JP6514559B2 - Plastic oil and fat composition and food to which the plastic oil and fat composition is added - Google Patents
Plastic oil and fat composition and food to which the plastic oil and fat composition is added Download PDFInfo
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- JP6514559B2 JP6514559B2 JP2015087724A JP2015087724A JP6514559B2 JP 6514559 B2 JP6514559 B2 JP 6514559B2 JP 2015087724 A JP2015087724 A JP 2015087724A JP 2015087724 A JP2015087724 A JP 2015087724A JP 6514559 B2 JP6514559 B2 JP 6514559B2
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- oil
- fatty acid
- fat
- plastic oil
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- Bakery Products And Manufacturing Methods Therefor (AREA)
- Edible Oils And Fats (AREA)
Description
本発明は、可塑性油脂組成物及び可塑性油脂組成物が添加された食品に関する。 The present invention relates to a plastic fat and oil composition and a food to which the plastic fat and oil composition is added.
従来より、パン類や菓子類等の焼成品は、パサツキ感がなく、ネチャツキ感が抑えられた食感が求められている。 2. Description of the Related Art Conventionally, baked products such as breads and confectionery products are required to have a texture that has no feeling of puffiness and a reduced feeling of sloppy feeling.
特に、サンドイッチのような食材を配合するパン類は、食材の保管を考慮する必要があるため、チルド温度域で流通し、販売される。 In particular, breads containing ingredients such as sandwiches are distributed and sold in a chilled temperature range because it is necessary to consider storage of the ingredients.
しかしながら、パン類や菓子類等の焼成品は小麦粉等の澱粉類を主成分とするため、特に、チルド温度域では、澱粉による老化や、サンドイッチ等の食材がパン生地の水分を奪うため、パサついた食感となる。 However, since baked products such as breads and confectionery products are mainly composed of starches such as wheat flour, especially in chilled temperature ranges, aging with starch and food products such as sandwiches deplete the moisture of bread dough, It has a mouthfeel.
そこで、パン類や菓子類の保管により生じるパサツキ感、ネチャツキ感を抑えるための各種の方法が開発されている。 Under the circumstances, various methods have been developed to reduce the feeling of puffiness and squeakiness caused by storage of bread and confectionery.
例えば、特許文献1には、所定量の食用油脂、乳化剤、及び保湿剤を含有し、食用油脂を構成する全脂肪酸残基に対して不飽和脂肪酸残基が75%以上であることを特徴とする可塑性油脂組成物が開示されている。特許文献1には、該可塑性油脂組成物によると、製品保管中の老化防止効果を向上させるとともに、食感の低下、特に、ねとつき等の発現に伴う口どけ感の低下を抑制し得ることが記載されている。 For example, Patent Document 1 is characterized in that it contains a predetermined amount of edible fat and oil, an emulsifier, and a humectant, and the unsaturated fatty acid residue is 75% or more with respect to all fatty acid residues constituting the edible fat and oil. Plastic fat and oil compositions are disclosed. In Patent Document 1, according to the plastic oil / fat composition, it is possible to improve the antiaging effect during product storage and to suppress the deterioration of the texture, in particular, the deterioration of the mouthfeel due to the appearance of rattling and the like. It is described.
特許文献2には、パン生地に糊化膨潤抑制澱粉を配合して焼成されたパンが開示されており、このようなパンは、冷蔵温度において老化現象が起こりにくいことが記載されている。 Patent Document 2 discloses a bread obtained by blending a gelatinization-swelling-inhibited starch in a bread dough and baking the bread, and it is described that such a bread hardly causes an aging phenomenon at a refrigerated temperature.
特許文献3には、液状油とパームステアリンを非選択的エステル交換した油脂とを混合した可塑性油脂組成物が開示されており、該可塑性油脂組成物によると、パン・ケーキ類の作製に用いることで、冷やして食べる時に硬くなく、パサツキ感がないパン・ケーキ類を得られることが記載されている。 Patent Document 3 discloses a plastic oil-and-fat composition obtained by mixing a liquid oil and a non-selective transesterified oil-and-fat with palm stearin. According to the plastic oil-and-fat composition, it is used for making bread and cakes. In addition, it is described that it is possible to obtain bread and cakes which are not hard when eaten cold and have no feeling of coldness.
しかしながら、特許文献1や特許文献3の可塑性油脂組成物によると、チルド温度域での保管によるパン類や菓子類等の焼成品のパサツキ感を抑制はできるものの、ネチャツキ感を抑制する点で十分にでない。特許文献2のパンは、チルド温度域で保管した際に、満足しうるパサツキ感抑制効果を得られるものでない。 However, according to the plastic fat and oil compositions of Patent Document 1 and Patent Document 3, although it is possible to suppress the feeling of parsley of baked products such as breads and confectioneries by storage in a chilled temperature range, it is sufficient from the point of Not to. The bread of Patent Document 2 can not obtain a satisfactory feeling of suppressing a feeling of parsack when stored in a chilled temperature range.
そのため、特にチルド温度域での保管によるパン類や菓子類のパサツキ感とネチャツキ感の抑制のバランスに優れる方法が求められる。 Therefore, there is a need for a method that is excellent in the balance between suppressing the feeling of parsley and the feeling of sloppy feeling of breads and confectioneries particularly by storage in a chilled temperature range.
本発明は、以上の実情に鑑みてなされたものであり、パン類や菓子類等の焼成品に配合することで、チルド温度域での保管により生じる、パン類や菓子類等の焼成品のパサツキ感とネチャツキ感の抑制のバランスに優れた可塑性油脂組成物、及びこのような可塑性油脂組成物が添加された食品を提供することを目的とする。 The present invention has been made in view of the above circumstances, and by blending it with baked products such as breads and confections, the baked products such as breads and confections produced by storage in a chilled temperature range An object of the present invention is to provide a plastic oil-and-fat composition which is excellent in the balance between suppression of a feeling of crunch and a feeling of sneezing, and a food to which such a plastic oil-and-fat composition is added.
本発明者らは、所定量の飽和脂肪酸を構成脂肪酸として有する可塑性油脂組成物において、ポリグリセリン縮合リシノレイン酸エステルと、グリセリン脂肪酸エステルと、増粘多糖類とを配合することで、チルド温度域での保管により生じる、パン類や菓子類等の焼成品のパサツキ感とネチャツキ感の抑制のバランスに優れることを見出し、本発明を完成するに至った。より具体的には、本発明は以下のようなものを提供する。 The present inventors, in a plastic oil-and-fat composition having a predetermined amount of saturated fatty acid as a constituent fatty acid, blend polyglycerin condensed ricinoleate, glycerine fatty acid ester and polysaccharide thickener in chilled temperature range It has been found that the baked products such as breads and confectioneries have excellent balance of suppression of a feeling of crunch and a feeling of sloppy feeling, which are produced by storage of the present invention, and the present invention has been completed. More specifically, the present invention provides the following.
(1) 飽和脂肪酸である構成脂肪酸の含有量が、油脂全体の構成脂肪酸の質量に対して、27〜55質量%であり、
ポリグリセリン縮合リシノレイン酸エステルと、グリセリン脂肪酸エステルと、増粘多糖類と、を含む、可塑性油脂組成物。
(1) The content of constituent fatty acids which are saturated fatty acids is 27 to 55 mass% with respect to the mass of constituent fatty acids of the whole oil and fat,
Plastic oil and fat composition containing polyglycerin condensation ricinoleate ester, glycerine fatty acid ester, and polysaccharide thickener.
(2) グリセリン有機酸脂肪酸エステルを更に含有する、(1)に記載の可塑性油脂組成物。 (2) The plastic oil-fat composition as described in (1) which further contains glycerol organic acid fatty acid ester.
(3) 2飽和−1不飽和型トリグリセリドと1飽和−2不飽和型トリグリセリドとの合計含有量に対するSSU型トリグリセリドとUSU型トリグリセリドとの合計含有量が、質量比で、0.30〜0.60である、(1)又は(2)に記載の可塑性油脂組成物。 (3) The total content of SSU-type triglycerides and USU-type triglycerides relative to the total content of 2-saturated-1 unsaturated triglycerides and mono-saturated-2-unsaturated triglycerides is 0.30 to 0. 0 by mass ratio. The plastic oil-fat composition as described in (1) or (2) which is 60.
(4) 2位にオレイン酸が結合されたトリグリセリドの合計含有量が、油脂全体の質量に対して27〜57質量%である、(1)から(3)のいずれかに記載の可塑性油脂組成物。 (4) The plastic oil and fat composition according to any one of (1) to (3), wherein the total content of triglycerides in which oleic acid is bound to the 2-position is 27 to 57% by mass with respect to the mass of the whole oil. object.
(5) 前記可塑性油脂組成物に含まれる全ての前記ポリグリセリン縮合リシノレイン酸エステルのうち、グリセリンの重合度が4〜6であるポリグリセリン縮合リシノレイン酸エステルの質量が最も多い、(1)から(4)のいずれかに記載の可塑性油脂組成物。 (5) Among all the polyglycerin condensed ricinoleic acid esters contained in the plastic oil / fat composition, the mass of polyglycerin condensed ricinoleic acid esters having a polymerization degree of 4 to 6 of glycerol is the largest, from (1) to (5) The plastic oil-fat composition as described in any one of 4).
(6) 糖質分解酵素又はリン脂質分解酵素の少なくともいずれか一方を更に含有する、(1)から(5)のいずれかに記載の可塑性油脂組成物。 (6) The plastic oil-fat composition in any one of (1) to (5) which further contains at least any one of a carbohydrate degradation enzyme or a phospholipid degradation enzyme.
(7) 食材配合パン製造用である、(1)から(6)のいずれかに記載の可塑性油脂組成物。 (7) The plastic oil-fat composition in any one of (1) to (6) which is for foodstuffs bread manufacturing.
(8) 前記パンは、チルド温度域で保管される、(7)に記載の可塑性油脂組成物。 (8) The plastic oil composition according to (7), wherein the bread is stored at a chilled temperature range.
(9) (1)から(8)のいずれかに記載の可塑性油脂組成物が添加された食品。 (9) A food to which the plastic oil composition according to any one of (1) to (8) is added.
(10) チルド温度域で保管される食材配合パンである、(9)に記載の食品。 (10) The food according to (9), which is a bread containing ingredients for food stored in a chilled temperature range.
本発明によれば、パン類や菓子類に配合することで、チルド温度域での保管により生じる、パン類や菓子類等の焼成品のパサツキ感とネチャツキ感の抑制のバランスに優れた可塑性油脂組成物、及びこのような可塑性油脂組成物が添加された食品を提供することができる。 According to the present invention, by blending in breads and confectionery, a plastic oil and fat having an excellent balance of suppressing the feeling of parsackiness and feeling of netchackiness of baked products such as breads and confectionery, which are produced by storage in a chilled temperature range. A composition, and a food to which such a plastic fat / oil composition is added can be provided.
以下、本発明の実施形態について説明するが、本発明はこれに限定されるものではない。 Hereinafter, although an embodiment of the present invention is described, the present invention is not limited to this.
<可塑性油脂組成物>
本発明の可塑性油脂組成物は、飽和脂肪酸である構成脂肪酸の含有量が、油脂全体の構成脂肪酸の質量に対して、27〜55質量%であり、ポリグリセリン縮合リシノレイン酸エステルと、グリセリン脂肪酸エステルと、増粘多糖類と、を含む。本発明の可塑性油脂組成物が添加されて得られた焼成品は、これにより、チルド温度域の保管により生じるパサツキ感とネチャツキ感の抑制のバランスに優れる。また、本発明の可塑性油脂組成物が添加されて得られた焼成品は、チルド温度域の保管により生じる焼成品のカット時に屑が生じることも抑制しやすい。なお、本発明において、「チルド温度域」とは、15℃〜0℃の温度域を指す。
<Plastic oil composition>
In the plastic fat and oil composition of the present invention, the content of the constituent fatty acid which is a saturated fatty acid is 27 to 55% by mass with respect to the mass of the constituent fatty acid of the whole fat and oil, polyglycerin condensed ricinoleate and glycerin fatty acid ester And polysaccharide thickeners. The baked product obtained by adding the plastic oil-fat composition of this invention is excellent in the balance of suppression of the feeling of parsackiness which arises by storage of a chilled temperature range, and a feeling of entangleing by this. Moreover, the baked product obtained by adding the plastic fat / oil composition of this invention tends to also suppress that a refuse arises at the time of cutting of the baked product which arises by storage of a chilled temperature range. In the present invention, “chilled temperature range” refers to a temperature range of 15 ° C. to 0 ° C.
