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JPH01183310A - Surface covering carbonization tungsten group cemented carbide made throw away tip for milling cutter - Google Patents

Surface covering carbonization tungsten group cemented carbide made throw away tip for milling cutter

Info

Publication number
JPH01183310A
JPH01183310A JP352888A JP352888A JPH01183310A JP H01183310 A JPH01183310 A JP H01183310A JP 352888 A JP352888 A JP 352888A JP 352888 A JP352888 A JP 352888A JP H01183310 A JPH01183310 A JP H01183310A
Authority
JP
Japan
Prior art keywords
hard
carbide
cemented carbide
dispersed phase
cutting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP352888A
Other languages
Japanese (ja)
Inventor
Hironori Yoshimura
吉村 寛範
Akira Osada
晃 長田
Katsu Kitagaki
北垣 克
Munenori Nakajima
中島 宗則
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Metal Corp
Original Assignee
Mitsubishi Metal Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Metal Corp filed Critical Mitsubishi Metal Corp
Priority to JP352888A priority Critical patent/JPH01183310A/en
Publication of JPH01183310A publication Critical patent/JPH01183310A/en
Pending legal-status Critical Current

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  • Milling Processes (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)

Abstract

PURPOSE:To improve heat resisting shock property and crack resistance so as to prevent the generation of a pitting and a crack and to extend the life of the tip in the caption by containing Co containing volume in WC group cemented carbide relatively, making the grading of a hard disperse phase and thinning the thickness of a hard covering layer. CONSTITUTION:WC group cemented carbide base body the average diameter of the grading of which is 0.5-2mum is formed in a way that 2-10% of one kind or two kind of TiC and TiN as the forming components of a hard dispersing phase, 2-15% of one kind or two kind of TaC and NbC and 15-25% of Co as the forming component of a connecting phase are contained and the constitution of remainders are WC and unavoidable impurities. Its surface is formed 2-6mum of average layer in thickness by a hard covering layer consisting of metallic carbide, nitride and oxide of 4a, 5a and 6a group is the element periodic table, aluminum oxide and one kind of a single layer of more than two kinds of plural layers in more than two kinds of solid solution. The above-mentioned covering tip has a normal abrasion mainly as the state of the cutting edge, the generation of a pitting is very few and the abrasion is not uniform so that superion milling cutting property is displayed.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、特に7ライス切削で、すぐれた耐欠損性を
発揮する表面被覆炭化タングステン(以下WCで示す)
基超硬合金製スローアウェイチップに関するものである
[Detailed Description of the Invention] [Industrial Application Field] This invention provides surface-coated tungsten carbide (hereinafter referred to as WC) that exhibits excellent fracture resistance, especially in 7-rice cutting.
This invention relates to an indexable tip made of base cemented carbide.

〔従来の技術〕[Conventional technology]

従来1重量−で(以下−は重量−を示す)。 Conventionally, 1 weight - (hereinafter - indicates weight).

硬質分散相形成成分として、炭化チタン(以下TiCで
示す)および窒化チタン(以下TiNで示す)のうちの
1種または2種:10%以下。
As a hard dispersed phase forming component, one or two of titanium carbide (hereinafter referred to as TiC) and titanium nitride (hereinafter referred to as TiN): 10% or less.

同じく硬質分散相形成成分として、炭化タンタル(以下
TaCで示す)および炭化ニオブ(以下。
Similarly, tantalum carbide (hereinafter referred to as TaC) and niobium carbide (hereinafter referred to as TaC) are hard dispersed phase forming components.

NbCで示す)のうちの1種または2種:l〇−以下。One or two of the following (denoted as NbC): l〇- or less.

結合相形成成分として、Co: 5〜1296.通常は
5〜グ鳴。
As a bonded phase forming component, Co: 5 to 1296. Usually 5 to 40 seconds.

を含有し、残りが同じく硬質分散相形成成分としてのW
Cと不可避不純物からなる組成を有し、かつ硬質分散相
の平均粒径が3.6〜4.5μ諷であるWC基超硬合雀
基体の表面に、通常の化学蒸着法を用いて1元素絢期体
表の4a、5a、および6a族の金属の炭化物、i!窒
化物および酸化物。
, and the rest is W as a hard dispersed phase forming component.
A WC-based cemented carbide base material having a composition consisting of C and inevitable impurities and having a hard dispersed phase with an average particle size of 3.6 to 4.5 μm is coated with 1 using a normal chemical vapor deposition method. Carbides of metals of groups 4a, 5a, and 6a of the elemental system, i! nitrides and oxides.

