JPH06126889A - Method for coating metal plate with fluororesin film by burying print pattern - Google Patents
Method for coating metal plate with fluororesin film by burying print patternInfo
- Publication number
- JPH06126889A JPH06126889A JP4317675A JP31767592A JPH06126889A JP H06126889 A JPH06126889 A JP H06126889A JP 4317675 A JP4317675 A JP 4317675A JP 31767592 A JP31767592 A JP 31767592A JP H06126889 A JPH06126889 A JP H06126889A
- Authority
- JP
- Japan
- Prior art keywords
- fluororesin film
- metal plate
- film
- pattern
- rough surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Laminated Bodies (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
Abstract
Description
【０００１】[0001]
【利用分野】印刷模様を透明のフッ素樹脂フィルムによ
り保護したフッ素樹脂フィルムを金属板に被覆する方法
で、ガスコンロなどの厨房用、また建物の内装材用に用
いられる。[Field of application] A method of coating a metal plate with a fluororesin film whose printed pattern is protected by a transparent fluororesin film, which is used for kitchens such as gas stoves and interior materials for buildings.
【０００２】[0002]
【従来技術】本出願人はフッ素樹脂フィルムを金属板に
被覆する方法について相当数の出願をしたが、そのいづ
れも印刷模様を表面に透視せしめ、意匠性を向上せしめ
る点については考えられなかった。2. Description of the Related Art The applicant of the present invention has filed a considerable number of applications for coating a fluororesin film on a metal plate, but none of them has been considered to improve the design by making the printed pattern visible on the surface. .
【０００３】[0003]
【技術的手段】本発明は印刷模様を埋設して、フッ素樹
脂フィルムを金属板に被覆する次の３発明を包含する。The present invention includes the following three inventions of embedding a printed pattern and coating a fluororesin film on a metal plate.
【０００４】第１発明：金属板ｍの表面に粗面ｒ０を形
成した後、該粗面ｒ０上に印刷模様ｐｒを印刷した後、
被覆するフッ素樹脂フィルムＦｆの融点以上に該粗面ｒ
０を加熱した後、フッ素樹脂フィルムＦｆを粗面ｒ０に
熱融着せしめる方法。First invention: After forming a rough surface r0 on the surface of the metal plate m, printing a print pattern pr on the rough surface r0,
Rough surface r above the melting point of the fluororesin film Ff to be coated
After heating 0, the fluororesin film Ff is heat-sealed to the rough surface r0.
【０００５】第２発明：金属板ｍの表面に粗面ｒ１を形
成した後、被覆するフッ素樹脂フィルムＦｆの融点以上
に加熱し、Second invention: After the rough surface r1 is formed on the surface of the metal plate m, it is heated above the melting point of the fluororesin film Ff to be coated,
【０００６】一方フッ素樹脂フィルムＦｆ裏面にコロナ
放電処理して粗面ｒ２を形成した後、印刷模様ｐｒを印
刷した後、金属板ｍの粗面ｒ１にフッ素樹脂フィルムＦ
ｆの裏面の粗面ｒ２を熱溶融せしめる方法。On the other hand, after the corona discharge treatment is applied to the rear surface of the fluororesin film Ff to form the rough surface r2, the printed pattern pr is printed, and then the fluororesin film F is formed on the rough surface r1 of the metal plate m.
A method of heat-melting the rough surface r2 of the back surface of f.
【０００７】第３発明：金属板ｍの表面に予め粗面ｒ３
を形成した後、該粗面ｒ３を加熱しておき、Third invention: A rough surface r3 is previously formed on the surface of the metal plate m.
After forming, the rough surface r3 is heated,
【０００８】一方、複層フッ素樹脂フィルムＦｆ３の下
側フィルムＦｆ１の表面にコロナ放電処理により粗面ｒ
２を形成した後、印刷模様ｐｒを印刷し、On the other hand, the surface of the lower film Ff1 of the multi-layer fluororesin film Ff3 is roughened by corona discharge treatment.
