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JPH08196829A - Air cleaning filter medium and its production - Google Patents

Air cleaning filter medium and its production

Info

Publication number
JPH08196829A
JPH08196829A JP7011886A JP1188695A JPH08196829A JP H08196829 A JPH08196829 A JP H08196829A JP 7011886 A JP7011886 A JP 7011886A JP 1188695 A JP1188695 A JP 1188695A JP H08196829 A JPH08196829 A JP H08196829A
Authority
JP
Japan
Prior art keywords
filter medium
fibers
fiber
air cleaning
binder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7011886A
Other languages
Japanese (ja)
Inventor
Katsushi Ogami
勝志 大上
Mitsuo Yoshida
光男 吉田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Paper Mills Ltd
Original Assignee
Mitsubishi Paper Mills Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Paper Mills Ltd filed Critical Mitsubishi Paper Mills Ltd
Priority to JP7011886A priority Critical patent/JPH08196829A/en
Publication of JPH08196829A publication Critical patent/JPH08196829A/en
Pending legal-status Critical Current

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  • Filtering Materials (AREA)
  • Separation Of Gases By Adsorption (AREA)

Abstract

PURPOSE: To produce an air cleaning filter medium having satisfactory deodorizing performance and dust removing performance and excellent also in gas permeability and workability. CONSTITUTION: This filter medium has a two-layered structure formed by integrating a filter medium A consisting of very thin glass fibers, org. fibers of <=20μm fiber diameter and binder fibers with a filter medium B consisting of active carbon fibers, natural fibers and binder fibers and having >=40,000m<2> /m<2> BET specific surface area and has <=10mmH<2> O pressure drop measured at 5.3cm/sec surface wind veloctiy in accordance with JIS B9908. The natural fibers in the filter medium B are preferably fibers of wood pulp, hemp pulp or cotton linter pulp and the filter media A, B are preferably wet nonwoven fabrics.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、空気清浄化フィルター
濾材およびその製造方法に関し、さらに詳しくは脱臭性
能および中性能フィルター濾材レベルの除塵性能の双方
を有し、ビル、家屋などの一般室内、自動車、航空機内
などにおける空気清浄化フィルターとして活用し得る空
気清浄化フィルター濾材およびその製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an air cleaning filter medium and a method for producing the same, more specifically, it has both deodorizing performance and medium performance filter medium level dust removing performance, and is used in general rooms such as buildings and houses. The present invention relates to an air cleaning filter medium that can be used as an air cleaning filter in automobiles, airplanes, etc., and a method for manufacturing the same.

【0002】[0002]

【従来の技術】ビル、家屋などの一般室内、自動車、航
空機内などにおいては、悪臭などの有害ガスと大気中の
浮遊粒子が共存しており、双方の除去性能を有する空気
清浄化フィルター濾材が所望されることが多い。空気清
浄化フィルター濾材としては、従来よりポリエステル繊
維のような有機繊維や、ガラス繊維などを混抄してなる
不織布や濾紙が使用されているが、これらの空気清浄化
フィルター濾材には脱臭性能がなく、脱臭性能を付与す
るためには、脱臭専用のフィルターを併用しなければな
らなかった。
2. Description of the Related Art In general rooms such as buildings and houses, automobiles, airplanes, etc., harmful gases such as malodors and suspended particles in the atmosphere coexist, and an air cleaning filter medium having both removal performance is available. Often desired. As the air cleaning filter media, non-woven fabrics and filter papers made by mixing organic fibers such as polyester fibers and glass fibers have been conventionally used, but these air cleaning filter media do not have deodorizing performance. In order to impart deodorizing performance, it was necessary to use a filter dedicated to deodorizing together.

【0003】従来の空気清浄化フィルター濾材のかかる
問題点を解決し、脱臭性能と除塵性能の双方を同時に有
する空気清浄化フィルター濾材として、例えば、特開昭
62−155914号公報には、活性炭素繊維、極細ガ
ラス繊維、セルロース繊維を一体化させた空気清浄用濾
紙が開示されている。該空気清浄用濾紙は、活性炭素繊
維で脱臭性能を、極細ガラス繊維で除塵性能を付与する
ことを特徴とする単層構造の空気清浄用濾紙である。同
様の単層構造の空気清浄化フィルター濾材として、特開
昭63−62518号公報には、カチオン交換体および
活性炭の粒子あるいは繊維を極細ガラス繊維、バインダ
ーと一体化させた空気清浄用フィルター材料が、また、
特開平2−115013号公報には、活性炭素繊維、極
細ガラス繊維を接着剤(繊維状ポリビニルアルコールな
ど)を用いて一体化させたフィルター用濾紙が開示され
ている。さらに、2層構造の空気清浄化フィルター濾材
としては、例えば、特開平2−135141号公報に、
微粒子状活性炭を担持させた脱臭性能を有する不織布と
通気性補強不織布とを一体化した空気浄化用フィルター
が開示されている。
As an air cleaning filter medium having both deodorizing performance and dust removing performance, which solves the above problems of the conventional air cleaning filter medium, for example, Japanese Patent Laid-Open No. 62-155914 discloses activated carbon. An air cleaning filter paper in which fibers, ultrafine glass fibers and cellulose fibers are integrated is disclosed. The air-cleaning filter paper is a single-layer structure air-cleaning filter paper characterized in that activated carbon fibers impart deodorizing performance and ultrafine glass fibers impart dust removing performance. As an air purifying filter medium having the same single layer structure, Japanese Patent Laid-Open No. 63-62518 discloses an air purifying filter material in which particles or fibers of a cation exchanger and activated carbon are integrated with an ultrafine glass fiber and a binder. ,Also,
Japanese Unexamined Patent Publication (Kokai) No. 2-115013 discloses a filter paper in which activated carbon fibers and ultrafine glass fibers are integrated by using an adhesive (fibrous polyvinyl alcohol or the like). Further, as an air cleaning filter medium having a two-layer structure, for example, in Japanese Patent Laid-Open No. 2-135141,
There is disclosed an air purification filter in which a non-woven fabric having deodorizing performance supporting fine particulate activated carbon and a breathable reinforced non-woven fabric are integrated.

【0004】しかしながら、上記の特開昭62−155
914号公報、特開昭63−62518号公報、並びに
特開平2−115013号公報に開示されているような
活性炭素繊維やイオン交換体などの脱臭素材、極細ガラ
ス繊維、バインダーなどを一体化させた単層構造の空気
清浄化フィルター濾材では、脱臭素材および極細ガラス
繊維の双方を同時に十分量配合することができず、十分
な脱臭、除塵性能を付与することができないばかりでな
く、単層構造であるが故に脱臭素材も大気中の浮遊粒子
などに直接晒されるため、脱臭素材への粒子の付着によ
り脱臭性能の低下を招くという問題点があった。
However, the above-mentioned Japanese Patent Laid-Open No. 62-155.
No. 914, JP-A-63-62518, and JP-A No. 2-115013, deodorizing materials such as activated carbon fibers and ion exchangers, ultrafine glass fibers, and binder are integrated. With a single layer structure air cleaning filter medium, it is not possible to mix sufficient amounts of both deodorizing material and ultrafine glass fiber at the same time, and not only sufficient deodorizing and dust removing performance cannot be imparted, but also a single layer structure. Therefore, since the deodorizing material is also directly exposed to airborne particles in the air, there is a problem that the deodorizing performance is deteriorated due to the adhesion of the particles to the deodorizing material.

