JP7427742B2 - Composition for skin pack and method for using the same - Google Patents
Composition for skin pack and method for using the same Download PDFInfo
- Publication number
- JP7427742B2 JP7427742B2 JP2022162611A JP2022162611A JP7427742B2 JP 7427742 B2 JP7427742 B2 JP 7427742B2 JP 2022162611 A JP2022162611 A JP 2022162611A JP 2022162611 A JP2022162611 A JP 2022162611A JP 7427742 B2 JP7427742 B2 JP 7427742B2
- Authority
- JP
- Japan
- Prior art keywords
- skin
- skin pack
- pack composition
- composition according
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims description 36
- 238000000034 method Methods 0.000 title claims description 13
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 25
- 239000000194 fatty acid Substances 0.000 claims description 25
- 229930195729 fatty acid Natural products 0.000 claims description 25
- 150000004665 fatty acids Chemical class 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000000440 bentonite Substances 0.000 claims description 11
- 229910000278 bentonite Inorganic materials 0.000 claims description 11
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 11
- 239000011148 porous material Substances 0.000 claims description 11
- 239000003513 alkali Substances 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000005187 foaming Methods 0.000 claims description 3
- 239000003755 preservative agent Substances 0.000 claims description 3
- 230000002335 preservative effect Effects 0.000 claims 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 39
- 239000000243 solution Substances 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 9
- 239000003921 oil Substances 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 8
- 229920006317 cationic polymer Polymers 0.000 description 7
- 235000019864 coconut oil Nutrition 0.000 description 6
- 239000003240 coconut oil Substances 0.000 description 6
- 239000000284 extract Substances 0.000 description 6
- 241000975357 Salangichthys microdon Species 0.000 description 5
- 235000021355 Stearic acid Nutrition 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 5
- 239000008117 stearic acid Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000003796 beauty Effects 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 238000006386 neutralization reaction Methods 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 238000002372 labelling Methods 0.000 description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 2
- BIVBRWYINDPWKA-VLQRKCJKSA-L Glycyrrhizinate dipotassium Chemical compound [K+].[K+].O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C([O-])=O)[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O BIVBRWYINDPWKA-VLQRKCJKSA-L 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- 235000021360 Myristic acid Nutrition 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical group O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- 229940101029 dipotassium glycyrrhizinate Drugs 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 229910052901 montmorillonite Inorganic materials 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- -1 polyoxypropylene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 1
- KTCCLEVCNRHWQL-UHFFFAOYSA-N 3-(2-oxotridecylamino)propanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)CNCCC(O)=O KTCCLEVCNRHWQL-UHFFFAOYSA-N 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 244000303965 Cyamopsis psoralioides Species 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 241000195955 Equisetum hyemale Species 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 244000170916 Paeonia officinalis Species 0.000 description 1
- 235000006484 Paeonia officinalis Nutrition 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 241001647091 Saxifraga granulata Species 0.000 description 1
- 206010039792 Seborrhoea Diseases 0.000 description 1
- 229920002385 Sodium hyaluronate Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 229940100608 glycol distearate Drugs 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 230000037312 oily skin Effects 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 210000002826 placenta Anatomy 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000009538 yokuinin Substances 0.000 description 1
Images
Landscapes
- Cosmetics (AREA)
Description
本発明は皮膚パック用組成物に関するものである。 The present invention relates to a skin pack composition.
従来の石鹸は、泡立ててから顔等に使用する。 Conventional soaps are lathered before being used on the face.
しかしながら、洗顔を泡立ててから使用するということは、換言すれば使用前に石鹸に水を含ませるということであって、これは石鹸の成分を薄めて使用している状態であるため、洗浄力がやや落ちていることになり本来持ちうる洗浄効果が、十分に発揮できないという問題がある。 However, lathering the face wash before use means soaking the soap in water before use, which dilutes the soap's ingredients and reduces its cleaning power. There is a problem that the original cleaning effect cannot be fully demonstrated.
上述の課題に鑑み、本発明では利便性が高い皮膚パック用組成物及びその使用方法を提供することを目的とする。 In view of the above-mentioned problems, an object of the present invention is to provide a highly convenient skin pack composition and a method for using the same.
本発明の第１の観点における皮膚パック用組成物によれば、 アルカリとの反応後に脂肪酸成分が残留し、 使用時に泡立を生ずることを特徴とする。 The skin pack composition according to the first aspect of the present invention is characterized in that a fatty acid component remains after reaction with an alkali, and foaming occurs during use.
