JPH09188869A - Effective utilization of product obtained from solution of waste cocoon in alkaline earth solution or liquid mixture thereof to obtain adhesive, antifrosting, snow-proofing, ice-proofing, thawed ice releasing and mildew-proofing properties - Google Patents

Abstract

PURPOSE: To obtain a product having adhesive, antifrosting, snow-proofing, ice-proofing thawed ice releasing, and mildew-proofing properties by dissolving waste cocoons in an acid or alkali, neutralizing the resultant solution, desalting the obtained product, and mixing the obtained cocoon component with a synthetic resin. CONSTITUTION: Waste cocoons are effectively utilized by dissolving them in an alkaline earth metal solution, or dissolving them in monochloroacetic acid, sulfuric acid or hydrochloric acid and then neutralizing the solution with an alkali, desalting the product, concentrating the product, and mixing the obtained product with a synthetic resin to accelerate the resinification and thereby improving low-temperature resistance, hygroscopicity and plasticity. Thus the waste cocoons are effectively utilized for antifrosting a freezer, or for snow-proofing, antifreezing and releasing purpose for the preparation of a package of a frozen food, refrigerator, roof, gutter, water pipe, building, glass, boots, etc., by coating them with a combination of the waste cocoons with a surfactant and the oily resin to improve the antifrosting and antifreezing effects.