酸化アルミニウム、並びにこれらの2′8以上の固溶体
のうちの1種の単層または2種以上の複層からなる硬質
被覆層を7〜10μ鳳1通常はB〜9μ講の平均層厚で
形成してなる表面被覆WCC超超硬合金構成し九スロー
アウェイチップがバイト切削に用いられていることは良
く知られるとζろである。
A hard coating layer consisting of aluminum oxide and a single layer or a multilayer of two or more of these 2'8 or more solid solutions is formed with an average layer thickness of 7 to 10 μm, usually B to 9 μm. It is well known that indexable inserts made of surface-coated WCC cemented carbide are used for cutting tools.

この従来表面被覆WC基超硬合金製スロー7ウエイチツ
プにおいては、上記のように(’o含有量を低くおさえ
、一方硬質分散相の粒度な粗くすると共に、硬質被覆層
の厚さを相対的に厚くすることによって、高いクリープ
強度とすぐれた耐摩耗性を確保し、切削温度の上昇が激
しく、これらの特性が要求されるバイト切削に適合させ
七いる。
In this conventional surface-coated WC-based cemented carbide throw 7-way chip, as described above, the 'o content is kept low, while the grain size of the hard dispersed phase is coarsened, and the thickness of the hard coating layer is relatively increased. By increasing the thickness, it ensures high creep strength and excellent wear resistance, making it suitable for cutting with a cutting tool where the cutting temperature rises rapidly and these characteristics are required.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

しかし、上記の従来表面被覆WCC超超硬合金製スロー
アウェイチップ、切削温良の上昇はバイト切削の場合よ
シも少ないが、加熱および冷却の繰り返しによる熱衝撃
の加わる7ライス切削に用いた場合には、耐熱衝撃性お
よび耐欠損性不足が原因で、切刃にチッピングや欠損が
発生し易く。
However, when using the conventional surface-coated WCC cemented carbide indexable insert mentioned above, the increase in cutting temperature is less than when cutting with a bite, but when used for 7-rice cutting, which is subject to thermal shock due to repeated heating and cooling. The cutting edge tends to chip or break due to insufficient thermal shock resistance and fracture resistance.

相対的に短かい使用寿命しか示さないのが現状である。Currently, they only have a relatively short service life.

〔問題点を解決するための手段〕[Means for solving problems]

そこで1本発明者等は、上述のような観点から。 Therefore, the inventors of the present invention, etc., from the above-mentioned viewpoint.

フライス切削用スローアウェイチップを開発すべく、特
に上記の従来表面被覆WCC超超硬合金着目し、研究を
行なつ九結果、従来、バイト切削に用いられている表面
被覆WC基超硬合金製スa −アウェイチップの基体を
構成するWCC超超硬合金Co含有豫を相対的に多くシ
、かつ硬質分散相の粒度な細かくシ、さらに硬質被覆層
の厚さを薄くすると、この結果の表面被覆WC基超硬合
金製ス−ロー7ウエイチップは、すぐれた耐熱衝撃性と
耐欠損性を具備するようになシ、これらの特性が要求さ
れるフライス切削に用いた場合にすぐれた切削性能を長
期に亘って発揮するという知見を得たのである。
In order to develop indexable inserts for milling cutting, we conducted research focusing on the above-mentioned conventional surface-coated WCC cemented carbide. a - By relatively increasing the Co content of the WCC cemented carbide that constitutes the base of the away chip, by making the hard dispersed phase finer in grain size, and by reducing the thickness of the hard coating layer, the resulting surface coating increases. The slow 7-way insert made of WC-based cemented carbide has excellent thermal shock resistance and chipping resistance, and provides excellent cutting performance when used in milling that requires these properties. We have obtained knowledge that it will be effective over a long period of time.

この発明は、上記知見にもとづいてなされたものであっ
て。
This invention was made based on the above findings.

硬質分散相形成成分として、 TiCおよび’I’iN
のうちの1種また酸2種:2〜lO饅。
As hard dispersed phase forming components, TiC and 'I'iN
One of these and two acids: 2 to 10 liters.