【0005】一方、特開平2−135141号公報に開
示されている2層構造の空気清浄化フィルターでは、微
粒子状活性炭の脱落を防止するために、繊維状ポリビニ
ルアルコールなどのバインダーを比較的多量に使用せね
ばならず、バインダーによる微粒子状活性炭の細孔被覆
によってその有効比表面積が低下するだけでなく、濾材
強度、濾材の通気性、抄紙性などを考慮した場合、微粒
子状活性炭を多量に配合することが難しく、濾材の単位
面積当たりの比表面積を大きくするためには高坪量の濾
材とせざるを得ず、濾材の厚みが増してユニットに組み
込む際に濾材面積を大きくとれない、加工時の断裁など
で微粒子状活性炭が脱落して加工性にも劣るという問題
点があった。加えて、該公報によれば、濾材の通気性の
低下を回避するべく、通気性補強不織布は薄く且つ粗な
構造であることが好ましいとされており、該不織布層に
おいて十分な除塵性能を得ることは困難である。
On the other hand, in the two-layer air cleaning filter disclosed in Japanese Patent Laid-Open No. 135141/1990, a relatively large amount of a binder such as fibrous polyvinyl alcohol is used to prevent the particulate activated carbon from falling off. It must be used, and not only the effective specific surface area is reduced due to the fine pore activated carbon coating with a binder, but a large amount of fine activated carbon is blended when considering the strength of the filter medium, air permeability of the filter medium, and papermaking properties. It is difficult to do so, in order to increase the specific surface area per unit area of the filter medium, it is unavoidable to use a high basis weight filter medium, and the thickness of the filter medium increases and the filter medium area cannot be increased when it is incorporated into the unit. However, there is a problem in that the fine-grained activated carbon falls off due to cutting, etc. and the workability is poor. In addition, according to the publication, it is preferable that the breathable reinforced nonwoven fabric has a thin and rough structure in order to avoid a decrease in breathability of the filter medium, and sufficient dust removing performance is obtained in the nonwoven fabric layer. Is difficult.

【0006】[0006]

【発明が解決しようとする課題】本発明は、上記の問題
点を解決するものであり、通気性に優れ、且つ脱臭性能
および中性能フィルター濾材レベルの除塵性能の双方を
有し、更に加工性にも優れる空気清浄化フィルター濾材
およびその製造方法を提供することを目的とする。
DISCLOSURE OF THE INVENTION The present invention solves the above-mentioned problems, has excellent breathability, has both deodorizing performance and dust removing performance at the level of a medium-performance filter medium, and has further processability. It is also an object of the present invention to provide an air cleaning filter medium excellent also in the above and a manufacturing method thereof.

【0007】[0007]

【課題を解決するための手段】本発明者らは、上記の課
題を解決するために鋭意検討した結果、空気清浄化フィ
ルター濾材およびその製造方法を発明するに至った。
Means for Solving the Problems As a result of intensive studies to solve the above problems, the inventors have invented an air cleaning filter medium and a method for producing the same.

【0008】即ち、本発明の空気清浄化フィルター濾材
は、極細ガラス繊維、繊維径20μm以下の有機繊維、
並びにバインダー繊維で構成される濾材A、および活性
炭素繊維、天然繊維、並びにバインダー繊維で構成さ
れ、且つ1m2 当たりのBET比表面積が4万m2 以上
の濾材Bを一体化した2層構造からなり、JIS B9
908に準じて面風速5.3cm/秒で測定される圧力
損失が10mmH2O 以下の値を有することを特徴とす
る。
That is, the air cleaning filter medium of the present invention comprises ultrafine glass fibers, organic fibers having a fiber diameter of 20 μm or less,
And filter material A composed of a binder fiber, and activated carbon fibers, natural fibers and is composed of binder fibers, and a two-layer structure in which the BET specific surface area per 1 m 2 are integrated 40,000 m 2 or more medium B, Nari, JIS B9
According to 908, the pressure loss measured at a surface wind velocity of 5.3 cm / sec has a value of 10 mmH 2 O or less.

【0009】本発明の空気清浄化フィルター濾材におい
て、天然繊維は、木材パルプ、麻パルプ、コットンリン
ターパルプの群から選ばれる少なくとも1種以上である
ことが好ましい。
In the air-cleaning filter medium of the present invention, the natural fiber is preferably at least one selected from the group consisting of wood pulp, hemp pulp and cotton linter pulp.

【0010】また、本発明の空気清浄化フィルター濾材
において、濾材Aまたは濾材Bが、湿式不織布であるこ
とが好ましい。
Further, in the air cleaning filter medium of the present invention, it is preferable that the filter medium A or the filter medium B is a wet non-woven fabric.

【0011】本発明の空気清浄化フィルター濾材の製造
方法において、極細ガラス繊維、繊維径20μm以下の
有機繊維、バインダー繊維を水中に混合して水性スラリ
ーを調製し、湿式抄紙法により該水性スラリーを用いて
抄造された濾材Aと、活性炭素繊維、天然繊維、バイン
ダー繊維を水中に混合して水性スラリーを調製し、湿式
抄紙法により該水性スラリーを用いて抄造された濾材B
とを抄き合わせて一体化し、乾燥することを特徴とす
る。
In the method for producing an air cleaning filter medium of the present invention, ultrafine glass fibers, organic fibers having a fiber diameter of 20 μm or less, and binder fibers are mixed in water to prepare an aqueous slurry, and the aqueous slurry is prepared by a wet papermaking method. The filter medium A produced by using the activated carbon fiber, the natural fiber, and the binder fiber are mixed in water to prepare an aqueous slurry, and the filter medium B produced by using the aqueous slurry by a wet papermaking method.
It is characterized in that and are combined and integrated, and dried.

【0012】以下、本発明の空気清浄化フィルター濾材
について、詳細に説明する。
The air cleaning filter medium of the present invention will be described in detail below.

【0013】まず、濾材Aについて、以下に具体的に説
明する。本発明の空気清浄化フィルター濾材を構成する
濾材Aは、主として極細ガラス繊維で空気中の浮遊粒子
を捕捉除去することを目的とした除塵性能を有する濾材
である。濾材Aで使用される繊維の具体的な説明を通じ
て濾材Aを説明する。
First, the filter medium A will be specifically described below. The filter medium A constituting the air cleaning filter medium of the present invention is a filter medium having a dust removing performance mainly for capturing and removing suspended particles in the air with ultrafine glass fibers. The filter medium A will be described through a specific description of the fibers used in the filter medium A.

