JP7584243B2 - Liquid or semi-solid acidic seasonings - Google Patents
Liquid or semi-solid acidic seasonings Download PDFInfo
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- JP7584243B2 JP7584243B2 JP2020095286A JP2020095286A JP7584243B2 JP 7584243 B2 JP7584243 B2 JP 7584243B2 JP 2020095286 A JP2020095286 A JP 2020095286A JP 2020095286 A JP2020095286 A JP 2020095286A JP 7584243 B2 JP7584243 B2 JP 7584243B2
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- liquid
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- oil
- solid acidic
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Description
本発明は、液状又は半固体状酸性調味料に関する。また、本発明は、液状又は半固体状酸性調味料の製造方法に関する。また、本発明は、液状又は半固体状酸性調味料における油脂の分散安定性を向上させる方法に関する。また、本発明は、液状又は半固体状酸性調味料における油脂の分散安定性向上剤に関する。 The present invention relates to a liquid or semi-solid acidic seasoning. The present invention also relates to a method for producing a liquid or semi-solid acidic seasoning. The present invention also relates to a method for improving the dispersion stability of fats and oils in a liquid or semi-solid acidic seasoning. The present invention also relates to an agent for improving the dispersion stability of fats and oils in a liquid or semi-solid acidic seasoning.
水及び油脂を含有する液状又は半固体状酸性調味料は数多く存在するが、通常、油脂を水中に油滴として安定に分散させるために、卵黄や乳化剤が使用される。乳化剤としては、具体的には、界面活性剤や両親媒性の乳化性多糖類(例えば、アラビアガム、ガティガム等)が使用され、当該乳化剤が均質化処理によって生じた油滴と水との界面に吸着してミセルを形成し、油滴を水中に分散安定させる。このように、乳化剤を使用して油滴を分散させた液状又は半固体状酸性調味料は、油滴の分散が維持された状態で長期間安定に保存できるので、喫食前に容器を振る必要が無く、利便性が高いという利点を有する。 There are many liquid or semi-solid acidic seasonings that contain water and fats and oils, but egg yolk or an emulsifier is usually used to stably disperse the fats and oils as oil droplets in the water. Specifically, surfactants and amphipathic emulsifying polysaccharides (e.g., gum arabic, gum ghatti, etc.) are used as emulsifiers, and the emulsifier adsorbs to the interface between the oil droplets generated by the homogenization process and the water to form micelles, stably dispersing the oil droplets in the water. In this way, liquid or semi-solid acidic seasonings in which oil droplets are dispersed using an emulsifier can be stored stably for long periods of time while maintaining the dispersion of the oil droplets, and have the advantage of being highly convenient, as there is no need to shake the container before eating.
人間の舌が美味しさを感じるファクターの一つとして、油の存在感(油脂感)が挙げられる。しかし、乳化剤を使用して油滴を分散させた液状又は半固体状酸性調味料では、乳化粒子径が小さくなる傾向があり、また油滴の表面を乳化剤が覆ってしまうため、油脂感が損なわれるという欠点を有している。 One of the factors that determines the palatability of a food to the human tongue is the presence of oil (oily texture). However, liquid or semi-solid acidic seasonings in which oil droplets are dispersed using an emulsifier tend to have small emulsion particle sizes, and the emulsifier covers the surface of the oil droplets, which reduces the oily texture.
乳化剤を使用せずに、又は乳化剤の使用量を抑えつつ、油を水中に安定分散させる試みとしては、例えば、柑橘類を搾汁して得られる原果汁から分離されたパルプ成分を水分80%以上に調整し、臼式摩砕機により粒度2~50μmに微粉砕して得られる処理済パルプ成分又はその乾燥物を配合してなる水中油型乳化食品(特許文献1)や、果物に含有する結晶セルロースから選択されるセルロース0.05~4重量%、ガム質を0.05~2重量%、及び油脂分0.5~95重量%含有する乳化組成物(特許文献2)等が公知である。 Attempts to stably disperse oil in water without using emulsifiers or while minimizing the amount of emulsifier used include, for example, an oil-in-water emulsified food (Patent Document 1) that is made by blending a treated pulp component or its dried product obtained by adjusting the moisture content of the pulp component separated from the raw juice obtained by squeezing citrus fruits to 80% or more and finely grinding it to a particle size of 2 to 50 μm using a mortar-type grinder, and an emulsion composition that contains 0.05 to 4% by weight of cellulose selected from crystalline cellulose contained in fruits, 0.05 to 2% by weight of gum, and 0.5 to 95% by weight of fats and oils (Patent Document 2).
特許文献1及び2に開示された発明では、液状又は半固体状酸性調味料における油脂の分散安定性が十分ではない。また、喫食した際の油脂感が十分でなかったり、べたつきやぬめりといった食感の問題が生じたりする。したがって、本発明は、油脂を1~80質量%含有する液状又は半固体状酸性調味料において、高い油脂感と、べたつきやぬめりが軽減された優れた食感を有しつつも、油脂の分散安定性が向上した液状又は半固体状酸性調味料を提供することを目的とする。 In the inventions disclosed in Patent Documents 1 and 2, the dispersion stability of the oils and fats in the liquid or semi-solid acidic seasonings is insufficient. In addition, the oily feel when eaten is insufficient, and problems with the texture such as stickiness and sliminess occur. Therefore, the object of the present invention is to provide a liquid or semi-solid acidic seasoning containing 1 to 80% by mass of oils and fats, which has a high oily feel and an excellent texture with reduced stickiness and sliminess, while also having improved dispersion stability of the oils and fats.
本発明者は、上記課題を解決するために鋭意検討した結果、(A)油脂を1~80質量%含有する液状又は半固体状酸性調味料において、(B)キサンタンガムを0.005~1質量%、(C)果実由来食物繊維を0.05~2質量%、及び(D)寒天を0.001~0.5質量%併用することにより、高い油脂感と、べたつきやぬめりが軽減された優れた食感を有しつつも、油脂の分散安定性に優れた液状又は半固体状酸性調味料を提供できることを見出し、本発明に至った。 As a result of intensive research to solve the above problems, the present inventors discovered that by combining (A) a liquid or semi-solid acidic seasoning containing 1 to 80% by mass of fats and oils with (B) 0.005 to 1% by mass of xanthan gum, (C) 0.05 to 2% by mass of fruit-derived dietary fiber, and (D) 0.001 to 0.5% by mass of agar, it is possible to provide a liquid or semi-solid acidic seasoning that has a high oily feel and an excellent texture with reduced stickiness and sliminess, while also having excellent dispersion stability of fats and oils, and thus arrived at the present invention.
詳細には、本発明は以下の態様を有する;
項1.以下(A)~(D)を含有する、液状又は半固体状酸性調味料;
(A)油脂を1~80質量%、
(B)キサンタンガムを0.005~1質量%、
(C)果実由来食物繊維を0.05~2質量%、
(D)寒天を0.001~0.5質量%。
項2.液状又は半固体状酸性調味料に、以下(A)~(D)を含有させる工程を含む、液状又は半固体状酸性調味料の製造方法;
(A)油脂を1~80質量%、
(B)キサンタンガムを0.005~1質量%、
(C)果実由来食物繊維を0.05~2質量%、
(D)寒天を0.001~0.5質量%。
項3.(A)油脂を1~80質量%含有する液状又は半固体状酸性調味料における油脂の分散安定性を向上させる方法であって、
液状又は半固体状酸性調味料に、(B)キサンタンガムを0.005~1質量%、(C)果実由来食物繊維を0.05~2質量%、及び(D)寒天を0.001~0.5質量%含有させることを特徴とする、液状又は半固体状酸性調味料における油脂の分散安定性を向上させる方法。
項4.(A)油脂を1~80質量%含有する液状又は半固体状酸性調味料における油脂の分散安定性向上剤であって、
(B)キサンタンガム、(C)果実由来食物繊維、及び(D)寒天を含有することを特徴とする、液状又は半固体状酸性調味料における油脂の分散安定性向上剤。
In detail, the present invention has the following aspects:
Item 1. A liquid or semi-solid acidic seasoning comprising the following (A) to (D):
(A) 1 to 80% by mass of fats and oils,
(B) 0.005 to 1% by mass of xanthan gum,
(C) 0.05 to 2% by mass of fruit-derived dietary fiber,
(D) 0.001 to 0.5% by mass of agar.
Item 2. A method for producing a liquid or semi-solid acidic seasoning, comprising the steps of: (A) adding the following (A) to (D) to the liquid or semi-solid acidic seasoning;
(A) 1 to 80% by mass of fats and oils,
(B) 0.005 to 1% by mass of xanthan gum,
(C) 0.05 to 2% by mass of fruit-derived dietary fiber,
(D) 0.001 to 0.5% by mass of agar.
Item 3. (A) A method for improving the dispersion stability of an oil or fat in a liquid or semi-solid acidic seasoning containing 1 to 80% by mass of an oil or fat,
A method for improving the dispersion stability of oils and fats in a liquid or semi-solid acidic seasoning, comprising adding to the liquid or semi-solid acidic seasoning (B) 0.005 to 1 mass % of xanthan gum, (C) 0.05 to 2 mass % of fruit-derived dietary fiber, and (D) 0.001 to 0.5 mass % of agar.
Item 4. (A) An agent for improving the dispersion stability of an oil or fat in a liquid or semi-solid acidic seasoning containing 1 to 80% by mass of an oil or fat,
An agent for improving the dispersion stability of oils and fats in a liquid or semi-solid acidic seasoning, comprising (B) xanthan gum, (C) fruit-derived dietary fiber, and (D) agar.
