JPH06345464A - Mold for optical element molding, production thereof and method of molding optical element - Google Patents
Mold for optical element molding, production thereof and method of molding optical elementInfo
- Publication number
- JPH06345464A JPH06345464A JP13804093A JP13804093A JPH06345464A JP H06345464 A JPH06345464 A JP H06345464A JP 13804093 A JP13804093 A JP 13804093A JP 13804093 A JP13804093 A JP 13804093A JP H06345464 A JPH06345464 A JP H06345464A
- Authority
- JP
- Japan
- Prior art keywords
- molding
- optical element
- molding die
- die
- mold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B11/00—Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
- C03B11/06—Construction of plunger or mould
- C03B11/08—Construction of plunger or mould for making solid articles, e.g. lenses
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B2215/00—Press-moulding glass
- C03B2215/72—Barrel presses or equivalent, e.g. of the ring mould type
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、形状精度と面精度が優
れた、安価な光学素子成形型およびその製造方法および
光学素子製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an inexpensive optical element molding die having excellent shape accuracy and surface accuracy, a method of manufacturing the same, and a method of manufacturing an optical element.
【0002】[0002]
【従来の技術】従来、プレス成形により光学素子を製造
する場合、成形する光学材料をその軟化温度まで予備加
熱する。この予備加熱された光学材料を、プレス成形後
に、所定の光学素子表面と同一形状になるように加工さ
れた上型と下型の間に供給し、所定の温度と圧力で加圧
成形する方法が一般的であった。2. Description of the Related Art Conventionally, when an optical element is manufactured by press molding, an optical material to be molded is preheated to its softening temperature. A method of press-molding the preheated optical material, supplying it between an upper mold and a lower mold that are processed to have the same shape as the surface of a predetermined optical element, and pressing at a predetermined temperature and pressure. Was common.
【0003】このような光学素子をプレス成形するため
の成形型は、耐熱性と耐食性に優れた超硬金属材料を超
精密旋盤で高精度に研削加工して製作されていた。しか
し、このような精密研削加工は加工時間が長くなるとと
もに、加工途中に砥石が摩耗し、加工途中に砥石を交換
しなければならないなど、高精度な成形型を量産するに
は多くの問題があった。A molding die for press-molding such an optical element has been manufactured by highly accurately grinding a superhard metal material having excellent heat resistance and corrosion resistance with an ultraprecision lathe. However, such a precision grinding process requires a long machining time, and the grindstone wears during the machining, and the grindstone must be replaced during the machining.There are many problems in mass-producing high-precision molds. there were.
【0004】そこで、成形型材料にガラスを用い、ガラ
ス製成形型をプレス成形によって製作する方法(例えば
特開昭64−33022号公報)が注目されてきた。以
下に図面を参照しながら、従来のガラス製成形型につい
て説明する。図6に光学素子成形用型を作成するための
成形母型の構成を示す。図に示すように、成形型を作成
するための成形母型31,32とヒータを内蔵した加熱
リング33とで囲まれる空間に、光学素子成形用型に用
いるガラス素材30を置く。成形母型32の下面は平面
に、成形母型31の上面はプレス加工する光学素子の表
面形状に加工されている。加熱リング33により成形母
型31,32とガラス素材30をガラス素材30の軟化
温度付近まで十分加熱した後、成形母型31,32を押
圧して成形母型の表面形状をガラス素材30に転写し、
冷却して型からガラス成形型を取り出す。図7に成形さ
れた光学素子成形用ガラス成形型42の形状を示す。そ
の後、ガラス成形型42の成形表面には、例えば真空蒸
着法などの方法によって離型性皮膜を形成する。Therefore, a method of using glass as a molding die material and manufacturing a glass molding die by press molding (for example, Japanese Patent Laid-Open No. 64-33022) has attracted attention. A conventional glass mold will be described below with reference to the drawings. FIG. 6 shows a structure of a molding die for making an optical element molding die. As shown in the figure, a glass material 30 used for an optical element molding die is placed in a space surrounded by molding mother dies 31 and 32 for forming a molding die and a heating ring 33 containing a heater. The lower surface of the molding die 32 is processed into a flat surface, and the upper surface of the molding die 31 is processed into the surface shape of an optical element to be pressed. The molding dies 31, 32 and the glass material 30 are sufficiently heated by the heating ring 33 to near the softening temperature of the glass material 30, and then the molding dies 31, 32 are pressed to transfer the surface shape of the molding dies to the glass material 30. Then
Cool and remove the glass mold from the mold. FIG. 7 shows the shape of the glass molding die 42 for molding an optical element formed. After that, a mold-releasing film is formed on the molding surface of the glass molding die 42 by a method such as a vacuum deposition method.
【0005】図8にガラス成形型を用いた光学素子成形
装置の構成を示す。図に示すように、ガラス下型41と
ガラス上型42と加熱リング、いわゆる胴型43で囲ま
れる空間に光学素材40を置き、光学素材の軟化温度付
近まで加熱した後、加圧し、押圧したまま除冷し、光学
素子を取り出していた。FIG. 8 shows the configuration of an optical element molding apparatus using a glass molding die. As shown in the figure, the optical material 40 is placed in the space surrounded by the lower glass mold 41, the upper glass mold 42, and the heating ring, that is, the so-called body mold 43, heated to near the softening temperature of the optical material, and then pressed and pressed. It was cooled as it was, and the optical element was taken out.
