JP6923546B2 - ジフルオロメタン、ペンタフルオロエタン、テトラフルオロエタン、テトラフルオロプロペン、及び二酸化炭素を含む冷媒混合物、並びにその使用 - Google Patents
ジフルオロメタン、ペンタフルオロエタン、テトラフルオロエタン、テトラフルオロプロペン、及び二酸化炭素を含む冷媒混合物、並びにその使用 Download PDFInfo
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- JP6923546B2 JP6923546B2 JP2018545491A JP2018545491A JP6923546B2 JP 6923546 B2 JP6923546 B2 JP 6923546B2 JP 2018545491 A JP2018545491 A JP 2018545491A JP 2018545491 A JP2018545491 A JP 2018545491A JP 6923546 B2 JP6923546 B2 JP 6923546B2
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- 239000005431 greenhouse gas Substances 0.000 description 1
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- 150000002367 halogens Chemical class 0.000 description 1
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- 125000005842 heteroatom Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
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- 238000005984 hydrogenation reaction Methods 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-O hydron;1,3-oxazole Chemical compound C1=COC=[NH+]1 ZCQWOFVYLHDMMC-UHFFFAOYSA-O 0.000 description 1
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- 239000008235 industrial water Substances 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- NUHSROFQTUXZQQ-UHFFFAOYSA-N isopentenyl diphosphate Chemical compound CC(=C)CCO[P@](O)(=O)OP(O)(O)=O NUHSROFQTUXZQQ-UHFFFAOYSA-N 0.000 description 1
- 229960005280 isotretinoin Drugs 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- FCCDDURTIIUXBY-UHFFFAOYSA-N lipoamide Chemical compound NC(=O)CCCCC1CCSS1 FCCDDURTIIUXBY-UHFFFAOYSA-N 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000003879 lubricant additive Substances 0.000 description 1
- 235000012661 lycopene Nutrition 0.000 description 1
- OAIJSZIZWZSQBC-GYZMGTAESA-N lycopene Chemical compound CC(C)=CCC\C(C)=C\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C=C(/C)CCC=C(C)C OAIJSZIZWZSQBC-GYZMGTAESA-N 0.000 description 1
- 239000001751 lycopene Substances 0.000 description 1
- 229960004999 lycopene Drugs 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- GTIBACHAUHDNPH-WHYMJUELSA-N n,n'-bis[(z)-benzylideneamino]oxamide Chemical compound C=1C=CC=CC=1\C=N/NC(=O)C(=O)N\N=C/C1=CC=CC=C1 GTIBACHAUHDNPH-WHYMJUELSA-N 0.000 description 1
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- 239000001272 nitrous oxide Chemical class 0.000 description 1
- ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
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- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 1
- WRXFONORSZHETC-UHFFFAOYSA-N phenyl propan-2-yl hydrogen phosphate Chemical compound CC(C)OP(O)(=O)OC1=CC=CC=C1 WRXFONORSZHETC-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- BOTWFXYSPFMFNR-PYDDKJGSSA-N phytol Chemical compound CC(C)CCC[C@@H](C)CCC[C@@H](C)CCC\C(C)=C\CO BOTWFXYSPFMFNR-PYDDKJGSSA-N 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002207 retinal effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- ZCIHMQAPACOQHT-ZGMPDRQDSA-N trans-isorenieratene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/c1c(C)ccc(C)c1C)C=CC=C(/C)C=Cc2c(C)ccc(C)c2C ZCIHMQAPACOQHT-ZGMPDRQDSA-N 0.000 description 1
- KBPHJBAIARWVSC-XQIHNALSSA-N trans-lutein Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C(=CC(O)CC2(C)C)C KBPHJBAIARWVSC-XQIHNALSSA-N 0.000 description 1
- 125000001425 triazolyl group Chemical group 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- VPAYJEUHKVESSD-UHFFFAOYSA-N trifluoroiodomethane Chemical compound FC(F)(F)I VPAYJEUHKVESSD-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- KOWVWXQNQNCRRS-UHFFFAOYSA-N tris(2,4-dimethylphenyl) phosphate Chemical compound CC1=CC(C)=CC=C1OP(=O)(OC=1C(=CC(C)=CC=1)C)OC1=CC=C(C)C=C1C KOWVWXQNQNCRRS-UHFFFAOYSA-N 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 150000003735 xanthophylls Chemical class 0.000 description 1