好ましくは、防腐剤及び添加剤を含有しないことを特徴とする。好ましくは、多孔質物質を含有することを特徴とする。 Preferably, it is characterized by not containing preservatives and additives. Preferably, it is characterized by containing a porous material.
好ましくは、前記多孔質物質として、ベントナイトを含有することを特徴とする。 Preferably, the porous material contains bentonite.
好ましくは、前記多孔質物質として、火山灰を含有することを特徴とする。 Preferably, the porous material contains volcanic ash.
本発明の第２の観点における皮膚パック用組成物によれば、ＨＬＢ０の脂肪酸、トリグリセライド、及び多孔質物質を含有し、前記脂肪酸は、ミリスチン酸及びステアリン酸、油脂を含有し、前記多孔質物質は、ベントナイト、カチオンを有する多孔質物質を含有することを特徴とする。 According to the skin pack composition according to the second aspect of the present invention, the composition contains an HLB0 fatty acid, a triglyceride, and a porous substance, the fatty acid contains myristic acid and stearic acid, and oil and fat, and the porous substance is characterized by containing bentonite, a porous material having cations.
好ましくは、前記ベントナイトは粒径が７０μｍ以下であることを特徴とする。 Preferably, the bentonite has a particle size of 70 μm or less.
好ましくは、前記脂肪酸及び前記トリグリセライドの中和剤として、水酸化カリウムを含有することを特徴とする。 Preferably, it is characterized by containing potassium hydroxide as a neutralizing agent for the fatty acid and the triglyceride.
好ましくは、前記水酸化カリウムの前記脂肪酸との中和価を１００質量％とした場合、前記水酸化カリウムは８５質量％以上９８質量％以下であることを特徴とする。 Preferably, when the neutralization value of the potassium hydroxide with the fatty acid is 100% by mass, the potassium hydroxide is 85% by mass or more and 98% by mass or less.
本発明の第３の観点における皮膚パック用組成物によれば、前記皮膚パック用組成物を部位に塗り、前記部位に塗られた前記皮膚パック用組成物に水を加え泡立てることを特徴とする。 According to the skin pack composition according to the third aspect of the present invention, the skin pack composition is applied to a site, and water is added to the skin pack composition applied to the site and foamed. .
本発明に係る皮膚パック用組成物及びその使用方法によれば、利便性の向上を図ることができる。 According to the skin pack composition and method of using the same according to the present invention, convenience can be improved.
以下では、本発明に係る皮膚パック用組成物及びその使用方法について、実施例により図面を用いて説明する。 Hereinafter, the composition for skin packs and the method of using the same according to the present invention will be explained using examples and drawings.
本実施例に係る皮膚パック用組成物は、図１の表中に示すように、精製水、濃グリセリン、ソルビット液、水酸化カリウム、酸化チタン、無水ケイ酸、１，３－ブチレングリコール、ベントナイト、ヒアルロン酸ナトリウム（２）、ケイ酸・ケイ酸アルミニウム焼成物、ラウロイルメチルーβーアラニンナトリウム液、ヤシ油脂肪酸ジエタノールアミド、ポリ塩化ジメチルジメチレンピロリジニウム液、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、馬油、ペンタオレイン酸ポリグリセリル、グリチルリチン酸ジカリウム、水溶性プラセンタエキス、水溶性コラーゲン液（３）、ヨクイニンエキス、トウキエキス（１）、チンピエキス、シャクヤクエキス、及び、ユキノシタエキスを備えている。 The skin pack composition according to this example contains purified water, concentrated glycerin, sorbitol solution, potassium hydroxide, titanium oxide, silicic anhydride, 1,3-butylene glycol, bentonite, as shown in the table of FIG. , sodium hyaluronate (2), silicate/aluminum silicate calcined product, lauroylmethyl-β-alanine sodium solution, coconut oil fatty acid diethanolamide, polychlorinated dimethyldimethylenepyrrolidinium solution, lauric acid, myristic acid, palmitic acid , stearic acid, horse oil, polyglyceryl pentaoleate, dipotassium glycyrrhizinate, water-soluble placenta extract, water-soluble collagen solution (3), yokuinin extract, horsetail extract (1), chimpi extract, peony extract, and saxifrage extract. There is.
