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JPH09277034A - Method for continuously casting molten metal - Google Patents

Method for continuously casting molten metal

Info

Publication number
JPH09277034A
JPH09277034A JP8861196A JP8861196A JPH09277034A JP H09277034 A JPH09277034 A JP H09277034A JP 8861196 A JP8861196 A JP 8861196A JP 8861196 A JP8861196 A JP 8861196A JP H09277034 A JPH09277034 A JP H09277034A
Authority
JP
Japan
Prior art keywords
molten metal
immersion nozzle
nozzle
electromagnetic coil
time
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8861196A
Other languages
Japanese (ja)
Other versions
JP3468978B2 (en
Inventor
Masahiro Tani
雅弘 谷
Takehiko Fuji
健彦 藤
Eiichi Takeuchi
栄一 竹内
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP08861196A priority Critical patent/JP3468978B2/en
Publication of JPH09277034A publication Critical patent/JPH09277034A/en
Application granted granted Critical
Publication of JP3468978B2 publication Critical patent/JP3468978B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Continuous Casting (AREA)
  • Casting Support Devices, Ladles, And Melt Control Thereby (AREA)

Abstract

PROBLEM TO BE SOLVED: To prevent the sticking and the growth of non-metallic inclusion onto the inner wall surface of a nozzle by arranging an electromagnetic coil on the outer periphery of the immersion nozzle and supplying pulse-state AC current into the electromagnetic coil to develop the pulsation to molten metal in the nozzle. SOLUTION: In a continuous casting of the molten metal, the electromagnetic coil 5 is arranged on the outer periphery of the immersion nozzle 3 and AC current I is supplied into the electromagnetic coil 5. Then, magnetic field H changed with time is generated at the surroundings of the immersion nozzle 3. Further, eddy current (i) is induced into the molten metal in the immersion nozzle 3 by changing the magnetic field H with time. The magnetic field H and the eddy current are mutually affected and restraint F toward the center direction of the immersion nozzle 3 is worked. Then, at the time of periodically repeating the time which supplies the current, and the time which does not supply the current, the restraint F is intermittently acted to the molten metal to develop the pulsation to the fluid of molten metal in the immersion nozzle 3. The molten metal fluid in the immersion nozzle 3 is uniformized by the pulsation, and the stuck quantity of the non-metallic inclusion of alumina, etc., onto the inner wall surface of the immersion nozzle 3 is reduced.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、溶融金属の連続鋳
造方法に関し、詳しくは浸漬ノズル内の溶融金属流動を
制御することにより、ノズル閉塞ならびに溶融金属の鋳
型内偏流を防止する連続鋳造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a continuous casting method for molten metal, and more particularly to a continuous casting method for preventing nozzle clogging and drift of molten metal in a mold by controlling molten metal flow in an immersion nozzle. .

【0002】[0002]

【従来の技術】連続鋳造工程においてタンディッシュ内
の溶融金属を鋳型内の注入する際に、ノズル内壁面の溶
融金属流動の低速領域に、アルミナ等の酸化物系介在物
の付着が時間と共に進行して成長すると、ノズルの閉塞
状態が発生するので、これを防止するためにノズルの使
用時間が制限される。また、ノズル内壁面から付着物が
剥離すると、これが鋳型内に流動して鋳片内に補足さ
れ、大型介在物となって製品欠陥を誘発させる。さら
に、ノズル内に付着・成長した介在物により、ノズル内
溶融金属流速分布ならびにノズルから吐出する溶融金属
流速分布が不均一になり、鋳型内における溶融金属の偏
流が生じて鋳型内湯面の連鋳パウダを巻き込んで製品欠
陥を誘発させる。
2. Description of the Related Art When a molten metal in a tundish is poured into a mold in a continuous casting process, an oxide-based inclusion such as alumina adheres to a low-speed region of molten metal flow on the inner wall of a nozzle with time. If it grows, the nozzle will be blocked, and the nozzle usage time is limited to prevent this. Further, when the adhering matter is separated from the inner wall surface of the nozzle, the adhering matter flows into the mold and is trapped in the slab and becomes a large inclusion to induce a product defect. Furthermore, due to the inclusions that have adhered and grown in the nozzle, the molten metal flow velocity distribution in the nozzle and the molten metal flow velocity distribution discharged from the nozzle become non-uniform, causing uneven flow of molten metal in the mold and continuous casting of the molten metal in the mold Involve powder and induce product defects.

