JP6618071B6 - Production method of bamboo extract - Google Patents
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Description
本発明は、竹抽出液の製造方法に関する。 The present invention relates to the production how bamboo extract.
生育中のマダケ(苦竹・真竹)等の竹は、節と節との間に一般的に「竹水」と呼ばれる液体を貯留することがある。この竹水は、アミノ酸、保湿効果を有する糖類、抗酸化作用を有するポリフェノール等を含んでおり、そのまま化粧水とすることが行われている。 Bamboo, such as growing mushrooms (bamboo bamboo / matake), may store a liquid generally called "bamboo water" between nodes. This bamboo water contains amino acids, sugars having a moisturizing effect, polyphenols having an antioxidant effect, and the like, and is used as it is as a lotion.
また、竹の茎を原料とする従来の竹抽出液の製造方法が特許文献1に開示されている。この製造方法は、竹の茎を常温下で微粉砕し、粉砕物を得る粉砕工程と、粉砕物を常温の水に浸漬し、抽出物を得る浸漬工程と、抽出物をろ過して抽出液を得るろ過工程と、抽出液を濃縮する濃縮工程とを備えている。こうして得られた竹抽出液は、皮脂欠乏性変化や炎症性変化を有する皮膚の健常化や健常性の保持効果を発揮可能とされている。 Patent Document 1 discloses a conventional method for producing a bamboo extract using bamboo stems as a raw material. This manufacturing method is a pulverizing step of finely pulverizing bamboo stems at room temperature to obtain a pulverized product, a dipping step of immersing the pulverized product in water at room temperature to obtain an extract, and filtering the extract to extract the extract. And a concentration step of concentrating the extract. The bamboo extract thus obtained is said to be capable of exhibiting the effect of making the skin having sebum deficiency changes and inflammatory changes healthy and maintaining the health.
しかし、竹水そのものや上記製造方法で得られた竹抽出液は、アミノ酸等の含有量が少なく、竹抽出液としての作用を十分に期待し難い。かといって、大気圧下において濃縮工程を行うと、熱によってアミノ酸等を分解したり、変質させたり、劣化させたりし易く、竹抽出液としての作用を減殺してしまうおそれもある。 However, bamboo water itself and the bamboo extract obtained by the above-mentioned production method have a low content of amino acids and the like, and it is difficult to sufficiently expect the action as a bamboo extract. On the other hand, when the concentration step is performed under atmospheric pressure, amino acids and the like are easily decomposed, degraded, or degraded by heat, and the action as a bamboo extract may be reduced.
本発明は、上記従来の実情に鑑みてなされたものであって、作用をより十分に期待可能な竹抽出液を提供することを解決すべき課題としている。 The present invention has been made in view of the above-mentioned conventional circumstances, and has as an object to solve the problem of providing a bamboo extract which can be expected to have a sufficient effect.
本発明の竹抽出液の製造方法は、青竹の茎を常温下で微粉砕し、粉砕物を得る粉砕工程と、
前記粉砕物を常温の水のみに24〜48時間浸漬し、抽出物を得る浸漬工程と、
前記抽出物を20〜60°Cで減圧蒸留し、アミノ酸として多い順でアルギニン、アスパラギン酸、トレオニン、プロリン、セリン、ヒスチジン、ロイシン、リジン、アラニン、フェニルアラニン及びグリシンを含む竹抽出液を得る蒸留工程とを備えていることを特徴とする。
The method for producing a bamboo extract of the present invention is a pulverizing step of finely pulverizing a green bamboo stem at room temperature to obtain a pulverized product,
An immersion step of immersing the pulverized material only in water at room temperature for 24 to 48 hours to obtain an extract,
A distillation step of vacuum-distilling the extract at 20 to 60 ° C. to obtain a bamboo extract containing arginine, aspartic acid, threonine, proline, serine, histidine, leucine, lysine, alanine, phenylalanine and glycine in the descending order of amino acids. And characterized in that:
本発明の製造方法では、粉砕工程を常温下で行うとともに、常温の水のみに24〜48時間浸漬して浸漬工程を行う。そして、蒸留工程において、得られた抽出物を20〜60°Cで減圧蒸留して竹抽出液を得る。このため、竹抽出液は、アミノ酸等を分解したり、変質させたり、劣化させたりし難く、より高い濃度でアミノ酸等を含有している。 In the production method of the present invention, the pulverizing step is performed at room temperature, and the immersion step is performed by immersing in water at room temperature only for 24 to 48 hours . Then, in the distillation step, the obtained extract is distilled under reduced pressure at 20 to 60 ° C. to obtain a bamboo extract. For this reason, the bamboo extract is unlikely to degrade, alter, or degrade amino acids and the like, and contains amino acids and the like at a higher concentration.