なお、本実施例に係る皮膚パック用組成物は、防腐剤及び添加剤を含有しない。 Note that the skin pack composition according to this example does not contain preservatives or additives.
本実施例に係る皮膚パック用組成物は、図１の表中に示す、水酸化カリウムと、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸を含む脂肪酸成分とを化学反応させることで生成される。さらに本実施例に係る皮膚パック用組成物は、無水ケイ酸、ベントナイト、及び、ケイ酸・ケイ酸アルミニウム焼成物を含有する多孔質物質（粘土成分）を入れて、カチオンを含ませている。なお、多孔質物質は火山灰を含有するようにしてもよい。
火山灰は、シラスであるとより白くなり見た目もよくなりパックとしてより適切となる。またシラスの場合、多孔質物質の火山灰の大きさが一定の範囲でそろうことにより、各種の効果をコントロールしやすくなる。
さらに、火山灰は、シラスバルーンであると、より適切である。シラスバルーンによる汚れ除去機能が働くからである。
The skin pack composition according to this example is produced by chemically reacting potassium hydroxide with fatty acid components including lauric acid, myristic acid, palmitic acid, and stearic acid, as shown in the table of FIG. . Further, the skin pack composition according to this example contains a porous material (clay component) containing silicic anhydride, bentonite, and a fired product of silicic acid and aluminum silicate to contain cations. Note that the porous material may contain volcanic ash.
When volcanic ash is shirasu, it becomes whiter and looks better, making it more suitable as a pack. In addition, in the case of whitebait, the size of the porous volcanic ash is uniform within a certain range, making it easier to control various effects.
Furthermore, volcanic ash is more suitable in the form of whitebait balloons. This is because the dirt removal function of the whitebait balloon works.
また、本実施例に係る皮膚パック用組成物は、水酸化カリウムの脂肪酸との中和価を１００質量％とした場合、好ましくは、水酸化カリウム（アルカリ）を９２質量％とし、過脂肪酸の状態（アルカリとの反応後に脂肪酸成分が反応せずに残留している状態）とする。これにより肌に対し低刺激で優しくなる。また、油成分を取りすぎるということがなくなる。 In addition, in the skin pack composition according to this example, when the neutralization value of potassium hydroxide with fatty acids is 100% by mass, preferably the potassium hydroxide (alkali) is 92% by mass, and the content of perfatty acid is 92% by mass. state (a state in which fatty acid components remain unreacted after reaction with alkali). This makes it less irritating and gentle to the skin. In addition, there is no need to take too much oil component.
また、肌の中でも特に顔の汚れは主として、たんぱく質が、油成分で表面に定着していることが多く、これは脂肪酸成分に溶ける。つまり、本実施例では、水で薄められる前に顔の汚れの油成分が過脂肪酸部分に溶けることになる。さらに、上記油成分は、水洗いで本実施例に係る皮膚パック用組成物を落とした後も肌に残り、肌から脂分が落ちすぎることによる乾燥を防ぐことができる（しっとり効果を奏する）。 In addition, stains on the skin, especially on the face, are often made of proteins fixed on the surface as oil components, which dissolve in fatty acid components. That is, in this example, the oil component of the dirt on the face dissolves in the perfatty acid portion before being diluted with water. Furthermore, the oil component remains on the skin even after the skin pack composition according to this example is removed by washing with water, and can prevent dryness due to excessive removal of oil from the skin (providing a moisturizing effect).
なお、上述では、水酸化カリウムの脂肪酸との中和価を１００質量％とした場合、好ましくは水酸化カリウム（アルカリ）を９２質量％として説明したが、水酸化カリウムを８５質量％以上９８質量％以下としてもよい。 In addition, in the above, when the neutralization value of potassium hydroxide with fatty acids is 100% by mass, it is preferably explained that potassium hydroxide (alkali) is 92% by mass, but potassium hydroxide is preferably 85% by mass or more and 98% by mass. It may be less than %.
なぜなら、水酸化カリウムが９５質量％を超えると、過脂肪酸が不足し、これにより肌荒れの発生頻度が上昇し、肌にある、必要な油脂まで、落としてしまうことになる。また、水酸化カリウムが８５質量％未満になると、過脂肪酸が多くなりすぎ、これにより水洗いがしづらくなり、さっぱり感がなくなってしまうからである。 This is because when potassium hydroxide exceeds 95% by mass, there is a shortage of perfatty acids, which increases the frequency of rough skin and even removes essential oils and fats from the skin. On the other hand, if the potassium hydroxide content is less than 85% by mass, the amount of perfatty acids increases too much, making it difficult to wash with water and resulting in a lack of refreshing feeling.