After forming 2, print pattern pr is printed,
【０００９】この印刷模様ｐｒを印刷した下側フィルム
Ｆｆ１の表面を、下側フィルムＦｆ１と融点が等しいか
あるいは高い上側フィルムＦｆ２とを接着して、複層フ
ッ素樹脂フィルムＦｆ３を形成し、The surface of the lower film Ff1 on which the printed pattern pr is printed is adhered to the upper film Ff2 having a melting point equal to or higher than that of the lower film Ff1 to form a multi-layer fluororesin film Ff3,
【００１０】前記複層フッ素樹脂フィルムＦｆ３の下側
フィルムＦｆ１の下面側を金属板ｍの加熱した粗面ｒ３
に熱融着する方法。On the lower surface side of the lower film Ff1 of the multi-layer fluororesin film Ff3, the roughened surface r3 of the metal plate m is heated.
The method of heat fusion to.
【００１１】[0011]
【作用】第１〜第３発明とも金属板ｍあるいはフッ素樹
脂フィルムにコロナ放電により、印刷用粗面を形成した
ので、模様ｐｒが金属板ｍあるいはフッ素樹脂フィルム
とより密着し、使用中損傷することがない。In the first to third inventions, since the rough surface for printing is formed on the metal plate m or the fluororesin film by corona discharge, the pattern pr is more closely adhered to the metal plate m or the fluororesin film and is damaged during use. Never.
【００１２】（第１発明の実施例）まづ、図１に示され
た第１発明の実施例について説明する。(Embodiment of the First Invention) First, the embodiment of the first invention shown in FIG. 1 will be described.
【００１３】図１において亜鉛鋼板、ステンレスなどの
金属板ｍはコロナ放電処理される。図１においてｃ＋は
コロナ電極のプラス極、ｃ−は同じくマイナス極で、ｒ
０はコロナ放電処理された結果生成される金属板ｍの表
面の粗面である。In FIG. 1, a metal plate m such as a zinc steel plate or stainless steel is subjected to corona discharge treatment. In FIG. 1, c + is the positive pole of the corona electrode, c− is also the negative pole, and r
0 is a rough surface of the surface of the metal plate m generated as a result of the corona discharge treatment.
【００１４】この粗面ｒ０上に印刷ロールｐｏで模様ｐ
ｒが印刷される。A pattern p is formed on the rough surface r0 by the printing roll po.
r is printed.
【００１５】つぎに金属板ｍ表面はフッ素樹脂フィルム
Ｆｆの融点以上に加熱装置ｈで加熱される。Next, the surface of the metal plate m is heated by the heating device h above the melting point of the fluororesin film Ff.
【００１６】この加熱された粗面ｒ０上にフッ素樹脂フ
ィルムＦｆが熱融着される。The fluororesin film Ff is heat-sealed on the heated rough surface r0.
【００１７】模様ｐｒが粗面ｒ０とされた後、印刷され
るので模様ｐｒが金属板ｍにより固定される。Since the pattern pr is made to be the rough surface r0 and then printed, the pattern pr is fixed by the metal plate m.
【００１８】またフッ素樹脂フィルムとしては四フッ化
エチレンコポリマーが好適である。四フッ化エチレンコ
ポリマーの構造式はFurther, a tetrafluoroethylene copolymer is suitable for the fluororesin film. The structural formula of tetrafluoroethylene copolymer is
【化１】 のように推定される。[Chemical 1] Is estimated as.
【化１】[Chemical 1]
【００１９】またその性状は次の通りである。 物理的性質 比重 １．７３〜１．７５ 融点 ２５５〜２７０℃ 溶融粘度 １０４〜１０５ ｐｏｉｓｅThe properties are as follows. Physical properties Specific gravity 1.73 to 1.75 Melting point 255 to 270 ° C. Melt viscosity 10 4 to 10 5 poise
【００２０】機械的性質 引張強度（２３℃） ４１０〜４７０ｋｇ／ｃｍ２ 降伏強度（２３℃） １９０〜２２０ｋｇ／ｃｍ２ 伸 度 （２３℃） ４２０〜４４０％ 引張弾性率 ｋｇ／ｃｍ２ ５〜８×１０３ 摩擦係数（対ステンレス） ０．２０[0020] Mechanical properties Tensile strength (23 ℃) 410~470kg / cm 2 yield strength (23 ℃) 190~220kg / cm 2 elongation at (23 ℃) 420~440% tensile elastic modulus kg / cm 2 5 to 8 × 10 3 Friction coefficient (against stainless steel) 0.20
【００２１】熱的性質 熱膨張係数 ９．４×１０−５ ｃ−１ 燃焼性 不燃 連続耐熱使用温度 １８０℃Thermal Properties Thermal Expansion Coefficient 9.4 × 10 −5 c −1 Flammability Non-combustible Continuous heat resistant operating temperature 180 ° C.
