JP6957330B2 - Manufacturing method of rubber member for pneumatic tire and manufacturing method of pneumatic tire - Google Patents

Description

The present invention relates to a method for producing a rubber member for a pneumatic tire obtained by vulcanizing a rubber composition and a method for producing a pneumatic tire.

Conventionally, in the rubber industry, it has been known to use a rubber wet masterbatch in order to improve the processability and the dispersibility of the filler when producing a rubber composition containing a filler such as carbon black. There is. In this method, the filler and the dispersion solvent are mixed in advance at a constant ratio, and the filler-containing slurry solution in which the filler is dispersed in the dispersion solvent by a mechanical force and the rubber latex solution are mixed in a liquid phase. Then, a coagulating agent such as an acid is added to coagulate the coagulated product, which is then collected and dried. When the rubber wet masterbatch is used, the dispersibility of the filler is excellent and the rubber physical properties such as workability and reinforcing property are excellent as compared with the case of using the rubber dry masterbatch obtained by dry mixing the filler and rubber. Vulcanized rubber is obtained. By using such a rubber composition as a raw material, for example, a rubber product such as a pneumatic tire having reduced rolling resistance and excellent bending fatigue can be manufactured.

However, if the dispersibility of the dispersant in the rubber composition is poor, for example, when an unvulcanized rubber composition is extruded, dimensional changes may occur immediately after extrusion and after cooling, resulting in deterioration of processability. there were.

Patent Document 1 below describes a technique for blending a predetermined amount of a plate-shaped filler and a metal salt with at least a diene elastomer, a reinforcing filler, and a rubber composition based on a cross-linking system.

Japanese Patent Application Laid-Open No. 2012-522902

However, the technique described in Patent Document 1 is aimed at improving the oxygen impermeability of the vulcanized rubber, and does not mean that the dispersibility of the filler can be further improved.

The present invention has been made in view of the above circumstances, and an object of the present invention is a method for manufacturing a rubber member for a pneumatic tire having excellent dimensional stability and a method for manufacturing a pneumatic tire having a rubber member having excellent dimensional stability. Is to provide.

（式（Ｉ）中、Ｒ^１およびＲ^２は、水素原子、ならびに炭素数１〜２０のアルキル基、アルケニル基またはアルキニル基を示し、Ｒ^１およびＲ^２は同一であっても異なっていてもよい。Ｍ^＋はナトリウムイオン、カリウムイオンまたはリチウムイオンを示す。）を添加し、前記式（Ｉ）に記載の化合物を添加した後に、硫化モリブデンを添加することにより製造されることを特徴とする空気入りタイヤ用ゴム部材の製造方法に関する。 The above object can be achieved by the present invention as described below. That is, the present invention is a method for producing a rubber member for a pneumatic tire obtained by vulcanizing a rubber composition, wherein the rubber composition mixes a filler, a dispersion solvent, and a rubber latex solution. A step of producing a filler-containing rubber latex solution (i), a step of coagulating the filler-containing rubber latex solution to produce a filler-containing rubber coagulant (ii), and dehydrating the filler-containing rubber coagulant. It is produced via a step of producing a rubber wet master batch by drying (iii) and a step of adding a rubber compounding agent to the rubber wet master batch and dry mixing (iv). In step (i), the compound represented by the following formula (I):

(In formula (I), R ¹ and R ² represent a hydrogen atom and an alkyl group having 1 to 20 carbon atoms, an alkenyl group or an alkynyl group, and R ¹ and R ² may be the same or different. It is good. M ⁺ represents a sodium ion, a potassium ion or a lithium ion.), And the compound according to the formula (I) is added, and then molybdenum sulfide is added. The present invention relates to a method for manufacturing a rubber member for a pneumatic tire.

According to the above manufacturing method, when producing a rubber composition as a raw material for a rubber member for a pneumatic tire, a step of mixing a filler, a dispersion solvent, and a rubber latex solution to produce a filler-containing rubber latex solution. In (i), the compound of formula (I) is added. In the step (i), the filler and the rubber latex solution exist in a liquid phase state, and when the compound described in the formula (I) is added in this state, the filler and the rubber polymer constituting the rubber latex are formed. A bond is efficiently formed via the compound represented by the formula (I). This improves the dispersibility of the filler in the filler-containing rubber latex solution. However, not all of the filler can be bonded to the rubber polymer constituting the rubber latex, and there are not a few fillers released in an unreacted state, and such fillers reaggregate. Therefore, the fillers are left as they are. It can be inferred that the effect of improving the dispersibility of is not increased.

