JPH08509508A - ヒドロキシル機能性ブロックコポリマーポリエステルの被覆組成物 - Google Patents
ヒドロキシル機能性ブロックコポリマーポリエステルの被覆組成物Info
- Publication number
- JPH08509508A JPH08509508A JP6517326A JP51732694A JPH08509508A JP H08509508 A JPH08509508 A JP H08509508A JP 6517326 A JP6517326 A JP 6517326A JP 51732694 A JP51732694 A JP 51732694A JP H08509508 A JPH08509508 A JP H08509508A
- Authority
- JP
- Japan
- Prior art keywords
- hydroxyl
- block copolymer
- coating composition
- coating
- polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31529—Next to metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31681—Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31794—Of cross-linked polyester
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.圧伸(drawing)抵抗性塗膜を持つ金属基板を製造する方法であって、そ の製法は硬化性液状被覆組成物を基板に塗布しそして塗膜を予定の時間にわたり 予定の温度に処することにより上記塗膜を硬化することからなり; 上記液状被覆組成物は、エポキシ樹脂とカルボキシル機能性ポリエステルとの 反応生成物であるヒドロキシル機能性ブロックコポリマーポリエステル、及び上 記予定の温度と時間で硬化した時、室温で10日にわたり又は同等の老化条件で 老化した時、圧伸の際の塗膜のひび割れ抵抗性が20%より多く減少しないよう に十分に高い架橋密度を提供するヒドロキシル反応性架橋剤からなる方法。 2.上記ブロックコポリマーポリエステル樹脂中の反応性ヒドロキシル基に対 する架橋剤中の官能基のモル比が少なくとも2.0である請求項1記載の方法。 3.被覆組成物が顔料を含有しない請求項1記載の方法。 4.上記エポキシ樹脂が室温で液状でありそして5.5ないし3のエポキシ価 を持つ請求項1記載の方法。 5.上記ひび割れ抵抗性を裏面衝撃試験法により測定する段階を包含する請求 項1記載の方法。 6.缶又は他種の容器を被覆するための液状被覆組成物であって、1,2−エ ポキシ樹脂とカルボキシル機能性ポリエステル樹脂との反応生成物である硬化性 ヒドロキシル機能性ブロックコポリマーポリエステル、及び上記ブロッ クコポリマーのヒドロキシル当量当たり少なくとも2当量のヒドロキシル反応性 官能基を提供するのに十分な量のヒドロキシル反応性架橋剤からなる組成物。 7.架橋剤が、架橋剤とポリエステル樹脂の組み合わせ重量に基づいて40% より多くない濃度で存在する請求項6記載の被覆組成物。 8.ブロックコポリマーのヒドロキシル当量当たりのヒドロキシル反応性官能 基の当量比が2.5ないし10の範囲内にある請求項6記載の被覆組成物。 9.ブロックコポリマーが60℃より大きくないTgを持ちそして数平均分子 量が7,000ない60,000の範囲内にある請求項6記載の方法。 10.上記硬化性ヒドロキシル機能性ブロックコポリマーポリエステルが、7 ,000ないし30,000の範囲にある数平均分子量を持つコポリマーを提供 するために、1ないし5.5エポキシド・ミリ当量/gmを持つ1,2−エポキ シ樹脂と20−100の範囲内の酸価を持つカルボキシル機能性ポリエステル樹 脂との十分な相対量の反応生成物である請求項6記載の被覆組成物。 11. a.1,2−エポキシ樹脂とカルボキシル機能性ポリエステル樹脂と の反応生成物である硬化性ヒドロキシル機能性ブロックコポリマーポリエステル を、そのブロックコポリマーのヒドロキシル官能価と反応できる架橋剤のいろい ろの量と混合した液を提供し; b.そのような液の金属上の硬化塗膜を、室温における 少なくとも10日の老化期間又は同等の老化期間にわたり、ひび割れ抵抗性を周 期的に試験して、上記期間にわたるひび割れ抵抗性の喪失を測定し;次いで c.上記期間にわたるひび割れ抵抗性の喪失が20%より多くない液に相当す る上記架橋剤の量を被覆組成物のために選択する ことからなるひび割れ抵抗性被覆を製造するための被覆組成物を製剤する方法 。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US1136293A | 1993-01-29 | 1993-01-29 | |
US08/011,362 | 1993-01-29 | ||
PCT/US1994/000983 WO1994017111A1 (en) | 1993-01-29 | 1994-01-26 | Coating composition of a hydroxyl-functional block copolymer polyester |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH08509508A true JPH08509508A (ja) | 1996-10-08 |
Family
ID=21750062
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6517326A Ceased JPH08509508A (ja) | 1993-01-29 | 1994-01-26 | ヒドロキシル機能性ブロックコポリマーポリエステルの被覆組成物 |
Country Status (8)
Country | Link |
---|---|
US (1) | US5567781A (ja) |
EP (1) | EP0681591B1 (ja) |
JP (1) | JPH08509508A (ja) |
AU (1) | AU691171B2 (ja) |
DE (1) | DE69418308T2 (ja) |
DK (1) | DK0681591T3 (ja) |
HK (1) | HK1003714A1 (ja) |
WO (1) | WO1994017111A1 (ja) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998022546A1 (fr) * | 1995-05-19 | 1998-05-28 | Daicel Chemical Industries, Ltd. | Compositions de resine de revetement |
WO1999010405A1 (en) * | 1997-08-26 | 1999-03-04 | Ranbar Electrical Materials, Inc. | Varnished compositions, methods of making and components made therefrom |
