JPH0645024A - Anisotropic conductive adhesive film - Google Patents
Anisotropic conductive adhesive filmInfo
- Publication number
- JPH0645024A JPH0645024A JP4195198A JP19519892A JPH0645024A JP H0645024 A JPH0645024 A JP H0645024A JP 4195198 A JP4195198 A JP 4195198A JP 19519892 A JP19519892 A JP 19519892A JP H0645024 A JPH0645024 A JP H0645024A
- Authority
- JP
- Japan
- Prior art keywords
- adhesive
- anisotropic conductive
- electrode
- electrodes
- circuit substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002313 adhesive film Substances 0.000 title claims description 13
- 239000002245 particle Substances 0.000 claims abstract description 18
- 239000012790 adhesive layer Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 5
- 239000011347 resin Substances 0.000 claims abstract description 5
- 239000010419 fine particle Substances 0.000 claims description 21
- 239000000155 melt Substances 0.000 claims description 4
- 239000000758 substrate Substances 0.000 abstract description 19
- 239000000853 adhesive Substances 0.000 abstract description 13
- 230000001070 adhesive effect Effects 0.000 abstract description 13
- 239000010408 film Substances 0.000 abstract description 10
- 239000010409 thin film Substances 0.000 abstract description 5
- 239000004973 liquid crystal related substance Substances 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 239000011889 copper foil Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229920006332 epoxy adhesive Polymers 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
Landscapes
- Non-Insulated Conductors (AREA)
- Liquid Crystal (AREA)
- Multi-Conductor Connections (AREA)
- Coupling Device And Connection With Printed Circuit (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、液晶表示モジュール等
の電極と相対峙させた回路基板の電極を接続固定するの
に用いられる異方導電性接着フィルムに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an anisotropic conductive adhesive film used for connecting and fixing an electrode of a liquid crystal display module or the like and an electrode of a circuit board which is placed opposite to the electrode.
【0002】[0002]
【従来の技術】近年、電子部品の小型化、薄型化、高性
能化が進んでおり、それと共に経済的な高密度実装技術
の開発が活発に行われている。例えば、液晶表示モジュ
ール(LCD)とTAB(Tape Automated Bonding)もし
くはFPC(Flexible PrintedCircuit)基板等の微細電
極同士を接続するに際し、異方導電性接着フィルムを相
対峙させた電極間に挟み、加熱加圧することにより複数
の電極を一括接続する方法が行われつつある。2. Description of the Related Art In recent years, electronic parts have become smaller, thinner, and have higher performance, and along with this, economical high-density mounting technology has been actively developed. For example, when connecting fine electrodes such as a liquid crystal display module (LCD) and a TAB (Tape Automated Bonding) or FPC (Flexible Printed Circuit) substrate, an anisotropic conductive adhesive film is sandwiched between the electrodes, and heated. A method of collectively connecting a plurality of electrodes by applying pressure is being used.
【0003】[0003]
【発明が解決しようとする課題】近年、液晶表示モジュ
ール等の高精細化が進み、従来の電極ピッチ200μm
(5本/mm)程度から100μ以下(10本/mm以
上)が要求されてきている。これに伴い、異方導電性接
着フィルムも従来の電極間の電気的接続と接着のみでな
く、導電性微粒子の凝集による電極間ショートに対して
も特性の向上が求められている。従来の方法では接続時
の熱と圧力により回路基板の電極下の導電性微粒子を含
んだ樹脂層が溶融し、回路基板の電極間スペースに流動
し、液晶表示モジュール等の電極と回路基板の電極が導
電性微粒子により電気的接続が得られていたが、回路基
板の電極間スペースに流入した接着剤に含まれる導電性
微粒子が特に樹脂だまりや流動先端等に凝集し、これよ
り電極間がショートするといった問題があった。In recent years, as the definition of liquid crystal display modules has become higher and higher, the conventional electrode pitch is 200 μm.
From about (5 lines / mm) to 100 μ or less (10 lines / mm or more) is required. Along with this, the anisotropic conductive adhesive film is required not only to have conventional electrical connection and adhesion between electrodes but also to have improved characteristics against short circuit between electrodes due to aggregation of conductive fine particles. In the conventional method, the resin layer containing conductive particles under the electrodes of the circuit board is melted by the heat and pressure at the time of connection and flows into the space between the electrodes of the circuit board, and the electrodes of the liquid crystal display module and the electrodes of the circuit board. However, the conductive particles contained in the adhesive that flowed into the space between the electrodes on the circuit board aggregated especially in the resin pool or the flow front, which caused a short circuit between the electrodes. There was a problem of doing.
