JPH05457A - Manufacture of fiber reinforced resin molded product - Google Patents
Manufacture of fiber reinforced resin molded productInfo
- Publication number
- JPH05457A JPH05457A JP3153211A JP15321191A JPH05457A JP H05457 A JPH05457 A JP H05457A JP 3153211 A JP3153211 A JP 3153211A JP 15321191 A JP15321191 A JP 15321191A JP H05457 A JPH05457 A JP H05457A
- Authority
- JP
- Japan
- Prior art keywords
- resin liquid
- resin
- mandrel
- thermosetting
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Moulding By Coating Moulds (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】この発明は、フィラメントワイン
ディング法による維強化樹脂成形品の製造方法に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a fiber-reinforced resin molded product by a filament winding method.
【０００２】[0002]
【従来の技術】フィラメントワインディング法による繊
維強化樹脂成形品は、一般に熱硬化性樹脂液を含浸させ
たロービング繊維材をマンドレルの外周に巻付けて積層
し、これを常温で又は加熱して樹脂を硬化させることに
より製造される。2. Description of the Related Art A fiber-reinforced resin molded product produced by a filament winding method is generally a roving fiber material impregnated with a thermosetting resin liquid, wound around an outer periphery of a mandrel and laminated, and the resin is heated at room temperature or heated to form a resin. It is manufactured by curing.
【０００３】このような製造方法では、マンドレルに巻
付けられたロービング繊維材中の樹脂液が外側へと移動
していき、内側のロービング繊維材中には樹脂が少なく
なり、所謂樹脂枯れが起こる。そのため、製品の内側部
分にはクラックやボイドが発生したり、層間剥離が起こ
ったりして機械的強度が低下するという欠点がある。ま
た、配管のようにその中を流れる流体による内圧がかか
るような用途では、ウイーピング（発汗）が生ずるとい
う欠点がある。In such a manufacturing method, the resin liquid in the roving fiber material wound around the mandrel moves to the outside, the amount of the resin in the roving fiber material on the inner side is reduced, and so-called resin death occurs. . Therefore, there are drawbacks such that cracks and voids are generated in the inner part of the product, and delamination occurs, which lowers the mechanical strength. In addition, there is a drawback that weeping (perspiration) occurs in applications such as piping where internal pressure is applied by a fluid flowing therein.
【０００４】特開昭64−45625 号公報には、ハンドレイ
アップ法で管継手の半割型の芯部材を作り、この半割型
の芯部材を管継手状に互いに接合し、その外周に熱硬化
性樹脂液を含浸させたロービング繊維材を巻付けて積層
し、樹脂を硬化させることにより繊維強化樹脂管継手を
製造する方法が提案されている。In Japanese Patent Laid-Open No. 64-45625, a half member of a pipe joint is made by a hand lay-up method, the core members of the half joint are joined to each other in a pipe joint shape, and the outer periphery thereof is formed. A method of manufacturing a fiber-reinforced resin pipe joint by winding and laminating a roving fiber material impregnated with a thermosetting resin liquid and curing the resin has been proposed.
【０００５】この方法によれば、製品の内側部分におけ
るクラックやボイドの発生が防止され、内圧がかかるよ
うな用途ではウイーピングの発生も一応は防止される。
ところが、ハンドレイアップ法を用いるので、成形に手
間と時間がかかり生産性が悪く、しかも芯部材とこれに
積層されるロービング繊維材との層間接着性も充分とは
いえない。また、半割型の芯部材の継ぎ目からウイーピ
ングが生ずることがあり、品質の信頼性に欠ける。According to this method, the generation of cracks and voids in the inner part of the product is prevented, and the occurrence of weeping is also prevented in applications where internal pressure is applied.
However, since the hand lay-up method is used, it takes a lot of time and time for molding, the productivity is poor, and the interlayer adhesion between the core member and the roving fiber material laminated thereon is not sufficient. In addition, weaping may occur from the seam of the half-divided core member, resulting in poor quality reliability.
【０００６】[0006]
【発明が解決しようとする課題】このような欠点を改善
するために、この発明者は、マンドレルの表面に熱硬化
性樹脂液を塗布し、これを加熱して樹脂液をゲル化さ
せ、これに熱硬化性樹脂液を含浸させたロービング繊維
材を巻付けて積層し、加熱して全部の樹脂を硬化させる
方法を試みた。この場合、製品の内側部分にクラックや
ボイドの発生が防止され、層間剥離もなく、流体による
内圧がかかるような用途ではウイーピングの発生も良好
に防止されることが判った。In order to improve such drawbacks, the inventor of the present invention applied a thermosetting resin liquid to the surface of a mandrel and heating it to gel the resin liquid. An attempt was made to wind a roving fiber material impregnated with a thermosetting resin liquid on the above, laminate them, and heat them to cure all the resins. In this case, it has been found that generation of cracks and voids in the inner part of the product is prevented, delamination does not occur, and weeping is also effectively prevented in applications where internal pressure is applied by the fluid.
