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JPH06346255A - Treatment of surface of stainless steel - Google Patents

Treatment of surface of stainless steel

Info

Publication number
JPH06346255A
JPH06346255A JP13844893A JP13844893A JPH06346255A JP H06346255 A JPH06346255 A JP H06346255A JP 13844893 A JP13844893 A JP 13844893A JP 13844893 A JP13844893 A JP 13844893A JP H06346255 A JPH06346255 A JP H06346255A
Authority
JP
Japan
Prior art keywords
stock
stainless steel
treatment
subjected
dried
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP13844893A
Other languages
Japanese (ja)
Inventor
Hiroshi Kanamaru
弘志 金丸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hino Motors Ltd
Original Assignee
Hino Motors Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hino Motors Ltd filed Critical Hino Motors Ltd
Priority to JP13844893A priority Critical patent/JPH06346255A/en
Publication of JPH06346255A publication Critical patent/JPH06346255A/en
Pending legal-status Critical Current

Links

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  • Application Of Or Painting With Fluid Materials (AREA)
  • ing And Chemical Polishing (AREA)

Abstract

PURPOSE:To improve the wear resistance of stock and to prevent the aggregation of the stock by subjecting cleaned stainless steel stock to etching treatment, thereafter coating the surface with fluorinated resin, drying it and executing heating treatment. CONSTITUTION:The stock of stainless steel is cleaned, is thereafter immersed in a corrosive liq. such as a marble soln. and is subjected to etching treatment to form a recessed part of several mum on the surface of the stock, which is subjected to neutralizing treatment by NaOH or the like, is water-washed and is dried. Next, the surface of this stock is coated with fluorinated such as tetrafluoroethylene, which is dried and is subjected to heating treatment. In this way, the fluororesin infiltrates into the recessed part formed on the surface of the stock form a coating layer having good adhesion at a low temp. without generating strains, by which the service life of the stainless steel stock can remarkably be prolonged.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、ステンレス鋼の表面処
理方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a surface treatment method for stainless steel.

【0002】[0002]

【従来の技術】一般に、ステンレス鋼のような材料を利
用した摺動部材等の場合、耐摩耗性を向上し且つ凝着を
防ぐために、素材の表面にドライフィルム等のコーティ
ング処理を施したり、或いは、1000℃前後の加熱炉
内に生成化合物の成分を含む原料ガスを送り込み、Ti
C、TiN、Al23等の超硬質物質を2〜10μの厚
さに蒸着させる化学蒸着(Chemical Vapo
r Deposition)や、500℃前後の減圧炉
内で生成化合物のもとになる金属と反応ガスとをグロー
放電でイオン化し、その反応生成物であるTiC、Ti
N等を2〜10μの厚さに蒸着させる物理蒸着(Phy
sical Vapor Deposition)が行
われていた。
2. Description of the Related Art Generally, in the case of a sliding member using a material such as stainless steel, in order to improve wear resistance and prevent adhesion, the surface of the material is coated with a dry film or the like, Alternatively, the raw material gas containing the components of the produced compound is fed into a heating furnace at about 1000 ° C.
Chemical vapor deposition for depositing ultra-hard materials such as C, TiN, and Al 2 O 3 to a thickness of 2 to 10 μm (Chemical Vapor
Deposition) or a reaction gas such as TiC, Ti, which is a reaction product of a metal and a reaction gas, which are the bases of the generated compound, are ionized by glow discharge in a decompression furnace at about 500 ° C.
Physical vapor deposition (Phy) for depositing N or the like to a thickness of 2 to 10 μm.
The medical Vapor Deposition) was performed.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、ステン
レス鋼は常温下で表面に極薄い不働態被膜が生成されて
いるため、前述の如く素材の表面にドライフィルム等の
コーティング処理を施すのでは密着性が劣り、耐摩耗性
向上並びに凝着防止には不充分であり、又、化学蒸着や
物理蒸着のような処理では、素材の温度が1000℃前
後或いは500℃前後と高温になることから、歪み発生
の原因にもつながり、あまり好ましい処理方法であると
は言えなかった。
However, since an extremely thin passivation film is formed on the surface of stainless steel at room temperature at room temperature, if the surface of the material is coated with a dry film or the like as described above, the adhesion will be poor. Is insufficient to improve wear resistance and prevent adhesion, and in processes such as chemical vapor deposition and physical vapor deposition, the temperature of the material rises to around 1000 ° C or around 500 ° C, which causes strain. It was also a cause of the occurrence and was not a very preferable treatment method.