US6136927A (en) * | 1997-09-24 | 2000-10-24 | Ppg Industries Ohio, Inc. | Phosphatized amine chain-extended epoxy polymeric compounds |
GB9814437D0 (en) * | 1998-07-03 | 1998-09-02 | Ici Plc | Coating composition |
US6359062B1 (en) | 1999-03-02 | 2002-03-19 | The Valspar Corporation | Coating compositions |
US6787188B1 (en) | 2000-10-02 | 2004-09-07 | Imperial Chemical Industries Plc | Coating composition |
CA2472128A1 (en) * | 2002-03-08 | 2003-09-18 | Valspar Sourcing, Inc. | Coatings having low volatile organic compound content |
EP1485437B1 (en) * | 2002-03-08 | 2006-05-31 | Valspar Sourcing, Inc. | Polymerization of a reactive diluent in the presence of an epoxy-amine material, and coating compositions prepared thereby |
US7341762B2 (en) * | 2003-01-08 | 2008-03-11 | The Glidden Company | Coating composition having improved release properties and the process for making the same |
CN102858893B (zh) | 2010-04-16 | 2016-08-03 | 威士伯采购公司 | 用于包装制品的涂料组合物以及涂布方法 |
KR20140048854A (ko) | 2011-02-07 | 2014-04-24 | 발스파 소싱 인코포레이티드 | 용기 및 기타 물품을 위한 코팅 조성물 및 코팅 방법 |
EP2882658B1 (en) | 2012-08-09 | 2021-09-08 | Swimc Llc | Container coating system |
JP2015527455A (ja) | 2012-08-09 | 2015-09-17 | ヴァルスパー・ソーシング・インコーポレーテッド | 容器及び他の物品のための組成物並びにその使用方法 |
US20140303283A1 (en) * | 2013-03-15 | 2014-10-09 | The Sherwin-Williams Company | Curable compositions |
CN110790914A (zh) | 2014-04-14 | 2020-02-14 | 宣伟投资管理有限公司 | 制备用于容器和其它制品的组合物的方法以及使用所述组合物的方法 |
TWI614275B (zh) | 2015-11-03 | 2018-02-11 | Valspar Sourcing Inc | 用於製備聚合物的液體環氧樹脂組合物 |
MX2020002960A (es) * | 2017-09-19 | 2020-07-22 | Swimc Llc | Composiciones de revestimiento que incluyen un poliester que contiene furano, articulos y metodos de revestimiento. |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL133343C (ja) * | 1962-12-21 | |||
GB1271406A (en) * | 1968-04-24 | 1972-04-19 | Ashland Oil Inc | Polyester-epoxy coating composition of increased pot life |
US3650997A (en) * | 1970-08-13 | 1972-03-21 | Immont Corp | Coating compositions containing epoxy resins and carboxyl terminated polyesters |
US3939051A (en) * | 1971-08-02 | 1976-02-17 | Ppg Industries, Inc. | Process for electrodeposition of cationic thermosetting compositions |
US4247439A (en) * | 1973-11-06 | 1981-01-27 | E. I. Du Pont De Nemours And Company | Water-borne coating composition made from epoxy resin, polymeric acid and tertiary amine |
US4064026A (en) * | 1976-04-12 | 1977-12-20 | Mobil Oil Corporation | Polyepoxide ether polyacrylate mixtures |
US4164487A (en) * | 1976-12-23 | 1979-08-14 | The Dow Chemical Company | Water-thinnable mixtures of base-neutralized products of reaction of H3 PO4 with polyether epoxides and with other type epoxides |
US4442246A (en) * | 1978-06-12 | 1984-04-10 | Scm Corporation | Aqueous coating composition comprising self-emulsifiable ester of epoxy and acid containing addition polymer |
US4308121A (en) * | 1979-12-21 | 1981-12-29 | E. I. Du Pont De Nemours And Company | Electrocoating process using polyhydroxyamine and second polymers |
DE3038243A1 (de) * | 1980-10-10 | 1982-05-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung waermehaertender, mit wasser verduennbarer lacke und deren verwendung fuer beschichtungen |
