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JPH07277745A - Burner for formation of glass - Google Patents

Burner for formation of glass

Info

Publication number
JPH07277745A
JPH07277745A JP8771494A JP8771494A JPH07277745A JP H07277745 A JPH07277745 A JP H07277745A JP 8771494 A JP8771494 A JP 8771494A JP 8771494 A JP8771494 A JP 8771494A JP H07277745 A JPH07277745 A JP H07277745A
Authority
JP
Japan
Prior art keywords
nozzle
gas
nozzles
glass
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8771494A
Other languages
Japanese (ja)
Inventor
Shigeru Emori
滋 江森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujikura Ltd
Original Assignee
Fujikura Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujikura Ltd filed Critical Fujikura Ltd
Priority to JP8771494A priority Critical patent/JPH07277745A/en
Publication of JPH07277745A publication Critical patent/JPH07277745A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/012Manufacture of preforms for drawing fibres or filaments
    • C03B37/014Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
    • C03B37/01413Reactant delivery systems
    • C03B37/0142Reactant deposition burners
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00Other methods of shaping glass
    • C03B19/14Other methods of shaping glass by gas- or vapour- phase reaction processes
    • C03B19/1415Reactant delivery systems
    • C03B19/1423Reactant deposition burners
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2207/00Glass deposition burners
    • C03B2207/04Multi-nested ports
    • C03B2207/06Concentric circular ports
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2207/00Glass deposition burners
    • C03B2207/04Multi-nested ports
    • C03B2207/12Nozzle or orifice plates
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2207/00Glass deposition burners
    • C03B2207/20Specific substances in specified ports, e.g. all gas flows specified
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2207/00Glass deposition burners
    • C03B2207/20Specific substances in specified ports, e.g. all gas flows specified
    • C03B2207/22Inert gas details
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2207/00Glass deposition burners
    • C03B2207/20Specific substances in specified ports, e.g. all gas flows specified
    • C03B2207/24Multiple flame type, e.g. double-concentric flame
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2207/00Glass deposition burners
    • C03B2207/36Fuel or oxidant details, e.g. flow rate, flow rate ratio, fuel additives
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2207/00Glass deposition burners
    • C03B2207/42Assembly details; Material or dimensions of burner; Manifolds or supports

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Glass Melting And Manufacturing (AREA)
  • Manufacture, Treatment Of Glass Fibers (AREA)
  • Pre-Mixing And Non-Premixing Gas Burner (AREA)

Abstract

PURPOSE:To reduce labor required for newly determining and resetting the conditions in exchange by making it possible to exchange only a broken part when a nozzle is broken and, accordingly, reducing the influence by the individual difference in exchange. CONSTITUTION:A concentric-circle double tube nozzle 10 for introducing a raw material gas and six concentric-circle double tube nozzles 20 for generating oxygen-hydrogen flame are independently detachably attached to a frame 30 so that the nozzles 20 may surround the nozzle 10 existing at the central position. Silicon tetrachloride gas and argon gas are allowed to blow off through the central tube 11 of the nozzle 10 for introducing a raw material gas and argon gas is allowed to blow off through the outside tube 12. Oxygen gas is allowed to blow off through the respective central tubes 21 of six nozzles 20 for generating oxygen-hydrogen flame and hydrogen gas is allowed to blow off through the outside tubes 22.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、気相反応によってガ
ラス微粒子を生成するバーナーの改良に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an improvement in a burner which produces glass particles by a gas phase reaction.

【0002】[0002]