【0006】[0006]
【発明が解決しようとする課題】しかし、このような従
来のガラス型成形装置および成形方法では、ガラス成形
型41,42は円筒状になる。成形されたガラス成形型
41,42は光学素子成形に先だって、離型被膜を表面
に形成されるが、そのとき形状が円筒型であるために滑
り易く、加工工程中の保持が困難になる。すなわち、真
空蒸着法で離型被膜を形成するには、蒸着源の上方に、
離型被膜形成面(光学素子成形面)を下向きにして水平
に保持する必要がある。そのため、例えばガラス成形型
の側面に保持用の切り欠き溝を形成し、この溝を利用し
て滑落を防ぎながら蒸着装置内にガラス成形型を固定す
ることが考えられる。しかし、多数のガラス成形型に真
空蒸着するには、ガラス成形型の固定に手間がかかり蒸
着工程の生産性が低下するという問題があった。However, in such a conventional glass molding apparatus and molding method, the glass molding dies 41 and 42 have a cylindrical shape. Prior to the optical element molding, the molded glass molding dies 41 and 42 are formed with a release coating on the surface. However, since the shape is cylindrical, they are slippery and difficult to hold during the working process. That is, in order to form a release coating by the vacuum vapor deposition method, above the vapor deposition source,
It is necessary to keep the release coating formation surface (optical element molding surface) facing downward and hold it horizontally. Therefore, for example, it is conceivable to form a notch groove for holding on the side surface of the glass molding die and use the groove to fix the glass molding die in the vapor deposition device while preventing sliding. However, when vacuum vapor deposition is performed on a large number of glass molding dies, there is a problem in that it takes time and effort to fix the glass molding dies and the productivity of the deposition process decreases.
【0007】また、ガラス成形型を用いて光学素子をプ
レス成形するときには、ガラス成形型を分解組立ステー
ジから成形ステージに移送するのに、ガラス成形型4
1,42の側面を挟持して保持するか、ガラス下型41
の下にプレートを挿入してガラス成形型41,42を移
送する方法がある。しかし、側面を挟持して移送すると
光学素子成形素材を保持具で損傷し易く、損傷された光
学素子成形素材を成形して作成された光学素子は傷が成
形後にも残留する。また、プレートに搭載して移送する
と、成形装置に設置するときに振動や衝撃により光学素
子成形素材が損傷されるという問題があった。When the optical element is press-molded using the glass molding die, the glass molding die 4 is used to transfer the glass molding die from the disassembling and assembling stage to the molding stage.
The side surfaces of 1, 42 are clamped and held, or the lower glass mold 41
There is a method in which a plate is inserted underneath to transfer the glass molding dies 41 and 42. However, if the optical element molding material is transported by sandwiching the side surface, the optical element molding material is easily damaged by the holder, and the optical element formed by molding the damaged optical element molding material remains with scratches even after molding. In addition, when mounted on a plate and transferred, there is a problem that the optical element molding material is damaged by vibration or impact when it is installed in the molding apparatus.
【0008】また、ガラス成形型41,42は円筒型で
あるため、成形工程中、特にプレス成形後の冷却工程に
おいてガラス成形型が41,42が胴型の内面に沿って
移動しやすいので、成形後の光学素子の厚みが一定せ
ず、光学性能がばらつくという問題があった。Further, since the glass molding dies 41 and 42 are cylindrical, the glass molding dies 41 and 42 easily move along the inner surface of the barrel mold during the molding process, particularly in the cooling process after press molding. The thickness of the optical element after molding was not constant, and there was a problem that the optical performance varied.
【0009】本発明はこのような課題を解決するもの
で、ガラス成形型のチャッキングが容易で、移送中に光
学素子成形素材が損傷されず、光学性能が一定でばらつ
きの少ない光学素子成形型およびその製造方法および光
学素子成形方法を提供することを目的とするものであ
る。The present invention solves such a problem, and the glass mold is easily chucked, the optical element molding material is not damaged during the transfer, and the optical performance is constant and the variation is small. And a manufacturing method thereof and an optical element molding method.
【0010】[0010]
【課題を解決するための手段】上記課題を解決するため
に本発明は、上成形型と下成形型とを摺動自在に内蔵す
る成形胴型とを備え、上下成形型と成形胴型で囲まれた
空間に光学素子素材を置き、光学素子素材を加熱して軟
化させ押圧成形する方法であって、上成形型および下成
形型はガラス材料を主体とし、光学素子の光学面を成形
するための所定の形状に加工された成形面を有する円筒
部または柱状部と、円筒部または柱状部の成形面と反対
側の端面に連結した鍔部をそれぞれ備え、光学素子の形
状に近似した形状に加工した光学面を有する上下加工型
により加熱加圧して成形型を形成するようにしたもので
ある。In order to solve the above-mentioned problems, the present invention comprises a forming cylinder mold in which an upper forming mold and a lower forming mold are slidably incorporated. A method of placing an optical element material in an enclosed space, heating the optical element material to soften it, and press-molding it. The upper molding die and the lower molding die are mainly glass materials, and the optical surface of the optical element is molded. A cylindrical portion or a columnar portion having a molding surface processed into a predetermined shape, and a collar portion connected to the end surface of the cylindrical portion or the columnar portion on the side opposite to the molding surface, each of which has a shape similar to the shape of the optical element. The mold is formed by heating and pressurizing with an upper and lower processing mold having an optical surface processed into the above.
【0011】また、上成形型および下成形型はガラス材
料を主体とし、光学素子の光学面を成形するための所定
の形状に加工された成形面を有する円筒部または柱状部
と、円筒部または柱状部の成形面と反対側の端面に連結
した鍔部をそれぞれ備え、光学素子の形状に近似した形
状に加工した光学面を有する上下加工型により加熱加圧
して上下成形型を形成し、上成形型と下成形型とを摺動
自在に成形胴型内に配置し、上下成形型と成形胴型で囲
まれた空間に光学素子素材を置き、光学素子素材を加熱
して軟化させ、上成形型を下降させ光学素子素材を押圧
成形する光学素子を製造するようにしたものである。The upper molding die and the lower molding die are mainly made of a glass material, and have a cylindrical portion or a columnar portion having a molding surface processed into a predetermined shape for molding the optical surface of the optical element, and the cylindrical portion or The upper and lower forming dies are formed by heating and pressurizing with the upper and lower processing dies each having a collar part connected to the end surface on the side opposite to the forming surface of the columnar part, and having an optical surface processed into a shape similar to the shape of the optical element. The mold and the lower mold are slidably arranged in the mold body, the optical element material is placed in the space surrounded by the upper and lower molds and the mold body, and the optical element material is heated to soften it. The optical element is manufactured by lowering the molding die and press-molding the optical element material.