【0014】本発明で用いられる極細ガラス繊維とは、
平均繊維径が0.2〜4μmのガラス繊維であり、除塵
性能を決定づける繊維である。極細ガラス繊維の配合量
は、濾材Aの重量の3〜20%が好ましく、さらに好ま
しくは5〜15%である。3%未満では十分な除塵性能
を得ることができず、一方、20%を超えて多いと、除
塵性能は向上するものの、濾水性の低下によって抄紙性
が悪化するばかりでなく、空気清浄化フィルター濾材の
通気性が低下するので好ましくない。
The ultrafine glass fiber used in the present invention is
It is a glass fiber having an average fiber diameter of 0.2 to 4 μm and is a fiber that determines the dust removal performance. The blending amount of the ultrafine glass fiber is preferably 3 to 20% of the weight of the filter medium A, and more preferably 5 to 15%. If it is less than 3%, sufficient dust removal performance cannot be obtained. On the other hand, if it exceeds 20%, the dust removal performance is improved, but not only the papermaking property is deteriorated due to a decrease in drainage, but also an air cleaning filter. It is not preferable because the air permeability of the filter material is lowered.

【0015】次に、有機繊維について、以下に説明す
る。本発明で用いられる有機繊維とは、繊維径が20μ
m以下の繊維である。有機繊維は、柔軟性に富み屈曲し
易いため、剛直で自着能力のない極細ガラス繊維に良く
絡み合い、均一なネットワークの形成に有効に作用する
ばかりでなく、該有機繊維の繊維径が20μm以下と細
く、緻密なネットワークを形成するために、極細ガラス
繊維の保持性にも優れる。
Next, the organic fiber will be described below. The organic fiber used in the present invention has a fiber diameter of 20 μm.
It is a fiber of m or less. Since the organic fiber is highly flexible and easy to bend, it not only entangles well with the ultrafine glass fiber which is rigid and does not have self-adhesion ability and effectively acts to form a uniform network, but the diameter of the organic fiber is 20 μm or less. Since it forms a fine and dense network, it is also excellent in retaining ultrafine glass fibers.

【0016】従って、該有機繊維の使用によって、極細
ガラス繊維の配合量が少ない場合でさえも良好な除塵性
能が得られるため、濾材の通気性を損なうことなく良好
な除塵性能を付与することができる。有機繊維の繊維径
が20μmを超えて大きいと、濾材内における有機繊維
の本数が少なくなり、粗なネットワークとなるために、
該有機繊維による極細ガラス繊維の保持能力が低下し、
抄紙時にワイヤーから流出する極細ガラス繊維量が増加
するため、十分な除塵性能が得られなくなるばかりでな
く、高価な極細ガラス繊維の歩留まりが低下して経済性
にも劣るので好ましくない。
Therefore, by using the organic fibers, good dust removing performance can be obtained even when the amount of the ultrafine glass fibers is small, so that good dust removing performance can be imparted without impairing the air permeability of the filter medium. it can. If the fiber diameter of the organic fibers is larger than 20 μm, the number of organic fibers in the filter medium decreases, and a coarse network is formed.
The retention capacity of the ultrafine glass fiber by the organic fiber is reduced,
Since the amount of ultrafine glass fibers flowing out from the wire during papermaking increases, sufficient dust removal performance cannot be obtained, and the yield of expensive ultrafine glass fibers decreases, which is also unfavorable in economic efficiency.

【0017】有機繊維の種類としては、20μm以下の
繊維径を有するものであれば特に限定されるものではな
く、ポリアミド系繊維、ポリエステル系繊維、ポリアク
リロニトリル系繊維、ポリエチレン系繊維、ポリプロピ
レン系繊維、ポリビニルアルコール系繊維、フェノール
系繊維、再生繊維などの合成繊維および木材パルプ、麻
パルプ、コットンリンターパルプなどの天然繊維から選
ばれる繊維を単独あるいは複数混合して使用することが
できる。
The type of organic fiber is not particularly limited as long as it has a fiber diameter of 20 μm or less. Polyamide fiber, polyester fiber, polyacrylonitrile fiber, polyethylene fiber, polypropylene fiber, Fibers selected from synthetic fibers such as polyvinyl alcohol fibers, phenol fibers, recycled fibers and natural fibers such as wood pulp, hemp pulp and cotton linter pulp can be used alone or in combination.

【0018】有機繊維の繊維長は1〜20mmが好まし
く、さらに好ましくは3〜6mmである。1mmよりも
短いと緻密な濾材となり、通気性が低下するばかりでな
く、スラリーの濾水性が低下し、生産性の悪化を招くの
で好ましくない。20mmを超えて長いと、水中での分
散性が悪くなり、均一で地合の良好な濾材が得られない
ので好ましくない。
The fiber length of the organic fiber is preferably 1 to 20 mm, more preferably 3 to 6 mm. When the length is shorter than 1 mm, it becomes a dense filter medium, and not only the air permeability is lowered, but also the drainage of the slurry is lowered and the productivity is deteriorated, which is not preferable. If the length is more than 20 mm, the dispersibility in water is deteriorated, and a uniform filter material having a good texture cannot be obtained, which is not preferable.

【0019】有機繊維の配合量は、濾材Aの重量の20
〜70%が好ましく、さらに好ましくは30〜50%で
ある。20%未満では、濾材内における有機繊維の本数
が少なくなり、極細ガラス繊維とのネットワーク形成能
が低下するため、十分な除塵性能が得られないので好ま
しくない。70%超えて多いと、後述するバインダー繊
維の配合量が少なくなり、濾材の強度が低下し、加工性
に劣る濾材となるので好ましくない。
The amount of the organic fiber blended is 20 times the weight of the filter medium A.
˜70% is preferable, and more preferably 30-50%. When it is less than 20%, the number of organic fibers in the filter medium decreases, and the ability to form a network with the ultrafine glass fibers decreases, so that sufficient dust removal performance cannot be obtained, which is not preferable. When it is more than 70%, the amount of binder fiber to be described later becomes small, the strength of the filter medium is lowered, and the processability becomes poor, which is not preferable.

【0020】次に、バインダー繊維について、以下に説
明する。本発明で用いられるバインダー繊維としては、
熱溶融性繊維あるいは熱水溶解性繊維が例示される。
Next, the binder fiber will be described below. As the binder fiber used in the present invention,
Examples are heat-meltable fibers and hot-water-soluble fibers.

【0021】熱溶融性繊維は、ポリエステル、ポリオレ
フィン、ポリアミドなどの合成樹脂から選ばれた繊維状
のもので、合成樹脂の融点以上の温度で処理することに
よって合成樹脂が溶融し、接着および強度を発現するも
のである。
The heat-fusible fiber is a fibrous material selected from synthetic resins such as polyester, polyolefin and polyamide, and the synthetic resin is melted when treated at a temperature higher than the melting point of the synthetic resin to improve adhesion and strength. It will be expressed.

【0022】熱水溶解性繊維は、ポリビニルアルコー
ル、エチレンビニルアルコールなどの合成樹脂から選ば
れた繊維状のもので、加熱により含水状態のウェブを乾
燥させる工程で水温の上昇によって溶解し、ウェブが乾
燥することで接着および強度を発現するものである。
The hot water-soluble fiber is a fibrous material selected from synthetic resins such as polyvinyl alcohol and ethylene vinyl alcohol, and is melted by increasing the water temperature in the step of drying the wet web by heating to form a web. When dried, it exhibits adhesion and strength.