可塑性油脂組成物中の油脂の、飽和脂肪酸である構成脂肪酸の含有量が、少なすぎると、チルド温度域の保管により焼成品がネチャツキ感やすくなり、多すぎると、チルド温度域の保管により焼成品がパサツキ感が生じやすくなる。また、可塑性油脂組成物が、ポリグリセリン縮合リシノレイン酸エステル、グリセリン脂肪酸エステル、増粘多糖類を組み合わせて含むことにより、焼成品のチルド温度域の保管により生じるパサツキ感とネチャツキ感の抑制のバランスが良くなり、焼成品のカット時に屑が生じることも抑制しやすい。本発明の可塑性油脂組成物は、これにより、チルド温度域の保管により生じるパサツキ感とネチャツキ感の抑制のバランスに優れるものと推測される。 When the content of the constituent fatty acid which is a saturated fatty acid in the plastic oil composition is too small, the baked product becomes easy to feel sticky due to storage in the chilled temperature range, and if too large, the baked product is stored in the chilled temperature range There is a tendency for a sense of pain to occur. In addition, the plastic oil-and-fat composition contains a combination of polyglycerin condensed ricinoleate, glycerin fatty acid ester, and polysaccharide thickener, so that the balance between suppression of crunch feeling and squeaky feeling caused by storage of chilled temperature range of baked goods It improves, and it is easy to control that wastes are generated at the time of cutting a baked product. The plastic oil-fat composition of this invention is estimated to be excellent in the balance of suppression of the feeling of parsackiness which arises by storage of a chilled temperature range by this, and a feeling of netchackiness.
(油脂)
本発明の可塑性油脂組成物において、飽和脂肪酸である構成脂肪酸の含有量は、油脂全体の構成脂肪酸の質量に対して、27〜55質量%であれば特に限定されないが、焼成品のチルド温度域により生じるネチャツキ感、歯切れ、カット時の焼成品の屑の発生を抑制できることから、30質量%以上であることが好ましく、33質量%以上であることがより好ましく、37質量%以上であることが更に好ましく、40質量%以上であることが最も好ましい。他方、焼成品のチルド温度域における保管により生じるパサツキ感を抑制できることから、52質量%以下であることが好ましく、50質量%以下であることがより好ましく、48質量%以下であることが更に好ましく、46質量%以下であることが最も好ましい。
(Fat and oil)
In the plastic oil composition of the present invention, the content of the constituent fatty acid which is a saturated fatty acid is not particularly limited as long as it is 27 to 55 mass% with respect to the mass of the constituent fatty acid of the whole oil. The amount is preferably 30% by mass or more, more preferably 33% by mass or more, and 37% by mass or more, since generation of squeaky feeling, chipping, and generation of scraps of baked products at the time of cutting can be suppressed. More preferably, it is 40% by mass or more. On the other hand, it is preferably 52% by mass or less, more preferably 50% by mass or less, and still more preferably 48% by mass or less, since it can suppress a feeling of parsack caused by storage in a chilled temperature range of a baked product. Most preferably 46% by mass or less.
本明細書において、「S」は、油脂を構成する飽和脂肪酸を意味し、「U」は、油脂を構成する不飽和脂肪酸を意味する。また、トリグリセリドの1、2、3位とは、構成脂肪酸が結合された位置を意味する。 In the present specification, “S” means a saturated fatty acid constituting fat and oil, and “U” means an unsaturated fatty acid constituting fat and oil. In addition, the 1, 2, 3 position of triglyceride means the position where the constituent fatty acid is bound.
本発明の油脂中の構成脂肪酸である飽和脂肪酸Sとしては、特に限定されないが、例えば、酪酸(4)、カプロン酸(6)、カプリル酸(8)、カプリン酸(10)、ラウリン酸(12)、ミリスチン酸(14)、パルミチン酸(16)、ステアリン酸(18)、アラキジン酸(20)、ベヘン酸(22)、リグノセリン酸(24)等が挙げられる。なお、上記数値表記は、各脂肪酸の炭素数である。本発明の油脂中の構成脂肪酸である飽和脂肪酸Sは、同一の飽和脂肪酸であってもよいし、異なる飽和脂肪酸であってもよい。 The saturated fatty acid S which is a constituent fatty acid in the oil and fat of the present invention is not particularly limited, and examples thereof include butyric acid (4), caproic acid (6), caprylic acid (8), capric acid (10), lauric acid (12 And myristic acid (14), palmitic acid (16), stearic acid (18), arachidic acid (20), behenic acid (22), lignoceric acid (24) and the like. The above numerical notation is the carbon number of each fatty acid. The saturated fatty acid S which is a constituent fatty acid in the oil and fat of the present invention may be the same saturated fatty acid or different saturated fatty acids.
本発明の油脂中の構成脂肪酸である不飽和脂肪酸Uとしては、特に限定されないが、例えば、ミリストレイン酸(14:1)、パルミトレイン酸(16:1)、ヒラゴン酸(16:3)、オレイン酸(18:1)、リノール酸(18:2)、リノレン酸(18:3)、エイコセン酸(20:1)、エルカ酸(22:1)、セラコレイン酸(24:1)等が挙げられる。上記不飽和脂肪酸についての括弧内の数値表記は、左側が脂肪酸の炭素数であり、右側が二重結合数を意味する。本発明の油脂中の構成脂肪酸である不飽和脂肪酸Uは、同一の不飽和脂肪酸であってもよいし、異なる不飽和脂肪酸であってもよい。 The unsaturated fatty acid U, which is a constituent fatty acid in the oil and fat of the present invention, is not particularly limited, and examples thereof include myristoleic acid (14: 1), palmitoleic acid (16: 1), hilagonic acid (16: 3), olein Acid (18: 1), linoleic acid (18: 2), linolenic acid (18: 3), eicosenoic acid (20: 1), erucic acid (22: 1), ceracholeic acid (24: 1), etc. . The numerical expression in the parenthesis for the unsaturated fatty acid means that the carbon number of the fatty acid is on the left and the double bond number is on the right. The unsaturated fatty acid U which is a constituent fatty acid in the oil and fat of the present invention may be the same unsaturated fatty acid or may be different unsaturated fatty acids.
本発明の可塑性油脂組成物において、油脂全体における、2飽和−1不飽和型トリグリセリドと1飽和−2不飽和型トリグリセリドとの合計含有量に対するSSU型トリグリセリドとUSU型トリグリセリドとの合計含有量は、特に限定されないが、より一層、得られる焼成品のネチャツキ感を抑制できることから、質量比で、0.30〜0.60であることが好ましく、0.35〜0.55であることがより好ましく、0.40〜0.50であることが更に好ましく、0.42〜0.48であることが最も好ましい。 In the plastic oil composition of the present invention, the total content of SSU-type triglycerides and USU-type triglycerides relative to the total content of disaturated-1-unsaturated triglycerides and monosaturated-2-unsaturated triglycerides in the whole oil / fat is The mass ratio is preferably 0.30 to 0.60, and more preferably 0.35 to 0.55, although it is not particularly limited, as it can further suppress the feel of the baked product to be obtained. And 0.40 to 0.50 are more preferable, and 0.42 to 0.48 are most preferable.
本発明の可塑性油脂組成物において、2位にオレイン酸が結合されたトリグリセリドの合計含有量は、特に限定されないが、チルド温度域における保管によるネチャツキ感を抑制しやすいことから、油脂全体の質量に対して27〜57質量%であることが好ましく、30質量%〜55質量であることが好ましく、35〜53質量%であることが更に好ましく、40〜50質量%であることが最も好ましい。 In the plastic oil composition of the present invention, the total content of triglycerides in which oleic acid is bound to the 2-position is not particularly limited, but it is easy to suppress the feeling of chew upon storage in the chilled temperature range. On the other hand, 27 to 57% by mass is preferable, 30 to 55% by mass is preferable, 35 to 53% by mass is more preferable, and 40 to 50% by mass is most preferable.
本発明の可塑性油脂組成物において、2位にオレイン酸が結合されたトリグリセリドの1、3位の構成脂肪酸は、飽和脂肪酸又は不飽和脂肪酸のいずれであってもよい。2位がオレイン酸であるトリグリセリドとしては、例えば、SOS型トリグリセリド、SOU型トリグリセリド、UOU型トリグリセリド等が挙げられるが、特に限定されない。なお、「O」とは、トリグリセリドの構成脂肪酸であるオレイン酸を意味する。焼成品のチルド温度域における保管によるネチャツキ感を抑制しやすいことから、2位にオレイン酸が結合されたトリグリセリドの1位又は3位の構成脂肪酸が飽和脂肪酸である場合、炭素数4〜24の飽和脂肪酸であることが好ましい。2位にオレイン酸が結合されたトリグリセリドの1位又は3位の構成脂肪酸が不飽和脂肪酸である場合、炭素数18の不飽和脂肪酸(オレイン酸(18:1)、リノール酸(18:2)、リノレン酸(18:3)等)、炭素数20の不飽和脂肪酸であることが好ましい。2位にオレイン酸が結合されたトリグリセリドの1位又は3位の構成脂肪酸が飽和脂肪酸と不飽和脂肪酸である場合、上述の飽和脂肪酸(炭素数4〜24の飽和脂肪酸)と不飽和脂肪酸(炭素数18の不飽和脂肪酸(オレイン酸(18:1)、リノール酸(18:2)、リノレン酸(18:3)等)、炭素数20の不飽和脂肪酸)であることが好ましい。 In the plastic fat and oil composition of the present invention, the constituent fatty acids at positions 1 and 3 of triglyceride in which oleic acid is bound at position 2 may be either saturated fatty acids or unsaturated fatty acids. Examples of triglyceride in which the 2-position is oleic acid include, but not particularly limited to, SOS triglyceride, SOU triglyceride, UOU triglyceride and the like. "O" means oleic acid which is a constituent fatty acid of triglyceride. Since it is easy to suppress the feeling of chewing by storage in the chilled temperature range of a baked product, when the constituent fatty acid at the 1st or 3rd position of the triglyceride having oleic acid bound to the 2nd position is a saturated fatty acid, it has 4 to 24 carbon atoms It is preferred that it is a saturated fatty acid. The unsaturated fatty acid having 18 carbon atoms (oleic acid (18: 1), linoleic acid (18: 2) when the constituent fatty acid at position 1 or 3 of triglyceride in which oleic acid is bound at position 2 is an unsaturated fatty acid And linolenic acid (18: 3 etc.) and unsaturated fatty acids having 20 carbon atoms are preferable. When the constituent fatty acid at position 1 or 3 of triglyceride in which oleic acid is bound at position 2 is a saturated fatty acid and an unsaturated fatty acid, the above-mentioned saturated fatty acid (saturated fatty acid having 4 to 24 carbon atoms) and unsaturated fatty acid (carbon It is preferable that it is several 18 unsaturated fatty acid (Oleic acid (18: 1), linoleic acid (18: 2), linolenic acid (18: 3 etc.), C20 unsaturated fatty acid).
本発明の可塑性油脂組成物は、油脂の構成脂肪酸としてトランス酸を含んでいてもよく、含まなくてもよいが、トランス酸の摂取量が多くなると、人体に摂取された際のLDLコレステロールが増加しうる。よって、これを抑制しやすい観点で、本発明においては、油脂の構成脂肪酸中のトランス酸の含有量は、油脂の構成脂肪酸全体の質量に対して10質量%未満であることが好ましく、5質量%未満であることがより好ましく、3質量%未満であることが最も好ましい。 The plastic fat composition of the present invention may or may not contain trans acid as a constituent fatty acid of fat or oil, but when the intake of trans acid increases, LDL cholesterol increases when it is ingested by the human body It can. Therefore, from the viewpoint of easily suppressing this, in the present invention, the content of trans acid in the constituent fatty acids of the oil is preferably less than 10% by mass with respect to the total mass of the constituent fatty acids of the oil, 5 mass It is more preferably less than%, and most preferably less than 3% by mass.
本発明において、トリグリセリドの構成脂肪酸の分析は、ガスクロマトグラフ法(基準油脂分析試験法(公益社団法人日本油化学会)の「2.4.2.2−2013 脂肪酸組成(FID昇温ガスクロマトグラフ法)」と「奨2−2013 2位脂肪酸組成」)により行う。 In the present invention, analysis of fatty acid component of triglyceride is carried out by gas chromatography (standard fat and oil analysis test method (Japan Oil Chemistry Association) “2.4.2.2-2013 Fatty acid composition (FID temperature rising gas chromatography method) ) And “Reward 2-2013 fatty acid composition”)).
(ポリグリセリン縮合リシノレイン酸エステル)
本発明の可塑性油脂組成物に含まれるポリグリセリン縮合リシノレイン酸エステルは、増粘多糖類、グリセリン脂肪酸エステルと組み合わせて含むことにより、得られる焼成品は、チルド温度域の保管により生じるパサツキ感とネチャツキ感の抑制のバランスが良くなり、焼成品のカット時に屑が生じることも抑制しやすい。
(Polyglycerin condensed ricinoleate ester)
The baked product obtained by containing the polyglycerin condensation ricinoleic acid ester contained in the plastic oil-fat composition of this invention in combination with a polysaccharide thickener and a glycerol fatty acid ester has a feeling of crunchy feeling and squeakyness produced by storage of a chilled temperature range. The balance of suppression of feeling is improved, and it is easy to suppress the generation of scraps at the time of cutting the baked product.