【0012】[0012]
【作用】上記の構成と方法によれば、予め超硬鋼材を機
械加工して鍔部を有する加工型を作製しておき、この加
工型を用いて光学素子素材のガラス転移点より高いガラ
ス転移点を有するガラス素材を加熱下にプレス成形して
鍔部を有する成形型を作製する。光学素子素材をこの成
形型間に置き、ガラス転移点近傍の温度でプレス成形す
ることができる。また、本発明によれば、一対の加工型
を機械加工により製作し、この加工型を用いて成形型用
高融点ガラス成形型を成形することにより、多数のガラ
ス製成形型を作製できる。さらに、複数のガラス製成形
型を鍔部を挟持して搬送ロボットを用いて、加熱、成
形、冷却の各工程を移送し、自動機によりプレス成形を
連続的に行うことにより、精度の高い光学素子を大量に
均一に生産することができることとなる。According to the structure and method described above, a machining die having a collar portion is prepared by machining a cemented carbide material in advance, and using this machining die, the glass transition temperature higher than the glass transition point of the optical element material is used. A glass material having dots is press-molded under heating to form a mold having a collar portion. An optical element material can be placed between the molds and press-molded at a temperature near the glass transition point. Further, according to the present invention, a large number of glass molding dies can be manufactured by manufacturing a pair of working molds by machining and molding a high melting point glass molding mold for a molding mold using the working molds. In addition, a plurality of glass molds are sandwiched between the flanges, and the transfer robot is used to transfer the heating, molding, and cooling steps, and press molding is performed continuously by an automatic machine to ensure high-precision optics. It is possible to produce a large number of elements uniformly.
【0013】[0013]
【実施例】以下に本発明の一実施例の光学素子成形型お
よびその製造方法および光学素子成形方法を図面を参照
しながら説明する。図1(a)〜(e)に本実施例のガ
ラス成形型の製造装置の構成を示す。図1(a)に示す
ように、組立ステージ6A上に光学素子成形型(以下成
形型と略す)2を成形する成形母型(以下母型と略す)
となる下加工型3の上に平板状の成形型材料10aを載
置し、その後加工胴型5を成形型材料の外径に合わせて
挿入し、下端が下加工型3に当接するまで押圧する。平
板状の成形型材料10aは、上面の表面粗さを0.1μ
m以下に仕上げることが必要である。一方、ガラスの棒
材を応力割断することによってできた割断面は鏡面であ
るから、さらに鏡面加工する必要がない。従って、本実
施例では成形型材料として少なくとも割断面を上面に有
する円盤を使用した。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An optical element molding die according to an embodiment of the present invention, a method for manufacturing the same, and an optical element molding method will be described below with reference to the drawings. 1 (a) to 1 (e) show the configuration of a glass molding die manufacturing apparatus of this embodiment. As shown in FIG. 1A, a molding master mold (hereinafter abbreviated as a master mold) for molding an optical element molding mold (hereinafter abbreviated as a mold mold) 2 on an assembly stage 6A.
The flat plate-shaped molding die material 10a is placed on the lower working die 3 to be the following, and then the working barrel die 5 is inserted according to the outer diameter of the molding die material, and the lower end is pressed until it contacts the lower working die 3. To do. The plate-shaped molding die material 10a has a surface roughness of the upper surface of 0.1 μm.
It is necessary to finish to m or less. On the other hand, since the fractured surface formed by stress-breaking the glass rod material is a mirror surface, it is not necessary to further perform mirror surface processing. Therefore, in this example, a disk having at least a split cross section on its upper surface was used as the molding die material.
【0014】下加工型3は超硬鋼材で作成され、加工面
は平面研削盤により予め高精度に平面加工されている。
下加工型3の外径をロボットアームで挟持して、図1
(b)に示すように加工ステージ6Bに搬送する。加工
ステージ6Bにはヒータが内蔵されていて、予め所定の
温度に保たれている。成形型材料10aは光学素子素材
のガラス軟化温度よりも高い軟化温度を有することが必
要である。本実施例で用いる光学素子材料はSF8であ
り、ガラス転移点は420℃である。また、成形型材料
10aと10bにはガラス転移点が550℃であるBK
7を用いた。加工ステージ6Bの温度は750℃に設定
した。また、上ヒータブロック7Bはヒータを内蔵し、
加圧シリンダに連結されていて、上下に移動する。上ヒ
ータブロック7Bは770℃に設定した。The lower working die 3 is made of a cemented carbide steel, and the working surface is prefabricated with high precision by a surface grinder.
The outer diameter of the lower processing die 3 is clamped by the robot arm,
It is conveyed to the processing stage 6B as shown in (b). A heater is built in the processing stage 6B and is kept at a predetermined temperature in advance. The mold material 10a needs to have a softening temperature higher than the glass softening temperature of the optical element material. The optical element material used in this example is SF8, and the glass transition point is 420 ° C. Further, the molding die materials 10a and 10b have a BK having a glass transition point of 550 ° C.
7 was used. The temperature of the processing stage 6B was set to 750 ° C. Further, the upper heater block 7B has a built-in heater,
It is connected to a pressure cylinder and moves up and down. The upper heater block 7B was set to 770 ° C.
【0015】ここでは、先ず図2に示す成形型の鍔部1
1を形成する。加工ステージ6B上に搬送された下加工
型3は10分間予備加熱され、成形型材料10aを十分
加熱した後、上ヒータブロックを下降させ、加工胴型5
の上端面に当接させる。その後、3kg/cm2の圧力を加
え、加工胴型5の下端面が下加工型3の鍔部の上面に当
接するまで押圧する。加工ステージ6Bと図1(c)に
示す成形ステージ6Cの間には組立ロボット(図示せ
ず)が配置されている。図2に示す成形型10Aの円筒
部12を形成するために、この組立ロボットにより、成
形型材料10bをさきに鍔部が成形加工された成形型材
料10aの上に載置する。成形型材料10bは円柱形が
適当で、成形型材料10aと同様に、棒材を応力割断し
て作成した円柱形の材料を用いた。Here, first, the collar portion 1 of the molding die shown in FIG.
