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JPH01287190A - Abrasive lubricant for glass processing - Google Patents

Abrasive lubricant for glass processing

Info

Publication number
JPH01287190A
JPH01287190A JP11769888A JP11769888A JPH01287190A JP H01287190 A JPH01287190 A JP H01287190A JP 11769888 A JP11769888 A JP 11769888A JP 11769888 A JP11769888 A JP 11769888A JP H01287190 A JPH01287190 A JP H01287190A
Authority
JP
Japan
Prior art keywords
water
benzotriazole
acid
glass processing
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11769888A
Other languages
Japanese (ja)
Other versions
JPH0623395B2 (en
Inventor
Atsushi Hatanaka
畑中 敦史
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Matsumura Oil Research Corp
Original Assignee
Matsumura Oil Research Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsumura Oil Research Corp filed Critical Matsumura Oil Research Corp
Priority to JP63117698A priority Critical patent/JPH0623395B2/en
Publication of JPH01287190A publication Critical patent/JPH01287190A/en
Publication of JPH0623395B2 publication Critical patent/JPH0623395B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C19/00Surface treatment of glass, not in the form of fibres or filaments, by mechanical means

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)

Abstract

PURPOSE:To obtain the title lubricant with high machinability, causing no cloggings in whetstone, enhancing processing efficiency, by incorporating a base consisting of water and/or a polyhydric alcohol with a benzotriazole or a specific chelating agent. CONSTITUTION:The objective lubricant can be obtained by incorporating a base consisting of water and/or a polyhydric alcohol with (A) 0.1-10 (pref. 1-3)wt% of a benzotriazole such as benzotriazole or tolyltriazole or an aminocarboxylic acid-based chelating agent such as ethylenediaminetetraacetic acid or nitrilotriacetic acid, and furthermore, if needed, (B) an organophosphorus- or boron-based detergent.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明はガラス、特に光学用部品に用いられるガラスの
表面をダイヤモンド砥石、グイヤそンドベレット或いは
ラッピングマシン等により研削または研磨をVる際に使
用する研磨油剤に関するものである。更に詳しくは、ガ
ラス表面に作用して高い研削性を得ると共に、砥石の1
1詰りに起因する研削性の低下を解消して、高研削性を
持続さゼ得るガラス加工用の研磨油剤に関するものであ
る。。
Detailed Description of the Invention (Field of Industrial Application) The present invention is used for grinding or polishing the surface of glass, particularly glass used for optical parts, with a diamond grindstone, a guysonde pellet, a lapping machine, etc. The present invention relates to a polishing oil. More specifically, it works on the glass surface to obtain high grindability, and also
The present invention relates to a polishing oil for glass processing that eliminates deterioration in grindability caused by clogging and maintains high grindability. .

(従来の技術) ガラスの一般的な加工は次のような方法で行われている
(Prior Art) Glass is generally processed by the following method.

切断・プレス−→研削(荒ずり)−→ラッピング(砂か
け)−→研磨(ポリッシング)−→芯取り・化学処理 研削工程では、ダイヤモンド砥石を用いて球面或いは平
面研削により研削処理する。
Cutting/pressing -> Grinding (roughing) -> Lapping (sanding) -> Polishing -> Centering/chemical treatment In the grinding process, a diamond grindstone is used to perform spherical or surface grinding.

ラッピング工程では、鋳鉄工具と微細砥粒とでラッピン
グマシンを用いて形状精度と仕上げ面粗さを向上させる
ための加工が行われるが、最近の傾向として技能依存度
低減のため、比較的低精度の光学部品を対象としで、ラ
ッピング工程でt離砥粒のかわりに固定砥粒であるダイ
ヤモンドベレットを利用した加工が行われるようになっ
てきている。
In the lapping process, processing is performed using a lapping machine with cast iron tools and fine abrasive grains to improve shape accuracy and finished surface roughness, but the recent trend is to reduce skill dependence, resulting in relatively low precision. In the lapping process, diamond pellets, which are fixed abrasive grains, are being used instead of T-abrasive grains in the lapping process for optical components.

これらガラスの研削研磨加工には、潤滑剤として専ら水
が用いられている。しかしながら水のみを用いた場合、
砥石が目詰りをおこして研削性が低下しやすく、そのほ
かにも機械の錆や糸状菌による腐敗等の問題がおこりや
すい。それゆえ一部の加工業者では、一般に金属類の研
削研磨に使用されている水溶性の油剤或いは自動11(
用の不凍液等を水で10・〜100倍に希釈しで使用し
ているが、研削性の低下が−1−分に抑止されていると
は、−rいがたく、作業者の手荒れ、ワークのヌメリな
と新r−な問題も発生している。
Water is exclusively used as a lubricant in these glass grinding and polishing processes. However, when using only water,
Grinding wheels tend to become clogged, reducing grinding performance, and other problems such as machine rust and rot due to filamentous fungi are also likely to occur. Therefore, some processing companies use water-soluble oil or automatic 11 (
Antifreeze, etc., diluted 10 to 100 times with water, is used, but it is difficult to say that the deterioration in grinding performance is suppressed to -1 minute, and the workers' hands get rough. A new problem is also occurring when the workpiece becomes slimy.