【0004】[0004]
【課題を解決するための手段】本発明はかかる課題を解
決するためになされた。本発明者らは本課題を解決する
ために異方導電性接着フィルムによる接続プロセスにつ
いて詳細に検討した。現在、実際に供試されている異方
導電性接着フィルムは、略々20μm程度の膜厚をもつ
エポキシ系等の樹脂中に5〜10μm程度の導電性微粒
子を分散させたものが多い。これを液晶表示モジュール
等の基板上に形成された薄膜電極(ITO,Al等)と
TAB、FPC等の回路基板の電極との間に挟持し、両
基板の電極の位置合わせを行った後、熱圧着をするプロ
セスが一般的である。このとき回路基板の電極は略々1
8〜35μm厚さの銅箔にスズ等のメッキを施したもの
が多用されているが、その電極間は銅箔がエッチアウト
されて空洞部となっている第1図に本発明の、第2図に
従来例の場合について概略を示したが、熱圧着時は回路
基板3の電極部分4接する接着剤にまず熱が伝わり溶融
する。加圧によってこの溶融した接着剤は、含まれてい
る導電性微粒子と共に回路基板の空洞部5へと流動して
いく。加圧が進み回路基板の電極部分4と表示モジュー
ルの基板1上の薄膜電極2との距離が導電性微粒子の粒
径と同じになると粒子は両電極間の加圧力により電極間
に保持され、接着剤のみが回路基板の電極間空洞部5に
流動する。The present invention has been made to solve the above problems. The present inventors have studied in detail the connection process using an anisotropic conductive adhesive film in order to solve this problem. Many of the anisotropic conductive adhesive films that are actually tested at present are ones in which conductive fine particles of about 5 to 10 μm are dispersed in an epoxy resin or the like having a film thickness of about 20 μm. After sandwiching this between a thin film electrode (ITO, Al, etc.) formed on a substrate such as a liquid crystal display module and an electrode of a circuit substrate such as TAB, FPC, etc., the electrodes on both substrates are aligned, The process of thermocompression bonding is common. At this time, the electrode of the circuit board is about 1
A copper foil having a thickness of 8 to 35 μm plated with tin or the like is often used, but the copper foil is etched out between the electrodes to form a cavity. FIG. 2 shows an outline of the case of the conventional example. At the time of thermocompression bonding, heat is first transferred to the adhesive which contacts the electrode portion 4 of the circuit board 3 and melts. The pressure-sensitive adhesive melts into the cavity 5 of the circuit board together with the conductive particles contained therein. When the pressure is increased and the distance between the electrode portion 4 of the circuit board and the thin film electrode 2 on the substrate 1 of the display module becomes the same as the particle diameter of the conductive fine particles, the particles are held between the electrodes due to the pressure applied between the electrodes. Only the adhesive flows into the interelectrode cavity 5 of the circuit board.