Description

Detailed Description of the Invention

This invention, as a part of the effective use of cocoon waste, as an aqueous solution obtained by heating cocoon waste dissolved in alkaline earth water solution or a solution obtained by dissolving cocoon protein in monochloroacetic acid, sulfuric acid or hydrochloric acid in this aqueous solution as an alkaline solution. Concentrated cocoon scrap alkaline earth liquid with neutralized desalted purified liquid, dissolved chitin chitosan or calcium carbonate dispersed alkaline earth liquid is used as a purification adsorbent for automobile exhaust gas in fibers and ceramics. Adsorbed and used for purification of pollution gas, or a synthetic resin such as urea resin mixed with this liquid to impregnate a fibrous material or a plastics film with a cold-resistant adhesive or moisture absorbent to impregnate it. To
A fiber impregnated with a surfactant is combined with an oil-based cold-resistant resin, and a frost-proof and anti-icing fiber-processed fiber processed product is used as a snow and anti-icing agent for power lines and towers. It is processed on the surface and also suppresses the frosting property of the freezer and the packaging of frozen foods and frozen medical products to give peeling property and prevents snow, frost and frost on the roof, toyo, wooden house and frozen food defroster. Effective utilization of cold frost resistance, adsorption, deicing, and deicing peelability by the combined use of alkaline earth of cocoon, oily resin, surfactant and fiber paper cloth characterized by imparting ice peeling property Is.
Generally, the cocoon waste has been reduced to the soil, but about 30 to 40% of the cocoon thread is produced as the cocoon waste, so that its effective use has been desired. Therefore, as a part of it, from the use of ceracin protein, it is dissolved in acid and then neutralized with alkali, the resulting salt is purified and removed, and the purified ceracin protein and the already decomposed liponucleic acid are recovered, tofu or confectionery, The time has come for the foods added to foods to be put into practical use, but if the addition amount is large, the flavor becomes worse than that of the conventional products, so the addition amount was limited. For this reason, it was necessary to develop new cocoon waste as an industrial raw material used in large quantities. Therefore, as a recycle of this cocoon waste, cocoon waste dissolved in hydrochloric acid, monochloroacetic acid, alcohol acetic acid, etc. together with chitosan and chitin is used as a continuous crop damage inhibitor for vegetables, lawns and other plants, and necessary soil microorganisms are used. As an innkeeper, the antibacterial property due to the enveloping of harmful gold was used to bring about the effect. In addition, for the purification of water, a hydrochloric acid solution of cocoon waste and an alkaline cocoon waste alkaline earth liquid were used as a condensing agent. D. O. We have also continued research on methods to reduce the P value, but in order to meet more practical demand, when mixing the cocoon waste alkaline earth water solution with urea formal resin, a certain amount of urea resin must be added in the resulting urea resin. A synthetic resin that retains water is formed and becomes thermoplastic, but when the addition amount is small, it becomes thermosetting. This thermosetting resin does not crack in the dry areas of deserts such as the United States, the Middle East and Egypt. Its properties have been improved even in linden, melamine resin, and huminol resin, and it accelerates the reaction and pulverization at the initial stage of the resin, and laminates pulverized resin with fiber paper or fiber cloth. The heat processing operation is simplified, and-
It is used for processing synthetic resin moldings that can withstand 20 ° C. However, the use of the alkaline earth liquor of this coconut waste is used as a recycle of the clay-limestone mixed sludge in the mining of limestone, which is a consistent industrial waste, and this sludge is used for the production of maltite, pumice, zeolite, and bentonite. When mixed and fired, the calcium carbonate in the limestone is pyrolyzed by firing and C
aCo3 → Cao + Co2 ↑ becomes Co2 and diverges in the form of gas, but at that time, 0.025 micron pores are made in the fired product of the ceramic, so the one impregnated with the cocoon waste alkaline earth liquid is the ceramic fired. The material has a honeycomb structure and also functions as an adsorbent. or,
When waste pulp sludge is mixed with sodium alginate water and alkaline earth cocoon waste and molded with an extruder, not only can the sludge be effectively used as recycled paper, but also the molded product of honeycomb coil can be obtained by extrusion. It is strengthened by adding chitosan to water. Also, when processing waste paper such as newspaper and waste paper into recycled paper, it becomes deliquescent paper when impregnated with cocoon waste alkaline earth, so that this fiber cloth does not become fragile and aged during thermal processing. . In particular, it is a great advantage that pulp has less breakage of oxygen bridges of the glucose group in its molecular structure. In this case, the cocoon waste alkaline earth acts as a hardening accelerator, but it goes without saying that hardening increases as the added amount increases, so it is necessary to appropriately determine the added amount. In the reaction of phenol and formalin, a resin which can increase the added amount of formalin can be obtained. Also, in the reaction of formalin, ultrapin, and paraaldehyde in a solution of polyamide, polyethylene terephthalic acid resin, or polypropylene terephthalic resin dissolved in phenol as a solvent, the addition of cocoon waste alkaline earth should be after addition of alcohol. It can also be used as a unique mixed thermoplastic phenolic resin by heat. Further, when mixed with concrete cement, strength cold resistance is improved by 20% even at -10 ° C. It can also be used as an adsorbent for exhaust gas, and this cocoon waste alkaline earth is mixed with industrial waste limestone and sludge and applied to pulp paper, ceramics porous, and fiber cloth for denitrification. It has the effect of expanding the lasting effect of and effectively reacting to the desulfurization of sulfur dioxide in factories and coal collection chambers. That is, H
2o + So2 + CaCo3 → CaSo3 + Co2 ↑ + H
2o H2o + CacL2 + So2 + CaCo3 → CaSo3
+ H2cL2 → CaSo3 + CacL2 + Co2 ↑ In the case of denitration, H2o + CacL2 + No2 + CaCo3 → CaN3 +
CaCL2 + Co2 ↑ and cocoon protein is produced HCL
Has the effect of absorbing the secondary pollution of the exhaust gas. or,
Installed at the exhaust gas outlet of the automobile is this ceramic sintered honeycomb or pulp honeycomb impregnated with cocoon scrap alkaline earth calcium carbonate liquid, and vents the automobile combustion exhaust gas into the porous body of ceramics or fiber paper. At this time, the free carbon block generated by the Diesel engine is slightly larger than the pores of the porous body and cannot be separated by filtration, and is separated by the viscous liquid of the impregnated alkaline alkaline earth liquid remaining in the porous body. The gas exhausted from the exhaust port is adsorbed as nitrogen oxide, sulfurous acid, and anhydrous sulfuric acid, and is exhausted from the exhaust port as an exhaust gas with almost no pollution. The cocoon of the adsorption catalyst absorbs an appropriate amount of water by an alkaline alkaline earth water solution and always keeps it wet. Calcium carbonate, to replenish the water in the water-containing porous alkaline earth solution. Further, since the porous material such as slag is regenerated and separated into an adsorbate when washed with an alkaline earth liquid, it is used for purification of regenerated exhaust gas. In the case of paper quality, the structure of the exhaust stack bag is used as exhaust gas ventilation holes through the pores of the corrugated partition structure of the honeycomb structure or the corrugated board structure. In the case of plastics, a heat resistant resin is used to withstand the heating temperature of the exhaust gas. The diameter of this exhaust gas vent hole becomes stronger as it forms finer holes, but the adhesion with the exhaust gas becomes stronger, but with such a honeycomb structure, the production cost increases, so glass fiber, mineral fiber, metal fiber,
It is also used for press compression plates and sintered plates of cutting metal scraps, and also for ceramic porous bodies. Further, in the case of a mineral substance such as glass fiber, if the exhaust gas pressure is strong, the fibers are scattered in the exhaust gas to cause secondary pollution. Therefore, it is also necessary to prevent the scattering by coating with a resin in advance. In this adsorption of exhaust gas, the wind velocity of exhaust gas is generally 20 US or more. Therefore, when adsorption is not sufficiently performed on a part, denitration is performed by electrostatic adsorption or discharge adsorption on this porous material. Since it is more important to enhance the desulfurization effect, it is necessary to sufficiently insulate the conductivity of the porous tubular bag by using an insulator. or,
As a simple matter, waste paper is coarsely filled with waste paper into a waste paper system by the disposal method, and the inside of the bag is impregnated with a liquid mixed with alkaline earth liquid, alkaline liquid, calcium carbonate or calcium hydroxide liquid. A method of degassing and denitrifying sulfur by introducing a gas into a filter is also used. If it is discarded every day, replace it every day, screw it to the outlet of the exhaust pipe with a fixed ring and fix it, and replace it when it loses its usefulness. Coarse, chip coarse,
Ground pulp fibers are used. As a known purification method of this kind of exhaust gas, a ceramic molded porous material in which a platinum catalyst, nickel, cobalt, manganese catalyst, titanium or vanadium is impregnated with a catalyst has been used in a muffler of an exhaust stack. However, due to the generation of free carbon, it loses its vitality and the denitrification and desulfurization action also decreases by about 20 to 50%. However, the number of automobiles literally increases every month and the amount of harmful gas exhausted increases automatically. It is in a state where regulations must be enforced. Because of this,
Although an electric vehicle without exhaust gas was developed, the cost of the electric vehicle was more than three times that of a practical vehicle, and the cost of the solar cell vehicle as the power source of the solar cell was further increased. For this reason, an exhaust gas cylinder bag made of extremely cheap and lightweight paper or papermaking is made by an automatic machine, and when using the same solution containing alkaline alkaline earth liquid containing cocoon waste or synthetic resin, Cocoon Alkaline alkaline earth liquid is always deliquescent and absorbs moisture in automobile combustion gas well to maintain its activity. Therefore, it also absorbs nitrogen oxide, sulfurous acid gas and some carbon dioxide gas, and also absorbs ammonia gas. At the same time, the free carbon is wet-attached by the deliquescent surface to clean the black smoke, so the production cost is not only cheaper than using the catalyst ceramic molded body even if it is discarded around ■■, The denitrification rate is 80% or more, and the desulfurization rate is 85% or more. When the exhaust pipe of the car is installed so as to perform in the traveling direction and the secondary air is promoted to enter the exhaust pipe, Pollution of the gas is extremely a useful invention that has 混抄 zeolite or calcium salt in an exhaust pipe bag paper making to enhance also its denitration 硫率 sustained reactive because lead to further decrease, also,
In the case of paper made by mixing glass fiber, mineral fiber, and carbon fiber, the absolute degree of kinship is twice that of normal pulp paper, and the expansion and contraction due to vertical and horizontal humidity is reduced, so a standardized molded product is obtained and a filter effect is also obtained. It is characterized by high air resistance and low air resistance. When a generator with a high static voltage of 1 to 50,000 bottles is installed on this and both screen electrodes are fixed in series at a fixed interval, the exhaust gas passing through these electrodes is forcibly electrodeposited by the discharge charge, especially free carbon. Since more than 80% of the air pollution is separated, air pollution is reduced and the denitrification rate is 9%.
Since it reaches 6%, static electricity can be obtained by a multiplication method using a rotary disk type triboelectric generator or an induction coil.
It can also be obtained by pressurizing the piezoelectric element, and to enhance its strength and durability as an exhaust stack, use a corrugated corrugated structure of corrugated cardboard or a structure with minute fine holes made of honeycomb coils, or a ceramic porous molding hole. When impregnating this with the alkaline alkaline earth liquid containing cocoon dust, it is said that it exerts the same denitrification effect as paper fiber, and it also contains this cocoon dust. The alkaline alkaline earth liquid has increased water retention and temperature compared to the alkaline alkaline earth of cocoon waste. Further, when the cocoon concentration is increased with respect to the alkaline alkaline earth containing the cocoon and it is dissolved under pressure in a high-pressure gas can, a nematic liquid crystal is obtained, and when the cocoon concentration exceeds 3%, The liquid crystal effect gradually increases, and it has the same effect as cholesterol, but its production cost is not only lower than that of cholesterol, but it is also resource-friendly. In addition, P-nitrophenol, sodium, No2C6H4 DNA-2H2o was added to the alkaline earth liquid of this cocoon waste.
Or a mixture of surface active agents such as guaiacol, dodecyl, sodium benzyl sulfonate, etc. applied to plastics paper, cellophane paper or paper, or a film applied to polyurethane or porous synthetic resin on the cooling surface of the refrigerator. When it is attached to the surface of a heat exchanger or a heat exchanger, the anti-frost and snow-prevention effects are greatly improved, and those containing a greater amount of sodium P-nitrophenol are less frost-proof. Therefore,
These are also used for snow protection on roofs, toco doors, door handles, doorways, and road surfaces. In addition, a high-pressure molded product obtained by mixing and sintering zirconium oxide, hafnium oxide, monaz sand, etc. into an alloy containing beryllium copper in aluminum is useful as a deicing plate, but this defrosting plate is also used when the temperature falls below the freezing point. Although the ice-melting plate gradually decreases as the temperature decreases, the use of anti-frost and snow-proofing agents for the ice-breaking of frozen foods promotes the ice-melting effect at room temperature. In addition, anti-frost agents such as
It is also used as an antifreeze for cold weathering of plants and has the effect of preventing the formation of ice on trees and trees such as tea. In particular, the straw muscillo or rope impregnated has the property that it is difficult to form rime. An embodiment of the present invention will be described below with reference to the drawings.

