JPH01242452A - Production of inorganic plate - Google Patents
Production of inorganic plateInfo
- Publication number
- JPH01242452A JPH01242452A JP7018088A JP7018088A JPH01242452A JP H01242452 A JPH01242452 A JP H01242452A JP 7018088 A JP7018088 A JP 7018088A JP 7018088 A JP7018088 A JP 7018088A JP H01242452 A JPH01242452 A JP H01242452A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- cement
- asbestos
- curing
- aggregate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000000835 fiber Substances 0.000 claims abstract description 30
- 239000004568 cement Substances 0.000 claims abstract description 17
- 238000001125 extrusion Methods 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 244000025254 Cannabis sativa Species 0.000 claims description 12
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims description 12
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims description 12
- 235000009120 camo Nutrition 0.000 claims description 12
- 235000005607 chanvre indien Nutrition 0.000 claims description 12
- 239000011487 hemp Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 5
- 239000000314 lubricant Substances 0.000 claims description 4
- 238000007796 conventional method Methods 0.000 claims description 3
- 238000007580 dry-mixing Methods 0.000 claims description 2
- 239000010425 asbestos Substances 0.000 abstract description 9
- 229910052895 riebeckite Inorganic materials 0.000 abstract description 9
- 239000000463 material Substances 0.000 abstract description 7
- 238000005452 bending Methods 0.000 abstract description 6
- 238000004898 kneading Methods 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 241000208202 Linaceae Species 0.000 abstract 2
- 235000004431 Linum usitatissimum Nutrition 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- 239000012783 reinforcing fiber Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 241000763859 Dyckia brevifolia Species 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
Landscapes
- Press-Shaping Or Shaping Using Conveyers (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は無機質板の製造方法に関し、詳しくは無石綿
配合のセメント原料を用いて無機質板を製造する改良さ
れた方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a method for manufacturing an inorganic board, and more particularly to an improved method for manufacturing an inorganic board using an asbestos-free cement raw material.
セメント製品の補強用繊維として石綿は製品強度向上の
みならず、上記セメント製品の製造工程における未硬化
時、例えば押出成形における押出直後の未硬化製品に対
しても曲げ強度、耐クラツク性を付与するため、セメン
ト製品の補強材として極めて有用であることは周知のと
おりであるが、石綿は粉塵公害の原因となり、また、一
方において資源の枯渇といったことによりその使用は次
第に制限されつつある。As a reinforcing fiber for cement products, asbestos not only improves the strength of the product, but also imparts bending strength and crack resistance to the uncured product during the above-mentioned cement product manufacturing process, for example, immediately after extrusion in extrusion molding. As is well known, asbestos is extremely useful as a reinforcing material for cement products.However, asbestos causes dust pollution, and on the other hand, its use is gradually being restricted due to resource depletion.
従って、石綿に代わるJ11i強繊維の開発が種々活発
に試みられているところであるが、現時点においては未
だ充分なものを得るには至っていない。Therefore, various attempts are being made to develop J11i strong fibers to replace asbestos, but at present, nothing satisfactory has yet been achieved.
例えば、石綿の代替物質としてガラス繊維が従前より提
案され、かつ、かなり実用化されるに至っているが、ガ
ラス繊維は基本的に耐アルカリ性が低く、この改良のた
めの複雑な処理技術を要し高価となるといった問題の他
に、一般にガラス繊維は表面が平滑であるため、未硬化
板材内において、いわゆる「すり抜け」が生じやすく、
従って押出成形のように材料の押出直後から成形品自身
に保型性が要求される場合にあっては、充分な保型のた
めの補強効果が期待出来ないといった問題があった。For example, glass fiber has been proposed for some time as a substitute for asbestos, and has come into practical use to a large extent, but glass fiber generally has low alkali resistance and requires complex processing techniques to improve this property. In addition to the problem of being expensive, glass fibers generally have smooth surfaces, so they tend to "slip through" in uncured board materials.
Therefore, in cases such as extrusion molding where the molded product itself is required to have shape retention immediately after extrusion of the material, there is a problem in that a sufficient reinforcing effect for shape retention cannot be expected.
また、合成繊維は、成形品の未硬化時の保型性向上には
役立っても成形品の高温高圧養生時に溶融してしまうの
で、このような養生工程を要するものには使用出来ず、
汎用性に乏しいといった問題があった。In addition, although synthetic fibers are useful for improving the shape retention of molded products when they are not cured, they melt when molded products are cured at high temperatures and high pressures, so they cannot be used in products that require such a curing process.
There was a problem that it lacked versatility.