1 is formed. The lower working die 3 conveyed onto the working stage 6B is preheated for 10 minutes to sufficiently heat the forming die material 10a, and then the upper heater block is lowered to move the working die 5
Abut the upper end surface of. Thereafter, a pressure of 3 kg / cm 2 is applied, and the lower end surface of the working cylinder die 5 is pressed until it comes into contact with the upper surface of the flange portion of the lower working die 3. An assembly robot (not shown) is arranged between the processing stage 6B and the molding stage 6C shown in FIG. 1 (c). In order to form the cylindrical portion 12 of the forming die 10A shown in FIG. 2, the assembling robot places the forming die material 10b on the forming die material 10a whose brim portion is formed. A cylindrical shape is suitable for the molding die material 10b, and similarly to the molding die material 10a, a cylindrical material formed by stress-cutting a bar material was used.
【0016】成形型材料10bを成形型材料10aの上
に載置した後、組立ロボットにより上加工型4を加工胴
型5内に挿入して成形型材料10bの上面に当接させた
状態で図1(c)の成形ステージ6Cに移送する。上加
工型4は下加工型3と同様に超硬鋼材を用いていて、成
形面は完成時の光学素子の一方の面の形状と同一形状に
超高精度に予め加工されている。成形ステージ6Cは加
工ステージ6Bと同様に、予め750℃に、上ヒータブ
ロック7Cは770℃に加熱されている。成形ステージ
6Cに搬送した後、上ヒータブロック7Cを下降させ、
7分間予備加熱した後、4kg/cm2の圧力で3分間成形型
材料10bを加圧して、上加工型4の成形面の形状を成
形型材料10bに転写する。After the molding die material 10b is placed on the molding die material 10a, the upper working die 4 is inserted into the working barrel die 5 by the assembling robot and brought into contact with the upper surface of the molding die material 10b. It is transferred to the molding stage 6C of FIG. The upper working die 4 uses a cemented carbide steel as in the lower working die 3, and the forming surface is pre-machined with the same shape as the shape of one surface of the optical element at the time of completion with ultrahigh precision. Like the processing stage 6B, the molding stage 6C is preheated to 750 ° C. and the upper heater block 7C is preheated to 770 ° C. After conveying to the molding stage 6C, lower the upper heater block 7C,
After preheating for 7 minutes, the molding material 10b is pressed at a pressure of 4 kg / cm 2 for 3 minutes to transfer the shape of the molding surface of the upper working mold 4 to the molding material 10b.
【0017】次に、図1(d)に示す550℃に加熱し
た冷却ステージ6Dに搬送し上ヒータブロック7Dを接
触させる。10分後、成形型材料10bの温度がそのガ
ラス転移点である550℃に近くなったところで上ヒー
タブロック7Dを上昇させ、図1(e)に示す冷却ステ
ージ6Eに搬送する。10分間放置してから、下加工型
3の最外側をロボットアームで挟持して図1(a)に示
す型分解組立ステージ6Aに搬送し、加工型を分解して
下成形型10Aを取り出す。Next, it is conveyed to the cooling stage 6D heated to 550 ° C. shown in FIG. 1 (d) and brought into contact with the upper heater block 7D. After 10 minutes, when the temperature of the molding die material 10b becomes close to 550 ° C. which is its glass transition point, the upper heater block 7D is moved up and conveyed to the cooling stage 6E shown in FIG. 1 (e). After leaving it for 10 minutes, the outermost side of the lower working die 3 is sandwiched by a robot arm and conveyed to the die disassembling / assembling stage 6A shown in FIG. 1A, and the working die is disassembled to take out the lower shaping die 10A.
【0018】上記の成形型製造法で上成形型10Bも同
様に作製する。作製された成形型10A,10Bの成形
面は上下加工型3,4の成形面の形状と全くずれのない
形状が得られた。The upper molding die 10B is similarly manufactured by the above-described molding die manufacturing method. The molding surfaces of the molding dies 10A and 10B thus produced had a shape that was completely the same as the shapes of the molding surfaces of the upper and lower working dies 3 and 4.
【0019】なお、本実施例では円筒形の成形型につい
て説明したが、断面形状が楕円形、四角形あるいは菱型
の柱状部を鍔部に連結することも可能である。また、鍔
部の外形も柱状部と同様に形状を選択することができ
る。In the present embodiment, the cylindrical mold is explained, but it is also possible to connect a columnar part having an elliptical, quadrangular or rhombic cross section to the collar part. Further, the outer shape of the collar portion can be selected similarly to the columnar portion.
【0020】上記の成形型の製造装置および製造方法に
よれば、10分タクトで成形型の量産が可能である。成
形加工した成形型はまとめて成形面へ保護膜を形成する
ことができる。例えば、スパッタ装置を用いてPt−I
r系合金膜を形成するが、鍔部を利用した搬送冶具を用
いて、成膜前の脱脂洗浄やスパッタ装置への設置を機械
的に安全に行うことができ、成形面を損傷することを防
ぐことができる。According to the above-described molding die manufacturing apparatus and manufacturing method, the molding die can be mass-produced in 10 minutes. A protective film can be collectively formed on the molding surface of the molding dies that have been molded. For example, using a sputtering device, Pt-I
Although an r-based alloy film is formed, it is possible to mechanically and safely perform degreasing and cleaning before film formation and installation on a sputtering device by using a transfer jig that uses the collar, and to prevent damage to the forming surface. Can be prevented.
