JPH04247002A - Method for eliminating herbicide and weed - Google Patents
Method for eliminating herbicide and weedInfo
- Publication number
- JPH04247002A JPH04247002A JP3258828A JP25882891A JPH04247002A JP H04247002 A JPH04247002 A JP H04247002A JP 3258828 A JP3258828 A JP 3258828A JP 25882891 A JP25882891 A JP 25882891A JP H04247002 A JPH04247002 A JP H04247002A
- Authority
- JP
- Japan
- Prior art keywords
- herbicide
- weed
- rice
- benfuresate
- active ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 241000196324 Embryophyta Species 0.000 title claims abstract description 13
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 12
- 239000004009 herbicide Substances 0.000 title claims abstract description 10
- 238000000034 method Methods 0.000 title claims description 4
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 10
- 235000009566 rice Nutrition 0.000 claims abstract description 9
- 239000004480 active ingredient Substances 0.000 claims abstract description 8
- 108090000623 proteins and genes Proteins 0.000 claims abstract 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 241000209094 Oryza Species 0.000 abstract description 9
- QGQSRQPXXMTJCM-UHFFFAOYSA-N Benfuresate Chemical compound CCS(=O)(=O)OC1=CC=C2OCC(C)(C)C2=C1 QGQSRQPXXMTJCM-UHFFFAOYSA-N 0.000 abstract description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract description 2
- 230000003042 antagnostic effect Effects 0.000 abstract description 2
- 239000004202 carbamide Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- NNYRZQHKCHEXSD-UHFFFAOYSA-N Daimuron Chemical compound C1=CC(C)=CC=C1NC(=O)NC(C)(C)C1=CC=CC=C1 NNYRZQHKCHEXSD-UHFFFAOYSA-N 0.000 abstract 2
- 239000003974 emollient agent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 241000234653 Cyperus Species 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- -1 polyoxyethylene Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 241000192043 Echinochloa Species 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000000729 antidote Substances 0.000 description 1
- 229940075522 antidotes Drugs 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 244000082735 tidal marsh flat sedge Species 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【0001】0001
【産業上の利用分野】本発明は、ベンフレセート(be
nfuresate)およびダイムロン(dymron
)からなる新規除草剤に関する。[Industrial Field of Application] The present invention relates to benfuresate (benfuresate).
nfuresate) and dymron (dymron
).
【0002】0002
【発明の構成】有効成分として、
a) ベンフレセートと
b) ダイムロン
の混合物を含有する除草剤は、一定の栽培植物、例えば
、イネにおいて、良好な選択的除草活性を有することが
見出された。It has been found that herbicides containing as active ingredients a mixture of a) benfuresate and b) Daimeron have good selective herbicidal activity in certain cultivated plants, such as rice.
【0003】これらの成分またはその混合物は、栽培植
物において拮抗作用を示し、かつ解毒剤または緩和剤と
呼称することができる。These components or mixtures thereof exhibit antagonistic effects in cultivated plants and can be referred to as antidotes or palliatives.
【0004】ベンフレセートは、一般名を2,3‐ジヒ
ドロ‐3,3‐ジメチル‐5‐ベンゾフラニルエタンス
ルホネートという。Benfuresate has a common name 2,3-dihydro-3,3-dimethyl-5-benzofuranylethanesulfonate.
【0005】ダイムロンは、一般名を1‐(4‐メチル
フェニル)‐3‐(1‐メチル‐1‐フェニエチル)尿
素という。Daimeron's generic name is 1-(4-methylphenyl)-3-(1-methyl-1-phenythyl)urea.
【0006】成分a)とb)との重量比は、一般に1:
10〜10:1の間である。The weight ratio of components a) and b) is generally 1:
It is between 10 and 10:1.
【0007】本発明による混合物は、別の活性剤、例え
ば、別の植物防護剤または殺虫剤との混合物で使用され
てもよい。The mixtures according to the invention may also be used in mixtures with other active agents, for example other plant protection agents or insecticides.
【0008】作用の強さおよび速度の改善は、例えば、
有機溶剤、潤滑剤および油のような適当な助剤の添加に
よって得られる。このような添加剤は、用量の減少を可
能にすることができる。Improvements in the strength and speed of action can be achieved, for example, by
Obtained by addition of suitable auxiliaries such as organic solvents, lubricants and oils. Such additives may allow dosage reduction.
【0009】記載された有効成分またはこれらの混合物
は、適宜、例えば、粉末、微粉末、顆粒、溶液、乳濁液
または懸濁液として、液状担体および/または固体状担
体および/または稀釈剤および場合によっては、結合助
剤、潤滑助剤、乳化助剤および/または分散助剤を添加
しながら使用することができる。The active ingredients or mixtures thereof may be present in the presence of liquid and/or solid carriers and/or diluents, for example as powders, fine powders, granules, solutions, emulsions or suspensions, as appropriate. Optionally, binding aids, lubricating aids, emulsifying aids and/or dispersing aids can also be used.