(発明が解決しようとする課題) 本発明の目的は高い研削性を有してなおかつ砥石の目詰
りがなく高能率でガラスの研削研磨加土を行えるガラス
加工用の研磨油剤を提0(することにある。
(Problems to be Solved by the Invention) The object of the present invention is to provide a polishing oil for glass processing that has high grindability and can grind, polish, and sand glass with high efficiency without clogging the grindstone. There is a particular thing.

(課題を解決するための手段) 本発明は水及び多価アルコール類から選はRr、=1種
又は2種以−にの混合物を11(剤とし、ベンゾ1リア
ゾール類或いはアミ/カルボン酸系のキレート剤を含有
することを更に含有するガラス加工用研磨油剤に係る。
(Means for Solving the Problems) The present invention uses water and polyhydric alcohols selected from Rr, = one type or a mixture of two or more as a 11 (agent), The present invention relates to a polishing oil for glass processing, further comprising a chelating agent.

本発明におけるベンゾ1リアゾール類とし′ζは、通常
銅の防食剤として知られているものを使用でrl− き、例えばベンゾ1リアゾール、)・リルトリアゾール
等を挙げることができる。アミ7カルボン酸系のキレー
ト剤としては、例えばエチレンンアミンテトラ酢酸(E
 D T A )、ニトリロ三酢酸(NTA)、ノエチ
レントリアミン五酢酸(DTPA)、1リエチレンテト
ラミン六酢酸(’FT I−I A )、ヒドロキシエ
チルエチレンジアミン三酢酸(IIF:r)TA)、ヒ
ドロキシエチルイミ7二酢酸(トITDA)及びこれら
のすトリウム塩などが挙げられる。これらは単独で使用
してもよいし、2種以」−を混合して使用してもよい。
In the present invention, the benzo-1-lyazole compound 'ζ is prepared by using what is generally known as a copper corrosion inhibitor, such as benzo-1-lyazole, lylutriazole, and the like. Examples of amide-7 carboxylic acid-based chelating agents include ethyleneaminetetraacetic acid (E
DTA), nitrilotriacetic acid (NTA), noethylenetriaminepentaacetic acid (DTPA), 1-lyethylenetetraminehexaacetic acid ('FTI-IA), hydroxyethylethylenediaminetriacetic acid (IIF:r)TA), hydroxyethyl Examples include imi7diacetic acid (ITDA) and thorium salts thereof. These may be used alone or in combination of two or more.

これら化合物の配合量は原液に対して0.1・〜10%
、好ましくは1−3%の範囲にあることが望ましい。0
.1%より少ないと効果を示しにくく、10%より多い
と鉄の腐食やオペレーターの手荒れ等の問題を起こしや
すい。
The blending amount of these compounds is 0.1-10% based on the stock solution.
, preferably in the range of 1-3%. 0
.. If it is less than 1%, it is difficult to show any effect, and if it is more than 10%, problems such as corrosion of iron and roughness of the operator's hands are likely to occur.

本発明における有機リン系の洗浄剤としては、次式11
)で表わされる酸性リン酸エステル或いはl+)で表わ
されるポリエーテルの酸性リン酸塩のアルカフールアミ
ン塩等が挙げられる。
As the organic phosphorus-based cleaning agent in the present invention, the following formula 11 is used.
Examples include acidic phosphoric acid esters represented by () and alkafuramine salts of acidic phosphates of polyethers represented by (l+).

fl)O (R’0)aP(Of()I+ (式中R1はC1〜1.のアルキル又はアルケニルツメ
1、n=1又は2、a+b=、’(である)1+)  
            (’)CR20(CHzCI
120)1.+:]qP(ON)+・(式中R2は01
〜1.のアルキル、アルケニル又はアルキルフェニル基
、1)=1〜10、n=1又は2、q+r=3である) 中和に用いるアルカノールアミンとしてはモノエタノー
ルアミン(MEA)、ジェタノールアミン(DEA)、
1リエクノールアミン(TEA)、アミ/エチル呈タノ
ールアミン(AlΣl・;A)等が早げられるが手荒れ
の面り信)もマイルドなT E A等が好ましい。
fl)O (R'0)aP(Of()I+ (wherein R1 is C1-1. alkyl or alkenyl 1, n=1 or 2, a+b=,'(is)1+)
(')CR20(CHzCI
120)1. +:]qP(ON)+・(In the formula, R2 is 01
~1. alkyl, alkenyl or alkylphenyl group, 1) = 1 to 10, n = 1 or 2, q + r = 3) As the alkanolamine used for neutralization, monoethanolamine (MEA), jetanolamine (DEA),
TEA and the like are preferable, as they are gentler on the skin, although they can speed up the process, such as ethanolamine (TEA) and amine/ethylated ethanolamine (AlΣl.;A).

