JP6317057B2 - Plain bearing - Google Patents

Description

  The present invention relates to a sliding bearing, and more particularly to a sliding bearing in which a resin layer mainly composed of a polyethylene resin is formed by injection molding on a sliding surface of a metal substrate.

  As a sliding bearing used for office equipment, medical instruments, food machines, and other general machines, a bearing in which a resin layer is formed on a sliding surface of a base material such as sintered metal has been proposed. For example, sintered metal is used as the outer peripheral portion of the bearing, and a resin layer is formed by insert molding a resin material on the sliding portion of the outer peripheral portion of the bearing, and at least the surface of the outer peripheral portion of the bearing is in contact with the resin layer. A fine concave portion is provided on the surface portion of the outer peripheral portion of the bearing, and (the linear expansion coefficient of the resin material) × (the thickness of the resin layer) in the resin layer is 0.15 or less, and the total apparent area occupied by the concave portion is A high-accuracy plain bearing having a surface area of 25 to 95% of the surface portion of the outer peripheral portion of the bearing in contact with the resin layer is known (see Patent Document 1). This high-accuracy plain bearing is excellent in lubricity while having high accuracy because the dimensional change due to the temperature change of the resin layer can be suppressed. In addition, since the resin layer is formed on the sliding portion, attacking the soft mating member and occurrence of abnormal noise are suppressed. Furthermore, since the resin layer enters the fine recess, the anchor effect improves the adhesion between the bearing outer periphery and the resin layer.

  In order to prevent deterioration of bearing performance due to gate marks during injection molding, a sliding bearing having a similar configuration has a plurality of grooves on the sliding surface, and a tunnel in which the gate position is set at the bottom position of the groove. A bearing in which a resin layer is formed by a gate is known (see Patent Document 2).

  These sliding bearings are mainly developed as an alternative to rolling bearings, and in order to achieve a low coefficient of friction, polyethylene (hereinafter referred to as “ Often a resin is used. The PE resin can obtain a low friction coefficient as compared with a case where a polyacetal resin, a polyphenylene sulfide resin, a polytetrafluoroethylene (hereinafter referred to as “PTFE”) resin, or the like is employed as a base resin.

JP 2003-239976 A Japanese Patent No. 4515824

  In recent years, the above-mentioned office equipment has been required to have higher functions, energy savings, and downsizing, so that the specification conditions (surface pressure (load) and sliding speed) of the sliding bearing have become more severe. Further, when a sliding bearing is used as an alternative to a rolling bearing, the substitutable range greatly depends on a PV value (multiplied by a surface pressure (P) and a sliding speed (V)) that can be supported by the sliding bearing, and is 5 MPa. M / min. About 20%, 15 MPa · m / min. This will allow about 85% substitution.

  From such a background, it is required that a sliding bearing as an alternative to the rolling bearing in these devices can cope with a high PV value while maintaining a low friction coefficient. As a general method for improving the friction and wear characteristics of a plastic sliding bearing, there is a method of blending a solid lubricant such as PTFE resin powder, graphite powder, molybdenum disulfide or the like. Therefore, it is difficult to make the dynamic friction coefficient μ less than about 0.1.

  In addition, in the sliding bearing having the structure of Patent Documents 1 and 2, when a high molecular weight PE resin that can be injection-molded is used as the base resin of the resin layer, although a low friction coefficient can be maintained, a high PV value (for example, 5 MPa · m) is achieved. / Min.), Sufficient wear resistance may not be obtained. On the other hand, when a non-injectable ultrahigh molecular weight polyethylene (hereinafter referred to as “UHMWPE”) resin having an average molecular weight exceeding 1,000,000 is used as a base resin, insert injection molding cannot be performed, resulting in poor productivity.

  The present invention has been made in order to cope with such problems, and an object thereof is to provide a plain bearing that can cope with a high PV value while maintaining a low coefficient of friction, and that is excellent in productivity. .

  The sliding bearing of the present invention is a sliding bearing having a metal base material and a resin layer integrally formed by injection molding using a resin material on a surface serving as a sliding surface of the base material. The material is a material mainly composed of an injection-moldable PE resin (A) and containing a non-injection-moldable UHMWPE resin (B). 5-30 mass% is contained with respect to the total mass of A) and the said UHMWPE resin (B). Particularly, the sliding bearing has a PV value obtained by multiplying the surface pressure (P) and the sliding speed (V) by 5 MPa · m / min. It is a bearing that is used under conditions that exceed the above.