【0023】バインダー繊維の繊度は、0.1〜15デ
ニールが好ましい。0.1デニール未満では、スラリー
の濾水性が小さくなり、生産性の悪化を招くので好まし
くない。15デニールを超えて大きいと、濾材内のバイ
ンダー繊維の本数が少なくなり、接着力の低下を補うべ
くバインダー繊維の配合量を増やさねばならず、他の構
成繊維の配合量が低下するばかりでなく、抄紙時のウェ
ブの含水率が小さくなり、ワイヤーからのピックアップ
が困難になるので好ましくない。
The fineness of the binder fiber is preferably 0.1 to 15 denier. When it is less than 0.1 denier, the drainage of the slurry becomes small and the productivity is deteriorated, which is not preferable. If it is larger than 15 denier, the number of binder fibers in the filter medium will decrease, and the amount of binder fibers must be increased in order to compensate for the decrease in adhesive strength, and not only the amount of other constituent fibers will decrease. However, the water content of the web at the time of paper making becomes small and it becomes difficult to pick up from the wire, which is not preferable.

【0024】繊維長は1〜20mmが好ましく、さらに
好ましくは3〜6mmである。1mmよりも短いと緻密
な濾材となり、通気性が低下するので好ましくない。2
0mmを超えて長いと、水中での分散性が悪くなり、均
一で地合の良好な濾材が得られないので好ましくない。
The fiber length is preferably 1 to 20 mm, more preferably 3 to 6 mm. If it is shorter than 1 mm, it becomes a dense filter medium and the air permeability is lowered, which is not preferable. Two
When the length is more than 0 mm, the dispersibility in water is deteriorated, and a uniform filter material having a good texture cannot be obtained, which is not preferable.

【0025】バインダー繊維の配合量は、濾材Aの重量
の30〜60%が好ましく、さらに好ましくは、40〜
50%である。30%未満では、接着力に不足し、濾材
の強度が低下するので好ましくない。60%を超えて多
いと、接着力は大きいが、他の構成繊維の配合量が減少
し、除塵性能に劣る濾材となるので好ましくない。
The content of the binder fiber is preferably 30 to 60% of the weight of the filter medium A, more preferably 40 to 60%.
50%. If it is less than 30%, the adhesive strength is insufficient and the strength of the filter medium is lowered, which is not preferable. If it is more than 60%, the adhesive force is large, but the amount of the other constituent fibers is decreased, and the filter material is inferior in dust removal performance, which is not preferable.

【0026】次に、濾材Bについて、以下に具体的に説
明する。本発明の濾材Bは、活性炭素繊維によって、悪
臭ガスなどを吸着除去する濾材であって、脱臭性能には
濾材BのBET比表面積が大きく関与する。濾材Bに使
用される繊維の説明を通じて、濾材Bについて、以下に
詳細に説明する。
Next, the filter medium B will be specifically described below. The filter medium B of the present invention is a filter medium that adsorbs and removes malodorous gas and the like by activated carbon fibers, and the BET specific surface area of the filter medium B is greatly involved in deodorizing performance. The filter medium B will be described in detail below through the description of the fibers used for the filter medium B.

【0027】本発明で用いられる活性炭素繊維は、濾材
BのBET比表面積を決定づける繊維であって、再生繊
維、フェノール繊維、ポリアクリロニトリル繊維などを
前駆体として製造された従来公知のものを広く活用する
ことができる。活性炭素繊維の比表面積は、特に限定さ
れるものではないが、比表面積があまりに大きい場合に
は、単糸強度が小さくなり、抄紙時の離解、分散工程に
おける撹拌シェアや、プレスパートでの加圧などによっ
て容易に繊維損傷を起こし、活性炭素繊維の微粉末の発
生を招くため、比表面積は2500m2/g以下であること
が好ましい。
The activated carbon fiber used in the present invention is a fiber which determines the BET specific surface area of the filter medium B, and widely used conventionally known ones produced from recycled fiber, phenol fiber, polyacrylonitrile fiber and the like as precursors. can do. The specific surface area of the activated carbon fiber is not particularly limited, but when the specific surface area is too large, the strength of the single yarn becomes small, the disintegration at the time of paper making, the stirring share in the dispersion step, and the addition at the press part. The specific surface area is preferably 2,500 m 2 / g or less because fiber damage easily occurs due to pressure and the like to generate fine powder of activated carbon fibers.

【0028】活性炭素繊維の繊維径や繊維長は特に限定
されるものではないが、抄紙時の濾水性や繊維分散性を
考慮すると、平均繊維径は5〜30μmが好ましく、一
方、平均繊維長は1〜20mmが好ましく、さらに好ま
しくは3〜6mmである。
Although the fiber diameter and fiber length of the activated carbon fiber are not particularly limited, the average fiber diameter is preferably 5 to 30 μm in view of drainage property and fiber dispersibility during paper making, while the average fiber length is Is preferably 1 to 20 mm, more preferably 3 to 6 mm.

【0029】使用する活性炭素繊維の吸着特性にもよる
が、濾材Bの1m2 当たりのBET比表面積が4万m2
以上であれば、脱臭性能の指標の一つとして用いられる
ベンゼン吸着量を15g/m2以上確保することが可能であ
り、十分な脱臭性能が得られるので、BET比表面積が
該値の範囲内にある限り、活性炭素繊維の配合量は特に
限定されるものではない。しかしながら、活性炭素繊維
の配合量が濾材Bの重量の90%を超えて多いと、後述
する天然繊維の配合量が減少し、活性炭素繊維の脱落が
顕著となるため、活性炭素繊維の配合量は濾材Bの重量
の90%以下であることが好ましい。
The BET specific surface area per 1 m 2 of the filter medium B is 40,000 m 2 though it depends on the adsorption characteristics of the activated carbon fiber used.
If it is above, it is possible to secure the benzene adsorption amount used as one of the indicators of the deodorizing performance of 15 g / m 2 or more, and sufficient deodorizing performance can be obtained. Therefore, the BET specific surface area is within the range. The amount of activated carbon fiber is not particularly limited as long as it is within the range. However, if the content of the activated carbon fibers exceeds 90% of the weight of the filter medium B, the content of the natural fibers described below is decreased and the active carbon fibers are more likely to fall off. Is preferably 90% or less of the weight of the filter medium B.

