JP6490490B2 - Polycarbonate resin composition and thin optical component - Google Patents

Description

  The present invention relates to a polycarbonate resin composition and a thin-walled optical component, and more specifically, a polycarbonate resin composition having high transparency and good hue, and a molded product that is difficult to be charged when releasing from a mold, and a thin-walled product formed by molding the polycarbonate resin composition It relates to optical components. Polycarbonate resin composition

  A surface light source device is incorporated in a liquid crystal display device used for a personal computer, a cellular phone and the like in order to meet demands for thinning, lightening, labor saving, and high definition. The surface light source device has a wedge-shaped cross-section light guide plate or a flat plate shape with a uniform inclined surface for the purpose of uniformly and efficiently guiding incident light to the liquid crystal display side. A light guide plate is provided. In some cases, an uneven pattern is formed on the surface of the light guide plate to provide a light scattering function.

  Such a light guide plate is obtained by injection molding of a thermoplastic resin, and the above concavo-convex pattern is imparted by transferring a concavo-convex portion formed on the surface of the nest. Conventionally, the light guide plate has been molded from a resin material such as polymethylmethacrylate (PMMA). Recently, however, a display device that displays a clearer image has been demanded, and the temperature inside the device is increased by heat generated near the light source. Therefore, it is being replaced with a polycarbonate resin material having higher heat resistance.

  Polycarbonate resin is excellent in mechanical properties, thermal properties, electrical properties, and weather resistance, but its transparency is lower than that of PMMA, etc., so that a surface light source body is formed from a light guide plate made of polycarbonate resin and a light source. When configured, there is a problem that the luminance is low. Recently, it has been demanded to reduce the difference in chromaticity between the light incident portion of the light guide plate and a location away from the light incident portion, but there is a problem that the polycarbonate resin is more easily yellowed than the PMMA resin.

  Patent Document 1 describes a method for improving light transmittance and luminance by adding an acrylic resin and an alicyclic epoxy. Patent Document 2 describes a method for modifying the end of the polycarbonate resin to transfer the uneven portion to the light guide plate. A method for improving the brightness by increasing the brightness, and Patent Document 3 propose a method for improving the brightness by introducing a copolyester carbonate having an aliphatic segment to improve the transferability.

  However, in the method of Patent Document 1, the hue is improved by the addition of the acrylic resin, but since it becomes cloudy, the transparency and the luminance cannot be increased, and the transparency is improved by adding the alicyclic epoxy. Although there is a possibility, the effect of improving the hue is not recognized. In the case of Patent Document 2 and Patent Document 3, although an improvement effect of fluidity and transferability can be expected, there is a drawback that heat resistance is lowered.

On the other hand, it is known to blend polyethylene glycol or poly (2-methyl) ethylene glycol or the like into a thermoplastic resin such as a polycarbonate resin, and Patent Document 4 discloses a γ-ray radiation resistant polycarbonate resin containing the same. Patent Document 5 describes a thermoplastic resin composition excellent in antistatic properties and surface appearance blended with PMMA or the like.
Then, Patent Document 6, _{wherein: X-О- [CH (-R} ) -CH 2 -O] polyethylene glycol or poly (is R hydrogen atom or an alkyl group having 1 to 3 carbon atoms) n-Y represented by The proposal which improves transparency and a hue by mix | blending (2-alkyl) ethylene glycol is made | formed. By adding polyethylene glycol or poly (2-alkyl) ethylene glycol, transparency and yellowing (yellow index: YI) are slightly improved.

  However, in recent years, especially in various portable terminals such as smartphones and tablet terminals, thinning and large-sized thinning are proceeding at a remarkable speed, and the edge type in which light is incident on the light guide plate from the direct edge type to the side edge. As an ultra-thin light source, sufficient brightness has been demanded even when the optical path length is long. In such a high-end light guide plate, at present, the required specifications are not satisfied at the transparency and YI level achieved by the above-described conventional technology.

  In addition, when the molded product is in such an ultra-thin level, the molded product is likely to be charged when released from the mold, and dust and the like are likely to adhere. The adhesion of dust is fatal for optical parts such as a light guide plate, and therefore, it is necessary to remove electricity by means of electricity removal blow or the like in all processes from molding to shipping.

JP-A-11-158364 JP 2001-208917 A JP 2001-215336 A JP-A-1-22959 JP-A-9-227785 Japanese Patent No. 4069364

  The present invention has been made in view of the above circumstances, and the purpose thereof is a polycarbonate resin that is excellent in transparency and hue without any loss of the original properties of the polycarbonate resin, and in which charging immediately after mold release is suppressed. It is to provide a composition.

As a result of intensive studies to achieve the above-mentioned problems, the inventor blends a polyalkylene glycol having a methylene group bonded linearly and a polyalkylene glycol having an alkyl branch in a specific amount with a polycarbonate resin. As a result, it has been found that it has more excellent transparency and hue and can suppress the charging of a molded product immediately after mold release, and has completed the present invention.
The present invention provides the following polycarbonate resin composition, thin optical component and method for producing the thin optical component.

[1] With respect to 100 parts by mass of the polycarbonate resin (A), (B1) a polyalkylene glycol derived from a linear alkylene glycol having 4 or more carbon atoms or a derivative thereof of 40 to 100% by mass and (B2) having 3 or more carbon atoms A polyalkylene glycol (B) containing a polybranched alkylene glycol or a derivative thereof derived from a branched alkylene glycol 60 to 0% by mass (provided that the total of (B1) and (B2) is 100% by mass) A polycarbonate resin composition comprising 10 parts by mass.
[2] The polycarbonate resin composition according to [1], wherein (B1) is polytetramethylene glycol or a derivative thereof.
[3] The polycarbonate resin composition according to the above [1], wherein (B2) is poly (2-methyl) ethylene glycol or a derivative thereof.
[4] The polycarbonate resin composition according to [1], wherein (B2) is poly (2-ethyl) ethylene glycol or a derivative thereof.

[5] The polycarbonate resin composition according to any one of [1] to [4], further including a phosphorus-based stabilizer (C).
[6] The polycarbonate resin composition according to the above [5], wherein the phosphorus stabilizer (C) is a phosphite stabilizer.
[7] The polycarbonate resin composition according to any one of [1] to [6], wherein the polycarbonate resin (A) has a viscosity average molecular weight (Mv) of 10,000 to 15,000.
[8] A thin optical component obtained by molding the polycarbonate resin composition according to any one of [1] to [7].
[9] The thin optical component according to [8], which is a light guide plate having a thickness of 1 mm or less.
[10] A method for producing a thin optical component having a thickness of 1 mm or less, which is obtained by injection molding the polycarbonate resin composition according to any one of [1] to [7] at 305 to 380 ° C.

  The polycarbonate resin composition of the present invention has good transmittance and hue and suppresses charging during mold release. Therefore, the polycarbonate resin composition of the present invention can be particularly suitably used for ultra-thin optical components.

  Hereinafter, the present invention will be described in detail with reference to embodiments and examples.

The polycarbonate resin composition of the present invention comprises (B1) a polyalkylene glycol derived from a linear alkylene glycol having 4 or more carbon atoms or a derivative thereof of 40 to 100% by mass and (B2) with respect to 100 parts by mass of the polycarbonate resin (A). A polyalkylene glycol (B) containing 60 to 0% by mass of a polybranched alkylene glycol derived from a branched alkylene glycol having 3 or more carbon atoms or a derivative thereof (provided that the total of (B1) and (B2) is 100% by mass), It contains more than 2 parts by mass to 10 parts by mass.
Hereinafter, each component, thin-walled optical component and the like constituting the polycarbonate resin composition of the present invention will be described in detail.