FIG. 1 shows a vertical cross-sectional view of a denitrification sulfur muffler cover (1), and (2) is a tubular bag made of metal paper, fiber mat, and ceramic. Adsorbed catalyst paper pieces, glass fibers, mince mineral fibers, and ceramic porous plastics (3) are pressed into the cylindrical bag.

FIG. 2 is a side view of a denitrification muffler cover tubular bag (1). The paper piece (3) inside the tubular body (1) is made to adsorb and push the adsorption catalyst liquids (A) and (A '), and is screwed and fixed to the exhaust port (4) of the automobile of FIG. . Explaining the action climate of this adsorptive denitrification muffler cover (1),
The combustion exhaust gas after burning the fuel in the engine (5) of the automobile (B) passes through the exhaust muffler and after the denitrification muffler cover (1) is screwed to the tip of the exhaust port (4). The exhaust gas is introduced into the cover (1) to contact the fiber paper or the like (#) which has adsorbed the cocoon waste alkaline alkaline earth liquids (A), (A) and (A ') and is desulfurized and Since the free carbon is adsorbed on the surface and is exhausted through the pores (7) of the fiber paper cylinder bag while being filtered to the outside, the black free carbon is separated by furnace and the decolorized exhaust gas is emitted. This tubular bag has a diameter of about 15 rations and a length of 30 rations. It is neutralized and denitrified in a cocoon-alkaline alkaline earth mixture liquid of paper-like dusty paper, hemp fibers and glass fiber ceramic granules. Since 80% of them are adsorbed, air pollution is reduced accordingly. This paper tube is generally 24 hours to 4 hours
Adsorption will be completed in 8 hours, so replace with a new tubular bag and use. However, since this cylinder bag is a disposable purifying paper bag, it has a low durability and durability, but to strengthen it further and improve its durability.

As shown in FIG. 3, the corrugated cardboard (2a) is wound into a spiral shape and processed so that the exhaust gas passes between the mountain wave chambers (3a).
A cocoon-alkaline alkaline earth mixture (A) on this fiber paper
It is used as a muffler cover (1a) which is impregnated with (A ') and is subjected to a denitrification by contact reaction when passing through each room (3a).

[Fig. 5] A straw-like thin tube is filled as shown in the longitudinal sectional view of Fig. 5, and the cocoon-alkaline alkaline earth mixed liquids (A) and (A ') are adsorbed on the straw-like fibers (3b) to cause a catalytic reaction with exhaust gas. That purifies exhaust gas by

[Fig. 4] For example, a muffler cover (1b) for forming a honeycomb-shaped honeycomb such as a 6-membered ring and impregnating and adsorbing the liquids (A) and (A ') on it to purify the reaction is used. Molded fiber cylinder

[Fig. 6] Frangi (5d) in the center of the purifier (C)
At (5'd), the bolts and nuts are screwed and fixed, and the discharge electrodes (8d) (9d) (8'd) (9) are fixed inside the conical cylinders (7d) (7, d) at both ends. Connect'd) to the electrostatic generator (10a) (10'd) and lead wires (11d) (11'd)
And connect to print 10,000 to 50,000 volts. This discharge electrode (8
d) (9d) (8'd) (9'd) beside the porous ceramics of titanium, vanadium zirconium, hafnium thorium and silicate catalysts (12d) (12'd), The insertion pipe (3d) fitted in (4) is fitted and screwed to the exhaust pipe (4) with a ball nut. The combustion gas of the automobile engine exhausted from the inside of the exhaust stack (4) is first subjected to denitrification by the catalysts (12d) (12'd) and enters the honeycomb coil layer (14d) of the central cylinder (15d) to form this coil. Further, it is denitrified and adsorbed free carbon in a cocoon scrap alkaline alkaline earth mixed solution which has been impregnated in advance, and then enters the conical cylinder (7'd) to discharge the internal discharge electrode (8 ').
d) The exhaust gas burned by the engine is introduced into the diesel engine of the automobile which is discharged at (9'd) and passes through the catalyst layer (12'd) and is exhausted from the exhaust port (4 '). 400 p.m. when adsorbing with the alkaline-alkaline-earth mixed liquid of No. 1 and performing denitrification by electrostatic deposition. p. m of 125 p.
p. m becomes 30 to 50 p. p. Residual nitrogen oxides are reduced to m, and sulfurous acid gas is reduced at the same rate.

FIG. 8 shows its characteristics. When using a titanium, vanadium, zirconium, hafnium or thorium silicate catalyst, ammonia water is added to the fuel and the exhaust gas is purified by harmless nitrogen gasification.

FIG. 8 (a) is an adsorption honeycomb (1
4d) was adsorbed on the adsorbed cocoon waste alkaline alkaline earth mixed solution, (b) is the characteristic by the electro-deposition catalyst method, and (c) is the result of operating with the electro-deposition catalyst attached to both ends. is there. Also, a simple disposable disposable bag, that is,

FIG. 2 (e) shows the adsorption characteristics of the purified product of FIG. (F) is the case of direct exhaust.

[Fig. 9] is a mixture of cocoon waste alkaline alkaline earth mixed with synthetic resin polyvinyl alcohol and polyacrylic acid polyvinyl alcohol water. P-nitrophenol sodium, 5 nitroguaiacol sodium, O-nitrophenol alcohol is applied on one side. , Sodium dodecine benzyl sulfonate or dodecyl benzyl nitro soda coated with a surfactant (1e) dissolved in alcoholic water, dried, and cocoon waste alkaline alkaline earth water solution or ammonium sulfate solution added to the back surface Liquid (2e) in which polyvinyl alcohol is dissolved is applied and lightly dried, and an oily liquid (5e) containing water-resistant silicone resin, castor oil, and fluorinated resin is further applied to the surface of the surfactant (1e). What is applied and finished

FIG. 9 is useful as a power transmission line

(3L) in FIG. 9 is an electric wire.