したがって、本発明の製造方法によれば、作用をより十分に期待可能な竹抽出液を製造することができる。 Therefore, according to the production method of the present invention, it is possible to produce a bamboo extract that can be expected to have a sufficient effect.
こうして得られる竹抽出液は、フェノキシエタノール等の防腐剤等を僅かに加えることにより、皮膚、頭皮等用の化粧水の他、化粧クリーム、石鹸、リップクリーム、シャンプー等に使用可能である。なお、フェノキシエタノールは、人体に安心の防腐剤である。 The bamboo extract thus obtained can be used for a lotion for the skin, scalp, etc., as well as a cosmetic cream, soap, lip balm, shampoo, etc. by adding a small amount of an antiseptic such as phenoxyethanol. Phenoxyethanol is a preservative that is safe for the human body.
青竹は、茎が青い、つまり生育中又は伐採して間もない竹である。伐採後に長時間を経た竹では、アミノ酸等が分解、変質又は劣化するからである。竹としては、マダケ(苦竹・真竹)、モウソウチク(孟宗竹)、ハチク(淡竹)、メダケ(女竹)、クロチク(黒竹)、ホテイチク(布袋竹)、シホウチク(四方竹)、トウチク(唐竹)、クマザサ(隈笹)、チシマザサ(千島笹)、ミヤコザサ(都笹)等を採用することができる。 Green bamboo is a bamboo whose stem is blue, that is, growing or freshly cut. This is because in bamboo that has passed a long time after felling, amino acids and the like are decomposed, deteriorated or deteriorated. As for bamboo, Madake (bamboo and bamboo), Moso bamboo (Moso bamboo), Hachik (tan bamboo), Medake (memboo), Kurochiku (black bamboo), Hoteichi (Hotei bamboo), Shihoutiku (Yomotake bamboo), Touchiku (karatake), Kumazasa (Kumasa), Chishimasa (Chishima Sasa), Miyakozasa (Miyasa) etc. can be adopted.
粉砕工程では、青竹の茎を常温下で微粉砕し、粉砕物を得る。この際、発明者らの試験結果によれば、例えば、特開2002−301394号等に開示されているように、青竹の粉砕物をセルロースまで押し潰すことが可能な植繊機(登録商標)によって植繊することが好ましい。これによってセルロース中のアミノ酸等をより多く抽出することができるからである。但し、この粉砕工程は、青竹の茎や粉砕物が摩擦熱によって例えば100°Cを超える等、常温を超えないようにする。青竹の茎や粉砕物が高温にさらされると、青竹が含むアミノ酸等が熱によって分解したり、変質したり、劣化したりし易く、竹抽出液としての作用が減殺されるからである。 In the pulverizing step, the stem of the green bamboo is finely pulverized at room temperature to obtain a pulverized product. At this time, according to the test results of the inventors, for example, as disclosed in Japanese Patent Application Laid-Open No. 2002-301394 or the like, a fiber planter (registered trademark) capable of crushing pulverized green bamboo to cellulose is used. It is preferable to fiber. This is because more amino acids and the like in cellulose can be extracted. However, in this pulverization step, the temperature and the temperature of the green bamboo stems and the pulverized material are not exceeded, for example, 100 ° C. due to frictional heat. If the bamboo stalks or crushed materials are exposed to high temperatures, amino acids and the like contained in the green bamboo are easily decomposed, deteriorated, or degraded by heat, and the action as a bamboo extract is reduced.
浸漬工程では、粉砕物を常温の水のみに24〜48時間浸漬し、抽出物を得る。12時間未満の浸漬時間では粉砕物からアミノ酸等を十分に抽出し難い。 In the immersion step, the pulverized material is immersed in only room temperature water for 24 to 48 hours to obtain an extract. If the immersion time is less than 12 hours, it is difficult to sufficiently extract amino acids and the like from the pulverized material .