However, according to the above-mentioned production method, by adding molybdenum sulfide after adding the compound of the formula (I), molybdenum sulfide can be dispersed and penetrate between the fillers to suppress reaggregation of the fillers. As a result, it is possible to produce a rubber composition in which the dispersibility of the filler is improved and the dispersion stability of the filler is also improved. Since the filler in the rubber composition used as a raw material has excellent dispersibility and dispersion stability, it is dimensionally stable even when an unvulcanized rubber member for a tire is manufactured by, for example, extrusion molding of the rubber composition. Since it is excellent in properties, processability is improved.

In the method for manufacturing a rubber member for a pneumatic tire, when the total amount of rubber components is 100 parts by mass and the amount of molybdenum sulfide compounded is 0.1 to 5.0 parts by mass, it is for unvulcanized tires. Due to the excellent dimensional stability of the rubber member, the processability is further improved.

In the method for manufacturing a rubber member for a pneumatic tire, it is preferable that the molybdenum sulfide is added during the step (iv). The timing of adding molybdenum sulfide after adding the compound of the formula (I) can be appropriately selected, but the rubber compounding agent is added to the rubber wet master batch obtained after the step (iii) and dry-mixed. In the step (iv), when molybdenum sulfide is added together with other rubber compounding agents and dry-mixed, the dispersibility of the molybdenum sulfide in the rubber composition is further enhanced, so that the filler in the rubber composition is dispersed. Sexuality and dispersion stability can be particularly improved. As a result, the processability is further improved due to the excellent dimensional stability of the unvulcanized rubber member for the tire.

The present invention also relates to a method for manufacturing a pneumatic tire including a rubber member, wherein the rubber member is manufactured by the manufacturing method according to any one of claims 1 to 3. .. According to such a manufacturing method, since a rubber member having excellent dimensional stability is used, the processability when manufacturing a pneumatic tire is excellent.

The method for producing a rubber member for a pneumatic tire according to the present invention includes a step of vulcanizing a rubber composition, and when producing such a rubber composition, at least a filler, a dispersion solvent, and a rubber latex solution are used as raw materials. do.

In the present invention, the filler means a filler usually used in the rubber industry, such as carbon black, silica, clay, talc, calcium carbonate, magnesium carbonate, and aluminum hydroxide. Among the above-mentioned fillers, carbon black can be particularly preferably used in the present invention.

As the carbon black, for example, in addition to carbon black used in the ordinary rubber industry such as SAF, ISAF, HAF, FEF, and GPF, conductive carbon black such as acetylene black and Ketjen black can be used. The carbon black may be a granulated carbon black or an ungranulated carbon black that has been granulated in consideration of its handleability in the ordinary rubber industry. When the total amount of the rubber component is 100 parts by mass, the blending amount of the filler, particularly carbon black, is preferably 10 to 80 parts by mass, and more preferably 20 to 60 parts by mass.

As the dispersion solvent, it is particularly preferable to use water, but for example, water containing an organic solvent may be used.

As the rubber latex solution, a natural rubber latex solution and a synthetic rubber latex solution can be used.

The natural rubber latex solution is a natural product due to the metabolic action of plants, and a natural rubber / aqueous solution in which the dispersion solvent is water is particularly preferable. The number average molecular weight of the natural rubber in the natural rubber latex used in the present invention is preferably 2 million or more, more preferably 2.5 million or more. As for the natural rubber latex solution, concentrated latex or fresh latex called field latex can be used without distinction. Examples of the synthetic rubber latex solution include those produced by emulsion polymerization of styrene-butadiene rubber, butadiene rubber, nitrile rubber, and chloroprene rubber.

（式（Ｉ）中、Ｒ^１およびＲ^２は、水素原子、ならびに炭素数１〜２０のアルキル基、アルケニル基またはアルキニル基を示し、Ｒ^１およびＲ^２は同一であっても異なっていてもよい。Ｍ^＋はナトリウムイオン、カリウムイオンまたはリチウムイオンを示す。） In the present invention, when the rubber composition is produced, the filler, the dispersion solvent, and the rubber latex solution are mixed to form the filler-containing rubber latex solution, and the following formula (I) is used in the step (i). Add the listed compound.

(In formula (I), R ¹ and R ² represent a hydrogen atom and an alkyl group having 1 to 20 carbon atoms, an alkenyl group or an alkynyl group, and R ¹ and R ² may be the same or different. Good. M ⁺ indicates sodium ion, potassium ion or lithium ion.)