FIG. 20 is a vertical cross-sectional view of the cutting (1 L) is a tape impregnated with a surfactant, and (2 L) is a coating surface of a cocoon waste alkaline alkaline earth water solution, and a surfactant solution ( 1 L) paper is coated with an oily liquid (5 L) to make it insulating. This power transmission line is screwed to the insulators (5L) (5'L) of the antenna (4L) (4'L) suspension body pulled between the steel towers 1L and 2L by a screwing body. On the surface of this steel tower, polyethylene coated with the oil-based defrosting agent,
Polypropylene, polyethylene vinyl acetate films are laminated and insulated, but those with silicone resin applied and baked or fluorinated resin Silicon resin or fluorinated resin,
Polyurethane resin paint is applied.

FIG. 10 is an enlarged side view of a paper or fiber tape (1′e) coated with a surfactant solution (1 L) and dried. A cocoon scrap alkaline alkaline earth mixture solution is applied to the back surface of the tape or 1′e for insulation. In order to raise the height, an oily liquid (5e) is applied to the front surface, and a tape having the oily liquid (3e) applied to the back surface is laminated.

FIG. 11

FIG. 9 is an enlarged side view of FIG. That is, 1 L of surfactant liquid
Which is coated with dried tape fiber (1'e) and coated with cocoon waste alkaline alkaline earth mixed solution (2e),
Cocoon waste Alkaline earth urea resin, melamine resin, phenol resin, aniline resin, popper resin, polyacrylic acid resin, polyvinylketone resin, etc. are used and mixed with sodium alginate, gelatin, casein starch, and fibrin ether resin. Liquid is used.

[Figure 12] is a frozen box (1f) for sushi, seafood, and beef and pork meat
The front view of this freezer box has a glass window (1'f) vertically inserted in contrast to the rear side as a peep window, and the rear side window is an opening / closing door. A cooling pipe (2f) is horizontally fitted and screwed in the center of the upper part of the freezing box. The surface of the pipe (2f) is covered with a paper tape (1'e) and a surfactant (1e). After coating and drying, a frost-preventing adhesive (2 L) was applied and wound on the back surface in the same manner as described above. Below the box of the cooling pipe (2f), fish meat (5f) or the like to be cooled is allowed to stand and the cooling pipe (2f)
Cooled in f). The cooling pipe (2f) is connected to the cooler (3f) by the side conduit (4f) to circulate the cooling, and when the inside of the cooling box (1f) is kept cool, the fiber paper tape (1'e). First absorbs water vapor carried by the invasion of air on the paper surface and contains water, but the surfactant (1e) disperses evenly in the fiber like water droplets without freezing and partly convection in the cooling box. The water returned from the water vapor is re-vaporized and absorbed, and is retained in a wet state and has no frosting property. Generally, this tape and paper not impregnated with a surfactant cause a frosting phenomenon. Without the tape, a frosting phenomenon occurs more quickly, but this method does not cause frosting even after cooling for 2 weeks. Since the activator has a strong bactericidal power, the bacterial bacteria present in the frost are sterilized, which makes it hygienic. The thickness of this fiber or paper is 0.01-0.
A one-ply one is used, and even a thin one does not reduce cooling efficiency. Also, when this fiber paper is switched to a plastic non-porous film, white frosting will occur over time, so a sensor will send a signal to the cooling surface of the freezer of a general electric manufacturer to detect frosting. The ice is heated automatically. However, since this equipment is not available in large-scale freezing factories, when fiber paper is attached to the cooling pipe as in this method, part of the liquid on the fiber paper evaporates at low temperature due to forced air blow, and the other part contains water. Although it remains in the state, the frosting property disappears on the surface containing a lot of water.

[Fig. 13] is a freezer for asui candy and frozen food (3
g), a transparent glass or plastics plate (2g) that can be inserted and inserted is fitted to the lower part of the upper lid (1g), and a hollow aluminum alloy cooling casing (7g) is attached to the inner wall of the freezer (3g). ) Is fitted, and liquid gas such as ammonia or freon gas is circulated. Then, the ice cream food (5g) to be cooled is inserted into the inside of the freezing case (7g) to keep it cool. In this general freezer (3g), the inside of the freezing case (3g) is cooled. (7g) Moisture in the air gathers inside the vessel by glass or plastics plate (2g) on the inner surface, white frost deposits thickly as cooling continues, and many bacteria are present in the frost layer with heat insulation properties. However, cooling efficiency is further reduced, and power loss of 8 to 10% is possible. For this reason, this method uses the cooling box (7) on the inner surface of the freezer (3 g).
The surface of g) is attached with a resin liquid coated with an antifreeze defrosting agent and a surface active agent, and a lattice base (8g) is attached to the bottom of the legs (9g).
(10g) and support it with the bottom of the cooling housing (7g),
A space is created and a separation space (11 g) is created between it and the storage of water. Next, a refrigerator (6g) containing a compressor / refrigerant tank is screwed to the side surface of the freezer (3g), and a refrigerant gas circulation pipe (12g) during cooling is connected to a space (13g) of a cooling casing (7g). ) It is joined to the bottom. The sensor connected to the power supply (4g) of this refrigerator (6g) and the time switch (15g) cut off the electricity in 24 hours to prevent frost formation. At this time, the one coated with the defrosting agent and the surfactant is It is extremely easy to peel off frost and frost, and is 1/10
The following is done quickly. Therefore, it is not necessary to constantly heat the heater as in a general freezer.

[Fig. 14] is a large rapid freezer (1h) in which cooling air is blown into each freezing chamber by a forced turbo fan, but a horizontal grid (2) is provided in front of the blower outlet (1'h) of the refrigerator (1h).
h) A large number of (2'h) are joined to each other with a fixed space between the frame (3h) and the rear box (4h), which is blown by the cooling fan (5h) to the grid (2h) ( 2 '
The air is blown through the space of h). (6h) in the figure shows the present cooling pipe. This horizontal grid (2h) (2'h) is constantly frozen and frosted, so operation is often stopped, but when applying a cloth or paper material impregnated with this anti-frost agent and surfactant. Does not need to be stopped because it prevents frost formation, but since it is continuously operated for one year, it is effective to easily remove frost formation by changing the temperature and using the time switch together in the rainy season. Also, when sticking paper quality to the surface of this many lattices, it takes time and effort, so dispersing pulp fibers and other fibers in the surfactant liquid solution and spraying with the bonding agent will produce the same effect, When the surface of the power transmission line is sprayed with a helicopter for surface treatment and oil-based defrosting agent is applied to enhance the snow protection effect, the insulation and water resistance can be increased.

FIG. 19 shows a side view of the transmission line, fiber paper (1′e)
A synthetic resin solution (1e) of cocoon waste alkaline earth water is applied and dried, and a frost-proof resin solution (2e) is applied to the back surface and automatically wound.
This core (5 L) was used as a wire rope copper wire, which was impregnated with castor oil with a fluororesin and a silicone resin oil. (3 L) is an oil-based defrosting agent that improves insulation and water resistance.