  The UHMWPE resin (B) has a weight average molecular weight of 1,000,000 to 4,000,000. The PE resin (A) that can be injection-molded is characterized in that, based on JIS K 7210, the MFR when measured at a load of 10 kg and 190 ° C. is 1 to 30 g / 10 minutes.

  In the resin material, the UHMWPE resin (B) is blended in a powder form having an average particle size of 10 to 200 μm. The average particle diameter is a value measured by a laser diffraction method.

  The resin material contains porous silica and silicone oil, and is characterized in that the porous silica is preliminarily impregnated with the silicone oil. Moreover, in the said resin material, the said porous silica and the said silicone oil are contained by 25-50 mass% with respect to the whole resin material by these total mass.

  The resin layer has a thickness of 0.1 to 0.5 mm. The metal substrate is a sintered metal substrate.

  The sliding bearing is used in a temperature atmosphere of 80 ° C. or lower.

  The sliding bearing of the present invention has a metal base material and a resin layer integrally formed by injection molding using a resin material on the surface which becomes a sliding surface of the base material. The main component is a moldable PE resin (A) and a non-injectable UHMWPE resin (B). In the resin material, the UHMWPE resin (B) is composed of PE resin (A) and UHMWPE resin ( Since it is contained in an amount of 5 to 30% by mass with respect to the total mass with B), the resin layer can be subjected to insert injection molding, excellent in productivity, low friction at a high PV value, and excellent in wear resistance. Furthermore, since the resin material contains porous silica and silicone oil and is blended in a state where the porous silica is impregnated with silicone oil in advance, low friction can be maintained over a long period of time. As a result, the plain bearing of the present invention can be suitably used as a substitute for the rolling bearing in many applications.

It is the perspective view and sectional drawing which show an example of the slide bearing of this invention. It is sectional drawing which shows the aspect of the structure of the resin layer formed in a bearing outer peripheral part. It is a figure which shows the relationship between PV value and a wear coefficient.

  The sliding bearing of the present invention has a metal base material and a resin layer integrally molded (insert molding) by injection molding using a resin material on the surface serving as a sliding surface of the base material. The resin material for forming this resin layer is a material mainly composed of injection-moldable PE resin (A) and containing a predetermined amount of non-injection-moldable UHMWPE resin (B).

The PE resin (A) as the main component of the resin material may be any PE resin that can be injection molded. As injection molding conditions, for example, any injection molding conditions may be used as long as the molding temperature is 200 ° C. to 270 ° C. and the injection pressure is 100 to 160 MPa. In addition, high-density, high-molecular-weight PE resin with excellent properties such as wear resistance, self-lubrication, impact resistance, chemical resistance, lightness that is lighter than the specific gravity of water, and dimensional stability due to low water absorption. preferable. For example, a high density PE resin having a density (ASTM D 1505) of 942 kg / m ³ or more is preferable, and the upper limit of the density of the high density PE resin is less than 1000 kg / m ³ , strictly speaking, 980 kg / m ³ or less.

  The MFR (melt flow rate: JIS K 7210 (190 ° C., 10 kgf)) of the PE resin (A) is preferably 1 to 30 g / 10 minutes, more preferably 1 to 15 g / 10 minutes, and 2 to 6 g / 10 minutes. Is particularly preferred. As a weight average molecular weight, it is less than 1 million, Preferably it is about 250,000-950,000. Moreover, as a structure, a linear thing and the branched thing containing the branch of a methyl group may be sufficient. In addition, PE resin of (A) component may be used individually by 1 type, and 2 or more types may be mixed and used for it.

Commercially available products of PE resin (A) that can be used in the present invention include trade names Lübmer L3000 (density: 969 kg / m ³ , MFR: 15 g / 10 min) and L4000 (density: 967 kg / m ³ ) manufactured by Mitsui Chemicals. , MFR: 6 g / 10 min), L5000 (density: 966 kg / m ³ , MFR: 2 g / 10 min), and the like.

  The UHMWPE resin (B) blended in the resin material is a non-injectable UHMWPE resin. UHMWPE resin is a resin in which the molecular weight of PE resin, usually 20,000 to 300,000, is increased to about 500,000 to 11 million, and has low friction characteristics. Moreover, since UHMWPE resin has a high molecular weight, it has good wear resistance. However, among UHMWPE resins, especially those having a molecular weight of 1 million or more have extremely high viscosity at the time of melting and hardly flow. Therefore, they cannot be molded by a normal injection molding method as a base resin, and are usually heated. After forming the material by compression molding or ram extrusion, it is processed into a desired shape by machining. Such a non-injection-moldable UHMWPE resin (B) has lower frictional properties and excellent wear resistance than injection-moldable PE resin (A). The non-injectable UHMWPE resin (B) preferably has a higher molecular weight than the PE resin (A).