このような養生条件に耐え、保形性も発揮出来る繊維と
してパルプ繊維があるが、このパルプ繊維のみでは硬化
後の板材強度に問題がある。Pulp fibers are a type of fiber that can withstand such curing conditions and exhibit shape-retaining properties, but this pulp fiber alone has a problem with the strength of the board after curing.
さらに粘土鉱物の使用も本発明者らの実験によればかな
り有効であることが確認されているが、石綿と同様な粉
塵公害の懸念がある。Furthermore, although the use of clay minerals has been confirmed to be quite effective according to experiments conducted by the present inventors, there are concerns about dust pollution similar to that of asbestos.
この発明は上記問題点に鑑み、無石綿配合でありながら
保形性並びに養生硬化後の成形体の曲げ強度、たわみ性
等を有効に付与できる無機質板の製造方法を提供するこ
とを目的としてなされたものである。In view of the above-mentioned problems, the present invention was made with the object of providing a method for manufacturing an inorganic board that is asbestos-free and can effectively impart shape retention, bending strength, flexibility, etc. to a molded product after curing and hardening. It is something that
〔課題を解決するに至った技術〕
即ち、この発明の無機質板の製造方法はセメン)30〜
40重量%、シリカ質骨材30〜41重量%パルプ繊維
3〜8重量%、滑材10〜20重量%、必要星の軽量発
泡骨材にフィブリル化した麻繊維を1〜3重量%添加し
乾式混合した後、押出助剤及び水を加えて混練し、該原
料を押出成形し、得た成形体を常法により養生硬化する
ことを特徴とするものである。[Technology that led to solving the problem] That is, the method for manufacturing an inorganic board of the present invention is based on cement) 30~
40% by weight, 30-41% by weight of siliceous aggregate, 3-8% by weight of pulp fiber, 10-20% by weight of lubricant, and 1-3% by weight of fibrillated hemp fiber added to the necessary lightweight foamed aggregate. After dry mixing, an extrusion aid and water are added and kneaded, the raw materials are extruded, and the obtained molded product is cured by a conventional method.
セメント組成物の補強繊維として既述のように種々のも
のが考えられるが、上記以外のものとして、麻、椰子、
竹、或いは藁などの繊維がある。As mentioned above, various reinforcing fibers can be used as reinforcing fibers for cement compositions, but in addition to the above, hemp, coconut,
There are fibers such as bamboo or straw.
このうち、麻繊維はパルプ繊維に比し弾性および切断強
度に優れ、パルプ繊維より有利な条件を具備していると
考えられる。Among these, hemp fibers are superior in elasticity and cutting strength to pulp fibers, and are considered to have more advantageous conditions than pulp fibers.
本発明は、この麻繊維の特性に着目したものである。The present invention focuses on the characteristics of this hemp fiber.
本発明においてフィブリル化した麻繊維を用いるのは、
麻繊維そのままでは表面が滑らかでそのまま使った場合
セメントとの付着性が悪いためである。The fibrillated hemp fibers used in the present invention are
This is because hemp fibers have a smooth surface and have poor adhesion to cement when used as is.
また、粉砕により繊維をより細くし、分散しやすくする
ことが出来、また表面が粗面化され、物理的にセメント
マトリックスとの接着性が向上し、かつ、繊維間のから
みも向上し、これらによって成形板体の曲げ強度、たわ
み性が向上するのである。In addition, pulverization makes the fibers finer and easier to disperse, and also roughens the surface, improving physical adhesion with the cement matrix and improving intertwining between the fibers. This improves the bending strength and flexibility of the molded plate.
この発明において、セメント及びシリカ質骨材の配合量
は従来のものと同様であり、特に説明するまでもないが
、パルプ繊維を3〜8重量%とするのは、パルプ繊維に
よる繊維補強効果並びに押出性改良のためであり、3重
量%より少ないと、上記の効果が無く、また、8重量%
を超えて添加すれば、成形板材の吸水性が低下するため
である。In this invention, the blending amounts of cement and siliceous aggregate are the same as those of conventional ones, and although there is no need to explain specifically, the reason why the content of pulp fiber is 3 to 8% by weight is due to the fiber reinforcing effect and the fiber reinforcing effect of pulp fiber. This is to improve extrudability, and if it is less than 3% by weight, the above effect will not be achieved, and if it is less than 8% by weight.
This is because if it is added in excess of this amount, the water absorbency of the molded plate material will decrease.
また、滑材を10〜20重量%添加するのは麻繊維添加
によるセメント原料のバルキー性を改良し、成形時の表
面を平滑にするためであって、水酸化マグネシウム、炭
酸カルシウムのように、水を含んだ時、粘性が発揮され
る物質が使用される。In addition, the reason why 10 to 20% by weight of lubricant is added is to improve the bulkiness of the cement raw material by adding hemp fiber and to make the surface smooth during molding. A substance that exhibits viscosity when it contains water is used.