[Polycarbonate resin (A)]
There is no restriction | limiting in the kind of polycarbonate resin used in this invention, A polycarbonate resin may use 1 type and may use 2 or more types together by arbitrary combinations and arbitrary ratios.

The polycarbonate resin is a polymer having a basic structure having a carbonic acid bond represented by the formula: — [— O—X—O—C (═O) —] —.
In the formula, X is generally a hydrocarbon, but for imparting various properties, X into which a hetero atom or a hetero bond is introduced may be used.

  The polycarbonate resin can be classified into an aromatic polycarbonate resin in which carbon directly bonded to a carbonic acid bond is aromatic carbon and an aliphatic polycarbonate resin in which aliphatic carbon is aliphatic carbon, either of which can be used. Of these, aromatic polycarbonate resins are preferred from the viewpoints of heat resistance, mechanical properties, electrical characteristics, and the like.

  Although there is no restriction | limiting in the specific kind of polycarbonate resin, For example, the polycarbonate polymer formed by making a dihydroxy compound and a carbonate precursor react is mentioned. At this time, in addition to the dihydroxy compound and the carbonate precursor, a polyhydroxy compound or the like may be reacted. Further, a method of reacting carbon dioxide with a cyclic ether using a carbonate precursor may be used. The polycarbonate polymer may be linear or branched. Further, the polycarbonate polymer may be a homopolymer composed of one type of repeating unit or a copolymer having two or more types of repeating units. At this time, the copolymer can be selected from various copolymerization forms such as a random copolymer and a block copolymer. In general, such a polycarbonate polymer is a thermoplastic resin.

  Among monomers used as raw materials for aromatic polycarbonate resins, examples of aromatic dihydroxy compounds include:

Dihydroxybenzenes such as 1,2-dihydroxybenzene, 1,3-dihydroxybenzene (ie, resorcinol), 1,4-dihydroxybenzene;
Dihydroxybiphenyls such as 2,5-dihydroxybiphenyl, 2,2′-dihydroxybiphenyl, 4,4′-dihydroxybiphenyl;

2,2′-dihydroxy-1,1′-binaphthyl, 1,2-dihydroxynaphthalene, 1,3-dihydroxynaphthalene, 2,3-dihydroxynaphthalene, 1,6-dihydroxynaphthalene, 2,6-dihydroxynaphthalene, , 7-dihydroxynaphthalene, dihydroxynaphthalene such as 2,7-dihydroxynaphthalene;

2,2′-dihydroxydiphenyl ether, 3,3′-dihydroxydiphenyl ether, 4,4′-dihydroxydiphenyl ether, 4,4′-dihydroxy-3,3′-dimethyldiphenyl ether, 1,4-bis (3-hydroxyphenoxy) Dihydroxy diaryl ethers such as benzene and 1,3-bis (4-hydroxyphenoxy) benzene;

2,2-bis (4-hydroxyphenyl) propane (ie, bisphenol A),
1,1-bis (4-hydroxyphenyl) propane,
2,2-bis (3-methyl-4-hydroxyphenyl) propane,
2,2-bis (3-methoxy-4-hydroxyphenyl) propane,
2- (4-hydroxyphenyl) -2- (3-methoxy-4-hydroxyphenyl) propane,
1,1-bis (3-tert-butyl-4-hydroxyphenyl) propane,
2,2-bis (3,5-dimethyl-4-hydroxyphenyl) propane,
2,2-bis (3-cyclohexyl-4-hydroxyphenyl) propane,
2- (4-hydroxyphenyl) -2- (3-cyclohexyl-4-hydroxyphenyl) propane,
α, α′-bis (4-hydroxyphenyl) -1,4-diisopropylbenzene,
1,3-bis [2- (4-hydroxyphenyl) -2-propyl] benzene,
Bis (4-hydroxyphenyl) methane,
Bis (4-hydroxyphenyl) cyclohexylmethane,
Bis (4-hydroxyphenyl) phenylmethane,
Bis (4-hydroxyphenyl) (4-propenylphenyl) methane,
Bis (4-hydroxyphenyl) diphenylmethane,
Bis (4-hydroxyphenyl) naphthylmethane,
1,1-bis (4-hydroxyphenyl) ethane,
1,1-bis (4-hydroxyphenyl) -1-phenylethane,
1,1-bis (4-hydroxyphenyl) -1-naphthylethane,
1,1-bis (4-hydroxyphenyl) butane,
2,2-bis (4-hydroxyphenyl) butane,
2,2-bis (4-hydroxyphenyl) pentane,
1,1-bis (4-hydroxyphenyl) hexane,
2,2-bis (4-hydroxyphenyl) hexane,
1,1-bis (4-hydroxyphenyl) octane,
2,2-bis (4-hydroxyphenyl) octane,
1,1-bis (4-hydroxyphenyl) hexane,
2,2-bis (4-hydroxyphenyl) hexane,
4,4-bis (4-hydroxyphenyl) heptane,
2,2-bis (4-hydroxyphenyl) nonane,
1,1-bis (4-hydroxyphenyl) decane,
1,1-bis (4-hydroxyphenyl) dodecane,
Bis (hydroxyaryl) alkanes such as;

1,1-bis (4-hydroxyphenyl) cyclopentane,
1,1-bis (4-hydroxyphenyl) cyclohexane,
1,1-bis (4-hydroxyphenyl) -3,3-dimethylcyclohexane,
1,1-bis (4-hydroxyphenyl) -3,4-dimethylcyclohexane,
1,1-bis (4-hydroxyphenyl) -3,5-dimethylcyclohexane,
1,1-bis (4-hydroxyphenyl) -3,3,5-trimethylcyclohexane,
1,1-bis (4-hydroxy-3,5-dimethylphenyl) -3,3,5-trimethylcyclohexane,
1,1-bis (4-hydroxyphenyl) -3-propyl-5-methylcyclohexane, 1,1-bis (4-hydroxyphenyl) -3-tert-butyl-cyclohexane,
1,1-bis (4-hydroxyphenyl) -4-tert-butyl-cyclohexane,
1,1-bis (4-hydroxyphenyl) -3-phenylcyclohexane,
1,1-bis (4-hydroxyphenyl) -4-phenylcyclohexane,
Bis (hydroxyaryl) cycloalkanes such as;

9,9-bis (4-hydroxyphenyl) fluorene,
Cardio structure-containing bisphenols such as 9,9-bis (4-hydroxy-3-methylphenyl) fluorene;

4,4′-dihydroxydiphenyl sulfide,
Dihydroxydiaryl sulfides such as 4,4′-dihydroxy-3,3′-dimethyldiphenyl sulfide;

Dihydroxydiaryl sulfoxides such as 4,4'-dihydroxydiphenyl sulfoxide, 4,4'-dihydroxy-3,3'-dimethyldiphenyl sulfoxide;

4,4′-dihydroxydiphenyl sulfone,
Dihydroxydiaryl sulfones such as 4,4′-dihydroxy-3,3′-dimethyldiphenyl sulfone;
Etc.

Among these, bis (hydroxyaryl) alkanes are preferable, and bis (4-hydroxyphenyl) alkanes are particularly preferable, and 2,2-bis (4-hydroxyphenyl) propane (especially from the viewpoint of impact resistance and heat resistance). That is, bisphenol A) is preferred.
In addition, 1 type may be used for an aromatic dihydroxy compound and it may use 2 or more types together by arbitrary combinations and a ratio.