【００２２】化学的性質 耐薬品性 優 吸水率（２３℃） ０．０１％＞Chemical properties Chemical resistance Excellent water absorption (23 ° C) 0.01%>
【００２３】電気的性質 耐電圧（ｓｈｏｒｔ ｔｉｍｅ） １２ ＫＶ／０．
１ｍｍフィルム 体積固有抵抗 １０１７ Ｏｈａ
・ｃｍ 耐アーク性 １２０ ｓｅｃElectrical Properties Short voltage 12 KV / 0.
1mm film Volume resistivity 10 17 Oha
・ Cm Arc resistance 120 sec
【００２４】（第２発明の実施例）つぎに図２に示され
た第２発明の実施例について説明する。金属板ｍには予
めコロナ放電処理を施して、その表面側に粗面ｒ１を形
成しておく。(Embodiment of the Second Invention) Next, the embodiment of the second invention shown in FIG. 2 will be described. The metal plate m is previously subjected to corona discharge treatment to form a rough surface r1 on the surface side thereof.
【００２５】一方フッ素樹脂フィルムＦｆの裏面側には
コロナ放電処理しておき、印刷用粗面ｒ２を形成してお
く。On the other hand, the back side of the fluororesin film Ff is subjected to corona discharge treatment to form a rough surface r2 for printing.
【００２６】印刷用粗面ｒ２に印刷ロールｐｏで模様ｐ
ｒを印刷する。そして金属板ｍの粗面ｒ１とフッ素樹脂
フィルムＦｆの印刷用粗面ｒ２とを熱融着する。A pattern p is formed on the rough surface r2 for printing by the printing roll po.
print r. Then, the rough surface r1 of the metal plate m and the rough printing surface r2 of the fluororesin film Ff are heat-sealed.
【００２７】この際金属板ｍは予め加熱装置ｈでフッ素
樹脂フィルムＦｆの融点以上に加熱しておく。At this time, the metal plate m is heated in advance by the heating device h above the melting point of the fluororesin film Ff.
【００２８】フッ素樹脂フィルムＦｆとしては実施例１
と同様のものを用いる。Example 1 was used as the fluororesin film Ff.
Use the same as.
【００２９】第２発明では模様ｐｒはフッ素樹脂フィル
ムＦｆに印刷用粗面ｒ２を形成しておくので模様がフッ
素樹脂フィルムＦｆによく固定される。In the second invention, since the pattern pr has the rough printing surface r2 formed on the fluororesin film Ff, the pattern is well fixed to the fluororesin film Ff.
【００３０】（第３発明の実施例）つぎに図３に示され
た第３発明の実施例について説明する。(Embodiment of Third Invention) Next, an embodiment of the third invention shown in FIG. 3 will be described.
【００３１】金属板ｍはコロナ放電処理されて、その表
面に粗面ｒ３が形成される。The metal plate m is subjected to corona discharge treatment to form a rough surface r3 on its surface.
【００３２】一方複層フッ素樹脂フィルムＦｆ３を形成
する下側のフィルムＦｆ１はその表面側がコロナ放電処
理され、その表面に印刷用粗面ｒ４が形成される。その
印刷用粗面ｒ４上に印刷ロールｐｏで印刷ｐｒが施され
る。On the other hand, the lower film Ff1 forming the multi-layer fluororesin film Ff3 is subjected to corona discharge treatment on its surface side, and a rough surface for printing r4 is formed on the surface thereof. The printing pr is performed on the rough surface r4 for printing by the printing roll po.
【００３３】この下側のフィルムＦｆ１と上側のフィル
ムＦｆ２とは接着剤ａｄで接着される。そして、上下フ
ィルムＦｆ１，Ｆｆ２は複層フィルムＦｆ３となって、
金属板ｍの粗面ｒ３上に熱融着される。The lower film Ff1 and the upper film Ff2 are adhered by an adhesive ad. Then, the upper and lower films Ff1 and Ff2 become a multilayer film Ff3,
It is heat-sealed on the rough surface r3 of the metal plate m.