同じく硬質分散相形成成分として、TaCおよびNbC
(7)うちの1種または2種:2〜151!。
Similarly, TaC and NbC are used as hard dispersed phase forming components.
(7) One or two of these: 2 to 151! .

結合相形成成分として、Co:15〜25−。As a bonded phase forming component, Co: 15-25-.

を含有し、残りが同じく硬質分散相形成成分としてのW
Cと不可避不純物からなる組成を有し、かつ硬質分散相
の平均粒径が0.5〜2μ票であるwe基超硬合金苓体
の表面K。
, and the rest is W as a hard dispersed phase forming component.
Surface K of a we-based cemented carbide having a composition consisting of carbon and inevitable impurities, and in which the average particle size of the hard dispersed phase is 0.5 to 2 μm.

元素尚期律表の4a、5a、および6a族の金属の炭化
物、窒化物、および酸化物、酸化アルミニウム、並びに
これらの2種以上の固溶体のうちのINiの単層ま九は
2a以上の複層からなる硬質被覆層を2〜6μ寓の平均
層厚で形成してなるフライス切削用表面被覆we基超硬
合金製スローアウェイチップに特徴を有するもので6る
Among the carbides, nitrides, and oxides of metals in Groups 4a, 5a, and 6a of the Periodic Table of Elements, aluminum oxide, and solid solutions of two or more of these, INi is a single layer or a complex of 2a or more. The present invention is characterized by a surface-coated we-based cemented carbide indexable insert for milling cutting, which is formed by forming a hard coating layer with an average layer thickness of 2 to 6 μm.

つぎに、この発明のスローアウェイチップにおいて、こ
れを構成する基体の成分組成および硬質分散相の平均粒
径、並びに硬質被覆層の平均層厚を上記の通りに限定し
た理由を説明する。
Next, in the indexable tip of the present invention, the reason why the component composition of the substrate constituting the tip, the average particle size of the hard dispersed phase, and the average layer thickness of the hard coating layer are limited as described above will be explained.

(al  Ticおよび’riN、並びにTaCおよび
NbCの含有量 これらの成分には、 TiCおよび/または’INと。
(Al Tic and 'riN, as well as TaC and NbC content. These components contain TiC and/or 'IN.

TaCおよび/またはNbCとが共存し良状態で、基体
の硬さを著しく向上させ、もって耐摩耗性を向上させる
作用があるが、それぞれその含有量が2−未満では、所
望のすぐれた耐摩耗性を確保することができず、一方そ
の含有量が、 TiCおよびTiNにあっては10%、
TaCおよびNbCKあっては15−をそれぞれ越える
と基体の耐欠損性が低下するようになることから、その
含有量を’riCおよびTiN: 2〜l O4,Tt
hCおよびNbC: 2〜15−とそれぞれ定めた。
When TaC and/or NbC coexist in a good condition, they have the effect of significantly improving the hardness of the substrate and thereby improving the wear resistance, but if the content of each is less than 2 -, the desired excellent wear resistance is not achieved. However, the content of TiC and TiN is 10%,
For TaC and NbCK, if the content exceeds 15-1, the fracture resistance of the substrate decreases, so the content is reduced to 'riC and TiN: 2~l O4,Tt
hC and NbC: 2 to 15-, respectively.

lb)  Co含有量 Co成分には、チップの耐熱衝撃性および耐欠損性を向
上させる作用があるが、その含有量が15−未満では前
記作用に所望の効果が得られず、−方その含有量が25
%を越えると、耐塑性変形性が低下するようになること
から、その含有量を15〜25囁と定めた。
lb) Co content Co component has the effect of improving the thermal shock resistance and chipping resistance of the chip, but if its content is less than 15%, the desired effect cannot be obtained; amount is 25
If the content exceeds 15% to 25%, the plastic deformation resistance decreases, so the content was set at 15-25%.

(C)  硬質分散相の平均粒径 その平均粒径が0.6μ諺未満では、所望のすぐれた耐
欠損性を確保することができず、一方平均粒径が2μ諺
を越えると耐熱衝撃性が低下するようになることから、
その平均粒径な0.6〜2μ雪と定めた。
(C) Average particle size of hard dispersed phase If the average particle size is less than 0.6 μm, the desired excellent fracture resistance cannot be secured, whereas if the average particle size exceeds 2 μm, thermal shock resistance will be poor. As the
The average particle size of snow was determined to be 0.6 to 2μ.