【0003】上記アルミナ等の酸化物系介在物の浸漬ノ
ズル内壁面への付着を防止する目的で、特開昭62−1
30754号公報には、黒鉛質浸漬ノズルにおいて、吐
出口側壁部及び底部に設けたガス均圧室(スリット)よ
りノズル内壁面にガス吹き込みを行うようにした、ガス
吹き込み型浸漬ノズルが開示されている。このノズルを
用いることにより、従来タイプノズルと比較してノズル
閉塞防止効果が格段に向上し、多連続鋳造が可能になっ
たとしている。また、特公平7−34978号公報に
は、浸漬ノズルの少なくとも溶鋼に接する部分の耐火物
をZrO2 −CaO−C系の耐火物とすることにより、
ノズル孔部および吐出口の壁面へのアルミナ付着を抑止
する方法が開示されている。
In order to prevent the above-mentioned oxide inclusions such as alumina from adhering to the inner wall surface of the immersion nozzle, JP-A-62-1 is used.
Japanese Patent No. 30754 discloses a gas injection type immersion nozzle, in which a gas is injected into a nozzle inner wall surface from a gas pressure equalizing chamber (slit) provided in a discharge port side wall portion and a bottom portion in a graphite immersion nozzle. There is. It is said that the use of this nozzle significantly improves the nozzle clogging prevention effect as compared with the conventional type nozzle, and enables multi-continuous casting. Further, in Japanese Patent Publication No. 7-34978, a refractory of at least a portion of the immersion nozzle in contact with the molten steel is a ZrO 2 —CaO—C refractory,
A method for suppressing the adhesion of alumina to the nozzle hole and the wall surface of the discharge port is disclosed.

【0004】[0004]

【発明が解決しようとする課題】前記したように、特開
昭62−130754号公報には、ノズル内壁面にガス
吹き込みを用いる方法が開示されているが、この方法の
場合浸漬ノズルから溶鋼に同伴されて吐出したArガス
等の気泡が鋳型内において凝固シェルの凝固前面に捕捉
されると、鋼板の圧延過程において気泡性欠陥を誘発さ
せる。また、特公平7−34978号公報には、ノズル
材質の変更により、ノズル内壁面への付着量を減少させ
ることが試みられているが、付着抑止効果は十分とはい
えない。
As described above, Japanese Patent Laid-Open No. 62-130754 discloses a method in which gas is blown into the inner wall surface of the nozzle. In this method, molten steel is fed from the immersion nozzle. When bubbles of Ar gas or the like that are entrained and discharged are trapped on the solidification front surface of the solidification shell in the mold, they induce bubble defects in the rolling process of the steel sheet. Further, Japanese Patent Publication No. 7-34978 attempts to reduce the amount of adhesion to the inner wall surface of the nozzle by changing the nozzle material, but the effect of suppressing adhesion is not sufficient.

【0005】本発明の目的は、浸漬ノズル内壁面にガス
吹き込みを行ったり、浸漬ノズルの内壁に特殊な材質の
耐火物を用いることなしに、電磁力を用いて浸漬ノズル
内を流動する溶融金属に脈動を発生させることにより、
ノズル内壁面へのアルミナ等酸化物系非金属介在物の付
着・成長を阻止し、浸漬ノズルの閉塞を防止するととも
に、鋳型内における溶融金属の偏流を防止して、内部品
質ならびに表面品質の優れた連鋳鋳片を製造することの
できる連続鋳造方法を提供することにある。
An object of the present invention is to provide a molten metal that flows in the immersion nozzle by using electromagnetic force without blowing gas into the inner wall of the immersion nozzle or using a refractory material of a special material on the inner wall of the immersion nozzle. By generating pulsation in
Prevents adhesion and growth of oxide-based non-metallic inclusions such as alumina on the inner wall of the nozzle, prevents clogging of the immersion nozzle, and prevents drift of the molten metal in the mold, providing excellent internal and surface quality. Another object of the present invention is to provide a continuous casting method capable of producing continuous cast slabs.