  The weight average molecular weight of the non-injectable UHMWPE resin (B) is preferably 1 million to 4 million. With UHMWPE resin powder of less than 1 million, the effect of improving wear resistance is poor. When it exceeds 4 million, thin-wall moldability is inhibited.

  In the resin material, the non-injection-moldable UHMWPE resin (B) is contained in an amount of 5 to 30% by mass with respect to the total mass (A + B) of the PE resin (A) and the non-injection-moldable UHMWPE resin (B). If it is less than 5% by mass, the effect of improving wear resistance is poor, and 5 MPa · m / min. When using at a PV value exceeding 100%, the wear resistance may be inferior. On the other hand, when it exceeds 30 mass%, there exists a possibility of inhibiting injection moldability. Preferably it is 8-30 mass%, More preferably, it is 14-30 mass%.

In the present invention, among UHMWPE resins, non-injection-moldable UHMWPE resin is used as a filler for improving wear resistance, not the main component of the resin layer. The non-injectable UHMWPE resin (B) and the PE resin (A) are both the same type of resin having a main chain containing —CH ₂ —CH ₂ — units, and are excellent in compatibility. By melt-kneading at the time of injection molding, the non-injectable UHMWPE resin (B) is dispersed in the PE resin (A) in a completely or partially compatible state.

  At the time of melt-kneading at the time of injection molding of the resin material, the non-injection-moldable UHMWPE resin (B) is blended in a powder form having an average particle diameter of 10 to 200 μm. Preferably, it is in the form of a powder having an average particle size of 10 to 50 μm. By blending in a fine powder form, the thin moldability of the resin layer is not hindered, the compatibility is excellent, and the wear resistance is easily improved. Moreover, the powder of 2 or more types of UHMWPE resin (B) from which an average particle diameter differs can also be mix | blended. Furthermore, since the powder shape of the non-injectable UHMWPE resin (B) is excellent in kneadability, a spherical shape is preferable. The average particle diameter is a value measured by a laser diffraction method.

As a commercial product of the non-injectable UHMWPE resin powder (B) that can be used in the present invention, trade name Mipelon (spherical, weight average molecular weight: 2 million, density: 940 kg / m ³ , average particle diameter, manufactured by Mitsui Chemicals, Inc.) 25-30 μm), trade name Hi-Zex Million (weight average molecular weight: 1.15 million to 4 million, density: 935 to 940 kg / m ³ , average particle size: 120 to 160 μm) manufactured by Mitsui Chemicals.

  The resin material for forming the resin layer of the sliding bearing includes porous silica (C) which is a filler having communication holes in addition to PE resin (A) that can be injection-molded and UHMWPE resin (B) that is non-injectable. And a lubricant (D) are preferably blended. Furthermore, a solid lubricant (E) can also be blended.

  As the porous silica (C), a powder mainly composed of amorphous silicon dioxide can be used. For example, precipitated silica, which is an aggregate of fine particles having a primary particle diameter of 15 nm or more, and an alkali silicate aqueous solution containing an alkali metal salt or an alkaline earth metal salt are emulsified in an organic solvent and gelled with carbon dioxide. Examples thereof include true spherical porous silica. In the present invention, porous silica in which primary fine particles having a particle diameter of 3 to 8 nm are aggregated to form true spherical silica particles has communication holes, and thus is particularly preferable. The average particle diameter of the true spherical silica particles is preferably 0.5 to 100 μm, and is particularly preferably 1 to 20 μm in consideration of ease of handling and slidability. As such a spherical porous silica, trade name Sunsphere manufactured by AGC S-Tech is available.

True spherical silica particles in which primary fine particles having a particle diameter of 3 to 8 nm are aggregated have a specific surface area of 200 to 900 m ² / g, preferably 300 to 800 m ² / g, a pore volume of 1 to 3.5 ml / g, fine particles. It is preferable that the pore diameter is 5 to 30 nm, preferably 20 to 30 nm, and the oil absorption is 150 to 400 ml / 100 g, preferably 300 to 400 ml / 100 g. Moreover, even if it dries again after being immersed in water, it is preferable that the said pore volume and oil absorption amount maintain 90% or more before immersion. The specific surface area and the pore volume are values measured by a nitrogen adsorption method, and the oil absorption is a value measured according to JIS K5101.