(a)  硬質被覆層の平均層厚 その平均層厚が2μ諺未満では、所望の耐雄耗性向上効
果が得られず、一方その平均層厚軒6μ貢を越えると、
耐欠損性および耐熱衝撃性が低下するようKなることか
ら、その平均層厚を2〜6μmと定めた。
(a) Average layer thickness of the hard coating layer If the average layer thickness is less than 2 μm, the desired effect of improving wear resistance cannot be obtained; on the other hand, if the average layer thickness exceeds 6 μm,
The average layer thickness was determined to be 2 to 6 μm since the chipping resistance and thermal shock resistance decreased.

〔実施例〕〔Example〕

つぎに、この発明のスローアウェイチップを実施例によ
り具体的に説明する。
Next, the indexable tip of the present invention will be specifically explained using examples.

原料粉末として、0.5〜1.5μ重の範囲内の所定の
平均粒径を有するWC粉末、 TiC粉末、 ’riN
粉末、 TaC粉末、 Nt)C粉末、およびCo粉末
を用意し、これら原料粉末をそれぞれ第1表に示される
配合組成に配合し、96時間ボールミルにて粉砕・混合
し、プレス成形して圧粉体とした後、10”2トルの真
空中、温度:1350〜1400℃、保持時間:1時間
の条件で焼結して、実質的に配合組成と同一の成分組成
を有し、かつ硬質分散相がそれぞれm11表に示される
平均粒径をもったwe基超超硬合金基体製造し、ついで
どの基体の表面に1通常の化学蒸着法を用い、同じく第
1表に示される組成および平均層厚の硬質被覆層を形成
することによって8NP 632の本発明表面被覆we
基超硬合金製スローアウエイチッグ(以下本発明被覆チ
ップという)1〜9および比較表面被覆we基S硬合金
製スローアウェイチップ(以下比較被覆チップという)
1〜lOをそれぞれ製造した。
Raw material powders include WC powder, TiC powder, and 'riN powder, each having a predetermined average particle size within the range of 0.5 to 1.5 μw.
Powder, TaC powder, Nt)C powder, and Co powder were prepared, and these raw material powders were each blended into the composition shown in Table 1, ground and mixed in a ball mill for 96 hours, and then press-molded to form a compacted powder. After forming a body, it is sintered in a vacuum of 10"2 Torr at a temperature of 1350 to 1400°C and a holding time of 1 hour to obtain a material having substantially the same composition as the blended composition and a hard dispersion. We-based cemented carbide substrates in which each phase has an average grain size as shown in Table 1 are prepared, and then a conventional chemical vapor deposition method is applied to the surface of each substrate to form a layer with a composition and an average layer also shown in Table 1. The present invention surface coating of 8NP 632 by forming a thick hard coating layer
Throwaway chips made of base cemented carbide (hereinafter referred to as the present invention coated chips) 1 to 9 and comparative surface-coated we base S hard alloy indexable tips (hereinafter referred to as comparative coated chips)
1 to 1O were produced, respectively.

なお、比較被覆チップ1〜10は、いずれも基体の成分
組成、基体における硬質分散相の平均粒径、および硬質
被覆層の平均層厚のうちのいずれかの条件(第1表に※
印を付す)がこの発明の範囲から外れたものである。
Comparative coated chips 1 to 10 were all tested under any of the following conditions (Table 1 *
(marked) are outside the scope of this invention.

また、比較の目的で、p30のwe基超超硬合金基体表
面に、第1表に示される組成および平均層厚の硬質被覆
層を形成することによって従来表面波@WC基超硬合金
製スロー7ウエイチツプ(以下従来被覆チップという)
を製造した。
In addition, for comparison purposes, a hard coating layer with the composition and average layer thickness shown in Table 1 was formed on the surface of a P30 WE-based cemented carbide substrate to create a conventional surface wave @ WC-based cemented carbide throw. 7-way chip (hereinafter referred to as conventional coated chip)
was manufactured.