を使用することが特に好ましい。 In order to increase the affinity for the filler, particularly carbon black, the following formula (I') in which R ¹ and R ² in the formula (I) are hydrogen atoms and M ⁺ is a sodium ion is used. Described compound:

Is particularly preferred.

Considering the dispersibility of the filler in the rubber member for a pneumatic tire, the compounding amount of the compound represented by the formula (I) is 0.1 to 5.0 when the total amount of the rubber components is 100 parts by mass. It is preferably parts by mass.

Further, in the method for producing a rubber member for a pneumatic tire according to the present invention, when producing a rubber composition as a raw material, molybdenum sulfide is added after the compound represented by the formula (I) is added in the step (i). Is added. Molybdenum sulfide is a sulfide of molybdenum and is a black solid whose _{composition formula is represented by MoS 2.} In the present invention, it is particularly preferable to use powdered molybdenum sulfide. Considering the dispersibility and dispersion stability of the filler in the rubber member for pneumatic tires, the amount of molybdenum sulfide compounded is 0.1 to 5.0 parts by mass when the total amount of rubber components is 100 parts by mass. It is preferably 0.3 to 3.0 parts by mass, and more preferably 0.3 to 3.0 parts by mass.

Hereinafter, a method for manufacturing a rubber member for a pneumatic tire according to the present invention will be specifically described. Such a production method includes a step of vulcanizing a rubber composition, and the rubber composition is a step of mixing a filler, a dispersion solvent, and a rubber latex solution to produce a filler-containing rubber latex solution (i). , A step of coagulating the filler-containing rubber latex solution to produce a filler-containing rubber coagulant (iii), and a step of producing a rubber wet master batch by dehydrating and drying the filler-containing rubber coagulant (iii). , And the rubber compounding agent is added to the rubber wet master batch, and the rubber compounding agent is added through the step (iv) of dry mixing, and the compound of the formula (I) is added during the step (i). It is characterized in that it is produced by adding the compound represented by the formula (I) and then adding molybdenum sulfide.

(1) Step (i)
In step (i), the filler, the dispersion solvent, and the rubber latex solution are mixed to produce a filler-containing rubber latex solution. In particular, in the present invention, in the step (i), when the filler is dispersed in the dispersion solvent, at least a part of the rubber latex solution is added to fill the filler to which the rubber latex particles are attached. The step of producing a slurry solution containing the material (i- (a)), and the slurry solution containing the filler to which the rubber latex particles are attached are mixed with the remaining rubber latex solution to mix the rubber latex particles. It is preferable to include the step (i- (b)) of producing the filler-containing rubber latex solution to which the filler is attached. The steps (i- (a)) and the steps (i- (b)) will be described below. In particular, in this embodiment, an example in which carbon black is used as the filler will be described.

Step (i- (a))
In the step (i- (a)), when the carbon black is dispersed in the dispersion solvent, at least a part of the rubber latex solution is added to produce a slurry solution containing the carbon black to which the rubber latex particles are attached. do. The rubber latex solution may be mixed with a dispersion solvent in advance, and then carbon black may be added and dispersed. Further, carbon black may be added to the dispersion solvent, and then carbon black may be dispersed in the dispersion solvent while adding the rubber latex solution at a predetermined addition rate, or carbon black may be added to the dispersion solvent. Then, the carbon black may be dispersed in the dispersion solvent while adding a certain amount of the rubber latex solution in several portions. By dispersing carbon black in the dispersion solvent in the presence of the rubber latex solution, a slurry solution containing carbon black to which the rubber latex particles are attached can be produced. The amount of the rubber latex solution added in the step (i- (a)) is relative to the total amount of the rubber latex solution used (the total amount added in the step (i- (a)) and the step (i- (b))). 0.075 to 12% by mass is exemplified.

In the step (i- (a)), the solid content (rubber) of the rubber latex solution to be added is preferably 0.25 to 15% by mass ratio with carbon black, preferably 0.5 to 6%. It is preferable to have. Further, the solid content (rubber) concentration in the rubber latex solution to be added is preferably 0.2 to 5% by mass, more preferably 0.25 to 1.5% by mass. In these cases, it is possible to produce a rubber composition in which the degree of dispersion of carbon black is increased while the rubber latex particles are surely adhered to the carbon black.