【0021】次に、上記の成形型を用いた光学素子製造
方法を説明する。図3に本実施例の光学素子製造装置の
構成を示す。図3に示すように、任意の高さに調整した
成形胴型22の内側に、ガラス材料で構成された上成形
型10Bと下成形型10Aを挿入し、両成形型の軸ずれ
を防ぎながら所定の厚みの光学素子を成形する。上成形
型10Bと下成形型10Aと成形胴型22により囲まれ
た空間に、図4に示す円柱形状の光学素子素材1をその
両端面が上、下成形型10A,10Bに接するように円
柱軸を縦向きに設置する。成形胴型22は光学素子素材
1の線膨張係数よりも大きいガラス材料で作製されてい
る。本実施例では、線膨張係数が100〜300℃で1
50×10-7/℃のガラス材料を使用した。上ヒータブ
ロック23はシリンダロッドに連結されていて、エアー
シリンダによって上ヒータブロック23を介して上成形
型10Bに所定の圧力が加えられる。光学素子素材1は
直径3mm、長さ4mmの光学ガラスSF8で、ガラス転移
点420℃、屈服温度454℃、軟化温度550℃、線
膨張係数は100〜300℃で90×10-7/℃であ
る。側面はセンタレス加工により仕上げられていて、表
面荒さは3μmである。上下の光学面は研磨により鏡面
に仕上げられていて、表面荒さは0.1μmである。光
学素子素材をプレス成形し、成形が完了するまでの総変
形寸法は2mmである。Next, a method of manufacturing an optical element using the above molding die will be described. FIG. 3 shows the configuration of the optical element manufacturing apparatus of this embodiment. As shown in FIG. 3, an upper molding die 10B and a lower molding die 10A made of a glass material are inserted inside the molding barrel die 22 adjusted to an arbitrary height to prevent axial misalignment of both molding dies. An optical element having a predetermined thickness is molded. In a space surrounded by the upper molding die 10B, the lower molding die 10A, and the molding barrel die 22, a cylindrical optical element material 1 shown in FIG. 4 is formed into a cylinder so that both end surfaces thereof are in contact with the upper molding die 10A and the lower molding die 10B. Install the shaft vertically. The molding barrel die 22 is made of a glass material having a coefficient of linear expansion larger than that of the optical element material 1. In this embodiment, the linear expansion coefficient is 100 to 300 ° C.
A glass material of 50 × 10 −7 / ° C. was used. The upper heater block 23 is connected to a cylinder rod, and a predetermined pressure is applied to the upper molding die 10B via the upper heater block 23 by an air cylinder. The optical element material 1 is an optical glass SF8 having a diameter of 3 mm and a length of 4 mm, a glass transition point of 420 ° C., a yielding temperature of 454 ° C., a softening temperature of 550 ° C., and a linear expansion coefficient of 100 × 300 ° C. at 90 × 10 −7 / ° C. is there. The side surface is finished by centerless processing, and the surface roughness is 3 μm. The upper and lower optical surfaces are mirror-finished by polishing, and the surface roughness is 0.1 μm. The total deformation dimension is 2 mm until the optical element material is press-molded and the molding is completed.
【0022】次に、光学素子の成形工程を説明する。成
形型を成形機内の成形ステージ24上に移送し、上ヒー
タブロック23を上成形型10Bの上面に当接させる。
このとき、成形型内には上下成形型10A,10Bのそ
れぞれの成形面と光学素子1の端面との間に密閉空間X
ができている。上ヒータブロック23と成形ステージ2
4は光学素子成形素材1が成形型の押圧力により変形し
やすい温度まで加熱する必要がある。しかし、加熱温度
が高すぎると所定の形状精度に成形できなくなるので、
一般に、光学素子成形素材1の屈服温度と軟化温度の間
の温度に設定される。Next, the molding process of the optical element will be described. The forming die is transferred onto the forming stage 24 in the forming machine, and the upper heater block 23 is brought into contact with the upper surface of the upper forming die 10B.
At this time, in the molding die, a closed space X is formed between the molding surfaces of the upper and lower molding dies 10A and 10B and the end surface of the optical element 1.
Is made. Upper heater block 23 and molding stage 2
In No. 4, it is necessary to heat the optical element molding material 1 to a temperature at which it is easily deformed by the pressing force of the molding die. However, if the heating temperature is too high, it will not be possible to mold to the specified shape accuracy, so
Generally, the temperature is set between the bending temperature and the softening temperature of the optical element molding material 1.
【0023】本実施例では上ヒータブロックと下ヒータ
ブロックの温度は540℃に設定した。この温度は、従
来の超硬鋼材を母材とする成形型よりもやや高めであ
る。これは、成形型がガラスで構成されているので、熱
伝導率が小さいためである。光学素子素材1の温度が5
40℃近傍まで達したときに、光学素子素材の粘度は1
010ポアズになっている。次に、上ヒータブロックを押
圧し上成形型10Bにより光学素子素材1をプレスす
る。このときの圧力は2kg/mm2以上が望ましい。成形工
程は2段階で行われる。総変形寸法2mmのうち、まず
1.6mmを加圧成形する。加圧開始後0.8mm変形した
ところで一旦加圧をやめ、上ヒータブロック23を上昇
させて上成形型10Bから離す。加圧をやめる直前、正
圧が加わっていた密閉空間Xは常圧に戻る。加圧を止め
たときでも成形型と光学素子素材は接触状態を保ってい
る。In this embodiment, the temperature of the upper heater block and the lower heater block is set to 540 ° C. This temperature is slightly higher than that of a conventional mold having a base material of cemented carbide. This is because the mold is made of glass and has a low thermal conductivity. The temperature of the optical element material 1 is 5
When it reaches around 40 ℃, the viscosity of the optical element material becomes 1
It is 0 10 poise. Next, the upper heater block is pressed and the optical element material 1 is pressed by the upper molding die 10B. The pressure at this time is preferably 2 kg / mm 2 or more. The molding process is performed in two stages. Of the total deformation size of 2 mm, 1.6 mm is first pressure-molded. After the start of pressurization, when 0.8 mm is deformed, the pressurization is stopped once, and the upper heater block 23 is lifted and separated from the upper molding die 10B. Immediately before stopping the pressurization, the closed space X to which the positive pressure was applied returns to the normal pressure. Even when the pressure is stopped, the mold and the optical element material are kept in contact with each other.