つぎに、この結果得られた各種の被覆チップについて。Next, we will discuss the various coated chips obtained as a result.

切削方式:1OIllI厚の板材の端面切削。Cutting method: End face cutting of 1OIllI thick plate material.

被剛材: 8NCM439 (硬さ:I(B270)。Rigid material: 8NCM439 (hardness: I (B270).

切削速度:250m/m、 送j) : −0,8ml
刃。
Cutting speed: 250m/m, Feed: -0.8ml
blade.

切込み:1m、      切削油:なし。Depth of cut: 1m, Cutting oil: None.

の条件で鋼の7ライス切削試験を行ない、切刃の逃は面
摩耗幅が0.4101に至るまでの切削長さを測定した
。なお、切削途中で切刃にチッピングが発生し、使用不
能に至った場合は、それまでの切削長さを示し九。これ
らの測定結果を切刃の状態と共に第1表に示した。
A 7-rice cutting test was conducted on steel under the following conditions, and the cutting length was measured until the relief of the cutting edge reached a surface wear width of 0.4101. In addition, if chipping occurs on the cutting edge during cutting and it becomes unusable, the cutting length up to that point will be shown. These measurement results are shown in Table 1 along with the condition of the cutting edge.

〔発明の効果〕〔Effect of the invention〕

第1表に示される結果から1本発明被覆チップ1〜9は
、いずれも長い切削寿命を示し、切刃の状態も正常摩耗
を主体とし、チッピングの発生があっても僅かであった
シ、多少摩耗が不均一であったシする程度で、すぐれた
7ライス切削性能を示すのに対して、比較被覆チップ1
〜10に見られるように、基体の成分組成、基体におけ
る硬質分散相の平均粒径、および硬質被覆層の平均層厚
のうちのいずれかの条件でもこの発明の範囲から外れる
と、切刃に大チッピングや欠損、あるいは異常摩耗が発
生して、比較的短時間で使用寿命に至るもので6シ、ま
た従来バイト切削に用いられている従来被覆チップをフ
ライス切削に用いるのは不可mlでちることが明らかで
ある。
From the results shown in Table 1, the coated inserts 1 to 9 of the present invention all exhibited long cutting life, and the cutting edge condition was mainly normal wear, with only a small amount of chipping occurring. The comparative coated tip 1 showed excellent cutting performance with 7 slices, although the wear was somewhat uneven.
10, if any of the component composition of the substrate, the average particle diameter of the hard dispersed phase in the substrate, and the average layer thickness of the hard coating layer deviate from the scope of the present invention, the cutting edge may deteriorate. Large chipping, breakage, or abnormal wear occurs, and the service life ends in a relatively short period of time, and it is impossible to use conventional coated tips for milling, which are conventionally used for tool cutting. That is clear.

上述のように、この発明の表面被覆we基超超硬合金製
スローアウェイチップ、耐欠損性にすぐれ、さらに耐熱
衝撃にすぐれているので、これらの特性が要求される7
ライス切削に用いた場合に著しく長期に亘ってすぐれ良
性能を発揮するのである。
As mentioned above, the surface-coated WE-based cemented carbide indexable insert of the present invention has excellent fracture resistance and furthermore has excellent thermal shock resistance, so these characteristics are required.
When used for rice cutting, it exhibits excellent performance over an extremely long period of time.

Claims (1)