【0006】[0006]

【課題を解決するための手段】本発明は上記課題を解決
するためになしたものであり、その主旨とするところは
下記の通りである。 (1)溶融金属の連続鋳造方法において、タンディッシ
ュ内の溶融金属を鋳型内に注入する浸漬ノズルの外周に
電磁コイルを配設し、該電磁コイルにパルス状の交流電
流を通電することにより浸漬ノズル内を流動する溶融金
属流に脈動を発生させて、浸漬ノズルの内壁にアルミナ
等の非金属介在物の付着・成長を阻止することにより、
浸漬ノズルの閉塞を防止するとともに、鋳型内における
溶融金属の偏流を防止することを特徴とする溶融金属の
連続鋳造方法である。 (2)前項(1)の方法において、電磁コイルが、偏平
な導電体と絶縁物を交互に積み重ねて形成される螺旋コ
イルの軸方向に、冷却水を通水させるたの複数の通水路
を貫通て、該電磁コイルを冷却する構造であるビターコ
イルを利用することを特徴とする溶融金属の連続鋳造方
法である。
The present invention has been made to solve the above problems, and the gist thereof is as follows. (1) In a continuous casting method for molten metal, an electromagnetic coil is arranged around the immersion nozzle for injecting the molten metal in a tundish into a mold, and immersion is performed by passing a pulsed alternating current through the electromagnetic coil. By pulsating the molten metal flow flowing in the nozzle to prevent the non-metallic inclusions such as alumina from adhering and growing on the inner wall of the immersion nozzle,
It is a continuous casting method for molten metal, which prevents clogging of an immersion nozzle and prevents drift of molten metal in a mold. (2) In the method of (1) above, the electromagnetic coil has a plurality of water passages for passing cooling water in the axial direction of the spiral coil formed by alternately stacking flat conductors and insulators. A continuous casting method for molten metal is characterized in that a bitter coil having a structure for cooling the electromagnetic coil is used to penetrate therethrough.

【0007】[0007]

【発明の実施の形態】本発明の実施の形態を図1〜5に
従って説明する。図1に示す溶融金属の連続鋳造におい
て、溶融金属1は、タンディッシュ2から浸漬ノズル3
を通して鋳型4に注入される。浸漬ノズル3の内壁面へ
の酸化物系介在物の付着は、浸漬ノズル3内部のスライ
ディングノズル直下、ノズル内メニスカスの下方、ノズ
ル吐出口の周辺ならびにノズル底部のいわゆる溶融金属
流動の低速領域において発生する。
BEST MODE FOR CARRYING OUT THE INVENTION An embodiment of the present invention will be described with reference to FIGS. In the continuous casting of the molten metal shown in FIG. 1, the molten metal 1 is fed from the tundish 2 to the immersion nozzle 3
Is injected into the mold 4. Adhesion of oxide-based inclusions to the inner wall surface of the immersion nozzle 3 occurs immediately below the sliding nozzle inside the immersion nozzle 3, below the meniscus in the nozzle, around the nozzle discharge port and in the so-called low-velocity region of molten metal flow at the bottom of the nozzle. To do.

【0008】この時、図2に示すように浸漬ノズル3の
外周に設置した電磁コイル5に交流電流Iを通電する
と、浸漬ノズル3の周囲には時間的に変化する磁場Hが
生じる。また、磁場Hの時間変動によって、浸漬ノズル
3内の溶融金属に渦電流iが誘起される。この磁場Hと
渦電流iとがお互いに作用し合い、浸漬ノズル3の中心
方向に向かった拘束力Fが働く。
At this time, when an alternating current I is applied to the electromagnetic coil 5 installed on the outer periphery of the immersion nozzle 3 as shown in FIG. 2, a time-varying magnetic field H is generated around the immersion nozzle 3. Further, an eddy current i is induced in the molten metal in the immersion nozzle 3 due to the time variation of the magnetic field H. The magnetic field H and the eddy current i act on each other, and the restraining force F toward the center of the immersion nozzle 3 acts.