本発明によれば、油脂を1~80質量%含有する液状又は半固体状酸性調味料において、高い油脂感と、べたつきやぬめりが軽減された優れた食感を有しつつも、油脂の分散安定性が向上した液状又は半固体状酸性調味料を提供することができる。 According to the present invention, it is possible to provide a liquid or semi-solid acidic seasoning containing 1 to 80% by mass of fats and oils, which has a high oily feel and an excellent texture with reduced stickiness and sliminess, while also improving the dispersion stability of the fats and oils.
本発明において、液状又は半固体状酸性調味料とは、酸性を示す原材料を含有する液状又は半固体状の流動性を有する調味料である。 In the present invention, a liquid or semi-solid acidic seasoning is a seasoning that has liquid or semi-solid fluidity and contains an acidic raw material.
上記酸性を示す原材料とは、例えば、有機酸、無機酸、醸造酢、柑橘系果汁等が挙げられ、具体的には、例えば、乳酸、クエン酸、酢酸、グルコン酸(グルコノデルタラクトンを含む)、アジピン酸、酒石酸、フマル酸、リンゴ酸等の有機酸;リン酸等の無機酸;米酢、玄米酢、もろみ酢、大麦黒酢、その他穀物酢、リンゴ酢、ブドウ酢、その他果実酢等の醸造酢;レモン果汁、リンゴ果汁、ユズ果汁等の柑橘系果汁等が挙げられる。風味の点において、有機酸、醸造酢及び柑橘系果汁からなる群より選択される1種以上を使用することが好ましい。 Examples of raw materials exhibiting acidity include organic acids, inorganic acids, brewed vinegar, citrus juice, etc., and more specifically, examples include organic acids such as lactic acid, citric acid, acetic acid, gluconic acid (including glucono delta lactone), adipic acid, tartaric acid, fumaric acid, malic acid, etc.; inorganic acids such as phosphoric acid; brewed vinegars such as rice vinegar, brown rice vinegar, moromi vinegar, barley black vinegar, other grain vinegars, apple vinegar, grape vinegar, other fruit vinegars; and citrus juices such as lemon juice, apple juice, and yuzu juice. In terms of flavor, it is preferable to use one or more selected from the group consisting of organic acids, brewed vinegar, and citrus juice.
このような液状又は半固体状酸性調味料の商品群としては、例えば、ドレッシング類;ポン酢、おろしだれ、甘酢ソース等のたれ・ソース類等が挙げられる。 Examples of such liquid or semi-solid acidic seasoning products include dressings; sauces and sauces such as ponzu sauce, oroshidare sauce, and sweet and sour sauce.
[1.液状又は半固体状酸性調味料]
本発明は、以下(A)~(D)を含有する、液状又は半固体状酸性調味料に関するものである;
(A)油脂を1~80質量%、
(B)キサンタンガムを0.005~1質量%、
(C)果実由来食物繊維を0.05~2質量%、
(D)寒天を0.001~0.5質量%。
[1. Liquid or semi-solid acidic seasoning]
The present invention relates to a liquid or semi-solid acidic seasoning comprising the following (A) to (D):
(A) 1 to 80% by mass of fats and oils,
(B) 0.005 to 1% by mass of xanthan gum,
(C) 0.05 to 2% by mass of fruit-derived dietary fiber,
(D) 0.001 to 0.5% by mass of agar.
(A)油脂
本発明に係る液状又は半固体状酸性調味料は、油脂を1~80質量%含有する。健康志向の観点から、調味料における油脂の含有量は、例えば、75質量%以下、70質量%以下、65質量%以下、60質量%以下、55質量%以下、50質量%以下、45質量%以下、40質量%以下、35質量%以下、30質量%以下、25質量%以下、20質量%以下、15質量%以下、10質量%以下、5質量%以下とすることができる。また、油脂含量が多いほど、油脂の分散安定性を保持することが困難となるが、本発明によれば、液状又は半固体状酸性調味料における油脂の含有量が、例えば、5質量%以上、10質量%以上、15質量%以上、20質量%以上、25質量%以上、30質量%以上、35質量%以上、40質量%以上、45質量%以上、50質量%以上、55質量%以上、60質量%以上、65質量%以上、70質量%以上、75質量%以上であっても、べたつきやぬめりが軽減された優れた食感を有しつつ、油脂の分散安定性を向上させることができる。
(A) Fats and Oils The liquid or semi-solid acidic seasoning according to the present invention contains 1 to 80% by mass of fats and oils. From the viewpoint of health consciousness, the content of fats and oils in the seasoning can be, for example, 75% by mass or less, 70% by mass or less, 65% by mass or less, 60% by mass or less, 55% by mass or less, 50% by mass or less, 45% by mass or less, 40% by mass or less, 35% by mass or less, 30% by mass or less, 25% by mass or less, 20% by mass or less, 15% by mass or less, 10% by mass or less, or 5% by mass or less. Furthermore, the higher the fat or oil content, the more difficult it becomes to maintain the dispersion stability of the fat or oil. However, according to the present invention, even if the fat or oil content in the liquid or semi-solid acidic seasoning is, for example, 5% by mass or more, 10% by mass or more, 15% by mass or more, 20% by mass or more, 25% by mass or more, 30% by mass or more, 35% by mass or more, 40% by mass or more, 45% by mass or more, 50% by mass or more, 55% by mass or more, 60% by mass or more, 65% by mass or more, 70% by mass or more, or 75% by mass or more, the dispersion stability of the fat or oil can be improved while maintaining an excellent texture with reduced stickiness and sliminess.
本発明に係る液状又は半固体状酸性調味料で使用される油脂としては、食用油脂であれば特に制限されず、例えば、菜種油、大豆油、ヒマワリ油、綿実油、落花生油、米油、コーン油、サフラワー油、椿油、オリーブ油、カポック油、胡麻油、月見草油、パーム油、パーム核油、シア脂、サル脂、カカオ脂、ヤシ油、ココナッツ油、キャノーラ油、小麦胚芽油、エゴマ油、シソ油等の植物性油脂;乳脂、牛脂、豚脂、魚油、鯨油等の動物性油脂;及びこれらを加工した食用油脂(例えば、分別油脂、硬化油脂、エステル交換油脂等)等が挙げられる。 The fats and oils used in the liquid or semi-solid acidic seasoning according to the present invention are not particularly limited as long as they are edible fats and oils, and examples thereof include vegetable fats and oils such as rapeseed oil, soybean oil, sunflower oil, cottonseed oil, peanut oil, rice oil, corn oil, safflower oil, camellia oil, olive oil, kapok oil, sesame oil, evening primrose oil, palm oil, palm kernel oil, shea butter, monkey fat, cacao butter, palm oil, coconut oil, canola oil, wheat germ oil, perilla oil, and shiso oil; animal fats and oils such as milk fat, beef tallow, lard, fish oil, and whale oil; and edible fats and oils processed from these (for example, fractionated fats and oils, hardened fats and oils, and interesterified fats and oils, etc.).
一般に、液状又は半固体状酸性調味料における油脂の分散安定性は、乳化粒子が長期的に分散安定しているほど、優れていると評価される。また、油脂の分散安定性は、乳化粒子径が小さい程、向上する傾向がある。本発明においては、調製した油脂が分散した調味料の平均粒子径(μm)を測定することにより、当該水性食品の乳化安定性を評価することができる。なお、本発明において、平均粒子径(μm)とは、レーザー回析式粒度分布測定装置SALD-2100(株式会社島津製作所製)を用いた測定値をいう。 In general, the dispersion stability of fats and oils in liquid or semi-solid acidic seasonings is evaluated as being better the longer the emulsion particles remain stable. Furthermore, the smaller the emulsion particle size, the better the dispersion stability of fats and oils tends to be. In the present invention, the emulsion stability of the aqueous food can be evaluated by measuring the average particle size (μm) of the seasoning in which the prepared fats and oils are dispersed. In the present invention, the average particle size (μm) refers to the value measured using a laser diffraction particle size distribution analyzer SALD-2100 (manufactured by Shimadzu Corporation).
人間の舌が美味しさを感じるファクターの一つとして、油脂の存在感(油脂感)が挙げられるが、乳化剤を使用して油滴を分散させた液状又は半固体状酸性調味料では、乳化粒子径が小さく、油脂感が損なわれる。一方、本発明に係る液状又は半固体状酸性調味料は、一般的な乳化剤を使用して油滴を分散させた液状又は半固体状酸性調味料の乳化粒子よりも大きい粒子径を有する油滴を含有するため、高い油脂感を有する。本発明に係る液状又は半固体状酸性調味料は、例えば、5μm以上、10μm以上、15μm以上、20μm以上、25μm以上、30μm以上、35μm以上、40μm以上、45μm以上、50μm以上、55μm以上、60μm以上、65μm以上、70μm以上、75μm以上、80μm以上、85μm以上、90μm以上、95μm以上、100μm以上の平均粒子径を有する油滴を含有し得る。 One of the factors that determines the palatability of a food to the human tongue is the presence of fats and oils (oily texture), but in liquid or semi-solid acidic seasonings in which oil droplets are dispersed using an emulsifier, the emulsified particle size is small and the oily texture is lost. On the other hand, the liquid or semi-solid acidic seasoning of the present invention contains oil droplets that have a larger particle size than the emulsified particles of liquid or semi-solid acidic seasonings in which oil droplets are dispersed using a general emulsifier, and therefore has a high oily texture. The liquid or semi-solid acidic seasoning of the present invention may contain oil droplets having an average particle size of, for example, 5 μm or more, 10 μm or more, 15 μm or more, 20 μm or more, 25 μm or more, 30 μm or more, 35 μm or more, 40 μm or more, 45 μm or more, 50 μm or more, 55 μm or more, 60 μm or more, 65 μm or more, 70 μm or more, 75 μm or more, 80 μm or more, 85 μm or more, 90 μm or more, 95 μm or more, or 100 μm or more.