【0005】従って、従来方法では圧着初期から両電極
間の距離が導電性微粒子の粒径と同じになるまで回路基
板の電極間空洞に流入した導電性微粒子の凝集が電極間
ショートの原因になっていることが分かる。特に、電極
間空洞部の流動先端等にこの凝集が多いことから、加圧
初期、換言すれば異方導電性接着フィルムの回路基板側
に接する部分に含まれている導電性微粒子が問題である
ことが明らかとなった。そこで、本発明者らは、回路基
板に接する側は導電性微粒子を含まない接着剤層である
2槽構成の異方導電性接着フィルムを用いることで所望
の目的を達成することを見出した。この時、導電性微粒
子を含まない接着剤層の方が、接続時の温度に於ける溶
融粘度が異方導電性フィルム本体の溶融粘度より低いこ
とが重要である。なぜならば、本発明を達成するために
は、接続時に導電性微粒子を含まない接着剤層が先に回
路基板の電極間スペースに流動しなければならないから
である。もし異方導電性フィルム本体の方が溶融粘度が
低い場合には、表示基板に接する側からの流動が起こ
り、好ましくない。また、上記接続メカニズムにより異
方導電性フィルム本体の膜厚を導電性微粒子の粒径と略
々同一にすれば導電性微粒子の回路基板の電極間ペース
への流入は一切なく、電極間は当初のフィルムの導電性
微粒子の分散状態が保持されるので、本発明の完全な実
施が可能となる。 なお、接着剤の種類や導電粒子の
径、種類等は上記の説明に用いたものに限定されないこ
とは本発明の趣旨を見れば明確である。Therefore, in the conventional method, the agglomeration of the conductive fine particles that have flowed into the interelectrode cavity of the circuit board from the initial stage of pressure bonding until the distance between both electrodes becomes equal to the particle diameter of the conductive fine particles causes a short circuit between the electrodes. I understand that. In particular, since there is a large amount of this aggregation at the flow tips of the inter-electrode cavities, etc., the conductive fine particles contained in the initial stage of pressing, in other words, in the portion in contact with the circuit board side of the anisotropic conductive adhesive film is a problem. It became clear. Therefore, the present inventors have found that a desired object can be achieved by using an anisotropic conductive adhesive film having a two-chamber structure in which the side in contact with the circuit board is an adhesive layer containing no conductive fine particles. At this time, it is important that the adhesive layer containing no conductive fine particles has a lower melt viscosity at the temperature of connection than the melt viscosity of the anisotropic conductive film body. This is because in order to achieve the present invention, the adhesive layer containing no conductive fine particles must first flow into the inter-electrode space of the circuit board at the time of connection. If the anisotropic conductive film body has a lower melt viscosity, flow from the side in contact with the display substrate occurs, which is not preferable. Further, if the thickness of the anisotropic conductive film body is made substantially equal to the particle diameter of the conductive fine particles by the above connection mechanism, there is no inflow of the conductive fine particles into the pace between the electrodes of the circuit board, and the distance between the electrodes is initially Since the dispersed state of the conductive fine particles of the film is maintained, the present invention can be completely carried out. Note that it is clear from the point of view of the present invention that the type of adhesive, the diameter and type of conductive particles are not limited to those used in the above description.
【0006】[0006]
【実施例】エポキシ系接着剤Aに導電性微粒子として平
均粒径が10μmのNi,Auメッキを施したプラスチ
ック粒子を2vol%含んだ厚さ10μの接着フィルム
を離型フィルム上に流延成形し、その上に導電性微粒子
を含まないエポキシ系接着剤Bを15μm流延成形して
2層の異方導電性接着フィルムを作成した。接着剤Aと
接着剤Bの160℃での粘度を硬化剤を除いて測定した
ところ接着剤Aは接着剤Bの粘度の1.8倍であった。
これを接着剤Aが表示基板側に配置されるように、ガラ
ス基板上にITO電極が70μmピッチで形成された表
示基板と、75μmポリイミドフィルム上に25μの銅
箔(Snメッキ品)の電極が70μmピッチで形成され
たFPC回路基板の間に挟み、160℃、20kg/c
m2 、20secの熱圧着条件で接続した。EXAMPLE An adhesive film having a thickness of 10 μ and containing 2 vol% of plastic particles plated with Ni and Au having an average particle size of 10 μm as conductive fine particles on an epoxy adhesive A is cast on a release film. Then, an epoxy-based adhesive B containing no conductive fine particles was cast thereon to a thickness of 15 μm to form a two-layer anisotropic conductive adhesive film. When the viscosities of the adhesive A and the adhesive B at 160 ° C. were measured without the curing agent, the adhesive A was 1.8 times the viscosity of the adhesive B.
A display substrate having ITO electrodes formed on a glass substrate at a pitch of 70 μm and a 25 μm copper foil (Sn plated product) electrode on a 75 μm polyimide film are provided so that the adhesive A is disposed on the display substrate side. It is sandwiched between FPC circuit boards formed with a 70 μm pitch, 160 ° C., 20 kg / c
m 2 Connection was performed under thermocompression bonding conditions of 20 sec.
【0007】比較のため、エポキシ系接着剤Aに℃微粒
子として、平均粒径が10μmのNi,Auメッキを施
したプラスチック粒子を2vol%含んだ厚さ25μの
接着フィルムを離型フィルム上に流延成形し、実施例に
用いた表示基板とに挟持し、実施例と同条件で接続し
た。実施例、比較例、各々160本の電極をもつ基板5
枚について接続抵抗と回路間のショートを測定したとこ
ろ、接続抵抗は実施例、比較例共に同レベルの平均1.