In addition, when an example of a monomer that is a raw material of the aliphatic polycarbonate resin is given,
Ethane-1,2-diol, propane-1,2-diol, propane-1,3-diol, 2,2-dimethylpropane-1,3-diol, 2-methyl-2-propylpropane-1,3- Alkanediols such as diol, butane-1,4-diol, pentane-1,5-diol, hexane-1,6-diol, decane-1,10-diol;

  Cyclopentane-1,2-diol, cyclohexane-1,2-diol, cyclohexane-1,4-diol, 1,4-cyclohexanedimethanol, 4- (2-hydroxyethyl) cyclohexanol, 2,2,4, Cycloalkanediols such as 4-tetramethyl-cyclobutane-1,3-diol;

  Glycols such as ethylene glycol, 2,2'-oxydiethanol (ie, diethylene glycol), triethylene glycol, propylene glycol, spiro glycol and the like;

  1,2-benzenedimethanol, 1,3-benzenedimethanol, 1,4-benzenedimethanol, 1,4-benzenediethanol, 1,3-bis (2-hydroxyethoxy) benzene, 1,4-bis ( 2-hydroxyethoxy) benzene, 2,3-bis (hydroxymethyl) naphthalene, 1,6-bis (hydroxyethoxy) naphthalene, 4,4′-biphenyldimethanol, 4,4′-biphenyldiethanol, 1,4- Aralkyl diols such as bis (2-hydroxyethoxy) biphenyl, bisphenol A bis (2-hydroxyethyl) ether, bisphenol S bis (2-hydroxyethyl) ether;

  1,2-epoxyethane (ie ethylene oxide), 1,2-epoxypropane (ie propylene oxide), 1,2-epoxycyclopentane, 1,2-epoxycyclohexane, 1,4-epoxycyclohexane, 1-methyl And cyclic ethers such as -1,2-epoxycyclohexane, 2,3-epoxynorbornane, and 1,3-epoxypropane;

  Among the monomers used as the raw material for the polycarbonate resin, carbonyl halides, carbonate esters and the like are used as examples of the carbonate precursor. In addition, 1 type may be used for a carbonate precursor and it may use 2 or more types together by arbitrary combinations and a ratio.

  Specific examples of carbonyl halides include phosgene; haloformates such as bischloroformate of dihydroxy compounds and monochloroformate of dihydroxy compounds.

  Specific examples of the carbonate ester include diaryl carbonates such as diphenyl carbonate and ditolyl carbonate; dialkyl carbonates such as dimethyl carbonate and diethyl carbonate; biscarbonate bodies of dihydroxy compounds, monocarbonate bodies of dihydroxy compounds, and cyclic carbonates. And carbonate bodies of dihydroxy compounds such as

-Manufacturing method of polycarbonate resin The manufacturing method of polycarbonate resin is not specifically limited, Arbitrary methods are employable. Examples thereof include an interfacial polymerization method, a melt transesterification method, a pyridine method, a ring-opening polymerization method of a cyclic carbonate compound, and a solid phase transesterification method of a prepolymer.
Hereinafter, a particularly preferable one of these methods will be described in detail.

-Interfacial polymerization method First, the case where a polycarbonate resin is manufactured by the interfacial polymerization method will be described.
In the interfacial polymerization method, a dihydroxy compound and a carbonate precursor (preferably phosgene) are reacted in the presence of an organic solvent inert to the reaction and an aqueous alkaline solution, usually at a pH of 9 or higher. Polycarbonate resin is obtained by interfacial polymerization in the presence. In the reaction system, a molecular weight adjusting agent (terminal terminator) may be present as necessary, or an antioxidant may be present to prevent the oxidation of the dihydroxy compound.

  The dihydroxy compound and the carbonate precursor are as described above. Of the carbonate precursors, phosgene is preferably used, and a method using phosgene is particularly called a phosgene method.

  Examples of the organic solvent inert to the reaction include chlorinated hydrocarbons such as dichloromethane, 1,2-dichloroethane, chloroform, monochlorobenzene and dichlorobenzene; aromatic hydrocarbons such as benzene, toluene and xylene; It is done. In addition, 1 type may be used for an organic solvent and it may use 2 or more types together by arbitrary combinations and a ratio.

  Examples of the alkali compound contained in the alkaline aqueous solution include alkali metal compounds and alkaline earth metal compounds such as sodium hydroxide, potassium hydroxide, lithium hydroxide, and sodium hydrogen carbonate, among which sodium hydroxide and water Potassium oxide is preferred. In addition, 1 type may be used for an alkali compound and it may use 2 or more types together by arbitrary combinations and a ratio.

  Although there is no restriction | limiting in the density | concentration of the alkali compound in alkaline aqueous solution, Usually, in order to control pH in the alkaline aqueous solution of reaction to 10-12, it is used at 5-10 mass%. For example, when phosgene is blown, the molar ratio of the bisphenol compound and the alkali compound is usually 1: 1.9 or more in order to control the pH of the aqueous phase to be 10 to 12, preferably 10 to 11. Among these, it is preferable that the ratio is 1: 2.0 or more, usually 1: 3.2 or less, and more preferably 1: 2.5 or less.

  Examples of the polymerization catalyst include aliphatic tertiary amines such as trimethylamine, triethylamine, tributylamine, tripropylamine, and trihexylamine; alicyclic rings such as N, N′-dimethylcyclohexylamine and N, N′-diethylcyclohexylamine. Formula tertiary amines; aromatic tertiary amines such as N, N′-dimethylaniline and N, N′-diethylaniline; quaternary ammonium salts such as trimethylbenzylammonium chloride, tetramethylammonium chloride, triethylbenzylammonium chloride, etc. Pyridine; guanidine salt; and the like. In addition, 1 type may be used for a polymerization catalyst and it may use 2 or more types together by arbitrary combinations and a ratio.

  Examples of the molecular weight regulator include aromatic phenols having a monohydric phenolic hydroxyl group; aliphatic alcohols such as methanol and butanol; mercaptans; phthalimides and the like. Of these, aromatic phenols are preferred. Specific examples of such aromatic phenols include alkyl groups such as m-methylphenol, p-methylphenol, m-propylphenol, p-propylphenol, p-tert-butylphenol, and p-long chain alkyl-substituted phenol. Examples thereof include substituted phenols; vinyl group-containing phenols such as isopropenyl phenol; epoxy group-containing phenols; carboxyl group-containing phenols such as o-hydroxybenzoic acid and 2-methyl-6-hydroxyphenylacetic acid; In addition, a molecular weight regulator may use 1 type and may use 2 or more types together by arbitrary combinations and a ratio.

  The usage-amount of a molecular weight regulator is 0.5 mol or more normally with respect to 100 mol of dihydroxy compounds, Preferably it is 1 mol or more, and is 50 mol or less normally, Preferably it is 30 mol or less. By making the usage-amount of a molecular weight modifier into this range, the thermal stability and hydrolysis resistance of a resin composition can be improved.

In the reaction, the order of mixing the reaction substrate, reaction medium, catalyst, additive and the like is arbitrary as long as a desired polycarbonate resin is obtained, and an appropriate order may be arbitrarily set. For example, when phosgene is used as the carbonate precursor, the molecular weight regulator can be mixed at any time as long as it is between the reaction (phosgenation) of the dihydroxy compound and phosgene and the start of the polymerization reaction.
In addition, reaction temperature is 0-40 degreeC normally, and reaction time is normally several minutes (for example, 10 minutes)-several hours (for example, 6 hours).