【0004】本発明は、斯かる実情に鑑み、耐摩耗性を
向上し得且つ凝着防止に有効なステンレス鋼の表面処理
方法を提供しようとするものである。
In view of the above situation, the present invention aims to provide a surface treatment method for stainless steel which can improve wear resistance and is effective in preventing adhesion.

【0005】[0005]

【課題を解決するための手段】本発明は、洗浄したステ
ンレス鋼の素材を腐食液中に浸漬するエッチング処理を
行い、中和処理し洗浄して乾燥させた後、フッ素樹脂を
表面に塗布して乾燥させ、加熱処理することを特徴とす
るものである。
According to the present invention, a cleaned stainless steel material is subjected to an etching treatment by immersing it in a corrosive liquid, neutralized, washed and dried, and then a fluororesin is applied to the surface. It is characterized in that it is dried by heating and heat-treated.

【0006】[0006]

【作用】従って、洗浄したステンレス鋼の素材を腐食液
中に浸漬するエッチング処理を行い、中和処理し洗浄し
て乾燥させた後、フッ素樹脂を表面に塗布して乾燥さ
せ、加熱処理すると、前記エッチング処理により素材の
表面に形成された数μの凹部にフッ素樹脂が入り込む形
となって、該フッ素樹脂によるコーティング層の素材に
対する密着性が良好となり、又、加熱処理も化学蒸着や
物理蒸着のような処理の場合に比べ低温で済むため、素
材に歪みが生ずる心配もない。
Therefore, when the washed stainless steel material is subjected to an etching treatment by immersing it in a corrosive liquid, neutralized, washed and dried, a fluororesin is applied to the surface and dried, and a heat treatment is performed. By the etching treatment, the fluororesin enters into the concave portions of several μ formed on the surface of the material, the adhesion of the coating layer by the fluororesin to the material is improved, and the heat treatment is performed by chemical vapor deposition or physical vapor deposition. Since the temperature is lower than that in the case of such treatment, there is no concern that the material will be distorted.

【0007】[0007]

【実施例】以下、本発明の実施例を図面を参照しつつ説
明する。
Embodiments of the present invention will be described below with reference to the drawings.

【0008】図1は本発明のステンレス鋼の表面処理方
法の一実施例を表わすものであり、先ず所定の摺動面粗
さに加工されたステンレス鋼の素材を洗浄した後、マー
ブル溶液等の腐食液中に約10分間浸漬するエッチング
処理を行い、カセイソーダ(NaOH)等の中和剤によ
り中和処理する。尚、前記マーブル溶液は、塩酸(HC
l)を20cc、水(H2O)を20cc、硫酸銅(C
uSO4)を4gの割合で混合したものである。
FIG. 1 shows an embodiment of the surface treatment method for stainless steel according to the present invention. First, a stainless steel material processed to have a predetermined sliding surface roughness is washed, and then a marble solution or the like is used. An etching treatment is performed by immersing it in a corrosive liquid for about 10 minutes, and a neutralizing agent such as caustic soda (NaOH) is used. The marble solution is hydrochloric acid (HC
l) 20 cc, water (H 2 O) 20 cc, copper sulfate (C
uSO 4 ) was mixed at a ratio of 4 g.

【0009】続いて、前記中和処理したステンレス鋼の
素材を水洗しつつブラッシングしてから乾燥させた後、
テトラフロロエチレン等のフッ素樹脂を表面にスプレイ
コーティングして乾燥させ、約260℃で約10分間加
熱処理する。
Next, after the neutralized stainless steel material is washed with water, brushed and dried,
A fluororesin such as tetrafluoroethylene is spray coated on the surface, dried, and heat-treated at about 260 ° C. for about 10 minutes.

【0010】この結果、前記エッチング処理により素材
の表面に形成された数μの凹部にテトラフロロエチレン
等のフッ素樹脂が入り込む形となって、該フッ素樹脂に
よるコーティング層の素材に対する密着性が良好とな
り、又、加熱処理も化学蒸着や物理蒸着のような処理の
場合に比べ低温で済むため、素材に歪みが生ずる心配も
ない。
As a result, the fluororesin such as tetrafluoroethylene enters into the recess of several μ formed on the surface of the material by the etching treatment, and the adhesion of the coating layer by the fluororesin to the material becomes good. In addition, since the heat treatment can be performed at a lower temperature than in the case of treatment such as chemical vapor deposition or physical vapor deposition, there is no fear that the material will be distorted.