【0024】次に、再び上ヒータブロックを下降し、上
成形型に当接させる。この工程では密閉空間Xは消失し
ている。ついで、加熱を止め冷却しながら加圧を開始
し、総変形量0.4mmまで成形する。成形型の温度が4
00℃になったときに加圧を終了し、上ヒータブロック
23を上昇させる。総変形量を成形した後の冷却工程で
は、光学素子は温度の降下とともに収縮するが、成形胴
型22も同様に収縮する。光学素子と成形胴型両者の収
縮量は、温度差tに対して、縦方向の長さLと線膨張係
数Aともに成形胴型の方が大きい。収縮量はt×L×A
で表されるが、成形胴型の収縮量の方が光学素子の収縮
量より大きい。そのため、冷却工程中、特に光学素子の
ガラス転移点近傍までの間では、上下成形型の成形面は
光学素子表面に押圧密着しているので、成形された光学
素子の形状が崩れることはない。冷却工程終了後、上下
成形型10A,10Bを成形ステージ24から取り出し
常温まで冷却する。完全に冷却後、成形型を開き、光学
素子を取り出す。成形された光学素子は設計通りの形状
精度を有し、光学的特性も満足していた。Next, the upper heater block is lowered again and brought into contact with the upper mold. In this step, the closed space X has disappeared. Then, the heating is stopped and the pressurization is started while cooling, so that the total deformation amount is 0.4 mm. Mold temperature is 4
When the temperature reaches 00 ° C., the pressurization is terminated and the upper heater block 23 is raised. In the cooling step after the total deformation amount is molded, the optical element shrinks as the temperature drops, but the molding cylinder die 22 also shrinks. The amount of shrinkage of both the optical element and the forming cylinder mold is larger in the forming cylinder mold with respect to the temperature difference t, both in the longitudinal length L and the linear expansion coefficient A. Shrinkage is t × L × A
The shrinkage amount of the molding cylinder is larger than that of the optical element. Therefore, during the cooling process, especially until the vicinity of the glass transition point of the optical element, the molding surfaces of the upper and lower molding dies are pressed and brought into close contact with the surface of the optical element, so that the shape of the molded optical element does not collapse. After the cooling process is completed, the upper and lower molds 10A and 10B are taken out from the molding stage 24 and cooled to room temperature. After cooling completely, the mold is opened and the optical element is taken out. The molded optical element had the shape accuracy as designed and satisfied the optical characteristics.
【0025】成形型は3000ショット程度で成形面が
荒れてきて使用不能になる。しかし、上記の成形型製造
方法により非常に安価に大量生産できるので、光学素子
の量産には支障はない。The molding die becomes unusable after about 3000 shots because the molding surface becomes rough. However, mass production of the optical element can be carried out very inexpensively by the above-mentioned molding die manufacturing method, and thus there is no problem in mass production of optical elements.
【0026】(表1)に各種の成形型材料と光学素子素
材の組合せ、ガラス転移点、100ショット成形後の成
形型表面の変化を示す。(表1)ではガラス材料名はシ
ョット社の材料名を用いた。この組合せではNo.3の
み成形型の形状が変化したが、他の組合せでは変化はな
かった。以上の結果から、成形型材料と光学素子素材の
ガラス転移点の差は50℃以上が必要であることがわか
る。Table 1 shows combinations of various mold materials and optical element materials, glass transition points, and changes in the mold surface after 100 shots molding. In (Table 1), the material name of Schott was used as the glass material name. In this combination No. Only in No. 3, the shape of the mold changed, but in other combinations, there was no change. From the above results, it is understood that the difference in glass transition point between the mold material and the optical element material needs to be 50 ° C. or higher.
【0027】[0027]
【表1】 [Table 1]
【0028】なお、本実施例では成形型表面に保護膜を
形成する例について説明したが、保護膜の代わりに、光
学素子素材の表面に予め離型材を塗布しておいても同様
の効果が得られる。また、本実施例では、光学素子素材
にSF8を用いた例について説明したが、本発明はこれ
に限定されるものではなく、他の光学素子素材、例えば
ポリメチルメタアクリレート(PMMA)などの有機高
分子材料を用いても同様の効果が得られる。In this embodiment, an example in which a protective film is formed on the surface of the molding die has been described, but the same effect can be obtained even if a mold release material is applied in advance on the surface of the optical element material instead of the protective film. can get. Further, in the present embodiment, an example in which SF8 is used as the optical element material has been described, but the present invention is not limited to this, and other optical element materials such as organic materials such as polymethylmethacrylate (PMMA) can be used. The same effect can be obtained by using a polymer material.
【0029】また、本実施例では成形型材料と光学素子
素材のガラス転移点の差が120℃である例について説
明したが、本発明はこれに限定されるものではなく、成
形型材料のガラス転移点は可能な限り高い方が望まし
く、さらに硬度が高く、耐摩耗性に優れるものが望まし
い。In this embodiment, the difference in glass transition point between the mold material and the optical element material is 120 ° C., but the present invention is not limited to this, and the glass of the mold material is used. It is desirable that the transition point is as high as possible, and it is desirable that the transition point is high and the abrasion resistance is excellent.
【0030】[0030]
【発明の効果】以上の実施例の説明から明かなように本
発明によれば、予め超硬鋼材を機械加工して加工型を作
製しておき、この加工型を用いて光学素子素材のガラス
転移点より高いガラス転移点を有するガラス素材を加熱
下にプレス成形して成形型を作製する。光学素子素材を
この成形型間に置き、ガラス転移点近傍の温度でプレス
成形する。この方法によれば、一対の加工型を準備する
ことにより、多数のガラス製成形型を作製できる。さら
に、ガラス製成形型を用いてガラス製光学素子を大量に
均一に生産することができる。As is apparent from the above description of the embodiments of the present invention, according to the present invention, a working die is prepared by machining a cemented steel material in advance, and the working die is used to form a glass of an optical element material. A glass material having a glass transition point higher than the transition point is press-molded under heating to produce a mold. An optical element material is placed between the molds and press-molded at a temperature near the glass transition point. According to this method, a large number of glass molding dies can be produced by preparing a pair of working dies. Further, it is possible to uniformly produce a large number of glass optical elements using the glass mold.
【図1】(a)〜(e)は本発明の一実施例の成形型の
製造方法を示す断面図1A to 1E are cross-sectional views showing a method for manufacturing a mold according to an embodiment of the present invention.
【図2】同下成形型の構成を示す断面図FIG. 2 is a cross-sectional view showing the structure of the lower molding die.
【図3】同光学素子成形装置の構成を示す断面図FIG. 3 is a sectional view showing the configuration of the optical element molding apparatus.
【図4】同光学素子素材の形状を示す斜視図FIG. 4 is a perspective view showing the shape of the optical element material.
【図5】同光学素子の構成を示す断面図FIG. 5 is a sectional view showing the structure of the optical element.
【図6】従来の成形型製造装置の構成を示す断面図FIG. 6 is a cross-sectional view showing the configuration of a conventional molding die manufacturing apparatus.