【0030】次に、天然繊維について、以下に説明す
る。本発明で用いられる天然繊維は、自着能力のない活
性炭素繊維を有効に保持し、シート状に成形するために
使用されるものであって、従来公知の植物繊維を広く活
用することができる。該天然繊維は柔軟性に富み、剛直
で自着能力のない活性炭素繊維に良く絡み合って均一な
ネットワークを形成し、比較的少ない配合量の場合で
も、活性炭素繊維を有効且つ強固に保持するため、濾材
をさして緻密化させることなく、活性炭素繊維をシート
状に成形することが可能である。活性炭素繊維をシート
化するために、熱溶融性繊維や熱水溶解性繊維に代表さ
れるバインダー繊維を使用した場合には、該バインダー
繊維の融着によって活性炭素繊維表面のミクロポアが閉
塞されるため、これに起因する活性炭素繊維の性能低下
は避けられないが、本発明の天然繊維を使用した場合に
は、このような活性炭素繊維の性能低下が皆無に近いと
いう利点がある。また、該バインダー繊維のみによって
接着された活性炭素繊維シートは、ひだ折り加工時に活
性炭素繊維シート内で紙層剥離を生じ易いという問題が
あり、それを解決するべく活性炭素繊維のミクロポアを
閉塞するバインダー繊維の配合量を多くせざるを得なか
ったが、本発明の天然繊維は、該繊維自体が自着能力を
有し、且つ上述の如く活性炭素繊維に良く絡み合ってい
るため、そのような問題は皆無である。加えて、該天然
繊維の使用によって、濾材のこしが強くなり、加工性も
向上する。
Next, the natural fiber will be described below. The natural fiber used in the present invention effectively retains the activated carbon fiber having no self-adhesion ability and is used for forming into a sheet, and conventionally known plant fibers can be widely utilized. . Since the natural fiber is highly flexible, it is entwined well with the activated carbon fiber which is rigid and has no self-adhesion ability to form a uniform network, so that the activated carbon fiber can be effectively and firmly retained even in a relatively small amount. It is possible to mold the activated carbon fiber into a sheet without inserting the filter medium to densify it. When a binder fiber typified by a heat-meltable fiber or a hot-water-soluble fiber is used for forming the activated carbon fiber into a sheet, the fusion of the binder fiber blocks the micropores on the surface of the activated carbon fiber. Therefore, the performance deterioration of the activated carbon fiber due to this is inevitable, but when the natural fiber of the present invention is used, there is an advantage that such a performance deterioration of the activated carbon fiber is almost zero. Further, the activated carbon fiber sheet adhered only by the binder fiber has a problem that the paper layer peeling easily occurs in the activated carbon fiber sheet during the pleating process, and in order to solve this, the micropores of the activated carbon fiber are closed. Although the blending amount of the binder fiber had to be increased, the natural fiber of the present invention has such self-adhesive ability and is well entangled with the activated carbon fiber as described above. There are no problems. In addition, the use of the natural fiber strengthens the strain of the filter medium and improves the processability.

【0031】天然繊維の種類は、植物繊維であれば特に
限定されるものではないが、木材パルプ、麻パルプ、コ
ットンリンターパルプは、安価で且つ入手が容易である
上に、ビーターやリファイナーのような通常の叩解機に
よる叩解で繊維の比表面積を調整し得るため、該繊維に
よる活性炭素繊維の保持性能や濾材の通気性を任意に調
整することも可能であり、加えて、親水性で抄紙性にも
優れている点で特に好ましい素材である。
The type of natural fiber is not particularly limited as long as it is a vegetable fiber, but wood pulp, hemp pulp and cotton linter pulp are inexpensive and easily available, and are like those of beaters and refiners. Since the specific surface area of the fiber can be adjusted by beating with an ordinary beating machine, it is also possible to arbitrarily adjust the retention performance of the activated carbon fiber by the fiber and the air permeability of the filter medium. It is a particularly preferable material because it has excellent properties.

【0032】天然繊維の配合量は、濾材Bの重量の5〜
50%が好ましく、さらに好ましくは20〜40%であ
る。5%未満では活性炭素繊維の保持能力に不足し、活
性炭素繊維の脱落が顕著となるので好ましくない。50
%を超えて多いと、活性炭素繊維の保持能力は大きい
が、緻密な濾材となり、通気性に欠ける濾材となるので
好ましくない。
The blending amount of the natural fiber is 5 to the weight of the filter medium B.
It is preferably 50%, more preferably 20-40%. If it is less than 5%, the ability to retain the activated carbon fibers is insufficient, and the activated carbon fibers are significantly detached, which is not preferable. Fifty
When it is more than 0.1%, the activated carbon fiber holding capacity is large, but it becomes a dense filter medium and a filter medium lacking air permeability, which is not preferable.

【0033】次に、バインダー繊維について、以下に説
明する。本発明で用いられるバインダー繊維としては、
先の濾材Aに例示された熱溶融性繊維あるいは熱水溶解
性繊維を活用することができる。濾材Bにおいて、該バ
インダー繊維は活性炭素繊維の接着にも関与するが、濾
材Aと濾材Bとを抄き合わせ一体化した際の層間強度の
発現を主な目的として使用されるものである。
Next, the binder fiber will be described below. As the binder fiber used in the present invention,
The heat-meltable fiber or the hot-water-soluble fiber exemplified in the above filter medium A can be utilized. In the filter medium B, the binder fiber also participates in the adhesion of the activated carbon fiber, but it is mainly used for the purpose of developing the interlaminar strength when the filter medium A and the filter medium B are laminated and integrated.

【0034】バインダー繊維の配合量は、濾材Bの重量
の3〜20%であることが好ましい。3%未満では、層
間接着強度が不十分なものとなり、ひだ折り加工などの
際に層間剥離が生ずるので好ましくない。一方、20%
を超えて多いと、層間接着強度は大きくなるが、バイン
ダー繊維の融着によって活性炭素繊維のミクロポアが閉
塞され、その特性が損なわれるので好ましくない。
The content of the binder fiber is preferably 3 to 20% of the weight of the filter medium B. If it is less than 3%, the interlaminar adhesive strength becomes insufficient, and delamination occurs during pleating, which is not preferable. On the other hand, 20%
If it is more than 1.0, the interlaminar adhesive strength increases, but the fusion of the binder fibers blocks the micropores of the activated carbon fibers and impairs the characteristics thereof, which is not preferable.

【0035】上述の濾材Aと濾材Bとを一体化させるこ
とによって、本発明の空気清浄化フィルター濾材を得
る。該濾材は、脱臭性能を有する中性能フィルター濾材
として活用し得るもので、実用に適する濾材となり得る
ためには、中性能フィルター濾材に匹敵する通気性を有
する必要があり、JIS B9908に準じて面風速
5.3cm/秒で測定される圧力損失が10mmH2
以下である必要がある。圧力損失が該値を超えて大きい
と、運転経費の上昇、濾材寿命の低下、使用時の騒音増
大などの不都合が生ずるので好ましくない。
The air cleaning filter medium of the present invention is obtained by integrating the filter medium A and the filter medium B described above. The filter medium can be used as a medium-performance filter medium having a deodorizing performance, and in order to be a filter medium suitable for practical use, it needs to have air permeability comparable to that of the medium-performance filter medium. Pressure loss measured at a wind speed of 5.3 cm / sec is 10 mmH 2 O
Must be: If the pressure loss exceeds this value and is large, operating costs increase, the life of the filter medium decreases, and noise during use increases, which is not preferable.