なお、アルカリ成分については、上述では水酸化カリウムとしたが、それ以外にも、水酸化ナトリウム、トリエタノールアミン、モノエタノールアミン等、皮膚パック用組成物を作ることができるアルカリであれば代用することができる。もちろんこれらを代用することで、それに対応（１００％反応）する（中和価となる）１００質量％の脂肪酸の質量は変わる。 Regarding the alkali component, potassium hydroxide was used in the above, but other alkalis such as sodium hydroxide, triethanolamine, monoethanolamine, etc. can be used as long as they can be used to make skin pack compositions. be able to. Of course, by substituting these, the mass of 100% by mass fatty acid (which corresponds to the neutralization value) that corresponds to it (100% reaction) will change.
また、本実施例における脂肪酸について、特に重要な成分は、ミリスチン酸及びステアリン酸、および、馬油などのトリグリセライドである。ミリスチン酸は、主にヤシ油又はパーム核油から得られる高級脂肪酸（飽和脂肪酸）であり、洗浄力や起泡性が高い。ステアリン酸は、主に植物油脂から得られる高級脂肪酸であり、泡を持続させる作用を有する。 Furthermore, particularly important components of the fatty acids in this example are myristic acid, stearic acid, and triglycerides such as horse oil. Myristic acid is a higher fatty acid (saturated fatty acid) obtained mainly from coconut oil or palm kernel oil, and has high detergency and foaming properties. Stearic acid is a higher fatty acid obtained mainly from vegetable oils and has the effect of sustaining foam.
多孔質物質について、特に重要な成分はベントナイトである。ベントナイトとは、粘土鉱物であるモンモリロナイトを主成分とする岩石であり、モンモリロナイトは膨潤性や粘性が高い。 For porous materials, a particularly important component is bentonite. Bentonite is a rock whose main component is montmorillonite, a clay mineral, and montmorillonite has high swelling and viscosity.
また、ソルビット液は、刺激を低減するために使用される。 Also, sorbitol solution is used to reduce irritation.
本実施例では、これらの脂肪酸及び多孔質物質を混合することで、それぞれの特性がより活かされるという作用を奏する。 In this example, by mixing these fatty acids and porous materials, the characteristics of each are effectively utilized.
なお、多孔質物質については、いずれも、目に入った時に容易に洗い流せるように粒の径を７０μｍ以下としている。７０μｍよりも大きい径のものを用いると、目に入ってしまった場合に水で洗い流すのが難しくなり、問題が生じる可能性があるためである。 Note that the particle size of all porous substances is set to 70 μm or less so that they can be easily washed away if they get into the eyes. This is because if a diameter larger than 70 μm is used, if it gets into the eyes, it will be difficult to wash it away with water, which may cause problems.
カチオンはマイナスに帯電した物質を引き寄せる力があるため、皮脂やホコリ、タバコの煙や排気ガスなどの汚れを吸着させて取り除く作用がある。そこで、特に脂性肌の場合は多めにイオン導出も行うのが適切である。 Cations have the ability to attract negatively charged substances, so they have the ability to adsorb and remove dirt such as sebum, dust, cigarette smoke, and exhaust gas. Therefore, especially in the case of oily skin, it is appropriate to extract more ions.
本実施例に係る皮膚パック用組成物は、洗浄剤としては、陰イオン、非イオンの成分を使用しているのでマイナス帯電する。これにより、肌に付着した汚れや皮脂を引き上げ、多孔質であるカチオンに吸着させ有効成分の浸透を助長することができる。 The skin pack composition according to this example uses an anionic and nonionic component as a cleansing agent, so it is negatively charged. As a result, dirt and sebum adhering to the skin can be pulled up and adsorbed to the porous cations to promote penetration of the active ingredients.