【0010】適当な液状担体は、例えば、脂肪族炭化水
素および芳香族炭化水素、例えば、ベンゼン、トルエン
、キシレン、シクロヘキサノン、イソホロン、ジメチル
スルホキシド、ジメチルホルムアミドおよび別の鉱油画
分および植物油である。Suitable liquid carriers are, for example, aliphatic and aromatic hydrocarbons, such as benzene, toluene, xylene, cyclohexanone, isophorone, dimethylsulfoxide, dimethylformamide and further mineral oil fractions and vegetable oils.
【0011】適当な固体状担体は、例えば、ベントナイ
ト、シリカゲル、滑石、陶土、アタパルジャイト、石灰
石、珪酸および植物製品、例えば、小麦粉を包含する。Suitable solid carriers include, for example, bentonite, silica gel, talc, china clay, attapulgite, limestone, silicic acid and vegetable products such as flour.
【0012】界面活性剤として、例えば、カルシウムリ
グノスルホネート、ポリオキシエチレンアルキルフェニ
ルエーテル、ナフタリンスルホン酸およびこれらの塩、
フェノールスルホン酸およびこれらの塩、ホルムアルデ
ヒド縮合物、脂肪アルコ−ル硫酸並びに置換されたベン
ゼンスルホン酸およびこれらの塩が使用できる。Examples of surfactants include calcium lignosulfonate, polyoxyethylene alkylphenyl ether, naphthalene sulfonic acid and salts thereof,
Phenolsulfonic acids and their salts, formaldehyde condensates, fatty alcohol sulfates and substituted benzenesulfonic acids and their salts can be used.
【0013】種種の調製剤中の有効成分の百分率は、広
範囲に及ぶことができる。例えば、組成物は、有効成分
約10〜90重量%および液状担体または固体状担体9
0〜10重量%並びに場合によっては、界面活性剤20
重量%までを含有してよい。The percentage of active ingredient in the various preparations can vary within a wide range. For example, the composition may include about 10-90% by weight of active ingredient and 9% by weight of a liquid or solid carrier.
0 to 10% by weight and optionally surfactant 20%
% by weight.
【0014】薬剤は、常法では、例えば、担体としての
水と共に容量約100〜1000l/haの噴霧混合物
中で供給され得る。薬剤は、公知技術の低容量または超
低容量を用いて、もしくはいわゆる極微粒子の形で供給
され得る。The drug can be supplied in a conventional manner, for example in a spray mixture with a volume of about 100 to 1000 l/ha with water as carrier. The drug can be delivered using low or ultra-low volumes known in the art or in the form of so-called microparticles.
【0015】前記記載の調製は、公知の方法で、例えば
粉砕工程または混合工程によって実施することができる
。場合によっては、個個の成分は使用の直前に、例えば
、いわゆる一般に使用されたタンクミクシング(tan
k‐mixing)法によって混合することができる。The preparations described above can be carried out in known manner, for example by grinding or mixing steps. In some cases, the individual ingredients may be subjected to immediately prior to use, for example in the so-called commonly used tank mixing
k-mixing) method.
【0016】以下の実施例は、本発明による組成物の使
用を記載している。The following examples describe the use of compositions according to the invention.
【0017】[0017]
【実施例】例A
容器(13.5×13.5cmおよび高さ8.0cm)
を、いぬびえ(Echinochloa crus‐
galli)の種子およびみずがやつり(Cyperu
s serotinus)の塊茎を含有する土壌90
0mlを用いて充填した。1日後に容器を、乾燥を避け
るためにプラスチック薄膜を用いて覆った。2日後に、
2.5葉段階に達したイネ科植物〔変種コシヒカリ(k
oshihikari)〕を3cmおよび1cmの深さ
で容器の中に移植した。深さ1cmの苗を、杭で支えた
。イネを栽培して3日後、有効成分の溶液を土壌の表面
上へ、ピペットを用いてできるだけ平均的に分布させた
。
容器を1〜2のレベルに水で充填した。使用の18日後
、百分率での損傷を評価した。評価を対照と比較して実
施した。[Example] Example A Container (13.5 x 13.5 cm and height 8.0 cm)
Echinochloa crus-
seeds of Cyperu galli and seeds of Cyperu galli
Soil containing tubers of S serotinus)90
It was filled using 0 ml. After one day, the containers were covered with a plastic membrane to avoid drying out. Two days later,
A grass family plant that has reached the 2.5-leaf stage [variety Koshihikari (k
oshihikari)] were transplanted into the containers at a depth of 3 cm and 1 cm. Seedlings were supported at a depth of 1 cm with stakes. After 3 days of cultivating the rice, the solution of the active ingredient was distributed over the soil surface using a pipette as evenly as possible. The container was filled with water to 1-2 levels. After 18 days of use, the damage in percentage was evaluated. Evaluations were performed in comparison to controls.