ポリグリセリン縮合リシノレイン酸エステルの種類は、特に限定されず、例えば、グリセリンの重合度が2〜10であるポリグリセリン縮合リシノレイン酸エステルが挙げられる。また、市販品としては、阪本薬品工業社製のSY グリスターCR−ED(ポリタイプ)SY グリスターCR−310(テトラグリセリン 重合度4)、SY グリスターCR−500(ヘキサグリセリン 重合度 6)、太陽化学株式会社製のサンソフト 818DG(テトラグリセリン 重合度4)、サンソフト 818R(ペンタグリセリン 重合度5)、サンソフト 818SK(ヘキサグリセリン 重合度6)等が挙げられる。これらのうち、得られる焼成品において、チルド温度域の保管により生じるパサツキ感とネチャツキ感の抑制のバランスが良くなり、焼成品のカット時に屑が生じることも抑制しやすいことから、本発明の可塑性油脂組成物に含まれる全てのポリグリセリン縮合リシノレイン酸エステルのうち、グリセリンの重合度が4〜6であるポリグリセリン縮合リシノレイン酸エステルの質量が最も多いことが好ましい。ポリグリセリン縮合リシノレイン酸エステルは、ポリグリセリンと縮合リシノール酸とのエステル化物であり、エステル化反応は公知の方法で製造される。ポリグリセリンは、通常グリセリンもしくはグリシドールやエピクロルヒドリン等を加熱し、重縮合反応させて得られる重合度の異なるポリグリセリンの混合物である。そのため市販品においては、異なる重合度のグリセリンのポリグリセリン縮合リシノレイン酸エステルの混合物であり、上述の市販品のグリセリンの重合度は、最も多いグリセリンの重合度を示している。特に、焼成品のパサツキを抑制するという観点では、グリセリンの重合度が高いポリグリセリン縮合リシノレイン酸エステル(より具体的には、グリセリンの重合度6のポリグリセリン縮合リシノレイン酸エステル)を用いることが好ましい。また、焼成品のネチャツキ感を抑制するという観点では、グリセリンの重合度が低いポリグリセリン縮合リシノレイン酸エステル(より具体的には、グリセリンの重合度4のポリグリセリン縮合リシノレイン酸エステル)が好ましい。また、ポリグリセリン縮合リシノレイン酸エステルのリシノレイン酸の重合度は、特に限定されず、例えば、2〜10であるものを使用することができる。 The type of polyglycerin condensed ricinoleate is not particularly limited, and examples thereof include polyglycerin condensed ricinoleate having a degree of polymerization of glycerin of 2 to 10. As commercially available products, SY Glyster CR-ED (polytype) SY Glyster CR-310 (tetraglycerin polymerization degree 4), SY Glyster CR-500 (hexaglycerin polymerization degree 6), manufactured by Sakamoto Yakuhin Kogyo Co., Ltd. Sunsoft 818 DG (tetraglycerin degree of polymerization 4), Sunsoft 818R (pentaglycerin degree of polymerization 5), Sunsoft 818 SK (hexaglycerin degree of polymerization 6), etc. may be mentioned. Among these, in the fired product to be obtained, the balance between suppression of a feeling of slap and a feeling of squeaky feeling caused by storage in a chilled temperature range is improved, and generation of scraps at the time of cutting of a fired product is easily suppressed. It is preferable that the mass of polyglycerin condensation ricinoleic acid ester whose degree of polymerization of glycerol is 4 to 6 among all the polyglycerin condensation ricinoleate contained in the oil and fat composition is the largest. The polyglycerin condensed ricinoleate is an ester of polyglycerin and a condensed ricinoleic acid, and the esterification reaction is produced by a known method. The polyglycerin is usually a mixture of polyglycerins having different degrees of polymerization, which is obtained by heating and polycondensation reaction of glycerin or glycidol, epichlorohydrin or the like. Therefore, in the commercial product, it is a mixture of polyglycerin condensed ricinoleate ester of glycerin having different degrees of polymerization, and the polymerization degree of the commercially available glycerin mentioned above indicates the highest polymerization degree of glycerin. In particular, it is preferable to use polyglycerin condensed ricinoleic acid ester having a high degree of polymerization of glycerin (more specifically, polyglycerin condensed ricinoleic acid ester having a degree of polymerization of glycerin of 6) from the viewpoint of suppressing the puffiness of baked products. . In addition, from the viewpoint of suppressing the squeaky feeling of the baked product, polyglycerin condensed ricinoleate having a low degree of polymerization of glycerin (more specifically, polyglycerin condensed ricinoleate having a degree of polymerization of glycerin) is preferable. Moreover, the polymerization degree of the ricinoleic acid of polyglycerin condensation ricinoleic acid ester is not specifically limited, For example, what is 2-10 can be used.
ポリグリセリン縮合リシノレイン酸エステルの含有量は、特に限定されないが、得られる焼成品が、チルド温度域の保管により生じるパサツキ感とネチャツキ感の抑制のバランスが良くなり、焼成品に異味を生じにくなり、また焼成品のカット時に屑が生じることも抑制しやすいことから、可塑性油脂組成物全体の質量に対して、0.001〜2.0質量%であることが好ましく、0.005〜1.5質量%であることがより好ましく、0.01〜1.0質量%であることが更に好ましい。0.02〜0.6質量%であることが最も好ましい。特に、本発明の可塑性油脂組成物に含まれる全重合度のポリグリセリン縮合リシノレイン酸エステルのうち、重合度が4〜6であるポリグリセリン縮合リシノレイン酸エステルの質量が最も多い場合は、得られる焼成品に異味が生じにくく、チルド温度域の保管により生じるパサツキ感とネチャツキ感の抑制のバランスが良くなり、焼成品のカット時に屑が生じることも抑制しやすいことから、ポリグリセリン縮合リシノレイン酸エステルの含有量は、可塑性油脂組成物全体の質量に対して、0.01〜1.5質量%であることが好ましく、0.1〜1.2質量%であることがより好ましく、0.1〜1.0質量%であることが更に好ましい。 The content of the polyglycerin condensed ricinoleate is not particularly limited, but the resulting baked product has a good balance between suppression of a feeling of pasackiness and a feeling of netache caused by storage in a chilled temperature range, and the baked product is not likely to have an unpleasant taste. In addition, it is preferable that the content is 0.001 to 2.0% by mass with respect to the total mass of the plastic oil-and-fat composition, because it is easy to suppress generation of scraps at the time of cutting the baked product. The content is more preferably 0.5 mass%, further preferably 0.01 to 1.0 mass%. It is most preferable that it is 0.02-0.6 mass%. In particular, when the mass of polyglycerin condensed ricinoleic acid ester having a polymerization degree of 4 to 6 among polyglycerin condensed ricinoleic acid esters having a total degree of polymerization contained in the plastic oil / fat composition of the present invention, The product is unlikely to produce off-tastes, and the balance between the feeling of crunchy feeling and the feeling of netchasing caused by storage in the chilled temperature range is well balanced, and it is easy to suppress the generation of scraps when cutting baked products. The content is preferably 0.01 to 1.5% by mass, more preferably 0.1 to 1.2% by mass, and more preferably 0.1 to 1.2% by mass with respect to the mass of the entire plastic oil and fat composition. More preferably, it is 1.0% by mass.
(グリセリン脂肪酸エステル)
本発明の可塑性油脂組成物は、グリセリン脂肪酸エステルを、ポリグリセリン縮合リシノレイン酸エステルと増粘多糖類と組合せて含むことにより、得られる焼成品は、チルド温度域の保管により生じるパサツキ感とネチャツキ感の抑制のバランスが良くなり、焼成品のカット時に屑が生じることも抑制しやすい。
(Glycerin fatty acid ester)
The plastic fat and oil composition of the present invention contains glycerin fatty acid ester in combination with polyglycerin condensed ricinoleate and a polysaccharide thickener, so that the baked product obtained has a feeling of parsackiness and feeling of netache due to storage in a chilled temperature range. The balance of suppression is improved, and it is easy to suppress the generation of scraps at the time of cutting the fired product.
グリセリン脂肪酸エステルは、特に限定されないが、例えば、ジグリセリンモノ脂肪酸エステル、トリグリセリンモノ脂肪酸エステル、ペンタグリセリンモノ脂肪酸エステル等のポリグリセリン脂肪酸エステルの他、モノグリセリンモノ脂肪酸エステルが挙げられる。これらのうち、モノグリセリンモノ脂肪酸エステルは、焼成品中のデンプン構造に入り込み、デンプンの結晶化を抑制して保水力を向上させることができ、結果として、得られる焼成品において、チルド温度域の保管により生じるパサツキ感を抑制しやすいことから、モノグリセリンモノ脂肪酸エステルを用いることが好ましい。 The glycerin fatty acid ester is not particularly limited, and examples thereof include monoglycerin mono fatty acid esters in addition to polyglycerin fatty acid esters such as diglycerin mono fatty acid ester, triglycerin mono fatty acid ester, pentaglycerin mono fatty acid ester and the like. Among these, monoglycerin mono-fatty acid ester enters the starch structure in the baked product, can suppress the crystallization of starch and improve the water holding capacity, and as a result, in the obtained baked product, the chilled temperature range It is preferable to use monoglycerin mono-fatty acid ester because it is easy to suppress the feeling of coldness caused by storage.
モノグリセリンモノ脂肪酸エステルの種類は、特に限定されず、例えば、モノグリセリンモノステアリン酸エステル、モノグリセリンモノオレイン酸エステル、モノグリセリンモノリノール酸エステル、モノグリセリンモノラウリン酸エステル、モノグリセリンモノミリスチン酸エステル、モノグリセリンモノパルミチン酸エステル、モノグリセリンモノアラキジン酸エステル、モノグリセリンモノベヘン酸エステル、モノグリセリンモノリグノセリン酸エステル、モノグリセリンモノミリストレイン酸エステル、モノグリセリンモノパルミトレイン酸エステル、モノグリセリンモノリノレン酸エステル、モノグリセリンモノエルカ酸エステル、モノグリセリンモノカプリン酸エステル、モノグリセリンモノカプリル酸エステル、モノグリセリンモノカプロン酸エステル、モノグリセリンモノ酪酸エステル、モノグリセリンモノデカン酸エステル、モノグリセリンモノノナン酸エステル、モノグリセリンモノオクタン酸エステル、モノグリセリンモノヘプタン酸エステル、モノグリセリンモノヘキサン酸エステル、モノグリセリンモノペンタン酸エステル、モノグリセリンモノブタン酸エステル等が挙げられる。これらのうち、得られる焼成品が、チルド温度域の保管により生じるパサツキ感とネチャツキ感の抑制のバランスが良くなり、焼成品のカット時に屑が生じることも抑制しやすいことから、モノグリセリンモノステアリン酸エステルを用いることが好ましい。これらは、単独で用いてもよく、2種以上を併用してもよい。 The type of monoglycerin mono fatty acid ester is not particularly limited. For example, monoglycerin monostearate, monoglycerin monooleate, monoglycerin monolinoleate, monoglycerin monolaurate, monoglycerin monomyristic ester, Monoglycerin monopalmitate ester, monoglycerin monoarachidic acid ester, monoglycerin monobehenic acid ester, monoglycerin mono lignoceric acid ester, monoglycerin monomyristoleate ester, monoglycerin monopalmitoleate ester, monoglycerin monolinolenic acid Ester, monoglycerin mono-erucic acid ester, mono-glycerin mono-caprylate ester, mono-glycerin mono-caprylate ester, mono-glycerine Monocaproic ester, monoglycerin monobutyric ester, monoglycerin monodecanoic acid ester, monoglycerin monononanoic acid ester, monoglycerin monooctanoic acid ester, monoglycerin monoheptanoic acid ester, monoglycerin monohexanoic acid ester, monoglycerin monopentanoic acid Ester, monoglycerin monobutanoic acid ester, etc. are mentioned. Among these, the obtained baked product has a good balance between suppression of a feeling of thinness and feeling of netache feeling caused by storage in a chilled temperature range, and it is easy to suppress generation of scraps when cutting a baked product. It is preferred to use an acid ester. These may be used alone or in combination of two or more.
グリセリン脂肪酸エステルの含有量は、特に限定されないが、得られる焼成品が、チルド温度域の保管により生じるパサツキ感とネチャツキ感の抑制のバランスが良くなり、焼成品のカット時に屑が生じることも抑制しやすいことから、0.01〜5.0質量%であることが好ましく、0.05〜3.0質量%であることがより好ましく、0.1〜2.0質量%であることが更に好ましく、0.5〜1.5質量%であることが最も好ましい。 The content of the glycerin fatty acid ester is not particularly limited, but the resulting baked product has a good balance between suppression of a feeling of crunch and a feeling of entanglement caused by storage in a chilled temperature range, and generation of scraps at the time of cutting the baked product is also suppressed. It is preferable that it is 0.01-5.0 mass%, it is more preferable that it is 0.05-3.0 mass%, and it is further more preferable that it is 0.1-2.0 mass%, since it is easy to carry out. Preferably, 0.5 to 1.5% by mass is the most preferable.