【０００７】しかし、この方法では、マンドレルの表面
に塗布される熱硬化性樹脂液を加熱してゲル化させる工
程に相当の時間（例えば数十分）を要し、この工程とフ
ィラメントワインディング工程との速度バランスが悪
く、製品の生産性にまだ問題がある。また、上記のゲル
化状態にばらつきが生じ、製品の品質が安定しないとい
う問題のあることが判った。However, this method requires a considerable amount of time (for example, several tens of minutes) in the step of heating the thermosetting resin liquid applied to the surface of the mandrel to gel it, and this step and the filament winding step are required. The speed balance is poor, and there is still a problem in product productivity. Further, it has been found that there is a problem in that the above-mentioned gelling state varies and the quality of the product is not stable.
【０００８】この発明は、上記の問題を解決するもの
で、その目的とするところは、フィラメントワインディ
ング法により繊維強化樹脂成形品を製造する方法におい
て、製品の内側部分にクラックやボイドの発生がなく、
流体による内圧がかかるような用途でウイーピングの発
生しない製品を安定して生産性よく製造する方法を提供
することにある。The present invention is intended to solve the above problems, and it is an object of the present invention to produce a fiber-reinforced resin molded product by a filament winding method without causing cracks or voids in the inner part of the product. ,
It is an object of the present invention to provide a method for stably producing with high productivity a product which does not generate weeping in an application where internal pressure is applied by a fluid.
【０００９】[0009]
【課題を解決するための手段】上記の目的を達成するた
め、この発明では、マンドレルの表面に光硬化剤と熱硬
化剤を含有する硬化性樹脂液を塗布し、これに光を照射
して硬化性樹脂液をゲル化させ、その外周に熱硬化性樹
脂液を含浸させたロービング繊維材を巻付けて積層し、
これを常温で又は加熱して全部の樹脂を硬化させて、維
強化樹脂成形品を製造するものである。In order to achieve the above object, in the present invention, a curable resin liquid containing a photo-curing agent and a thermo-curing agent is applied to the surface of a mandrel and irradiated with light. The curable resin liquid is gelled, and the roving fiber material impregnated with the thermosetting resin liquid is wound around the outer periphery and laminated,
The resin is cured at room temperature or by heating to cure all the resin to produce a fiber-reinforced resin molded product.
【００１０】この発明においては、先ず、マンドレルの
表面に光硬化剤と熱硬化剤を含有する硬化性樹脂液が塗
布される。塗布方法としては、刷毛塗り、ロール塗り、
吹き付け等が採用される。塗布厚さは一般に0.5 〜２mm
の範囲に設定され、特に１mm程度が好ましい。In the present invention, first, a curable resin liquid containing a photocuring agent and a thermosetting agent is applied to the surface of the mandrel. As a coating method, brush coating, roll coating,
Spraying is adopted. Coating thickness is generally 0.5-2 mm
The range is set to, and about 1 mm is particularly preferable.
【００１１】この硬化性樹脂液としては、不飽和ポリエ
ステルにスチレンのような架橋用モノマーを溶解させた
慣用の不飽和ポリエステル樹脂液に、光硬化剤と熱硬化
剤の両方を添加した硬化性不飽和ポリエステル樹脂液が
好適である。この場合、硬質の硬化層を形成する樹脂よ
りも軟質の硬化層を形成する樹脂を用いるのが望まし
い。その他、光硬化剤と熱硬化剤の両方を添加した硬化
性ビニルエステル樹脂液も好ましい。This curable resin liquid is a conventional unsaturated polyester resin liquid prepared by dissolving a crosslinking monomer such as styrene in an unsaturated polyester, and a curable resin prepared by adding both a photo-curing agent and a thermosetting agent to the curable resin. A saturated polyester resin liquid is preferred. In this case, it is desirable to use a resin that forms a softer cured layer than a resin that forms a hardened layer. In addition, a curable vinyl ester resin liquid containing both a photo-curing agent and a thermo-curing agent is also preferable.
【００１２】光硬化剤としては、２,2−ジメトキシ−２
−フェニルアセトフェノン、メトキシアセトフェノンな
どのアセトフェノン系、ベンゾインエチルエーテル、ベ
ンゾインイソプロピルエーテルなどのベンゾインエーテ
ル系、ベンジルジメチルケタールなどのケタール系、ジ
フェニルジサルファイドなどのジサルファイド系が用い
られる。このような光硬化剤は、一般に、前記の不飽和
ポリエステル樹脂液やビニルエステル樹脂液100 重量部
に対して、0.1〜２重量部の範囲で使用される。The photo-curing agent is 2,2-dimethoxy-2.
-Acetophenone type such as phenylacetophenone and methoxyacetophenone, benzoin ether type such as benzoin ethyl ether and benzoin isopropyl ether, ketal type such as benzyl dimethyl ketal, and disulfide type such as diphenyl disulfide are used. Such a photocuring agent is generally used in the range of 0.1 to 2 parts by weight with respect to 100 parts by weight of the unsaturated polyester resin liquid or vinyl ester resin liquid.