【0009】ここで、図3(a)に例示するようにノズ
ル内溶融金属に拘束力Fを作用させる大電流I1 を通電
する時間t1 と電流を通電しない時間t2 を周期的に繰
り返す、もしくは図3(b)に例示するようにノズル内
溶融金属に拘束力Fを作用させる大電流I1 を通電する
時間t1 とこれとは異なる作用を得るための小電流I3
を通電する時間t3 を周期的に繰り返すことにより、溶
融金属に拘束力Fが間欠的に作用し、浸漬ノズル内の溶
融金属流動に脈動を発生させる。
Here, as illustrated in FIG. 3A, a time t 1 for applying a large current I 1 for applying a restraining force F to the molten metal in the nozzle and a time t 2 for not applying the current are periodically repeated. Alternatively, as illustrated in FIG. 3B, a time t 1 for applying a large current I 1 for applying a restraining force F to the molten metal in the nozzle and a small current I 3 for obtaining an action different from this
By periodically repeating the time t 3 for energizing the molten metal, the restraining force F acts intermittently on the molten metal, causing pulsation in the molten metal flow in the immersion nozzle.

【0010】この脈動によりノズル内溶融金属流動を均
一化させ、低速流動領域を減少させることにより、浸漬
ノズル内壁面への介在の付着量を低減させる。また、脈
動にによる圧力変動により、浸漬ノズル内壁面に付着直
後の介在物を剥離させる。さらに、ノズル内溶融金属流
動を均一化させることにより、浸漬ノズル3から吐出す
る溶融金属流動が均一になるので、鋳型内溶融金属の偏
流を防止することがでできる。
By this pulsation, the molten metal flow in the nozzle is made uniform, and the low-speed flow region is reduced, so that the amount of interposition adhered to the inner wall surface of the immersion nozzle is reduced. Further, due to the pressure fluctuation caused by the pulsation, the inclusions immediately after adhering to the inner wall surface of the immersion nozzle are peeled off. Further, by making the molten metal flow in the nozzle uniform, the molten metal flow discharged from the immersion nozzle 3 becomes uniform, so that the drift of the molten metal in the mold can be prevented.

【0011】また、ノズル3の外周に設置した電磁コイ
ル5は、ビターコイルであることが望ましい。ビターコ
イルは、 M.Garnierが1990年にIISCの名古屋で
公開しているコイル構造で、図5に示す偏平な導電体
6、絶縁物7、冷却水孔8、ボルト孔9から形成される
構造であり、コイルの軸方向に導電体6と絶縁物7を貫
通させて冷却水を通過させる。このビターコイルの構造
に関しては、Proceedingof The 6th IISC,1990,Nagoya,
ISIJ Vol.4 P223,Fig-1及び本文に記載されている。通
常の水冷管を用いた水冷コイルに比べて、ビターコイル
では冷却水の流路における圧損が少なく大量の冷却水を
供給できるので、大電流の印加に適しており、電磁コイ
ルのコンパクト化が可能である。
The electromagnetic coil 5 installed on the outer periphery of the nozzle 3 is preferably a bitter coil. The bitter coil is a coil structure disclosed by M. Garnier in Nagoya of IISC in 1990, and is composed of a flat conductor 6, an insulator 7, a cooling water hole 8 and a bolt hole 9 shown in FIG. That is, the cooling water is passed through the conductor 6 and the insulator 7 in the axial direction of the coil. Regarding the structure of this bitter coil, Proceeding of The 6th IISC, 1990, Nagoya,
It is described in ISIJ Vol.4 P223, Fig-1 and the text. Compared to a water-cooled coil that uses a normal water-cooled tube, the bitter coil has less pressure loss in the cooling water flow path and can supply a large amount of cooling water, making it suitable for applying a large current and enabling compact electromagnetic coils. Is.