(増粘多糖類)
本発明の可塑性油脂組成物は、増粘多糖類を、ポリグリセリン縮合リシノレイン酸エステルとグリセリン脂肪酸エステルと組合せて含むことにより、得られる焼成品は、チルド温度域の保管により生じるパサツキ感とネチャツキ感の抑制のバランスが良くなり、焼成品のカット時に屑が生じることも抑制しやすい。
(Thickening polysaccharide)
The plastic oil / fat composition of the present invention contains a polysaccharide thickener in combination with polyglycerin condensed ricinoleate and glycerin fatty acid ester, so that the baked product obtained has a feeling of puffiness and squeaky feeling caused by storage in a chilled temperature range. The balance of suppression is improved, and it is easy to suppress the generation of scraps at the time of cutting the fired product.
増粘多糖類の種類は、特に限定されないが、ジェランガム、カラヤガム、タマリンド種子ガム、タラガム、グルコマンナン、キサンタンガム、ローカストビーンガム、プルラン、グアガム、イオタカラギナン、ペクチン、トラガントガム、結晶性セルロース、PGA(アルギン酸プロピレングリコールエステル)、SSHC(水溶性大豆多糖類)、ガティガム、メチルセルロース、ヒドロキシプロピルメチルセルロース、サイリウムシード、カシヤガム等が挙げられる。これらのうち、より焼成品のシトリが向上させてカット時の屑の発生を抑制できることから、キサンタンガム、ペクチン、グアガムを用いることが好ましい。別の観点で、特に高い保水力を有し、チルド温度域の保管により生じるパサツキ感を抑制し、かつ焼成品のソフトさとシトリが更に向上させてカット時の屑の発生を抑制できることから、キサンタンガムを用いることが好ましい。これらは単独で用いてもよく、2種以上を併用してもよい。 The type of polysaccharide thickener is not particularly limited, but gellan gum, karaya gum, tamarind seed gum, tara gum, glucomannan, xanthan gum, locust bean gum, pullulan, guar gum, iota carrageenan, pectin, tragant gum, crystalline cellulose, PGA (alginic acid Propylene glycol ester), SSHC (water-soluble soybean polysaccharide), gati gum, methylcellulose, hydroxypropyl methylcellulose, pylium seed, oak gum and the like. Among these, it is preferable to use xanthan gum, pectin and guar gum, since it is possible to further improve the diet of the baked product and to suppress the generation of chips at the time of cutting. From another point of view, it has particularly high water holding capacity, suppresses the feeling of parsock caused by storage in the chilled temperature range, and further improves the softness and setting of the baked product to suppress generation of scraps at the time of cutting; It is preferable to use These may be used alone or in combination of two or more.
増粘多糖類の含有量は、特に限定されないが、得られる焼成品が、チルド温度域の保管により生じるパサツキ感とネチャツキ感の抑制のバランスが良くなり、焼成品のカット時に屑が生じることも抑制しやすいことから、可塑性油脂組成物全体の質量に対して、0.01〜7.0質量%であることが好ましく、0.1〜5.0質量%であることがより好ましく、1.0〜3.5質量%であることが更に好ましい。 The content of the polysaccharide thickener is not particularly limited, but the resulting baked product has a good balance between suppression of a feeling of crunch and a feeling of entanglement caused by storage in a chilled temperature range, and scraps may also be generated when cutting the baked product. It is preferable that it is 0.01-7.0 mass% with respect to the mass of the whole plastic oil-fat composition, since it is easy to suppress, it is more preferable that it is 0.1-5.0 mass%, 1. More preferably, it is 0 to 3.5% by mass.
(グリセリン有機酸脂肪酸エステル)
本発明の可塑性油脂組成物は、更にグリセリン有機酸脂肪酸エステルを含有してもよく、含有しなくてもよいが、得られる焼成品が、チルド温度域の保管により生じるパサツキ感及びネチャツキ感を抑制させ、歯切れを向上させ、焼成品のカット時に屑が生じることを抑制できることから、グリセリン有機酸脂肪酸エステルを更に含有することが好ましい。
(Glycerin organic acid fatty acid ester)
The plastic oil-and-fat composition of the present invention may or may not further contain a glycerin organic acid fatty acid ester, but the resulting baked product suppresses the sensation of parsackiness and netchuck caused by storage in the chilled temperature range. It is preferable to further contain a glycerin organic acid fatty acid ester because it can improve the chipping and suppress the generation of scraps at the time of cutting the baked product.
グリセリン有機酸脂肪酸エステルの種類は、特に限定されないが、例えば、グリセリン酢酸脂肪酸エステル、グリセリン乳酸脂肪酸エステル、グリセリンクエン酸脂肪酸エステル、グリセリンコハク酸脂肪酸エステル、グリセリンジアセチル酒石酸脂肪酸エステル等が挙げられる。これらのうち、得られる焼成品のチルド温度域の保管により生じるパサツキ感をより抑制できることから、グリセリンクエン酸脂肪酸エステル、グリセリンコハク酸脂肪酸エステルを用いることが好ましい。グリセリン有機酸脂肪酸エステルは、単独で使用してもよく、2種以上を併用してもよい。 The type of glycerin organic acid fatty acid ester is not particularly limited, and examples thereof include glycerin acetic acid fatty acid ester, glycerin lactic acid fatty acid ester, glycerin citric acid fatty acid ester, glycerin succinic acid fatty acid ester, glycerin diacetyl tartaric acid fatty acid ester and the like. Among these, it is preferable to use a glycerin citric acid fatty acid ester or a glycerin succinic acid fatty acid ester because it can further suppress a feeling of coldness caused by storage of a chilled temperature range of a baked product to be obtained. The glycerin organic acid fatty acid ester may be used alone or in combination of two or more.
本発明の可塑性油脂組成物中のグリセリン有機酸脂肪酸エステルの含有量は、特に限定されないが、得られる焼成品のチルド温度域の保管により生じるパサツキ感をより抑制できることから、可塑性油脂組成物全体の質量に対して0.01〜5.0質量%であることが好ましく、0.01〜1.5質量であることが好ましく、0.1〜1.2質量%であることが更に好ましく、0.1〜1.0質量%であることが最も好ましい。 The content of the glycerin organic acid fatty acid ester in the plastic oil / fat composition of the present invention is not particularly limited, but it is possible to further suppress the sensation of palpitation caused by storage of the chilled temperature range of the obtained baked product. It is preferable that it is 0.01-5.0 mass% with respect to mass, It is preferable that it is 0.01-1.5 mass, It is still more preferable that it is 0.1-1.2 mass%, 0 It is most preferable that it is 0.1 to 1.0% by mass.
本発明において、グリセリン有機酸脂肪酸エステルの含有量の分析は、HPLC−MS/MSにより行う。 In the present invention, analysis of the content of glycerin organic acid fatty acid ester is performed by HPLC-MS / MS.
(糖質分解酵素、リン脂質分解酵素)
本発明の可塑性油脂組成物は、糖質分解酵素又はリン脂質分解酵素の少なくともいずれか一方を更に含有してもよく、含有しなくてもよい。本発明の可塑性油脂組成物は、糖質分解酵素又はリン脂質分解酵素の少なくともいずれか一方を含むことにより、焼成品のパサツキ感を抑制することができる。通常、糖質分解酵素、リン脂質分解酵素を用いると、焼成品が弾力性を失いやすいが、本発明の可塑性油脂組成物は、糖質分解酵素、リン脂質分解酵素を含んだ場合においても、焼成品が弾力性を失わず、焼成品のパサツキ感を抑制することができる。このように、焼成品の弾力性を維持しつつ、焼成品のパサツキ感を抑制できることから、糖質分解酵素、リン脂質分解酵素を含むことが好ましい。
(Carbodolytic enzyme, phospholipid hydrolyzing enzyme)
The plastic fat and oil composition of the present invention may or may not further contain at least one of a carbohydrate degrading enzyme and a phospholipid degrading enzyme. The plastic oil-fat composition of this invention can suppress the feeling of parched feeling of baked goods by containing at least any one of a carbohydrate degradation enzyme or a phospholipid degradation enzyme. In general, the baked good tends to lose elasticity when using a carbohydrate degrading enzyme and a phospholipid degrading enzyme, but the plastic fat and oil composition of the present invention contains a carbohydrate degrading enzyme and a phospholipid degrading enzyme, The baked product does not lose elasticity, and the feeling of the baked product can be suppressed. As described above, it is preferable to contain a carbohydrate-degrading enzyme and a phospholipid-degrading enzyme, since it is possible to suppress the feeling of thinness of the baked product while maintaining the elasticity of the baked product.
本発明における糖質分解酵素は、特に限定されないが、例えば、αアミラーゼ、βアミラーゼ、イソアミラーゼ、グルコアミラーゼ、キシラナーゼ、ガラクタナーゼ、セルラーゼ等が挙げられる。これらのうち、αアミラーゼを用いることが好ましい。これらは単独で用いてもよく、2種以上を併用してもよい。 The carbohydrate degrading enzyme in the present invention is not particularly limited, and examples thereof include α-amylase, β-amylase, isoamylase, glucoamylase, xylanase, glactanase, cellulase and the like. Among these, it is preferable to use α-amylase. These may be used alone or in combination of two or more.
本発明におけるリン脂質分解酵素は、特に限定されないが、例えば、ホスホリパーゼA、ホスホリパーゼB、ホスホリパーゼC、ホスホリパーゼD等が挙がられる。これらのうち、ホスホリパーゼAを用いることが好ましい。これらは単独で用いてもよく、2種以上を併用してもよい。 The phospholipid degradation enzyme in the present invention is not particularly limited, and examples thereof include phospholipase A, phospholipase B, phospholipase C, phospholipase D and the like. Among these, it is preferable to use phospholipase A. These may be used alone or in combination of two or more.
本発明の可塑性油脂組成物における糖質分解酵素又はリン脂質分解酵素の、可塑性油脂組成物中における合計含有量は、特に限定されず、例えば、可塑性油脂組成物全体の質量に対して、0.0001〜0.01質量%であってもよいが、0.001〜0.01質量%であることが好ましい。なお、上記糖質分解酵素又はリン脂質分解酵素の可塑性油脂組成物中の含有量は、いずれも可塑性油脂組成物に含まれる場合は、糖質分解酵素及びリン脂質分解酵素の合計含有量であってもよく、各々の含有量であってもよい。 The total content of the carbohydrate-degrading enzyme or the phospholipid-degrading enzyme in the plastic fat-and-oil composition of the present invention is not particularly limited, and is, for example, 0. 0 to the mass of the entire plastic fat-and-oil composition. Although it may be 0001-0.01 mass%, it is preferable that it is 0.001-0.01 mass%. The content of the above-mentioned carbohydrate degrading enzyme or phospholipid degrading enzyme in the plastic oil-fat composition is the total content of the carbohydrate degrading enzyme and the phospholipid degrading enzyme when all are contained in the plastic oil-fat composition. Each content may be used.
(その他)
本発明の可塑性油脂組成物は、水相を実質的に含有しない形態と、水相を含有する形態のいずれの形態であってもよい。水相を含有する形態の場合、本発明の可塑性油脂組成物は、特に限定されないが、例えば、マーガリン類であってもよい。また、水相を含有する乳化形態は、特に限定されないが、例えば、油中水型、水中油型、油中水中油型、水中油中水型等が挙げられる。この場合の油相の含有量は、可塑性油脂組成物の全体の質量に対して、好ましくは55〜99.95質量%であり、より好ましくは60〜99.4質量%であり、より好ましくは65〜98質量%である。また、水相の含有量は、可塑性油脂組成物の全体の質量に対して、好ましくは0.5〜45質量%であり、より好ましくは、0.6〜40質量%であり、更に好ましくは、2〜35質量%である。乳化形態は、特に、得られる焼成品において、チルド温度域の保管により生じるパサツキ感及びネチャツキ感を抑制させ、歯切れを向上させ、焼成品のカット時に屑が生じることを抑制できることから、油中水型であることが好ましい。
(Others)
The plastic fat and oil composition of the present invention may be in any form of a form substantially containing no aqueous phase and a form containing an aqueous phase. In the case of the form containing an aqueous phase, the plastic oil / fat composition of the present invention is not particularly limited, and may be, for example, margarines. The form of the emulsion containing the aqueous phase is not particularly limited, and examples thereof include a water-in-oil type, an oil-in-water type, an oil-in-water-in-oil type, and a water-in-oil-in-water type. The content of the oil phase in this case is preferably 55 to 99.95% by mass, more preferably 60 to 99.4% by mass, based on the total mass of the plastic oil-fat composition, more preferably It is 65-98 mass%. In addition, the content of the aqueous phase is preferably 0.5 to 45% by mass, more preferably 0.6 to 40% by mass, and still more preferably, with respect to the total mass of the plastic oil / fat composition. And 2 to 35% by mass. In the emulsified form, in particular, in the obtained baked product, it is possible to suppress a feeling of thinness and feeling of spinaching caused by storage in a chilled temperature range, improve tooth breakage, and suppress generation of debris when cutting the baked product. Preferably it is a mold.