【従来の技術】光ファイバのガラス母材を作製するため
のVAD法などでは、酸水素火炎中に四塩化硅素などの
ガラス原料ガスを導入して加水分解反応によってガラス
(二酸化硅素)の微粒子を生成し、これを堆積させる。
その火炎を発生させ、加水分解反応を生じさせるために
バーナーが用いられる。このバーナーに酸素および水素
の燃焼ガスと、キャリアガスに運ばれる原料ガスが送り
込まれる。従来のバーナーは、石英ガラス等で形成され
た同心円状の多重管ノズル構造となっており、その中心
のノズルからキャリアガスを含んだ原料ガスを噴出し、
その外側の多重管のそれぞれより、中心側から外側に向
かって順に、水素ガス、シールガス(アルゴン、窒素、
ヘリウム等)、酸素ガスが吹き出される。
2. Description of the Related Art In the VAD method or the like for producing a glass preform for optical fibers, glass (silicon dioxide) fine particles are produced by introducing a glass raw material gas such as silicon tetrachloride into an oxyhydrogen flame and performing a hydrolysis reaction. Produce and deposit this.
A burner is used to generate the flame and cause a hydrolysis reaction. Combustion gases of oxygen and hydrogen and a raw material gas carried as a carrier gas are fed into the burner. A conventional burner has a concentric multi-tube nozzle structure made of quartz glass or the like, and a raw material gas containing a carrier gas is ejected from a nozzle at the center of the burner.
From each of the outer multiple tubes, hydrogen gas and seal gas (argon, nitrogen,
Helium, etc.) and oxygen gas are blown out.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、従来の
このような同心多重管ノズル構造のガラス生成用バーナ
ーでは、交換時に新たに火炎条件を求めて、ガス供給量
などを再設定する必要があるという問題がある。すなわ
ち、バーナーは使用を続けていると酸水素火炎の熱のた
めにノズルの先端部を中心に削れが起こり、火炎温度に
変化が現われ、安定したガラス微粒子堆積を行なうこと
ができなくなってしまうが、従来の同心多重管ノズル構
造のガラス生成用バーナーではこのような場合にはバー
ナー全体を交換せざるを得ず、そうするとバーナー間で
の固体差が無視できないので、ガラス微粒子堆積につい
てより正確な制御を行なうために、新たなバーナーにつ
いて新たに火炎条件を求めて、ガス供給量などを再設定
することになる。
However, in the conventional burner for producing glass having such a concentric multi-tube nozzle structure, it is necessary to newly set flame conditions at the time of replacement and reset the gas supply amount and the like. There's a problem. That is, if the burner continues to be used, the heat of the oxyhydrogen flame causes abrasion around the nozzle tip, which causes a change in flame temperature, making it impossible to perform stable glass particle deposition. In such a case, the conventional burner for glass production with the concentric multi-tube nozzle has no choice but to replace the entire burner, and the solid difference between the burners cannot be neglected. In order to perform the above, a new flame condition is newly obtained for the new burner, and the gas supply amount and the like are reset.

【0004】この発明は、上記に鑑み、破損したノズル
のみを部分的に交換することを可能とし、もって交換時
の固体差の影響を受けにくくし、交換時に新たに条件を
求めて再設定を行なう作業を軽減することができるよう
に改善でき、さらに火炎温度分布を任意にコントロール
することをも可能とする、ガラス生成用バーナーを提供
することを目的とする。
In view of the above, the present invention makes it possible to partially replace only a damaged nozzle, thereby making it difficult to be affected by the individual difference at the time of replacement, and resetting by newly finding a condition at the time of replacement. It is an object of the present invention to provide a burner for glass production, which can be improved so that the work to be performed can be reduced, and the flame temperature distribution can be controlled arbitrarily.

【0005】[0005]

【課題を解決するための手段】上記の目的を達成するた
め、この発明にかかるガラス生成用バーナーにおいて
は、ガラス原料ガスを噴出するための第1のノズルと、
該第1のノズルの周囲を取り囲むように配置される、複
数の独立した酸水素火炎発生のための第2のノズルと、
該第1、第2のノズルが上記の位置において取り外し可
能に保持される保持体とが備えられている。
In order to achieve the above object, in a burner for producing glass according to the present invention, a first nozzle for ejecting a glass raw material gas,
A second nozzle for generating a plurality of independent oxyhydrogen flames, which is arranged so as to surround the first nozzle;
And a holder for detachably holding the first and second nozzles at the above positions.