【0012】[0012]

【実施例】本発明の効果を検討するために溶鋼での鋳造
実験を行った。溶鋼は中炭素アルミキルド鋼を用いた。
浸漬ノズルの内径は80mmφ、連続鋳造速度は1.0m
/min、浸漬ノズルの材質はアルミナ−グラファイト質
(内層ジルコニア質)、浸漬ノズル周囲の電磁コイルに
は、0.5秒間隔で通電と非通電を繰り返す通電パター
ンの200Hzの交流電流を印加した。図4に、鋳造時間
100分後のアルミナ付着厚さを比較した結果を示す。
本発明法は従来法と比較してアルミナ付着量が、1/2
〜1/3に減少している。
EXAMPLE A casting experiment with molten steel was conducted in order to examine the effect of the present invention. Medium carbon aluminum killed steel was used as the molten steel.
Inner diameter of immersion nozzle is 80mmφ, continuous casting speed is 1.0m
/ min, the material of the immersion nozzle was alumina-graphite material (inner layer zirconia material), and an alternating current of 200 Hz was applied to the electromagnetic coil around the immersion nozzle in an energization pattern in which energization and de-energization were repeated at intervals of 0.5 seconds. FIG. 4 shows the results of comparing the alumina adhesion thickness after 100 minutes of casting time.
According to the method of the present invention, the amount of adhered alumina is 1/2 that of the conventional method.
It has decreased to ⅓.

【0013】[0013]

【発明の効果】本発明によって、溶融金属の連続鋳造工
程におけるタンディッシュ内の溶融金属を鋳型内に注入
する浸漬ノズル内壁面への酸化物系介在物の付着を防止
し、さらに、鋳型内溶融金属の偏流を防止できるので、
内部品質ならびに表面品質の優れた連鋳鋳片を製造する
ことができる。
According to the present invention, in the continuous casting process of molten metal, oxide inclusions are prevented from adhering to the inner wall surface of the immersion nozzle for injecting the molten metal in the tundish into the mold. Since it is possible to prevent uneven flow of metal,
A continuous cast slab having excellent internal quality and surface quality can be manufactured.

【図面の簡単な説明】[Brief description of drawings]

【図1】溶融金属の連続鋳造工程におけるタンディッシ
ュ、浸漬ノズル、電磁コイル、鋳型の取り合いを示す概
要図である。
FIG. 1 is a schematic diagram showing the arrangement of a tundish, an immersion nozzle, an electromagnetic coil, and a mold in a continuous casting process of molten metal.

【図2】電磁コイルへの交流電流の通電により、ノズル
内溶融金属へ作用する拘束力Fを示す説明図である。
FIG. 2 is an explanatory diagram showing a restraining force F acting on molten metal in a nozzle when an alternating current is applied to an electromagnetic coil.

【図3】電磁コイルに通電するパルス状交流電流の印加
パターンの例を示す図である。
FIG. 3 is a diagram showing an example of an application pattern of a pulsed alternating current that is applied to an electromagnetic coil.

【図4】ノズル内壁へのアルミナ付着量の比較を示す図
である。
FIG. 4 is a diagram showing a comparison of the amount of alumina adhered to the inner wall of the nozzle.

【図5】ビターコイルの概念図である。FIG. 5 is a conceptual diagram of a bitter coil.

【符号の説明】[Explanation of symbols]

1:溶融金属 2:タンディッシュ 3:浸漬ノズル 4:鋳型 5:電磁コイル 6:電導体 7:絶縁物 8:冷却水孔 9:ボルト孔 1: Molten metal 2: Tundish 3: Immersion nozzle 4: Mold 5: Electromagnetic coil 6: Electric conductor 7: Insulator 8: Cooling water hole 9: Bolt hole

フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 B22D 27/02 B22D 27/02 U 41/62 41/62 Continuation of the front page (51) Int.Cl. 6 Identification code Office reference number FI technical display location B22D 27/02 B22D 27/02 U 41/62 41/62