本発明では、このように、通常であれば容易に二層分離しやすい、大きな粒子径を有する油滴を含有しつつも、意外にも油脂の長期分散安定性に優れた液状又は半固体状酸性調味料を提供できるという新たな知見に基づいてなされた発明である。本発明において、油脂の分散(状態)が安定している状態とは、油滴が水相中に存在しており、水相と油相が二層に分離していないことを示す。 The present invention is based on the new knowledge that it is possible to provide a liquid or semi-solid acidic seasoning that contains oil droplets with large particle sizes that would normally be easily separated into two layers, but which surprisingly has excellent long-term dispersion stability of the oil. In the present invention, a stable dispersion (state) of the oil means that the oil droplets are present in the aqueous phase, and the aqueous phase and the oil phase are not separated into two layers.
(B)キサンタンガム
本発明に係る液状又は半固体状酸性調味料に使用されるキサンタンガムは、キサントモナス・キャンペストリス(Xanthomonas campestris)が菌体外に生産する多糖類であり、D-マンノース、D-グルコース、D-グルクロン酸から構成されている。主鎖はβ-1,4結合しているD-グルコースからなり、側鎖は主鎖のD-グルコース残基1つおきに、D-マンノース2分子とD-グルクロン酸とが結合している。側鎖の末端にあるD-マンノースは、ピルビン酸塩になっている場合がある。また、主鎖に結合したD-マンノースのC-6位は、アセチル化されている場合がある。キサンタンガムは商業的に入手することができ、例えば、サンエース(登録商標)(三栄源エフ・エフ・アイ株式会社製)が挙げられる。
(B) Xanthan gum Xanthan gum used in the liquid or semi-solid acidic seasoning according to the present invention is a polysaccharide produced extracellularly by Xanthomonas campestris, and is composed of D-mannose, D-glucose, and D-glucuronic acid. The main chain is composed of D-glucose bonded with β-1,4 bonds, and the side chain has two D-mannose molecules and D-glucuronic acid bonded to every other D-glucose residue in the main chain. The D-mannose at the end of the side chain may be pyruvate. In addition, the C-6 position of the D-mannose bonded to the main chain may be acetylated. Xanthan gum is commercially available, and examples thereof include SAN-ACE (registered trademark) (manufactured by SAN-EI GEN F.F.I. Co., Ltd.).
本発明に係る液状又は半固体状酸性調味料における(B)キサンタンガムの含有量は、他の成分の種類やその含有量、調味料の種類等により適宜調整され、特に制限されないが、通常0.005~1質量%、好ましくは0.0075~0.75質量%、より好ましくは0.01~0.5質量%である。 The content of (B) xanthan gum in the liquid or semi-solid acidic seasoning of the present invention is adjusted appropriately depending on the type and content of other ingredients, the type of seasoning, etc., and is not particularly limited, but is usually 0.005 to 1 mass%, preferably 0.0075 to 0.75 mass%, and more preferably 0.01 to 0.5 mass%.
(C)果実由来食物繊維
本発明に係る液状又は半固体状酸性調味料に使用される果実由来食物繊維は、果実を原料として得られる食物繊維であれば特に制限されず、一般に流通している果実由来食物繊維を広く利用することができる。原料の果実としては、例えば、柑橘類(例えば、オレンジ、みかん、いよかん、なつみかん、はっさく、ポンカン、シイクワシャー、かぼす、柚子、グレープフルーツ、レモン、ライム等)、リンゴ、マンゴ、パパイヤ、トマト、なし等が挙げられる。好ましくは柑橘類及び/又はリンゴ由来の食物繊維であり、より好ましくは柑橘類由来の食物繊維であり、更に好ましくはオレンジ、レモン、及びライムからなる群より選択される1種以上由来の食物繊維であり、より更に好ましくはレモン及び/又はライム由来の食物繊維である。
(C) Fruit-derived dietary fiber The fruit-derived dietary fiber used in the liquid or semi-solid acidic seasoning of the present invention is not particularly limited as long as it is dietary fiber obtained from fruit as a raw material, and generally available fruit-derived dietary fiber can be widely used. Examples of raw fruit include citrus fruits (e.g., oranges, mandarin oranges, iyokan oranges, summer mandarins, hassaku oranges, ponkan oranges, shiikuwasha oranges, kabosu oranges, yuzu oranges, grapefruits, lemons, limes, etc.), apples, mangoes, papayas, tomatoes, pears, etc. Dietary fiber derived from citrus fruits and/or apples is preferred, dietary fiber derived from citrus fruits is more preferred, dietary fiber derived from one or more fruits selected from the group consisting of oranges, lemons, and limes is even more preferred, and dietary fiber derived from lemons and/or limes is even more preferred.
本発明に係る液状又は半固体状酸性調味料に使用される(C)果実由来食物繊維は、公知の方法によって得ることができ、例えば、前記果実の圧搾後に果汁を除いた残渣、又はその生成物として調製できる。具体例としては、前記果実からペクチンを採取する際に生じる残渣を乾燥し、粉砕することにより調製できる。本発明に係る液状又は半固体状酸性調味料に使用される(C)果実由来食物繊維は、例えば、果実の細胞のミセル構造が壊れポーラスな構造を有しているものであることができる。 The fruit-derived dietary fiber (C) used in the liquid or semi-solid acidic seasoning of the present invention can be obtained by a known method, and can be prepared, for example, as the residue obtained by removing the juice after squeezing the fruit, or a product thereof. As a specific example, it can be prepared by drying and pulverizing the residue generated when extracting pectin from the fruit. The fruit-derived dietary fiber (C) used in the liquid or semi-solid acidic seasoning of the present invention can be, for example, one having a porous structure in which the micellar structure of fruit cells is broken down.
本発明に係る液状又は半固体状酸性調味料に使用される(C)果実由来食物繊維は、好適に、水溶性食物繊維、及び水不溶性食物繊維を含有する複合型食物繊維であることができる。本発明に係る液状又は半固体状酸性調味料に使用される果実由来食物繊維は、好ましくは、ペクチン質を含有する食物繊維である。
上記水溶性食物繊維としては、例えば、水溶性ヘミセルロース、及びペクチン、並びにそれらの組合せが挙げられる。上記水不溶性食物繊維としては、例えば、セルロース、リグニン、水不溶性ヘミセルロース、及びプロトペクチン、並びにそれらの組合せが挙げられる。
上記複合型食物繊維は、好ましくは、食物繊維を40質量%以上、45質量%以上、50質量%以上、55質量%以上、60質量%以上、65質量%以上、70質量%以上、75質量%以上又は80質量%以上含有することができる。
上記複合型食物繊維は、好ましくは、水溶性食物繊維を、例えば、5質量%以上、10質量%以上、15質量%以上、20質量%以上、25質量%以上、30質量%以上、35質量%以上、40質量%以上、45質量%以上、50質量%以上、55質量%以上又は60質量%以上含有することができる。
上記複合型食物繊維は、好ましくは、水不溶性食物繊維を、5質量%以上、10質量%以上、15質量%以上、20質量%以上、25質量%以上、30質量%以上、35質量%以上、40質量%以上、45質量%以上、50質量%以上、55質量%以上又は60質量%以上含有することができる。
The fruit-derived dietary fiber (C) used in the liquid or semi-solid acidic seasoning of the present invention may be a complex dietary fiber containing water-soluble dietary fiber and water-insoluble dietary fiber, and is preferably a dietary fiber containing pectin.
Examples of the water-soluble dietary fiber include water-soluble hemicellulose and pectin, and combinations thereof. Examples of the water-insoluble dietary fiber include cellulose, lignin, water-insoluble hemicellulose and protopectin, and combinations thereof.
The above-mentioned complex dietary fiber may preferably contain dietary fiber at 40% by mass or more, 45% by mass or more, 50% by mass or more, 55% by mass or more, 60% by mass or more, 65% by mass or more, 70% by mass or more, 75% by mass or more, or 80% by mass or more.
The above-mentioned complex dietary fiber may preferably contain water-soluble dietary fiber in an amount of, for example, 5% by mass or more, 10% by mass or more, 15% by mass or more, 20% by mass or more, 25% by mass or more, 30% by mass or more, 35% by mass or more, 40% by mass or more, 45% by mass or more, 50% by mass or more, 55% by mass or more, or 60% by mass or more.
The above-mentioned complex dietary fiber may preferably contain water-insoluble dietary fiber in an amount of 5% by mass or more, 10% by mass or more, 15% by mass or more, 20% by mass or more, 25% by mass or more, 30% by mass or more, 35% by mass or more, 40% by mass or more, 45% by mass or more, 50% by mass or more, 55% by mass or more, or 60% by mass or more.
上記複合型食物繊維が含有する水溶性食物繊維及び水不溶性食物繊維の質量比は、好ましくは0.05:1~15:1であり、より好ましくは0.075:1~10:1であり、更に好ましくは0.1:1~5:1である。 The mass ratio of water-soluble dietary fiber to water-insoluble dietary fiber contained in the complex dietary fiber is preferably 0.05:1 to 15:1, more preferably 0.075:1 to 10:1, and even more preferably 0.1:1 to 5:1.
