for the purpose of supersensitization.

A typical example is U.S. Patent No. 2,688,545, 2.9
No. 77, 229, No. 3,397,060, No. 3,52
No. 2,052, No. 3,527,641, No. 3,617
, No. 293, No. 3,628.964, No. 3,666.
No. 480, No. 3,672,898, No. 3,679,4
No. 28, No. 3,703.377, No. 3,769,30
No. 1, No. 3,814,609, No. 3,837,862
No. 4,026,707, British Patent No. 1,344,2
No. 81, No. 1.507, 803, Special Publication No. 43-493
No. 6, No. 53-12375, JP-A No. 52-11061
No. 8, No. 52-109925.

Along with the sensitizing dye, it is a dye that itself does not have a spectral sensitizing effect or a substance that does not substantially absorb visible light,
A substance exhibiting supersensitization may also be included in the emulsion. for example,
Aminostyl compounds substituted with nitrogen-containing heterocyclic groups (for example, U.S. Pat. No. 2,933,390, U.S. Pat. No. 3,635,7)
21), aromatic organic acid formaldehyde condensates (such as those described in US Pat. No. 3,743,510), cadmium salts, azaindene compounds, and the like.

U.S. Patent No. 3,615,613, U.S. Patent No. 3,615,641
The combinations described in No. 3,617,295 and No. 3,635,721 are particularly useful.

Photographic additives that can be used in the present invention are described in Research Disclosure No. N1117643 and Research Disclosure No. M18716, and the relevant sections are summarized in the table below.

Chemical aggravator Sensitivity enhancer 4 Brightener 9 Hardener 10 Binder 11 Plasticizer, lubricant RD17643 23 pages RD18716 648 pages Right column Same as above 26 pages 26 Pages 27 Page 651 Left column Same as above 650 Pages Right column In addition, formaldehyde gas In order to prevent deterioration of photographic performance due to is preferred.

Various color couplers can be used in the present invention, specific examples of which can be found in the above-mentioned Research Disclosure (
RD) N117643, ■-C-G.

As a yellow coupler, for example, U.S. Patent Tube 3.93
No. 3,501, No. 4.022,620, No. 4.3
No. 26,024, No. 4,401,752, No. 4,2
48,961, Japanese Patent Publication No. 58-10739, British Patent No. 1,425.020, British Patent No. 1,476.760,
U.S. Patent No. 3,973.968, U.S. Patent No. 4.314.0
No. 23, No. 4,511.649, European Patent No. 249
, No. 473 A, etc. are preferred.

As magenta couplers, 5-pyrazolone and pyrazoloazole compounds are preferred, and US Pat.
No. 0,619, No. 4,351,897, European Patent No. 73.636, US Patent No. 3,061,432, US Patent No. 3,725.067, Research Disclosure No. 24220 (June 1984) month), JP-A-60-3
No. 3552, Research Disclosure N1124
230 (June 1984), JP 60-43659, JP 6172238, JP 60-35730, JP 55
Particularly preferred are those described in US Pat. No. 4,500,630, No. 4,540,654, US Pat.

Cyan couplers include phenolic and naphthol couplers, and are disclosed in U.S. Patent No. 4,052,212.
No. 4.146,396, No. 4.228,23
No. 3, No. 4.296.200, No. 2,369.9
No. 29, No. 2.801, 171, No. 2.772.
No. 162, No. 2,895,826, No. 3.772
, No. 002, No. 3,758,308, No. 4.33
No. 4,011, No. 4,327,173, West German Patent Publication No. 3.329,729, European Patent No. 121,365
No. A, No. 249, 453 A, U.S. Patent No. 3,44
No. 6,622, No. 4.333,999, No. 4.4
No. 51,559, No. 4,427,767, No. 4,
No. 690.889, No. 4,254,212, No. 4
．． 296.199, JP-A No. 61-42658, etc. are preferred.

Colored couplers for correcting unnecessary absorption of coloring dyes are available at Research Disclosure Floor 17643.
- Section G, U.S. Patent No. 4,163.670, Special Publication No. 1983
-39413, U.S. Patent No. 4.004,929, U.S. Patent No. 4.138,258, British Patent No. 1,146,36
The one described in No. 8 is preferred.

Couplers whose colored dyes have appropriate diffusivity include U.S. Patent No. 4,366.237 and British Patent No. 2.125.
, 570, European Patent No. 96,570, and German Patent Publication No. 3,234,533 are preferred.