FIG. 20 is an enlarged vertical sectional view thereof.

FIG. 15 is a front elevational view of a snow remover (D) fixed to the roof of a house. This snow remover consists of a support frame (3i) made of aluminum alloy and a small conveyor (1j) (1j).
a) (1jb) and (1jc) are attached by rolls, and rolls (4ja) and (4j) that move up and down by rotation are attached to the rolls.
b) While (4jc) is attached and the snow cover (2i) is vibrated up and down, the snow cover descends from a high place to a low place of the roof (D) and falls from the end, so that the snow cover ( Make 7j).

FIG. 16 shows this snow removal conveyor, (1j)
A plurality of (2j), (3j), and (4j) are inclined and fixed from the top of the roof (D). A window (6j) is attached to the house (D ') and a space (8j) between the house (D') and the roof (D)
Is made and a plastic film (9j) is stretched,
It was created to protect the passage of snow. This action climate is such that when the accumulated snow (2j) is piled up on the conveyor, the conveyor roll is rotated to move to the lower part and dropped to remove the snow, which is a mechanized work done every year. For the conveyor, a laminated film of polyester, polyaramid, polycarbonate, polyacrylic resin or polyurethane resin is used for the fiber cloth to reduce the weight. Rubber and thin objects are also used.
Synthetic fiber mat (R) is bonded to the surface of the conveyor, and an alkaline earth resin solution of cocoon waste is applied as a frost preventive agent to the surface of the conveyor. An oil-based defrosting agent is applied to the surface to improve slippage and facilitate peeling, thus preventing peeling difficulty due to freezing.

FIG. 21 is an oblique side view of a container for frozen ice cream food. The ice cream and the food (3m) are put inside the Parapin paper box (1m) and the upper lid (2m) is fitted.

FIG. 13: When the product is pushed into the freezer (7g) shown in FIG. 13 and cooled, the printing surface (4m) of the upper lid (2m) is erased by frosting, so the printing advertisement value and production date are unknown. Therefore, frosting does not occur when the surface of the printed surface on which the present surfactant has been applied is previously applied to the upper lid of this paper. As described above, the moisture is adjusted by breathing with paper or fibrous material, and the surfactant impregnated in the paper material diffuses quickly to prevent freezing and enhances the aeration, so frost by the heater is used. It does not need to be untwisted and can be peeled off with a simple wipe even when it is frosted.

FIG. 22 shows an oblique front view of a cold-insulating cardboard box (1 m) in a freezing room, in which the paper quality (2 m) of this cardboard box is impregnated with this surfactant, and the surface of which is provided with parapin fluororesin and silicone resin. It is applied and waterproofed. (3 m) is a corrugated honeycomb made of paper, and the adhesive of the corrugated honeycomb is cured at 180 ° C. by using a cold-resistant and hygroscopic bonding agent in which urea formalin resin and cocoon waste alkaline earth liquid are mixed. At the very least, food and medical products are placed in a cardboard box (1 m), and this cardboard box is made by a conventional method.

FIG. 23 is an oblique side view of the felt boots (1d), in which the surface of the felt is coated with water-resistant castor oil, a fluororesin, and a silicone resin (1′d) to be waterproofed, and the inner surface thereof. Is impregnated with the present surfactant (2d), and the castor oil, the fluororesin, and the silicone resin liquid (2'd) that are waterproof are applied. (3Q) is Kagato.

[Fig. 24] is an aluminum alloy plate (1Q) that also serves as a deicing plate and a far infrared ray, and contains copper beryllium, zirconium, hafnium,
Monazite oxide is mixed. This surface is coated with scrap cocoon alkaline earth liquor, and the surface is Kikano Foods (3Q)
When put on, the ice is thawed in 1 / 10th compared to the thawing time in general air, and when a defrosting agent is applied, it is further accelerated to 12 to 15th. This thaw plate (Q) has a notch on the surface (4Q)
Insert the electric wire (5Q) (5'Q) at both ends and open and close with the switch (6'Q) (6Q), connect to the power supply (7Q), and connect this defroster (1Q) to 80 ° C. Heat as a heating element. In addition, this thaw plate (1Q) is a metal stand (8Q)
And load it on the gas burner (9Q). When it is used as a grilled plate (1a) for grilled meat, the grilled meat can be processed with almost no charring. this

FIG. 24 shows.

FIG. 17 is a side view of a high-pressure tank (1K) containing a defrosting agent and a surfactant. A pipe (3k) protruding in the center of the upper part of the tank (1k) is molded, a push plate (4k) for operating a push valve is fitted in the center of the protruding pipe (3k), and a nozzle pipe (5k) is joined and pushed. Defrosting agent, surfactant (6k) fibers are introduced from the nozzle by pushing the board (4k),
Injected with gas pressure (7k)

FIG. 16: On the roof of or on the roof (D) conveyor (1
j) (2j) (3j) (4j) (5j). The following is an example of blending the anti-frosting agent and the surfactant.

[Example 1] Surfactant P Nitrophenol sodium 10 g 5-Nitroguaiacol sodium 10 g Water or alcohol water 100 g

[Example 2] Surfactant P Sodium nitrophenol 10 g Sodium dodecyl benzyl sulfonate or dodecyl benzyl nitro soda 10 g Water or alcohol water 100 g Synthetic resin 1 g

[Example 3] Defrosting agent Cocoon waste 5% Calcium chloride 50% Water 35% Ammonium nitrate 0-10% Synthetic resin 0-1%

[Example 4] Oil-based defrosting agent Castor oil Silicon oil 10 parts Fluorine resin 30 parts Alcohol 100 parts Synthetic resin 10 parts Glycol alkylbenzene sodium sulfonate 0-10 parts

[Example 5] Numatec type liquid crystal liquid Cocoon 5 g Calcium chloride 800 g Water 800 g

[Example 6] Defrosting agent Silicone resin 10 parts Fluorocarbon resin 50 parts Alcohol 100 parts Reinforcing agent 0.1 part Glycol 5-nitroguaiacol sodium 3 parts

[Example 1] ~

In Example 6, a frost-preventing agent that is placed in a stainless steel tank and mixed well with a stirrer is applied to fibers and dried or semi-dried before use.