【００１３】熱硬化剤としては、メチルエチルケトンパ
ーオキサイド、シクロヘキサノンパーオキサイド、ベン
ゾイルパーオキサイド、ビス−（４−ｔ−ブチルシクロ
ヘキシル）パーオキシジカーボネート等の60〜80℃で硬
化可能な中温硬化用、或いはこれにナフテン酸コバル
ト、ジメチルアニリン等の促進剤を加えた常温硬化用が
用いられる。このような熱硬化剤は、一般に前記の不飽
和ポリエステル樹脂液や硬化性ビニルエステル樹脂液に
対して、0.5 〜２重量部の範囲で使用される。Examples of the heat-curing agent include methyl ethyl ketone peroxide, cyclohexanone peroxide, benzoyl peroxide, bis- (4-t-butylcyclohexyl) peroxydicarbonate, and the like, which can be cured at 60 to 80 ° C., or A room temperature curing agent containing an accelerator such as cobalt naphthenate or dimethylaniline is used. Such a thermosetting agent is generally used in the range of 0.5 to 2 parts by weight based on the unsaturated polyester resin liquid or the curable vinyl ester resin liquid.
【００１４】上記のように、マンドレルの表面に光硬化
剤と熱硬化剤を含有する硬化性樹脂液が塗布され、その
後これに光が照射される。照射する光としては、紫外線
や可視光線などの活性光線、特に300 〜410 nmの波長を
有する紫外線ランプ、高圧水銀灯、メタルハロゲンラン
プ等が用いられる。照射は、製品の形状や大きさにより
異なるが、一般に出力40〜1000Wで10〜100cm の距離か
ら硬化性樹脂液が均一にゲル化するように行われる。ゲ
ル化に要する照射時間は数分で充分である。ここで、ゲ
ル化とは、樹脂液の粘度が急激に上昇して寒天状に固化
した半硬化の状態を意味する。As described above, the curable resin liquid containing the photo-curing agent and the thermo-curing agent is applied to the surface of the mandrel, and thereafter the light is irradiated. As the light to be applied, active rays such as ultraviolet rays and visible rays, particularly ultraviolet lamps having a wavelength of 300 to 410 nm, high pressure mercury lamps, metal halogen lamps and the like are used. Irradiation varies depending on the shape and size of the product, but is generally performed so that the curable resin liquid gels uniformly from a distance of 10 to 100 cm at an output of 40 to 1000 W. The irradiation time required for gelation is several minutes. Here, the gelation means a semi-cured state in which the viscosity of the resin liquid rapidly increases and solidifies in an agar form.
【００１５】次いで、このゲル化層の外周に、熱硬化性
樹脂液を含浸させたロービング繊維材が巻付けられ積層
される。樹脂含浸ロービング繊維材は、フィラメントワ
インディング装置により予め決められたパターンで、例
えばヘリカル状に巻き付けられ所望の厚さに積層され
る。樹脂含浸ロービング繊維材は、一般に１〜30mmとな
るように積層される。Then, a roving fiber material impregnated with a thermosetting resin liquid is wound around the outer periphery of the gelled layer and laminated. The resin-impregnated roving fiber material is wound in a predetermined pattern by a filament winding device, for example, in a helical shape and laminated to a desired thickness. The resin-impregnated roving fiber material is generally laminated to have a thickness of 1 to 30 mm.
【００１６】ここで用いる熱硬化性樹脂液は、一般に硬
質の硬化層を形成する不飽和ポリエステル樹脂液やビニ
ルエステル樹脂液に前記と同じような熱硬化剤を添加し
た熱硬化性不飽和ポリエステル樹脂液、或いは熱硬化性
ビニルエステル樹脂液である。ロービング繊維として
は、連続するモノフィラメントの数百〜数千本から構成
された繊維束で、例えば、ガラス繊維、炭素繊維等の無
機繊維、或いはポリエステル繊維、アラミド繊維等の有
機繊維が好適に用いられる。モノフィラメントの直径は
１〜50μm が好ましい。ロービング繊維材の含有量は、
一般に30〜70容量％とされる。The thermosetting resin liquid used here is generally a thermosetting unsaturated polyester resin obtained by adding a thermosetting agent as described above to an unsaturated polyester resin liquid or a vinyl ester resin liquid which forms a hard cured layer. Liquid or thermosetting vinyl ester resin liquid. The roving fiber is a fiber bundle composed of hundreds to thousands of continuous monofilaments, and for example, inorganic fibers such as glass fibers and carbon fibers, or organic fibers such as polyester fibers and aramid fibers are preferably used. . The diameter of the monofilament is preferably 1 to 50 μm. The content of roving fiber material is
Generally, it is 30 to 70% by volume.