-Melt transesterification method Next, the case where polycarbonate resin is manufactured by the melt transesterification method is demonstrated.
In the melt transesterification method, for example, a transesterification reaction between a carbonic acid diester and a dihydroxy compound is performed.

The dihydroxy compound is as described above.
On the other hand, examples of the carbonic acid diester include dialkyl carbonate compounds such as dimethyl carbonate, diethyl carbonate, and di-tert-butyl carbonate; diphenyl carbonate; substituted diphenyl carbonate such as ditolyl carbonate, and the like. Among these, diphenyl carbonate and substituted diphenyl carbonate are preferable, and diphenyl carbonate is more preferable. In addition, carbonic acid diester may use 1 type and may use 2 or more types together by arbitrary combinations and a ratio.

  The ratio of the dihydroxy compound and the carbonic acid diester is arbitrary as long as the desired polycarbonate resin is obtained, but it is preferable to use an equimolar amount or more of the carbonic acid diester with respect to 1 mol of the dihydroxy compound, and above all, 1.01 mol or more is used. It is more preferable. The upper limit is usually 1.30 mol or less. By setting it as such a range, the amount of terminal hydroxyl groups can be adjusted to a suitable range.

  In the polycarbonate resin, the amount of terminal hydroxyl groups tends to have a great influence on thermal stability, hydrolysis stability, color tone and the like. For this reason, you may adjust the amount of terminal hydroxyl groups as needed by a well-known arbitrary method. In the transesterification reaction, a polycarbonate resin in which the amount of terminal hydroxyl groups is adjusted can be usually obtained by adjusting the mixing ratio of the carbonic diester and the aromatic dihydroxy compound; the degree of vacuum during the transesterification reaction, and the like. In addition, the molecular weight of the polycarbonate resin usually obtained can also be adjusted by this operation.

When adjusting the amount of terminal hydroxyl groups by adjusting the mixing ratio of the carbonic acid diester and the dihydroxy compound, the mixing ratio is as described above.
Further, as a more aggressive adjustment method, there may be mentioned a method in which a terminal terminator is mixed separately during the reaction. Examples of the terminal terminator at this time include monohydric phenols, monovalent carboxylic acids, carbonic acid diesters, and the like. In addition, 1 type may be used for a terminal terminator and it may use 2 or more types together by arbitrary combinations and a ratio.

  When producing a polycarbonate resin by the melt transesterification method, a transesterification catalyst is usually used. Any transesterification catalyst can be used. Among them, it is preferable to use, for example, an alkali metal compound and / or an alkaline earth metal compound. In addition, auxiliary compounds such as basic boron compounds, basic phosphorus compounds, basic ammonium compounds, and amine compounds may be used in combination. In addition, 1 type may be used for a transesterification catalyst and it may use 2 or more types together by arbitrary combinations and a ratio.

  In the melt transesterification method, the reaction temperature is usually 100 to 320 ° C. The pressure during the reaction is usually a reduced pressure condition of 2 mmHg or less. As a specific operation, a melt polycondensation reaction may be performed under the above-mentioned conditions while removing a by-product such as an aromatic hydroxy compound.

  The melt polycondensation reaction can be performed by either a batch method or a continuous method. When performing by a batch type, the order which mixes a reaction substrate, a reaction medium, a catalyst, an additive, etc. is arbitrary as long as a desired aromatic polycarbonate resin is obtained, What is necessary is just to set an appropriate order arbitrarily. However, considering the stability of the polycarbonate resin and the like, the melt polycondensation reaction is preferably carried out continuously.

  In the melt transesterification method, a catalyst deactivator may be used as necessary. As the catalyst deactivator, a compound that neutralizes the transesterification catalyst can be arbitrarily used. Examples thereof include sulfur-containing acidic compounds and derivatives thereof. In addition, 1 type may be used for a catalyst deactivator and it may use 2 or more types together by arbitrary combinations and a ratio.

  The amount of the catalyst deactivator used is usually 0.5 equivalents or more, preferably 1 equivalent or more, and usually 10 equivalents or less, relative to the alkali metal or alkaline earth metal contained in the transesterification catalyst. Preferably it is 5 equivalents or less. Furthermore, it is 1 ppm or more normally with respect to polycarbonate resin, and is 100 ppm or less normally, Preferably it is 20 ppm or less.

The molecular weight of the polycarbonate resin (A) is preferably 10,000 to 15,000 in terms of viscosity average molecular weight (Mv) converted from the solution viscosity measured at a temperature of 25 ° C. using methylene chloride as a solvent. Preferably it is 10,500 or more, More preferably, it is 11,000 or more, Especially, 11,500 or more, Most preferably, it is 12,000 or more, More preferably, it is 14,500 or less. By making the viscosity average molecular weight more than the lower limit of the above range, the mechanical strength of the polycarbonate resin composition of the present invention can be further improved, and by making the viscosity average molecular weight not more than the upper limit of the above range, The fluidity of the polycarbonate resin composition of the invention can be suppressed and improved, and the molding processability can be improved and the thin-wall molding process can be easily performed.
Two or more types of polycarbonate resins having different viscosity average molecular weights may be mixed and used, and in this case, a polycarbonate resin having a viscosity average molecular weight outside the above-mentioned preferred range may be mixed.

The viscosity average molecular weight [Mv] is obtained by using methylene chloride as a solvent and obtaining an intrinsic viscosity [η] (unit: dl / g) at a temperature of 20 ° C. using an Ubbelohde viscometer. , Η = 1.23 × 10 ⁻⁴ Mv ^0.83 . The intrinsic viscosity [η] is a value calculated from the following equation by measuring the specific viscosity [η _sp ] at each solution concentration [C] (g / dl).

  The terminal hydroxyl group concentration of the polycarbonate resin is arbitrary and may be appropriately selected and determined, but is usually 1000 ppm or less, preferably 800 ppm or less, more preferably 600 ppm or less. Thereby, the residence heat stability and color tone of polycarbonate resin can be improved more. In addition, the lower limit is usually 10 ppm or more, preferably 30 ppm or more, more preferably 40 ppm or more, particularly for polycarbonate resins produced by the melt transesterification method. Thereby, the fall of molecular weight can be suppressed and the mechanical characteristic of a resin composition can be improved more.

  In addition, the unit of a terminal hydroxyl group density | concentration represents the mass of the terminal hydroxyl group with respect to the mass of polycarbonate resin in ppm. The measurement method is colorimetric determination (method described in Macromol. Chem. 88 215 (1965)) by the titanium tetrachloride / acetic acid method.

  The polycarbonate resin is a polycarbonate resin alone (the polycarbonate resin alone is not limited to an embodiment containing only one type of polycarbonate resin, and is used in a sense including an embodiment containing a plurality of types of polycarbonate resins having different monomer compositions and molecular weights, for example. .), Or an alloy (mixture) of a polycarbonate resin and another thermoplastic resin may be used in combination. Further, for example, for the purpose of further improving flame retardancy and impact resistance, a polycarbonate resin is copolymerized with an oligomer or polymer having a siloxane structure; for the purpose of further improving thermal oxidation stability and flame retardancy A monomer, oligomer or polymer having a copolymer; a monomer, oligomer or polymer having a dihydroxyanthraquinone structure for the purpose of improving thermal oxidation stability; A copolymer with an oligomer or polymer having an olefin structure; a copolymer with a polyester resin oligomer or polymer for the purpose of improving chemical resistance; Good.