In step (i- (a)), as a method of mixing carbon black and a dispersion solvent in the presence of a rubber latex solution, a high shear mixer, a high shear mixer, a homomixer, a ball mill, a bead mill, a high-pressure homogenizer, an ultrasonic homogenizer, etc. A method of dispersing carbon black using a general disperser such as a colloid mill can be mentioned.

The above-mentioned "high shear mixer" is a mixer provided with a rotor and a stator, and the rotor rotates with a precise clearance provided between a rotor capable of high-speed rotation and a fixed stator. Means a mixer with high shearing action. In order to produce such a high shearing action, it is preferable that the clearance between the rotor and the stator is 0.8 mm or less and the peripheral speed of the rotor is 5 m / s or more. As such a high shear mixer, a commercially available product can be used, and examples thereof include a "high shear mixer" manufactured by SILVERSON.

In the present invention, when carbon black and a dispersion solvent are mixed in the presence of a rubber latex solution to produce a slurry solution containing carbon black to which rubber latex particles are attached, a surfactant is used to improve the dispersibility of the carbon black. May be added. As the surfactant, a surfactant known in the rubber industry can be used, and examples thereof include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants. Be done. Further, alcohol such as ethanol may be used instead of the surfactant or in addition to the surfactant. However, when a surfactant is used, there is a concern that the rubber physical properties of the rubber member for pneumatic tires may deteriorate. Therefore, the amount of the surfactant compounded is 100 parts by mass of the solid content (rubber) of the rubber latex solution. On the other hand, it is preferably 2 parts by mass or less, more preferably 1 part by mass or less, and substantially no surfactant is used.

Step (i- (b))
In the step (i- (b)), the slurry solution and the remaining rubber latex solution are mixed to produce a carbon black-containing rubber latex solution to which the rubber latex particles are attached. The method of mixing the slurry solution and the remaining rubber latex solution in the liquid phase is not particularly limited, and the slurry solution and the remaining rubber latex solution are mixed with a high shear mixer, a high shear mixer, a homomixer, a ball mill, and a bead mill. , A method of mixing using a general disperser such as a high pressure homogenizer, an ultrasonic homogenizer, or a colloid mill. If necessary, the entire mixing system such as a disperser may be heated during mixing.

The remaining rubber latex solution preferably has a higher solid content (rubber) concentration than the rubber latex solution added in the step (i- (a)), considering the dehydration time and labor in the next step (iii). Specifically, the solid content (rubber) concentration is preferably 10 to 60% by mass, and more preferably 20 to 30% by mass.

In the present invention, the compound represented by the formula (I) is added to the step (i), but in the step (i), when carbon black is first dispersed in a dispersion solvent to produce a slurry solution, the said The compound of the formula (I) may be added to the slurry solution, or may be added when the slurry solution and the rubber latex solution are mixed. Further, when the step (i) includes the step (i- (a)) and the step (i- (b)), the compound represented by the formula (I) can be added at any of these steps.

(2) Step (ii)
In the step (ii), the carbon black-containing rubber latex solution is solidified to produce a carbon black-containing rubber coagulated product. As a coagulation method, a method of containing a coagulant in a carbon black-containing rubber latex solution to which rubber latex particles are attached can be exemplified. In this case, as the coagulant, an acid such as formic acid or sulfuric acid, which is usually used for coagulating a rubber latex solution, or a salt such as sodium chloride can be used. After the step (ii) and before the step (iii), if necessary, for the purpose of appropriately reducing the amount of water contained in the filler-containing rubber coagulated product, for example, a solidification step such as a centrifugation step or a heating step. A liquid separation step may be provided.

(3) Step (iii)
In the step (iii), a rubber wet masterbatch is produced by dehydrating and drying the carbon black-containing rubber coagulated product. In the step (iii), for example, a single-screw extruder can be used to dehydrate and dry the carbon black-containing rubber coagulated product while applying a shearing force while heating it to 100 to 250 ° C. Further, in order to further dry the rubber wet masterbatch, various drying devices such as an oven, a vacuum dryer, and an air dryer can be used.

(4) Step (iv)
In the step (iv), a rubber composition is produced by dry-mixing various rubber compounding agents in a rubber wet masterbatch. Examples of rubber compounding agents that can be used include sulfur-based vulcanizing agents, vulcanization accelerators, antiaging agents, silica, silane coupling agents, zinc oxide, methylene acceptors and methylene donors, stearic acid, and vulcanization promoting agents. Examples include auxiliaries, vulcanization retardants, organic peroxides, softeners such as waxes and oils, and compounding agents commonly used in the rubber industry such as processing auxiliaries.