【0011】こうして、素材の耐摩耗性を向上すること
ができると共に、素材の凝着を防止することが可能とな
り、素材の寿命を大幅に延長することができる。
In this way, the wear resistance of the material can be improved and the adhesion of the material can be prevented, and the life of the material can be greatly extended.

【0012】尚、本発明のステンレス鋼の表面処理方法
は、上述の実施例にのみ限定されるものではなく、本発
明の要旨を逸脱しない範囲内において種々変更を加え得
ることは勿論である。
The stainless steel surface treatment method of the present invention is not limited to the above-mentioned embodiments, and it goes without saying that various modifications can be made without departing from the scope of the present invention.

【0013】[0013]

【発明の効果】以上、説明したように本発明のステンレ
ス鋼の表面処理方法によれば、素材の耐摩耗性を向上し
得且つ素材の凝着を防止し得、素材の寿命を大幅に延長
することができるという優れた効果を奏し得る。
As described above, according to the surface treatment method for stainless steel of the present invention, the wear resistance of the material can be improved and the adhesion of the material can be prevented, and the life of the material can be greatly extended. The excellent effect of being able to do it can be produced.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例のフローチャート図である。FIG. 1 is a flowchart of an embodiment of the present invention.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 洗浄したステンレス鋼の素材を腐食液中
に浸漬するエッチング処理を行い、中和処理し洗浄して
乾燥させた後、フッ素樹脂を表面に塗布して乾燥させ、
加熱処理することを特徴とするステンレス鋼の表面処理
方法。
1. A stainless steel material that has been washed is subjected to an etching treatment by immersing it in a corrosive liquid, neutralized, washed and dried, and then a fluororesin is applied to the surface and dried.
A surface treatment method for stainless steel, which comprises heat treatment.
JP13844893A 1993-06-10 1993-06-10 Treatment of surface of stainless steel Pending JPH06346255A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13844893A JPH06346255A (en) 1993-06-10 1993-06-10 Treatment of surface of stainless steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13844893A JPH06346255A (en) 1993-06-10 1993-06-10 Treatment of surface of stainless steel

Publications (1)

Publication Number Publication Date
JPH06346255A true JPH06346255A (en) 1994-12-20

Family

ID=15222247

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13844893A Pending JPH06346255A (en) 1993-06-10 1993-06-10 Treatment of surface of stainless steel

Country Status (1)

Country Link
JP (1) JPH06346255A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006500974A (en) * 2002-06-28 2006-01-12 アルザ・コーポレーシヨン Transdermal drug delivery device with coated microprojections
JP2007291554A (en) * 2006-04-24 2007-11-08 Chuo Spring Co Ltd Colored wire rope and method for producing colored wire rope
KR100872891B1 (en) * 2007-02-21 2008-12-10 (주)삼영코넥 A method for preventing rust of stainless steel after welding
JP2012207295A (en) * 2011-03-30 2012-10-25 Nippon Steel & Sumikin Stainless Steel Corp Surface treated duplex stainless steel and method of manufacturing the same
CN104458511A (en) * 2014-12-01 2015-03-25 上海交通大学 Method for testing autstenitic grain size of steel bainite structure for nuclear pressure vessel
CN104483246A (en) * 2014-12-01 2015-04-01 上海交通大学 Method for displaying austenitic grain size of high-Cr heat resistant steel

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006500974A (en) * 2002-06-28 2006-01-12 アルザ・コーポレーシヨン Transdermal drug delivery device with coated microprojections
JP2007291554A (en) * 2006-04-24 2007-11-08 Chuo Spring Co Ltd Colored wire rope and method for producing colored wire rope
KR100872891B1 (en) * 2007-02-21 2008-12-10 (주)삼영코넥 A method for preventing rust of stainless steel after welding
JP2012207295A (en) * 2011-03-30 2012-10-25 Nippon Steel & Sumikin Stainless Steel Corp Surface treated duplex stainless steel and method of manufacturing the same
CN104458511A (en) * 2014-12-01 2015-03-25 上海交通大学 Method for testing autstenitic grain size of steel bainite structure for nuclear pressure vessel
CN104483246A (en) * 2014-12-01 2015-04-01 上海交通大学 Method for displaying austenitic grain size of high-Cr heat resistant steel

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