【００１７】その後、加熱炉等に入れられ適当な温度で
加熱硬化され、最後にマンドレルから脱型される。な
お、マンドレルは種々の形状に設定され、この形状に応
じて、例えばチーズ型、エルボ型、ソケット型の管継手
或いは長尺パイプ、容器など種々の形状の繊維強化樹脂
成形体を製造することができる。加熱温度は、一般に60
〜100 ℃の範囲とされるが、加熱温度が常温であっても
熱硬化可能な場合もある。このようにして、下層のゲル
化樹脂とその上層の繊維含浸樹脂の熱硬化が行われる。
熱硬化時間は、一般に60〜120 分である。After that, it is placed in a heating furnace or the like, is heated and cured at an appropriate temperature, and is finally released from the mandrel. The mandrel is set in various shapes, and depending on this shape, for example, cheese-type, elbow-type, socket-type pipe joints or long pipes, various shapes of fiber-reinforced resin molded articles such as containers can be manufactured. it can. The heating temperature is generally 60
It is set in the range of up to 100 ° C, but it may be thermosettable even if the heating temperature is room temperature. In this way, the gelling resin in the lower layer and the fiber-impregnated resin in the upper layer are thermoset.
The heat setting time is generally 60 to 120 minutes.
【００１８】この発明においては、光硬化剤と熱硬化剤
を含有する硬化性樹脂液に炭酸カルシウム、タルク、ク
レー、水酸化アルミニウムのような充填剤（特に、無機
充填剤）やガラス短繊維を含有せておくのが好ましい。
ガラス短繊維の長さは一般に５〜50ｍｍが好ましい。充
填剤は、一般に前記の不飽和ポリエステル樹脂液やビニ
ルエステル樹脂液100 重量部に対して、10〜 200重量部
の範囲で含有される。また、ガラス短繊維は、一般に前
記の不飽和ポリエステル樹脂液やビニルエステル樹脂液
100 重量部に対して、１〜10重量部の範囲で含有され
る。In the present invention, a curable resin liquid containing a photo-curing agent and a thermo-curing agent is filled with fillers (particularly inorganic fillers) such as calcium carbonate, talc, clay and aluminum hydroxide, and short glass fibers. It is preferable to contain it.
Generally, the length of the glass short fibers is preferably 5 to 50 mm. The filler is generally contained in the range of 10 to 200 parts by weight with respect to 100 parts by weight of the unsaturated polyester resin liquid or the vinyl ester resin liquid. In addition, the glass short fibers are generally the above-mentioned unsaturated polyester resin liquid or vinyl ester resin liquid.
It is contained in the range of 1 to 10 parts by weight with respect to 100 parts by weight.
【００１９】[0019]
【作用】マンドレルの外周に熱硬化性樹脂液を含浸させ
たロービング繊維材を巻付けて積層し、これを常温で又
は加熱して樹脂を硬化させる際に、予めマンドレルの表
面に光硬化剤と熱硬化剤を含有する硬化性樹脂液を塗布
し、これに光を照射してこの硬化性樹脂液をゲル化させ
ておくと、このゲル化層は流動性が低下しているので外
側へと移動しにくく、内側の樹脂枯れが起こらず、製品
の内側部分にクラックやボイドの発生が防止される。[Function] A roving fiber material impregnated with a thermosetting resin liquid is wound around the mandrel and laminated, and when the resin is cured at room temperature or by heating, a photocuring agent is preliminarily applied to the surface of the mandrel. When a curable resin liquid containing a thermosetting agent is applied, and the curable resin liquid is gelled by irradiating it with light, the gelled layer has a reduced fluidity, so the gelled layer is exposed to the outside. It does not move easily, the inner resin does not die, and the occurrence of cracks and voids inside the product is prevented.
【００２０】また、上記のゲル化層は光の照射により形
成され、この光の照射は極めて短時間でよく、且つ照射
を止めることによりその制御も自由に行うことができる
ので、樹脂の硬化は全体として比較的短時間で且つ所望
のゲル化度合いに正確に設定することができる。The above gelled layer is formed by light irradiation, and this light irradiation can be performed for an extremely short time, and its control can be freely performed by stopping the light irradiation. As a whole, the desired degree of gelation can be accurately set in a relatively short time.
【００２１】しかも、未だ半硬化状態のゲル化層に熱硬
化性樹脂液を含浸させたロービング繊維材が巻き付けら
れるので、このゲル化層とその上の樹脂含浸ロービング
繊維材とは良好に接着され、その後の常温で又は加熱に
よる熱硬化により強固に一体化され、層間剥離が防止さ
れる。Moreover, since the roving fiber material impregnated with the thermosetting resin liquid is wound around the semi-cured gelling layer, the gelling layer and the resin-impregnated roving fiber material on the roving fiber material are well bonded. After that, they are firmly integrated at room temperature or by heat curing by heating, and delamination is prevented.