Typical examples of polymerized dye-forming couplers are U.S. Pat.
No. 4,576.910, British Patent No. 2.102
．． It is described in No. 173, etc.

Couplers that release photographically useful residues upon coupling are also preferably used in the present invention. QIR couplers releasing development inhibitors include the aforementioned RD17643,
■-Patent listed in Section F, JP-A-57-151944
No. 57-154234, No. 60184248,
No. 63-37346, U.S. Patent No. 4,248,962
Preferably, those listed in No.

Couplers that release a nucleating agent or a development accelerator imagewise during development include British Patent No. 2,097,140;
No. 2,131,188, JP 59-157638
No. 59-170840 is preferred.

In addition, examples of couplers that can be used in the photosensitive material of the present invention include competitive couplers described in U.S. Pat. No. 4,130,427, U.S. Pat. , DIR redox compound releasing couplers or DIR couplers described in JP-A-60-185950, JP-A-62-24252, JP-A-62-291645, etc. Releasing coupler or DIR coupler Releasing redox compound or DIR redox compound Releasing redox, coupler releasing a dye that recolors after separation as described in European Patent No. 173,302A, R, D, N1
11449, 24241, JP-A-61-201247
No. 4, U.S. Pat.
Examples include Gantt release couplers described in No. 553,477 and the like.

Table A lists specific examples of color couplers that can be used in the present invention, but is not limited thereto.

The coupler used in the present invention can be introduced into the light-sensitive material by various known dispersion methods.

Examples of high boiling point solvents used in the oil-in-water dispersion method are described in US Pat. No. 2.322.027 and the like.

Specific examples of high-boiling organic solvents with a boiling point of 175°C or higher at normal pressure used in the oil-in-water dispersion method include phthalic acid esters (e.g., dibutyl phthalate, dicyclohexyl phthalate, di-2-ethylhexyl phthalate, Decyl phthalate, bis(2゜4-di-t-amylphenyl)
Phthalate, bis(2,4-di-t-amylphenyl)
isophthalate, bis(1,1-diethylpropyl) phthalate), esters of phosphoric or phosphonic acids (e.g. triphenyl phosphate, tricresyl phosphate, 2-ethylhexyl diphenyl phosphate, tricyclohexyl phosphate, tri-2-ethylhexyl) phosphate, tridodecyl phosphate, tributoxyethyl phosphate, trichloropropyl phosphate, di-2-ethylhexyl phenyl phosphonate), benzoic acid esters (e.g. 2-ethylhexylbenzoate, dodecylbenzoate, 2-ethylhexyl-p-hydroxybenzoate) , amides (e.g. N,N-diethyldodecanamide, N,N-diethyllaurylamide, N-tetradecylpyrrolidone), alcohols or phenols (e.g. isostearyl alcohol, 2.4 di-t-amylphenol), fats. Group carboxylic acid esters MC such as bis(2-ethylhexyl) sebacate, dioctyl azelate, glycerol tributyrate, isostearyl lactate, trioctyl citrate), aniline derivatives such as N, N-dibutyl-2-butoxy-5 -octylaniline),
Examples include hydrocarbons (for example, paraffin, dodecylbenzene, diisopropylnaphthalene), and the like. Further, as an auxiliary solvent, the melting point is about 30°C or higher, preferably 50°C.
Any solvent having a temperature above about 160° C. or below can be used, and typical examples include ethyl acetate, butyl acetate, ethyl propionate, methyl ethyl ketone, cyclohexanone, 2-ethoxyethyl acetate, dimethylformamide and the like.

Specific examples of latex dispersion process steps, effects, and latex for impregnation include U.S. Pat. It is described in.

The present invention can be applied to various color photosensitive materials. Typical examples include color negative film for general use or movies, and color reversal film for slides or television.

Suitable supports that can be used in the present invention include, for example, the above-mentioned R
D,'! '1kL17643 page 28 and the same magnetic 1B
716, from the right column on page 647 to the left column on page 648.

The color photographic light-sensitive material according to the present invention has the above-mentioned RD, 1
1, 11764.3, pages 28-29, and 187
16, No. 651, left column to right column.