上記のような(C)果実由来食物繊維は、商業的に入手することができる。
本発明に関し、食物繊維含有量、水溶性食物繊維含有量、及び水不溶性食物繊維含有量は、プロスキー変法によって測定される。当業者が通常理解する通り、プロスキー変法によって測定された複合型食物繊維の食物繊維含有量は、必ずしも100質量%、又はこれに近い値ではない。
The above-mentioned (C) fruit-derived dietary fiber is commercially available.
In the present invention, the dietary fiber content, the water-soluble dietary fiber content, and the water-insoluble dietary fiber content are measured by the modified Prosky method. As a person skilled in the art would normally understand, the dietary fiber content of complex dietary fiber measured by the modified Prosky method is not necessarily 100% by mass or a value close to it.
本発明に係る液状又は半固体状酸性調味料における(C)果実由来食物繊維の含有量は、特に限定されないが、本発明の効果を顕著に奏する観点から、通常0.05~2質量%、好ましくは0.075~1.75質量%、より好ましくは0.1~1.5質量%である。 The content of (C) fruit-derived dietary fiber in the liquid or semi-solid acidic seasoning of the present invention is not particularly limited, but from the viewpoint of significantly exhibiting the effects of the present invention, it is usually 0.05 to 2 mass%, preferably 0.075 to 1.75 mass%, and more preferably 0.1 to 1.5 mass%.
本発明に係る液状又は半固体状酸性調味料における、(B)キサンタンガム1質量部に対する(C)果実由来食物繊維の含有量は特に限定されないが、本発明の効果を顕著に奏する観点から、好ましくは0.05~400質量部、より好ましくは0.06~80質量部、更に好ましくは0.75~60質量部、より更に好ましくは1~50質量部、特に好ましくは1.2~40質量部、より特に好ましくは1.5~30質量部、殊更に好ましくは1.75~20質量部、最も好ましくは2~10質量部である。 In the liquid or semi-solid acidic seasoning according to the present invention, the content of (C) fruit-derived dietary fiber per 1 part by mass of (B) xanthan gum is not particularly limited, but from the viewpoint of significantly achieving the effects of the present invention, it is preferably 0.05 to 400 parts by mass, more preferably 0.06 to 80 parts by mass, even more preferably 0.75 to 60 parts by mass, even more preferably 1 to 50 parts by mass, particularly preferably 1.2 to 40 parts by mass, even more particularly preferably 1.5 to 30 parts by mass, even more particularly preferably 1.75 to 20 parts by mass, and most preferably 2 to 10 parts by mass.
(D)寒天
本発明に係る液状又は半固体状酸性調味料に使用される寒天は、紅藻(テングサ科、オゴノリ科等)から得られる多糖類である。また、製造技術によりゲル強度を高めた(弱めた)もの、粘弾性を高めた(弱めた)もの、高融点化(低融点化)したもの、低分子化(高分子化)したものなど、いずれのものも使用することができる。また、異なる種類の寒天を組みあわせて使用することもできる。寒天は商業的に入手することができ、例えば、ゲルアップ(登録商標) J-1630(三栄源エフ・エフ・アイ株式会社製)が挙げられる。
(D) Agar The agar used in the liquid or semi-solid acidic seasoning according to the present invention is a polysaccharide obtained from red algae (Geranium family, Gracilaria family, etc.). Any agar with increased (reduced) gel strength, increased (reduced) viscoelasticity, high (low) melting point, low molecular weight (high molecular weight), etc., can be used depending on the manufacturing technique. Different types of agar can also be used in combination. Agar can be commercially obtained, and an example of such agar is Gel Up (registered trademark) J-1630 (manufactured by San-Ei Gen F.F.I. Co., Ltd.).
本発明に係る液状又は半固体状酸性調味料における(D)寒天の含有量は、特に限定されないが、本発明の効果を顕著に奏する観点から、通常0.001~0.5質量%、好ましくは0.003~0.3質量%、より好ましくは0.005~0.1質量%である。 The content of (D) agar in the liquid or semi-solid acidic seasoning of the present invention is not particularly limited, but from the viewpoint of significantly achieving the effects of the present invention, it is usually 0.001 to 0.5 mass%, preferably 0.003 to 0.3 mass%, and more preferably 0.005 to 0.1 mass%.
本発明に係る液状又は半固体状酸性調味料における、(B)キサンタンガム1質量部に対する(D)寒天の含有量は特に限定されないが、本発明の効果を顕著に奏する観点から、好ましくは0.001~100質量部、より好ましくは0.01~50質量部、更に好ましくは0.1~1質量部、より更に好ましくは0.15~0.75質量部、特に好ましくは0.2~0.5質量部である。 In the liquid or semi-solid acidic seasoning according to the present invention, the content of (D) agar per 1 part by mass of (B) xanthan gum is not particularly limited, but from the viewpoint of significantly achieving the effects of the present invention, it is preferably 0.001 to 100 parts by mass, more preferably 0.01 to 50 parts by mass, even more preferably 0.1 to 1 part by mass, even more preferably 0.15 to 0.75 parts by mass, and particularly preferably 0.2 to 0.5 parts by mass.
(その他成分)
本発明に係る液状又は半固体状酸性調味料は、本発明の効果を妨げない範囲において、任意の可食成分を含有することができる。このような任意の可食成分としては、例えば、糖類、高甘味度甘味料、ビタミン類、アミノ酸類、油脂類、タンパク質類、ミネラル類、乳、卵、果汁、果肉、植物抽出物、食物繊維、香料、着色料、調味料、酸味料、抗酸化剤、保存料、抗菌剤等を挙げることができる。
(Other ingredients)
The liquid or semi-solid acidic seasoning according to the present invention may contain any edible component within the range that does not impair the effects of the present invention. Examples of such any edible component include sugars, high-intensity sweeteners, vitamins, amino acids, fats and oils, proteins, minerals, milk, eggs, fruit juice, fruit pulp, plant extracts, dietary fiber, flavors, colorants, seasonings, acidulants, antioxidants, preservatives, antibacterial agents, etc.
本発明に係る液状又は半固体状酸性調味料は、本発明の効果を妨げない範囲において、上記(B)~(D)の成分以外の多糖類を含有することができる。本発明に係る液状又は半固体状酸性調味料に使用することができる多糖類としては、例えば、グァーガム、ローカストビーンガム、タマリンドシードガム、サイリウムシードガム、カラギナン(例えば、カッパカラギナン、イオタカラギナン、ラムダカラギナン等)、ジェランガム(例えば、脱アシル型ジェランガム、ネイティブ型ジェランガム等)、ペクチン(例えば、HMペクチン、LMペクチン等)、グルコマンナン、アルギン酸、アルギン酸塩(例えば、アルギン酸ナトリウム、アルギン酸カリウム、アルギン酸カルシウム等)、マクロホモプシスガム、カードラン、トラガントガム、アラビノガラクタン、カラヤガム、ファーセレラン、キチン、澱粉(例えば、馬鈴薯澱粉、コーンスターチ、タピオカ澱粉、小麦澱粉、米澱粉、豆澱粉、甘藷澱粉、サゴヤシ澱粉等)、化学的、酵素的又は物理的な処理を施した澱粉(例えば、酸分解澱粉、酵素分解澱粉、酸化澱粉、α化澱粉、グラフト化澱粉、エーテル化澱粉、エステル化澱粉、架橋澱粉、加熱処理澱粉、湿熱処理澱粉等)、セルロース類(例えば、カルボキシメチルセルロースナトリウム、カルボキシメチルセルロースカルシウム、カルボキシメチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシプロピルエチルセルロース、ヒドロキシエチルセルロース、ヒドロキシメチルセルロース、エチルセルロース、メチルセルロース、発酵セルロース、結晶セルロース等)、デキストリン類(例えば、ポリデキストロース、難消化性デキストリン等)等が挙げられ、2種以上の多糖類を使用してもよい。 The liquid or semi-solid acidic seasoning of the present invention may contain polysaccharides other than the above components (B) to (D) to the extent that the effects of the present invention are not impaired. Examples of polysaccharides that can be used in the liquid or semi-solid acidic seasoning according to the present invention include guar gum, locust bean gum, tamarind seed gum, psyllium seed gum, carrageenan (e.g., kappa carrageenan, iota carrageenan, lambda carrageenan, etc.), gellan gum (e.g., deacylated gellan gum, native gellan gum, etc.), pectin (e.g., HM pectin, LM pectin, etc.), glucomannan, alginic acid, alginates (e.g., sodium alginate, potassium alginate, calcium alginate, etc.), macrophomopsis gum, curdlan, tragacanth gum, arabinogalactan, karaya gum, furcellaran, chitin, and starch (e.g., potato starch, corn starch, tapioca starch, wheat starch, rice starch, soybean starch, sweet potato starch). , sago palm starch, etc.), starches that have been subjected to chemical, enzymatic or physical treatments (for example, acid-decomposed starch, enzymatically decomposed starch, oxidized starch, gelatinized starch, grafted starch, etherified starch, esterified starch, crosslinked starch, heat-treated starch, moist heat-treated starch, etc.), celluloses (for example, sodium carboxymethylcellulose, calcium carboxymethylcellulose, carboxymethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxypropylethylcellulose, hydroxyethylcellulose, hydroxymethylcellulose, ethylcellulose, methylcellulose, fermented cellulose, crystalline cellulose, etc.), dextrins (for example, polydextrose, resistant dextrin, etc.), etc., and two or more kinds of polysaccharides may be used.