The sulfur as the sulfur-based vulcanizing agent may be ordinary sulfur for rubber, and for example, powdered sulfur, precipitated sulfur, insoluble sulfur, highly dispersible sulfur and the like can be used.

As the vulcanization accelerator, a sulfur amide-based vulcanization accelerator, a thiuram-based vulcanization accelerator, a thiazole-based vulcanization accelerator, a thiourea-based vulcanization accelerator, and a guanidine-based vulcanization agent, which are usually used for rubber vulcanization. Vulcanization accelerators such as accelerators and dithiocarbamate-based vulcanization accelerators may be used alone or in admixture.

As anti-aging agents, aromatic amine-based anti-aging agents, amine-ketone-based anti-aging agents, monophenol-based anti-aging agents, bisphenol-based anti-aging agents, polyphenol-based anti-aging agents, dithiocarbamic acid, which are usually used for rubber. Anti-aging agents such as salt-based anti-aging agents and thiourea-based anti-aging agents may be used alone or in admixture.

In the present invention, molybdenum sulfide is added after the compound represented by the formula (I) is added. Specifically, in step (i), the compound represented by the formula (I) is added to a slurry solution or a mixed solution of a slurry solution and a rubber latex solution to disperse the compound, and then molybdenum sulfide is continuously added. It may be added and dispersed, or molybdenum sulfide may be mixed during the step (iii) and the step (iii). However, in the present invention, when the above-mentioned various rubber compounding agents are added to the rubber wet masterbatch obtained after the step (iii) and molybdenum sulfide is added together with other rubber compounding agents in the dry mixing step (iv). , It is preferable because the dispersibility and dispersion stability of the filler in the rubber composition can be particularly improved due to the further increase in the dispersibility of molybdenum sulfide in the rubber composition.

The rubber composition obtained above is molded into a predetermined shape in an unvulcanized state and vulcanized to produce a rubber member for a pneumatic tire such as a tire tread and a pneumatic tire provided with the rubber member. can do. In the present invention, in the rubber composition molded into a predetermined shape in the unvulcanized state, the dispersibility of the filler is excellent, so that the molded rubber is excellent in dimensional stability. Therefore, the method for manufacturing a pneumatic tire according to the present invention is excellent in processability.

Hereinafter, examples of the present invention will be described and more specifically described.

(Raw materials used)
a) Rubber latex solution; "Natural rubber latex solution (NR field latex)" manufactured by Golden Hope (DRC = 31.2%)
b) Carbon black; "Seast SO" manufactured by Tokai Carbon Co., Ltd.
c) The compound represented by the formula (I) ((2Z) -4-[(4-aminophenyl) amino] -4-oxo-2-butenoate); "Sumilink 200" manufactured by Sumitomo Chemical Co., Ltd.
d) Zinc oxide; Mitsui Mining & Smelting Co., Ltd., "Zinc Hana No. 1"
e) Stearic acid; Kao Corporation, "Lunac S-20"
f) Wax; "OZOACE0355" manufactured by Nippon Seiro Co., Ltd.
g) Anti-aging agent (N-phenyl-N'-(1,3-dimethylbutyl) -p-phenylenediamine); Monsanto, "6PPD"
h) Molybdenum sulfide (MoS ₂ ); Sigma-Aldrich i) Sulfur; Tsurumi Chemical Industry Co., Ltd., "5% oil-containing fine powder sulfur"
j) Vulcanization accelerator; "Sun Cellar NS-G" manufactured by Sanshin Chemical Co., Ltd.
k) Natural rubber; "RSS # 3"

Examples 1-5
By adding the amount of carbon black shown in Table 1 to water as a dispersion solvent and dispersing the carbon black using PRIMIX Robomix (conditions of the Robomix: 9000 rpm, 30 minutes), a slurry solution. Manufactured. The compound represented by the formula (I) and the natural rubber latex solution are added to the obtained slurry solution in the amounts shown in Table 1 and mixed using a household mixer SM-L56 manufactured by SANYO (mixer conditions). 11300 rpm, 30 minutes) to produce a carbon black-containing natural rubber latex solution (step (i)).