  Moreover, it is preferable that the inside and the outer surface of the spherical silica particles are covered with silanol (Si—OH) because lubricating oil or the like can be easily held inside. Furthermore, the porous silica can be subjected to organic or inorganic surface treatment suitable for the base material. The shape of the above-mentioned porous silica is not particularly limited, and non-spherical porous silica can be used as long as the average particle diameter, specific surface area, oil absorption and the like are within the range of the true spherical silica particles. In addition, spherical and true spherical particles are more preferable from the standpoint of attacking the counterpart material and kneading properties. Here, the spherical shape refers to a sphere having a ratio of the short diameter to the long diameter of 0.8 to 1.0, and the true sphere refers to a sphere closer to the true sphere than the above sphere.

  As the lubricant (D), any substance having a lubricating effect such as a lubricating oil that is liquid at room temperature, an ionic liquid, or a grease containing a thickener in the lubricating oil can be used.

  The lubricating oil can be used as long as it is widely used for bearings, for example, mineral oil such as spindle oil, refrigerator oil, turbine oil, machine oil, dynamo oil, polybutene, poly-α-olefin, alkylnaphthalene, Hydrocarbon synthetic oils such as alicyclic compounds, or ester oils of natural oils and polyols, phosphate esters, diester oils, polyglycol oils, silicone oils, polyphenyl ether oils, alkyl diphenyl ether oils, alkyl benzenes, fluorinated Examples include non-hydrocarbon synthetic oils such as oil. As grease, these lubricants are used as base oils, and soap-based thickeners such as metal soaps and composite metal soaps, or non-soap-based thickeners such as benton, silica gel, urea compounds, urea / urethane compounds, etc. Grease using is used. In addition, a solid wax may be blended.

  Since the sliding bearing of the present invention requires low friction, it is preferable to use silicone oil among the above as the lubricant (D). Silicone oil has an affinity for the silanol groups remaining on the porous silica surface. As the silicone oil, either a silicone oil having no functional group or a silicone oil having a functional group can be used.

  When the porous silica (C) and the lubricant (D) are blended in the resin material, the kneading order is not particularly limited, but the porous silica and the lubricant are kneaded in advance and the porous silica is impregnated with the lubricant. It is preferable to knead with other materials after the mixing. A method of impregnating a lubricant after kneading the base resin and porous silica into a molded body is also possible. Moreover, since porous silica is easy to absorb moisture or absorb water, it is preferable to dry before kneading. The drying means is not particularly limited, and drying in an electric furnace, vacuum drying, or the like can be employed. Since the lubricating oil can be sufficiently retained in the porous silica and is excellent in kneadability, it is preferably blended with other materials in the state of oil-containing porous silica in which the porous silica is impregnated with silicone oil or the like in advance.

  In the resin material, the porous silica (C) and the lubricant (D) such as silicone oil are preferably contained in a total mass (C + D) of 25 to 50% by mass with respect to the entire resin material. More preferably, it is 25-45 mass%, More preferably, it is 30-40 mass%, Most preferably, it is 35-40 mass%. The breakdown is preferably about (C) :( D) = 1: 3 in terms of mass. By blending the oil-containing porous silica in an amount of 25 to 50% by mass with respect to the entire resin material, the lubricating oil can be supplied with excellent lubrication and wear characteristics.

  It is also possible to impregnate the outer peripheral portion of the bearing made of a sintered metal base material with the lubricating oil and ooze and lubricate the sliding surface through the resin layer having the communication hole structure.

  As the solid lubricant (E), PTFE resin, graphite, molybdenum disulfide, boron nitride, tungsten disulfide and the like can be used.

  The PTFE resin (powder) may be any of a molding powder by suspension polymerization, a fine powder by emulsion polymerization, and a PTFE resin powder that has been heat-fired, but a heat-fired PTFE resin powder may be employed. preferable. This is because molding powder and fine powder that have not been heated and fired have low frictional properties, but are inferior in uniform dispersibility and wear resistance. The heat-fired PTFE resin powder may be a powder obtained by pulverizing molding powder or fine powder after heat-firing (material molding, heat treatment), or a powder obtained by further irradiating the powder with γ rays or electron beams. The particle size of the PTFE resin powder is not particularly limited, but the average particle size is preferably 5 to 30 μm in order to obtain stable low friction characteristics.