The color developing solution used in the development of the light-sensitive material of the present invention is preferably an alkaline aqueous solution containing an aromatic primary amine color developing agent as a main component. Aminophenol compounds are also useful as color developing agents, but p-phenylenediamine compounds are preferably used, representative examples of which include 3-methyl-4-amino-N, N-diethylaniline, 3- Methyl-4-amino-N-ethyl-N
-β-hydroxyethylaniline, 3-methyl4-amino-N-ethyl-N-β-methanesulfonamidoethylaniline, 3-methyl-4-amino-N-ethyl-N-
Examples include β-methoxyethylaniline and their sulfates, hydrochlorides, and p-)luenesulfonates. Two or more of these compounds can be used in combination depending on the purpose.

The color developer may contain pH buffering agents such as alkali metal carbonates, borates or phosphates, development inhibitors such as tetrabromide salts, iodide salts, benzimidazoles, benzothiazoles or mercapto compounds or It generally contains antifoggants and the like. In addition, if necessary, hydroxylamine, diethylhydroxylamine, sulfite hydrazines, phenyl semicarbazides, triethanolamine, catechol sulfonic acids, triethylenediamine (4-diazabicyclo[2゜2.2]octane), etc. Various preservatives, organic solvents such as ethylene glycol and diethylene glycol, benzyl alcohol, polyethylene glycol, quaternary ammonium salts,
Development accelerators such as amines, dye-forming couplers, fogging agents such as competing couplers sodium boron hydride, auxiliary developing agents such as 1-phenyl-3-virapritone, viscosity-imparting agents, aminopolycarboxylic acids, aminopolyphosphones. Various chelating agents such as acids, alkylphosphonic acids, and phosphonocarboxylic acids, such as ethylenediaminetetraacetic acid, nitrilotriacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, hydroxyethyliminodiacetic acid, and ■-hydroxyethylidene- 1
, 1-didiphosphonic acid, nitrilo-N,N,N-trimethylenephosphonic acid, ethylenediamine-N,N.

Representative examples include N',N'-tetramethylenephosphonic acid, ethylene glycol (0-hydroxyphenylacetic acid), and salts thereof.

Further, when performing reversal processing, black and white development is usually performed and then color development is performed. This black and white developer contains known black and white developing agents such as dihydroxybenzenes such as hydroquinone, 3-pyrazolidones such as -phenyl-3-pyrazolidone, or aminophenols such as N-methyl-p-aminophenol. Alternatively, they can be used in combination.

The pH of these color developing solutions and black and white developing solutions is generally 9 to 12. Although the amount of replenishment of these developing solutions depends on the color photographic light-sensitive material being processed, it is generally less than 3β per square meter of light-sensitive material, and by reducing the bromide ion concentration in the replenisher, 500 mJ
! You can also do the following: When reducing the amount of replenishment, it is preferable to prevent evaporation of the liquid and air oxidation by reducing the area of contact with the air in the processing tank. Furthermore, the amount of replenishment can be reduced by using means for suppressing the accumulation of bromide ions in the developer.

Example 1 On a subbed cellulose triacetate film support,
Sample 101, which is a multi-tank color photosensitive material consisting of each layer having the composition shown below, was prepared.

(Composition of photosensitive layer) The coating amount is g/g for silver halide and colloidal silver.
The amount of silver expressed in %, the amount expressed in g/n (for additives and gelatin), and the amount expressed in moles per mole of halogenated 5'f3 in the same layer for sensitizing dyes. .

Note that the symbols indicating additives have the meanings shown below. However, if a substance has multiple effects, one of them is listed as a representative.