[Example 5]

FIG. 25: Apply to the groove (2R) of the liquid crystal plate (1R) of
A cover glass or a plastic plate (3R) is overlapped and bonded, and electrode films (4R) (4'R) are coated on both ends in advance, and conductors (5R) (5'R) are bonded to the electric wire (6
When it is connected to R), the cocoon fluorescent molecules are arranged in a certain direction to form a fluorescent surface, and therefore, a loading voltage of 5 v to 0.08 amperes, which is substituted for cholesterol as a liquid crystal. In this way, the alkaline earth mixed liquor of cocoon waste exerts its denitrification effect when treating exhaust gas from diesel engines and gasoline engines. It has the function of absorbing water in the combustion gas by itself because it is deliquescent that does not dry, and it has the property of easily adsorbing the sulfurous acid and nitrite gas associated with it.
Since the original paper quality is dry, the denitration sulfuric acid effect passes the pollution gas through the nitrogen, so it is difficult to perform denitration sulfurization sufficiently. Especially, since the exhaust gas flow velocity is 20M or more, discharge adsorption is necessary. If so, the active adsorptivity is further enhanced. In addition, when the concentration of cocoon waste in alkaline earth in cocoon waste weakens, dissolve the cocoon waste in monochloroacetic acid or add 25% hydrochloric acid.
% Neutralized by dissolving it in a solution with a concentration of more than 100%, and then electrolytically dialysis the resulting neutralized salt to desalinize it, and add it to alkaline earth to increase the cocoon concentration and use it to prevent bed slip of oscillating paper cloth It can be used in combination with alginic acid or chitosan solution for stable attachment. Further, as an anti-frosting agent, the effect can be enhanced by adding ammonia nitrate, glass nitrate, etc. to the alkaline earth liquor of cocoon dust, but cocoon dust is effective as a stabilizer for retaining water in alkaline earth, and, Ceramic calcined products using calcium silicate carbonate as a treatment for calcium carbonate and limestone mine waste, and those adsorbed on this cocoon alkaline earth are also useful for denitrification of engine combustion exhaust gas and save expensive platinum catalysts. It has an effect. In addition, a resin solution of cocoon alkaline earth used for snow removal on the roof and a surface active agent such as nitroguaiacol soda applied to the fiber and piled up are used for the transmission line by the combined use with an oil-based defrosting agent. It is effective for snow protection, and when applied to the roof or the conveyor surface of the snow remover, it has the effect of improving slippage and preventing freezing. When used as a defroster for a freezer, it saves an average of 5-8% in electric power costs and has the effect of preventing the preservation of bacteria.
Especially when used in combination with fiber cloth, mint mineral fiber, pulp paper,
It is extremely useful for large freezers, popsicles, and for defrosting frozen foods. Therefore, a thin Japanese paper, carbon paper, or fiber paper coated with the anti-frost solution or the surfactant solution in advance and dried can be sold as a paper product or a fiber product alone, which is practical. In particular, it is useful for defrosting ice cream and other printed labels in cold regions, and when used as a defrosting agent for plants, it has an effect of suppressing frost damage and cold damage. In particular, the range of application is expanded as an effective use of cocoon waste, the dry cracking of water-soluble resin, especially urea resin is prevented by this addition, and the use of the molded product in the dry area is effective use of cocoon waste. As described above, the one obtained by neutralizing and purifying the liquid obtained by decomposition of alkaline earth, monochloroacetic acid, or sulfuric acid and dissolving it in alkaline earth contributes greatly to new uses. Therefore, this invention is an industrially useful invention.

FIG. 1 is a vertical sectional view of a paper bag adsorbent.

FIG. 2 is a side view of an exhaust gas adsorbent.

FIG. 3

FIG. 4

FIG. 5 is a vertical sectional view of an exhaust gas adsorbent honeycomb structure.

FIG. 6 is a side view of the exhaust gas adsorber device.

FIG. 7: Side view of car

[Fig. 8] Characteristics of exhaust gas purification

FIG. 9: Side view of tape with frost inhibitor, surfactant and oiliness agent impregnated

FIG. 10

FIG. 11 is an enlarged side view of the tape paper cloth.

[Figure 12] Front view of the sushi freezer

FIG. 13: Side view of ice cream, frozen food, freezer

FIG. 14 is an oblique front view of the quick freezer.

FIG. 15: Front view of the snow removal conveyor on the roof

[Fig. 16] Front view of the house

FIG. 17 is a side view of the defrosting agent injector.

FIG. 18: Side view of transmission line tower

FIG. 19 is an enlarged side view of the power transmission line.

FIG. 20 is a vertical sectional view thereof.

FIG. 21 is an oblique side view of the ice cream container

FIG. 22 is an oblique front view of a cardboard packaging box.

FIG. 23: Side view of the felt cold-resistant duck

FIG. 24 is an oblique front view of a household appliance with a thawing plate and a far infrared heating plate.

FIG. 25 is a front view of a liquid crystal plate.

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[Procedure amendment]

[Submission date] October 3, 1996

[Procedure 3]

[Document name to be amended] Statement

[Correction target item name] Detailed description of the invention

[Correction method] Change

[Correction contents]