  In addition, an appropriate filler can be added to the resin material forming the resin layer of the sliding bearing in order to improve the friction and wear characteristics and to reduce the linear expansion coefficient. For example, glass fibers, carbon fibers, pitch-based carbon fibers, PAN-based carbon fibers, aramid fibers, alumina fibers, polyester fibers, boron fibers, silicon carbide fibers, boron nitride fibers, silicon nitride fibers, metal fibers, and the like Woven into cloth, minerals such as calcium carbonate, talc, silica, clay, mica, inorganic whiskers such as aluminum borate whisker and potassium titanate whisker, various heat resistant resins such as polyimide resin and polybenzimidazole, etc. Is mentioned. When there is a risk of attacking the soft mating material, the fibrous filler is not blended. Furthermore, you may use a well-known additive together with the compounding quantity which does not inhibit the effect of this invention. For example, additives such as antistatic agents (carbon nanofibers, carbon black, graphite, etc.), mold release agents, flame retardants, weather resistance improvers, antioxidants, pigments, and the like may be added as appropriate. The method is not particularly limited.

  In the sliding bearing of the present invention, the most preferable composition as the resin material for forming the resin layer is injection-moldable PE resin (A), non-injection-moldable UHMWPE resin (B), porous silica (C), silicone oil. The composition is substantially composed of four components of the lubricant (D). In this case, when the total amount (C + D) of the porous silica (C) and the lubricant (D) such as silicone oil is 25 to 50% by mass with respect to the entire resin material, the PE resin (A) and UHMWPE The total mass (A + B) with the resin (B) is 50 to 75 mass% with respect to the entire resin material.

  The means for mixing and kneading the raw materials in the resin material forming the resin layer of the sliding bearing is not particularly limited, and is mixed with a Henschel mixer, a ball mixer, a ribbon blender, a Redige mixer, etc. Melting and kneading can be performed with a melt extruder such as a shaft extruder to obtain molding pellets. In addition, as a part of the filler material, side feed may be employed when melt-kneading with a twin screw extruder or the like. Using this molding pellet, a resin layer is injection-molded by insert molding on a metal substrate. By adopting injection molding, it is excellent in precision moldability and productivity. Moreover, you may employ | adopt treatments, such as an annealing process, for physical property improvement.

  Even when the porous silica impregnated with silicone oil is blended only by using the PE resin (A) as the resin base material of the resin material, the PV value is 3 MPa · m / min. However, the PV value exceeding this level could significantly deteriorate the wear resistance. In contrast, by replacing a part of the PE resin (A) with a non-injectable UHMWPE resin (B) within a predetermined blending range, the wear resistance at a high PV value is remarkably improved. I was able to. In particular, Mitsui Chemicals 'brand name Lubemer L5000 is used as the PE resin (A), and Mitsui Chemicals' brand name Mipelon XM220 is used as the non-injectable UHMWPE resin (B). By blending porous silica impregnated with silicone oil, 15 MPa · m / min. A sliding bearing capable of exhibiting excellent wear resistance even with the above high PV value could be obtained (see Examples described later). As a result, the sliding bearing of the present invention can be suitably used as a substitute for a rolling bearing in many applications.

  The sliding bearing of the present invention will be described with reference to FIG. FIG. 1A is a perspective view of a sliding bearing, and FIG. 1B is a cross-sectional view taken along line AA. The slide bearing 1 has a bearing outer peripheral portion 2 formed of a sintered metal base material, and a resin layer formed on the inner peripheral side that becomes the sliding portion of the bearing outer peripheral portion 2 using the above-described resin material (molding pellet). 3 is insert-molded through a tunnel gate. The resin layer 3 has a plurality of grooves 4 on the bearing sliding surface, and a gate mark 5 is formed at the bottom of the groove 4. In FIG. 1A, the plurality of grooves 4 are formed as axial grooves 4A and 4B on the radial sliding surface of the cylindrical bearing, and a gate mark 5 is formed at the bottom position of the axial groove 4A. The gate mark 5 is not formed on 4B. Further, the plurality of grooves 4 can be provided on the radial sliding surface, the thrust sliding surface, or both the radial sliding surface and the thrust sliding surface of the cylindrical bearing.

  Insert molding through a tunnel gate can be performed using a known mold structure. Since the tunnel gate trace is formed at the bottom of the groove, no gate processing is required in the molding process, and mass production is possible while having high accuracy.

  The plurality of axial grooves 4 are composed of a groove 4A having a tunnel gate trace and a groove 4B having no tunnel gate trace. Moreover, it arrange | positions so that the distance on the bearing sliding surface from the both sides of the groove | channel 4A to the groove | channel 4B may become equal. Preferably, the same number of grooves A and grooves B are formed at equal intervals. With this arrangement, a weld portion at the time of injection molding is formed in the groove B. Further, the wear powder can be captured in the groove 4 to suppress the occurrence of abnormal wear.