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 溶融金属の連続鋳造方法において、タン
ディッシュ内の溶融金属を鋳型内に注入する浸漬ノズル
の外周に電磁コイルを配設し、該電磁コイルにパルス状
の交流電流を通電することにより浸漬ノズル内を流動す
る溶融金属流に脈動を発生させて、浸漬ノズルの内壁に
アルミナ等の非金属介在物の付着・成長を阻止し、浸漬
ノズルの閉塞を防止するとともに、鋳型内における溶融
金属の偏流を防止することを特徴とする溶融金属の連続
鋳造方法。
1. A continuous casting method for molten metal, wherein an electromagnetic coil is provided around an outer circumference of a dipping nozzle for injecting the molten metal in a tundish into a mold, and a pulsed alternating current is applied to the electromagnetic coil. Generates pulsation in the molten metal flow flowing in the immersion nozzle, prevents adhesion and growth of non-metallic inclusions such as alumina on the inner wall of the immersion nozzle, prevents clogging of the immersion nozzle, and melts in the mold. A continuous casting method for molten metal, characterized by preventing uneven flow of metal.
【請求項2】 請求項1に記載の電磁コイルが、偏平な
導電体と絶縁物を交互に積み重ねて形成される螺旋コイ
ルの軸方向に、冷却水を通水させるたの複数の通水路を
貫通させて、該電磁コイルを冷却する構造であるビター
コイルを利用することを特徴とする請求項1に記載の溶
融金属の連続鋳造方法。
2. The electromagnetic coil according to claim 1, wherein a plurality of water passages for passing cooling water are provided in an axial direction of a spiral coil formed by alternately stacking flat conductors and insulators. The method for continuous casting of molten metal according to claim 1, wherein a bitter coil having a structure for cooling the electromagnetic coil by penetrating is used.
JP08861196A 1996-04-10 1996-04-10 Continuous casting method of molten metal Expired - Fee Related JP3468978B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP08861196A JP3468978B2 (en) 1996-04-10 1996-04-10 Continuous casting method of molten metal

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CN100357049C (en) * 2005-09-29 2007-12-26 赫冀成 Electromagnetic eddy flow downspout
CN104028717A (en) * 2014-06-10 2014-09-10 东北大学 Electromagnetic swirling continuous casting method
CN107999718A (en) * 2017-12-07 2018-05-08 安徽工业大学 A kind of method for improving micro-alloyed steel continuous casting process castability
CN109759576A (en) * 2019-03-19 2019-05-17 北京科技大学 It is a kind of for heating the device and its dynamic control method of molten steel in submersed nozzle
RU2721768C1 (en) * 2017-02-20 2020-05-22 Абб Аб Method and system of mixing, designed to control electromagnetic mixer
WO2022063425A1 (en) * 2020-09-24 2022-03-31 Karlsruher Institut Für Technologie (Kit) Magnet device based on the bitter principle and use of a magnet device based on the bitter principle
CN115229150A (en) * 2022-07-04 2022-10-25 攀钢集团攀枝花钢铁研究院有限公司 Method for controlling rail inclusions
CN115716126A (en) * 2022-11-15 2023-02-28 包头钢铁(集团)有限责任公司 Method for solving blockage problem of rare earth steel continuous casting submerged nozzle

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100357049C (en) * 2005-09-29 2007-12-26 赫冀成 Electromagnetic eddy flow downspout
CN104028717A (en) * 2014-06-10 2014-09-10 东北大学 Electromagnetic swirling continuous casting method
RU2721768C1 (en) * 2017-02-20 2020-05-22 Абб Аб Method and system of mixing, designed to control electromagnetic mixer
US10919088B2 (en) 2017-02-20 2021-02-16 Abb Schweiz Ag Method and stirring system for controlling an electromagnetic stirrer
CN107999718A (en) * 2017-12-07 2018-05-08 安徽工业大学 A kind of method for improving micro-alloyed steel continuous casting process castability
CN109759576A (en) * 2019-03-19 2019-05-17 北京科技大学 It is a kind of for heating the device and its dynamic control method of molten steel in submersed nozzle
WO2022063425A1 (en) * 2020-09-24 2022-03-31 Karlsruher Institut Für Technologie (Kit) Magnet device based on the bitter principle and use of a magnet device based on the bitter principle
CN115229150A (en) * 2022-07-04 2022-10-25 攀钢集团攀枝花钢铁研究院有限公司 Method for controlling rail inclusions
CN115229150B (en) * 2022-07-04 2024-05-14 攀钢集团攀枝花钢铁研究院有限公司 Method for controlling rail inclusions
CN115716126A (en) * 2022-11-15 2023-02-28 包头钢铁(集团)有限责任公司 Method for solving blockage problem of rare earth steel continuous casting submerged nozzle

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