【００３４】このとき金属板ｍは複層フィルムＦｆ３と
熱融着する前に予め、加熱装置ｈでフッ素樹脂フィルム
Ｆｆの融点より高く加熱されている。At this time, the metal plate m is previously heated to a temperature higher than the melting point of the fluororesin film Ff by the heating device h before being heat-sealed to the multilayer film Ff3.
【００３５】なお、上下のフィルムＦｆ１，Ｆｆ２とし
ては実地例１と同様のものを用いるか、あるいは下側の
フィルムＦｆ１として四フッ化エチレンコポリマーを、
上側のフィルムＦｆ２としては四フッ化エチレンコポリ
マーより融点の高いたとえば過フッ化アルコキシを用い
る。As the upper and lower films Ff1 and Ff2, the same ones as in the practical example 1 are used, or as the lower film Ff1, a tetrafluoroethylene copolymer is used.
As the upper film Ff2, for example, perfluorinated alkoxy having a melting point higher than that of the tetrafluoroethylene copolymer is used.
【００３６】フッ化アルコシキの構造式はThe structural formula of fluorinated alcohol is
【化２】 のように推定される。[Chemical 2] Is estimated as.
【化２】[Chemical 2]
【００３７】またその融点は３１０℃、連続耐熱温度は
２００℃耐薬品性は四フッ化エチレンコポリマーと同様
である。The melting point is 310 ° C., the continuous heat resistance temperature is 200 ° C., and the chemical resistance is the same as that of the tetrafluoroethylene copolymer.
【００３８】なお前記した金属板ｍの加熱温度はたとえ
ば下側フィルムＦｆ１の融点より高く、上側フィルムＦ
ｆ２の融点より低いのが理想的であるが、実際には上下
側フィルムＦｆ１，Ｆｆ２の融点より高くなっても差支
えない。The heating temperature of the metal plate m is higher than the melting point of the lower film Ff1, for example, and the upper film F is
It is ideally lower than the melting point of f2, but in reality, it may be higher than the melting points of the upper and lower films Ff1 and Ff2.
【００３９】（第１発明の効果）金属板ｍの表面を予め
粗面ｒ０とした後、模様ｐｒを印刷するので模様ｐｒが
金属板ｍ表面によく密着し、剥げることがない。また模
様ｐｒが透明のフッ素樹脂フィルムＦｆにより保護され
ているので、損傷することがなく意匠性を高く保持でき
る。(Effect of the first invention) Since the surface of the metal plate m is roughened in advance to r0 and then the pattern pr is printed, the pattern pr is well adhered to the surface of the metal plate m and is not peeled off. Further, since the pattern pr is protected by the transparent fluororesin film Ff, the design can be kept high without being damaged.
【００４０】（第２発明の効果）フッ素樹脂フィルムＦ
ｆの裏面をコロナ放電処理して粗面ｒ２を形成した後、
模様ｐｒを印劇するので、模様ｐｒはフッ素樹脂フィル
ムＦｆとよく密着し、かつ透明のフッ素樹脂フィルムＦ
ｆにより模様３は金属板ｍとの境界面に保護されている
ので、模様ｐｒが損傷することなく、意匠性が長く保た
れる。(Effect of the Second Invention) Fluorine Resin Film F
After the corona discharge treatment of the back surface of f to form the rough surface r2,
Since the pattern pr is printed, the pattern pr is well adhered to the fluororesin film Ff and is transparent to the fluororesin film F.
Since the pattern 3 is protected on the boundary surface with the metal plate m by f, the pattern pr is not damaged and the designability is maintained for a long time.
【００４１】（第３発明の効果）第１，第２発明と異な
り、模様ｐｒが複層フィルムＦｆ３の下側フィルムＦｆ
１とＦｆ２の境界面に位置しているので、複層フィルム
Ｆｆ３が金属板ｍと熱融着するとき熱融着による損傷を
受けないので、印刷模様の美しさを製造段階において損
なうことがない。(Effect of the third invention) Different from the first and second inventions, the pattern pr has the lower film Ff of the multilayer film Ff3.
Since the multilayer film Ff3 is located at the boundary surface between 1 and Ff2, the multilayer film Ff3 is not damaged by heat fusion when heat-sealed with the metal plate m, so that the beauty of the printed pattern is not impaired in the manufacturing stage. .