  The bearing outer peripheral part 2 is a cylindrical member constituting the outer peripheral part of the sliding bearing, and is a member having a sliding part. The sliding portion refers to a sliding portion on the inner diameter side for supporting a load in the radial direction. When supporting a load in the thrust direction, not only the inner sliding portion but also an end surface sliding portion is used. Includes moving parts.

  Examples of the material of the sintered metal base material constituting the bearing outer peripheral portion 2 include Fe-based sintered metal, Cu-based sintered metal, and Fe-Cu-based sintered metal, and may include C, Zn, and Sn as components. Good. Further, a small amount of a binder may be added in order to improve moldability and releasability. Further, an aluminum-based material containing Cu, Mg, Si, or a metal-synthetic resin material in which iron powder is bonded with an epoxy-based synthetic resin may be used. Furthermore, in order to improve the adhesion with the resin layer, it is possible to perform a surface treatment or to interpose an adhesive as long as the molding is not hindered.

  In order to obtain a sliding bearing having high dimensional accuracy and rotational accuracy and excellent mechanical strength and durability, Fe-based sintered metal is preferable. Here, “Fe-based” means that the Fe content is 90% or more by mass ratio. As long as this condition is satisfied, other components such as Cu, Sn, Zn, and C may be contained. “Fe” also includes stainless steel. Fe-based sintered metal is formed by, for example, forming a raw metal powder containing Fe in the above content (a small amount of a binder may be added to improve moldability and releasability) into a predetermined shape, degreasing, The sintered body obtained by firing can be formed by subjecting it to a post-treatment such as sizing, if necessary. The sintered metal has a large number of internal pores due to a porous structure, and the surface has a large number of surface pores formed by opening the internal pores to the outside. The internal pores can be impregnated with the above-described lubricating oil, for example, by vacuum impregnation.

  A resin layer 3 is insert-molded on the sliding portion of the bearing outer peripheral portion 2 made of a sintered metal base material to form a bearing surface that slides with the shaft member. At the time of molding, the molten resin forming the resin layer enters the internal pores of the surface layer portion from the surface opening and solidifies, so that the resin layer adheres firmly to the base surface by a kind of anchor solidification. For this reason, the resin layer is hardly peeled off or dropped off by sliding with the shaft member, and high durability is obtained.

  The surface porosity of the surface on which the resin layer made of a sintered metal substrate is formed is preferably 20 to 50%. If the surface area ratio is less than 20%, the anchor effect on the resin layer cannot be sufficiently obtained, and if the surface area ratio exceeds 50%, the dimensional accuracy and mechanical strength may not be maintained. The “surface aperture ratio” is the ratio (area ratio) of the total area of surface apertures per unit area of the surface.

  Moreover, you may form the bearing outer peripheral part 2 with a molten metal base material. The molten metal material is preferably iron, aluminum, an aluminum alloy, copper, or a copper alloy. Examples of iron include general structural carbon steel (SS400, etc.), mild steel (SPCC, SPCE, etc.), stainless steel (SUS304, SUS316, etc.), and these irons may be plated with zinc, nickel, copper, or the like. . Examples of aluminum include A1100 and A1050, examples of aluminum alloys include A2017 and A5052 (including anodized products), examples of copper include C1100, and examples of copper alloys include C2700 and C2801.

  When the bearing outer peripheral portion 2 is made of a molten metal base material, the joint surface is roughened into an uneven shape by shot blasting, tumbler, machining or the like in order to improve adhesion with the resin layer at the time of insert molding (for example, (Ra 4 μm or more). In addition, chemical surface treatment such as acidic solution treatment (mixed with sulfuric acid, nitric acid, hydrochloric acid, etc., or other solutions), alkaline solution treatment (mixed with sodium hydroxide, potassium hydroxide, etc., or other solutions) is performed. It is preferable to form a fine uneven shape on the joint surface. Since the fine uneven shape formed by the chemical surface treatment has a complicated three-dimensional structure such as a porous structure, the anchor effect can be easily exerted, and strong adhesion can be achieved.

  In the resin layer, (the linear expansion coefficient of the resin material (unit: 1 / ° C.) × (the thickness of the resin layer (unit: μm)) is preferably 0.15 or less, preferably 0.13 or less, 0.10 When the above value is greater than 0.15, the thickness or expansion of the resin layer also increases, and since the outer diameter side of the resin layer is constrained by the metal base, It cannot expand beyond the expansion, but expands toward the inner diameter side, reducing the inner diameter dimension, resulting in a decrease in the clearance with the shaft, and depending on the initial clearance setting, the shaft may be stiff due to temperature rise. In addition, excessive gap fluctuation is not preferable because it causes torque fluctuation, and it is preferable that the gap is small from the viewpoint of rotational accuracy.In addition, dimensional change due to water absorption increases, and excessive gap fluctuation occurs. There is.