【0036】次に、本発明の空気清浄化フィルター濾材
の製造方法について、以下に説明する。まず、濾材Aの
必須成分を水中に順次添加し、水性スラリーを調製す
る。繊維を添加する順序に特に制限はないが、水中での
均一な分散のために、水性スラリーの繊維濃度は、0.
1〜5重量%であることが好ましい。次いで、濾材Bの
水性スラリーについても、同様の方法で調製する。
Next, a method for producing the air cleaning filter medium of the present invention will be described below. First, the essential components of the filter medium A are sequentially added to water to prepare an aqueous slurry. The order of adding the fibers is not particularly limited, but the fiber concentration of the aqueous slurry is 0.
It is preferably from 1 to 5% by weight. Then, the aqueous slurry of the filter medium B is also prepared by the same method.

【0037】一般紙や湿式不織布を製造するための抄紙
機、例えば長網抄紙機、円網抄紙機、傾斜ワイヤー式抄
紙機などを2機組み合わせたコンビネーションマシンを
用いて、該水性スラリーより濾材Aと濾材Bとを抄き合
わせ一体化させたウェブを形成し、プレス、乾燥して空
気清浄化フィルター濾材を製造する。ウェブの乾燥に
は、シリンダドライヤー、ヤンキードライヤー、エアド
ライヤーなどを活用することができる。
A filter machine A is prepared from the aqueous slurry by using a combination machine which is a combination of two paper machines such as ordinary paper and wet non-woven fabric, for example, fourdrinier paper machine, cylinder paper machine and inclined wire paper machine. And a filter medium B are combined to form a web, which is pressed and dried to produce an air cleaning filter medium. A cylinder dryer, a Yankee dryer, an air dryer or the like can be used to dry the web.

【0038】[0038]

【作用】本発明の空気清浄化フィルター濾材は、除塵性
能を有する濾材Aと、脱臭性能を有する濾材Bとが一体
化した2層構造を有するものである。
The air cleaning filter medium of the present invention has a two-layer structure in which the filter medium A having dust removing performance and the filter medium B having deodorizing performance are integrated.

【0039】濾材Aにおいては、極細ガラス繊維に繊維
径20μm以下の有機繊維が良く絡み合い、均一且つ緻
密なネットワークを形成し、極細ガラス繊維の配合量が
少ない場合でさえも優れた除塵性能が得られるため、通
気性を損なうことなく除塵性能に優れた濾材を得ること
ができる。
In the filter medium A, the ultrafine glass fibers are well entangled with the organic fibers having a fiber diameter of 20 μm or less to form a uniform and dense network, and excellent dust removal performance is obtained even when the amount of the ultrafine glass fibers is small. Therefore, it is possible to obtain a filter medium excellent in dust removal performance without impairing air permeability.

【0040】一方、濾材Bにおいては、吸着速度の大き
な活性炭素繊維が、そのミクロポアを閉塞されることな
く、天然繊維によって強固に保持されており、活性炭素
繊維の脱落が少なく、且つBET比表面積の大きな濾材
を得ることが可能であり、さらに、該天然繊維の使用に
よって、濾材のこしが強くなり、加工性も向上する。
On the other hand, in the filter medium B, the activated carbon fibers having a high adsorption rate are firmly held by the natural fibers without blocking their micropores, the activated carbon fibers are less likely to fall off, and the BET specific surface area is small. It is possible to obtain a filter medium having a large size, and by using the natural fiber, the strain of the filter medium becomes strong and the processability is improved.

【0041】従って、本発明の空気清浄化フィルター濾
材は、脱臭性能と除塵性能の双方に優れ、且つ通気性お
よび加工性にも優れるので、ハニカム、ひだ折りなどの
様々な構造体に加工し、ビル、家屋などの一般室内、自
動車、航空機内などにおける空気清浄化フィルター濾材
として有効に作用する。
Therefore, since the air cleaning filter medium of the present invention is excellent in both deodorizing performance and dust removing performance, and is also excellent in breathability and workability, it is processed into various structures such as honeycombs and folds, Effectively works as an air purifying filter medium in general rooms such as buildings and houses, automobiles, airplanes, etc.

【0042】[0042]

【実施例】以下に実施例を挙げて本発明を具体的に説明
するが、本発明は本実施例に限定されるものではない。
The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples.

【0043】実施例1〜10 [濾材Aの作製]極細ガラス繊維(平均繊維径0.6μ
m)、繊維径20μm以下の有機繊維としてポリエステ
ル繊維(繊維径7μm、14μm、18μm、繊維長は
5mm)、バインダー繊維として芯鞘型熱融着性ポリエ
ステル繊維(繊維径14μm、繊維長5mm、鞘部融点
110℃)を下記表1に示す繊維配合(重量%で記載)
で混合して水性スラリーを調製し、これらのスラリーか
ら角型手抄き抄紙機を用いて坪量60g/m2の濾材Aを作
製した。
Examples 1 to 10 [Preparation of filter medium A] Extra fine glass fiber (average fiber diameter 0.6 μm)
m), polyester fibers (fiber diameters 7 μm, 14 μm, 18 μm, fiber length 5 mm) as organic fibers having a fiber diameter of 20 μm or less, and core-sheath type heat-fusible polyester fibers (fiber diameter 14 μm, fiber length 5 mm, sheath) as binder fibers. Partial melting point 110 ° C.) Fiber blend shown in Table 1 below (described in wt%)
To prepare an aqueous slurry, and a filter material A having a basis weight of 60 g / m 2 was prepared from these slurries by using a square handmade paper machine.

【0044】[濾材Bの作製]活性炭素繊維(公称比表
面積950m2/g)、天然繊維として針葉樹晒クラフトパ
ルプ(濾水度550ml)、麻パルプ(同640m
l)、コットンリンターパルプ(同610ml)、バイ
ンダー繊維として芯鞘型熱融着性ポリエステル繊維(繊
維径14μm、繊維長5mm、鞘部融点110℃)を表
1に示す繊維配合で混合して水性スラリーを調製し、こ
れらのスラリーから角型手抄き抄紙機を用いて坪量10
0g/m2の濾材Bを作製した。
[Preparation of filter medium B] Activated carbon fiber (nominal specific surface area: 950 m 2 / g), natural fiber softwood bleached kraft pulp (freeness 550 ml), hemp pulp (640 m)
1), cotton linter pulp (same as 610 ml), and core-sheath type heat-fusible polyester fiber (fiber diameter 14 μm, fiber length 5 mm, sheath melting point 110 ° C.) as a binder fiber, mixed in a fiber formulation shown in Table 1 Slurries were prepared and the basis weight of these slurries was 10 using a square handmade paper machine.
A filter medium B of 0 g / m 2 was prepared.

【0045】[空気清浄化フィルター濾材の作製]湿紙
状態の濾材Aと濾材Bとを抄き合わせて一体化させた
後、プレス、乾燥して実施例1〜10の空気清浄化フィ
ルター濾材を作製した。
[Preparation of Filter Material for Air Cleaning Filter] Filter material A and filter material B in the form of wet paper are combined and integrated, then pressed and dried to obtain the filter materials for air cleaning filter of Examples 1-10. It was made.