ホウ素系の洗浄剤としてはホウ酸の無槻塩類或いはホウ
酸のアルカフールアミン塩が挙げられる1゜これら洗浄
剤の配合mは原液1こ対し′ζ1〜;(0%の範囲にあ
ることが望ましい、1配会量を増やせば洗浄性は向」ニ
するが、下記に挙げる基剤との相溶性が各洗浄剤によっ
て異なるため、それぞれの#lIカせしよって最適な配
合量を決定することが好まし。
Examples of boron-based cleaning agents include unsalted boric acid salts and alkafuramine salts of boric acid.1゜The blend m of these cleaning agents may be in the range of 1 ~ (0%) per 1 undiluted solution. It is desirable to increase the amount of detergent, but the compatibility with the bases listed below differs depending on the detergent, so determine the optimal amount based on the strength of each detergent. That's preferable.

し1゜ 本発明の加]二油剤の基剤としては水或いはエチレング
リコール(E G )、プロピレングリコール(pG)
、ノエチレングリコール(r)EG)等のグリコール類
が挙げられる。これらは単独で用いてもよいし2種類以
上を混合して使用してもよい。グリコール類を基剤とし
て用いれば一屑その浸透性により研削性を向上させるこ
とができる。
1゜The base of the two oils according to the present invention is water, ethylene glycol (EG), propylene glycol (pG).
, noethylene glycol (r) EG) and the like. These may be used alone or in combination of two or more. If glycols are used as a base, the grindability can be improved due to their permeability.

本発明の加工油剤は」二記アルカメールアミン類によっ
て、pHを7.5〜8.5に調整することが望ましい。
The pH of the processing oil of the present invention is desirably adjusted to 7.5 to 8.5 using an alcamelamine.

これにより本油剤は適度な防錆性を有する。As a result, this oil agent has appropriate rust prevention properties.

+18は研削性に直接関与しないが、7.5より低いと
防錆性は極端に低下し、8.5より高いとオペレーター
の手荒れの問題が生ずる。本発明の加工油剤には必要に
応じて公知の防腐防黴剤、防錆剤、消泡剤をその目的に
応じて使用することができる。
+18 does not directly affect the grindability, but if it is lower than 7.5, the rust prevention property will be extremely reduced, and if it is higher than 8.5, the problem of roughness of the operator's hands will occur. In the processing oil of the present invention, known preservatives, antifungal agents, rust preventives, and antifoaming agents can be used as necessary depending on the purpose.

尚、本油剤は通常10〜100倍、好ましくは20〜4
0倍の水で希釈して用いるのが好ましい。
In addition, this oil agent is usually 10 to 100 times, preferably 20 to 4 times
It is preferable to use it after diluting it with 0 times the amount of water.

(発明の効果) 本発明のガラス加工用研磨油剤は著しく向」ニされた研
削性を有し、11つ砥石の目詰りがなく高い研削性を持
続させることが11fjgである、1(実 施 例) 以下実施例により本発明を更に説明[るか、本発明はこ
れに限定されるものではない。実施例中の数字は重量基
準の濃度(%)で・ある1、実施例1〜4 第1表の配合に従って本発明の加工油剤をii!:l製
した。表においてa)城北化学玉業”Jl (J P 
−504)、b)BASF製(K(]、ANTTN  
1.tlB)、C)含窒素硫黄系防黴剤、(1)シリコ
ーン系消泡剤である1゜第1表 試験例1 実施例1〜4の加工油剤の30倍希釈液を用いて、光学
ガラス(nK−7,60φ)を$1500のダイヤモン
ドペレットを有するオスカー式−軸中仕上げ蝦により、
回転数]200rlIIn、押え圧4.5kg/ cm
2の条件で研削加工した。1分間の加工を20回行い、
最後の5回の平均研磨州を求めて研削性を評価した。。
(Effects of the Invention) The polishing oil for glass processing of the present invention has significantly improved grinding properties, and 11 fjg maintains high grinding properties without clogging of the grindstone. Examples) The present invention will be further explained below with reference to Examples, but the present invention is not limited thereto. The numbers in the examples are concentrations (%) on a weight basis.Examples 1 to 4 The processing oil of the present invention was prepared according to the formulations in Table 1.ii! :1 made. In the table a) Seonghoku Kagaku Yugyo "Jl (J P
-504), b) Made by BASF (K(], ANTTN
1. tlB), C) Nitrogen-containing sulfur-based fungicide, (1) silicone-based antifoaming agent 1゜ Table 1 Test Example 1 Using a 30-fold dilution of the processing oil of Examples 1 to 4, optical glass (nK-7,60φ) by Oscar type-finishing shrimp with diamond pellets of $1500,
Rotation speed] 200rlIIn, presser foot pressure 4.5kg/cm
Grinding was carried out under the following conditions. Perform 1 minute processing 20 times,
The grindability was evaluated by determining the average polishing state of the last 5 times. .