マーガリン類とは、マーガリン又はファットスプレッドのことを指す。マーガリンは、油脂を80質量%以上含み、ファットスプレッドは、油脂を80質量%未満含むものである。 Margarines refer to margarine or fat spread. Margarine contains 80% by mass or more of fat and oil, and fat spread contains less than 80% by mass of fat and oil.
水相を実質的に含有しない形態としては、ショートニングが挙げられる。本発明において、「実質的に含有しない」とは、水分(揮発分を含む。)の含有量が0.5質量%以下であることである。 A form that does not substantially contain the aqueous phase includes shortening. In the present invention, "substantially free of" means that the content of water (including volatile matter) is 0.5% by mass or less.
本発明の可塑性油脂組成物は、上記のポリグリセリン縮合リシノレイン酸エステル有機酸モノグリセリン脂肪酸エステル、及びグリセリンモノ脂肪酸エステル以外の乳化剤を含んでもよく、含まなくてもよいが、そのような乳化剤としては、例えば、レシチン、ショ糖脂肪酸エステル、プロピレングリコール脂肪酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル等が挙げられる。 The plastic fat and oil composition of the present invention may or may not contain an emulsifier other than the above polyglycerin polycondensed ricinoleic acid ester organic acid monoglycerin fatty acid ester and glycerol monofatty acid ester, but as such an emulsifier For example, lecithin, sucrose fatty acid ester, propylene glycol fatty acid ester, calcium stearoyl lactate, sodium stearoyl lactate, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester and the like can be mentioned.
本発明の可塑性油脂組成物は、上記成分以外に、従来の公知の成分を含んでもよく、含まなくてもよい。そのような公知の成分としては、特に限定されないが、例えば、乳、乳製品、糖質分解酵素及びリン脂質分解酵素以外の酵素又は蛋白質、増粘多糖類以外の糖質、塩類、卵加工品、酸味料、pH調整剤、抗酸化剤、調味料、コンソメ・ブイヨン等の植物及び動物エキス、ウイスキー・ウォッカ・ブランデー等の蒸留酒、ワイン・日本酒・ビール等の醸造酒、各種リキュール、乳製品を酵素処理した呈味剤、香辛料、着色成分、香料等の食品素材や食品添加物が挙げられる。乳としては、例えば、牛乳等が挙げられる。乳製品としては、脱脂乳、クリーム、チーズ(ナチュラルチーズ、プロセスチーズ等)、発酵乳、濃縮乳、脱脂濃縮乳、無糖れん乳、加糖れん乳、無糖脱脂れん乳、加糖脱脂れん乳、全粉乳、脱脂粉乳、クリームパウダー、ホエイパウダー、タンパク濃縮ホエイパウダー、ホエイ蛋白コンセントレート(WPC)、ホエイ蛋白アイソレート(WPI)、バターミルクパウダー、トータルミルクプロテイン、カゼインナトリウム、カゼインカリウム等が挙げられる。糖質分解酵素及びリン脂質分解酵素以外の蛋白質としては、大豆蛋白、エンドウ豆蛋白、小麦蛋白等の植物蛋白等が挙げられる。増粘多糖類以外の糖質としては、単糖(グルコース、フルクトース、ガラクトース、マンノース等)、二糖類(ラクトース、スクロース、マルトース、トレハロース等)、オリゴ糖、糖アルコール等が挙げられる、抗酸化剤としては、例えば、L−アスコルビン酸、L−アスコルビン酸誘導体、トコフェロール、トコトリエノール、リグナン、ユビキノン類、キサンチン類、オリザノール、植物ステロール、カテキン類、ポリフェノール類、茶抽出物等が挙げられる。香辛料としては、例えば、カプサイシン、アネトール、オイゲノール、シネオール、ジンゲロン等が挙げられる。着色成分としては、例えば、カロテン、アスタキサンチン、アナトー等が挙げられる。香料としては、バターフレーバー、ミルクフレーバー等が挙げられる。 The plastic fat and oil composition of the present invention may or may not contain conventionally known components in addition to the above components. Examples of such known components include, but are not limited to, for example, enzymes or proteins other than milk, dairy products, carbohydrate degrading enzymes and phospholipid degrading enzymes, carbohydrates other than thickening polysaccharides, salts, processed eggs Acidulants, pH adjusters, antioxidants, seasonings, plant and animal extracts such as konsome and bouillon, distilled liquors such as whiskey, vodka and brandy, brews such as wine, sake and beer, various liqueurs, dairy products And food ingredients and food additives such as flavoring agents, spices, coloring ingredients, flavors and the like obtained by enzymatic treatment of Examples of milk include milk and the like. As dairy products, skimmed milk, cream, cheese (natural cheese, processed cheese, etc.), fermented milk, concentrated milk, skimmed concentrated milk, non-sugared milk, sweetened milk, sweetened skimmed milk, sweetened skimmed milk, Whole milk powder, skimmed milk powder, cream powder, whey powder, protein-concentrated whey powder, whey protein concentrate (WPC), whey protein isolate (WPI), buttermilk powder, total milk protein, casein sodium, casein potassium etc. . Examples of proteins other than carbohydrate degrading enzymes and phospholipid degrading enzymes include plant proteins such as soybean protein, pea protein and wheat protein. Carbohydrates other than polysaccharide thickeners include monosaccharides (glucose, fructose, galactose, mannose, etc.), disaccharides (lactose, sucrose, maltose, trehalose, etc.), oligosaccharides, sugar alcohols, etc. Antioxidants Examples of L-ascorbic acid, L-ascorbic acid derivatives, tocopherols, tocotrienols, lignans, ubiquinones, xanthines, oryzanols, plant sterols, catechins, polyphenols, tea extracts and the like. Examples of the spice include capsaicin, anethole, eugenol, cineole, zingerone and the like. Examples of the coloring component include carotene, astaxanthin, annatto and the like. As a flavor, butter flavor, milk flavor, etc. are mentioned.
本発明の可塑性油脂組成物の用途は特に限定されず、製菓又は製パン用、バタークリーム用、スプレッド用に用いることができる。製菓又は製パン用としては、ロールイン用、練り込み用等が挙げられる。特に、本発明の可塑性油脂組成物は、製パン用として用いた場合に、得られる焼成品において、チルド温度域の保管により生じるパサツキ感及びネチャツキ感の抑制のバランスに優れ、焼成品のカット時に屑が生じることを抑制できる。このことから、本発明の可塑性油脂組成物は、製パン用として用いることが好ましい。 The application of the plastic fat / oil composition of the present invention is not particularly limited, and it can be used for confectionery or baking, for butter cream, for spread. For confectionery or baking, roll-in, kneading and the like can be mentioned. In particular, when the plastic oil-and-fat composition of the present invention is used for bread making, the baked product obtained is excellent in the balance of suppression of feeling of parsackiness and feeling of netchasing caused by storage in chilled temperature range, and at the time of cutting baked product. It is possible to suppress the generation of waste. From this, it is preferable to use the plastic fat and oil composition of the present invention for baking.
パン類として、食材を配合するようなもの(例えば、サンドイッチのような食材を挟むもの等)は、チルド温度域における保管によりカットの際にパン屑が発生しやすく、特に、サンドイッチのような薄くスライスするものではこの問題は重要であるため、加工耐性のあるものが求められる。特に、食材を配合するパンは、食材の種類によっては、パンの水分を奪うことがあり、更に乾いてしまい、得られるパンはチルド温度域における保管によりパサツキ感が生じやすい。特に、サンドイッチのような、1センチ程度と薄くスライスされるものは、パンの乾きが速いため、より一層にパンが乾いてしまい、得られるパンはチルド温度域における保管により一層パサツキ感が生じやすい。このような問題に対し、本発明の可塑性油脂組成物によると、上述のとおり、カットの際にパン屑を防止しやすく、また、チルド温度域における保管により生じるパサツキ感を抑制することができる。このことから、本発明の可塑性油脂組成物は、食材が配合されたパン(以下、本明細書において、「食材配合パン」という。)の製造用として用いることが好ましい。食材配合パンとしては、例えば、サンドイッチ、ドックパン、バターロール等が挙げられる。特にサンドイッチのような食材配合パンは、薄いにもかかわらず、カットの際にパン屑を防止しやすく、また、チルド温度域における保管により生じるパサツキ感を抑制することができることから、チルド温度域で保管される食材配合パンの製造用として用いることが好ましい。 Breads, such as those which mix food (eg sandwiching food like sandwiches), tend to generate bread crumbs when cut in storage at chilled temperature range, especially thin like sandwiches Since this problem is important in slicing, it is required to have processing resistance. In particular, depending on the type of food, the bread containing the food may deprive the water of the bread, and the food may be further dried, and the obtained bread is likely to have a feeling of parsley due to storage in a chilled temperature range. In particular, a slice such as a sandwich, which is sliced as thin as about 1 cm, dries the bread faster, and the bread is further dried, and the obtained bread is more likely to have a feeling of parsley due to storage in a chilled temperature range. . With respect to such a problem, according to the plastic fat / oil composition of the present invention, as described above, it is easy to prevent bread crumbs at the time of cutting, and it is possible to suppress the feeling of parsock caused by storage in the chilled temperature range. From this, it is preferable to use the plastic fat and oil composition of the present invention for the production of bread containing a food (hereinafter referred to as "food-containing bread" in the present specification). Examples of the ingredient-containing bread include sandwiches, dock pans, butter rolls and the like. In particular, food-containing bread such as sandwich is easy to prevent bread crumbs at the time of cutting although it is thin, and it can suppress the feeling of parsock caused by storage in the chilled temperature range, so It is preferable to use for production of food material-containing bread to be stored.
<可塑性油脂組成物の製造方法>
本発明の可塑性油脂組成物は、公知の方法により製造することができる。例えば、水相を含有する形態のもの(マーガリン類等)は、本発明の油脂組成物を含む油相と水相とを、適宜に加熱し混合して乳化した後、コンビネーター、パーフェクター、ボテーター、ネクサス等の冷却混合機により急冷捏和し得ることができる。水相を含有しない形態のもの(ショートニング)は、本発明の油脂組成物を含む油相を加熱した後、コンビネーター、パーフェクター、ボテーター、ネクサス等の冷却混合機により急冷捏和し、必要に応じて熟成(テンパリング)して、得ることができる。
<Method for producing plastic oil / fat composition>
The plastic oil-fat composition of this invention can be manufactured by a well-known method. For example, in the form containing an aqueous phase (margarines etc.), an oil phase containing the oil and fat composition of the present invention and an aqueous phase are appropriately heated and mixed and emulsified, and then a combinator, Perfector, It can be quenched and quenched by a cooling mixer such as a botatizer or nexus. The water phase-free form (shortening) is prepared by heating the oil phase containing the oil and fat composition of the present invention, quenching and cooling with a cooling mixer such as a combinator, perfector, votator, nexus, etc. It can be obtained by aging (tempering) accordingly.
本発明の可塑性油脂組成物は、水相を含有する場合は、ポリグリセリン縮合リシノレイン酸エステル、グリセリン脂肪酸エステル及びグリセリン有機酸脂肪酸エステルは、水相、油相いずれにも添加できるが、油相に添加し溶解することが好ましい。 When the plastic oil-and-fat composition of the present invention contains an aqueous phase, polyglycerin condensed ricinoleate, glycerin fatty acid ester and glycerin organic acid fatty acid ester can be added to either the water phase or oil phase. It is preferable to add and dissolve.
増粘多糖類は、あらかじめ水相、又は油相に添加してもよく、あるいは、可塑性油脂組成物を製造した後添加することもできるが、油相に添加し分散することが、生地への分散性が向上し、焼成品のパサツキ感とネチャツキ感の抑制が一層向上するので好ましい。 The polysaccharide thickener may be added in advance to the aqueous phase or oil phase, or may be added after producing the plastic fat composition, but adding and dispersing it in the oil phase is a matter of course. It is preferable because the dispersibility is improved, and the suppression of the sizziness and the squeakiness of the baked product is further improved.
酵素は、あらかじめ水相、又は油相に添加してもよく、あるいは、可塑性油脂組成物を製造した後添加することもできる。その際に酵素が失活しない温度で混合することが好ましい。油相に添加し分散させると、乳化物を製造する際に酵素が失活するのを抑制し、製菓製パンの生地作製時に酵素反応が発現でき、また生地への分散性が向上し、焼成品のパサツキ感とネチャツキ感の抑制が一層向上するので好ましい。 The enzyme may be added to the aqueous phase or oil phase in advance, or may be added after producing the plastic fat composition. At that time, it is preferable to mix at a temperature at which the enzyme does not inactivate. When added to the oil phase and dispersed, the enzyme is prevented from being inactivated when producing the emulsion, and the enzyme reaction can be expressed when producing the dough of confectionery bread, and the dispersibility in the dough is improved, and the baking is performed. It is preferable because the suppression of the feeling of stuffiness and the feeling of sloppy feeling is further improved.