【0046】比較例1 濾材Aの有機繊維として、繊維径20μmを超えるポリ
エステル繊維(繊維径25μm、繊維長5mm)を使用
した点を除いて、実施例1〜3と同様の方法で比較例1
の空気清浄化フィルター濾材を作製した。
Comparative Example 1 Comparative Example 1 was carried out in the same manner as in Examples 1 to 3 except that polyester fibers having a fiber diameter of more than 20 μm (fiber diameter 25 μm, fiber length 5 mm) were used as the organic fibers of the filter medium A.
The air cleaning filter material of No. 3 was produced.

【0047】比較例2 濾材Bにおいて、活性炭素繊維(公称比表面積950m2
/g)を70重量%、針葉樹晒クラフトパルプ(濾水度5
50ml)を30重量%の繊維配合とした点を除いて、
実施例1と同様の方法で比較例2の空気清浄化フィルタ
ー濾材を作製した。
Comparative Example 2 In the filter medium B, activated carbon fiber (nominal specific surface area 950 m 2
/ g) 70% by weight, softwood bleached kraft pulp (freeness 5
Except that 50 ml) was mixed with 30% by weight of fiber,
An air cleaning filter medium of Comparative Example 2 was produced in the same manner as in Example 1.

【0048】比較例3 濾材Bにおいて、活性炭素繊維(公称比表面積950m2
/g)を40重量%、針葉樹晒クラフトパルプ(濾水度5
50ml)を40重量%、芯鞘型熱融着性ポリエステル
繊維(繊維径14μm、繊維長5mm、鞘部融点110
℃)を20重量%の繊維配合とした点を除いて、実施例
1と同様の方法で比較例3の空気清浄化フィルター濾材
を作製した。
Comparative Example 3 In the filter medium B, activated carbon fiber (nominal specific surface area 950 m 2
/ g) 40% by weight, softwood bleached kraft pulp (freeness 5
50 ml), 40% by weight, core-sheath type heat-fusible polyester fiber (fiber diameter 14 μm, fiber length 5 mm, sheath portion melting point 110)
An air cleaning filter medium of Comparative Example 3 was produced in the same manner as in Example 1 except that the content of the fiber was 20% by weight.

【0049】[0049]

【表1】 [Table 1]

【0050】上記実施例および比較例で作製した空気清
浄化フィルター濾材について、圧力損失、粒子捕集効
率、濾材BのBET比表面積、ベンゼン吸着量、濾材A
/濾材Bの層間強度は以下の方法で評価し、その結果を
下記表2に示した。 [圧力損失]空気清浄化フィルター濾材の圧力損失(m
mH2O )は、JIS B9908に準じて面風速5.
3cm/秒の条件で測定した。この値が10mmH2
以下であれば、通気性は良好である。
Regarding the air cleaning filter media produced in the above Examples and Comparative Examples, pressure loss, particle collection efficiency, BET specific surface area of filter media B, benzene adsorption amount, filter media A
/ The interlayer strength of filter medium B was evaluated by the following method, and the results are shown in Table 2 below. [Pressure loss] Pressure loss of air cleaning filter media (m
mH 2 O) has a surface wind speed of 5. in accordance with JIS B9908.
It was measured under the condition of 3 cm / sec. This value is 10mmH 2 O
If it is the following, the air permeability is good.

【0051】[粒子捕集効率]空気清浄化フィルター濾
材の粒子捕集効率(%)は、JIS B9908に準じ
て面風速5.3cm/秒の条件で測定した。測定対象粒
子として、DOPエアロゾル(フタル酸ジオクチル、粒
径0.3μm)を使用し、粒子数の計測には、リオン
(株)のパーティクルカウンター(KC−11)を使用
した。
[Particle Collection Efficiency] The particle collection efficiency (%) of the air cleaning filter material was measured in accordance with JIS B9908 under a surface wind velocity of 5.3 cm / sec. DOP aerosol (dioctyl phthalate, particle size 0.3 μm) was used as the particles to be measured, and a particle counter (KC-11) manufactured by Rion Co., Ltd. was used to measure the number of particles.

【0052】[BET比表面積]濾材BのBET比表面
積(m2)は、(株)島津製作所のアキュソーブ2100
−02形を用いて窒素吸着量を測定し、BETプロット
より算出した比表面積を、濾材Bの1m2当たりの値に
換算して表示した。
[BET Specific Surface Area] The BET specific surface area (m 2 ) of the filter medium B is Accusorb 2100 manufactured by Shimadzu Corporation.
The amount of nitrogen adsorbed was measured using a -02 type, and the specific surface area calculated from the BET plot was converted into a value per 1 m 2 of the filter material B and displayed.

【0053】[ベンゼン吸着量]濾材Bのベンゼン吸着
量(g/m2)は、JIS K1474に準じて測定し、濾
材Bの1m2当たりの値に換算して表示した。 この値が
15g/m2以上であれば、濾材Bの脱臭性能は良好であ
る。
[Benzene adsorption amount] The benzene adsorption amount (g / m 2 ) of the filter medium B was measured according to JIS K1474, and converted into a value per 1 m 2 of the filter medium B and displayed. When this value is 15 g / m 2 or more, the deodorizing performance of the filter medium B is good.

【0054】[濾材A/濾材Bの層間強度]濾材Aと濾
材Bとの層間強度は、空気清浄化フィルター濾材をひだ
折り加工した際の層間の状況を目視により調べた。濾材
間に層間剥離が観察されなかった場合には記号○で、観
察された場合には記号×で表示してある。
[Interlayer Strength of Filter Material A / Filter Material B] The interlayer strength between the filter material A and the filter material B was examined by visually observing the condition between the layers when the air cleaning filter material was pleated. When no delamination was observed between the filter media, it was indicated by the symbol o, and when observed, it was indicated by the symbol x.

【0055】[0055]

【表2】 [Table 2]

【0056】評価:実施例1〜10の空気清浄化フィル
ター濾材は、極細ガラス繊維が有効に保持され、除塵性
能に優れるばかりでなく、十分な脱臭性能を有すること
が判る。また、圧力損失が小さく、良好な通気性を有す
るのみならず、ひだ折り加工時の層間剥離も見られず、
加工性にも優れている。
Evaluation: It is understood that the air cleaning filter media of Examples 1 to 10 have not only excellent dust-removing performance, but also sufficient deodorizing performance since the ultrafine glass fibers are effectively retained. In addition, the pressure loss is small, and not only does it have good air permeability, but delamination during pleating is not observed,
Excellent workability.

【0057】比較例1の空気清浄化フィルター濾材は、
濾材Aにおいて、20μmを超える繊維径の有機繊維を
配合した点を除いて、実施例1〜3の空気清浄化フィル
ター濾材と同一の構成でなるものである。しかしなが
ら、比較例1の空気清浄化フィルター濾材においては、
極細ガラス繊維の保持性に劣り、実施例1〜3の空気清
浄化フィルター濾材と比較した場合、粒子の捕集効率が
大きく低下していることが判る。
The air cleaning filter medium of Comparative Example 1 was
The filter medium A has the same configuration as the air cleaning filter medium of Examples 1 to 3 except that the filter medium A contains an organic fiber having a fiber diameter of more than 20 μm. However, in the air cleaning filter medium of Comparative Example 1,
It can be seen that the retention of the ultrafine glass fibers is inferior and the efficiency of collecting particles is greatly reduced when compared with the air cleaning filter media of Examples 1 to 3.