蒸留工程では、抽出物を20〜60°Cで減圧蒸留して竹抽出液を得る。この際、大気圧を下回る圧力で竹抽出液を得るため、アミノ酸等を分解、変質又は劣化し難い。減圧蒸留の条件は、製造する竹抽出液の用途に応じて種々選択され得る。 In the distillation step, the extract is distilled under reduced pressure at 20 to 60 ° C. to obtain a bamboo extract. At this time, since the bamboo extract is obtained at a pressure lower than the atmospheric pressure, amino acids and the like are not easily decomposed, deteriorated or deteriorated. The conditions of the vacuum distillation can be variously selected according to the use of the bamboo extract to be produced.
こうして得られる竹抽出液は、アミノ酸として多い順でアルギニン、アスパラギン酸、トレオニン、プロリン、セリン、ヒスチジン、ロイシン、リジン、アラニン、フェニルアラニン及びグリシンを含む。 Thus obtained bamboo extract, arginine decreasing order as amino acid, aspartic acid, threonine, proline, serine, histidine, leucine, lysine, alanine, including phenylalanine and glycine.
こうして得られる竹抽出液は、上記の本発明の製造方法によって製造されるため、上記の多くのアミノ酸等を高い含有量で含有している。このため、この竹抽出液は作用をより十分に期待可能である。 Since the bamboo extract thus obtained is produced by the above-described production method of the present invention, it contains a large amount of the above-mentioned many amino acids and the like. For this reason, this bamboo extract can be expected to work more fully.
本発明の製造方法によれば、作用をより十分に期待可能な竹抽出液を製造することができる。 ADVANTAGE OF THE INVENTION According to the manufacturing method of this invention, the bamboo extract which can expect an effect | action more fully can be manufactured .
以下、本発明を具体化した実施例1を図面を参照しつつ説明する。 Hereinafter, a first embodiment of the present invention will be described with reference to the drawings.
(実施例1)
実施例1では、図1に示す製造方法を実施した。この製造方法は、伐採工程S1、裁断工程S2、粉砕工程S3、浸漬工程S4及び蒸留工程S5からなる。
(Example 1)
In Example 1, the manufacturing method shown in FIG. 1 was performed. This manufacturing method includes a logging step S1, a cutting step S2, a crushing step S3, a dipping step S4, and a distillation step S5.
竹林において3〜4年間育ったモウソウチクが毎年3〜4月に最も筍を成長させ易く、茎の節と節との間に竹水を最も多く含有している。このため、伐採工程S1では、そのようなモウソウチクの地上から3m以内の青茎を伐採した。 Moso bamboo grown in bamboo forests for 3 to 4 years is the easiest to grow bamboo shoots every March to April, and contains the most bamboo water between the nodes of the stem. For this reason, in the cutting process S1, the green stem of such a Moso bamboo within 3 m from the ground was cut.
裁断工程S2及び粉砕工程S3では、破砕機が一体となった植繊機(登録商標)(神鋼造機(株)製「SM−18−30CR」)を用いた。すなわち、まず、伐採工程S1で得た青茎を常温下で5〜10mm四方の細片に裁断した。そして、裁断工程S2で得た各細片を常温下で連続的に微粉砕し、粉砕物を得た。こうして各細片を連続的に粉砕物にすることにより、アミノ酸等の分解等を抑制しやすい。但し、この粉砕工程S3は、各細片や粉砕物が摩擦熱によって例えば100°Cを超えないよう、投入量を加減した。 In the cutting step S2 and the pulverizing step S3, a fiber planting machine (registered trademark) (“SM-18-30CR” manufactured by Shinko Zoki Co., Ltd.) in which a crusher was integrated was used. That is, first, the green stem obtained in the logging step S1 was cut into small pieces of 5 to 10 mm square at normal temperature. And each piece obtained in the cutting step S2 was finely pulverized continuously at room temperature to obtain a pulverized material. In this way, by continuously pulverizing each strip, it is easy to suppress the decomposition of amino acids and the like. However, in the pulverizing step S3, the input amount was adjusted so that each strip or pulverized material did not exceed, for example, 100 ° C. due to frictional heat.
浸漬工程S4では、粉砕工程S3で得た粉砕物を常温の水に24〜48時間浸漬した。水と粉砕物との混合物をフィルターによってろ過し、ろ液としての抽出物を得た。フィルター上の残差は肥料等に使用可能である。 In the immersion step S4, the crushed material obtained in the crushing step S3 was immersed in water at normal temperature for 24 to 48 hours. The mixture of water and the pulverized product was filtered with a filter to obtain an extract as a filtrate. The residual on the filter can be used for fertilizer and the like.