比較例1−3としてそれぞれ水、自動小用不凍液の30
倍希釈液、水溶性切削油(、JISWi種1υ勺の30
倍希釈液に−)いて同様の評価を行った1、結果を第2
表に示す。
As Comparative Examples 1-3, 30% of water and automatic antifreeze were used, respectively.
Double diluted liquid, water-soluble cutting oil (30
A similar evaluation was carried out in the diluted solution (1), and the results were used in the second
Shown in the table.

第2表 出 願 人  株式会社松何石油41F究所代 理 人
  弁理士  1月 村   巌=8−
Applicant in Table 2: Matsuha Oil Co., Ltd. 41F Institute Representative Patent Attorney January Iwao Mura = 8-

Claims (2)

【特許請求の範囲】[Claims] (1)水及び多価アルコール類から選ばれた1種又は2
種以上の混合物を基剤とし、ベンゾトリアゾール類或い
はアミノカルボン酸系のキレート剤を含有することを特
徴とするガラス加工用研磨油剤。
(1) One or two selected from water and polyhydric alcohols
1. A polishing oil for glass processing, characterized in that it is based on a mixture of more than one species and contains a benzotriazole or aminocarboxylic acid chelating agent.
(2)有機リン系或いはホウ素系の洗浄剤を更に含有す
る請求項1記載のガラス加工用研磨油剤。
(2) The polishing oil for glass processing according to claim 1, further comprising an organic phosphorus-based or boron-based cleaning agent.
JP63117698A 1988-05-13 1988-05-13 Polishing oil for glass processing Expired - Fee Related JPH0623395B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63117698A JPH0623395B2 (en) 1988-05-13 1988-05-13 Polishing oil for glass processing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63117698A JPH0623395B2 (en) 1988-05-13 1988-05-13 Polishing oil for glass processing

Publications (2)

Publication Number Publication Date
JPH01287190A true JPH01287190A (en) 1989-11-17
JPH0623395B2 JPH0623395B2 (en) 1994-03-30

Family

ID=14718088

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63117698A Expired - Fee Related JPH0623395B2 (en) 1988-05-13 1988-05-13 Polishing oil for glass processing

Country Status (1)

Country Link
JP (1) JPH0623395B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5507962A (en) * 1993-05-18 1996-04-16 The United States Of America As Represented By The Secretary Of Commerce Method of fabricating articles

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3507791A (en) * 1967-02-01 1970-04-21 Sinclair Research Inc Biodegradable soluble lubricants
JPS4843705A (en) * 1971-10-05 1973-06-23
JPS5431683A (en) * 1977-08-15 1979-03-08 Neos Kk Cutting oil
JPS588799A (en) * 1981-07-10 1983-01-18 Nissan Motor Co Ltd Metal working oil
JPS59145296A (en) * 1983-02-07 1984-08-20 Idemitsu Kosan Co Ltd Metal working oil
JPS60382A (en) * 1983-06-10 1985-01-05 Yokogawa Medical Syst Ltd Azimuth angle adaptive type phased array sonar
JPS6181477A (en) * 1984-09-28 1986-04-25 Johnson Kk Water-soluble grinding composition

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3507791A (en) * 1967-02-01 1970-04-21 Sinclair Research Inc Biodegradable soluble lubricants
JPS4843705A (en) * 1971-10-05 1973-06-23
JPS5431683A (en) * 1977-08-15 1979-03-08 Neos Kk Cutting oil
JPS588799A (en) * 1981-07-10 1983-01-18 Nissan Motor Co Ltd Metal working oil
JPS59145296A (en) * 1983-02-07 1984-08-20 Idemitsu Kosan Co Ltd Metal working oil
JPS60382A (en) * 1983-06-10 1985-01-05 Yokogawa Medical Syst Ltd Azimuth angle adaptive type phased array sonar
JPS6181477A (en) * 1984-09-28 1986-04-25 Johnson Kk Water-soluble grinding composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5507962A (en) * 1993-05-18 1996-04-16 The United States Of America As Represented By The Secretary Of Commerce Method of fabricating articles

Also Published As

Publication number Publication date
JPH0623395B2 (en) 1994-03-30

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