本実施例に係る使用方法としては、本実施例に係る皮膚パック用組成物を、水を加えない状態でクリーム（パック）のように部位に塗り、その後、水を加えることで、使用時に泡立てを生ずるものである。水を加えて泡立てる方法は、手で水を掬うようにしても、水を含ませたブラシを用いても、あるいは、水をつけたスポンジを用いても良い。その後、従来どおり水洗いして皮膚パック用組成物を流す。
本発明においては、組成物の材質よりもこの皮膚パック用組成物を部位に塗り、前記部位に塗られた前記皮膚パック用組成物に水を加え泡立てること自体も大きな特徴（この使用方法自体が発明）であると考えている。
さらにいうと、このように使うのであれば、パックである必要もなく、この使用方法で使用すること自体も発明であると考えている（＝パックでなくてもこのような使用方法が発明）。
The method of use according to this example is to apply the skin pack composition according to this example to the area like a cream (pack) without adding water, and then add water to create a lather before use. It gives rise to The method of adding water and lathering may be by scooping water by hand, using a brush soaked in water, or using a sponge soaked in water. Thereafter, wash with water as usual to remove the skin pack composition.
In the present invention, the main feature of the present invention is that the skin pack composition is applied to the site, and water is added to the skin pack composition applied to the site to form a foam (this method of use itself is invention).
Furthermore, if it is used in this way, it does not need to be a pack, and using it in this way is itself an invention (= even if it is not a pack, this method of use is an invention) .
ただし、手や、水を付けたスポンジでは、肌との接触面積が大きく、肌への摩擦抵抗が大きくなり、負担が増加する。一方で、柔らかく、毛穴よりも直径の小さい極細のブラシ（例えば６０μｍ）を使用することで、少ない抵抗で洗顔料を泡立てることが可能であり、毛穴よりも小さいサイズの多孔質物質と相まって、汚れを掻き出し、吸着し、落とす力は高まる。 However, when using hands or a sponge moistened with water, the contact area with the skin is large, resulting in increased frictional resistance to the skin and an increased burden. On the other hand, by using a soft, ultra-fine brush with a diameter smaller than the pores (e.g. 60 μm), it is possible to lather the facial cleanser with less resistance. The ability to scrape out, adsorb, and remove substances increases.
本実施例に係る皮膚パック用組成物は、このようにして水を含ませて泡立てる前にまずパックのようにして直接部位に塗るため、水によって薄まりづらい。よって、従来よりも洗浄効果が向上し、利便性が向上する。 The skin pack composition according to this example is first applied directly to the skin area like a pack before being soaked with water and foamed, so it is difficult to dilute with water. Therefore, the cleaning effect is improved and the convenience is improved compared to the conventional method.
また、本実施例に係る皮膚パック用組成物に含まれる成分は、種々の変更が可能である。例えば、粘度調整の成分として、ヤシ油脂肪酸ジエタノールアミドに替えて、ヤシ油脂肪酸トリエタノールアミン、ヤシ油脂肪酸モノエタノールアミン、ジステアリン酸ポリエチレングリコール（１）、ポリオキシプロピレンヤシ油脂肪酸モノイソプロパノールアミド（１Ｐ．Ｏ．）や、アルカリに強い水溶性高分子としてもよい。 In addition, various changes can be made to the components contained in the skin pack composition according to this example. For example, as a component for viscosity adjustment, coconut oil fatty acid triethanolamine, coconut oil fatty acid monoethanolamine, polyethylene glycol distearate (1), polyoxypropylene coconut oil fatty acid monoisopropanolamide (1P) can be used instead of coconut oil fatty acid diethanolamide. .O.) or a water-soluble polymer that is resistant to alkali.
また、刺激を緩和する成分として、ソルビット液に替えて、ジグリセリン、グリセリルグリセリド等としてもよい。 Further, as a component for alleviating irritation, diglycerin, glycerylglyceride, etc. may be used in place of the sorbitol solution.
なお、本実施例に係る皮膚パック用組成物の製造方法は、
＜１：アルカリ作成工程＞
加温しながらアルカリ溶液（水、活性剤、アルカリ剤、グリセリン、グリチルリチン酸ジカリウム等）を作成する。
＜２：粉体投入・分散・撹拌工程＞
ベントナイト、ケイ酸・ケイ酸アルミニウム焼成物等の粉体を投入し分散させ、攪拌し
＜３：脂肪酸添加工程＞
前記撹拌をしながら、加温し溶解した脂肪酸を添加し、鹸化させる。
＜４：温度低下・美容成分添加工程＞
鹸化後は温度を下げて、４０℃以下程度になったら、その他の美容成分等を添加し、十分に混合攪拌を行い完成となる。
なお、脂肪酸にベントナイト等を投入して、その後、アルカリを投入するなど、製造方法は他の方法も当然にあり得る。
The method for producing the skin pack composition according to this example is as follows:
<1: Alkali creation process>
Create an alkaline solution (water, activator, alkaline agent, glycerin, dipotassium glycyrrhizinate, etc.) while heating.