そして、蒸留工程S5では、抽出物を蒸留塔内に入れ、減圧蒸留して竹抽出液を得た。この際、蒸留塔内の運転圧力を100〜500mmHgに下げて抽出物の沸点を20〜60°Cに下げて蒸留を行った。伐採工程S1から蒸留工程S5までを2〜3日以内に行った。 Then, in the distillation step S5, the extract was placed in a distillation column and distilled under reduced pressure to obtain a bamboo extract. At this time, distillation was performed by lowering the operating pressure in the distillation column to 100 to 500 mmHg and lowering the boiling point of the extract to 20 to 60 ° C. The steps from the logging step S1 to the distillation step S5 were performed within 2 to 3 days.
こうして得られた竹抽出液中のアミノ酸をHPLC(High Performance Liquid Chromatography)分析方法により分析した。なお、裁断工程S2で得た各細片を常温の水に24〜48時間浸漬し、水と各細片との混合物をフィルターによってろ過した。得られた抽出物中のアミノ酸も同様に分析した。結果を表1に示す(数値の単位はppmである。)。 Amino acids in the thus obtained bamboo extract were analyzed by HPLC (High Performance Liquid Chromatography) analysis method. In addition, each strip obtained in the cutting step S2 was immersed in water at room temperature for 24 to 48 hours, and a mixture of water and each strip was filtered with a filter. Amino acids in the obtained extract were similarly analyzed. The results are shown in Table 1 (the unit of the numerical value is ppm).
表1に示されるように、実施例1の竹抽出液は、アミノ酸等を分解したり、変質させたり、劣化させたりし難く、より高い濃度でアミノ酸等を含有していることがわかる。実施例1の製造方法では、伐採工程S1、裁断工程S2及び粉砕工程S3を常温下で行うとともに、常温の水で浸漬工程S4を行い、しかも、蒸留工程S5において、得られた抽出物を20〜60°Cで減圧蒸留して竹抽出液を得ているからである。 As shown in Table 1, it can be seen that the bamboo extract of Example 1 hardly decomposes, degrades, or deteriorates amino acids and the like, and contains amino acids and the like at a higher concentration. In the production method of Example 1, the logging step S1, the cutting step S2, and the pulverizing step S3 are performed at room temperature, the immersion step S4 is performed with water at room temperature, and the extract obtained in the distillation step S5 is separated by 20 %. This is because a bamboo extract is obtained by distillation under reduced pressure at 6060 ° C.
こうして得られた竹抽出液は、フェノキシエタノール等の防腐剤等を僅かに加えることにより、皮膚、頭皮等用の化粧水の他、化粧クリーム、石鹸、リップクリーム、シャンプー等に使用可能である。 The bamboo extract thus obtained can be used for a lotion for the skin, scalp, etc., as well as a cosmetic cream, soap, lip balm, shampoo, etc. by adding a small amount of a preservative such as phenoxyethanol.
得られた竹抽出液を含む化粧水等は、発明者らによって以下の作用効果が官能評価された。(1)頭皮用の化粧水として、頭皮に接触したところ、頭の毛が固くなり、髪に弾力性が出て髪が膨らむ。(2)頭皮用の化粧水として、頭皮に接触したところ、頭皮に潤いが出て、ふけが出ない。(3)顔用の化粧水として、顔に使用すると、一日中潤いが肌にあり、つるつるして光っている。(4)肌用の化粧水として、肌に使用しても、一日中潤いが肌にあり、つるつるして光っている。(5)肌用の化粧水として、脇、足等に使用すれば、臭いが約5秒位で消え、一日中効果が有る。(6)足用の化粧水として、足の踵(かかと)等に潤いを与える。(7)口臭防止液として、口の中に吹くと、口臭が消える。(8)手用の化粧水として、手に塗布し、手の甲を水道の水に当てると、小さな小さな気泡が見られる(皮膚の表面を竹抽出液がコーティングし、バリアの様に覆っていると思われる。)。(9)肌用の化粧水として、アトピーの人の痒い肌に使用すると、痒みが取れ、赤い部分が改善される。(10)防臭液として、タバコの吸殻にスプレーすると、ニコチン臭が消える。 The following functional effects of the obtained lotion and the like containing the bamboo extract were organoleptically evaluated by the inventors. (1) As a lotion for the scalp, when it comes into contact with the scalp, the hair on the head becomes hard, the hair becomes elastic and the hair swells. (2) As a lotion for the scalp, when it comes into contact with the scalp, the scalp is moisturized and no dandruff appears. (3) When used on the face as a lotion for the face, the skin is moisturized all day long and glows smoothly. (4) Even when used as a lotion for the skin, the skin has moisture all day long and shines smoothly. (5) If used as a skin lotion on the armpits, feet, etc., the odor disappears in about 5 seconds and is effective throughout the day. (6) Moisturizes the heels (heels) of the feet as a lotion for the feet. (7) When it is blown into the mouth as a bad breath prevention liquid, the bad breath disappears. (8) As a lotion for the hand, apply it to the hand, and touch the back of the hand to the tap water, you will see small tiny bubbles (If the surface of the skin is coated with bamboo extract and covered like a barrier Seem.). (9) When used as a skin lotion on itchy skin of atopic people, itching is removed and the red part is improved. (10) When sprayed on cigarette butts as a deodorant, the nicotine smell disappears.