Uv: ultraviolet absorber, 5olvs high boiling point organic solvent,
W: coating aid, H: hardener, ExS: sensitizing dye, ExC
Nijian coupler, ExM: Magenta coupler, ExY
: Yellow coupler, Cpd: Additive 1st layer: Antihalation layer Black colloid coating amount Silver coating amount 0.2 Gelatin
2.2U V -10,1 U V -20,2 Cpd-I Q,Q5Solv-
10,01 Solv-20,01 Solv-30,08 2nd layer; Intermediate layer fine grain silver bromide (equivalent sphere diameter 0.07 μm)'XM coating amount
0.15 Gelatin 1. OCp d −
20,2 Third layer: Low-sensitivity red-sensitive emulsion layer (RL) Silver iodobromide emulsion (Ag1 10.0 mol%, internal high Agl
Type, equivalent sphere diameter 0.8 μm, coefficient of variation of equivalent sphere diameter 28%,
Plate-like grains, diameter/thickness ratio 3.0) Silver-coated 1097 silver iodobromide emulsion (AgI 6.0 mol%, internal high Agl type, equivalent sphere diameter 0.5 μm, coefficient of variation of equivalent sphere diameter 26%, plate shaped particles, diameter/thickness ratio 3.0) Silver coating amount 0.5 Gelatin 2.0ExS-14,
5X10-'mol ExS-21, 5X10-'mol ExS-3o, 4xio-'mol ExS-40, 3X10-'mol ExC-10,55 ExC-20,01 ExC-30,03 Solv-10,2 Solv- 30,2 4th layer: Medium red-sensitive emulsion layer (RM) Silver iodobromide emulsion (Ag1 10.0 mol%, internal high AgI
Type, equivalent sphere diameter 1.0 μm, coefficient of variation of equivalent sphere diameter 30%,
Plate-shaped particles, diameter/thickness ratio 4.0) Coating amount 1.2 1.5 -2 ExS-3 ExS-4 ExC-I ExC-3 ExC-4 o1v-1 o1v-2 5th layer: Intermediate layer gelatin Cpd-4 1,0 0,15 4 moles 4 moles 4 moles 6th layer :Low-sensitivity green-sensitive emulsion N (GL) Silver iodobromide emulsion Ag1 (10.0 mol%) Internal high AgI
Type, equivalent sphere diameter 0.8 μm, coefficient of variation of equivalent sphere diameter 28%,
Plate grains, diameter/thickness ratio 3.0) Silver coating amount 0.2 Silver iodobromide emulsion (Ag1 6.0 mol%, internal high Agl
Type, equivalent sphere diameter 0.5 μm, coefficient of variation of equivalent sphere diameter 26%,
Plate-shaped particles, diameter/thickness ratio 3.0) 8! Coating amount 0.1 Gelatin 1.4ExS-55X
10-'mol ExS-62X10'''mol ExS-71 ) Silver iodobromide emulsion (Ag1 10.0 mol%, internal high iodine type, equivalent sphere diameter 0.85 μm, coefficient of variation of equivalent sphere diameter 28%
, plate-shaped particles, diameter/thickness ratio 3.0) Silver coating amount 1.0 Gelatin 0.75EXS-53
,5X10-'mol EXS-61,4X 10-4 moBv ExS-70,7X10-'mol ExM-10,25 ExM-30,05 Solv-10,15 8th layer: Intermediate layer gelatin 0.5Cpd-60 ，
07 9th layer: High-sensitivity red-sensitive emulsion layer (RH) Silver iodobromide emulsion (Ag1 10.0 mol%, inner cylinder Agl
Type, equivalent sphere diameter 1.5 μm, coefficient of variation of equivalent sphere diameter 32%,
Platy particles, diameter/thickness ratio 6.0) Silver coating amount 1゜5 1.4 2X10-'mol 0.6X10-'mol 0.2xlO-'mol 0.03 0.13 0゜12 0.12 Gelatin xS-1 X5-2 xS-3 xC-4 xC-5 o1v-1 o1v-2 10th layer: Intermediate layer gelatin 1.3Cp d -4
0.2 Fine particle silver bromide (equivalent sphere diameter 0.07 μm) Coating amount of silver
0.4 11th layer: High-sensitivity green-sensitive emulsion layer (G H) Silver iodobromide emulsion (
Ag1 10.0 mol%, internal high AgI type, equivalent sphere diameter 1
．． 5 μm, coefficient of variation of equivalent sphere diameter 32%, plate-like particles, diameter/thickness ratio 6.0) Silver coating amount 1.0 Gelatin 1.2ExS-5zx
to-'mol ExS-6o, 5xto-'mol ExS-70, 8xlO-'mol EXM-40,15 ExM-10,03 ExC-40,005 Solv-10,2 12th layer: Yellow filter layer Cp d - 30.05 Gelatin 0.5S o l v
-10,1 13th layer; middle layer gelatin 0.5Cp d -2
0,1 14th layer: Low sensitivity blue-sensitive emulsion layer (BL) Silver iodobromide emulsion (Agl 8.5 mol%, internal high iodine type, equivalent sphere diameter 0.7 μm, coefficient of variation of equivalent sphere diameter 21%,
Octahedral grains) Silver coating amount 0.2 Silver iodobromide emulsion (Agl 3.0 mol%, internal high iodine type, equivalent sphere diameter 0.3 μm, coefficient of variation of equivalent sphere diameter 22%,
Octahedral particles) 1 coated amount 0. 1 Gelatin 1.2ExS-83X
10-'mol Ex Y -10,7 ExY-20,03 Solv-10,5 15th layer: Medium-sensitivity blue-sensitive emulsion i (BM) Silver iodobromide emulsion (
Ag1 10.0 mol%, internal high AgI type, equivalent sphere diameter 1
．． 0 p m, coefficient of variation of equivalent sphere diameter 30%, plate-like particles,
Diameter/thickness ratio 4.0) Silver coating amount 0.4 Gelatin 0.3ExS-82x
lO-'mol Ex Y -10,3 Solv-10,2 16th eyebrow: Intermediate layer fine grain silver iodobromide (Agl 2 mol%, uniform type, equivalent sphere diameter 0.13 μm) Silver coating amount 0.4 Gelatin 0.36 17th layer: High-sensitivity blue-sensitive emulsion layer (B H) Silver iodobromide emulsion (Ag1 14
．． 0 mol%, internal high Agl type, equivalent sphere diameter 2.1 μm, coefficient of variation of equivalent sphere diameter 30%, plate-like particles, diameter/thickness ratio 5.
0) Silver coating amount 1.4 Gelatin 1.1ExS-8t,
5xto-'mol Ex Y-10,2 Solv-10,14 18th layer: 1st protective layer gelatin 1.8U V-10
,1 UV-20,2 Solv-10,01 Solv-20,01 19th layer: 2nd protective layer fine grain silver bromide (equivalent sphere diameter 0.07 μm)! I! Application amount
0.3 Gelatin 0.7 Polymethyl methacrylate particles (diameter 1.5 μm) 012W-10,0
2 H-10,4 Cpd-51,0 The structural formulas of the compounds used are shown in Table 8.