6Ωであったが、回路間のショートは実施例では0であ
ったのが、比較例では5枚の基板共20〜50か所のシ
ョートが見られた。For comparison, an adhesive film having a thickness of 25 μ containing 2 vol% of plastic particles plated with Ni and Au having an average particle size of 10 μm as fine particles at 0 ° C. is applied to a release film as a fine particle on the epoxy adhesive A. It was stretched, sandwiched between the display substrates used in the examples, and connected under the same conditions as the examples. Example, Comparative Example, Substrate 5 with 160 Electrodes Each
When the connection resistance and the short circuit between the circuits were measured for each of the sheets, the connection resistance was the same level of 1.
Although it was 6Ω, the short circuit between the circuits was 0 in the example, but in the comparative example, a short circuit was observed at 20 to 50 places in all of the five substrates.
【0006】[0006]
【発明の効果】本発明によれば、高精細度の液晶表示モ
ジュールと回路基板の接続がショートの恐れなく行うこ
とができる。According to the present invention, a high-definition liquid crystal display module and a circuit board can be connected without fear of a short circuit.
【図1】本発明による接続時の様子を示す概略図。FIG. 1 is a schematic diagram showing a state at the time of connection according to the present invention.
【図2】比較のため示した従来例の場合の接続の様子を
示す概略図。FIG. 2 is a schematic diagram showing a connection state in the case of a conventional example shown for comparison.
1 表示モジュール基板 2 表示基板上の薄膜電極 3 回路基板 4 回路基板上の電極 5 回路基板上の電極間空洞部 6 導電性微粒子を含む接着剤層 7 導電性微粒子を含まない接着剤層 8 導電性微粒子 1 Display Module Substrate 2 Thin Film Electrode on Display Substrate 3 Circuit Board 4 Electrode on Circuit Board 5 Cavity between Electrodes on Circuit Board 6 Adhesive Layer Containing Conductive Fine Particles 7 Adhesive Layer Not Containing Conductive Fine Particles 8 Conductivity Fine particles
───────────────────────────────────────────────────── フロントページの続き (72)発明者 伊藤 達夫 茨城県下館市大字五所宮1150番地 日立化 成工業株式会社五所宮工場内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Tatsuo Ito 1150 Gozamiya, Shimodate City, Ibaraki Prefecture Gotomiya Plant, Hitachi Chemical Co., Ltd.
Claims (2)
散してなる異方導電性フィルムにおいて、前記異方導電
性フィルムの少なくとも片面に、前記絶縁性樹脂より相
対的に低い溶融粘度を有する接着剤層を設けたことを特
徴とする異方導電性接着フィルム。1. An anisotropic conductive film having conductive fine particles uniformly dispersed in an insulating resin, wherein at least one surface of the anisotropic conductive film has a melt viscosity relatively lower than that of the insulating resin. An anisotropic conductive adhesive film having an adhesive layer having the above.