これら物質の添加量を10〜20重量%とする理由は、
10重量%より少ないと上述した効果が得られず、20
重撥%より多くするとセメントマトリックスの結合強度
に悪影響が生じるからである。The reason why the amount of these substances added is 10 to 20% by weight is as follows.
If it is less than 10% by weight, the above-mentioned effects cannot be obtained;
This is because if the amount exceeds the weight percent, the bonding strength of the cement matrix will be adversely affected.
軽量発泡骨材は成形体を軽量化する場合に添加され、パ
ーライト、発泡スチレンビーズなどが使用される。Lightweight foamed aggregate is added to reduce the weight of the molded body, and perlite, expanded styrene beads, etc. are used.
なお、軽量発泡骨材の添加■は、成形体の軽量化の目的
に合わせ、適当量添加される。Note that the lightweight foamed aggregate is added in an appropriate amount according to the purpose of reducing the weight of the molded product.
また、上記原料を成形に先立ち、まず乾式混合するのは
、繊維とセメント組成物との均一混合性を高め、特に麻
繊維のファイバーボール化を防止しつつ均一混合するた
めである。Further, the reason why the above raw materials are first dry mixed prior to molding is to improve the uniform miscibility of the fibers and the cement composition, and in particular to uniformly mix the hemp fibers while preventing them from becoming fiber balls.
押出助剤としては、常法と同様、メチルセルロース等が
使用される。As the extrusion aid, methylcellulose or the like is used as in the conventional method.
以上の配合材量を水の添加のもと、均一混練し、押出成
形すれば、平滑表面の成形体が得られ、養生硬化により
、強度、たわみ性に優れた板材が製造できる。By homogeneously kneading the above-mentioned amount of compounded materials with the addition of water and extrusion molding, a molded product with a smooth surface can be obtained, and by curing and curing, a plate material with excellent strength and flexibility can be manufactured.
次に、この発明の詳細な説明する。 Next, the present invention will be explained in detail.
天然麻繊維を長さ611Ilに切断したものをA、天然
麻繊維を鋸刃状粉砕機にかけ、粉砕フィブリル化したも
のをBとし、表1に示す配合にて、まず高速ミキサーで
乾式混合し、次いで水を加えてニーダで混練したものを
真空押出機により押出し、厚さ15mm、 Wさ1m、
幅10cm の板材を成形し、2・1時間の自然養生
後8 kg/cm” x 8時間のオートクレーブ養生
を行なった。A is natural hemp fiber cut into a length of 611 Il, B is a natural hemp fiber that has been crushed into fibrils by passing it through a saw-blade crusher, and the mixture is first dry-mixed using a high-speed mixer with the composition shown in Table 1. Next, water was added and kneaded using a kneader, which was then extruded using a vacuum extruder to obtain a product with a thickness of 15 mm and a width of 1 m.
A board with a width of 10 cm was formed, and after being naturally cured for 2.1 hours, it was cured in an autoclave for 8 kg/cm" x 8 hours.
表中、数字は重量%を示す。また、滑材としては水酸化
マグネシウムを使用した。In the table, numbers indicate weight %. Moreover, magnesium hydroxide was used as a lubricant.
上記、試験片につき、曲げ強度試験、及び、たわみ試験
を行なったところ、表2の結果が得られた。When the above test pieces were subjected to a bending strength test and a deflection test, the results shown in Table 2 were obtained.
この発明は以上説明したように、曲げ強度は麻Bを使用
したものが優れ、特に、たわみ性が改良される。As explained above, in this invention, the bending strength using hemp B is excellent, and in particular, the flexibility is improved.
従って、この発明によれば、無石綿でありながら強靭、
かつ、たわみ性に優れたセメント板材が!!!造可能に
なるのである。Therefore, according to this invention, it is asbestos-free and strong.
Moreover, the cement board has excellent flexibility! ! ! It becomes possible to build.