  Further, in order to improve the appearance of the molded product and improve the fluidity, the polycarbonate resin may contain a polycarbonate oligomer. The viscosity average molecular weight [Mv] of this polycarbonate oligomer is usually 1500 or more, preferably 2000 or more, and is usually 9500 or less, preferably 9000 or less. Furthermore, the polycarbonate ligomer contained is preferably 30% by mass or less of the polycarbonate resin (including the polycarbonate oligomer).

Further, the polycarbonate resin may be not only a virgin raw material but also a polycarbonate resin regenerated from a used product (so-called material-recycled polycarbonate resin).
However, the regenerated polycarbonate resin is preferably 80% by mass or less of the polycarbonate resin, and more preferably 50% by mass or less. Recycled polycarbonate resin is likely to have undergone deterioration such as heat deterioration and aging deterioration, so when such polycarbonate resin is used more than the above range, hue and mechanical properties can be reduced. It is because there is sex.

[Polyalkylene glycol (B)]
The polycarbonate resin composition of the present invention is derived from (B1) a polyalkylene glycol derived from a linear alkylene glycol having 4 or more carbon atoms or a derivative thereof and (B2) a branched alkylene glycol having 3 or more carbon atoms. Contains polybranched alkylene glycol or its derivatives.

As the linear alkylene glycol (B1) derived from a linear alkylene glycol having 4 or more carbon atoms, a linear polyalkylene glycol polymer having a linear alkylene ether unit represented by the following general formula (I) is preferable. .
(In the formula, n is an integer of 4 or more.)

  In said general formula (I), n is an integer greater than or equal to 4, Preferably it is 10 or less, More preferably, it is 8 or less, More preferably, it is 6 or less. As the linear alkylene ether unit represented by the general formula (I), when it is described as glycol, tetramethylene glycol in which n is 4, pentamethylene glycol in which n is 5, and hexamethylene glycol in which n is 6 are preferable. More preferred is tetramethylene glycol. Moreover, the copolymer which two or more of these copolymerized may be sufficient. The copolymer may be a random copolymer or a block copolymer.

  Moreover, in poly linear alkylene glycol (B1), it is preferable that the terminal group is a hydroxyl group. In addition, even if one end or both ends are blocked with alkyl ether, aryl ether, aralkyl ether, fatty acid ester, aryl ester, etc., there is no effect on the performance, and etherified products or esterified products are also used. it can.

  As the alkyl group constituting the alkyl ether, either linear or branched can be used, and an alkyl group having 1 to 22 carbon atoms such as a methyl group, an ethyl group, a propyl group, a butyl group, an octyl group, a lauryl group, Preferred examples include stearyl groups such as polyalkylene glycol methyl ether, ethyl ether, butyl ether, lauryl ether, and stearyl ether.

  The aryl group constituting the aryl ether is preferably an aryl group having 6 to 22 carbon atoms, more preferably 6 to 12 carbon atoms, still more preferably 6 to 10 carbon atoms, such as a phenyl group, a tolyl group, or a naphthyl group. And a phenyl group, a tolyl group and the like are preferable. The aralkyl group is preferably an aralkyl group having 7 to 23 carbon atoms, more preferably 7 to 13 carbon atoms, still more preferably 7 to 11 carbon atoms, and examples thereof include a benzyl group and a phenethyl group. Particularly preferred.

The fatty acid constituting the fatty acid ester may be either linear or branched, and may be a saturated fatty acid or an unsaturated fatty acid.
The fatty acid constituting the fatty acid ester is a monovalent or divalent fatty acid having 1 to 22 carbon atoms, such as a monovalent saturated fatty acid, such as formic acid, acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid. , Caprylic acid, capric acid, lauric acid, myristic acid, pentadecylic acid, palmitic acid, heptadecylic acid, stearic acid, nonadecanoic acid, arachidic acid, behenic acid and monounsaturated fatty acids such as oleic acid, elaidic acid, Unsaturated fatty acids such as linoleic acid, linolenic acid, and arachidonic acid, and divalent fatty acids having 10 or more carbon atoms such as sebacic acid, undecanedioic acid, dodecanedioic acid, tetradecanedioic acid, tapsiaic acid and decenedioic acid, undecene Diacid, dodecenedioic acid.

  The aryl group constituting the aryl ester is preferably an aryl group having 6 to 22 carbon atoms, more preferably 6 to 12 carbon atoms, and still more preferably 6 to 10 carbon atoms, such as a phenyl group, a tolyl group, or a naphthyl group. And a phenyl group, a tolyl group and the like are preferable. Since the end-capping group exhibits good compatibility with polycarbonate even if it is an aralkyl group, it can exhibit the same action as an aryl group. The aralkyl group preferably has 7 to 23 carbon atoms, more preferably Aralkyl groups having 7 to 13 carbon atoms, more preferably 7 to 11 carbon atoms are preferable, and examples thereof include benzyl group and phenethyl group, and benzyl group is particularly preferable.

The number average molecular weight of the poly linear alkylene glycol (B1) is preferably 200 to 5,000, more preferably 300 or more, further preferably 500 or more, more preferably 4,000 or less, still more preferably. Is 3,000 or less, particularly preferably 2,500 or less, and most preferably 2,000 or less. Exceeding the upper limit of the above range is not preferable because the compatibility is lowered, and if it is lower than the lower limit of the above range, gas is generated during molding, which is not preferable.
In the present specification, the number average molecular weight of the polyalkylene glycol polymer is a number average molecular weight calculated based on the hydroxyl value measured in accordance with JIS K1577.

  The polybranched alkylene glycol (B2) derived from a branched alkylene glycol having 3 or more carbon atoms is a polymer having a branched alkylene glycol ether unit in which at least one of the methylene hydrogens in the alkylene ether unit (I) is substituted with an alkyl group. It is.

  Preferred examples of the polybranched alkylene glycol (B2) derived from a branched alkylene glycol having 3 or more carbon atoms include those having polybranched alkylene glycol units represented by the following general formulas (II-1) to (II-4). .

(In formulas (II-1) to (II-4), R ^{1 to} R ¹⁰ independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and each of formulas (II-1) to (II- In 4), at least one of R ^{1 to} R ¹⁰ is an alkyl group having 1 to 3 carbon atoms.)

  As the branched alkylene ether unit represented by the general formula (II-1), when this is described as glycol, (2-methyl) ethylene glycol, (2-ethyl) ethylene glycol, (2,2-dimethyl) ethylene glycol, etc. Is mentioned. Moreover, the copolymer which two or more of these copolymerized may be sufficient.

  As a branched alkylene ether unit represented by the above general formula (II-2), when described as glycol, (2-methyl) trimethylene glycol, (3-methyl) trimethylene glycol, (2-ethyl) trimethylene glycol , (3-ethyl) triethylene glycol, (2,2-dimethyl) trimethylene glycol, (2,2-methylethyl) trimethylene glycol, (2,2-diethyl) trimethylene glycol, (3,3-dimethyl ) Trimethylene glycol, (3,3-methylethyl) trimethylene glycol, (3,3-diethyl) trimethylene glycol and the like.