US4480058A (en) * | 1980-12-04 | 1984-10-30 | Scm Corporation | Aqueous epoxy ester emulsions |
US4397970A (en) * | 1981-06-24 | 1983-08-09 | The Dow Chemical Company | Process for epoxy phosphate coating resins |
JPS58206662A (ja) * | 1982-05-26 | 1983-12-01 | Toyobo Co Ltd | ポリエステルブロツク共重合体組成物 |
DE3369689D1 (en) * | 1982-12-23 | 1987-03-12 | Akzo Nv | Pigment-containing liquid coating composition |
US4476262A (en) * | 1982-12-30 | 1984-10-09 | Mobil Oil Corporation | Aqueous coatings comprising ionic polymer ester and diluent polymer with reduced monomer residue and method of preparation |
US4446258A (en) * | 1982-12-30 | 1984-05-01 | Mobil Oil Corporation | Aqueous coating comprising dispersible epoxy resin-acid polymer ester and diluent polymer, and method of preparation |
DE3301729A1 (de) * | 1983-01-20 | 1984-07-26 | Hoechst Ag, 6230 Frankfurt | Bindemittelmischung und deren verwendung zur herstellung von einer zweischichten-metallic-lackierung |
US4767829A (en) * | 1985-11-14 | 1988-08-30 | E. I. Du Pont De Nemours And Company | Thermosetting coating composition comprising a hydroxy-functional epoxy-polyester graft copolymer |
US4816528A (en) * | 1986-06-23 | 1989-03-28 | E. I. Dupont De Nemours And Company | Chip resistant coating compositions containing epoxy-polyester graft copolymers |
DE3635296C2 (de) * | 1986-10-16 | 1995-12-21 | Nitrochemie Gmbh | Verfahren zum Herstellen von Treibladungspulver |
JPS63125528A (ja) * | 1986-11-17 | 1988-05-28 | Polyplastics Co | ケイ素含有コポリエステル及びその製造法 |
JP2623316B2 (ja) * | 1987-10-20 | 1997-06-25 | 東洋紡績株式会社 | 複合型制振材料及び制振材料用粘弾性樹脂組成物 |
US4981905A (en) * | 1989-02-21 | 1991-01-01 | Morton International, Inc. | Water reducible polyester resin composition and method for preparing same |
US4933429A (en) * | 1989-03-13 | 1990-06-12 | General Electric Company | Method for preparing polyester-polyepoxide compositions of high melt viscosity |
EP0399108A1 (en) * | 1989-05-26 | 1990-11-28 | Akzo N.V. | Polyester/epoxy block copolymer as binder for metal primer |
EP0442583A1 (en) * | 1990-02-16 | 1991-08-21 | Dsm N.V. | Powder coating based on a carboxyl-functional polyester and an epoxy-functional cross-linking agent |
-
1994
- 1994-01-26 WO PCT/US1994/000983 patent/WO1994017111A1/en active IP Right Grant
- 1994-01-26 JP JP6517326A patent/JPH08509508A/ja not_active Ceased
- 1994-01-26 DK DK94906717T patent/DK0681591T3/da active
- 1994-01-26 EP EP94906717A patent/EP0681591B1/en not_active Expired - Lifetime
- 1994-01-26 AU AU60329/94A patent/AU691171B2/en not_active Ceased
- 1994-01-26 DE DE69418308T patent/DE69418308T2/de not_active Expired - Fee Related
-
1995
- 1995-06-07 US US08/485,668 patent/US5567781A/en not_active Expired - Lifetime
-
1998
- 1998-04-02 HK HK98102804A patent/HK1003714A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE69418308T2 (de) | 1999-09-23 |
DK0681591T3 (da) | 1999-11-01 |
DE69418308D1 (de) | 1999-06-10 |
WO1994017111A1 (en) | 1994-08-04 |
EP0681591A4 (en) | 1996-02-21 |
AU691171B2 (en) | 1998-05-14 |
US5567781A (en) | 1996-10-22 |
EP0681591A1 (en) | 1995-11-15 |
HK1003714A1 (en) | 1998-11-06 |
EP0681591B1 (en) | 1999-05-06 |
AU6032994A (en) | 1994-08-15 |
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