【００２２】特に、光硬化剤と熱硬化剤を含有する硬化
性樹脂液に充填剤やガラス短繊維が含有されていると、
これによりマンドレルに対する樹脂液の撥水が改善さ
れ、また粘度も高くなって塗り残りが発生せず、塗布作
業性も向上する。In particular, when the curable resin liquid containing the photo-curing agent and the thermo-curing agent contains the filler and the glass short fibers,
As a result, the water repellency of the resin liquid to the mandrel is improved, the viscosity is increased, no coating residue occurs, and the coating workability is improved.
【００２３】[0023]
【実施例】以下、本発明の実施例及び比較例を示す。実施例１
組立分解の可能なＴ字形のマンドレルを用意し、このマ
ンドレルの表面に光硬化剤と熱硬化剤を含有する硬化性
不飽和ポリエステル樹脂液を刷毛で約１mmの厚さに塗布
した。硬化性不飽和ポリエステル樹脂液は、不飽和ポリ
エステル（ポリマール 6320F：武田薬品社製）100 重量
部と光硬化剤( イルガキュア 651：チバガイギー社製）
0.5 重量部と熱硬化剤（パーカドックス16：化薬アクゾ
社製）１重量部からなる。これに365nm の紫外線ランプ
（１KW×２本）をほぼ全周にわたり100cm の距離から３
分間照射して上記の樹脂液を均一にゲル化させた。EXAMPLES Examples and comparative examples of the present invention will be shown below. Example 1 A T-shaped mandrel which can be assembled and disassembled was prepared, and a curable unsaturated polyester resin liquid containing a photocuring agent and a thermosetting agent was applied to the surface of the mandrel with a brush to a thickness of about 1 mm. The curable unsaturated polyester resin liquid is 100 parts by weight of unsaturated polyester (Polymer 6320F: manufactured by Takeda Pharmaceutical Co., Ltd.) and a photo-curing agent (Irgacure 651: manufactured by Ciba Geigy).
0.5 parts by weight and 1 part by weight of a thermosetting agent (Perkadox 16: manufactured by Kayaku Akzo Co., Ltd.). Add a 365nm UV lamp (1KW x 2) to this over the entire circumference from a distance of 100cm to 3
The resin solution was uniformly irradiated by irradiation for a minute.
【００２４】一方、図１に示すように、ガラス繊維ロー
ビング（繊維径約16μm 、番手2230ｇ/km)多数のロービ
ング繊維11、12、13などの10本を引き揃え、これを繊維
送りロール31、樹脂含浸ロール40、繊維送りロール32に
通して、熱硬化性不飽和ポリエステル樹脂液を含浸させ
た10本の樹脂含浸繊維ロービングを形成した。On the other hand, as shown in FIG. 1, a large number of glass fiber rovings (fiber diameter of about 16 μm, count 2230 g / km), a large number of roving fibers 11, 12, 13 and the like, are aligned, and the fiber feed rolls 31, The resin impregnated roll 40 and the fiber feed roll 32 were passed through to form ten resin-impregnated fiber rovings impregnated with the thermosetting unsaturated polyester resin liquid.
【００２５】上記の熱硬化性不飽和ポリエステル樹脂液
は、不飽和ポリエステル（エスターR235：三井東圧社
製）100 重量部と熱硬化剤（カヤメックＭ：化薬アクゾ
社製）0.7 重量部からなる。また、ガラス繊維ロービン
グの含有量は約60容量％であった。The thermosetting unsaturated polyester resin liquid is composed of 100 parts by weight of unsaturated polyester (Ester R235: manufactured by Mitsui Toatsu Co., Ltd.) and 0.7 part by weight of a thermosetting agent (Kayamek M: manufactured by Kayaku Akzo Co., Ltd.). . The content of glass fiber roving was about 60% by volume.
【００２６】次いで、この樹脂含浸繊維ロービング11'
、12' 、13' などの10本を引き揃えた状態でトラバー
スアイ50に通して幅が約45mmのテープ状に収束した。こ
の収束されたテープ状の樹脂含浸繊維ロービング60を、
前記のゲル化層が形成されたマンドレル70の外周に、予
め決められたパターンでヘリカル状に巻き付けて積層
し、これを80℃で１時間加熱硬化させてチーズ型管継手
を製造した。なお、主管部分の長さは700 、分岐管部分
の長さは400mm 、管内径は165mm に設定した。Next, this resin-impregnated fiber roving 11 '
, 10 'such as 12' and 13 'were aligned and passed through the traverse eye 50 to converge into a tape with a width of about 45 mm. This converged tape-shaped resin-impregnated fiber roving 60,
The mandrel 70 having the gelled layer formed thereon was helically wound and laminated in a predetermined pattern, and this was heat-cured at 80 ° C. for 1 hour to manufacture a cheese-type pipe joint. The length of the main pipe was set to 700, the length of the branch pipe was set to 400 mm, and the pipe inner diameter was set to 165 mm.