  Moreover, the thickness of the resin layer that can be molded is about 50 μm, and if it is thinner than this, formation becomes difficult. Accordingly, the resin expansion coefficient × thickness needs to be 0.003 or more, preferably 0.01 or more, more preferably 0.015 or more.

  The thickness of the resin layer is preferably set to 0.1 to 0.5 mm (100 to 500 μm). The “thickness of the resin layer” in the present invention is the thickness (the thickness in the radial direction) of the surface portion that does not enter the metal substrate. If the thickness of the resin layer is less than 0.1 mm, the durability during long-term use may be poor. On the other hand, if the thickness of the resin layer exceeds 0.5 mm, sink marks may occur and dimensional accuracy may be reduced. In addition, heat due to friction is difficult to escape from the friction surface to the metal substrate, and the friction surface temperature increases. Furthermore, the amount of deformation due to the load increases and the real contact area on the friction surface also increases, which may increase the frictional force and frictional heat generation.

  As the shape of the sliding bearing of the present invention, an optimum bearing shape can be selected according to the shape of the sliding portion, such as a radial type, a flat plate type, and a flanged bush. Moreover, although the aspect which has a some groove | channel on the bearing sliding surface was demonstrated in FIG. 1, it is not limited to this, The aspect which does not form this groove | channel may be sufficient.

  Moreover, the place which insert-molds to the bearing outer peripheral part of a resin layer will not be specifically limited if it is a sliding part of a bearing outer peripheral part. For example, the cases as shown in FIGS. FIGS. 2A and 2E show a resin layer 3 formed on the radially inner radial sliding surface of the bearing outer peripheral portion 2 in order to support a load in the radial direction. FIGS. 2B, 2C and 2D are views in which a resin layer 3 is formed on the inner radial radial sliding surface and the thrust sliding surface of the bearing outer peripheral portion 2 in order to support loads in the radial direction and the thrust direction. It is. Although not shown, a resin layer can be applied to the outer diameter portion of the bearing as necessary. As shown in FIGS. 2C and 2E, the shape of a resin layer having a hooking portion that does not peel off the outer peripheral portion of the bearing and the resin layer may be adopted.

  The sliding bearing of the present invention has high accuracy, excellent sliding characteristics (low friction, low wear), does not attack a soft mating material such as an aluminum shaft, and can also suppress the generation of abnormal noise. For this reason, it can be used as a bearing that supports the rotating shaft of a rotating part in a developing unit, a photosensitive unit, a transfer unit, and the like of office equipment such as a copying machine and a printer. In addition, since it has PE resin as a main component, it can be suitably used mainly in a temperature atmosphere of 80 ° C. or lower.

  Further, 15 MPa · m / min. Since it is possible to use at the above high PV value, it is possible to use a part that is used at a load and speed that is conventionally supported by a rolling bearing instead of the rolling bearing.

  The sliding bearings of the examples and comparative examples were manufactured by the following materials and molding methods, and a predetermined frictional wear test was performed on those that could mold the resin layer.

1. Resin material Base resin;
(A) PE resin that can be injection-molded [trade name Lübmer L5000 manufactured by Mitsui Chemicals] (density (ASTM D 1505): 966 kg / m ³ , MFR (JIS K 7210 (190 ° C., 10 kgf)): 2 g / 10 minutes )
filler;
(B) Non-injectable UHMWPE resin [trade name Mipelon XM220 manufactured by Mitsui Chemicals, Inc.] (weight average molecular weight: 2 million, average particle diameter (laser diffraction method): 30 μm, bulk specific gravity (ASTM D 1895): 400 kg / M ³ , Shore hardness (ASTM D3418): 65D, spherical particles)
(C) Porous silica [trade name Sunsphere H53 manufactured by AGC S-Itech Co., Ltd.]
(D) Silicone oil [trade name KF-96H manufactured by Shin-Etsu Chemical Co., Ltd.]
A mixture (oil-containing porous silica) having a mixing ratio of porous silica and silicone oil of 1: 3 (mass conversion) was obtained, and 39% by mass of this mixture with respect to the entire resin material, PE resin capable of injection molding Was blended with a biaxial extruder to form a pellet for molding. X mass% was blended with Y mass% of non-injectable UHMWPE resin. Here, (X mass% + Y mass%) = 61 mass%, and details are shown in Table 2.