本発明の可塑性油脂組成物の製造に用いられる油脂としては、特に限定されないが、パーム系油脂、ラウリン系油脂、豚脂(ラード)、牛脂、菜種油、大豆油、綿実油、ヒマワリ油、米油、サフラワー油、オリーブ油、ゴマ油、乳脂、それらの分別油又はそれらの加工油(硬化及びエステル交換反応のうち1つ以上の処理がなされたもの)等が挙げられる。飽和脂肪酸である構成脂肪酸の含有量が、油脂全体の構成脂肪酸の質量に対して、27〜55質量%となるよう適宜調整するために、これらの油脂としては、1種あるいは2種以上を選択して含有させることが好ましい。 The fats and oils used for producing the plastic fat and oil composition of the present invention are not particularly limited, but palm based fats and oils, lauric fats and oils, pork fat (lard), beef tallow, rapeseed oil, soybean oil, cottonseed oil, sunflower oil, sunflower oil, rice oil, Examples thereof include safflower oil, olive oil, sesame oil, milk fat, fractionated oils thereof, or processed oils thereof (which have been subjected to one or more treatments of curing and transesterification), and the like. In order to appropriately adjust the content of the constituent fatty acids that are saturated fatty acids to 27 to 55 mass% with respect to the mass of constituent fatty acids of the whole fats and oils, one or two or more kinds of these fats and oils are selected It is preferable to contain it.
以下に、本発明の可塑性油脂組成物の製造に用いる油脂について、より具体的な例示を示す。本発明の油脂は、例えば、以下のA油脂、B油脂及びC油脂を組み合わせることで調製することができる。 Below, a more specific example is shown about the fats and oils used for manufacture of the plastic fats and oils composition of this invention. The fat and oil of the present invention can be prepared, for example, by combining the following fat and oil, fat and oil, and fat and oil C.
(A油脂)
本明細書において、「A油脂」とは、3飽和量が20〜50質量%でありヨウ素価が20〜40である油脂のことを指す。このようなA油脂としては、特に限定されないが、例えば、上記で述べたパーム系油脂、パーム系油脂のエステル交換油脂等を挙げることができ、1種以上組合せて使用することもできる。中でも、パーム分別硬質油、パーム系油脂とラウリン系油脂とのエステル交換油脂を用いることで結晶核となり、その結果、他油脂の結晶を誘発し、油脂結晶化しやすくなり、結晶化部分(固)と非結晶部分(液)がより明確となるため、焼成品のパサツキを抑制できる。なお、本明細書において、油脂の「3飽和量」とは、その油脂全体の質量に対する、その油脂に含まれる3飽和型トリグリセリドの質量を指し、例えば、上記A油脂の「3飽和量」は、A油脂全体の質量に対する、A油脂に含まれる3飽和型トリグリセリドの質量を意味する。
(A fat and oil)
In this specification, "A fats and oils" refers to the fats and oils which are 20-50 mass% of 3 saturation quantities, and whose iodine value is 20-40. Such A fats and oils are not particularly limited, and examples thereof include palm based fats and oils, transesterified fats and oils of palm based fats and oils described above, and the like, and one or more kinds may be used in combination. Among them, use of palm fractionated hard oil, transesterified oil of palm oil and fat and laurin oil results in crystal nuclei, and as a result, crystals of other oils and fats are induced to be easily crystallized, and the crystallized part (solid) And the non-crystal part (liquid) becomes clearer, so it is possible to suppress the heat buildup of the fired product. In the present specification, the “3 saturated amount” of fat or oil refers to the mass of trisaturated triglyceride contained in the fat or oil relative to the mass of the whole fat or oil, for example, “3 saturated amount of A fat or oil” A, means the mass of trisaturated triglyceride contained in A fat relative to the total mass of the fat.
(B油脂)
本明細書において、「B油脂」とは、3飽和量が2〜20質量%未満である油脂のことを指す。(但し「B油脂」としては、前述の「A油脂」及び後述の「C油脂」は包含しない)このようなB油脂としては、特に限定されないが、例えば、A油脂、C油脂以外の植物油脂、動物油脂(豚脂(ラード)、牛脂等)、これらの分別油、硬化油、エステル交換油脂が挙げられる。中でも、A油脂との相溶性を考慮すると、パーム系油脂であるパーム油、パーム分別軟質部、パーム分別軟質部のエステル交換油脂、豚脂等を組わせて用いることが好ましい。
(B fat and oil)
In this specification, "B fats and oils" refers to the fats and oils whose 3 saturation amount is less than 2-20 mass%. (However, "B fats and oils" does not include the aforementioned "A fats and oils" and "C fats and oils" described later.) Such B fats and oils are not particularly limited, but, for example, vegetable fats and oils other than A fats and C fats and oils And animal fats and oils (pig fat (lard), beef tallow, etc.), fractionated oils thereof, hydrogenated oils, transesterified fats and oils. Among them, in consideration of the compatibility with the A fat and oil, it is preferable to use palm oil which is a palm based fat and oil, a palm fractionated soft part, a transesterified fat and oil of a palm fractionated soft part, a pork fat and the like.
(C油脂)
本明細書において、「C油脂」とは、3飽和量が2%未満である油脂、又は3飽和量が50質量%超である油脂のことを指す。
(C oil and fat)
In the present specification, “C fat and oil” refers to fat and oil having a 3 saturated content of less than 2% or fat and a fat having a 3 saturated content of more than 50% by mass.
3飽和量が2%未満である油脂としては、特に限定されないが、例えば、菜種油、大豆油、コーン油、米油、綿実油、ヒマワリ油、ゴマ油、オリーブ油等が挙げられる。これらは1種単独で使用してもよく、2種以上を併用してもよい。 Examples of fats and oils having a 3-saturated amount of less than 2% include, but are not particularly limited to, rapeseed oil, soybean oil, corn oil, rice oil, cottonseed oil, sunflower oil, sesame oil, olive oil and the like. These may be used alone or in combination of two or more.
3飽和量が50質量%超である油脂としては、特に限定されないが、上記A油脂を除く植物油脂又は動物油脂の硬化油(部分水素添加油又は極度硬化油)や分別油の硬質油、これらを含む油脂を原料とするエステル交換油脂等が挙げられる。これらの中でも、植物油脂又は動物油脂の極度硬化油、あるいはこれを含む油脂を原料とするエステル交換油脂を用いることが好ましい。植物油脂の極度硬化油としては、例えば、ヤシ極度硬化油、パーム極度硬化油、パーム核極度硬化油、菜種極度硬化油等が挙げられる。動物油脂の極度硬化油としては、例えば、豚脂極度硬化油、牛脂極度硬化油等が挙げられる。焼成品の口溶けが良好となる観点からは、融点が50℃以上の極度硬化油を用いる場合は、油脂全量に対し、5質量%以下とすることが好ましい。 The fats and oils having a saturated amount of more than 50% by mass are not particularly limited, but hard oils of vegetable oils and fats except for A fats and oils or animal fats and oils (partially hydrogenated oil or extremely hardened oil) and fractionated oils, Transesterified fats and oils etc. which use as a raw material fats and oils containing this. Among these, it is preferable to use a transesterified oil which uses as a raw material an extremely hardened oil of a vegetable oil or fat, or an animal oil or fat. Examples of the extremely hardened oil of vegetable oil include palm extremely hardened oil, palm extremely hardened oil, palm kernel extremely hardened oil, rapeseed extremely hardened oil and the like. Examples of the extremely hardened oil of animal fats and oils include, for example, extremely hardened oil of pork fat, extremely hardened oil of beef tallow and the like. When using extremely hardened oil having a melting point of 50 ° C. or higher, it is preferable to set the amount to 5% by mass or less based on the total amount of fat and oil, from the viewpoint of improving the melt in the mouth of the baked product.
以上で述べたA油脂、B油脂の配合割合は、A油脂は、全油脂に対して3〜30質量%で配合することが好ましく、B油脂は、全油脂に対して45〜95質量%で配合することが好ましく、C油脂は、全油脂に対して0〜52質量%で配合することが好ましい。 It is preferable to mix A fats and oils with 3-30 mass% with respect to all fats and oils, and B fats and oils with 45-95 mass% with respect to all fats and oils with respect to the compounding ratio of A fats and oils and B fats and oils mentioned above It is preferable to mix | blend, and it is preferable to mix | blend C fats and oils with 0-52 mass% with respect to all fats and oils.
<可塑性油脂組成物が添加された食品>
本発明は、上記可塑性油脂組成物が添加された食品を包含する。
<Food to which a plastic oil composition is added>
The present invention includes a food to which the above-mentioned plastic oil-and-fat composition is added.
食品は、特に限定されないが、焼成品であることが好ましい。焼成品は、特に限定されないが、例えば、菓子類(例えば、パイ、ケーキ(パウンドケーキ等)、クッキー、ビスケット、クラッカー、ワッフル、スコーン、シュー、ドーナツ等)、パン類(食パン、菓子パン、クロワッサン、デニッシュ、ベーグル、ロールパン、コッペパン等)等が挙げられる。これらのうち、本発明の食品がパン類である場合、パン類は、特に、チルド温度域の保管により生じるパサツキ感及びネチャツキ感の抑制のバランスに優れ、カット時に屑が生じることを抑制することができる。このことから、本発明の食品は、パン類であることが好ましい。特に、本発明の食品は、食材の重みでパンが潰れることを抑制でき、また、加工耐性を付与することができることから、食材配合パンであることが好ましい。食材配合パンとしては、例えば、サンドイッチ、ドックパン、バターロール等が挙げられる。特にサンドイッチのような食材配合パンは、薄いにもかかわらず、カットの際にパン屑を防止しやすく、また、チルド温度域における保管により生じるパサツキ感を抑制することができることから、本発明の食品は、チルド温度域で保管される食材配合パンであることが好ましい。 The food is not particularly limited, but is preferably a baked product. The baked products are not particularly limited, but, for example, confectionery (for example, pie, cake (pound cake etc.), cookie, biscuit, cracker, waffle, scone, shoe, donut etc.), bread (baking bread, confectionery bread, croissant, Examples include danish, bagel, roll bread, coppe bread, etc. Among these, when the food of the present invention is bread, breads are particularly excellent in the balance between suppression of a sense of crunch and a feeling of sloppy feeling caused by storage in a chilled temperature range, and suppressing generation of scraps at the time of cutting Can. From this, the food of the present invention is preferably bread. In particular, the food of the present invention is preferably a food-containing bread, because it can suppress the bread from being crushed by the weight of the food and can impart processing resistance. Examples of the ingredient-containing bread include sandwiches, dock pans, butter rolls and the like. In particular, food-containing bread such as sandwich is easy to prevent bread crumbs at the time of cutting although it is thin, and it is possible to suppress a feeling of parsock caused by storage in a chilled temperature range. Is preferably a food-containing bread stored in a chilled temperature range.
<可塑性油脂組成物及び食パンの製造>
(エステル交換油脂の製造)
[エステル交換油脂](A油脂)
パーム核極度硬化油24質量%、パーム油49質量%、パーム極度硬化油27質量%を混合し、触媒としてナトリウムメチラート添加し、減圧下で、エステル交換反応した。エステル交換反応後、水洗、脱水、脱色しエステル交換油脂を得た。エステル交換油脂のヨウ素価は27、3飽和量は43.3質量%であった。
<Manufacture of plastic oil and fat composition and bread>
(Production of transesterified fats and oils)
[Transesterified fats and oils] (A fats and oils)
24 wt% of palm core extreme curing oil, 49 wt% of palm oil and 27 wt% of palm extreme curing oil were mixed, sodium methylate was added as a catalyst, and transesterification was performed under reduced pressure. After the transesterification reaction, it was washed with water, dehydrated and decolored to obtain a transesterified oil. The iodine value of the transesterified fat and oil was 27, 3 and the saturated amount was 43.3% by mass.
[パーム分別軟質部エステル交換油脂](B油脂)
パーム分別軟質油(パームオレイン)(ヨウ素価56)に触媒としてナトリウムメチラートを添加し、減圧下でエステル交換反応を行った。エステル交換反応後、水洗、脱水、脱色、脱臭しエステル交換油脂を得た。パーム分別軟質部エステル交換油脂のヨウ素価は56、3飽和量は9.1質量%であった。
[Palm fractionated soft part transesterified fat and oil] (B fat and oil)
Sodium methylate was added as a catalyst to palm fractionated soft oil (palm olein) (iodine number 56), and transesterification was performed under reduced pressure. After the transesterification reaction, the product was washed with water, dehydrated, decolorized and deodorized to obtain a transesterified oil. The iodine value of the palm fractionated soft part transesterified fat was 56, and the 3-saturation amount was 9.1% by mass.