  As a branched alkylene ether unit represented by the above general formula (II-3), when described as glycol, (3-methyl) tetramethylene glycol, (4-methyl) tetramethylene glycol, (3-ethyl) tetramethylene glycol , (4-ethyl) tetramethylene glycol, (3,3-dimethyl) tetramethylene glycol, (3,3-methylethyl) tetramethylene glycol, (3,3-diethyl) tetramethylene glycol, (4,4-dimethyl) ) Tetramethylene glycol, (4,4-methylethyl) tetramethylene glycol, (4,4-diethyl) tetramethylene glycol and the like. A copolymer in which two or more of these are copolymerized may be used.

  As a branched alkylene ether unit represented by the above general formula (II-4), when described as glycol, (3-methyl) pentamethylene glycol, (4-methyl) pentamethylene glycol, (5-methyl) pentamethylene glycol , (3-ethyl) pentamethylene glycol, (4-ethyl) pentamethylene glycol, (5-ethyl) pentamethylene glycol, (3,3-dimethyl) pentamethylene glycol, (3,3-methylethyl) pentamethylene glycol (3,3-diethyl) pentamethylene glycol, (4,4-dimethyl) pentamethylene glycol, (4,4-methylethyl) pentamethylene glycol, (4,4-diethyl) pentamethylene glycol, (5,5 -Dimethyl) pentamethyleneglycol , (5,5-methylethyl) pentamethylene glycol, and the like (5,5-diethyl) pentamethylene glycol. A copolymer in which two or more of these are copolymerized may be used.

As mentioned above, although (II-1)-(II-4) which comprises a branched alkylene ether unit was described by making glycol into an example for convenience, it is not restricted to these glycols, These alkylene oxides, or these polyether formation property It is understood that the derivatives are described as well.
The polybranched alkylene glycol (B2) may be a copolymer composed of a plurality of the aforementioned branched alkylene ether units. The copolymer may be a random copolymer or a block copolymer.

  As the polybranched alkylene glycol (B2), among the above, a polymer composed of 2-methylethylene ether units, a polymer composed of 2-ethylethylene ether units, a polymer composed of 3-methyltetramethylene ether units, 2, A polymer composed of 2-dimethyltrimethylene ether units is particularly preferred.

  The terminal group of the polybranched alkylene glycol (B2) is preferably a hydroxyl group, but as with the polybranched alkylene glycol (B1), one or both ends are alkyl ether, aryl ether, aralkyl ether, Derivatives blocked with fatty acid esters, aryl esters and the like do not affect the performance, and etherified products or esterified products can be used in the same manner. Alkyl ether, aryl ether, aralkyl ether, fatty acid ester, aryl ester and the like are the same as those described for the polybranched alkylene glycol (B1).

  The number average molecular weight of the polybranched alkylene glycol (B2) is preferably 200 to 5,000, more preferably 300 or more, further preferably 500 or more, more preferably 4,000 or less, still more preferably. It is 3,000 or less, particularly preferably 2,500 or less, and most preferably 2,000 or less. Exceeding the upper limit of the above range is not preferable because the compatibility tends to decrease, and if it is lower than the lower limit of the above range, gas is likely to be generated during molding, which is not preferable.

  A method for producing the branched alkylene glycol polymer (B2) is known, and can be produced by polycondensation of the above-described glycol, alkylene oxide or a polyether-forming derivative thereof using an acid catalyst. it can.

The polyalkylene glycol (B) composed of the above (B1) and (B2) is contained in an amount of more than 2 parts by mass to 10 parts by mass with respect to 100 parts by mass of the polycarbonate resin (A). When the content of the polyalkylene glycol (B) is 2 parts by mass or less, the charging potential is increased. The upper limit of the content of the polyalkylene glycol (B) is preferably 8 parts by mass, more preferably 7 parts by mass, especially 6 parts by mass, especially 5 parts by mass, especially 4 parts by mass.
And the ratio of (B1) and (B2) is (B1) 40-100 mass% and (B2) 60-0 mass% on the basis of the total of 100 mass% of (B1) and (B2). When the component (B2), that is, the polybranched alkylene glycol derived from a branched alkylene glycol having 3 or more carbon atoms or a derivative thereof exceeds 60% by mass, the charging potential is increased. The proportion of (B2) is preferably 0% by mass or 3% by mass or more, more preferably 5% by mass or more, preferably less than 50% by mass, more preferably 40% by mass or less, and further 30% by mass or less. In particular, it is preferably 20% by mass or less, particularly preferably 15% by mass or less.

[Phosphorus stabilizer (C)]
The polycarbonate resin composition of the present invention preferably contains a phosphorus stabilizer. By containing a phosphorus stabilizer, the hue of the polycarbonate resin composition of the present invention is improved, and the heat discoloration is further improved.
Any known phosphorous stabilizer can be used. Specific examples include phosphorus oxo acids such as phosphoric acid, phosphonic acid, phosphorous acid, phosphinic acid, and polyphosphoric acid; acidic pyrophosphate metal salts such as acidic sodium pyrophosphate, acidic potassium pyrophosphate, and acidic calcium pyrophosphate; phosphoric acid Phosphates of Group 1 or Group 2B metals such as potassium, sodium phosphate, cesium phosphate, and zinc phosphate; phosphate compounds, phosphite compounds, phosphonite compounds and the like are mentioned, and phosphite compounds are particularly preferred. By selecting a phosphite compound, a polycarbonate resin composition having higher discoloration resistance and continuous productivity can be obtained.

Here, the phosphite compound is a trivalent phosphorus compound represented by the general formula: P (OR) ₃ , and R represents a monovalent or divalent organic group.
Examples of such phosphite compounds include triphenyl phosphite, tris (monononylphenyl) phosphite, tris (monononyl / dinonyl phenyl) phosphite, tris (2,4-di-tert-butylphenyl) phosphine. Phyto, monooctyl diphenyl phosphite, dioctyl monophenyl phosphite, monodecyl diphenyl phosphite, didecyl monophenyl phosphite, tridecyl phosphite, trilauryl phosphite, tristearyl phosphite, distearyl pentaerythritol diphosphite, Bis (2,4-di-tert-butyl-4-methylphenyl) pentaerythritol phosphite, bis (2,6-di-tert-butylphenyl) octyl phosphite, 2,2-methylene (4,6-di-tert-butylphenyl) octyl phosphite, tetrakis (2,4-di-tert-butylphenyl) -4,4′-biphenylene-diphosphite, 6- [3- (3-tert- Butyl-hydroxy-5-methylphenyl) propoxy] -2,4,8,10-tetra-tert-butyldibenzo [d, f] [1,3,2] -dioxaphosphine.

  Among these phosphite compounds, the aromatic phosphite compound represented by the following formula (1) or (2) is more preferable because the heat discoloration of the polycarbonate resin composition of the present invention is effectively enhanced. .

[In Formula (1), R ¹ , R ² and R ³ may be the same or different and each represents an aryl group having 6 to 30 carbon atoms. ]

[In Formula (2), R ⁴ and R ⁵ may be the same or different and each represents an aryl group having 6 to 30 carbon atoms. ]

  As the phosphite compound represented by the above formula (1), triphenyl phosphite, tris (monononylphenyl) phosphite, tris (2,4-di-tert-butylphenyl) phosphite, etc. are preferable, Of these, tris (2,4-di-tert-butylphenyl) phosphite is more preferable. Specific examples of such organic phosphite compounds include, for example, “ADEKA STAB 1178” manufactured by ADEKA, “SUMILIZER TNP” manufactured by Sumitomo Chemical Co., Ltd., “JP-351” manufactured by Johoku Chemical Industry Co., Ltd., “ADEKA STAB manufactured by ADEKA 2112 "," Irgaphos 168 "manufactured by BASF," JP-650 "manufactured by Johoku Chemical Industry Co., Ltd., and the like.