粒子の粒径とほぼ同一である請求項1記載の異方導電性
接着フィルム。2. The anisotropic conductive adhesive film according to claim 1, wherein the thickness of the anisotropic conductive film is substantially the same as the particle size of the conductive fine particles.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4195198A JPH0645024A (en) | 1992-07-22 | 1992-07-22 | Anisotropic conductive adhesive film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4195198A JPH0645024A (en) | 1992-07-22 | 1992-07-22 | Anisotropic conductive adhesive film |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0645024A true JPH0645024A (en) | 1994-02-18 |
Family
ID=16337089
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4195198A Pending JPH0645024A (en) | 1992-07-22 | 1992-07-22 | Anisotropic conductive adhesive film |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0645024A (en) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11195860A (en) * | 1997-12-27 | 1999-07-21 | Canon Inc | Bonding member, multichip module with the bonding member and bonding method using the bonding member |
JP2000113919A (en) * | 1998-08-03 | 2000-04-21 | Sony Corp | Electrical connection device and electrically connecting method |
JP2000195584A (en) * | 1998-12-25 | 2000-07-14 | Sony Corp | Electrical connection device and electrical connection method |
JP2005200521A (en) * | 2004-01-15 | 2005-07-28 | Sony Chem Corp | Adhesive film and method of manufacturing adhesive film |
JP2007094412A (en) * | 2005-09-27 | 2007-04-12 | Samsung Sdi Co Ltd | Plasma display device |
JP2008071748A (en) * | 2006-08-16 | 2008-03-27 | Sony Chemical & Information Device Corp | Connecting method |
JP2008147473A (en) * | 2006-12-12 | 2008-06-26 | Matsushita Electric Ind Co Ltd | Electrode connection method and electrode connection structure |
JP2008300360A (en) * | 1995-02-07 | 2008-12-11 | Hitachi Chem Co Ltd | Connecting method of electrode |
JP2010009804A (en) * | 2008-06-25 | 2010-01-14 | Asahi Kasei E-Materials Corp | Anisotropic conductive adhesive sheet and fine connection structure |
WO2010058782A1 (en) * | 2008-11-20 | 2010-05-27 | ソニーケミカル&インフォメーションデバイス株式会社 | Connecting film, bonded body and method for manufacturing the bonded body |
JP2010278013A (en) * | 2008-06-26 | 2010-12-09 | Hitachi Chem Co Ltd | Resin film sheet, and electronic component |
JP2011070931A (en) * | 2009-09-25 | 2011-04-07 | Sekisui Chem Co Ltd | Anisotropic conductive material, manufacturing method of connection structure, and connection structure |
US8084083B2 (en) | 2003-12-04 | 2011-12-27 | Asahi Kasei Emd Corporation | Method for manufacturing an anisotropic conductive adhesive sheet |
US8247697B2 (en) | 2008-03-27 | 2012-08-21 | Sony Chemical & Information Device Corporation | Anisotropic conductive film, joined structure and method for producing the joined structure |
DE102012100535A1 (en) | 2012-01-23 | 2013-07-25 | Schott Solar Ag | Method for producing an electrically conductive contact on a solar cell |
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WO2019235589A1 (en) * | 2018-06-06 | 2019-12-12 | デクセリアルズ株式会社 | Method for manufacturing connector and connection method |
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-
1992
- 1992-07-22 JP JP4195198A patent/JPH0645024A/en active Pending
Cited By (32)
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JP2008300360A (en) * | 1995-02-07 | 2008-12-11 | Hitachi Chem Co Ltd | Connecting method of electrode |
JPH11195860A (en) * | 1997-12-27 | 1999-07-21 | Canon Inc | Bonding member, multichip module with the bonding member and bonding method using the bonding member |
JP2000113919A (en) * | 1998-08-03 | 2000-04-21 | Sony Corp | Electrical connection device and electrically connecting method |
JP2000195584A (en) * | 1998-12-25 | 2000-07-14 | Sony Corp | Electrical connection device and electrical connection method |
US8084083B2 (en) | 2003-12-04 | 2011-12-27 | Asahi Kasei Emd Corporation | Method for manufacturing an anisotropic conductive adhesive sheet |
JP2005200521A (en) * | 2004-01-15 | 2005-07-28 | Sony Chem Corp | Adhesive film and method of manufacturing adhesive film |
JP2007094412A (en) * | 2005-09-27 | 2007-04-12 | Samsung Sdi Co Ltd | Plasma display device |
JP2008071748A (en) * | 2006-08-16 | 2008-03-27 | Sony Chemical & Information Device Corp | Connecting method |
JP4648294B2 (en) * | 2006-12-12 | 2011-03-09 | パナソニック株式会社 | Electrode bonding method and electrode bonding structure |
JP2008147473A (en) * | 2006-12-12 | 2008-06-26 | Matsushita Electric Ind Co Ltd | Electrode connection method and electrode connection structure |
US8980043B2 (en) | 2008-03-27 | 2015-03-17 | Dexerials Corporation | Anisotropic conductive film, joined structure and method for producing the joined structure |
US8247697B2 (en) | 2008-03-27 | 2012-08-21 | Sony Chemical & Information Device Corporation | Anisotropic conductive film, joined structure and method for producing the joined structure |
JP2010009804A (en) * | 2008-06-25 | 2010-01-14 | Asahi Kasei E-Materials Corp | Anisotropic conductive adhesive sheet and fine connection structure |
JP2010278013A (en) * | 2008-06-26 | 2010-12-09 | Hitachi Chem Co Ltd | Resin film sheet, and electronic component |
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