<2: Powder introduction/dispersion/stirring process>
Powder such as bentonite, sintered silicic acid/aluminum silicate, etc. is added, dispersed, and stirred <3: Fatty acid addition step>
While stirring, the heated and dissolved fatty acid is added and saponified.
<4: Temperature reduction/beauty ingredient addition process>
After saponification, the temperature is lowered, and when the temperature drops to about 40°C or lower, other beauty ingredients are added, and the mixture is thoroughly mixed and stirred to complete the process.
Note that other manufacturing methods are possible, such as adding bentonite or the like to the fatty acid and then adding an alkali.
図２のように、火山灰（シラス、シラスバルーン）は、１３％以下が適切である。この１３％以下では、塗布時の伸びや滑り性は、ほぼ均一に抵抗が少なく滑らかに伸ばすことができた。
この１３％以下では均一に塗布が可能なことから、肌を隙間なく覆い密着し、美容成分の浸透及び汚れの吸着が可能となる。
ブラシによる泡立てや洗い流しも火山灰量が１７％以下までは泡立てやすいが、それ以上では泡立ちにくく、洗い残しができやすい。きれいに洗い流すには過剰なブラッシングが必要となる。
なお、火山灰の増減は水分で調整し、合計１００％（重量パーセント）とした。
図１の例では、この火山灰分は、ケイ酸・ケイ酸アルミニュウム焼成物は７．００００＋３．００００で１０．００００％である。
As shown in Figure 2, the appropriate amount of volcanic ash (whitebait, whitebait balloon) is 13% or less. At 13% or less, the elongation and slipperiness during application were almost uniform and could be spread smoothly with little resistance.
If it is 13% or less, it can be applied evenly, so it covers the skin closely without gaps, allowing beauty ingredients to penetrate and dirt to be absorbed.
Lathering and rinsing with a brush is easy when the amount of volcanic ash is less than 17%, but beyond that it is difficult to lather and it is easy to leave residue behind. Excessive brushing is required to get it clean.
Incidentally, the increase or decrease in volcanic ash was adjusted by moisture, and the total was 100% (weight percent).
In the example shown in FIG. 1, the volcanic ash content of the fired silicic acid/aluminum silicate product is 7.0000+3.0000, which is 10.0000%.
＜カチオンの変形例＞
カチオンとしては、ベントナイトのほか、図１に１．５％として記載した、ポリ塩化ジメチルジメチレンピロリジニウム液もカチオン高分子として利用している。
なお、このポリ塩化ジメチルジメチレンピロリジニウム液（以下、（１）と表記する場合がある）は、化粧品表示名称としては、ポリクオタニウム－６として表記する場合もある。
さらに、このカチオン高分子は、例えば
塩化Ｏ－［２－ヒドロキシ－３－（トリメチルアンモニオ）プロピル］グァーガム（化粧品表示名称：グアーヒドロキシプロピルトリモニウムクロリド）（以下、（２）と表記する場合もある）、
塩化Ｏ－［２－ヒドロキシ－３－（トリメチルアンモニオ）プロピル］ヒドロキシエチルセルロース（化粧品表示名称：ポリクオタニウムー１０）（以下、（３）と表記する場合もある）
なども利用できる。
つまり、このポリ塩化ジメチルジメチレンピロリジニウム液に変えて、上記２つのカチオン高分子を単独で利用することも可能である。さらに、このポリ塩化ジメチルジメチレンピロリジニウム液に加える形で、上記２つのカチオン高分子を加えることができる。
さらに、これらのカチオン高分子の２又は３つ以上の組み合わせを変えて、配合することも可能である。つまり、（２）と（３）の組み合わせ、（１）と（３）の組み合わせ、（１）と（２）の組み合わせ、（１）と（２）と（３）の組み合わせ、なども可能であり、もちろん、他のカチオン高分子との組み合わせも可能である。
<Modified examples of cations>
In addition to bentonite, polydimethyldimethylenepyrrolidinium chloride solution, which is shown as 1.5% in FIG. 1, is also used as a cationic polymer.