DETAILED DESCRIPTION OF THE INVENTION As a part of the effective use of cocoon waste, the present invention provides an aqueous solution of cocoon waste heated and dissolved in an alkaline earth water solution, or cocoon protein in this aqueous solution to monochloroacetic acid, sulfuric acid or hydrochloric acid. Concentrated cocoon waste alkaline solution containing chitin chitosan or calcium carbonate dispersed alkaline liquor in which concentrated cocoon waste has been added to the solution to neutralize the dissolved solution with an alkaline solution. It is adsorbed on fibers and ceramics as an agent and used for purification of pollutant gases. Also, a synthetic resin such as urea resin is mixed with this liquid to improve the cold resistance adsorbent and hygroscopicity, and to use it for fiber or plastics. For the film that is coated and impregnated,
A fiber impregnated with a surfactant is combined with an oil-based cold-resistant resin, and a frost-proof and anti-icing fiber-processed fiber processed product is used as a snow and anti-icing agent for power lines and towers. It is processed on the surface and also suppresses the frosting property of the freezer and the packaging of frozen foods and frozen medical products to give peeling property and prevents snow, frost and frost on the roof, toyo, wooden house and frozen food defroster. Effective utilization of cold frost resistance, adsorption, deicing, and deicing peelability by the combined use of alkaline earth of cocoon, oily resin, surfactant and fiber paper cloth characterized by imparting ice peeling property Is.
Generally, the cocoon waste has been reduced to the soil, but about 30 to 40% of the cocoon thread is produced as the cocoon waste, so that its effective use has been desired. Therefore, as a part of it, from the use of ceracin protein, it is dissolved in acid and then neutralized with alkali, the resulting salt is purified and removed, and the purified ceracin protein and the already decomposed liponucleic acid are recovered, tofu or confectionery, The time has come for the foods added to foods to be put into practical use, but if the addition amount is large, the flavor becomes worse than that of the conventional products, so the addition amount was limited. For this reason, it was necessary to develop new cocoon waste as an industrial raw material used in large quantities. Therefore, as a recycle of this cocoon waste, cocoon waste dissolved in hydrochloric acid, monochloroacetic acid, alcohol acetic acid, etc. together with chitosan and chitin is used as a continuous crop damage inhibitor for vegetables, lawns and other plants, and necessary soil microorganisms are used. As an innkeeper, the antibacterial property due to the enveloping of harmful gold was used to bring about the effect. In addition, for the purification of water, a hydrochloric acid solution of cocoon waste and an alkaline cocoon waste alkaline earth liquid were used as a condensing agent. D. O. We have also continued research on methods to reduce the P value, but in order to meet more practical demand, when mixing the cocoon waste alkaline earth water solution with urea formal resin, a certain amount of urea resin must be added in the resulting urea resin. A synthetic resin that retains water is formed and becomes thermoplastic, but when the addition amount is small, it becomes thermosetting. This thermosetting resin does not crack in the dry areas of deserts such as the United States, the Middle East and Egypt. Of course, the properties of melamine resin and huminol resin are also improved, which promotes the reaction and pulverization at the initial stage of the resin, such as laminating heat of the pulverized resin and the fiber paper or fiber cloth. Processing operation is simplified, and-
It is used for processing synthetic resin moldings that can withstand 20 ° C. However, the use of the alkaline earth liquor of this coconut waste is to recycle sludge mixed with clay limestone in the limestone mining, which is consistent with the industrial waste, and it is possible to use maltite, pumice, zeolite, and bentonite. When mixed and fired, the calcium carbonate in the limestone is pyrolyzed by firing and C
aCo3 → Cao + Co2 ↑ and Ca2 diverges in the form of gas, but at that time, 0.025 micron pores are made in the fired product of the ceramic, so the one impregnated with the cocoon waste alkaline earth liquid is the ceramic fired. The material has a honeycomb structure, and it has already been delivered as an adsorbent. or,
When waste pulp sludge is mixed with sodium alginate water and alkaline earth cocoon waste and molded with an extruder, not only can sludge be effectively used as recycled paper, but also molded honeycomb coils can be obtained by extrusion. It is fortified with the addition of chitosan. Also, when processing waste paper such as newspaper and waste paper into recycled paper, it becomes deliquescent paper when impregnated with cocoon waste alkaline earth, so that this fiber cloth does not become fragile and aged during thermal processing. . Particularly, in pulp, it is a great advantage that destruction of oxygen bridges of the glucose group in the molecular structure is reduced. In this case, the cocoon waste alkaline earth acts as a hardening accelerator, but it goes without saying that hardening increases as the added amount increases, so it is necessary to appropriately determine the added amount. In the reaction of phenol and formalin, a resin which can increase the added amount of formalin can be obtained. Also, in the reaction of formalin, ultrapin, and balaraldehyde in a solution of polyamide, polyethylene terephthalic acid resin, or polypropylene terephthalic resin using phenol as a solvent, the addition of cocoon waste alkaline earth must be done after the addition of alcohol. It can also be used as a unique mixed thermoplastic phenolic resin by heat. Further, when mixed with concrete cement, strength cold resistance is improved by 20% even at -10 ° C. It can also be used as an exhaust gas adsorbent, and this cocoon waste alkaline earth mixed with industrial waste limestone and sludge is applied to pulp paper, ceramics porous, and fiber cloth for denitrification. It has a long-lasting effect and reacts well with the desulfurization of sulfur dioxide in factories and coal collection chambers. That is, H
2o + So2 + CaCo3 → CaSo3 + Co2 ↑ + H
2o H2o + CacL2 + So2 + CaCo3 → CaSo3
+ H2cL2 → CaSo3 + CacL2 + Co2 In the case of denitration, H2o + CacL2 + No2 + CaCo3 → CaN3 +
It becomes CaCL2 + Co2 ↑ and absorbs the cocoon protein and the generated HCL to prevent secondary pollution of exhaust gas. At the exhaust gas outlet of the automobile, a ceramics sintered honeycomb or pulp honeycomb impregnated with cocoon waste alkaline earth calcium carbonate liquid is attached, and automobile combustion exhaust gas is introduced into the porous body of ceramics or fiber paper. When ventilated, the free carbon block generated by the Diesel engine is slightly larger than the pores of the porous material and cannot be filtered, so it is filtered and remains in the porous material and is adhered by the impregnated alkaline alkaline earth clay solution. Separated and purified, nitrogen oxide, sulfurous acid, and sulfuric anhydride gas are adsorbed and neutralized by reaction, and the gas exhausted from the exhaust port is exhausted as exhaust gas with almost no pollution. Deliquescent hygroscopic cocoon scraps An appropriate amount of water is absorbed by an alkaline-alkaline-earth water solution to keep it moist at all times. Debris, calcium carbonate, to replenish the water in the water-containing porous alkaline earth solution. Further, since the porous material such as slag is regenerated and separated into an adsorbate when washed with an alkaline earth liquid, it is used for purification of regenerated exhaust gas. In the case of paper quality, the structure of the exhaust stack bag is used as exhaust gas ventilation holes through the pores of the corrugated partition structure of the honeycomb structure or the corrugated board structure. In the case of plastics, a heat resistant resin is used to withstand the heating temperature of the exhaust gas. As for the diameter of this exhaust gas vent hole, the finer the hole, the stronger the adhesion with the exhaust gas,
Since such a honeycomb structure increases the production cost, a press compression plate or a sintered plate of glass fiber, mineral fiber, metal fiber, cutting metal waste, or a ceramic porous body is also used. Further, in the case of a mineral substance such as glass fiber, if the exhaust gas pressure is strong, the fibers are scattered in the exhaust gas to cause secondary pollution. Therefore, it is also necessary to prevent the scattering by coating with a resin in advance. In this adsorption of exhaust gas, the wind velocity of exhaust gas is generally 20 US or more. Therefore, when adsorption is not sufficiently performed on a part, denitration is performed by electrostatic adsorption or discharge adsorption on this porous material. Since it is more important to enhance the desulfurization effect, it is necessary to sufficiently insulate the conductivity of the porous tubular bag by using an insulator. Also, as a simple one, the inside of a bag is made by roughly filling Japanese paper or fiber paper with paper waste by the disposal method and impregnating this with a liquid in which alkaline earth liquid and alkaline liquid, calcium carbonate or calcium hydroxide liquid are mixed. A method of introducing exhaust gas into a filter to decarbonize it for denitrification of sulfur is also used. If it is discarded every day, replace it every day, screw it to the outlet of the exhaust pipe with a fixed ring and fix it, and replace it when it loses its usefulness. Coarse, chip coarse, and ground pulp fibers are used.As a known purification method for this kind of exhaust gas, a platinum catalyst, nickel, cobalt, manganese catalyst, titanium or vanadium is impregnated with a catalyst in a muffler of an exhaust stack. Although it is used as a molded porous material, it loses its vitality due to the generation of free carbon and also has a denitrifying and desulfurizing action of 20%.
However, the number of automobiles literally increases every month, and the amount of harmful gas exhausted automatically increases, and the total amount must be regulated. Therefore, an electric vehicle that does not emit exhaust gas has been developed. However, the cost is three times as high as that of a practical vehicle, and the cost of a solar cell vehicle that uses a solar cell as a power source is higher. there were. For this reason, an exhaust gas cylinder bag made of extremely cheap and lightweight paper or papermaking is made by an automatic machine, and when using the same solution containing alkaline alkaline earth liquid containing cocoon waste or synthetic resin, Cocoon Alkaline alkaline earth liquid is always deliquescent and absorbs moisture in automobile combustion gas well to maintain its activity. Therefore, it also absorbs nitrogen oxide, sulfurous acid gas and some carbon dioxide gas, and also absorbs ammonia gas. At the same time, the free carbon is wet attached by the deliquescent surface to clean the black smoke, so the manufacturing cost is not only cheaper than using the catalyst ceramic molded body even if it is discarded at about 100 yen, The denitration rate is 80% or more, and the desulfurization rate is 8
5% or more is recorded, and when the exhaust pipe of the car is installed so as to perform in the traveling direction to promote the entry of secondary air into the exhaust pipe, the pollution of exhaust gas will be further reduced, which is extremely It is a useful invention and its reactivity is sustained in a paper exhaust stack bag mixed with zeolite or calcium salt in order to increase its denitrification rate, and the glass fiber, mineral fiber, or carbon fiber mixed paper is an absolute temperature. Since the number of mats is twice that of ordinary pulp paper, there is less stretching and shrinkage due to vertical and horizontal humidity, so standardized moldings are obtained, and the filter effect is high and air resistance is also low. When a generator with a high static voltage of 1 to 50,000 V is installed on this and both screen electrodes are fixed in series at regular intervals, the exhaust gas passing through these electrodes is forcibly electrodeposited by the discharge charge, especially free carbon. Since more than 80% of it is separated, air pollution is smaller and the denitrification rate reaches 96%. Therefore, static electricity can be obtained by the multiplication method using a rotary disk type triboelectric generator or an induction coil, and the piezoelectric element It can also be obtained by pressurizing, and in order to increase its strength and durability as an exhaust stack, use a corrugated corrugated structure of corrugated cardboard or a structure of minute fine holes with honeycomb coils, or use ceramic porous molding holes. When impregnated with the alkaline alkaline earth liquid containing the cocoon dust, it exhibits the same denitrification effect as that of paper fiber. Alkaline earth solution water retention and the temperature is increased in comparison with the alkaline alkaline earth Mayukuzu. Further, when the cocoon concentration is increased with respect to the alkaline alkaline earth containing the cocoon and it is dissolved under pressure in a high-pressure gas can, a nematic liquid crystal is obtained, and when the cocoon concentration exceeds 3%, The liquid crystal effect gradually increases, and it has the same effect as cholesterol, but its production cost is not only lower than that of cholesterol, but it is also resource-friendly. In addition, P nitrophenol, sodium, No2C6 in alkaline earth liquid
Apply a mixture of surfactants such as H4DNA-2H2o, guaiacol, dodecyl, and sodium benzyl sulfonate to plastics paper, cellophane paper, and paper,
Alternatively, when a film coated with polyurethane or porous synthetic resin is attached to the cooling surface or heat exchanger surface of a refrigerator, the anti-frost and snow-proof effects are greatly improved, and those containing more P-nitrophenol sodium are prevented. It is characterized by less frostiness. Therefore, the cracks are also used for snow protection of roofs, tocoles, door handles, doorways, and road surfaces.
Also, a high-pressure molded body obtained by mixing and sintering zirconium oxide, hafnium oxide, monaz sand, etc. in an alloy containing beryllium copper in aluminum is useful as a thaw plate, but this thaw plate also works when the temperature falls below freezing. Although the ice-melting plate gradually decreases as the temperature decreases, the use of anti-frost and snow-proofing agents for the ice-breaking of frozen foods promotes the ice-melting effect at room temperature. In addition, anti-frost agents such as syrup are also used as antifreeze for cold-proofing plants, and have the action of preventing the formation of rime on trees such as tea. Especially,
Straw muscillo or rope impregnated has the property that it is difficult to form rime.