本発明に係る液状又は半固体状酸性調味料における水分の含有量は、例えば、95質量%以下、90質量%以下、85質量%以下、80質量%以下、75質量%以下、70質量%以下、65質量%以下、60質量%以下、55質量%以下、50質量%以下とすることができる。また、液状又は半固体状酸性調味料における水分の含有量は、例えば、5質量%以上、10質量%以上、15質量%以上、20質量%以上、25質量%以上、30質量%以上、35質量%以上、40質量%以上、45質量%以上とすることができる。本発明に係る液状又は半固体状酸性調味料における水分の含有量は、好ましくは10~95質量%、より好ましくは15~85質量%、更に好ましくは20~75質量%、より更に好ましくは25~65質量%、特に好ましくは30~60質量%である。 The water content in the liquid or semi-solid acidic seasoning according to the present invention can be, for example, 95% by mass or less, 90% by mass or less, 85% by mass or less, 80% by mass or less, 75% by mass or less, 70% by mass or less, 65% by mass or less, 60% by mass or less, 55% by mass or less, or 50% by mass or less. The water content in the liquid or semi-solid acidic seasoning according to the present invention can be, for example, 5% by mass or more, 10% by mass or more, 15% by mass or more, 20% by mass or more, 25% by mass or more, 30% by mass or more, 35% by mass or more, 40% by mass or more, or 45% by mass or more. The water content in the liquid or semi-solid acidic seasoning according to the present invention is preferably 10 to 95% by mass, more preferably 15 to 85% by mass, even more preferably 20 to 75% by mass, even more preferably 25 to 65% by mass, and particularly preferably 30 to 60% by mass.
(pH)
本発明に係る液状又は半固体状酸性調味料のpHは、酸性であれば特に制限されないが、例えば、pH6.5以下、pH6以下、pH5.5以下、pH5以下、pH4.5以下、pH4以下であっても、安定性が低下することなく長期的に油脂の分散を保持できる。
なお、本発明においてpHの測定方法は、対象試料を温度25℃に調温し、pHメータ(HORIBA社製、ポータブルpHメータ〈D-72〉)を用い、対象試料へ電極を浸漬した後、1分後に測定する。
(pH)
The pH of the liquid or semi-solid acidic seasoning of the present invention is not particularly limited as long as it is acidic, but even if it is, for example, pH 6.5 or less, pH 6 or less, pH 5.5 or less, pH 5 or less, pH 4.5 or less, or pH 4 or less, the dispersion of oils and fats can be maintained for a long period of time without a decrease in stability.
In the present invention, the pH is measured by adjusting the temperature of the target sample to 25° C., immersing an electrode in the target sample using a pH meter (HORIBA Portable pH Meter D-72) and measuring the pH one minute later.
(粘度)
本発明に係る液状又は半固体状酸性調味料の粘度は、好ましくは10,000mPa・s以下、より好ましくは7,000mPa・s以下、更に好ましくは5,000mPa・s以下、より更に好ましくは2,500mPa・s以下とすることができる。
本明細書において、粘度は、液状又は半固体状酸性調味料を25℃の条件下で、B型回転粘度計を用いて回転数60rpmで1分間測定することによって求められ、以下の方法によって測定された値を示す。
当該測定においては、液状又は半固体状酸性調味料の粘度に応じて、次のローターを使用する。
ローター1号1~100mPa・s
ローター2号101~500mPa・s
ローター3号501~2,000mPa・s
ローター4号2,001~10,000mPa・s
一般に、水及び油を含有する食品は、粘度が高い程、油相と水相との二層への分離が抑制されやすい。しかし、本発明に係る液状又は半固体状酸性調味料は、25℃における粘度が2,500mPa・s以下といった低粘度であっても、良好な油脂の分散安定性を有する。
(viscosity)
The viscosity of the liquid or semi-solid acidic seasoning according to the present invention can be preferably 10,000 mPa·s or less, more preferably 7,000 mPa·s or less, even more preferably 5,000 mPa·s or less, and even more preferably 2,500 mPa·s or less.
In this specification, the viscosity is determined by measuring a liquid or semi-solid acidic seasoning at 25°C for 1 minute using a B-type rotational viscometer at a rotation speed of 60 rpm, and indicates the value measured by the following method.
In the measurement, the following rotors are used depending on the viscosity of the liquid or semi-solid acidic seasoning.
Rotor No. 1: 1 to 100 mPa·s
Rotor No. 2 101 to 500 mPa·s
Rotor No. 3 501 to 2,000 mPa·s
Rotor No. 4 2,001 to 10,000 mPa·s
In general, the higher the viscosity of a food containing water and oil, the more likely it is that separation into two layers, an oil phase and an aqueous phase, is suppressed. However, the liquid or semi-solid acidic seasoning according to the present invention has good dispersion stability for oils and fats even when it has a low viscosity of 2,500 mPa·s or less at 25° C.
[2.液状又は半固体状酸性調味料の製造方法]
本発明は、液状又は半固体状酸性調味料に、以下(A)~(D)を含有させる工程を含む、液状又は半固体状酸性調味料の製造方法に関するものである;
(A)油脂を1~80質量%、
(B)キサンタンガムを0.005~1質量%、
(C)果実由来食物繊維を0.05~2質量%、
(D)寒天を0.001~0.5質量%。
[2. Method for producing liquid or semi-solid acidic seasoning]
The present invention relates to a method for producing a liquid or semi-solid acidic seasoning, the method comprising the steps of:
(A) 1 to 80% by mass of fats and oils,
(B) 0.005 to 1% by mass of xanthan gum,
(C) 0.05 to 2% by mass of fruit-derived dietary fiber,
(D) 0.001 to 0.5% by mass of agar.
本発明に係る液状又は半固体状酸性調味料の製造方法に使用される成分やその含有量、その他条件等の例は、上記[1.]に記載したとおりである。 Examples of the ingredients and their contents, as well as other conditions, used in the method for producing a liquid or semi-solid acidic seasoning according to the present invention, are as described above in [1.].
本発明に係る液状又は半固体状酸性調味料の製造方法は、液状又は半固体状酸性調味料に上記(A)~(D)の成分を含有させる工程を含めば、これらを含有させる順序や他の工程は特に制限されない。例えば、上記工程の他、食品に製造工程において一般的に行なわれる処理工程として、均質化処理工程、殺菌処理工程等を含むことができる。 The method for producing a liquid or semi-solid acidic seasoning according to the present invention is not particularly limited in the order in which the above components (A) to (D) are contained in the liquid or semi-solid acidic seasoning or in other steps, so long as it includes the step of containing these components in the liquid or semi-solid acidic seasoning. For example, in addition to the above steps, the method may include a homogenization step, a sterilization step, and the like, as processing steps that are generally carried out in the food manufacturing process.
[3.液状又は半固体状酸性調味料における油脂の分散安定性を向上させる方法]
本発明は、(A)油脂を1~80質量%含有する液状又は半固体状酸性調味料における油脂の分散安定性を向上させる方法であって、液状又は半固体状酸性調味料に(B)キサンタンガムを0.005~1質量%、(C)果実由来食物繊維を0.05~2質量%、及び(D)寒天を0.001~0.5質量%含有させることを特徴とする、液状又は半固体状酸性調味料における油脂の分散安定性を向上させる方法に関するものである。
[3. Method for improving dispersion stability of oils and fats in liquid or semi-solid acidic seasonings]
The present invention relates to a method for improving the dispersion stability of fats and oils in a liquid or semi-solid acidic seasoning containing (A) 1 to 80% by mass of fats and oils, the method being characterized in that the liquid or semi-solid acidic seasoning contains (B) 0.005 to 1% by mass of xanthan gum, (C) 0.05 to 2% by mass of fruit-derived dietary fiber, and (D) 0.001 to 0.5% by mass of agar.
本発明に係る液状又は半固体状酸性調味料における油脂の分散安定性を向上させる方法に使用される成分やその含有量、その他の条件等の例は、上記[1.]に記載したとおりである。 Examples of the components and their contents, as well as other conditions, used in the method for improving the dispersion stability of oils and fats in a liquid or semi-solid acidic seasoning according to the present invention, are as described in [1.] above.
本発明に係る液状又は半固体状酸性調味料における油脂の分散安定性を向上させる方法は、調味料に上記(A)~(D)の成分を含有させる工程を含めば、これらを含有させる順序や他の工程は特に制限されず、上記[2.]に記載したとおりである。なお、本発明によれば、均質化処理工程を経ることなく、調味料における油脂の分散安定性を向上させることができる。 The method for improving the dispersion stability of fats and oils in a liquid or semi-solid acidic seasoning according to the present invention includes the step of incorporating the above components (A) to (D) in the seasoning, and the order in which these components are incorporated and other steps are not particularly limited, and are as described in [2.] above. According to the present invention, it is possible to improve the dispersion stability of fats and oils in a seasoning without going through a homogenization treatment step.