As shown in Table 1, sample 102 is obtained by replacing the 9th and 11th layers of sample 101, sample 103 is obtained by changing the 10th layer to a yellow filter layer and the 12th layer is removed, and sample 102 is obtained by replacing the 9th and 11th layers of sample 101.
Sample 104 was prepared by removing the twelfth layer of the sample. The amount of silver and the amount of compound applied in each sample were expressed as increases and decreases from Sample 101.

Sunawachi, Sample 102 (7) 9th layer (DSJujt +
0.1 g is based on the 08th layer of sample 101, and the silver amount -0.5 g of the 11th layer of sample 102 is based on the RH of sample 101. Similarly, the 10th yellow filter layer of sample 103 is also similar to that of sample 101.
Cpd-4+ 0.2 for the yellow filter layer of
g, etc. The amount of sensitizing dye was varied in proportion to the amount of silver.

After the samples 101 to 104 were subjected to imagewise exposure, they were subjected to the next process.

Color development processing was carried out at 38° C. according to the following processing steps.

Color development 3 minutes 15 seconds Bleach White 6 minutes 30 seconds Water Wash 2 minutes 10 seconds Fixed arrival time: 4 minutes 20 seconds Water Wash 3 minutes 15 seconds Safe Fixed 1 minute 05 seconds The composition of the treatment liquid used in each step was as follows.

Color developer diethylenetriamine pentaacetic acid 1-hydroxyethylidene 1.1-diphosphonic acid Sodium sulfite Potassium carbonate Potassium bromide Potassium iodide Hydroxylamine sulfate 4-(N-ethyl-N-β- 1,0g 2.0g 4.0g 30.0 g 1.4 g 1.3 mg 2.4 g Hydroxyethylamino)-2-methylaniline sulfate 4.5 g Add water
1.01 pH 10.0 Bleach solution Ethylenediaminetetraacetic acid ferric ammonium salt Ethylenediaminetetraacetic acid - Sodium salt Ammonium bromide Ammonium nitrate Add water Fixer Ethylenediaminetetraacetic acid disodium salt Sodium sulfite Ammonium thiosulfate aqueous solution (70%) Sodium bisulfite 100 .0g 10,0g 150.0g 10,0g 1゜0R pH6,0 1,0g 4.0g 175.0ml! 4.6g Add water 1.0! ! pH6
,6 Stabilized liquid formalin (40%) 2.0 ml
Added 0.3 g of polyoxyethylene-p-monononylphenyl ether (average degree of polymerization 10) to 1.01. The density of the resulting image was measured to determine the relative sensitivity. The results are shown in Table 2. The sensitivity was determined by the exposure amount at a density of fog density + 0.1, and was expressed as a relative value with the sensitivity of B, G, and R of sample 101 set as 100.