【図１】 第１発明のフローシート、FIG. 1 is a flow sheet of the first invention,
【図２】 第２発明のフローシート、FIG. 2 is a flow sheet of the second invention,
【図３】 第３発明のフローシート、FIG. 3 is a flow sheet of the third invention,
ｃ＋：コロナ放電プラス極、ｃ−：コロナ放電マイナス
極、ｐｒ：模様、ｈ：加熱装置、Ｆｆ：フッ素樹脂フィ
ルム、ｐｏ：印刷ロール、ｒ０：金属板ｍの印刷用粗
面、ｒ１：金属板ｍの印刷しない粗面、ｒ２：フッ素樹
脂フィルムＦｆの印刷用粗面、ｒ３：下側フィルムＦｆ
１の印刷用粗面、Ｆｆ１：下側フッ素樹脂フィルム、Ｆ
ｆ２：上側フッ素樹脂フィルム、Ｆｆ３：複層フッ素樹
脂フィルム、ａｄ：接着剤。c +: corona discharge plus electrode, c−: corona discharge minus electrode, pr: pattern, h: heating device, Ff: fluororesin film, po: printing roll, r0: rough surface for printing of metal plate m, r1: metal plate m: non-printed rough surface, r2: fluororesin film Ff printing rough surface, r3: lower film Ff
1 rough surface for printing, Ff1: lower fluororesin film, F
f2: upper fluororesin film, Ff3: multi-layer fluororesin film, ad: adhesive.
Claims (6)
に被覆する方法において金属板ｍの表面に粗面ｒ０を形
成した後、該粗面ｒ０上に印刷模様ｐｒを印刷した後、
被覆するフッ素樹脂フィルムＦｆの融点以上に該粗面ｒ
０を加熱した後、フッ素樹脂フィルムＦｆを粗面ｒ０に
熱融着せしめる、 ことを特徴とする印刷模様を埋設してフッ素樹脂フィル
ムを金属板に被覆する方法。1. A method of coating a surface of a metal plate m with a fluororesin film Ff, after forming a rough surface r0 on the surface of the metal plate m, and then printing a print pattern pr on the rough surface r0,
Rough surface r above the melting point of the fluororesin film Ff to be coated
After heating 0, the fluororesin film Ff is heat-sealed onto the rough surface r0. A method for embedding a printed pattern to cover the fluororesin film on a metal plate.
に被覆する方法において、 金属板ｍの表面に粗面ｒ１を形成した後、被覆するフッ
素樹脂フィルムＦｆの融点以上に加熱し、 一方フッ素樹脂フィルムＦｆ裏面にコロナ放電処理して
粗面ｒ２を形成した後、印刷模様ｐｒを印刷した後、 金属板ｍの粗面ｒ１にフッ素樹脂フィルムＦｆの裏面の
粗面ｒ２を熱溶融せしめる、ことを特徴とする印刷模様
を埋設してフッ素樹脂フィルムを金属板に被覆する方
法。2. A method for coating a surface of a metal plate m with a fluororesin film Ff, wherein after forming a rough surface r1 on the surface of the metal plate m, the fluororesin film Ff is heated to the melting point or higher, After the rough surface r2 is formed on the back surface of the film Ff by corona discharge treatment, the printed pattern pr is printed, and then the rough surface r2 of the back surface of the fluororesin film Ff is heat-melted on the rough surface r1 of the metal plate m. A method of embedding a characteristic printed pattern and coating a fluororesin film on a metal plate.
エチレンコポリマーを用いた請求項１あるいは２記載の
方法。3. The method according to claim 1, wherein a tetrafluoroethylene copolymer is used as the fluororesin film Ff.