- 235000008210 xanthophylls Nutrition 0.000 description 1
- 235000010930 zeaxanthin Nutrition 0.000 description 1
- 239000001775 zeaxanthin Substances 0.000 description 1
- 229940043269 zeaxanthin Drugs 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
Classifications
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- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
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- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
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- C09K2205/104—Carboxylic acid esters
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- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
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- C09K2205/106—Carbon dioxide
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- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
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- C09K2205/12—Hydrocarbons
- C09K2205/122—Halogenated hydrocarbons
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- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
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- C09K2205/126—Unsaturated fluorinated hydrocarbons
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- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
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Description
本明細書で使用するとき、伝熱流体(伝熱媒体とも呼ばれる)という用語は、熱源からヒートシンクへ熱を運ぶために使用される組成物を意味する。
冷媒業界は、許容可能な性能及び環境持続可能性を提供する新規冷媒製品の開発に奮闘している。多くの用途では不燃性冷媒組成物を必要としており、新規地球温暖化規制により、新規冷媒組成物に関する地球温暖化係数(GWP)の上限が課される可能性がある。したがって、本業界では、冷却及び加熱の良好な性能も提供する、不燃性、低GWP(どのくらい低いGWPとするかは論議されている)、低毒性、低オゾン破壊係数(ODP)である成分を見出す必要がある。R−22の不燃性代替品を見出すことを、本業界は、数十年間研究してきた。長年、R−22の代用品として、R−410A(50重量パーセントのHFC−32及び50重量パーセントのHFC−125の不燃性ブレンド)が、空調及びヒートポンプに使用されてきているが、GWPが高すぎ、代替されなければならない。本明細書に記載の組成物は、かかる代替品を提供し、予想外の可燃特性を有する。
本明細書で開示された組成物は、伝熱組成物又は冷媒として有用である。特に、HFC−32、HFC−125、HFO−1234yf、HFC−134a、及びCO2を含む組成物が、冷媒として有用である。また、HFC−32、HFC−125、HFO−1234yf、HFC−134a、及びCO2を含む組成物は、冷却、空調、又はヒートポンプシステムのR−22又はR−410Aの代替品として有用である。
冷却性能
本発明の組成物の、空調機器及びヒートポンプ機器の典型的な条件での冷却性能を測定し、R−22との比較として、表1に表示する。GWP値は、Intergovernmental Panel on Climate Change(IPCC) Fourth Assessment Report,Working Group I,2007からの値である。蒸発器勾配(Evap Glide)、容積(Vol Cap)、及び圧縮機放出温度(Compr Disch Temp)を、以下の特定の条件での本発明の組成物の物理的特性の測定値から計算する。
冷却性能
本発明の組成物の、空調機器及びヒートポンプ機器の典型的な条件での冷却性能を測定し、R−410Aとの比較として、表2に表示する。GWP値は、Intergovernmental Panel on Climate Change(IPCC)Fourth Assessment Report,Working Group I,2007からの値である。蒸発器勾配(Evap Glide)、容積(Vol Cap)、及び圧縮機放出温度(Compr Disch Temp)を、以下の特定の条件での本発明の組成物の物理的特性の測定値から計算する。
可燃性
以下の組成物は、ASTM E−681−09の条件下で、電子点火源を用いて試験される。かかる可燃性試験を、101kPa(14.7psia)及び相対湿度50パーセントで、23℃で本開示の組成物に行う。60℃の空気中の様々な濃度で試験を行う。組成物が60℃で不燃性である場合、ASHRAE規定によって不燃性であると判定する。結果を表3及び4に示す。
冷却性能
本発明の組成物の、空調機器及びヒートポンプ機器の典型的な条件での冷却性能を測定し、R−407A、R407C、及びR407Fとの比較として、表4に表示する。GWP値は、Intergovernmental Panel on Climate Change(IPCC)Fourth Assessment Report,Working Group I,2007からの値である。蒸発器勾配(Evap Glide)、容積(Vol Cap)、及び圧縮機放出温度(Compr Disch Temp)を、以下の特定の条件での本発明の組成物の物理的特性の測定値から計算する。
冷却性能
本発明の組成物の、空調機器、中温冷却機器、及び低温冷却機器の典型的な条件での冷却性能を測定し、R−410Aとの比較として、表5(空調)、表6(中温冷却)、及び表7(低温冷却)に表示する。GWP値は、Intergovernmental Panel on Climate Change(IPCC)Fourth Assessment Report,Working Group I,2007からの値である。平均勾配(蒸発器勾配及び凝縮器勾配の平均)、容積(Vol Cap)、COP(エネルギー効率の性能−指標の係数)、圧縮機放出温度(Compr Disch Temp)、及び相対的質量流量(R410Aに対する)を、以下の特定の条件での本発明の組成物の物理的特性の測定値から計算する。
蒸気漏れ及び可燃性
本発明の組成物を使用して、蒸気漏れの模擬実験を行った。この組成物は、36/30/14/14/6重量%でR−32/125/134a/1234yf/CO2で構成された。プログラムNIST Refleak 4.0を使用して、最初に54.4℃で90質量%いっぱいに充電されたシリンダを使用して、蒸気漏れを模擬実験した。シリンダを−40℃まで冷却し、液相及び蒸気相の組成物を用いて蒸気漏れを行い、記録した。液相組成物の漏れ結果は、以下の表8、蒸気相は表9である。