[Procedure amendment 4]

[Document name to be amended] Statement

[Correction target item name] Brief description of drawings

[Correction method] Change

[Correction contents]

[Brief description of the drawings]

FIG. 1 is a vertical sectional view of a paper adsorbent.

FIG. 2 Side view of exhaust gas adsorber

FIG. 3 is a vertical sectional view of an exhaust gas adsorbent honeycomb structure.

FIG. 4 is a vertical sectional view of an exhaust gas adsorbent honeycomb structure.

FIG. 5 is a vertical cross-sectional view of an exhaust gas adsorbent high cam structure.

FIG. 6 is a side view of the exhaust gas adsorber device.

[Figure 7] Side view of a car

[Fig. 8] Characteristics of exhaust gas purification

FIG. 9: Side view of tape for impregnation with anti-frost agent, surfactant and oiliness agent

FIG. 10 is an enlarged side view of the tape paper cloth.

FIG. 11 is an enlarged side view of the tape paper cloth.

FIG. 12: Front view of the sushi freezer

FIG. 13: Side view of ice cream, frozen food, freezer

FIG. 14 is an oblique front view of the quick freezer.

FIG. 15: Front view of the snow removal conveyor on the roof

[Fig. 16] Front view of a house

FIG. 17 is a side view of the defrosting agent injector.

FIG. 18: Side view of transmission line tower

FIG. 19 is an enlarged side view of the power transmission line.

FIG. 20 is a vertical sectional view thereof.

FIG. 21 is an oblique side view of the ice cream container

FIG. 22: Side view of corrugated cardboard box

[Fig. 23] Side view of the felt cold weather resistant slant

FIG. 24 is an oblique front view of a household appliance for a thawing plate and a far infrared heating plate.

FIG. 25 is a front view of a liquid crystal plate.

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁶ Identification code Internal reference number FI Technical display location B65D 25/34 B65D 25/34 B C09K 3/18 101 C09K 3/18 101

Claims (1)

[Claims] As described later, cocoon debris dissolved in alkaline earth water is mixed with calcium carbonate and dispersed, and monochloroacetic acid or hydrochloric acid dissolved cocoon debris is neutralized and purified with an alkaline liquid. Exhaust gas pollution gas by adsorbing nucleic acid added to an alkaline earth liquid containing cocoon waste to increase the cocoon concentration to fiber cloth, fiber paper, plastics film, carbon paper and porous ceramic honeycomb fired material It is used as a defrosting agent for defrosters and toyu etc. by applying it to thin fiber paper and then applying a surfactant or oily resin. Used in combination with a snow protector, used as a defrosting remover for packaging of frozen foods and medical products, and also used as a defrosting accelerator for deicing plates and as a remover to add plasticity to plastic As an antifreeze to prevent vulnerabilities Calcium carbonate, surfactant, oily cold-resistant resin is added to alkaline earth liquid of cocoon waste, which is characterized by removing anti-fogging property of boots, eyeglass glass, automobile window glass, etc. Effective use of alkaline earth liquid of added cocoon waste.