ｍ表面に被覆する方法において、 金属板ｍの表面に予め粗面ｒ３を形成した後、該粗面ｒ
３を加熱しておき、 一方、複層フッ素樹脂フィルムＦｆ３の下側フィルムＦ
ｆ１の表面にコロナ放電処理により粗面ｒ２を形成した
後、印刷模様ｐｒを印刷し、 この印刷模様ｐｒを印刷した下側フィルムＦｆ１の表面
を、下側フィルムＦｆ１と融点が等しいかあるいは高い
上側フィルムＦｆ２とを接着して、複層フッ素樹脂フィ
ルムＦｆ３を形成し、 前記複層フッ素樹脂フィルムＦｆ３の下側フィルムＦｆ
１の下面側を金属板ｍの加熱した粗面ｒ３に熱融着す
る、ことを特徴とする印刷模様を埋設してフッ素樹脂フ
ィルムを金属板に被覆する方法。4. A method for coating the surface of a metal plate m with a multi-layer fluororesin film Ff3, which comprises forming a rough surface r3 on the surface of the metal plate m in advance and then forming the rough surface
3 has been heated, while the lower film F of the multi-layer fluororesin film Ff3 has been heated.
After a rough surface r2 is formed on the surface of f1 by corona discharge treatment, a print pattern pr is printed, and the surface of the lower film Ff1 on which the print pattern pr is printed has a melting point equal to or higher than that of the lower film Ff1. The multi-layer fluororesin film Ff3 is formed by adhering the film Ff2 to the lower film Ff of the multi-layer fluororesin film Ff3.
1. A method of embedding a printed pattern, wherein the lower surface side of 1 is heat-sealed to the heated rough surface r3 of the metal plate m to cover the metal plate with the fluororesin film.
ッ素樹脂フィルムＦｆ２として四フッ化エチレンコポリ
マーを用いた請求項４記載の方法。5. The method according to claim 4, wherein tetrafluoroethylene copolymer is used as the lower fluororesin film Ff1 and the upper fluororesin film Ff2.
フッ化エチレンコポリマーを、上側フッ素樹脂フィルム
Ｆｆ２としてフッ化アルコキシを用いた請求項４記載の
方法。6. The method according to claim 4, wherein a tetrafluoroethylene copolymer is used as the lower fluororesin film Ff1 and an alkoxy fluoride is used as the upper fluororesin film Ff2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4317675A JP3013012B2 (en) | 1992-10-15 | 1992-10-15 | Method to embed printed pattern in multi-layer fluororesin and cover metal plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4317675A JP3013012B2 (en) | 1992-10-15 | 1992-10-15 | Method to embed printed pattern in multi-layer fluororesin and cover metal plate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06126889A true JPH06126889A (en) | 1994-05-10 |
| JP3013012B2 JP3013012B2 (en) | 2000-02-28 |
Family
ID=18090772
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4317675A Expired - Fee Related JP3013012B2 (en) | 1992-10-15 | 1992-10-15 | Method to embed printed pattern in multi-layer fluororesin and cover metal plate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3013012B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100333054B1 (en) * | 1999-08-18 | 2002-04-24 | 김성권 | Coating Method of gold-card |
| WO2006117849A1 (en) * | 2005-04-27 | 2006-11-09 | Mitsubishi Denki Kabushiki Kaisha | Decoration member and process for producing the same |
| WO2015063274A1 (en) * | 2013-10-31 | 2015-05-07 | Umicore Building Products France | Patterned rolled zinc alloy sheet |
| JP2019084826A (en) * | 2017-11-01 | 2019-06-06 | Ａｇｃ株式会社 | Laminate and method for producing the same, and method for producing composite body |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20230143609A1 (en) | 2021-11-11 | 2023-05-11 | Arcutis Biotherapeutics, Inc. | Pharmaceutical compositions of spironolactone for deep dermal drug delivery |
-
1992
- 1992-10-15 JP JP4317675A patent/JP3013012B2/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100333054B1 (en) * | 1999-08-18 | 2002-04-24 | 김성권 | Coating Method of gold-card |
| WO2006117849A1 (en) * | 2005-04-27 | 2006-11-09 | Mitsubishi Denki Kabushiki Kaisha | Decoration member and process for producing the same |
| WO2015063274A1 (en) * | 2013-10-31 | 2015-05-07 | Umicore Building Products France | Patterned rolled zinc alloy sheet |
| US10494812B2 (en) | 2013-10-31 | 2019-12-03 | Umicore Building Products France | Patterned rolled zinc alloy sheet |
| JP2019084826A (en) * | 2017-11-01 | 2019-06-06 | Ａｇｃ株式会社 | Laminate and method for producing the same, and method for producing composite body |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3013012B2 (en) | 2000-02-28 |
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