  Examples of the phosphite compound represented by the above formula (2) include bis (2,4-di-tert-butyl-4-methylphenyl) pentaerythritol diphosphite and bis (2,6-di-tert- Those having a pentaerythritol diphosphite structure such as butyl-4-methylphenyl) pentaerythritol diphosphite and bis (2,4-dicumylphenyl) pentaerythritol diphosphite are particularly preferred. Specific examples of such an organic phosphite compound include “Adeka Stub PEP-24G”, “Adeka Stub PEP-36” manufactured by Adeka, “Doverphos S-9228” manufactured by Doverchemical, and the like.

Among the phosphite compounds, the aromatic phosphite compound represented by the above formula (2) is more preferable because the hue is more excellent.
In addition, 1 type may contain phosphorus stabilizer and 2 or more types may contain it by arbitrary combinations and a ratio.

  The preferable content of the phosphorus-based stabilizer (C) is 0.005 to 0.5 parts by mass, more preferably 0.007 parts by mass or more, and further preferably 100 parts by mass of the polycarbonate resin (A). 0.008 parts by mass or more, particularly preferably 0.01 parts by mass or more, more preferably 0.4 parts by mass or less, further preferably 0.3 parts by mass or less, especially 0.2 parts by mass or less, especially 0.1 mass part or less is preferable. When the content of the phosphorus stabilizer (C) is less than 0.005 parts by mass within the above range, the hue and heat discoloration tend to be insufficient, and the content of the phosphorus stabilizer (C) is 0.5 mass. When it exceeds the part, the heat discoloration tends to deteriorate, and the wet heat stability tends to decrease.

[Epoxy compound (D)]
It is also preferable that the resin composition of the present invention contains an epoxy compound (D). By including the epoxy compound (D) together with the polyalkylene glycol polymer (B), the heat discoloration can be further improved.

As the epoxy compound (D), a compound having one or more epoxy groups in one molecule is used. Specifically, phenyl glycidyl ether, allyl glycidyl ether, t-butylphenyl glycidyl ether, 3,4-epoxycyclohexylmethyl-3 ′, 4′-epoxycyclohexylcarboxylate, 3,4-epoxy-6-methylcyclohexylmethyl -3 ', 4'-epoxy-6'-methylcyclohexyl carboxylate, 2,3-epoxycyclohexylmethyl-3', 4'-epoxycyclohexyl carboxylate, 4- (3,4-epoxy-5-methylcyclohexyl) Butyl-3 ′, 4′-epoxycyclohexylcarboxylate, 3,4-epoxycyclohexylethylene oxide, cyclohexylmethyl 3,4-epoxycyclohexylcarboxylate, 3,4-epoxy-6-methylcyclohexylmethyl-6 ′ -Methylsiloxyl carboxylate, bisphenol-A diglycidyl ether, tetrabromobisphenol-A glycidyl ether, diglycidyl ester of phthalic acid, diglycidyl ester of hexahydrophthalic acid, bis-epoxy dicyclopentadienyl ether, bis- Epoxyethylene glycol, bis-epoxycyclohexyl adipate, butadiene diepoxide, tetraphenylethylene epoxide, octyl epoxytalate, epoxidized polybutadiene, 3,4-dimethyl-1,2-epoxycyclohexane, 3,5-dimethyl-1,2, -Epoxycyclohexane, 3-methyl-5-t-butyl-1,2-epoxycyclohexane, octadecyl-2,2-dimethyl-3,4-epoxycyclohexylcarboxy N-butyl-2,2-dimethyl-3,4-epoxycyclohexyl carboxylate, cyclohexyl-2-methyl-3,4-epoxycyclohexyl carboxylate, N-butyl-2-isopropyl-3,4-epoxy -5-methylcyclohexyl carboxylate, octadecyl-3,4-epoxycyclohexylcarboxylate, 2-ethylhexyl-3 ', 4'-epoxycyclohexylcarboxylate, 4,6-dimethyl-2,3-epoxycyclohexyl-3', 4′-epoxycyclohexylcarboxylate, 4,5-epoxytetrahydrophthalic anhydride, 3-tert-butyl-4,5-epoxytetrahydrophthalic anhydride, diethyl 4,5-epoxy-cis-1,2-cyclohexyldicarboxylate Rate, j-n-b Le -3-t-butyl-4,5-epoxy - cis-1,2-cyclohexyl dicarboxylate, epoxidized soybean oil, can be preferably exemplified such as epoxidized linseed oil.
Epoxy compounds may be used alone or in combination of two or more.

  Of these, alicyclic epoxy compounds are preferably used, and 3,4-epoxycyclohexylmethyl-3 ', 4'-epoxycyclohexylcarboxylate is particularly preferable.

  The content of the epoxy compound (D) is preferably 0.0005 to 0.2 parts by mass, more preferably 0.001 parts by mass or more, and still more preferably 0 with respect to 100 parts by mass of the polycarbonate resin (A). 0.003 parts by mass or more, particularly preferably 0.005 parts by mass or more, more preferably 0.15 parts by mass or less, still more preferably 0.1 parts by mass or less, particularly preferably 0.05 parts by mass or less. . When the content of the epoxy compound (D) is less than 0.0005 parts by mass, the hue and the heat discoloration tend to be insufficient, and when it exceeds 0.2 parts by mass, the heat discoloration tends to deteriorate rather than the hue and Wet heat stability tends to decrease.

[Additives, etc.]
The polycarbonate resin composition of the present invention includes other additives other than those described above, for example, antioxidants, mold release agents, ultraviolet absorbers, fluorescent brighteners, pigments, dyes, other polymers other than polycarbonate resins, Additives such as a flame retardant, an impact resistance improver, an antistatic agent, a plasticizer, and a compatibilizing agent can be contained. These additives may be used alone or in combination of two or more.

[Production Method of Polycarbonate Resin Composition]
There is no restriction | limiting in the manufacturing method of the polycarbonate resin composition of this invention, The manufacturing method of a well-known polycarbonate resin composition can be employ | adopted widely, Polycarbonate resin (A), poly linear alkylene glycol or its derivative (B1), and poly branched alkylene Glycol or its derivative (B2) and other components blended as necessary are mixed in advance using various mixers such as a tumbler or Henschel mixer, and then Banbury mixer, roll, Brabender, uniaxial kneading Examples thereof include a melt kneading method using a mixer such as an extruder, a twin-screw kneading extruder, and a kneader. The temperature for melt kneading is not particularly limited, but is usually in the range of 240 to 320 ° C.

The polycarbonate resin composition of the present invention exhibits high spectral transmittance, and the spectral transmittance at a wavelength of 420 nm measured with an optical path length of 300 mm is preferably as high as 50% or more. The spectral transmittance at a wavelength of 420 nm is a transmittance in a wavelength region close to the wavelength region of a blue LED often used in optical components such as a light guide plate, and if the transmittance in this wavelength region is low, yellowishness Will increase.
The spectral transmittance at a wavelength of 420 nm is measured with an optical path length of 300 mm using an injection molded long optical path molded product (300 mm × 7 mm × 4 mm).

[Thin optical components]
The polycarbonate resin composition of the present invention can produce a thin optical component by molding pellets obtained by pelletizing the above polycarbonate resin composition by various molding methods. Further, the resin melt-kneaded by an extruder can be directly molded into a thin optical component without going through the pellets.