Table 2 Also, when the RMS value was measured using a 48 μm diameter aperture after exposure and similar color development through a stepped wedge for RMS grain measurement, the R density DI = 0.
．． The measured values of samples 101 to 104 at No. 6 were respectively 0.
0293.0.0260゜0.0270,0.0270
was gotten.

From the above results, samples 102 to 104 having the structure of the present invention are 1
It was found that the sensitivity of the red-sensitive layer was higher and the graininess was better despite the lower amount of silver than in Sample No. 01, demonstrating the effects of the present invention.

Example 2 The 8th layer of the sample 102 of Example 1 was removed, and the 3rd layer of the 9th layer was removed.
Sample 102 except that the coating amount of the green photosensitive layer was reduced by 15%.
Sample 201 was prepared in the same manner as above.

When the same treatment as in Example 1 was applied, samples 102 and 2
The sensitivity of 01 was almost the same, but R at D = 0.6
The MS measurement values are 0.0265° and 0.0310, respectively, indicating that the graininess of the green photosensitive layer deteriorates when the eighth layer is removed.

Example 3 Samples 101 to 104 of Example 1 were stored at room temperature for 9 months, and then treated in the same manner as in Example 1 to measure graininess. As a result, sample 101 with R concentration = 0.6
The measured values of ~104 are 0.0363, 0.030, 0.0
315, 0.0320 was obtained, indicating that the deterioration of graininess over time was small in the sample of the present invention.

Example 4 Sample Lot, 102 from Example 1 was given a uniform exposure of 5 CMS and passed through the processing of Example 1. At this time, the bleaching process time was changed and the remaining Hit was 6 μg/
The time required for the temperature to drop below cal was determined. As a result, sample 101
was 4 minutes 10 seconds, and sample 102 was 3 minutes 30 seconds. It can be seen that the sample of the present invention can shorten the processing steps.

〔Effect of the invention〕

When the layer arrangement of the present invention is adopted, the layer arrangement (support, RL), which has been conventionally considered desirable for high sensitivity.

RM, GL, GM, RH, GH, YF, BL.

A desired photographic sensitivity can be achieved with a smaller amount of coated silver than silver halide color light-sensitive materials according to the standards (BM, BH, PL). Therefore, the burden of desilvering after color development is small, making it suitable for rapid processing. In addition, as a result of being able to achieve a desired high sensitivity with a smaller amount of coated silver, a decrease in sensitivity due to natural radiation during storage of the raw photosensitive material, an increase in fogging, etc. are suppressed, and a color photosensitive material for photography with good storage stability is produced. can get.

Table A C-+3) C-(41 C-(21 C-(51 C-(71 CH.

C-+61 10CH□CH÷-r---10CH.

CI+÷ko=-+Chz CH÷1 C-T8) molecular weight about 40.000 C-Qυ scream CoIC4H9 l H C-031 C-Q4) C-α one C-θ Enoki H :) U3Na C-θe CI+3 -CCHz C)■3---←C)I　, -CH 10th corner n 5CH, niH, niU, 11 +21 C-(21) H C-(22) C-(26) H C) 13 l 0 ■ \ Q) C, I( C-(30) c - (31) C-(34) H 0 ■ C-(37) H C (3 days) C-(39) e C-(41) C-(46) niN p H C II C-(55) CJ+t(L) C C-(61) H C5H.

CH.

I C C-(66) 0zCHs C-(72) CI! H H CO□H Cl1゜ C-(73) 0H No. table U■ ■ C11゜ H3 1011□ C--→,-+C1h C-Kun IV-2 xM xC H 2 ExC-1 ExM-1 Shil ExM ExC ExC-5 CIZI (ffis ExM-4 death! ExM-5 ExY-1 ExY xS xS C.11.

C.11.

xS ■ xS xS xS-8 xS-7 o1 (CI(z)*5OJN(CtHs):+o1 pd pd-4 H pd ■ pd H ]1 p d ■

Claims (1)

[Claims] (1) Sequentially from the side farthest from the support: at least one blue-sensitive silver halide emulsion layer, a high-sensitivity red-sensitive silver halide emulsion layer, a high-sensitivity green-sensitive silver halide emulsion layer, and a low-sensitivity silver halide emulsion layer. A silver halide color light-sensitive material provided on a support with a green-sensitive silver halide emulsion layer and a low-sensitivity red-sensitive silver halide emulsion layer adjacent to each other, or with a non-light-sensitive layer interposed as necessary.