上述の24.5/24.5/25.5/25.5重量%の比較例R−32/125/134a/1234yfに、同じ蒸気漏れ実験を模擬実験した。比較蒸気相の結果を表10に示す。
可燃性
可燃性混合物は、電子点火源を用いて、ASTM(American Society of Testing and Materials)E−681の下で試験することによって特定され得る。かかる可燃性試験を、ASTM E−681−09の条件下で、50パーセントの相対湿度(23℃で測定)で冷媒混合物に行った。
実施例A1:ジフルオロメタン、ペンタフルオロエタン、テトラフルオロプロペン、テトラフルオロエタン、及び二酸化炭素を含む、組成物。
Claims (7)
- 4〜40重量%のジフルオロメタン、6〜40重量パーセントのペンタフルオロエタン、7〜40重量パーセントの2,3,3,3−テトラフルオロプロペン、6〜30重量パーセントの1,1,1,2−テトラフルオロエタン、及び2〜20重量パーセントの二酸化炭素を含む、R−410Aを代替する組成物。
- 潤滑剤、染料、可溶化剤、相溶化剤、安定剤、トレーサー、摩耗防止剤、極圧添加剤、腐食及び酸化防止剤、金属表面エネルギー減少剤、金属表面不活性化剤、フリーラジカル捕捉剤、泡制御剤、粘度指数向上剤、流動点降下剤、洗剤、粘度調節剤、並びにそれらの混合物からなる群から選択される1つ以上の成分を更に含む、請求項1に記載の組成物。
- 冷却を生み出すプロセスであって、請求項1に記載の組成物を凝縮させる工程と、その後、冷却される物体の付近で前記組成物を蒸発させる工程と、を含む、プロセス。
- 加熱を生み出すプロセスであって、請求項1に記載の組成物を蒸発させる工程と、その後加熱される物体の付近で前記組成物を凝縮させる工程と、を含む、プロセス。
- 冷却、空調、又はヒートポンプシステムのR−410Aを代替する方法であって、前記R−410Aの代替品として、請求項1に記載の組成物を提供する工程を含む、方法。
- 蒸発器、圧縮機、凝縮器、及び膨張装置を備える空調又はヒートポンプシステムであって、請求項1に記載の組成物を含有する、システム。
- 冷却システムであって、蒸発器、圧縮機、凝縮器、及び膨張装置を備え、請求項1に記載の組成物を含有する、冷却システム。
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US62/339,427 | 2016-05-20 | ||
PCT/US2017/019649 WO2017151488A1 (en) | 2016-02-29 | 2017-02-27 | Refrigerant mixtures comprising difluoromethane, pentafluoroethane, tetrafluoroethane, tetrafluoropropene, and carbon dioxide and uses thereof |
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JP2021124228A Division JP7308889B2 (ja) | 2016-02-29 | 2021-07-29 | ジフルオロメタン、ペンタフルオロエタン、テトラフルオロエタン、テトラフルオロプロペン、及び二酸化炭素を含む冷媒混合物、並びにその使用 |
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JP2019512031A5 JP2019512031A5 (ja) | 2020-04-09 |
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JP2021124228A Active JP7308889B2 (ja) | 2016-02-29 | 2021-07-29 | ジフルオロメタン、ペンタフルオロエタン、テトラフルオロエタン、テトラフルオロプロペン、及び二酸化炭素を含む冷媒混合物、並びにその使用 |
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JP2021124228A Active JP7308889B2 (ja) | 2016-02-29 | 2021-07-29 | ジフルオロメタン、ペンタフルオロエタン、テトラフルオロエタン、テトラフルオロプロペン、及び二酸化炭素を含む冷媒混合物、並びにその使用 |
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US (3) | US10836942B2 (ja) |
EP (1) | EP3423541A1 (ja) |
JP (2) | JP6923546B2 (ja) |
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CN (2) | CN112391146B (ja) |
AU (1) | AU2017225674A1 (ja) |
BR (1) | BR112018067402A2 (ja) |
CA (1) | CA3015523A1 (ja) |
IL (1) | IL261234A (ja) |
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WO (1) | WO2017151488A1 (ja) |
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- 2017-02-27 WO PCT/US2017/019649 patent/WO2017151488A1/en active Application Filing
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- 2017-02-27 JP JP2018545491A patent/JP6923546B2/ja active Active
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- 2017-02-27 MX MX2018010417A patent/MX2018010417A/es unknown
- 2017-02-27 EP EP17711400.6A patent/EP3423541A1/en not_active Withdrawn
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KR20180118174A (ko) | 2018-10-30 |
JP7308889B2 (ja) | 2023-07-14 |
CN112391146A (zh) | 2021-02-23 |
CN112391146B (zh) | 2022-04-08 |
IL261234A (en) | 2018-10-31 |
AU2017225674A1 (en) | 2018-08-30 |
WO2017151488A1 (en) | 2017-09-08 |
CN108699428A (zh) | 2018-10-23 |
JP2021181578A (ja) | 2021-11-25 |
US11312891B2 (en) | 2022-04-26 |
US10836944B1 (en) | 2020-11-17 |
EP3423541A1 (en) | 2019-01-09 |
US20210024800A1 (en) | 2021-01-28 |
CA3015523A1 (en) | 2017-09-08 |
MX2018010417A (es) | 2018-11-29 |
BR112018067402A2 (pt) | 2019-01-22 |
US10836942B2 (en) | 2020-11-17 |
US20200354617A1 (en) | 2020-11-12 |
JP2019512031A (ja) | 2019-05-09 |
US20200165500A1 (en) | 2020-05-28 |
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