【0006】[0006]

【作用】第2のノズルは酸水素火炎発生のためのもので
あり、これが複数個、第1のノズルの周囲を取り囲むよ
うに配置されているので、酸水素火炎の輪が形成される
ことになり、その火炎の中心に第1のノズルから噴出さ
れたガラス原料ガスが導かれる。そのため、この酸水素
火炎中で加水分解反応が生じてガラス微粒子が生成され
る。これら第1、第2のノズルの各々はそれぞれ独立に
取り外し可能に保持体によって保持されているため、ど
れかのノズルが破損したとき、その破損したノズルのみ
を交換することができる。また、ガラス原料ガスを噴出
するための第1のノズルと複数の独立した酸水素火炎発
生のための第2のノズルとを備え、これらが独立である
ため、複数の酸水素火炎発生用ノズルの各々について酸
素ガス及び水素ガスの流量を別個に調整することにより
火炎温度分布を任意にコントロールすることが可能とな
る。
The second nozzle is for generating an oxyhydrogen flame, and since a plurality of the second nozzles are arranged so as to surround the periphery of the first nozzle, the ring of the oxyhydrogen flame is formed. Then, the glass raw material gas ejected from the first nozzle is guided to the center of the flame. Therefore, a hydrolysis reaction occurs in this oxyhydrogen flame to generate glass particles. Since each of the first and second nozzles is independently and detachably held by the holding body, when any nozzle is damaged, only the damaged nozzle can be replaced. In addition, a first nozzle for ejecting the glass raw material gas and a second nozzle for generating a plurality of independent oxyhydrogen flames are provided, and since these are independent, a plurality of oxyhydrogen flame generating nozzles are provided. The flame temperature distribution can be arbitrarily controlled by adjusting the flow rates of the oxygen gas and the hydrogen gas separately for each.

【0007】[0007]

【実施例】以下、この発明の好ましい一実施例について
図面を参照しながら詳細に説明する。図1に示すように
この発明にかかるガラス生成用バーナーは、複数のノズ
ルの集合体として構成されている。中心に位置するノズ
ル10は原料ガス導入用であり、その周囲を取り囲むよ
うに配置された6個のノズル20は酸水素火炎発生用で
ある。これら7個のノズルはいずれも同心円状の二重管
構造となっている。原料ガス導入用ノズル10の中心管
11からは四塩化硅素ガスとアルゴンガスが、その周囲
管12からはアルゴンガスがそれぞれ噴出する。酸水素
火炎発生用ノズル20の中心管21からは酸素ガスが、
その周囲管22からは水素ガスが吹き出される。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT A preferred embodiment of the present invention will now be described in detail with reference to the drawings. As shown in FIG. 1, the glass forming burner according to the present invention is configured as an assembly of a plurality of nozzles. The nozzle 10 located at the center is for introducing the raw material gas, and the six nozzles 20 arranged so as to surround the periphery thereof are for generating the oxyhydrogen flame. Each of these seven nozzles has a concentric double tube structure. A silicon tetrachloride gas and an argon gas are ejected from the central pipe 11 of the raw material gas introduction nozzle 10, and an argon gas is ejected from a peripheral pipe 12 thereof. Oxygen gas from the central tube 21 of the oxyhydrogen flame generation nozzle 20,
Hydrogen gas is blown out from the peripheral pipe 22.

【0008】これらのノズルの各管11、12、21、
22は石英ガラスのパイプにより形成されており、サイ
ズはたとえば、ノズル10の中心管11は内径2.0m
m、外径3.6mm、周囲管12は内径5.0mm、外
径6.6mm、ノズル20の中心管21は内径2.0m
m、外径3.6mm、周囲管22は内径10.0mm、
外径12.0mmとなっている。そして、これらノズル
10、20は適宜なフレーム30により保持されてお
り、個々独立に取り換え可能に構成されている。すなわ
ち、ここではノズル10、20はフレーム30に着脱自
在に嵌合されて保持されている。
The tubes 11, 12, 21, of these nozzles,
22 is formed of a quartz glass pipe. For example, the central tube 11 of the nozzle 10 has an inner diameter of 2.0 m.
m, outer diameter 3.6 mm, peripheral tube 12 has inner diameter 5.0 mm, outer diameter 6.6 mm, central tube 21 of nozzle 20 has inner diameter 2.0 m
m, outer diameter 3.6 mm, the peripheral tube 22 has an inner diameter 10.0 mm,
The outer diameter is 12.0 mm. The nozzles 10 and 20 are held by an appropriate frame 30 and are individually replaceable. That is, here, the nozzles 10 and 20 are detachably fitted and held in the frame 30.