本発明によれば、(A)油脂を1~80質量%含有する液状又は半固体状酸性調味料に、(B)キサンタンガムを0.005~1質量%、(C)果実由来食物繊維を0.05~2質量%、及び(D)寒天を0.001~0.5質量%含有させることにより、高い油脂感と、べたつきやぬめりが軽減された優れた食感を有しつつも、油脂の分散安定性を向上させることができる。 According to the present invention, by adding 0.005 to 1 mass % (B) xanthan gum, 0.05 to 2 mass % (C) fruit-derived dietary fiber, and 0.001 to 0.5 mass % (D) agar to a liquid or semi-solid acidic seasoning containing 1 to 80 mass % (A) oils and fats, it is possible to improve the dispersion stability of the oils and fats while maintaining a high oily feel and an excellent texture with reduced stickiness and sliminess.
本発明によれば、液状又は半固体状酸性調味料における油脂の分散安定性を向上させることができるため、油相と水相が分離せず、均一な状態で液状又は半固体状酸性調味料の製造工程・充填工程を進めることができる。また、液状又は半固体状酸性調味料を長期保存する場合であっても油脂の分散安定性が維持される。また、液状又は半固体状酸性調味料の喫食中も油脂の分散安定性が維持される。 According to the present invention, the dispersion stability of fats and oils in a liquid or semi-solid acidic seasoning can be improved, so that the oil and water phases do not separate and the manufacturing and filling processes of the liquid or semi-solid acidic seasoning can be carried out in a uniform state. In addition, the dispersion stability of fats and oils is maintained even when the liquid or semi-solid acidic seasoning is stored for a long period of time. In addition, the dispersion stability of fats and oils is maintained even while the liquid or semi-solid acidic seasoning is being consumed.
[4.液状又は半固体状酸性調味料における油脂の分散安定性向上剤]
本発明は、(A)油脂を1~80質量%含有する液状又は半固体状酸性調味料における油脂の分散安定性向上剤であって、(B)キサンタンガム、(C)果実由来食物繊維、及び(D)寒天を含有することを特徴とする、液状又は半固体状酸性調味料における油脂の分散安定性向上剤に関するものである。
[4. Dispersion stability improver for oils and fats in liquid or semi-solid acidic seasonings]
The present invention relates to (A) an agent for improving the dispersion stability of oils and fats in a liquid or semi-solid acidic seasoning containing 1 to 80 mass % of oils and fats, the agent being characterized by containing (B) xanthan gum, (C) fruit-derived dietary fiber, and (D) agar.
本発明に係る液状又は半固体状酸性調味料における油脂の分散安定性向上剤に使用される成分、その他の条件等の例は、上記[1.]に記載したとおりである。 Examples of ingredients and other conditions used in the dispersion stability improver for oils and fats in the liquid or semi-solid acidic seasoning of the present invention are as described in [1.] above.
本発明に係る液状又は半固体状酸性調味料における油脂の分散安定性向上剤の形状は特に制限されない。例えば、固体形状(例えば、粉末状、顆粒状及び錠剤状等)、液体形状(例えば、溶解液、分散液等)、ペースト等が挙げられる。 The shape of the oil/fat dispersion stability improver in the liquid or semi-solid acidic seasoning of the present invention is not particularly limited. Examples include solid shapes (e.g., powder, granules, tablets, etc.), liquid shapes (e.g., solutions, dispersions, etc.), pastes, etc.
本発明に係る液状又は半固体状酸性調味料における油脂の分散安定性向上剤における、果実由来食物繊維の含有量は、特に限定されないが、油脂の分散安定性向上剤の全量に対して、好ましくは1~99.5質量%であり、より好ましくは10~99質量%、更に好ましくは25~99質量%、より更に好ましくは50~98.5質量%である。 The content of fruit-derived dietary fiber in the dispersion stability improver for oils and fats in the liquid or semi-solid acidic seasoning according to the present invention is not particularly limited, but is preferably 1 to 99.5% by mass, more preferably 10 to 99% by mass, even more preferably 25 to 99% by mass, and even more preferably 50 to 98.5% by mass, based on the total amount of the dispersion stability improver for oils and fats.
本発明に係る液状又は半固体状酸性調味料における油脂の分散安定性向上剤における、(B)キサンタンガムの含有量は、特に限定されないが、油脂の分散安定性向上剤の全量に対して、好ましくは0.05~80質量%であり、より好ましくは0.1~70質量%、更に好ましくは0.5~60質量%、より更に好ましくは1~50質量%である。 The content of (B) xanthan gum in the dispersion stability improver for oils and fats in the liquid or semi-solid acidic seasoning according to the present invention is not particularly limited, but is preferably 0.05 to 80% by mass, more preferably 0.1 to 70% by mass, even more preferably 0.5 to 60% by mass, and even more preferably 1 to 50% by mass, based on the total amount of the dispersion stability improver for oils and fats.
本発明に係る液状又は半固体状酸性調味料における油脂の分散安定性向上剤における、(C)果実由来食物繊維の含有量は、特に限定されないが、油脂の分散安定性向上剤の全量に対して、好ましくは0.05~80質量%であり、より好ましくは0.1~70質量%、更に好ましくは0.5~60質量%、より更に好ましくは1~50質量%である。 The content of (C) fruit-derived dietary fiber in the dispersion stability improver for oils and fats in the liquid or semi-solid acidic seasoning according to the present invention is not particularly limited, but is preferably 0.05 to 80% by mass, more preferably 0.1 to 70% by mass, even more preferably 0.5 to 60% by mass, and even more preferably 1 to 50% by mass, based on the total amount of the dispersion stability improver for oils and fats.
本発明に係る液状又は半固体状酸性調味料における油脂の分散安定性向上剤における、(D)寒天の含有量は、特に限定されないが、油脂の分散安定性向上剤の全量に対して、好ましくは0.05~80質量%であり、より好ましくは0.1~70質量%、更に好ましくは0.5~60質量%、より更に好ましくは1~50質量%である。 The content of (D) agar in the dispersion stability improver for oils and fats in the liquid or semi-solid acidic seasoning according to the present invention is not particularly limited, but is preferably 0.05 to 80% by mass, more preferably 0.1 to 70% by mass, even more preferably 0.5 to 60% by mass, and even more preferably 1 to 50% by mass, based on the total amount of the dispersion stability improver for oils and fats.
本発明に係る液状又は半固体状酸性調味料における油脂の分散安定性向上剤における、(B)キサンタンガム1質量部に対する(C)果実由来食物繊維の含有量は、特に限定されないが、好ましくは0.05~400質量部、より好ましくは0.06~80質量部、更に好ましくは0.75~60質量部、より更に好ましくは1~50質量部、特に好ましくは1.2~40質量部、より特に好ましくは1.5~30質量部、殊更に好ましくは1.75~20質量部、最も好ましくは2~10質量部である。 In the dispersion stability improver for oils and fats in a liquid or semi-solid acidic seasoning according to the present invention, the content of (C) fruit-derived dietary fiber per 1 part by mass of (B) xanthan gum is not particularly limited, but is preferably 0.05 to 400 parts by mass, more preferably 0.06 to 80 parts by mass, even more preferably 0.75 to 60 parts by mass, even more preferably 1 to 50 parts by mass, particularly preferably 1.2 to 40 parts by mass, even more particularly preferably 1.5 to 30 parts by mass, even more preferably 1.75 to 20 parts by mass, and most preferably 2 to 10 parts by mass.
本発明に係る液状又は半固体状酸性調味料における油脂の分散安定性向上剤における、(B)キサンタンガム1質量部に対する(D)寒天の含有量は、特に限定されないが、例えば、0.001~100質量部、より好ましくは0.01~50質量部、更に好ましくは0.1~1質量部、より更に好ましくは0.15~0.75質量部、特に好ましくは0.2~0.5質量部である。 In the dispersion stability improver for oils and fats in a liquid or semi-solid acidic seasoning according to the present invention, the content of (D) agar per 1 part by mass of (B) xanthan gum is not particularly limited, but is, for example, 0.001 to 100 parts by mass, more preferably 0.01 to 50 parts by mass, even more preferably 0.1 to 1 part by mass, still more preferably 0.15 to 0.75 parts by mass, and particularly preferably 0.2 to 0.5 parts by mass.
対象となる液状又は半固体状酸性調味料に対する、本発明に係る液状又は半固体状酸性調味料における油脂の分散安定性向上剤の配合量は、特に限定されないが、本発明の効果を顕著に奏する観点から、液状又は半固体状酸性調味料における(B)キサンタンガム、(C)果実由来食物繊維、及び(D)寒天の含有量が上記[1.]に記載の範囲となるように配合することが好ましい。 The amount of the oil/fat dispersion stability improver in the liquid or semi-solid acidic seasoning of the present invention to be blended relative to the target liquid or semi-solid acidic seasoning is not particularly limited, but from the viewpoint of significantly achieving the effects of the present invention, it is preferable to blend it so that the contents of (B) xanthan gum, (C) fruit-derived dietary fiber, and (D) agar in the liquid or semi-solid acidic seasoning are within the ranges described in [1.] above.
以下に、実施例を用いて本発明を更に詳しく説明する。ただし、これらの例は本発明を制限するものではない。なお、実施例中の「部」「%」は、それぞれ「質量部」「質量%」を意味する。 The present invention will be described in more detail below using examples. However, these examples do not limit the present invention. In the examples, "parts" and "%" mean "parts by mass" and "% by mass", respectively.