Formic acid as a coagulant was added to the carbon black-containing natural rubber latex solution produced in step (i) until the entire solution reached pH 4, to produce a carbon black-containing natural rubber coagulated product (step (ii)). The obtained carbon black-containing natural rubber coagulated product was subjected to a solid-liquid separation step, then put into a screw press V-01 manufactured by Suehiro EPM, and dried to produce a rubber wet masterbatch (step (step (step)). iii)). The blending ratio in Table 1 is shown by the mass part (phr) when the total amount of the rubber component (solid content) in the natural rubber latex solution is 100 parts by mass.

A rubber composition was produced by adding various rubber compounding agents shown in Table 1 containing molybdenum sulfide to the obtained rubber wet masterbatch and dry-mixing them using a Banbury mixer (step (iv)). The blending ratio in Table 1 is shown by the mass part (phr) when the total amount of the rubber component (solid content) in the natural rubber latex solution is 100 parts by mass.

Comparative Examples 1 to 4
In Comparative Example 1, a rubber composition was produced by the same method as in Example except that neither the compound represented by the formula (I) nor molybdenum sulfide was blended. Further, in Comparative Example 2, a rubber composition was produced by the same method as in Example except that the compound represented by the formula (I) was not blended. Further, in Comparative Example 3, a rubber composition was produced by the same method as in Example except that molybdenum sulfide was not blended. Further, in Comparative Example 4, instead of producing the rubber wet master batch, the rubber dry master batch was prepared by dry-mixing natural rubber (RSS # 3) and carbon black at the blending ratios shown in Table 1. A rubber composition was produced by adding the compound represented by the formula (I) and various rubber compounding agents containing molybdenum sulfide to the mixture and mixing them in a dry manner.

The obtained rubber composition was supplied to an extruder provided with a base suitable for the tread member, and the extruded plate-shaped tread member was cut to a fixed size of 2500 mm to manufacture the tread member.

[Dimensional stability of rubber members]
The ratio of the tread width after cooling to the tread width immediately after extrusion molding and the ratio of the tread length after cooling to the tread length immediately after extrusion molding of the extruded tread member were measured. Here, "cooling" means that the tread member is extruded and then left at room temperature for 8 hours. Further, both the tread width ratio and the tread length ratio mean that the closer the index (after cooling / immediately after extrusion molding) is to 100, the better the dimensional stability of the rubber member and the pneumatic tire. The results are shown in Table 1.

From the results in Table 1, it can be seen that the tread members manufactured in Examples 1 to 5 are excellent in the dispersibility of carbon black, and therefore are excellent in processability due to the excellent dimensional stability. On the other hand, in Comparative Example 2, the compound represented by the formula (I) was not blended, and in Comparative Example 3, molybdenum sulfide was not blended, which was caused by the deterioration of the dispersibility of carbon black. , It can be seen that the dimensional stability of the tread member deteriorates. Further, in Comparative Example 4, the compound represented by the formula (I) could not sufficiently react with the carbon black and the natural rubber polymer, and as a result, the dispersibility of the carbon black deteriorated, so that the tread member was dimensionally stable. It can be seen that the sex deteriorates.

Claims (4)

A method for manufacturing a rubber member for a pneumatic tire obtained by vulcanizing a rubber composition.
The rubber composition
Step (i) of mixing a filler, a dispersion solvent, and a rubber latex solution to produce a filler-containing rubber latex solution, and coagulating the filler-containing rubber latex solution to produce a filler-containing rubber coagulated product. Step (ii), a step of producing a rubber wet master batch by dehydrating and drying the filler-containing rubber coagulant (iii), and a step of adding a rubber compounding agent to the rubber wet master batch and dry-mixing (iii). It is manufactured via iv) and
During the step (i), the compound represented by the following formula (I):

(In formula (I), R ¹ and R ² represent a hydrogen atom and an alkyl group having 1 to 20 carbon atoms, an alkenyl group or an alkynyl group, and R ¹ and R ² may be the same or different. Good. M ⁺ indicates sodium ion, potassium ion or lithium ion.)
A method for producing a rubber member for a pneumatic tire, which is produced by adding molybdenum sulfide after adding the compound according to the formula (I). The method for manufacturing a rubber member for a pneumatic tire according to claim 1, wherein the amount of molybdenum sulfide compounded is 0.1 to 5.0 parts by mass when the total amount of the rubber component is 100 parts by mass. The method for manufacturing a rubber member for a pneumatic tire according to claim 1 or 2, wherein the molybdenum sulfide is added during the step (iv). A method for manufacturing pneumatic tires equipped with rubber members.
A method for manufacturing a pneumatic tire, wherein the rubber member is manufactured by the manufacturing method according to any one of claims 1 to 3.