The polycarbonate resin composition of the present invention has excellent fluidity, and even when it is a thin molded product, it has excellent appearance of a molded product without white spot foreign matter, and can achieve both transmittance and hue. It is suitably used for molding optical components. The resin temperature at the time of injection molding is preferably molded at a resin temperature higher than 260 to 300 ° C., which is a temperature generally applied to injection molding of polycarbonate resin, and a resin temperature of 305 to 380 ° C. is preferable. The resin temperature is more preferably 310 ° C or higher, further preferably 315 ° C or higher, particularly preferably 320 ° C or higher, and more preferably 370 ° C or lower. In the case of using a conventional polycarbonate resin composition, there is a problem that white spot foreign matter tends to be generated on the surface of the molded product when the resin temperature at the time of molding is increased in order to form a thin molded product. By using the resin composition of the invention, it is possible to produce a thin molded article having a good appearance even in the above temperature range.
The resin temperature is grasped as the barrel set temperature when it is difficult to directly measure the resin temperature.

  In the present invention, the thin-walled molded article refers to a molded article having a plate-like portion having a thickness of usually 1 mm or less, preferably 0.8 mm or less, more preferably 0.6 mm or less. Here, the plate-like portion may be a flat plate or a curved plate, may be a flat surface, may have irregularities on the surface, and the cross section has an inclined surface. Or a wedge-shaped cross section.

Thin-walled optical components include components of equipment and instruments that directly or indirectly use light sources such as LEDs, organic EL, incandescent bulbs, fluorescent lamps, and cathode tubes, and light guide plates and surface light emitter members are typical. It is illustrated as a thing.
The light guide plate is used to guide light from a light source such as an LED in a liquid crystal backlight unit, various display devices, and lighting devices. It diffuses by the unevenness and emits uniform light. The shape is usually flat, and the surface may or may not have irregularities.
The light guide plate is usually formed preferably by an injection molding method, an ultra-high speed injection molding method, an injection compression molding method, or the like.
The light guide plate molded using the resin composition of the present invention does not have white turbidity or a decrease in transmittance, and has a very good transmittance and hue.

  The light guide plate made of the polycarbonate resin composition of the present invention can be suitably used in the fields of liquid crystal backlight units, various display devices, and lighting devices. Examples of such devices include mobile phones, mobile notebooks, netbooks, slate PCs, tablet PCs, smartphones, tablet terminals, and other portable terminals, cameras, watches, notebook computers, various displays, lighting devices, and the like. It is done.

  Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not construed as being limited to the following examples.

  The raw materials and evaluation methods used in the following examples and comparative examples are as follows. In addition, the measuring method of the viscosity average molecular weight of polycarbonate resin (A) is as having mentioned above.

(Examples 1-7, Comparative Examples 1-5)
[Production of resin composition pellets]
Each component described above was blended in the proportions (parts by mass) shown in Table 2 below, mixed for 20 minutes with a tumbler, and then a twin screw extruder with a screw diameter of 26 mm ("TEM26SX" manufactured by Toshiba Machine Co., Ltd.) Was melt-kneaded at a cylinder temperature of 240 ° C., and pellets were obtained by strand cutting.

[Measurement of Hue (YI)]
The obtained pellets were dried at 120 ° C. for 5 to 7 hours with a hot air circulating dryer, and then with an injection molding machine (“EC100SX-2A” manufactured by Toshiba Machine Co., Ltd.) at a resin temperature of 340 ° C. and a mold temperature of 80 ° C. A long optical path molded product (300 mm × 7 mm × 4 mm) was molded.
About this long optical path molded product, YI (yellowing degree) was measured at an optical path length of 300 mm. For the measurement, a long optical path spectral transmission color meter (“ASA 1” manufactured by Nippon Denshoku Industries Co., Ltd., C light source, 2 ° visual field) was used.

[Evaluation of charging potential]
The obtained pellets were dried at 120 ° C. for 4 hours or more, and then injected with an injection molding machine (“SE100DUHP”, screw diameter φ25 mm, manufactured by Sumitomo Heavy Industries, Ltd.), cylinder temperature 340 ° C., mold temperature 40 ° C., injection Injection molding was performed under the conditions of a speed of 800 mm / s, a holding pressure of 40 MPa, and a molding cycle of 20 seconds to obtain a test piece having a shape of 61 mm wide × 112 mm long × 0.4 mm thick.
The obtained test piece was placed on a stand made of polypropylene resin (cylinder having a diameter of 5.5 cm and a height of 1.5 cm) so that the center of the test piece is located at the center of the stand. An electrostatic potential measuring device (“KSD-0102” manufactured by Kasuga Denki Co., Ltd.) was installed at a position 100 mm directly above the test piece so that the sensor portion of the electrostatic potential measuring device was positioned, and the temperature was 23 ° C. The charging potential (unit: kV) was measured at a humidity of 50%. It can be said that the lower the absolute value of the potential, the better the molded article is less likely to adhere dust and the like.
At the time of measurement, there was no conductor (including a human body) affecting the measurement value around 500 mm around the measuring instrument, and the conductor was not touched to the molded product. The insulator part was not charged by spraying a static elimination blower each time, and the molded product was used immediately after molding.
The above evaluation results are shown in Table 2 below.

  The polycarbonate resin composition of the present invention has very good transparency and hue, and suppresses electrification at the time of mold release. Therefore, the polycarbonate resin composition can be used particularly suitably for thin-walled optical components, etc. Very expensive.

Claims (10)

(B1) Polyalkylene glycol derived from a linear alkylene glycol having 4 or more carbon atoms or a derivative thereof of 40 to 100% by mass and (B2) a branched alkylene glycol having 3 or more carbon atoms with respect to 100 parts by mass of the polycarbonate resin (A). Polyalkylene glycol (B) containing 60 to 0% by mass of polybranched alkylene glycol or derivative thereof (provided that the total of (B1) and (B2) is 100% by mass) (however, the following general formula (1) A polycarbonate resin composition characterized by containing more than 2 parts by mass to 10 parts by mass of a tetramethylene glycol derivative represented by the formula:
_{HO (C 4 H 8 O)} m (C 3 H 6 O) n H (1)
(In the formula, m and n each independently represent an integer of 4 to 60, and m + n represents an integer of 20 to 90.)   The polycarbonate resin composition according to claim 1, wherein (B1) is polytetramethylene glycol or a derivative thereof.   The polycarbonate resin composition according to claim 1, wherein the (B2) is poly (2-methyl) ethylene glycol or a derivative thereof.   The polycarbonate resin composition according to claim 1, wherein the (B2) is poly (2-ethyl) ethylene glycol or a derivative thereof.   Furthermore, the polycarbonate resin composition of any one of Claims 1-4 containing a phosphorus stabilizer (C).   The polycarbonate resin composition according to claim 5, wherein the phosphorus stabilizer (C) is a phosphite stabilizer.   The polycarbonate resin composition according to any one of claims 1 to 6, wherein the polycarbonate resin (A) has a viscosity average molecular weight (Mv) of 10,000 to 15,000.   The thin optical component which shape | molded the polycarbonate resin composition of any one of Claims 1-7.   The thin optical component according to claim 8, which is a light guide plate having a thickness of 1 mm or less.   A method for producing a thin optical part having a thickness of 1 mm or less, wherein the polycarbonate resin composition according to any one of claims 1 to 7 is injection-molded at 305 to 380 ° C.