This dimethyldimethylene pyrrolidinium chloride solution (hereinafter sometimes referred to as (1)) may also be referred to as polyquaternium-6 as a cosmetic labeling name.
Furthermore, this cationic polymer is, for example, O-[2-hydroxy-3-(trimethylammonio)propyl]guar gum chloride (cosmetic labeling name: guar hydroxypropyltrimonium chloride) (hereinafter also referred to as (2)). be),
O-[2-hydroxy-3-(trimethylammonio)propyl]hydroxyethylcellulose chloride (cosmetic labeling name: Polyquaternium-10) (hereinafter sometimes referred to as (3))
etc. are also available.
In other words, instead of this dimethyldimethylenepyrrolidinium polychloride solution, it is also possible to use the above two cationic polymers alone. Furthermore, the above two cationic polymers can be added to this polydimethyldimethylenepyrrolidinium chloride solution.
Furthermore, it is also possible to mix two or more of these cationic polymers in different combinations. In other words, combinations of (2) and (3), combinations of (1) and (3), combinations of (1) and (2), combinations of (1), (2), and (3), etc. are also possible. Of course, combinations with other cationic polymers are also possible.
これらの、カチオン高分子は、パック剤を増粘し、マイナスに帯電している肌表面への吸着し、皮膜を形成し、保湿力を高める、添加成分の肌への吸着を助ける効果がある。
つまり、実施形態においても、カチオン化高分子は洗浄後に皮膜として肌に残り、潤いと添加成分の吸着を助け、美容成分の持続的な浸透を補助している。
しかし、配合過多の場合には、本来、残留しにくい洗浄成分の肌への吸着を促進し刺激の原因となるため、本パック剤の様な脂肪酸せっけんベースのパック剤においては１．５％以下が適切である。
These cationic polymers have the effect of thickening the pack agent, adsorbing it to the negatively charged skin surface, forming a film, increasing moisturizing power, and helping the adsorption of added ingredients to the skin. .
That is, in the embodiment as well, the cationized polymer remains on the skin as a film after washing, helps absorb moisture and added ingredients, and assists in continuous penetration of beauty ingredients.
However, if too much is added, it promotes the adsorption of cleaning ingredients that normally do not remain on the skin and causes irritation, so in fatty acid soap-based packs like this one, it is recommended to use 1.5% or less. is appropriate.
本発明は皮膚パック用組成物として好適である。
The present invention is suitable as a composition for skin packs.
Claims (4)
使用時に泡立を生じ、
多孔質物質として、火山灰を含有し、
記多孔質物質として、さらにベントナイトを含有する
ことを特徴とする皮膚パック用組成物。 After reaction with alkali, fatty acid components remain,
Foaming occurs when used,
Contains volcanic ash as a porous material,
The porous material further contains bentonite.
A skin pack composition characterized by:
ことを特徴とする請求項１記載の皮膚パック用組成物。 The skin pack composition according to claim 1, which does not contain a preservative.
ことを特徴とする請求項１又は請求項２に記載の皮膚パック用組成物。 The skin pack composition according to claim 1 or 2, wherein the volcanic ash is 8 to 13% by mass.