【0009】酸水素火炎発生用ノズル20は、ここでは
6個使用され、これらが中心の原料ガス導入用ノズル1
0の周囲にリングをなすように配置されているので、従
来の同心円状の多重管構造のノズルと同様に、リング型
になった酸水素火炎が形成される。そして、その酸水素
火炎の中心に向けて、中心に配置された原料ガス導入用
ノズルからガラスの原料ガスが噴出されるため、酸水素
火炎の中心にガラス原料ガスが導入されることになり、
従来と同様に、加水分解反応によるガラス微粒子の生成
が良好な効率で行なわれる。
Six oxyhydrogen flame generating nozzles 20 are used here, and these are the main source gas introducing nozzles 1.
Since it is arranged so as to form a ring around 0, a ring-shaped oxyhydrogen flame is formed as in the conventional concentric multi-tube structure nozzle. Then, toward the center of the oxyhydrogen flame, since the raw material gas of the glass is ejected from the raw material gas introduction nozzle arranged in the center, the glass raw material gas will be introduced into the center of the oxyhydrogen flame,
As in the conventional case, the generation of glass fine particles by the hydrolysis reaction is performed with good efficiency.

【0010】このガラス生成用バーナーを長期間使用し
ていると、その先端に発生する酸水素火炎の熱で先端部
が溶融して徐々に削れてくる。このような削れ等の破損
が生じたときは、破損したノズルのみをフレーム30か
ら取り外し、新規なノズルと交換して、この新規なノズ
ルをフレーム30に装着することで対処する。これによ
り、バーナー全体を交換することを避け、その一部を交
換するにとどめることができるため、交換前後における
ガス噴出特性の差が少なくなる。このように固体差の影
響を僅少に抑えることができるので、交換後新たに各ガ
スの流量条件等を求める必要性と、それにしたがって各
ガスの流量条件を再設定する必要性とを軽減することが
可能となる。
When this glass-forming burner is used for a long period of time, the heat of the oxyhydrogen flame generated at the tip of the burner melts the tip and gradually scrapes it. When such damage such as scraping occurs, only the damaged nozzle is removed from the frame 30, replaced with a new nozzle, and the new nozzle is mounted on the frame 30. As a result, it is possible to avoid replacing the entire burner and replace only a part thereof, so that the difference in gas ejection characteristics before and after replacement is reduced. In this way, the influence of the solid difference can be suppressed to a small degree, so that it is possible to reduce the need to newly determine the flow rate conditions of each gas after replacement and the need to reset the flow rate conditions of each gas accordingly. Is possible.

【0011】また、原料ガス導入用ノズル10の周囲に
複数の独立の酸水素火炎発生用ノズル20を配置してい
るため、これら複数の酸水素火炎発生用ノズル20の各
々について酸素ガス及び水素ガスの流量を別個に調整す
ることができ、これにより従来では不可能であった火炎
温度分布を任意にコントロールする道が開け、ガラス微
粒子の堆積速度や堆積効率、あるいは屈折率分布などの
制御性等における改善が可能である。
Further, since a plurality of independent oxyhydrogen flame generating nozzles 20 are arranged around the raw material gas introducing nozzle 10, oxygen gas and hydrogen gas are provided for each of the plurality of oxyhydrogen flame generating nozzles 20. It is possible to adjust the flow rate of each separately, which opens a way to arbitrarily control the flame temperature distribution, which was impossible in the past, and to control the deposition rate and efficiency of glass particles, the refractive index distribution, etc. Can be improved.