【0058】比較例2の空気清浄化フィルター濾材は、
濾材Bにおいて、バインダー繊維を使用しなかった濾材
であり、ひだ折り加工時に濾材A/濾材Bの層間剥離が
見られ、加工性に劣る濾材であることが判る。
The air cleaning filter medium of Comparative Example 2 was
In the filter medium B, no binder fiber was used, and delamination of the filter medium A / filter medium B was observed during the pleating process, and it was found that the filter medium was inferior in processability.

【0059】比較例3の空気清浄化フィルター濾材は、
濾材Bの1m2 当たりのBET比表面積が4万m2 未満
であり、ベンゼン吸着量が少なく、脱臭性能に劣る濾材
であることが判る。
The air cleaning filter medium of Comparative Example 3 was
It can be seen that the BET specific surface area per 1 m 2 of the filter material B is less than 40,000 m 2 , the adsorbed amount of benzene is small, and the deodorant performance is poor.

【0060】[0060]

【発明の効果】本発明の空気清浄化フィルター濾材は、
除塵性能を有する濾材Aと、脱臭性能を有する濾材Bと
を一体化した2層構造を有する空気清浄化フィルター濾
材である。
The air cleaning filter medium of the present invention comprises:
An air cleaning filter medium having a two-layer structure in which a filter medium A having a dust removing performance and a filter medium B having a deodorizing performance are integrated.

【0061】濾材Aにおいては、極細ガラス繊維に繊維
径20μm以下の有機繊維が良く絡み合い、均一且つ緻
密なネットワークを形成し、極細ガラス繊維の配合量が
少ない場合でさえも優れた除塵性能が得られるため、通
気性を損なうことなく除塵性能に優れた濾材を得ること
ができる。
In the filter medium A, the ultrafine glass fibers are well entangled with the organic fibers having a fiber diameter of 20 μm or less to form a uniform and dense network, and excellent dust removing performance is obtained even when the amount of the ultrafine glass fibers is small. Therefore, it is possible to obtain a filter medium excellent in dust removal performance without impairing air permeability.

【0062】一方、濾材Bにおいては、吸着速度および
吸着能力の大きな活性炭素繊維が、そのミクロポアを閉
塞されることなく、天然繊維によって有効且つ強固に保
持されており、活性炭素繊維の脱落が少なく、且つBE
T比表面積の大きな脱臭性能に優れた濾材を得ることが
できるばかりでなく、該天然繊維の使用によって、濾材
のこしが強くなり、加工性も向上する。
On the other hand, in the filter medium B, the activated carbon fibers having a large adsorption rate and adsorption ability are effectively and firmly held by the natural fibers without blocking their micropores, and the activated carbon fibers are less likely to fall off. , And BE
Not only can a filter medium having a large T specific surface area and excellent in deodorizing performance be obtained, but the use of the natural fiber also strengthens the strain of the filter medium and improves processability.

【0063】従って、本発明の空気清浄化フィルター濾
材は、脱臭性能と除塵性能の双方に優れ、且つ通気性お
よび加工性にも優れるので、ハニカム、ひだ折りなどの
様々な構造体に加工し、ビル、家屋などの一般室内、自
動車、航空機内などにおける空気清浄化フィルター濾材
として活用することができる。
Therefore, since the air cleaning filter medium of the present invention is excellent in both deodorizing performance and dust removing performance, and is also excellent in breathability and workability, it is processed into various structures such as honeycombs and folds, It can be used as an air cleaning filter medium in general rooms such as buildings and houses, automobiles, airplanes, etc.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 極細ガラス繊維、繊維径20μm以下の
有機繊維、並びにバインダー繊維で構成される濾材A、
および活性炭素繊維、天然繊維、並びにバインダー繊維
で構成され、且つ1m2当たりのBET比表面積が4万
2以上の濾材Bを一体化した2層構造からなり、JI
S B9908に準じて面風速5.3cm/秒で測定さ
れる圧力損失が10mmH2O 以下の値を有する空気清
浄化フィルター濾材。
1. A filter medium A comprising ultrafine glass fibers, organic fibers having a fiber diameter of 20 μm or less, and binder fibers.
And active carbon fibers, is composed of natural fibers, and binder fibers, and a BET specific surface area per 1 m 2 is two-layer structure with an integrated 40,000 m 2 or more medium B, JI
An air cleaning filter medium having a pressure loss of 10 mmH 2 O or less measured according to S B9908 at a surface wind velocity of 5.3 cm / sec.
【請求項2】 天然繊維が、木材パルプ、麻パルプ、コ
ットンリンターパルプの群から選ばれる少なくとも1種
以上であることを特徴とする請求項1記載の空気清浄化
フィルター濾材。
2. The air cleaning filter medium according to claim 1, wherein the natural fiber is at least one selected from the group consisting of wood pulp, hemp pulp and cotton linter pulp.
【請求項3】 濾材Aまたは濾材Bが、湿式不織布であ
ることを特徴とする請求項1または2記載の空気清浄化
フィルター濾材。
3. The air cleaning filter medium according to claim 1 or 2, wherein the filter medium A or the filter medium B is a wet non-woven fabric.
【請求項4】 極細ガラス繊維、繊維径20μm以下の
有機繊維、バインダー繊維を水中に混合して水性スラリ
ーを調製し、湿式抄紙法により該水性スラリーを用いて
抄造された濾材Aと、活性炭素繊維、天然繊維、バイン
ダー繊維を水中に混合して水性スラリーを調製し、湿式
抄紙法により該水性スラリーを用いて抄造された濾材B
とを抄き合わせて一体化し、乾燥することを特徴とする
空気清浄化フィルター濾材の製造方法。
4. A filter medium A produced by mixing an ultrafine glass fiber, an organic fiber having a fiber diameter of 20 μm or less, and a binder fiber into water to prepare an aqueous slurry, and making the aqueous slurry by the wet papermaking method, and activated carbon. A filter medium B prepared by mixing fibers, natural fibers, and binder fibers in water to prepare an aqueous slurry, and using the aqueous slurry to make a paper.
A method for producing an air cleaning filter medium, characterized in that and are combined together and dried.
JP7011886A 1995-01-27 1995-01-27 Air cleaning filter medium and its production Pending JPH08196829A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7011886A JPH08196829A (en) 1995-01-27 1995-01-27 Air cleaning filter medium and its production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7011886A JPH08196829A (en) 1995-01-27 1995-01-27 Air cleaning filter medium and its production

Publications (1)

Publication Number Publication Date
JPH08196829A true JPH08196829A (en) 1996-08-06

Family

ID=11790215

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7011886A Pending JPH08196829A (en) 1995-01-27 1995-01-27 Air cleaning filter medium and its production

Country Status (1)

Country Link
JP (1) JPH08196829A (en)

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