(マーガリンの製造)
後述する表1に示す油脂配合で75℃の調温し、表1に示す乳化剤を添加し、溶解後、表1に示す増粘多糖類、酵素を分散させ油相を作製した。一方、水16部に脱脂粉乳1.5部添加し、85℃で加熱殺菌して水相を得た。次に、上記で得た油相82.5部に水相17.5部を添加し、プロペラ攪拌機で攪拌して、油中水型に乳化した後、コンビネーターによって急冷捏和して、可塑性油脂組成物である、実施例1〜13、比較例1〜6に係るマーガリンを製造した。
尚、パーム分別硬質油はヨウ素価32であり、3飽和トリグリセリド含量が25.8質量%である油脂を用い、パーム分別軟質油はヨウ素価56の油脂を用いた。
(Manufacture of margarine)
The temperature was adjusted to 75 ° C. by blending the fat and oil shown in Table 1 to be described later, the emulsifier shown in Table 1 was added, and after dissolution, the polysaccharide thickener and enzyme shown in Table 1 were dispersed to prepare an oil phase. On the other hand, 1.5 parts of skimmed milk powder was added to 16 parts of water and heat-sterilized at 85 ° C. to obtain an aqueous phase. Next, 17.5 parts of the aqueous phase is added to 82.5 parts of the oil phase obtained above, and the mixture is stirred with a propeller stirrer to emulsify into a water-in-oil type, and then rapidly cooled and combined by a combinator to obtain plasticity. Margarines according to Examples 1 to 13 and Comparative Examples 1 to 6, which are oil and fat compositions, were produced.
The palm fractionated hard oil had an iodine value of 32 and a trisaturated triglyceride content of 25.8% by mass, and the palm fractionated soft oil had an iodine value of 56.
(乳化剤)
上記実施例、比較例の油脂組成物の作製に用いた乳化剤を以下に示す。配合割合は、後述する表1に記載されたとおりである。
ポリグリセリン縮合リシノレイン酸エステル(CR500、重合度6、阪本薬品工業社製)
ポリグリセリン縮合リシノレイン酸エステル(CR310、重合度6、阪本薬品工業社製)
モノグリセリンモノステアリン酸エステル(エマルジーMS、理研ビタミン社製)
クエン酸モノグリセリン脂肪酸エステル(ポエムK−37V、理研ビタミン社製)
コハク酸モノグリセリン脂肪酸エステル(ポエムB−10、理研ビタミン社製)
尚、上記ポリグリセリン縮合リシノレイン酸エステルの重合度は、ポリグリセリン縮合リシノレイン酸エステルのグリセリンの重合度における最も多い重合度を示した。
(emulsifier)
The emulsifier used for preparation of the oil-fat composition of the said Example and comparative example is shown below. The blend ratio is as described in Table 1 described later.
Polyglycerin-condensed ricinoleic acid ester (CR500, degree of polymerization 6, manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.)
Polyglycerin-condensed ricinoleic acid ester (CR310, degree of polymerization 6, manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.)
Monoglycerin monostearate (Emulsey MS, manufactured by Riken Vitamin Co., Ltd.)
Citric acid monoglycerin fatty acid ester (Poem K-37V, manufactured by Riken Vitamin Co., Ltd.)
Succinic acid monoglycerin fatty acid ester (Poem B-10, manufactured by Riken Vitamin Co., Ltd.)
The degree of polymerization of polyglycerin condensed ricinoleate showed the highest degree of polymerization in the degree of polymerization of glycerin of polyglycerin condensed ricinoleate.
(増粘剤)
上記実施例、比較例の油脂組成物の作製に用いた増粘剤を以下に示す。配合割合は、後述する表1に記載されたとおりである。
キサンタンガム(ビストップD−3000S、三栄源エフ・エフ・アイ社製)
グアガム(RG100、三菱化学フーズ社製)
(Thickener)
The thickener used for preparation of the oil-fat composition of the said Example and comparative example is shown below. The blend ratio is as described in Table 1 described later.
Xanthan gum (Bistop D-3000S, manufactured by San-Ei Gen F.F.I.)
Guar gum (RG100, manufactured by Mitsubishi Chemical Foods Corporation)
(酵素)
上記実施例、比較例の油脂組成物の作製に用いた酵素を以下に示す。配合割合は、後述する表1に記載されたとおりである。
糖質分解酵素(ビオザイム、天野エンザイム株式会社製)
リン脂質分解酵素(デナベイクRICH、長瀬産業株式会社製)
(enzyme)
Enzymes used for preparation of the oil and fat composition of the above Examples and Comparative Examples are shown below. The blend ratio is as described in Table 1 described later.
Carbohydrate degrading enzyme (Biozyme, manufactured by Amano Enzyme Co., Ltd.)
Phospholipid degrading enzyme (Dena bake RICH, manufactured by Nagase Sangyo Co., Ltd.)
(食パンの製造)
上記で得たそれぞれのマーガリンを用いて、下記配合で食パンを製造した。まず、イーストを分散させた水、イーストフード、及び強力粉をミキサーボールに投入し、フックを使用し、低速4分、中低速1分でミキシングを行った。捏上げ温度は24℃であった。その後、27℃、湿度75%の条件で4時間発酵を行った。発酵の終点温度は29℃であり、発酵後、中種生地を得た。その後、上記で製造したマーガリン以外の材料及び中種生地を、低速3分、中高速3分でミキシングした後、上記で製造したマーガリンを投入し、さらに低速3分、中低速4分でミキシングしパン生地を得た。捏上温度は28℃であった。その後、室温で20分フロアタイムをとった後、パン生地を成型して3斤用の焼成型に入れ、38℃、湿度80%のホイロで45分発酵させた後、200℃で40分間焼成して、実施例1〜13及び比較例1〜6に係る食パンを製造した。焼成したパンを室温で放冷させた後、20℃の恒温槽にて1日保管した後、後述する各評価に用いた。以上で述べた食パンの配合を下記に示す。
(Manufacture of bread)
Using the margarines obtained above, bread was prepared according to the following formulation. First, water in which yeast was dispersed, yeast food, and strong flour were introduced into a mixer ball, and mixing was performed using a hook at a low speed of 4 minutes and a medium low speed of 1 minute. The raising temperature was 24 ° C. Thereafter, fermentation was performed at 27 ° C. and 75% humidity for 4 hours. The end point temperature of fermentation was 29 ° C., and after fermentation, a medium seed dough was obtained. Then, after mixing the materials other than margarine manufactured above and medium seed dough at low speed 3 minutes, middle high speed 3 minutes, throwing in margarine manufactured above, and further mixing at low speed 3 minutes, middle low speed 4 minutes I got bread dough. The pumping temperature was 28 ° C. Then, after taking a floor time for 20 minutes at room temperature, the bread dough is molded and put into a baking mold for 3 vessels, fermented with 38% Hilo at 80% humidity, for 45 minutes, and then baked for 40 minutes at 200 ° C. The breads according to Examples 1 to 13 and Comparative Examples 1 to 6 were manufactured. The baked bread was allowed to cool at room temperature and then stored for one day in a thermostat of 20 ° C., and then used for each evaluation described later. The composition of the bread described above is shown below.
[食パン配合]
・中種配合
強力粉 70質量部
イースト 2.5質量部
イーストフード 0.1質量部
水 40質量部
・本捏配合
強力粉 30質量部
上白糖 6質量部
食塩 1.8質量部
脱脂粉乳 2質量部
マーガリン 5質量部
水 25質量部
[Bread formula]
・ Middle class combination Strong powder 70 parts by mass Yeast 2.5 parts by mass Yeast food 0.1 part by mass Water 40 parts by mass ・ Hongu combination with strong powder 30 parts by mass Upper white sugar 6 parts by mass Salt 1.8 parts by mass Skimmed milk powder 2 parts by mass Margarine 5 parts by mass Water 25 parts by mass
<評価>
製造したマーガリン及びそれぞれ添加された食パンに関して、それぞれの10℃保管時における、パンのパサツキ感(1日又は3日保管後)、パンのネチャツキ感、パンの歯切れ、カット時のパンの屑について、評価を行った。
<Evaluation>
With regard to the margarine produced and the bread to which each has been added, the feeling of breadiness (after 1 or 3 days of storage), the feeling of looseness of the bread, the sharpness of the bread, the broken pieces of bread at the time of storage at 10 ° C. I made an evaluation.
(パンのパサツキ感)
食パンを10mmの厚さにスライスした後、10℃で1日又は3日保管した後、パネルによる官能評価を以下の基準で評価した。なお、評価を行ったパネルに関し、五味(甘、酸、塩、苦、うま味)の識別テスト、味の濃度差識別テスト、食品の味の識別テスト、基準臭覚テストを実施し、その各々のテストで適合と判定された20〜40代の男性5名、女性7名をパネルとして選抜した。なお、表1中の「10℃保管時のパンのパサツキ感」の欄の「D+1」は、10℃で1日保管した後についての評価であり、「D+3」は、10℃で3日保管した後についての評価を示す。
◎+:12名中10〜12人がパサツキ感はないと評価した。
◎:12名中8〜9人がパサツキ感はないと評価した。
○:12名中6〜7人がパサツキ感はないと評価した。
△:12名中4〜5人がパサツキ感はないと評価した。
×:12名中3人以下パサツキ感はないと評価した。
(The sense of breadiness)
After the bread was sliced to a thickness of 10 mm and stored at 10 ° C. for 1 day or 3 days, sensory evaluation by the panel was evaluated based on the following criteria. In addition, with respect to the panel that has been evaluated, the test for discrimination of Gomi (sweet, acid, salt, bitter, umami), test for discrimination of difference in concentration of taste, test for discrimination of food taste, and standard smell test were conducted. We selected five men and seven women in their 20s and 40s who were judged to be fit as a panel. In addition, "D + 1" of the column of "passack feeling of bread at 10 ° C. storage" in Table 1 is an evaluation after storage for 1 day at 10 ° C. "D + 3" is storage for 3 days at 10 ° C. Shows the evaluation of
+ +: 10 to 12 out of 12 people evaluated that there was no feeling of puffiness.
◎: 8 to 9 out of 12 evaluated that there was no feeling of puffiness.
○: 6 to 7 out of 12 evaluated that there was no feeling of puffiness.
Fair: 4 to 5 out of 12 people evaluated that there was no feeling of puffiness.
X: 3 or less out of 12 people were judged not to have a feeling of puffiness.
(パンのネチャツキ感)
食パンを10mmの厚さにスライスし、10℃で1日保管後、喫食し、口中でネチャツキ感の有無を上記パネルにて以下の基準で評価した。
◎:12名中8人以上がネチャツキ感ないと評価した。
○:12名中6〜7人がネチャツキ感ないと評価した。
△:12名中4〜5人がネチャツキ感ないと評価した。
×:12名中3人以下がネチャツキ感なしと評価した。
(Steaching feeling of bread)
The bread was sliced to a thickness of 10 mm, stored at 10 ° C. for 1 day, then eaten, and in the mouth, the presence or absence of a sticky feeling was evaluated in the above panel according to the following criteria.
◎: 8 or more out of 12 evaluated that they did not feel nervous.
○: 6 to 7 out of 12 people evaluated that they did not feel nervous.
Fair: 4 to 5 out of 12 people evaluated that they did not feel nervous.
X: Three or less persons out of 12 evaluated that there was no feeling of nervousness.
(パンの歯切れ)
食パンを10mmの厚さにスライスし、10℃で1日保管後、喫食し、歯切れの有無を上記パネルにて以下の基準で評価した。
◎:12名中8人以上が歯切れ良好であると評価した。
○:12名中6〜7人が歯切れ良好であると評価した。
△:12名中4〜5人が歯切れ良好であると評価した。
×:12名中3人以下歯切れ良好であると評価した。
(A piece of bread)
The bread was sliced to a thickness of 10 mm, stored at 10 ° C. for 1 day, then eaten, and the presence or absence of breakage was evaluated in the above panel according to the following criteria.
◎: 8 or more out of 12 persons were evaluated as having a good bite.
○: 6 to 7 out of 12 people rated it as good.
[Delta]: 4 to 5 out of 12 persons were evaluated as having a good bite.
X: It was evaluated that 3 or less out of 12 persons were good.
(カット時のパン屑の発生)
10℃で2日保管後、3斤サイズの食パンをスライサーで10mmの厚さにスライスしたときに発生したパン屑の重量を以下の基準で評価した。
◎:3g以下であった。
○:3g超〜5g以下であった。
△:5g超〜7g以下であった。
×:7g超であった。
(Generation of bread scraps at the time of cutting)
After storage at 10 ° C. for 2 days, the weight of the bread crumbs generated when the 3 loaf size bread was sliced to a thickness of 10 mm with a slicer was evaluated based on the following criteria.
◎: 3 g or less.
○: more than 3 g and not more than 5 g.
Δ: More than 5 g to 7 g or less.