【0012】[0012]

【発明の効果】以上説明したように、この発明のガラス
生成用バーナーによれば、ノズルの先端が破損したとき
など、ノズルの一部に不都合が生じたとき、バーナー全
体を交換することなく、その一部のノズルのみを交換す
ることで対処できる。そのため交換前後におけるガス噴
出特性の差が少なくなって、交換後新たに各ガスの流量
条件等を求めたり、それにしたがって各ガスの流量条件
を再設定したりする作業が軽減できる。
As described above, according to the burner for producing glass of the present invention, when a trouble occurs in a part of the nozzle such as when the tip of the nozzle is damaged, the burner is not replaced as a whole. This can be dealt with by replacing only some of the nozzles. Therefore, the difference in the gas ejection characteristics before and after the replacement is reduced, and the work of newly determining the flow rate condition of each gas after the replacement and resetting the flow rate condition of each gas accordingly can be reduced.

【図面の簡単な説明】[Brief description of drawings]

【図1】この発明の一実施例にかかるガラス生成用バー
ナーの模式的な斜視図。
FIG. 1 is a schematic perspective view of a glass forming burner according to an embodiment of the present invention.

【符号の説明】[Explanation of symbols]

10 原料ガス導入用ノズル 11 原料ガス導入用ノズルの中心管 12 原料ガス導入用ノズルの周囲管 20 酸水素火炎発生用ノズル 21 酸水素火炎発生用ノズルの中心管 22 酸水素火炎発生用ノズルの周囲管 30 フレーム 10 Nozzle for introducing raw material gas 11 Central pipe for nozzle for introducing raw material gas 12 Peripheral pipe for nozzle for introducing raw material gas 20 Nozzle for generating oxyhydrogen flame 21 Central pipe for nozzle for generating oxyhydrogen flame 22 Surrounding nozzle for generating oxyhydrogen flame Tube 30 frame

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 // G02B 6/00 356 A ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification number Office reference number FI technical display location // G02B 6/00 356 A

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 ガラス原料ガスを噴出するための第1の
ノズルと、該第1のノズルの周囲を取り囲むように配置
される、複数の独立した酸水素火炎発生のための第2の
ノズルと、該第1、第2のノズルが上記の位置において
取り外し可能に保持される保持体とを有することを特徴
とするガラス生成用バーナー。
1. A first nozzle for ejecting a glass source gas, and a second nozzle for surrounding a plurality of independent oxyhydrogen flames, which is arranged so as to surround the first nozzle. And a holder for detachably holding the first and second nozzles at the above-mentioned positions.
JP8771494A 1994-03-31 1994-03-31 Burner for formation of glass Pending JPH07277745A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8771494A JPH07277745A (en) 1994-03-31 1994-03-31 Burner for formation of glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8771494A JPH07277745A (en) 1994-03-31 1994-03-31 Burner for formation of glass

Publications (1)

Publication Number Publication Date
JPH07277745A true JPH07277745A (en) 1995-10-24

Family

ID=13922578

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8771494A Pending JPH07277745A (en) 1994-03-31 1994-03-31 Burner for formation of glass

Country Status (1)

Country Link
JP (1) JPH07277745A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007069772A1 (en) * 2005-12-14 2007-06-21 Osamu Hirota Injection flame burner and furnace and method for generating flame
JP2008175473A (en) * 2007-01-19 2008-07-31 Osamu Hirota Superhigh temperature pyrolysis equipment

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007069772A1 (en) * 2005-12-14 2007-06-21 Osamu Hirota Injection flame burner and furnace and method for generating flame
JP2007163044A (en) * 2005-12-14 2007-06-28 Osamu Hirota Injection flame burner, furnace and flame generation method
JP4645972B2 (en) * 2005-12-14 2011-03-09 修 廣田 Injection flame burner and furnace, and flame generation method
US8419421B2 (en) 2005-12-14 2013-04-16 Osamu Hirota Injection flame burner and furnace equipped with same burner and method for generating flame
JP2008175473A (en) * 2007-01-19 2008-07-31 Osamu Hirota Superhigh temperature pyrolysis equipment
JP4595944B2 (en) * 2007-01-19 2010-12-08 修 廣田 Ultra-high temperature pyrolysis equipment

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