[実験例1.液状ドレッシング]
表1及び2の処方に基づき、液状ドレッシングを調製した。詳細には以下のとおりである。
(1)水に多糖類を加え、10分間撹拌を行った。
(2)サラダ油を除く残りの原料を加え、更に5分間撹拌を行った。
(3)ホモミキサーで撹拌しながら、徐々にサラダ油を加え、10,000rpmで10分間撹拌を行った。
(4)85℃まで加温後、容器にホットパック充填した。
なお、果実由来食物繊維は、レモン及び/又はライム由来の食物繊維(水溶性食物繊維含有量22%、水不溶性食物繊維含有量78%)を使用した。
[Experimental Example 1. Liquid Dressing]
Liquid dressings were prepared based on the formulations in Tables 1 and 2. The details are as follows.
(1) The polysaccharide was added to the water and stirred for 10 minutes.
(2) The remaining ingredients except for the salad oil were added and stirred for an additional 5 minutes.
(3) While stirring with a homomixer, salad oil was gradually added and the mixture was stirred at 10,000 rpm for 10 minutes.
(4) After heating to 85°C, the mixture was hot-packed into a container.
The fruit-derived dietary fiber used was dietary fiber derived from lemons and/or limes (soluble dietary fiber content: 22%, water-insoluble dietary fiber content: 78%).
(油脂の分散安定性の評価)
得られた液状ドレッシングを25℃で28日間保存後、油の分離状態を目視にて観察した。結果を表3及び図1に示した。
(Evaluation of Dispersion Stability of Oils and Fats)
The resulting liquid dressing was stored at 25° C. for 28 days, and then the state of oil separation was visually observed. The results are shown in Table 3 and FIG.
(乳化粒子径の評価)
得られた液状ドレッシングを25℃に調温し、レーザー回折式粒度分布測定装置 SALD-2100(株式会社島津製作所製)を使用して、乳化粒子径の測定を行なった。結果を表3に示した。
(Evaluation of Emulsion Particle Size)
The temperature of the obtained liquid dressing was adjusted to 25° C., and the emulsion particle size was measured using a laser diffraction particle size distribution measuring device SALD-2100 (manufactured by Shimadzu Corporation). The results are shown in Table 3.
(粘度)
得られた液状ドレッシングを25℃に調温し、B型回転粘度計 TVB-10(東機産業株式会社製)を使用して、回転数60rpm、1分後の条件で粘度の測定を行った。結果を表3に示した。
(viscosity)
The temperature of the obtained liquid dressing was adjusted to 25° C., and the viscosity was measured using a B-type rotational viscometer TVB-10 (manufactured by Toki Sangyo Co., Ltd.) at a rotation speed of 60 rpm after 1 minute. The results are shown in Table 3.
(油脂感及び食感の評価)
得られた液状ドレッシングを25℃に調温し、油脂感及び食感の判定を日常的に行っているパネラー5名(A~E)により、ブラインドによる官能評価を行った。各評価項目について、良好度合いに応じて3>2>1の3段階評価を行った。具体的な評価基準は次のとおりである。なお、官能評価を実施するにあたり、パネル全体で討議し、各評価項目の特性に対してすり合わせを行って、各パネルが評価基準について共通認識を持つようにした。
(Evaluation of oily and fatty texture and food texture)
The obtained liquid dressing was adjusted to 25°C, and blind sensory evaluation was performed by five panelists (A-E) who routinely judge the oily and fatty texture and food texture. For each evaluation item, a three-level evaluation of 3>2>1 was performed according to the degree of goodness. The specific evaluation criteria are as follows. In conducting the sensory evaluation, the entire panel discussed and refined the characteristics of each evaluation item so that each panelist had a common understanding of the evaluation criteria.
「油脂感」の評価基準
3:油の存在感が非常に舌で感じられやすい。
2:油の存在感が舌で感じられやすい。
1:油の存在感が舌で感じられにくい。
Evaluation standard for "oily feel": 3: The presence of oil is very easily felt on the tongue.
2: The presence of oil is easily felt on the tongue.
1: The presence of oil is hard to sense on the tongue.
「食感」の評価基準
3:ぬめりやべたつきがなく、非常に滑らかな食感を有する。
2:ぬめりやべたつきがなく、滑らかな食感を有する。
1:ぬめりやべたつきがある。
結果を表3に示した。
Evaluation standard for "texture": 3: Not slimy or sticky, and has a very smooth texture.
2: Not slimy or sticky, and has a smooth texture.
1: Slimy or sticky.
The results are shown in Table 3.
キサンタンガム又は寒天のいずれかを欠く比較例1-1~1-4において、比較例1-1、1-3、及び1-4では、25℃で28日間保存後に、容器の上部にて油の分離が観察され、容器の下部にて離水が観察された。そして、比較例1-2では、油相(上層)と水相(下層)との完全分離が観察された。
一方、果実由来食物繊維、キサンタンガム、及び寒天を含有する実施例1-1及び1-2では、大きい粒子径を有する油滴を含有するにもかかわらず、25℃で28日間保存後も、油の分離や離水は観察されず、油の分散安定性に優れていた。さらには、実施例1-1及び1-2は、油の分散安定性に優れるだけではなく、良好な油脂感、及びぬめりやべたつきの無い優れた食感を有していた。
In Comparative Examples 1-1 to 1-4 lacking either xanthan gum or agar, separation of oil was observed in the upper part of the container and syneresis was observed in the lower part of the container after 28 days of storage at 25° C. in Comparative Examples 1-1, 1-3, and 1-4. In Comparative Example 1-2, complete separation of the oil phase (upper layer) and the aqueous phase (lower layer) was observed.
On the other hand, in Examples 1-1 and 1-2 containing fruit-derived dietary fiber, xanthan gum, and agar, even though they contained oil droplets with large particle sizes, no separation of oil or syneresis was observed even after storage for 28 days at 25° C., and the oil dispersion stability was excellent. Furthermore, Examples 1-1 and 1-2 not only had excellent oil dispersion stability, but also had a good oily feel and an excellent texture that was not slimy or sticky.
[実験例2.液状ドレッシング]
表4及び5の処方に基づき、液状ドレッシングを調製した。詳細には以下のとおりである。
(1)水に多糖類を加え、10分間撹拌を行った。
(2)サラダ油を除く残りの原料を加え、更に5分間撹拌を行った。
(3)ホモミキサーで撹拌しながら、徐々にサラダ油を加え、10,000rpmで10分間撹拌を行った。
(4)85℃まで加温後、容器にホットパック充填した。
なお、果実由来食物繊維は、レモン及び/又はライム由来の食物繊維(水溶性食物繊維含有量22%、水不溶性食物繊維含有量78%)を使用した。
[Experimental Example 2. Liquid dressing]
Liquid dressings were prepared based on the formulations in Tables 4 and 5. The details are as follows.
(1) The polysaccharide was added to the water and stirred for 10 minutes.
(2) The remaining ingredients except for the salad oil were added and stirred for an additional 5 minutes.
(3) While stirring with a homomixer, salad oil was gradually added and the mixture was stirred at 10,000 rpm for 10 minutes.
(4) After heating to 85°C, the mixture was hot-packed into a container.
The fruit-derived dietary fiber used was dietary fiber derived from lemons and/or limes (soluble dietary fiber content: 22%, water-insoluble dietary fiber content: 78%).
(油脂の分散安定性の評価)
得られた液状ドレッシングを25℃で28日間保存後、油の分離状態を目視にて観察した。結果を表6及び図2に示した。
(Evaluation of Dispersion Stability of Oils and Fats)
The resulting liquid dressing was stored at 25° C. for 28 days, and then the state of oil separation was visually observed. The results are shown in Table 6 and FIG.
(乳化粒子径の評価)
得られた液状ドレッシングについて、実験例1と同じ手法により、乳化粒子径の測定を行った。結果を表6に示した。
(Evaluation of Emulsion Particle Size)
The emulsion particle size of the obtained liquid dressing was measured by the same method as in Experimental Example 1. The results are shown in Table 6.
(粘度)
得られた液状ドレッシングについて、実験例1と同じ手法により、粘度の測定を行った。結果を表6に示した。
(viscosity)
The viscosity of the resulting liquid dressing was measured in the same manner as in Experimental Example 1. The results are shown in Table 6.
(油脂感及び食感の評価)
得られた液状ドレッシングについて、実験例1と同じ手法により、油脂感及び食感の評価を行った。結果を表6に示した。
(Evaluation of oily and fatty texture and food texture)
The oily and fatty texture and mouthfeel of the obtained liquid dressing were evaluated in the same manner as in Experimental Example 1. The results are shown in Table 6.
乳化性多糖類として、アラビアガム又はガティガムを含有し、寒天を欠く比較例2-1及び2-2では、25℃で28日間保存後に、容器の上部にて油の分離が観察され、容器の下部にて離水が観察された。また、比較例2-2では、油の存在感が舌で感じられにくく、油脂感が顕著に低かった。
一方、果実由来食物繊維、キサンタンガム及び寒天を含有する実施例2-1は、大きい粒子径を有する油滴を含有するにもかかわらず、25℃で28日間保存後も、油の分離や離水は観察されず、油の分散安定性に優れていた。さらに、実施例2-1は、油の分散安定性に優れるだけではなく、良好な油脂感、及びぬめりやべたつきの無い優れた食感を有していた。
In Comparative Examples 2-1 and 2-2, which contained gum arabic or gum ghatti as the emulsifying polysaccharide and lacked agar, separation of oil was observed in the upper part of the container and syneresis was observed in the lower part of the container after storage for 28 days at 25° C. Furthermore, in Comparative Example 2-2, the presence of oil was hardly felt on the tongue, and the oily feeling was significantly low.