【００２７】得られたチーズ型管継手の主管部分及び分
岐管部分の厚みは約５mm、主管部分と分岐管部分との合
流部分の厚みが10mmであり、このチーズ型管継手に強い
引張り応力13ton （規格13ton 以上）をかけても破壊は
起こらず、層間剥離も全く起こらなかった。また、内部
に強い水圧（破壊水圧40 kｇ/cm2) をかけても、ウイー
ピング( 水の滲み出し) は全く発生しなかった。The thickness of the main pipe portion and the branch pipe portion of the obtained cheese type pipe joint was about 5 mm, the thickness of the confluent portion of the main pipe portion and the branch pipe portion was 10 mm, and the cheese type pipe joint had a strong tensile stress of 13 tons. Destruction did not occur even when subjected to (standard 13 tons or more), and delamination did not occur at all. In addition, even if a strong water pressure (breaking water pressure 40 kg / cm 2 ) was applied to the inside, weeping (water exudation) did not occur at all.
【００２８】実施例２
実施例１において、光硬化剤と熱硬化剤を含有する硬化
性不飽和ポリエステル樹脂液に、ガラスロービング（繊
維径約16μm 、番手1150ｇ/km)をロータリーチョッパー
で約1/4 インチの長さに切断したチョップド短繊維３重
量部を混合した。それ以外は、実施例１と同様に行っ
た。 Example 2 In Example 1, glass roving (fiber diameter: about 16 μm, count: 1150 g / km) was added to a curable unsaturated polyester resin liquid containing a photo-curing agent and a thermo-curing agent by a rotary chopper at about 1 /. 3 parts by weight of chopped chopped fibers cut to a length of 4 inches were mixed. Other than that was performed like Example 1.
【００２９】この場合も、引張り応力13ton で破壊は起
こらず、層間剥離も全く起こらなかった。また、破壊水
圧（42 kｇ/cm2) でウイーピング( 水の滲み出し) は全
く発生しなかった。Also in this case, the tensile stress of 13 tons did not cause any breakage, and no delamination occurred at all. At the breaking water pressure (42 kg / cm 2 ), weeping (water bleeding) did not occur at all.
【００３０】実施例３
実施例１において、光硬化剤と熱硬化剤を含有する硬化
性不飽和ポリエステル樹脂液に、炭酸カルシウム100 重
量部を混合した。また、紫外線ランプの照射を10分間に
変更して上記の樹脂液をゲル化させた。それ以外は、実
施例１と同様に行った。 Example 3 In Example 1, 100 parts by weight of calcium carbonate was mixed with a curable unsaturated polyester resin liquid containing a photocuring agent and a thermosetting agent. Further, the irradiation of the ultraviolet lamp was changed to 10 minutes to gel the resin solution. Other than that was performed like Example 1.
【００３１】この場合も、引張り応力13ton で破壊は起
こらず、層間剥離も全く起こらなかった。また、破壊水
圧（40 kｇ/cm2) でウイーピング( 水の滲み出し) は全
く発生しなかった。Also in this case, the tensile stress of 13 tons did not cause the breakage, and the delamination did not occur at all. Further, at the breaking water pressure (40 kg / cm 2 ), weeping (water oozing) did not occur at all.
【００３２】比較例１
実施例１において用いたＴ字形のマンドレルと同じ寸法
の半割型のマンドレルを用意し、このマンドレルの表面
に熱硬化性樹脂液を含浸させたガラス繊維マットを置
き、ハンドレイアップ法で熱硬化性樹脂液を含浸させて
管継手状の半割型の芯部材を作った。 Comparative Example 1 A mandrel of a half-divided type having the same size as the T-shaped mandrel used in Example 1 was prepared, and a glass fiber mat impregnated with a thermosetting resin liquid was placed on the surface of this mandrel, and a hand was used. A thermosetting resin liquid was impregnated by a layup method to form a pipe joint-shaped half-core member.
【００３３】熱硬化性樹脂液は、不飽和ポリエステル
（エスターR235：三井東圧社製）100重量部と熱硬化剤
（カヤメックＭ：化薬アクゾ社製）0.7 重量部からな
る。ガラス繊維ロービングの含有量は約40容量％であっ
た。芯部材の厚さは10mmであった。The thermosetting resin liquid comprises 100 parts by weight of unsaturated polyester (Ester R235: manufactured by Mitsui Toatsu Co., Ltd.) and 0.7 part by weight of a thermosetting agent (Kayamek M: manufactured by Kayaku Akzo Co., Ltd.). The content of glass fiber roving was about 40% by volume. The thickness of the core member was 10 mm.
【００３４】この半割型の芯部材を互いに接合し、その
外周に実施例１と同様の条件で樹脂含浸繊維ロービング
を巻き付けて積層し、これを熱硬化させてチーズ型管継
手を製造した。The half-divided core members were joined together, the resin-impregnated fiber roving was wound around the outer periphery of the core members under the same conditions as in Example 1 and laminated, and this was thermoset to produce a cheese-type pipe joint.