【特許請求の範囲】[Claims] (1)炭化タングステン基超硬合金基体の表面に、元素
周期律表の4a、5a、および6a族の金属の炭化物、
窒化物、および酸化物、酸化アルミニウム、並びにこれ
らの2種以上の固溶体のうちの1種の単層または2種以
上の複層からなる硬質被覆層を形成してなる表面被覆炭
化タングステン基超硬合金製スローアウエイチツプにお
いて、上記基体を、 硬質分散相形成成分として、炭化チタンおよび窒化チタ
ンのうちの1種または2種:2〜10%、同じく硬質分
散相形成成分として、炭化タンタルおよび炭化ニオブの
うちの1種または2種:2〜15%、 結合相形成成分として、Co:15〜25%、を含有し
、残りが同じく硬質分散相形成成分としての炭化タング
ステンと不可避不純物からなる組成(以上重量%)を有
し、かつ硬質分散相の平均粒径が0.5〜2μmである
炭化タングステン基超硬合金で構成すると共に、上記硬
質被覆層の平均層厚を2〜6μmとしたことを特徴とす
るフライス切削用表面被覆炭化タングステン基超硬合金
製スローアウエイチツプ。
(1) carbides of metals from groups 4a, 5a, and 6a of the periodic table of the elements on the surface of the tungsten carbide-based cemented carbide substrate;
A surface-coated tungsten carbide-based carbide formed by forming a hard coating layer consisting of a single layer or a multilayer of two or more of nitrides, oxides, aluminum oxide, and solid solutions of two or more of these. In the alloy throwaway chip, the above-mentioned substrate contains 2 to 10% of one or both of titanium carbide and titanium nitride as hard dispersed phase forming components, and tantalum carbide and niobium carbide as hard dispersed phase forming components. One or two of them: 2 to 15%, Co: 15 to 25% as a binder phase forming component, and the remainder consisting of tungsten carbide as a hard dispersed phase forming component and unavoidable impurities ( % by weight) and whose hard dispersed phase has an average particle size of 0.5 to 2 μm, and the hard coating layer has an average layer thickness of 2 to 6 μm. A surface-coated tungsten carbide-based cemented carbide throw-away tip for milling.
JP352888A 1988-01-11 1988-01-11 Surface covering carbonization tungsten group cemented carbide made throw away tip for milling cutter Pending JPH01183310A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP352888A JPH01183310A (en) 1988-01-11 1988-01-11 Surface covering carbonization tungsten group cemented carbide made throw away tip for milling cutter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP352888A JPH01183310A (en) 1988-01-11 1988-01-11 Surface covering carbonization tungsten group cemented carbide made throw away tip for milling cutter

Publications (1)

Publication Number Publication Date
JPH01183310A true JPH01183310A (en) 1989-07-21

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03146668A (en) * 1989-10-30 1991-06-21 Toshiba Tungaloy Co Ltd Coated sintered hard alloy having controlled surface roughness and its production
US5066553A (en) * 1989-04-12 1991-11-19 Mitsubishi Metal Corporation Surface-coated tool member of tungsten carbide based cemented carbide
WO1992005296A1 (en) * 1990-09-17 1992-04-02 Kennametal Inc. Cvd and pvd coated cutting tools
US5106674A (en) * 1988-10-31 1992-04-21 Mitsubishi Materials Corporation Blade member of tungsten-carbide-based cemented carbide for cutting tools and process for producing same
US5232318A (en) * 1990-09-17 1993-08-03 Kennametal Inc. Coated cutting tools
US5250367A (en) * 1990-09-17 1993-10-05 Kennametal Inc. Binder enriched CVD and PVD coated cutting tool
US5266388A (en) * 1990-09-17 1993-11-30 Kennametal Inc. Binder enriched coated cutting tool
US5325747A (en) * 1990-09-17 1994-07-05 Kennametal Inc. Method of machining using coated cutting tools

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5106674A (en) * 1988-10-31 1992-04-21 Mitsubishi Materials Corporation Blade member of tungsten-carbide-based cemented carbide for cutting tools and process for producing same
US5066553A (en) * 1989-04-12 1991-11-19 Mitsubishi Metal Corporation Surface-coated tool member of tungsten carbide based cemented carbide
JPH03146668A (en) * 1989-10-30 1991-06-21 Toshiba Tungaloy Co Ltd Coated sintered hard alloy having controlled surface roughness and its production
WO1992005296A1 (en) * 1990-09-17 1992-04-02 Kennametal Inc. Cvd and pvd coated cutting tools
US5232318A (en) * 1990-09-17 1993-08-03 Kennametal Inc. Coated cutting tools
US5250367A (en) * 1990-09-17 1993-10-05 Kennametal Inc. Binder enriched CVD and PVD coated cutting tool
US5266388A (en) * 1990-09-17 1993-11-30 Kennametal Inc. Binder enriched coated cutting tool
US5325747A (en) * 1990-09-17 1994-07-05 Kennametal Inc. Method of machining using coated cutting tools
US5364209A (en) * 1990-09-17 1994-11-15 Kennametal Inc. CVD and PVD coated cutting tools
US5395680A (en) * 1990-09-17 1995-03-07 Kennametal Inc. Coated cutting tools

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