On the other hand, Example 2-1, which contained fruit-derived dietary fiber, xanthan gum, and agar, had excellent oil dispersion stability, with no oil separation or water syneresis observed even after storage for 28 days at 25° C., despite containing oil droplets with large particle diameters. Furthermore, Example 2-1 not only had excellent oil dispersion stability, but also had a good oily feel and an excellent texture that was not slimy or sticky.
[実験例3.液状ドレッシング]
表7の処方に基づき、液状ドレッシングを調製した。詳細には以下のとおりである。
(1)水に多糖類を加え、10分間撹拌を行った。
(2)サラダ油を除く残りの原料を加え、更に5分間撹拌を行った。
(3)ホモミキサーで撹拌しながら、徐々にサラダ油を加え、10,000rpmで10分間撹拌を行った。
(4)85℃まで加温後、容器にホットパック充填した。
なお、果実由来食物繊維は、レモン及び/又はライム由来の食物繊維(水溶性食物繊維含有量22%、水不溶性食物繊維含有量78%)を使用した。
[Experimental Example 3. Liquid dressing]
A liquid dressing was prepared based on the formulation in Table 7. The details are as follows.
(1) The polysaccharide was added to the water and stirred for 10 minutes.
(2) The remaining ingredients except for the salad oil were added and stirred for an additional 5 minutes.
(3) While stirring with a homomixer, salad oil was gradually added and the mixture was stirred at 10,000 rpm for 10 minutes.
(4) After heating to 85°C, the mixture was hot-packed into a container.
The fruit-derived dietary fiber used was dietary fiber derived from lemons and/or limes (soluble dietary fiber content: 22%, water-insoluble dietary fiber content: 78%).
(油脂の分散安定性の評価)
得られた液状ドレッシングを25℃で28日間保存後、油の分離状態を目視にて観察した。結果を表8に示した。
(Evaluation of Dispersion Stability of Oils and Fats)
The resulting liquid dressing was stored at 25° C. for 28 days, and then the state of oil separation was visually observed. The results are shown in Table 8.
(粘度)
得られた液状ドレッシングについて、実験例1と同じ手法により、粘度の測定を行った。結果を表8に示した。
(viscosity)
The viscosity of the resulting liquid dressing was measured in the same manner as in Experimental Example 1. The results are shown in Table 8.
(油脂感及び食感の評価)
得られた液状ドレッシングについて、実験例1と同じ手法により、油脂感及び食感の評価を行った。結果を表8に示した。
(Evaluation of oily and fatty texture and food texture)
The oily and fatty texture and mouthfeel of the obtained liquid dressing were evaluated in the same manner as in Experimental Example 1. The results are shown in Table 8.
キサンタンガムを欠く比較例3-1では、25℃で28日間保存後に、容器の上部にて油の分離が観察された。
一方、果実由来食物繊維、キサンタンガム、及び寒天を含有する実施例3-1では、25℃で28日間保存後も、油の分離や離水は観察されず、油の分散安定性に優れていた。また、実施例3-1は油の分散安定性に優れているだけでなく、良好な油脂感、及びぬめりやべたつきの無い優れた食感を有しており、総合的観点から比較例3-1に比べ優れていた。
In Comparative Example 3-1, which lacked xanthan gum, oil separation was observed at the top of the container after storage at 25° C. for 28 days.
On the other hand, in Example 3-1 containing fruit-derived dietary fiber, xanthan gum, and agar, no oil separation or water syneresis was observed even after storage for 28 days at 25° C., and the oil dispersion stability was excellent. Moreover, Example 3-1 not only had excellent oil dispersion stability, but also had a good oily feel and an excellent texture that was not slimy or sticky, and was superior to Comparative Example 3-1 from an overall perspective.
[実験例4.半固体状ドレッシング]
表9の処方に基づき、半固体状ドレッシングを調製した。詳細には以下のとおりである。
(1)水に多糖類を加え、10分間撹拌を行った。
(2)サラダ油を除く残りの原料を加え、更に5分間撹拌を行った。
(3)徐々にサラダ油を加え、更に5分間撹拌を行った。
(4)コロイドミル処理 (スリット幅 500μm、回転数 3,000rpm)を行った。
なお、果実由来食物繊維は、レモン及び/又はライム由来の食物繊維(水溶性食物繊維含有量22%、水不溶性食物繊維含有量78%)を使用した。
[Experimental Example 4. Semi-solid dressing]
Semi-solid dressings were prepared based on the formulation in Table 9. The details are as follows.
(1) The polysaccharide was added to the water and stirred for 10 minutes.
(2) The remaining ingredients except for the salad oil were added and stirred for an additional 5 minutes.
(3) The salad oil was gradually added and the mixture was stirred for an additional 5 minutes.
(4) Colloid mill treatment (slit width 500 μm, rotation speed 3,000 rpm) was performed.
The fruit-derived dietary fiber used was dietary fiber derived from lemons and/or limes (soluble dietary fiber content: 22%, water-insoluble dietary fiber content: 78%).
(油脂の分散安定性の評価)
得られた半固体状ドレッシングを25℃で1日間保存後、油の分離状態を目視にて観察した。結果を表10に示した。
(Evaluation of Dispersion Stability of Oils and Fats)
The resulting semi-solid dressing was stored at 25° C. for 1 day, and then the state of oil separation was visually observed. The results are shown in Table 10.
(粘度)
得られた半固体状ドレッシングについて、実験例1と同じ手法により、粘度の測定を行った。結果を表10に示した。
(viscosity)
The viscosity of the resulting semi-solid dressing was measured in the same manner as in Experimental Example 1. The results are shown in Table 10.
(油脂感及び食感の評価)
得られた半固体状ドレッシングについて、実験例1と同じ手法により、油脂感及び食感の評価を行った。結果を表10に示した。
(Evaluation of oily and fatty texture and food texture)
The oily and fatty feel and texture of the resulting semi-solid dressing were evaluated in the same manner as in Experimental Example 1. The results are shown in Table 10.
果実由来食物繊維を欠く比較例4-1において、25℃1日後に、表面に油のにじみが観察された。
一方、果実由来食物繊維、キサンタンガム、及び寒天を含有する実施例4-1は25℃1日後でも油のにじみは観察されず、油の分散安定性に優れていた。さらには、実施例4-1は油の分散安定性に優れているだけでなく、良好な油脂感、及びぬめりやべたつきの無い優れた食感を有していた。
In Comparative Example 4-1, which lacked fruit-derived dietary fiber, oily stains were observed on the surface after one day at 25°C.
On the other hand, Example 4-1, which contained fruit-derived dietary fiber, xanthan gum, and agar, had excellent oil dispersion stability, with no oil bleeding observed even after 1 day at 25° C. Furthermore, Example 4-1 not only had excellent oil dispersion stability, but also had a good oily feel and an excellent texture that was not slimy or sticky.
Claims (4)
(A)油脂を1~80質量%、
(B)キサンタンガムを0.005~1質量%、
(C)果実由来食物繊維を0.05~2質量%、
(D)寒天を0.001~0.5質量%。 A liquid or semi-solid acidic seasoning comprising the following (A) to (D):
(A) 1 to 80% by mass of fats and oils,
(B) 0.005 to 1% by mass of xanthan gum,
(C) 0.05 to 2% by mass of fruit-derived dietary fiber,
(D) 0.001 to 0.5% by mass of agar.
(A)油脂を1~80質量%、
(B)キサンタンガムを0.005~1質量%、
(C)果実由来食物繊維を0.05~2質量%、
(D)寒天を0.001~0.5質量%。 A method for producing a liquid or semi-solid acidic seasoning, comprising the steps of:
(A) 1 to 80% by mass of fats and oils,
(B) 0.005 to 1% by mass of xanthan gum,
(C) 0.05 to 2% by mass of fruit-derived dietary fiber,
(D) 0.001 to 0.5% by mass of agar.
液状又は半固体状酸性調味料に、(B)キサンタンガムを0.005~1質量%、(C)果実由来食物繊維を0.05~2質量%、及び(D)寒天を0.001~0.5質量%含有させることを特徴とする、液状又は半固体状酸性調味料における油脂の分散安定性を向上させる方法。 (A) A method for improving the dispersion stability of an oil or fat in a liquid or semi-solid acidic seasoning containing 1 to 80% by mass of an oil or fat, comprising:
A method for improving the dispersion stability of oils and fats in a liquid or semi-solid acidic seasoning, comprising adding to the liquid or semi-solid acidic seasoning (B) 0.005 to 1 mass % of xanthan gum, (C) 0.05 to 2 mass % of fruit-derived dietary fiber, and (D) 0.001 to 0.5 mass % of agar.
(B)キサンタンガム、(C)果実由来食物繊維、及び(D)寒天を含有し、(B)キサンタンガム1質量部に対する(C)果実由来食物繊維の含有量が0.05~400質量部であり、(B)キサンタンガム1質量部に対する(D)寒天の含有量が0.001~100質量部であることを特徴とする、液状又は半固体状酸性調味料における油脂の分散安定性向上剤。 (A) An agent for improving the dispersion stability of an oil or fat in a liquid or semi-solid acidic seasoning containing 1 to 80% by mass of an oil or fat,
An agent for improving the dispersion stability of oils and fats in a liquid or semi-solid acidic seasoning, comprising (B) xanthan gum, (C) fruit-derived dietary fiber, and (D) agar, wherein the content of the fruit-derived dietary fiber (C) per 1 part by mass of the xanthan gum (B) is 0.05 to 400 parts by mass, and the content of the agar (D) per 1 part by mass of the xanthan gum (B) is 0.001 to 100 parts by mass .
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