【図7】同母型の構成を示す断面図FIG. 7 is a sectional view showing the structure of the mother mold.
【図8】同光学素子成形装置の構成を示す断面図FIG. 8 is a cross-sectional view showing the configuration of the optical element molding apparatus.
1 光学素子素材 2 成形型 3 下加工型 4 上加工型 5 加工胴型 6A 型分解組立ステージ 6B 加工ステージ 6C 成形ステージ 6D,6E 冷却ステージ 7B,7C,7D 上ヒータブロック 10a,10b 成形型材料 10A 下成形型 10B 上成形型 11 鍔部 12 円筒部 22 成形胴型 23 上ヒータブロック 24 成形ステージ X 密閉空間 1 Optical Element Material 2 Mold 3 Lower Machining 4 Upper Machining 5 Machining Mold 6A Mold Disassembly and Assembly Stage 6B Machining Stage 6C Molding Stage 6D, 6E Cooling Stages 7B, 7C, 7D Upper Heater Block 10a, 10b Molding Material 10A Lower mold 10B Upper mold 11 Collar part 12 Cylindrical part 22 Mold body 23 Upper heater block 24 Molding stage X Closed space
Claims (15)
する成形胴型とを備え、前記上下成形型と成形胴型で囲
まれた空間に光学素子素材を置き、前記光学素子素材を
加熱して軟化させ押圧成形する構成であって、前記上成
形型および前記下成形型は、光学素子の光学面を成形す
るための所定の形状に加工された成形面を有する円筒部
または柱状部と、前記円筒部または前記柱状部の成形面
と反対側の端面に連結した鍔部をそれぞれ備え、光学素
子素材を押圧成形する光学素子成形型。1. An optical element material, comprising: a molding barrel mold in which an upper molding mold and a lower molding mold are slidably contained, wherein an optical element material is placed in a space surrounded by the upper and lower molding molds and the molding cylinder mold. A structure for heating and softening a material to press-mold it, wherein the upper molding die and the lower molding die have a cylindrical portion having a molding surface processed into a predetermined shape for molding an optical surface of an optical element, or An optical element molding die comprising a columnar portion and a collar portion connected to an end surface of the cylindrical portion or the columnar portion on the side opposite to the molding surface, and press-molding an optical element material.
した後、円筒部または柱状部を形成する請求項1記載の
光学素子成形型。2. The optical element molding die according to claim 1, wherein the upper molding die and the lower molding die first form a collar portion and then form a cylindrical portion or a columnar portion.
材のガラス転移点より高く、かつ、50℃を下限とする
ガラス転移点温度差を有する請求項1記載の光学素子成
形型。3. The optical element molding die according to claim 1, wherein the glass transition point of the molding die material is higher than the glass transition point of the optical element material, and the glass transition point temperature difference has a lower limit of 50 ° C.
料と、円筒部または柱状部を形成する円柱状材料とを備
えた請求項1記載の光学素子成形型。4. The optical element molding die according to claim 1, wherein the molding die material comprises a flat plate-shaped material forming a collar portion and a columnar material forming a cylindrical portion or a columnar portion.
たは円柱状の材料である請求項1記載の光学素子成形
型。5. The optical element molding die according to claim 1, wherein the molding die material is a flat plate-shaped or columnar material having a split cross section.
する成形胴型とを備え、前記上下成形型と成形胴型で囲
まれた空間に光学素子素材を置き、前記光学素子素材を
加熱して軟化させ押圧成形する方法であって、前記上成
形型および前記下成形型はガラス材料を主体とし、光学
素子の光学面を成形するための所定の形状に加工された
成形面を有する円筒部または柱状部と、前記円筒部また
は前記柱状部の成形面と反対側の端面に連結した鍔部を
それぞれ備え、光学素子の形状に近似した形状に加工し
た光学面を有する上下加工型により加熱加圧して成形型
を形成する光学素子成形型の製造方法。6. An optical element material is provided, which comprises a molding barrel that slidably houses an upper molding die and a lower molding die, and an optical element material is placed in a space surrounded by the upper and lower molding dies and the molding barrel. A method of heating and softening a material to press-mold it, wherein the upper molding die and the lower molding die are mainly made of a glass material, and a molding surface processed into a predetermined shape for molding an optical surface of an optical element. Vertical processing having a cylindrical portion or a columnar portion having a and a collar portion connected to the end surface on the opposite side of the molding surface of the cylindrical portion or the columnar portion, and having an optical surface processed into a shape similar to the shape of the optical element A method for manufacturing an optical element molding die, which comprises heating and pressurizing the mold to form a molding die.
した後、円筒部または柱状部を形成する請求項6記載の
光学素子成形型の製造方法。7. The method of manufacturing an optical element molding die according to claim 6, wherein the upper molding die and the lower molding die first form a collar portion and then form a cylindrical portion or a columnar portion.
材のガラス転移点より高く、かつ、50℃を下限とする
ガラス転移点温度差を有する請求項6記載の光学素子成
形型の製造方法。8. The method for producing an optical element molding die according to claim 6, wherein the glass transition point of the molding die material is higher than the glass transition point of the optical element material and has a glass transition point temperature difference of 50 ° C. as a lower limit. .
状材料と、円筒部または柱状部を形成する円柱状材料と
を用いる請求項6記載の光学素子成形型の製造方法。9. The method for manufacturing an optical element molding die according to claim 6, wherein a flat plate-shaped material forming a collar portion and a columnar material forming a cylindrical portion or a columnar portion are used as the molding die material.
板状または円柱状の材料を用いる請求項6記載の光学素
子成形型の製造方法。10. The method for producing an optical element molding die according to claim 6, wherein a flat plate-shaped or columnar material having a split cross section is used as the molding die material.