X: It was over 7 g.
<評価結果>
実施例1〜13及び比較例1〜6に係るマーガリンの組成並びに実施例1〜13及び比較例1〜6に係る食パンについての評価結果を、下記の表1に示す。なお、表1中の「PGPR」は、ポリグリセリン縮合リシノレイン酸エステルを意味し、「クエン酸MG」は、クエン酸モノグリセリン脂肪酸エステルを意味し、「コハク酸MG」は、コハク酸モノグリセリン脂肪酸エステルを意味する。表1中、「油脂配合」のそれぞれの欄の数値は、それぞれの配合された油脂の、油脂全体の質量に対する配合量(質量%)を意味する。表1中、「飽和脂肪酸」の欄の数値は、油脂全体の構成脂肪酸の質量に対する、飽和脂肪酸である構成脂肪酸の含有量(質量%)を意味する。表1中、「2位オレイン」の欄の数値は、油脂全体の質量に対する、2位にオレイン酸が結合されたトリグリセリドの合計含有量(質量%)を意味する。表1中、「SSU+USU/2飽和+2不飽和」は、2飽和−1不飽和型トリグリセリドと1飽和−2不飽和型トリグリセリドとの合計含有量に対する、SSU型トリグリセリドとUSU型トリグリセリドとの合計含有量の質量比を意味する。表1中の「PGPR」、「乳化剤」「増粘多糖類」、及び「酵素」の欄のそれぞれの数値は、それぞれの成分の、油脂組成物全体の質量に対する含有量(質量%)を意味する。
<Evaluation result>
The compositions of margarines according to Examples 1 to 13 and Comparative Examples 1 to 6 and the evaluation results for breads according to Examples 1 to 13 and Comparative Examples 1 to 6 are shown in Table 1 below. In addition, "PGPR" in Table 1 means polyglycerin condensed ricinoleic acid ester, "citric acid MG" means citric acid monoglycerin fatty acid ester, "succinic acid MG" is monoglycerin fatty acid succinate Stands for ester. In Table 1, the numerical value in each column of "oil and fat blending" means the blending amount (% by mass) of each blended fat and oil with respect to the mass of the whole fat and oil. In Table 1, the numerical value in the column of “saturated fatty acid” means the content (% by mass) of the constituent fatty acid which is a saturated fatty acid with respect to the mass of the constituent fatty acid of the whole oil. In Table 1, the numerical value in the column of "2-position olein" means the total content (% by mass) of triglyceride in which oleic acid is bound to 2-position relative to the mass of the whole oil. In Table 1, “SSU + USU / 2 saturated +2 unsaturated” is the total content of SSU type triglyceride and USU type triglyceride with respect to the total content of disaturated −1 unsaturated triglyceride and monosaturated 2 unsaturated triglyceride. Means mass ratio of quantities. The numerical values in the columns of “PGPR”, “emulsifier”, “thickening polysaccharide”, and “enzyme” in Table 1 mean the content (% by mass) of each component with respect to the mass of the whole oil composition. Do.
表1に示すように、実施例1〜13に係るマーガリンが添加された食パンは、10℃保管時における、パンのパサツキ感、パンのネチャツキ感の評価の全体のバランスが高かった。これに対し、比較例1〜6に係るマーガリンが添加された食パンには、10℃保管時における、パンのパサツキ感、パンのネチャツキ感の評価の全体のバランスが高かったものはなかった。実施例1〜13に係るマーガリンは、全て、飽和脂肪酸である構成脂肪酸の含有量が、油脂全体の構成脂肪酸の質量に対して、27〜55質量%であり、ポリグリセリン縮合リシノレイン酸エステルと、グリセリン脂肪酸エステルと、増粘多糖類と、を含むものである。これに対し、比較例1〜6に係るマーガリンは、飽和脂肪酸である構成脂肪酸の含有量が、油脂全体の構成脂肪酸の質量に対して27〜55質量%であり、かつ、ポリグリセリン縮合リシノレイン酸エステルと、グリセリン脂肪酸エステルと、増粘多糖類と、を含むという全ての条件を満たすものでない。この結果より、可塑性油脂組成物は、飽和脂肪酸である構成脂肪酸の含有量が、油脂全体の構成脂肪酸の質量に対して、27〜55質量%であり、ポリグリセリン縮合リシノレイン酸エステルと、グリセリン脂肪酸エステルと、増粘多糖類と、を含むことにより、10℃保管時における、パンのパサツキ感、パンのネチャツキ感の全体のバランスが優れることが示された。 As shown in Table 1, the breads to which margarines according to Examples 1 to 13 were added had a high balance of the evaluation of the feeling of breadiness and the feeling of looseness of bread when stored at 10 ° C. On the other hand, none of the breads to which margarines according to Comparative Examples 1 to 6 were added had a high overall balance of the evaluation of the feeling of breadiness and feeling of breadiness at 10 ° C. when stored. In the margarines according to Examples 1 to 13, the content of the constituent fatty acids, which are all saturated fatty acids, is 27 to 55% by mass with respect to the mass of constituent fatty acids of the whole oil, and polyglycerin condensed ricinoleate ester, It contains glycerin fatty acid ester and polysaccharide thickener. On the other hand, in the margarine according to Comparative Examples 1 to 6, the content of the constituent fatty acid which is a saturated fatty acid is 27 to 55% by mass with respect to the mass of the constituent fatty acid of the whole oil and fat, and polyglycerin condensed ricinoleic acid It does not satisfy all the requirements of including an ester, a glycerin fatty acid ester and a polysaccharide thickener. From this result, in the plastic fat and oil composition, the content of the constituent fatty acid which is a saturated fatty acid is 27 to 55 mass% with respect to the mass of the constituent fatty acid of the whole fat and oil, polyglycerin condensed ricinoleate and glycerin fatty acid By including the ester and the polysaccharide thickener, it was shown that the overall balance of the feeling of breadiness of bread and the feeling of looseness of bread at the time of storage at 10 ° C. are excellent.
グリセリン有機酸脂肪酸エステルを含まない実施例1及び2に係るマーガリンの10℃保管時のパンのネチャツキ感の評価が「△」であり、10℃保管時のパンの歯切れの評価が「×」であり、カット時のパン屑の発生の評価が「△」であるのに対し、グリセリン有機酸脂肪酸エステルであるクエン酸モノグリセリン脂肪酸エステル又はコハク酸モノグリセリン脂肪酸エステルを含む実施例3〜8及び10〜11に係るマーガリンは、10℃保管時のパンのネチャツキ感の評価、10℃保管時のパンの歯切れの評価、10℃保管時のカット時のパン屑の発生の評価が、「○」又は「◎」であった。この結果より、本発明の可塑性油脂組成物は、グリセリン有機酸脂肪酸エステルを更に含むことにより、10℃保管時のパンのネチャツキ感の抑制、パンの歯切れ、カット時のパン屑の発生の抑制がより一層良好となることが示された。なお、実施例9に係るマーガリンが、グリセリン有機酸脂肪酸エステルを含むにもかかわらず、10℃保管時のパンのネチャツキ感の評価が「△」であったのは、油脂全体の構成脂肪酸の質量に対する飽和脂肪酸である構成脂肪酸の含有量が、実施例3〜5に係るマーガリンと比較して少なかったためであると推測される。 "N" is the evaluation of the sense of feeling of the bread at 10 ° C storage of margarine according to Examples 1 and 2 which does not contain the glycerin organic acid fatty acid ester, and the evaluation of breakage of the bread at 10 ° C storage is "x" While evaluation of the generation of bread chips at the time of cutting is “Δ”, Examples 3 to 8 and 10 containing citric acid monoglycerin fatty acid ester or succinic acid monoglycerin fatty acid ester which are glycerin organic acid fatty acid esters The margarine according to 11 to 11 is evaluated as "necessity evaluation of bread at 10 ° C storage", evaluation of bread breakage at 10 ° C storage, evaluation of bread chips at cutting at 10 ° C storage is "○" or It was "◎". From this result, the plastic fat and oil composition of the present invention further contains a glycerin organic acid fatty acid ester, thereby suppressing the occurrence of a sticky feeling of bread at 10 ° C. storage and suppressing the generation of bread chips and bread chips at the time of cutting. It was shown to be even better. In addition, although the margarine based on Example 9 contains glycerol organic-acid fatty acid ester, the evaluation of the feeling of the feeling of the feeling of the bread at 10 degreeC storage was "(triangle | delta)" at the time of storage at 10 degreeC. It is inferred that the content of the constituent fatty acid which is a saturated fatty acid for is lower than that of margarine according to Examples 3 to 5.
糖質分解酵素及びリン脂質分解酵素を含まない実施例1〜11に係るマーガリンの10℃保管時のパンのパサツキ感の評価が「○」又は「◎」であるのに対し、糖質分解酵素又はリン脂質分解酵素を含む実施例12及び13に係るマーガリンは、10℃保管時のパンのパサツキ感の評価が「◎+」であった。この結果より、本発明の可塑性油脂組成物は、糖質分解酵素又はリン脂質分解酵素の少なくともいずれか一方を更に含むことにより、パン類の10℃保管時のパンのパサツキ感の抑制がより一層良好となることが示された。 The evaluation of the feeling of breadiness of bread at 10 ° C. storage of margarine according to Examples 1 to 11 not containing a carbohydrate degrading enzyme and a phospholipid degrading enzyme is “○” or “「 ”, while a carbohydrate degrading enzyme is Or the margarine which concerns on Example 12 and 13 containing a phospholipid decomposing enzyme was evaluated as "パ +" for the feeling of feeling of feeling of bread when stored at 10 ° C. From this result, the plastic fat and oil composition of the present invention further contains at least one of a carbohydrate degrading enzyme and a phospholipid degrading enzyme to further suppress the feeling of breadiness of bread when stored at 10 ° C. It was shown to be good.
Claims (9)
ポリグリセリン縮合リシノレイン酸エステルと、グリセリン脂肪酸エステルと、増粘多糖類と、を含み、
油脂全体における、2飽和−1不飽和型トリグリセリドと1飽和−2不飽和型トリグリセリドとの合計含有量に対するSSU型トリグリセリドとUSU型トリグリセリドとの合計含有量が、質量比で、0.30〜0.60であり、
前記ポリグリセリン縮合リシノレイン酸エステルの含有量が、可塑性油脂組成物全体の質量に対して0.001〜2.0質量%であり、
前記グリセリン脂肪酸エステルの含有量が、可塑性油脂組成物全体の質量に対して0.01〜5.0質量%であり、
前記増粘多糖類の含有量が、可塑性油脂組成物全体の質量に対して0.01〜7.0質量%である、
可塑性油脂組成物。 The content of the constituent fatty acid which is a saturated fatty acid is 27 to 55 mass% with respect to the mass of the constituent fatty acid of the whole oil and fat,
Polyglycerol condensed ricinoleic acid ester, a glycerin fatty acid ester, and polysaccharide thickener, only including,
The total content of SSU-type triglycerides and USU-type triglycerides relative to the total content of disaturated-1 unsaturated triglycerides and monosaturated-2-unsaturated triglycerides in the whole oil is 0.30 to 0 by mass ratio It is .60,
The content of the polyglycerin-condensed ricinoleate is 0.001 to 2.0% by mass with respect to the total mass of the plastic oil / fat composition,
Content of the said glycerol fatty acid ester is 0.01-5.0 mass% with respect to the mass of the whole plastic oil-fat composition,
The content of the polysaccharide thickener is 0.01 to 7.0% by mass with respect to the mass of the entire plastic oil composition.
Plastic oil and fat composition.
ポリグリセリン縮合リシノレイン酸エステルと、グリセリン脂肪酸エステルと、増粘多糖類と、を含み、A polyglycerin condensed ricinoleate, a glycerin fatty acid ester, and a polysaccharide thickener;
2位にオレイン酸が結合されたトリグリセリドの合計含有量が、油脂全体の質量に対して27〜57質量%であり、The total content of triglycerides in which oleic acid is bound to the 2-position is 27 to 57% by mass with respect to the mass of the whole oil,
前記ポリグリセリン縮合リシノレイン酸エステルの含有量が、可塑性油脂組成物全体の質量に対して0.001〜2.0質量%であり、The content of the polyglycerin-condensed ricinoleate is 0.001 to 2.0% by mass with respect to the total mass of the plastic oil / fat composition,
前記グリセリン脂肪酸エステルの含有量が、可塑性油脂組成物全体の質量に対して0.01〜5.0質量%であり、Content of the said glycerol fatty acid ester is 0.01-5.0 mass% with respect to the mass of the whole plastic oil-fat composition,
前記増粘多糖類の含有量が、可塑性油脂組成物全体の質量に対して0.01〜7.0質量%である、The content of the polysaccharide thickener is 0.01 to 7.0% by mass with respect to the mass of the entire plastic oil composition.
可塑性油脂組成物。Plastic oil and fat composition.
The food according to claim 8 , which is a bread containing ingredients stored in a chilled temperature range.
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