【００３５】この場合は、引張り応力13ton で破壊は起
こらなかったが、層間剥離が発生していた。また、破壊
水圧（35 kｇ/cm2) で半割型の芯部材の継ぎ目部分から
ウイーピング（水の滲み出し) が認められた。In this case, the tensile stress of 13 tons did not cause breakage, but delamination occurred. At the breaking water pressure (35 kg / cm 2 ), weeping (water bleeding) was observed from the joint part of the half core member.
【００３６】比較例２
実施例１と同じ組立分解の可能なＴ字形のマンドレルを
用意し、このマンドレルの表面に熱硬化性樹脂液を刷毛
で約１mmの厚さに塗布した。熱硬化性樹脂液は、不飽和
ポリエステル（エスターR235：三井東圧社製）100 重量
部と熱硬化剤（カヤメックＭ：化薬アクゾ社製）0.7 重
量部からなる。これを80℃で７分間加熱しその後20分間
放置して上記の樹脂液をゲル化させた。それ以外は、実
施例１と同様に行った。 Comparative Example 2 A T-shaped mandrel which can be assembled and disassembled as in Example 1 was prepared, and a thermosetting resin liquid was applied to the surface of the mandrel with a brush to a thickness of about 1 mm. The thermosetting resin liquid comprises 100 parts by weight of unsaturated polyester (Ester R235: manufactured by Mitsui Toatsu Co., Ltd.) and 0.7 part by weight of a thermosetting agent (Kayamek M: manufactured by Kayaku Akzo Co., Ltd.). This was heated at 80 ° C. for 7 minutes and then left for 20 minutes to gel the resin solution. Other than that was performed like Example 1.
【００３７】この場合は、引張り応力13ton で破壊は起
こらず、層間剥離も全く起こらなかった。また、破壊水
圧（40 kｇ/cm2) でウイーピング( 水の滲み出し) は全
く発生しなかった。しかし、マンドレルの表面の熱硬化
性樹脂液をゲル化させるのに、加熱と放置で合計27分を
要し、実施例１と比べ生産性が悪い。また、製品毎にゲ
ル化の度合いが異なり、安定しなかった。In this case, the tensile stress of 13 tons did not cause any breakage, and no delamination occurred at all. Further, at the breaking water pressure (40 kg / cm 2 ), weeping (water oozing) did not occur at all. However, it takes 27 minutes in total for heating and leaving to gel the thermosetting resin liquid on the surface of the mandrel, and the productivity is lower than that in Example 1. In addition, the degree of gelation was different for each product and was not stable.
【００３８】[0038]
【発明の効果】上述の通り、この発明の繊維強化樹脂成
形品の製造方法は、マンドレルの表面に光硬化剤と熱硬
化剤を含有する硬化性樹脂液を塗布し、これに光を照射
して硬化性樹脂液をゲル化させ、その外周に熱硬化性樹
脂液を含浸させたロービング繊維材を巻付けて積層し、
これを常温で又は加熱して全部の樹脂を硬化させるもの
であって、それにより成形品の内側部分にクラックやボ
イドの発生がなく、流体による内圧がかかるような用途
でウイーピングの発生しない製品を安定して生産性よく
製造することができる。As described above, according to the method for producing a fiber-reinforced resin molded product of the present invention, a curable resin liquid containing a photo-curing agent and a thermo-curing agent is applied to the surface of a mandrel, and this is irradiated with light. To gel the curable resin liquid, wrap the roving fiber material impregnated with the thermosetting resin liquid around the outer periphery, and stack it,
This is a product that cures all resins by heating at room temperature or by heating, so that cracks and voids do not occur inside the molded product, and weeping does not occur in applications where internal pressure is applied by fluid. It can be stably manufactured with high productivity.
【図１】この発明の一実施例を示す説明図である。FIG. 1 is an explanatory diagram showing an embodiment of the present invention.
11 ロービング繊維 12 ロービング繊維 13 ロービング繊維 11' 樹脂含浸ロービング繊維 12' 樹脂含浸ロービング繊維 13' 樹脂含浸ロービング繊維 40 樹脂含浸ロール 41 含浸槽 50 トラバースアイ 60 テープ状の樹脂含浸ロービング繊維 70 Ｔ字形のマンドレル。 11 roving fiber 12 roving fiber 13 roving fiber 11 'Resin impregnated roving fiber 12 'resin impregnated roving fiber 13 'resin impregnated roving fiber 40 Resin impregnated roll 41 Impregnation tank 50 traverse eyes 60 Tape-shaped resin-impregnated roving fiber 70 T-shaped mandrel.
Claims (3)
を含有する硬化性樹脂液を塗布し、これに光を照射して
硬化性樹脂液をゲル化させ、その外周に熱硬化性樹脂液
を含浸させたロービング繊維材を巻付けて積層し、これ
を常温で又は加熱して全部の樹脂を硬化させることを特
徴とする繊維強化樹脂成形品の製造方法。1. A curable resin liquid containing a photo-curing agent and a thermo-curing agent is applied to the surface of a mandrel, and the curable resin liquid is gelated by irradiating it with light, and the thermosetting resin is applied to the outer periphery of the curable resin liquid. A method for producing a fiber-reinforced resin molded article, which comprises winding and laminating a roving fiber material impregnated with a liquid, and curing the resin at room temperature or by heating all the resins.