前記部位に塗られた前記皮膚パック用組成物に水を加え泡立てる
ことを特徴とする使用方法。 Applying the skin pack composition according to any one of claims 1 to 3 to the site,
A method of use comprising adding water to the skin pack composition applied to the area and lathering the composition.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2023143210A JP2023155509A (en) | 2021-10-29 | 2023-09-04 | Skin pack composition and method of use thereof |
| JP2023205912A JP2024015504A (en) | 2021-10-29 | 2023-12-06 | Composition for skin pack and method for using the same |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2021177110 | 2021-10-29 | ||
| JP2021177110 | 2021-10-29 |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2023143210A Division JP2023155509A (en) | 2021-10-29 | 2023-09-04 | Skin pack composition and method of use thereof |
| JP2023205912A Division JP2024015504A (en) | 2021-10-29 | 2023-12-06 | Composition for skin pack and method for using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2023067777A JP2023067777A (en) | 2023-05-16 |
| JP7427742B2 true JP7427742B2 (en) | 2024-02-05 |
Family
ID=86326114
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022162611A Active JP7427742B2 (en) | 2021-10-29 | 2022-10-07 | Composition for skin pack and method for using the same |
| JP2023143210A Pending JP2023155509A (en) | 2021-10-29 | 2023-09-04 | Skin pack composition and method of use thereof |
| JP2023205912A Pending JP2024015504A (en) | 2021-10-29 | 2023-12-06 | Composition for skin pack and method for using the same |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2023143210A Pending JP2023155509A (en) | 2021-10-29 | 2023-09-04 | Skin pack composition and method of use thereof |
| JP2023205912A Pending JP2024015504A (en) | 2021-10-29 | 2023-12-06 | Composition for skin pack and method for using the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (3) | JP7427742B2 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002265351A (en) | 2001-03-06 | 2002-09-18 | Nippon Shikizai Inc | Skin cleaner |
| JP2013023493A (en) | 2011-07-15 | 2013-02-04 | Nisshin Kagaku Kk | Composition for facial massage pack cleanser |
| JP2022072897A (en) | 2020-10-30 | 2022-05-17 | 花王株式会社 | Detergent composition |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3213868B2 (en) * | 1993-11-12 | 2001-10-02 | 株式会社コーセー | Pack cosmetics |
| KR20100129541A (en) * | 2009-06-01 | 2010-12-09 | 안경모 | Cleansing pack composition |
-
2022
- 2022-10-07 JP JP2022162611A patent/JP7427742B2/en active Active
-
2023
- 2023-09-04 JP JP2023143210A patent/JP2023155509A/en active Pending
- 2023-12-06 JP JP2023205912A patent/JP2024015504A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002265351A (en) | 2001-03-06 | 2002-09-18 | Nippon Shikizai Inc | Skin cleaner |
| JP2013023493A (en) | 2011-07-15 | 2013-02-04 | Nisshin Kagaku Kk | Composition for facial massage pack cleanser |
| JP2022072897A (en) | 2020-10-30 | 2022-05-17 | 花王株式会社 | Detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2023067777A (en) | 2023-05-16 |
| JP2023155509A (en) | 2023-10-20 |
| JP2024015504A (en) | 2024-02-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2819002C (en) | Cleansing composition exhibiting creamy texture and comprising talc and a structuring agent | |
| RU2559634C2 (en) | Soap bar containing hydrogel phase particles | |
| KR100417365B1 (en) | Surfactant composition | |
| JP2008239792A (en) | Manufacturing method of scrub agent-containing soap composition | |
| CN107603789B (en) | Conditioning type solid shampoo soap | |
| TWI222877B (en) | Gommage cosmetic composition | |
| WO2019038547A1 (en) | Composition | |
| JP7427742B2 (en) | Composition for skin pack and method for using the same | |
| RU2193051C2 (en) | Soap composition | |
| JP2008111015A (en) | Solid soap composition | |
| JP5115945B2 (en) | Solid detergent composition | |
| JP6011419B2 (en) | Paste detergent composition | |
| JP4401419B1 (en) | Cleansing oil capable of foaming and skin care method using the same | |
| JP3589514B2 (en) | Non-aqueous gel skin cleanser | |
| JP3811168B2 (en) | Skin cleanser composition | |
| JPH0569804B2 (en) | ||
| JPH08183730A (en) | Solid cleanser composition and its production | |
| JP6705587B2 (en) | Process for producing liquid fatty acid sodium soap | |
| KR20210144226A (en) | Soap for removing keratin comprising of pumice as an active ingredient | |
| JP2024174781A (en) | Soap containing sericite, face wash, body soap, shaving foam, and method for manufacturing soap, etc. | |
| JP2000309800A (en) | Soap | |
| JPH07206666A (en) | Skin cleaning agent | |
| JP2000256160A (en) | Skin cosmetic | |
| JP2009167126A (en) | Detergent and method for producing the same | |
| JP3709131B2 (en) | Skin protection cosmetic cleaning product containing evening primrose seed powder |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AA64 | Notification of invalidation of claim of internal priority (with term) |
Free format text: JAPANESE INTERMEDIATE CODE: A241764 Effective date: 20221025 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20221026 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20230607 |
|
| A871 | Explanation of circumstances concerning accelerated examination |
Free format text: JAPANESE INTERMEDIATE CODE: A871 Effective date: 20230608 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20230718 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20230904 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20231114 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20231208 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20240123 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20240124 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 7427742 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |