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JP7463135B2 - Decorative Panel - Google Patents

Decorative Panel Download PDF

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JP7463135B2
JP7463135B2 JP2020038279A JP2020038279A JP7463135B2 JP 7463135 B2 JP7463135 B2 JP 7463135B2 JP 2020038279 A JP2020038279 A JP 2020038279A JP 2020038279 A JP2020038279 A JP 2020038279A JP 7463135 B2 JP7463135 B2 JP 7463135B2
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paint
resin
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decorative board
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JP2021138065A (en
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洋介 山田
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アイカテック建材株式会社
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Description

本発明は、化粧板に関する。 The present invention relates to decorative panels.

従来、石膏ボード、珪酸カルシウム板、繊維強化セメント板などの無機質板を基材とする内装材(化粧板)が知られている。押出成形セメント板は、セメント・珪酸カルシウム・無機質繊維を原料とし、中空板状に押出成形したパネルである。押出成形セメント板は、軽量でありながら、強度、耐候性、耐火性、耐震性に優れ、かつ美観と意匠性も兼ね備えた建築材料である。押出成形セメント板は、フラットな形状に限らず、押し出す際の口金の形状に応じて表面にリブ形状やエンボス模様を施すことが出来る等、設計の自由度が高い。 Traditionally, interior materials (decorative boards) using inorganic boards such as gypsum boards, calcium silicate boards, and fiber-reinforced cement boards as base materials have been known. Extruded cement boards are panels made from cement, calcium silicate, and inorganic fibers, extruded into a hollow board shape. Extruded cement boards are lightweight building materials that are strong, weather-resistant, fire-resistant, and earthquake-resistant, and also have aesthetic appeal and design features. Extruded cement boards are not limited to flat shapes, and can be given ribbed or embossed patterns on the surface depending on the shape of the nozzle used when extruding, allowing for a high degree of design freedom.

特開2000-43185号公報JP 2000-43185 A

しかしながら、従来の押出成型セメント板に意匠性を付与する場合には、その表面に単色塗装を施すのが一般的であった。 However, when adding a design to a conventional extruded cement board, it was common to apply a single-color paint to the surface.

そこで、化粧板に高い意匠性を付与するという解決すべき技術的課題が生じてくるのであり、本発明は、この課題を解決することを目的とする。 This creates a technical problem that needs to be solved: how to give decorative panels a high level of design. The present invention aims to solve this problem.

上記目的を達成するために、本発明に係る化粧板は、無機質系基材上に、プライマー層と、調色された下地層と、有色の顔料粒子及び半透明の樹脂から成るスパッタ塗料を含むスパッタ層とが、下からこの順で積層され、前記スパッタ層に含まれる樹脂量は、4wt%以上に設定され前記スパッタ層は、前記スパッタ塗料が平坦な前記下地層上に点状に散在して成る In order to achieve the above-mentioned object, the decorative board of the present invention comprises an inorganic base material on which a primer layer, a toned base layer, and a sputter layer containing a sputter paint consisting of colored pigment particles and a translucent resin are laminated in this order from the bottom , the amount of resin contained in the sputter layer is set to 4 wt % or more, and the sputter layer is formed by scattering the sputter paint in dots on the flat base layer .

この構成によれば、化粧板が、顔料粒子と樹脂とを混合したスパッタ塗料を散布して形成されたスパッタ層を備えていることにより、高い意匠性を化粧板に付与することができる。また、顔料粒子が樹脂に混合されることにより、顔料粒子が定着し易くなり、化粧板の塗膜の密着性を向上させることができる。さらに、無機質系材料表面の細かい凹凸(不陸)を覆うプライマー層が介在することにより、化粧板の表面を平滑にするともに化粧板の塗膜の密着性をさらに向上させることができる。 According to this configuration, the decorative board has a sputter layer formed by spraying a sputter paint that is a mixture of pigment particles and resin, which gives the decorative board a high level of design. In addition, by mixing the pigment particles with the resin, the pigment particles are more easily fixed, improving the adhesion of the coating film on the decorative board. Furthermore, the presence of a primer layer that covers fine irregularities (unevenness) on the surface of the inorganic material smoothes the surface of the decorative board and further improves the adhesion of the coating film on the decorative board.

また、スパッタ層の樹脂含有量が4wt%以上に設定されることにより、顔料粒子がさらに定着し易くなる。 Furthermore , by setting the resin content of the sputtered layer to 4 wt % or more, the pigment particles become more easily fixed.

また、本発明に係る化粧板は、前記無機質系基材は、繊維強化セメント板であることが好ましい。 In addition, in the decorative board according to the present invention, the inorganic substrate is preferably a fiber-reinforced cement board.

これまで単色塗装のみであった無機質板表面に、高い意匠性を付与することができる。 It is now possible to impart a high level of design to the surface of inorganic boards, which previously could only be painted in a single color.

本発明に係る化粧板の構成を示す縦断面図。FIG. 1 is a vertical cross-sectional view showing a configuration of a decorative board according to the present invention.

本発明の実施形態について図面に基づいて説明する。なお、以下では、構成要素の数、数値、量、範囲等に言及する場合、特に明示した場合及び原理的に明らかに特定の数に限定される場合を除き、その特定の数に限定されるものではなく、特定の数以上でも以下でも構わない。 The embodiment of the present invention will be described with reference to the drawings. Note that in the following, when referring to the number, numerical value, amount, range, etc. of components, unless otherwise specified or when it is clearly limited to a specific number in principle, it is not limited to that specific number, and it may be more or less than the specific number.

また、構成要素等の形状、位置関係に言及するときは、特に明示した場合及び原理的に明らかにそうでないと考えられる場合等を除き、実質的にその形状等に近似又は類似するもの等を含む。 In addition, when referring to the shape or positional relationship of components, etc., this includes things that are substantially similar or similar to that shape, etc., unless otherwise specified or considered in principle to be clearly different.

また、図面は、特徴を分かり易くするために特徴的な部分を拡大する等して誇張する場合があり、構成要素の寸法比率等が実際と同じであるとは限らない。また、断面図では、構成要素の断面構造を分かり易くするために、一部の構成要素のハッチングを省略することがある。 In addition, drawings may exaggerate characteristic parts to make the features easier to understand, and the dimensional ratios of components may not be the same as in reality. In addition, in cross-sectional views, hatching of some components may be omitted to make the cross-sectional structure of the components easier to understand.

本発明に関わる化粧板1は、無機質系基材2上に、プライマー層3、下地層4及びスパッタ層5が積層されている。 The decorative board 1 of the present invention has a primer layer 3, a base layer 4, and a sputtered layer 5 laminated on an inorganic substrate 2.

無機質系基材2の材料は、セメント板、繊維強化セメント板、火山性ガラス質複層板、ケイ酸カルシウム板、ケイ酸マグネシウム板などがあげられ、これら基材は難燃性能が高く、強度に優れる。 Materials for the inorganic substrate 2 include cement boards, fiber-reinforced cement boards, volcanic glass laminate boards, calcium silicate boards, magnesium silicate boards, etc., and these substrates have high flame retardancy and excellent strength.

特に、無機質系基材2の材料としては、強度、耐衝撃性、寸法安定性に優れる繊維強化セメント板が好ましい。繊維強化セメント板は、セメントをマトリックスとし、補強繊維、シリカ粉末、顔料を配合し、水を加えて混錬した後、押出成形し、次いで、オートクレーブ養生することにより得ることができる。 In particular, a fiber-reinforced cement board, which has excellent strength, impact resistance, and dimensional stability, is preferred as the material for the inorganic substrate 2. A fiber-reinforced cement board can be obtained by mixing cement as a matrix with reinforcing fibers, silica powder, and pigments, adding water and kneading, extruding, and then curing in an autoclave.

セメントは、特に限定されるものではなく、例えば、普通ポルトランドセメント、高炉セメント、シリカセメント、フライアッシュセメント等の混合セメント、アルミナセメント等が挙げられる。 The cement is not particularly limited, and examples include ordinary Portland cement, blast furnace cement, silica cement, mixed cement such as fly ash cement, alumina cement, etc.

補強繊維としては、ガラス繊維、カーボン繊維、ワラストナイトなどの無機繊維、パルプ繊維の如き天然有機繊維、ポリエチレン繊維、ポリプロピレン繊維、ビニリデン繊維、アラミド繊維などの有機合成繊維が挙げられる。 Reinforcing fibers include inorganic fibers such as glass fiber, carbon fiber, and wollastonite, natural organic fibers such as pulp fiber, and organic synthetic fibers such as polyethylene fiber, polypropylene fiber, vinylidene fiber, and aramid fiber.

シリカ微粉末のシリカ成分は、オートクレーブ養生時にセメント中のカルシウム成分と水熱反応によりカルシウム・シリケート系の結晶質となって強度を向上させる。 The silica component of the silica powder reacts hydrothermally with the calcium component in the cement during autoclave curing to form calcium silicate crystalline material, improving strength.

無機質系基材2の押出成形は、例えばスクリュー式押出成形機を用いて行う。オートクレーブ養生条件は、110~200℃、保持時間1~24時間とすれば、軽量かつ高強度の繊維強化セメント板になる。 The inorganic base material 2 is extruded using, for example, a screw-type extruder. If the autoclave curing conditions are 110 to 200°C and a holding time of 1 to 24 hours, a lightweight, high-strength fiber-reinforced cement board will be produced.

無機質系基材2の厚みは、強度、取扱易さから50mm~100mmが好ましい。また無機質系基材2の密度は、0.5~2.0g/cm3が好ましい。密度が下限に満たないとプライマー層3が吸い込まれやすく、上限を超えると重くなり取扱性が劣りやすくなる。 The thickness of the inorganic base material 2 is preferably 50 mm to 100 mm in terms of strength and ease of handling. The density of the inorganic base material 2 is also preferably 0.5 to 2.0 g/cm3. If the density is below the lower limit, the primer layer 3 is likely to be absorbed, and if the density exceeds the upper limit, the base material becomes heavy and is likely to be difficult to handle.

無機質系基材2の表面は、サンドブラスト、ショットブラスト、ダイヤロール、サンドペーパーなどにより表面研削されて平滑に形成されている。 The surface of the inorganic substrate 2 is smoothed by surface grinding using sandblasting, shot blasting, diamond rolls, sandpaper, etc.

無機質系基材2上に積層されたプライマー層3は、無機質系基材2のアルカリ成分が溶出することを防止する。プライマー層3は、無機質系基材2上にプライマー塗料を塗布して形成される。 The primer layer 3 laminated on the inorganic substrate 2 prevents the alkaline components of the inorganic substrate 2 from eluting. The primer layer 3 is formed by applying a primer paint onto the inorganic substrate 2.

プライマー塗料は、ナイロン樹脂、アルキド樹脂、エポキシ樹脂、アクリル樹脂、アクリル変性シリコーン樹脂、塩化ゴム樹脂、ウレタン樹脂、フェノール樹脂、ポリエステル樹脂およびメラミン樹脂、アルキルシリケート又はその加水分解縮合物等が採用可能である。また、プライマー塗料には、隠蔽性を向上させるため酸化チタンを配合しても良い。 Primer paints can be made from nylon resin, alkyd resin, epoxy resin, acrylic resin, acrylic-modified silicone resin, chlorinated rubber resin, urethane resin, phenol resin, polyester resin, melamine resin, alkyl silicate or its hydrolysis condensate, etc. Titanium oxide may also be added to the primer paint to improve hiding power.

プライマー塗料の塗布量は、膜厚で10~100μm程度であれば良く、公知のロールコーター、フローコーター、スプレー塗布などで行う。塗布量が下限に満たないと下地層4との密着が劣りやすく、上限を超えると発泡しやすく仕上がった製品の外観が劣りやすくなる。 The amount of primer paint applied should be about 10 to 100 μm thick, and can be applied using a known roll coater, flow coater, spray coater, etc. If the amount applied is less than the lower limit, adhesion to the base layer 4 is likely to be poor, and if the amount applied is more than the upper limit, foaming is likely to occur, and the appearance of the finished product is likely to be poor.

プライマー層3上には、下地層4が積層される。下地層4は、プライマー層3上に白や黒等に調色された下地塗料を塗布して形成される。 The base layer 4 is laminated on the primer layer 3. The base layer 4 is formed by applying a base paint that is toned to a color such as white or black onto the primer layer 3.

下地塗料は、オルガノポリシロキサン系樹脂塗料、フッ素樹脂塗料、2液硬化型アクリルウレタン樹脂塗料、アクリル樹脂塗料、エポキシ樹脂塗料、ポリウレタン樹脂塗料、塩化ビニル樹脂塗料、塩化ビニリデン樹脂塗料、アクリルシリコーン樹脂塗料などが挙げられ、塗膜乾燥性、塗膜表面硬度、プライマー層3との密着性、塗膜の耐薬品性や耐汚染性を考慮して適宜選択する。 Examples of base paints include organopolysiloxane resin paints, fluororesin paints, two-component curing acrylic urethane resin paints, acrylic resin paints, epoxy resin paints, polyurethane resin paints, vinyl chloride resin paints, vinylidene chloride resin paints, and acrylic silicone resin paints. An appropriate paint is selected taking into consideration the drying properties of the paint film, the surface hardness of the paint film, adhesion to the primer layer 3, and the chemical resistance and contamination resistance of the paint film.

下地塗料の塗布量は、膜厚で10~100μm程度であれば良く、公知のロールコーター、フローコーター、スプレー塗布などで行う。塗布量が下限に満たないとプライマー層3との密着が劣りやすく、上限を超えると発泡しやすく仕上がった製品の外観が劣りやすくなる。 The amount of base paint applied should be about 10 to 100 μm thick, and can be applied using a known roll coater, flow coater, spray coater, etc. If the amount applied is less than the lower limit, adhesion to the primer layer 3 is likely to be poor, and if the amount applied is more than the upper limit, foaming is likely to occur, and the appearance of the finished product is likely to be poor.

下地層4上には、スパッタ層5が積層される。スパッタ層5は、下地層4上にスパッタ塗装により形成される。 A sputtered layer 5 is laminated on the base layer 4. The sputtered layer 5 is formed on the base layer 4 by sputter coating.

スパッタ塗装は、有色の顔料粒子と半透明の樹脂とを混合して成るスパッタ塗料を塗布することにより行われる。これにより、有色の顔料粒子が、化粧板1上に点状に散布される。顔料粒子は、例えば、銀色のパールパウダーであったり、黒色の微粒子等である。顔料粒子の表面が樹脂に被膜されていることにより、スパッタ層5の密着性が向上する。 Sputter coating is performed by applying a sputter paint made of a mixture of colored pigment particles and translucent resin. This causes the colored pigment particles to be scattered in dots on the decorative board 1. The pigment particles can be, for example, silver pearl powder or black microparticles. The surfaces of the pigment particles are coated with resin, which improves the adhesion of the sputter layer 5.

パールパウダーを適量配合したパール塗料は、オルガノポリシロキサン系樹脂塗料、フッ素樹脂塗料、2液硬化型アクリルウレタン樹脂塗料、アクリル樹脂塗料、エポキシ樹脂塗料、ポリウレタン樹脂塗料、塩化ビニル樹脂塗料、塩化ビニリデン樹脂塗料、アクリルシリコーン樹脂塗料などが挙げられ、塗膜乾燥性、塗膜表面硬度、下地層4との密着性、塗膜の耐薬品性や耐汚染性、さらにパールの分散度合を考慮して適宜選択する。なお、スパッタ層5に含まれる樹脂量は、少なくとも4wt%以上であることが好ましい。4wt%では、顔料粒子が定着しにくく、4wt%以上の樹脂を添加する必要があるためである。 Examples of pearl paints containing an appropriate amount of pearl powder include organopolysiloxane resin paints, fluororesin paints, two-component curing acrylic urethane resin paints, acrylic resin paints, epoxy resin paints, polyurethane resin paints, vinyl chloride resin paints, vinylidene chloride resin paints, and acrylic silicone resin paints. They are selected appropriately taking into consideration the drying properties of the coating film, the surface hardness of the coating film, adhesion to the undercoat layer 4, the chemical resistance and contamination resistance of the coating film, and the degree of dispersion of the pearl. The amount of resin contained in the sputter layer 5 is preferably at least 4 wt% or more. This is because at 4 wt%, the pigment particles are difficult to adhere, and it is necessary to add 4 wt% or more of resin.

パール塗料の塗布量は、膜厚で10~100μm程度であれば良く、公知のロールコーター、フローコーター、スプレー塗布などで行う。塗布量が下限に満たないと下地層4との密着が劣りやすく、上限を超えると発泡しやすく仕上がった製品の外観が劣りやすくなる。 The amount of pearlescent paint applied should be about 10 to 100 μm thick, and can be done using a known roll coater, flow coater, spray coater, etc. If the amount applied is less than the lower limit, adhesion to the base layer 4 is likely to be poor, and if the amount applied is more than the upper limit, foaming is likely to occur, and the appearance of the finished product is likely to be poor.

また、パールパウダーの添加量は、スパッタ層5がパール特有の光沢感を得られ、且つパールがスパッタ層5内で沈降しない範囲内で任意に調整可能である。 The amount of pearl powder added can be adjusted as desired within a range that allows the sputtered layer 5 to have the luster characteristic of pearls and prevents the pearls from settling within the sputtered layer 5.

また、スパッタ層5は半透明であるため、下地層4の色調に応じて化粧板1の発色を調整することができる。すなわち、下地層4の色調及びスパッタ層5に含まれる顔料粒子の色調の組み合わせにより、化粧板1表面に点状散布したスパッタ外観の意匠性を変更することができる。 In addition, because the sputter layer 5 is translucent, the color of the decorative board 1 can be adjusted according to the color tone of the base layer 4. In other words, the design of the appearance of the sputtered dots scattered on the surface of the decorative board 1 can be changed by combining the color tone of the base layer 4 and the color tone of the pigment particles contained in the sputter layer 5.

スパッタ塗料の塗布量は、膜厚で10~100μm程度であれば良く、公知のロールコーター、フローコーター、スプレー塗布などで行う。塗布量が下限に満たないと下地層4との密着が劣りやすく、上限を超えると発泡しやすく仕上がった製品の外観が劣りやすくなる。 The amount of sputter coating to be applied should be about 10 to 100 μm in thickness, and can be done using a known roll coater, flow coater, spray coating, etc. If the amount applied is less than the lower limit, adhesion to the base layer 4 is likely to be poor, and if the amount applied is more than the upper limit, foaming is likely to occur, and the appearance of the finished product is likely to be poor.

スパッタ層5上には、化粧板1の耐薬品性を向上させる目的で上塗層6を積層するのが好ましい。また、上塗層6を積層することにより、スパッタ層5に奥行き感を付与できる。上塗層6は、スパッタ層5上に上塗塗料を塗布して形成される。 It is preferable to laminate a topcoat layer 6 on the sputtered layer 5 in order to improve the chemical resistance of the decorative board 1. Furthermore, by laminating the topcoat layer 6, a sense of depth can be imparted to the sputtered layer 5. The topcoat layer 6 is formed by applying a topcoat paint on the sputtered layer 5.

上塗塗料は、オルガノポリシロキサン系樹脂塗料、フッ素樹脂塗料、2液硬化型アクリルウレタン樹脂塗料、アクリル樹脂塗料、エポキシ樹脂塗料、ポリウレタン樹脂塗料、塩化ビニル樹脂塗料、塩化ビニリデン樹脂塗料、アクリルシリコーン樹脂塗料などが挙げられ、塗膜乾燥性、塗膜表面硬度、スパッタ層5との密着性、塗膜の耐薬品性や耐汚染性を考慮して適宜選択する。 Topcoat paints include organopolysiloxane resin paints, fluororesin paints, two-component curing acrylic urethane resin paints, acrylic resin paints, epoxy resin paints, polyurethane resin paints, vinyl chloride resin paints, vinylidene chloride resin paints, and acrylic silicone resin paints, and are selected appropriately taking into consideration the drying properties of the coating film, the surface hardness of the coating film, adhesion to the sputter layer 5, and the chemical resistance and contamination resistance of the coating film.

上塗塗料の塗布量は、膜厚で10~100μm程度であれば良く、公知のロールコーター、フローコーター、スプレー塗布などで行う。塗布量が下限に満たないとスパッタ層5との密着が劣りやすく、上限を超えると発泡しやすく仕上がった製品の外観が劣りやすくなる。 The amount of topcoat paint applied should be about 10 to 100 μm thick, and is applied using a known roll coater, flow coater, spray coater, etc. If the amount applied is less than the lower limit, adhesion to the sputtered layer 5 is likely to be poor, and if the amount applied is more than the upper limit, foaming is likely to occur, and the appearance of the finished product is likely to be poor.

また、下地層4、スパッタ層5及び上塗層6に同一の塗料(例えば、フッ素樹脂塗料)を採用することにより、化粧板1表面に耐候性に優れた塗膜を形成することができる。 In addition, by using the same paint (e.g., fluororesin paint) for the base layer 4, the sputtered layer 5, and the topcoat layer 6, a coating film with excellent weather resistance can be formed on the surface of the decorative board 1.

次に、本発明に係る実施例及び比較例を挙げて詳細に説明する。 Next, we will explain the present invention in detail using examples and comparative examples.

[実施例1]
実施例1に係る化粧板1は、以下の手順で構築される。
[無機質系基材(繊維強化セメント板)]
押出成型セメント板としてメース(登録商標)MHN-6060A(アイカテック建材(株)製、厚み60mm)を用意する。
[Example 1]
The decorative board 1 according to the first embodiment is constructed in the following manner.
[Inorganic substrate (fiber-reinforced cement board)]
As an extrusion molded cement board, Mace (registered trademark) MHN-6060A (manufactured by Aikatec Building Materials Co., Ltd., thickness 60 mm) is prepared.

[プライマー層]
無機質系基材2の表面をダイヤロール、サンドペーパーにより研削し、プライマー層3の膜厚を35~45μmとなるようにプライマー塗料をスプレーで無機質系基材2上に塗布した後に、120℃で20分乾燥した。
・主剤:エポニックスセラミック プライマー 主剤(大日本塗料(株)製、エポキシ樹脂系)
・硬化剤:エポニックスセラミック プライマー 硬化剤(大日本塗料(株)製、アミン系)
・混合比: 主剤:硬化剤=85:15
[Primer layer]
The surface of the inorganic substrate 2 was ground with a diamond roll and sandpaper, and a primer paint was sprayed onto the inorganic substrate 2 so that the thickness of the primer layer 3 was 35 to 45 μm, and then the primer paint was dried at 120° C. for 20 minutes.
Base material: Eponix Ceramic Primer Base material (manufactured by Dai Nippon Paint Co., Ltd., epoxy resin type)
Hardener: Eponix Ceramic Primer Hardener (Amine-based, manufactured by Dai Nippon Paint Co., Ltd.)
Mixing ratio: Base agent: Hardener = 85:15

[下地層]
下地層4の膜厚を30~40μmとなるように下地塗料をスプレーでプライマー層3上に塗布した後に、120℃で20分乾燥した。
・主剤:Vフロン#200上塗り 主剤(大日本塗料(株)製、フッ素系樹脂)
・硬化剤:Vフロン#200上塗り 硬化剤(大日本塗料(株)製、イソシアネート系)
・混合比: 主剤:硬化剤=90:10
[Base layer]
The undercoat paint was sprayed onto the primer layer 3 so that the undercoat layer 4 had a thickness of 30 to 40 μm, and then dried at 120° C. for 20 minutes.
Base material: V-Flon #200 top coat base material (manufactured by Dai Nippon Paint Co., Ltd., fluorine-based resin)
Hardener: V-Flon #200 topcoat hardener (manufactured by Dai Nippon Paint Co., Ltd., isocyanate type)
Mixing ratio: Base agent: Hardener = 90:10

[スパッタ層]
スパッタ層5を所定の膜厚にパール塗料をスプレーで下地層4上に塗布した後に、120℃で20分乾燥した。
・塗料:パールスパッタ塗料(大日本塗料(株)製、フッ素系樹脂)、パール添加量5%
[Sputtered layer]
The sputtered layer 5 was applied to a predetermined thickness on the undercoat layer 4 using a pearlescent paint by spraying, and then dried at 120° C. for 20 minutes.
Paint: Pearl sputter paint (manufactured by Dai Nippon Toryo Co., Ltd., fluororesin), pearl additive amount 5%

[上塗層]
上塗層6の膜厚を30~40μmとなるように上塗塗料をスプレーでスパッタ層5上に塗布した後に、12℃で20分乾燥した。
・主剤:Vフロン#200クリーンレイヤー 主剤(大日本塗料(株)製、フッ素系樹脂)
・硬化剤:Vフロン#200クリーンレイヤー 硬化剤(大日本塗料(株)製、イソシアネート系)
・混合比: 主剤:硬化剤=80:20
[Topcoat layer]
The topcoat paint was sprayed onto the sputtered layer 5 so that the topcoat layer 6 had a thickness of 30 to 40 μm, and then dried at 12° C. for 20 minutes.
Base material: V-Flon #200 Clean Layer Base material (manufactured by Dai Nippon Paint Co., Ltd., fluorine-based resin)
Hardener: V-Flon #200 Clean Layer hardener (manufactured by Dai Nippon Paint Co., Ltd., isocyanate type)
Mixing ratio: Base agent: Hardener = 80:20

[実施例2]
実施例2に係る化粧板1は、実施例1のスパッタ層5を以下のスパッタ層5(エナメル)に置き換えたものであり、それ以外は実施例1と同様に実施した。
[Example 2]
The decorative board 1 of Example 2 was produced in the same manner as Example 1, except that the sputtered layer 5 of Example 1 was replaced with the following sputtered layer 5 (enamel).

[スパッタ層]
スパッタ層5を所定の膜厚になるように所定量の黒色顔料粒子をVフロン#200(大日本塗料(株)製、フッ素系樹脂)に混合して得られたスパッタ塗料をスプレーで下地層4上に塗布した後に、120℃で20分乾燥した。
[Sputtered layer]
A sputtered layer 5 was formed by mixing a predetermined amount of black pigment particles with V-Flon #200 (a fluororesin manufactured by Dai Nippon Toryo Co., Ltd.) to obtain a predetermined thickness. The resulting sputtered paint was sprayed onto the undercoat layer 4 and then dried at 120°C for 20 minutes.

[実施例3]
実施例3に係る化粧板1は、実施例1の下地層4を省略したものであり、それ以外は実施例1と同様に実施した。
[Example 3]
The decorative board 1 according to Example 3 was prepared in the same manner as Example 1, except that the base layer 4 of Example 1 was omitted.

[実施例4]
実施例4に係る化粧板1は、実施例2の下地層4を省略したものであり、それ以外は実施例2と同様に実施した。
[Example 4]
The decorative board 1 according to Example 4 was prepared in the same manner as Example 2, except that the base layer 4 of Example 2 was omitted.

[実施例5]
実施例5に係る化粧板1は、実施例1の上塗層6を省略したものであり、それ以外は実施例1と同様に実施した。
[Example 5]
The decorative board 1 of Example 5 was prepared in the same manner as Example 1, except that the topcoat layer 6 of Example 1 was omitted.

[実施例6]
実施例6に係る化粧板1は、実施例2の上塗層6を省略したものであり、それ以外は実施例2と同様に実施した。
[Example 6]
The decorative board 1 of Example 6 was prepared in the same manner as Example 2, except that the topcoat layer 6 of Example 2 was omitted.

実施例1~6の比較対象として以下の比較例1~3を用意した。 The following Comparative Examples 1 to 3 were prepared for comparison with Examples 1 to 6.

[比較例1]
比較例1は、実施例1のプライマー層3を省略したものであり、それ以外は実施例1と同様に実施した。
[Comparative Example 1]
Comparative Example 1 was carried out in the same manner as in Example 1, except that the primer layer 3 in Example 1 was omitted.

[比較例2]
比較例2は、実施例2のプライマー層3を省略したものであり、それ以外は実施例2と同様に実施した。
[Comparative Example 2]
Comparative Example 2 was carried out in the same manner as in Example 2, except that the primer layer 3 in Example 2 was omitted.

[比較例3]
比較例3は、実施例1のスパッタ層5を、以下のスパッタ層5に置き換えたものであり、それ以外は実施例1と同様に実施した。
[Comparative Example 3]
Comparative Example 3 was carried out in the same manner as in Example 1, except that the sputtered layer 5 in Example 1 was replaced with the following sputtered layer 5.

[スパッタ層]
スパッタ層5を所定の膜厚になるように、パールパウダー(アルミペースト)をスプレーで下地層4上に塗布した後に、120℃で20分乾燥した。
[Sputtered layer]
Pearl powder (aluminum paste) was sprayed onto the undercoat layer 4 so that the sputtered layer 5 had a predetermined thickness, and then dried at 120° C. for 20 minutes.

実施例1~6及び比較例1~3の評価結果を表1に示す。 The evaluation results for Examples 1 to 6 and Comparative Examples 1 to 3 are shown in Table 1.

Figure 0007463135000001
Figure 0007463135000001

なお、実施例1~6及び比較例1~6に対する試験方法、評価方法は以下の通りである。 The test and evaluation methods for Examples 1 to 6 and Comparative Examples 1 to 6 are as follows:

[外観試験]
目視にて割れやフクレ等の外観異常がないかを確認し、外観の異常が無ければ○、異常があれば×とした。
[密着性試験]
JIS K5600-5-4に準拠したクロスカット法で行った。4mm間隔の25マスで剥離が生じていなければ○、剥離が生じていれば×とした。
[Appearance test]
The specimen was visually inspected for any abnormal appearance such as cracks or blisters. If there was no abnormal appearance, it was marked with an ◯, and if there was an abnormal appearance, it was marked with an X.
[Adhesion test]
The cross-cut method was performed according to JIS K5600-5-4. If no peeling occurred in 25 squares spaced 4 mm apart, it was marked with an ◯, and if peeling occurred, it was marked with an X.

表1によれば、実施例1~6については、外観試験及び密着性試験において異常は見当たらなかった。一方、実施例1~2及び比較例1~2を比較すると、比較例1~2は、プライマー層3を省略すると、無機質系基材2表面の凹凸(不陸)が目立ってしまい化粧板1の外観が損なわれがちで、且つ無機質系基材2表面の凹凸によって無機質系基材2と下地層4との間の密着性が確保できず、化粧板1の塗装面が剥離し易いことが分かる。また、実施例1及び比較例3を比較すると、比較例3は、アルミペーストが樹脂に被覆されていないために、アルミペーストの定着不良が生じていることが分かる。 According to Table 1, for Examples 1 to 6, no abnormalities were found in the appearance test and adhesion test. On the other hand, when comparing Examples 1 to 2 and Comparative Examples 1 to 2, it can be seen that in Comparative Examples 1 to 2, if the primer layer 3 is omitted, the unevenness (irregularity) of the surface of the inorganic base material 2 becomes noticeable, tending to impair the appearance of the decorative board 1, and the unevenness of the surface of the inorganic base material 2 makes it difficult to ensure adhesion between the inorganic base material 2 and the undercoat layer 4, making the painted surface of the decorative board 1 prone to peeling. In addition, when comparing Example 1 and Comparative Example 3, it can be seen that in Comparative Example 3, the aluminum paste does not adhere well because it is not covered with resin.

1 ・・・ 化粧板
2 ・・・ 無機質系基材
3 ・・・ プライマー層
4 ・・・ 下地層
5 ・・・ スパッタ層
6 ・・・ 上塗層
Reference Signs List 1: Decorative sheet 2: Inorganic base material 3: Primer layer 4: Undercoat layer 5: Sputtered layer 6: Topcoat layer

Claims (2)

無機質系基材上に、プライマー層と、調色された下地層と、有色の顔料粒子及び半透明の樹脂から成るスパッタ塗料を含むスパッタ層とが、下からこの順で積層され
前記スパッタ層に含まれる樹脂量は、4wt%以上に設定され
前記スパッタ層は、前記スパッタ塗料が平坦な前記下地層上に点状に散在してなることを特徴とする化粧板。
A primer layer, a toned undercoat layer, and a sputter layer containing a sputter coating material made of colored pigment particles and a translucent resin are laminated on an inorganic substrate in this order from the bottom ;
The amount of resin contained in the sputtered layer is set to 4 wt % or more.
The decorative board is characterized in that the sputtered layer is formed by scattering the sputtered paint in dots on the flat base layer .
前記無機質系基材は、繊維強化セメント板であることを特徴とする請求項1記載の化粧板。 2. The decorative board according to claim 1, wherein the inorganic base material is a fiber-reinforced cement board.
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