脂液に充填剤が含有されていることを特徴とする請求項
１記載の繊維強化樹脂成形品の製造方法。2. The method for producing a fiber-reinforced resin molded article according to claim 1, wherein a curable resin liquid containing a photocuring agent and a thermosetting agent contains a filler.
脂液にガラス短繊維が含有されていることを特徴とする
請求項１記載の繊維強化樹脂成形品の製造方法。3. The method for producing a fiber-reinforced resin molded article according to claim 1, wherein the curable resin liquid containing a photo-curing agent and a thermosetting agent contains short glass fibers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP03153211A JP3115023B2 (en) | 1991-06-25 | 1991-06-25 | Manufacturing method of fiber reinforced resin molded product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP03153211A JP3115023B2 (en) | 1991-06-25 | 1991-06-25 | Manufacturing method of fiber reinforced resin molded product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05457A true JPH05457A (en) | 1993-01-08 |
| JP3115023B2 JP3115023B2 (en) | 2000-12-04 |
Family
ID=15557479
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP03153211A Expired - Fee Related JP3115023B2 (en) | 1991-06-25 | 1991-06-25 | Manufacturing method of fiber reinforced resin molded product |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3115023B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100301360B1 (en) * | 1998-02-05 | 2001-09-22 | 니시무로 타이죠 | Process for preparing filament winding product |
| JP2009505866A (en) * | 2005-08-24 | 2009-02-12 | ウォルター ダブリュー． クセック | Method for producing reinforced PVC plastisol resin and product prepared thereby |
| JP2018161821A (en) * | 2017-03-27 | 2018-10-18 | トヨタ自動車株式会社 | Method for manufacturing high pressure tank |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105313344A (en) * | 2015-01-07 | 2016-02-10 | 北京玻钢院复合材料有限公司 | Winding molding device adopting sealed gum dipping |
-
1991
- 1991-06-25 JP JP03153211A patent/JP3115023B2/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100301360B1 (en) * | 1998-02-05 | 2001-09-22 | 니시무로 타이죠 | Process for preparing filament winding product |
| JP2009505866A (en) * | 2005-08-24 | 2009-02-12 | ウォルター ダブリュー． クセック | Method for producing reinforced PVC plastisol resin and product prepared thereby |
| JP2018161821A (en) * | 2017-03-27 | 2018-10-18 | トヨタ自動車株式会社 | Method for manufacturing high pressure tank |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3115023B2 (en) | 2000-12-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4892764A (en) | Fiber/resin composites, and method of making the same | |
| US4515737A (en) | Process for producing composite plastic pipe | |
| US3661670A (en) | Method of forming fiber glass pipe with integral joint thread | |
| JP2020510157A5 (en) | ||
| JPH05457A (en) | Manufacture of fiber reinforced resin molded product | |
| EP0510097A1 (en) | Process of forming fiber reinforced molded plastic articles and preforms therefor using a photosetting binder | |
| JP3375375B2 (en) | Method for producing fiber-reinforced resin tubular body | |
| JP3126442B2 (en) | Method of manufacturing fiber-reinforced resin fine wire | |
| JP2530698B2 (en) | Blow molding of curable resin and blow molding method thereof | |
| JP3327984B2 (en) | Method for producing fiber-reinforced resin shaped rods | |
| JPH0333045A (en) | Production of fiber reinforced resin wire rod with spiral recess | |
| JPH0137259B2 (en) | ||
| JPS5948120A (en) | Continuous draw forming of heat resisting fiber reinforced plastic pipe | |
| EP0558366A1 (en) | Process of making a rigid multi-layer preform | |
| WO2005057263A1 (en) | Frp tension member for drop optical fiber cable | |
| JPS61195827A (en) | Molding method of fiber reinforced plastic spring | |
| JP2996481B2 (en) | Method for manufacturing fiber reinforced curable resin spacer for supporting optical fiber | |
| JPS63205327A (en) | Cordlike or rodlike hollow prepreg | |
| JPS62773B2 (en) | ||
| JP4160966B2 (en) | Method for producing fiber-reinforced plastic tubular molded body | |
| JP4404535B2 (en) | Method for producing fiber-reinforced resin molded body | |
| JPH0691768A (en) | Manufacture of fiber-reinforced resin molded form by filament winding method | |
| JPH08267583A (en) | Production of fiber reinforced resin pipe | |
| JPH06166110A (en) | Stick-like article made of fiber reinforced resin | |
| JPH0751638B2 (en) | Method for manufacturing string-shaped or rod-shaped prepreg |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20070929 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080929 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080929 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090929 Year of fee payment: 9 |
|
| LAPS | Cancellation because of no payment of annual fees |