したがって、実施例1の製造方法によれば、作用をより十分に期待可能な竹抽出液を製造できることがわかる。 Therefore, according to the production method of Example 1, it can be seen that a bamboo extract which can be expected to have a sufficient effect can be produced.
以上において、本発明を実施例1に即して説明したが、本発明は上記実施例1に制限されるものではなく、その趣旨を逸脱しない範囲で適宜変更して適用できることはいうまでもない。 In the above, the present invention has been described with reference to the first embodiment. However, it is needless to say that the present invention is not limited to the first embodiment, and can be appropriately modified and applied without departing from the spirit thereof. .
例えば、上記実施例1では、破砕機が一体となった植繊機(登録商標)により裁断工程S2と粉砕工程S3とを連続的に行ったが、破砕機と、植繊機(登録商標)とが別体であっても、本発明を実施することは可能である。但し、この場合でも、破砕機と、植繊機(登録商標)とを連続的に載置し、各細片を連続的に粉砕物にすることが好ましい。 For example, in Example 1 described above, the cutting step S2 and the crushing step S3 were continuously performed by the fiber-planting machine (registered trademark) in which the crushing machine was integrated, but the crushing machine and the fiber-planting machine (registered trademark) The present invention can be practiced even if it is separate. However, even in this case, it is preferable that the crusher and the fiber-planting machine (registered trademark) are continuously placed, and each strip is continuously crushed.
また、図2に示すように、浸漬工程S4と蒸留工程S5との間に熟成工程S6を行うことも可能である。この熟成工程S6では、浸漬工程S4で得られた抽出物を常温で一定期間熟成することにより、抽出物に乳酸発酵を生じる。こうして得られる竹抽出液は人の肌及び消臭の面において優れた作用効果を発揮する。 Further, as shown in FIG. 2, an aging step S6 can be performed between the immersion step S4 and the distillation step S5. In the aging step S6, the extract obtained in the immersion step S4 is aged at room temperature for a certain period to cause lactic acid fermentation in the extract. The bamboo extract thus obtained exerts excellent effects on human skin and deodorization.
本発明は化粧水等に利用可能である。 The present invention can be used for lotion and the like.
S3…粉砕工程
S4…浸漬工程
S5…蒸留工程
S3: grinding process S4: dipping process S5: distillation process
Claims (2)
前記粉砕物を常温の水のみに24〜48時間浸漬し、抽出物を得る浸漬工程と、
前記抽出物を20〜60°Cで減圧蒸留し、アミノ酸として多い順でアルギニン、アスパラギン酸、トレオニン、プロリン、セリン、ヒスチジン、ロイシン、リジン、アラニン、フェニルアラニン及びグリシンを含む竹抽出液を得る蒸留工程とを備えていることを特徴とする竹抽出液の製造方法。 A pulverizing step of finely pulverizing the bamboo stem at room temperature to obtain a pulverized product,
An immersion step of immersing the pulverized material only in water at room temperature for 24 to 48 hours to obtain an extract,
A distillation step of vacuum-distilling the extract at 20 to 60 ° C. to obtain a bamboo extract containing arginine, aspartic acid, threonine, proline, serine, histidine, leucine, lysine, alanine, phenylalanine and glycine in the descending order of amino acids. And a method for producing a bamboo extract.
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