Claims (1)
41重量%、パルプ繊維3〜8重量%、滑材10〜20
重量%必要量の軽量発泡骨材にフィブリル化した麻繊維
を1〜3重量%添加し乾式混合した後、押出助剤及び水
を加えて混練し、該原料を押出成形し、得た成形体を常
法により養生硬化することを特徴とする無機質板の製造
方法。(1) Cement 30-40% by weight, siliceous aggregate 30-40%
41% by weight, pulp fiber 3-8% by weight, lubricant 10-20%
After adding 1 to 3% by weight of fibrillated hemp fibers to the required amount of lightweight foamed aggregate and dry mixing, extrusion aid and water are added and kneaded, and the raw material is extruded to obtain a molded product. A method for manufacturing an inorganic board, characterized by curing and hardening by a conventional method.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7018088A JP2619908B2 (en) | 1988-03-23 | 1988-03-23 | Manufacturing method of inorganic plate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7018088A JP2619908B2 (en) | 1988-03-23 | 1988-03-23 | Manufacturing method of inorganic plate |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH01242452A true JPH01242452A (en) | 1989-09-27 |
JP2619908B2 JP2619908B2 (en) | 1997-06-11 |
Family
ID=13424069
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7018088A Expired - Lifetime JP2619908B2 (en) | 1988-03-23 | 1988-03-23 | Manufacturing method of inorganic plate |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2619908B2 (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03208847A (en) * | 1990-01-08 | 1991-09-12 | Kubota Corp | Method for extrusion-molding inorganic board |
JP2000063161A (en) * | 1998-08-10 | 2000-02-29 | Ogawa Setsuo Kenkyusho:Kk | Filler inorganic hydraulic composition and board material |
US7758694B2 (en) | 2006-05-11 | 2010-07-20 | Nichiha Corporation | Fiber reinforced cement composition and products and manufacturing process |
US7828892B2 (en) | 2004-08-31 | 2010-11-09 | Nichiha Corporation | Inorganic board and a method for the manufacturing thereof |
US7837788B2 (en) | 2006-09-27 | 2010-11-23 | Nichiha Corporation | Fiber reinforced cement composition and products and manufacturing process |
US7879145B2 (en) | 2007-02-14 | 2011-02-01 | Nichiha Corporation | Inorganic composition and products and manufacturing process |
US7905956B2 (en) | 2006-02-15 | 2011-03-15 | Nichiha Corporation | Fiber reinforced cement composition and products and manufacturing process |
US7967907B2 (en) | 2007-01-26 | 2011-06-28 | Nichiha Corporation | Fiber reinforced cement composition and products and manufacturing process |
US7972433B2 (en) | 2006-12-27 | 2011-07-05 | Nichiha Co., Ltd. | Fiber reinforced cement composition and products and manufacturing process |
US7976626B2 (en) | 2006-09-27 | 2011-07-12 | Nichiha Corporation | Fiber reinforced cement composition and products and manufacturing process |
JP2013028869A (en) * | 2011-07-27 | 2013-02-07 | Kmew Co Ltd | Treatment method of pulp sheet and method for producing hydraulic material |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7722964B2 (en) | 2006-04-25 | 2010-05-25 | Nichiha Corporation | Fiber reinforced cement board and manufacturing process |
-
1988
- 1988-03-23 JP JP7018088A patent/JP2619908B2/en not_active Expired - Lifetime
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2574182B2 (en) * | 1990-01-08 | 1997-01-22 | 株式会社クボタ | Extrusion molding method of inorganic plate |
JPH03208847A (en) * | 1990-01-08 | 1991-09-12 | Kubota Corp | Method for extrusion-molding inorganic board |
JP2000063161A (en) * | 1998-08-10 | 2000-02-29 | Ogawa Setsuo Kenkyusho:Kk | Filler inorganic hydraulic composition and board material |
JP4558851B2 (en) * | 1998-08-10 | 2010-10-06 | 有限会社小川節夫研究所 | Inorganic hydraulic composition and plate material |
US7828892B2 (en) | 2004-08-31 | 2010-11-09 | Nichiha Corporation | Inorganic board and a method for the manufacturing thereof |
US7905956B2 (en) | 2006-02-15 | 2011-03-15 | Nichiha Corporation | Fiber reinforced cement composition and products and manufacturing process |
US7758694B2 (en) | 2006-05-11 | 2010-07-20 | Nichiha Corporation | Fiber reinforced cement composition and products and manufacturing process |
US7837788B2 (en) | 2006-09-27 | 2010-11-23 | Nichiha Corporation | Fiber reinforced cement composition and products and manufacturing process |
US7976626B2 (en) | 2006-09-27 | 2011-07-12 | Nichiha Corporation | Fiber reinforced cement composition and products and manufacturing process |
US7972433B2 (en) | 2006-12-27 | 2011-07-05 | Nichiha Co., Ltd. | Fiber reinforced cement composition and products and manufacturing process |
US7967907B2 (en) | 2007-01-26 | 2011-06-28 | Nichiha Corporation | Fiber reinforced cement composition and products and manufacturing process |
US7879145B2 (en) | 2007-02-14 | 2011-02-01 | Nichiha Corporation | Inorganic composition and products and manufacturing process |
JP2013028869A (en) * | 2011-07-27 | 2013-02-07 | Kmew Co Ltd | Treatment method of pulp sheet and method for producing hydraulic material |
Also Published As
Publication number | Publication date |
---|---|
JP2619908B2 (en) | 1997-06-11 |
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