を主体とし、光学素子の光学面を成形するための所定の
形状に加工された成形面を有する円筒部または柱状部
と、前記円筒部または前記柱状部の成形面と反対側の端
面に連結した鍔部をそれぞれ備え、光学素子の形状に近
似した形状に加工した光学面を有する上下加工型により
加熱加圧して上下成形型を形成し、前記上成形型と前記
下成形型とを摺動自在に成形胴型内に配置し、前記上下
成形型と成形胴型で囲まれた空間に光学素子素材を置
き、前記光学素子素材を加熱して軟化させ、前記上成形
型を下降させ光学素子素材を押圧成形する光学素子成形
方法。11. The upper molding die and the lower molding die are mainly made of a glass material, and a cylindrical portion or a columnar portion having a molding surface processed into a predetermined shape for molding an optical surface of an optical element, and the cylindrical portion. Alternatively, the upper and lower molding dies are formed by heating and pressing with a vertical processing die having a collar portion connected to the end surface on the side opposite to the molding surface of the columnar portion and having an optical surface processed into a shape similar to the shape of the optical element. The upper molding die and the lower molding die are slidably arranged in a molding barrel die, an optical element material is placed in a space surrounded by the upper and lower molding die and the molding barrel die, and the optical element material is heated. Then, the optical element molding method is performed in which the optical element material is softened, and the upper molding die is lowered to press-mold the optical element material.
請求項11記載の光学素子成形方法。12. The method for forming an optical element according to claim 11, wherein a barrel die mainly made of a glass material is used.
素材のガラス転移点より高く、かつ、50℃を下限とす
るガラス転移点温度差を有する請求項11記載の光学素
子成形方法。13. The method for molding an optical element according to claim 11, wherein the glass transition point of the molding die material is higher than the glass transition point of the optical element material, and the glass transition point temperature difference has a lower limit of 50 ° C.
用いる請求項11記載の光学素子成形方法。14. The optical element molding method according to claim 11, wherein a transparent organic polymer is used as the optical element material.
ラス材料の線膨張係数が上下成形型材料の線膨張係数よ
り大きいガラス材料を用いる請求項11記載の光学素子
成形方法。15. The optical element molding method according to claim 11, wherein the molding barrel is mainly made of a glass material, and a glass material having a linear expansion coefficient of the glass material larger than those of the upper and lower molding materials is used.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13804093A JP3203402B2 (en) | 1993-06-10 | 1993-06-10 | Optical element molding die, method of manufacturing the same, and optical element molding method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13804093A JP3203402B2 (en) | 1993-06-10 | 1993-06-10 | Optical element molding die, method of manufacturing the same, and optical element molding method |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH06345464A true JPH06345464A (en) | 1994-12-20 |
JP3203402B2 JP3203402B2 (en) | 2001-08-27 |
Family
ID=15212622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13804093A Expired - Fee Related JP3203402B2 (en) | 1993-06-10 | 1993-06-10 | Optical element molding die, method of manufacturing the same, and optical element molding method |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3203402B2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6514444B1 (en) | 1999-04-02 | 2003-02-04 | Suzuka Fuji Xerox Co., Ltd. | Method of manufacturing a molded plastic article and a glass molding plastics |
KR100827003B1 (en) * | 2005-11-29 | 2008-05-02 | 키니크 컴퍼니 | Axial symmetric molding glass lens and method for manufacturing an axial symmetric molding glass lens |
JP2019127425A (en) * | 2018-01-26 | 2019-08-01 | Hoya株式会社 | Molding tool made of glass |
JP2022107291A (en) * | 2021-01-08 | 2022-07-21 | Hoya株式会社 | Manufacturing method of glass molding tool and manufacturing method of optical element |
-
1993
- 1993-06-10 JP JP13804093A patent/JP3203402B2/en not_active Expired - Fee Related
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6514444B1 (en) | 1999-04-02 | 2003-02-04 | Suzuka Fuji Xerox Co., Ltd. | Method of manufacturing a molded plastic article and a glass molding plastics |
KR100827003B1 (en) * | 2005-11-29 | 2008-05-02 | 키니크 컴퍼니 | Axial symmetric molding glass lens and method for manufacturing an axial symmetric molding glass lens |
KR100827002B1 (en) * | 2005-11-29 | 2008-05-02 | 키니크 컴퍼니 | Mold assembly for an axial symmetric molding glass lens and method for manufacturing a mold assembly for an axial symmetric molding glass lens |
JP2019127425A (en) * | 2018-01-26 | 2019-08-01 | Hoya株式会社 | Molding tool made of glass |
JP2022107291A (en) * | 2021-01-08 | 2022-07-21 | Hoya株式会社 | Manufacturing method of glass molding tool and manufacturing method of optical element |
Also Published As
Publication number | Publication date |
---|---|
JP3203402B2 (en) | 2001-08-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4895585A (en) | Method of manufacturing lens elements | |
JPH0366256B2 (en) | ||
WO2003023458A2 (en) | Multiple lens molding system and method | |
KR20100015588A (en) | Method of producing glass molding product and mold press molding device | |
JP3886022B2 (en) | Method and apparatus for producing glass molded body | |
EP0463463B1 (en) | Method of manufacturing optical element | |
JPH0431328A (en) | Mold structure for forming optical element and press-molding method | |
JPH06345464A (en) | Mold for optical element molding, production thereof and method of molding optical element | |
JP4559784B2 (en) | Optical element manufacturing method | |
JP5021196B2 (en) | Mold press mold, optical element manufacturing method, and concave meniscus lens | |
JP2000095532A (en) | Press-formed optical element, its production, die for press-forming optical element and device for press- forming optical element | |
JP4094210B2 (en) | Manufacturing method of glass optical element and molding die for glass optical element used therefor | |
JP4426910B2 (en) | Mold press mold, optical element manufacturing method, and mold press lens | |
JPH07330347A (en) | Method for forming optical element | |
JP3587499B2 (en) | Method for manufacturing glass molded body | |
JP2001270724A (en) | Optical lens and metal mold for forming the same | |
JPH0146453B2 (en) | ||
JPS6346010B2 (en) | ||
JP2621956B2 (en) | Optical element molding method | |
JP2000247653A (en) | Metal mold for forming optical element and optical element | |
JPH01298034A (en) | Production of optical glass element | |
JPH1160251A (en) | Formation of optical element | |
JP5244575B2 (en) | Optical element manufacturing method | |
JP4473692B2 (en) | Manufacturing method of molded products | |
JPH02196039A (en) | Method for molding glass optical device |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
LAPS | Cancellation because of no payment of annual fees |