【0018】結果を以下の表中に表示し、この場合、O
RYSP = 深さ3cmのイネ(Oryza
sativa)
ORYSI = 深さ1cmのイネ(Oryza
sativa)
ECHCG = いぬびえ(Echinochlo
a crus‐galli)
CYPSE = みずがやつり(Cyperus
serotinus)を表す。The results are shown in the table below, where O
RYSP = 3cm deep rice (Oryza)
sativa) ORYSI = 1 cm deep rice (Oryza
sativa) ECHCG = Echinochlo
a crus-galli) CYPSE = water hawk (Cyperus
serotinus).
【0019】
O O
E C
R R C Y
Y Y
H P
S S C S
成分 g/ha中の割
合 P I G E
ベンフレセート 50
0 0 90 90 100
750 5 90 90
100
1000 5 90
90 95 ダイムロン
500 0 0
10 40
1000 0
0 10 50 ベンフレセート
+ダイムロン 500+ 500
0 10 80 90
500+1000
0 10 80 90
750+ 50
0 5 20 90 100
750+100
0 5 10 90 100
1000+ 50
0 5 50 100 95
1000+1000
5 50 100 100全濃度に
おいて、混合物は1cmの深さで栽培されたイネの中で
明白な毒性緩和効果を示すことが認められた。
いぬびえ(Echinochloa crus‐ga
lli)およびみずがやつり(Cyperus se
rotinus)に対する除草活性は、ほとんど影響を
及ぼされなかった。[0019]
O O
E C
R R C Y
Y Y
HP
S S C S
Component Proportion in g/ha P I G E
Benfresate 50
0 0 90 90 100
750 5 90 90
100
1000 5 90
90 95 Daimeron
500 0 0
10 40
1000 0
0 10 50 Benfresate + Daimron 500+ 500
0 10 80 90
500+1000
0 10 80 90
750+50
0 5 20 90 100
750+100
0 5 10 90 100
1000+50
0 5 50 100 95
1000+1000
5 50 100 100 At all concentrations, the mixture was observed to exhibit obvious toxicity mitigation effects in rice grown at a depth of 1 cm. Echinochloa crus-ga
lli) and water hawk (Cyperus se
The herbicidal activity against P. rotinus was hardly affected.
Claims (4)
) ベンフレセートと b) ダイムロン との混合物を含有することを特徴とする除草剤。Claim 1: In a herbicide, as an active ingredient, a
A herbicide characterized in that it contains a mixture of a) Benfresate and b) Daimeron.
〜10:1の間である、請求項1記載の除草剤。[Claim 2] The weight ratio of components a) and b) is 1:10.
2. The herbicide of claim 1, wherein the herbicide is between 10:1 and 10:1.
たは雑草の遺伝子に対して、請求項1または2記載の除
草剤を使用することを特徴とする、雑草を防除する方法
。3. A method for controlling weeds, which comprises using the herbicide according to claim 1 or 2 against weeds or the genes of the weeds.
記載の方法。Claim 4: Claim 3, which controls weeds in rice.
Method described.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4032465.6 | 1990-10-10 | ||
DE4032465A DE4032465A1 (en) | 1990-10-10 | 1990-10-10 | Herbicide with protective effect on crops - contains benfuresate and dymrone and is esp. for use in rice crops |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH04247002A true JPH04247002A (en) | 1992-09-03 |
JP3300001B2 JP3300001B2 (en) | 2002-07-08 |
Family
ID=6416185
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP25882891A Expired - Fee Related JP3300001B2 (en) | 1990-10-10 | 1991-10-07 | Herbicides and methods for controlling weeds |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP3300001B2 (en) |
KR (1) | KR0166975B1 (en) |
DE (1) | DE4032465A1 (en) |
-
1990
- 1990-10-10 DE DE4032465A patent/DE4032465A1/en not_active Withdrawn
-
1991
- 1991-10-07 JP JP25882891A patent/JP3300001B2/en not_active Expired - Fee Related
- 1991-10-09 KR KR1019910017670A patent/KR0166975B1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
JP3300001B2 (en) | 2002-07-08 |
DE4032465A1 (en) | 1992-04-16 |
KR920007538A (en) | 1992-05-27 |
KR0166975B1 (en) | 1999-01-15 |
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