2. Outer ring made of sintered metal substrate (sintered outer ring)
Size: φ8.5mm (inner diameter), φ16mm (outer diameter), 5mm (height)
Ingredients: copper (0.5-2.5% by mass), other (3% by mass or less), iron (remaining amount)
Manufacturing process: material powder blending, forming, sintering, sizing, rust prevention and drying

3. Insert molding conditions A sintered outer ring having the above-mentioned shape was inserted into a mold, and the molding pellets obtained above were passed through a tunnel gate, and insert molding was performed under the following conditions. The resin layer has a thickness of 0.25 mm.
Finished product size: φ8mm (inner diameter), φ16mm (outer diameter), 5mm (height)
Mold temperature: 120 ° C
Molding temperature: 250 ° C
Injection pressure: 100-140 MPa

摩耗係数
ｋ＝δ／（Ｆ×Ｄ）
ｋ：摩耗係数 ｍｍ／（Ｎ×ｍ） 定義：単位仕事量当たりの真円度増加量
Ｆ：ラジアル荷重 Ｎ
Ｄ：総滑り距離 ｍ
δ：摩耗量（真円度の増加量） ｍｍ δ＝δ１−δ０
δ０：試験前の供試軸受の内径２断面真円度（半径法）の平均値
δ１：試験後の供試軸受の内径２断面真円度（半径法）の平均値 4). Friction and wear test A friction and wear test was performed under the conditions shown in Table 1 below. The gap between the mating material shaft and the sliding bearing was 20 μm (measured at 20 ° C.). The wear coefficient was calculated by the following formula. The results of the friction and wear test are shown in Table 2.

Wear coefficient k = δ / (F × D)
k: Wear coefficient mm / (N × m) Definition: Roundness increase per unit work F: Radial load N
D: Total slip distance m
δ: Amount of wear (increase in roundness) mm δ = δ1-δ0
δ0: Average value of the inner diameter 2 section roundness (radius method) of the test bearing before the test δ1: Average value of the inner diameter 2 section roundness (radius method) of the test bearing after the test

  As shown in Table 2, each example in which PE resin contains non-injectable UHMWPE resin in a predetermined range can be injection-molded, and has a low friction coefficient at PV values of 5 and 15 MPa · m / min. In addition, it can be seen that the wear resistance is also excellent.

  Further, as Comparative Example 3, the same as Example 1 except that the non-injectable UHMWPE resin (B) is not included and the injection-moldable PE resin (A) is 61% by mass with respect to the entire resin material. Sliding bearings were manufactured under the conditions. With respect to Comparative Example 3 and Example 2, the frictional wear test was performed a plurality of times, and the relationship between the PV value and the wear coefficient was examined. The results are shown in Table 3 and FIG. FIG. 3 is a plot of the data in Table 3 with the PV value on the horizontal axis and the wear coefficient on the vertical axis.

  As shown in Table 3 and FIG. 3, it can be seen that Comparative Example 3, which does not contain any non-injectable UHMWPE resin, significantly deteriorates the wear resistance when the PV value exceeds 3 MPa · m / min. . Also, at high PV values, the variation in wear coefficient for each measurement is large. On the other hand, in Example 2 partially including non-injectable UHMWPE resin, the PV value is 5, 10, and 15 MPa · m / min, and the wear resistance is excellent and the variation is small. I understand.

  The sliding bearing of the present invention can be used suitably as a substitute for a rolling bearing in office equipment because it can cope with a high PV value while maintaining a low coefficient of friction and is excellent in productivity.

DESCRIPTION OF SYMBOLS 1 Sliding bearing 2 Bearing outer peripheral part 3 Resin layer 4 Groove 5 Gate trace

Claims (4)

A sliding bearing having a metal base material and a resin layer that is an injection-molded layer of a resin material integrally provided on a surface that becomes a sliding surface of the base material,
In the slide bearing, the outer peripheral part of the bearing is made of the metal base material, and the resin layer is provided on the inner peripheral side which becomes the sliding part of the outer peripheral part of the bearing, and the sliding part rotates the rotating part of the office equipment. The PV value obtained by supporting the shaft and multiplying the surface pressure (P) and the sliding speed (V) is 5 MPa · m / min. It is a bearing used under conditions that exceed
The resin material is impregnated with a non-injectable ultra-high molecular weight polyethylene resin (B) having a weight average molecular weight of 1,000,000 to 4,000,000 as a main component and a silicone oil. A material containing porous silica,
In the resin material, the powdery ultra high molecular weight polyethylene resin (B) is in a ratio of 5 to 30% by mass with respect to the total mass of the polyethylene resin (A) and the ultra high molecular weight polyethylene resin (B). In the resin layer, the ultrahigh molecular weight polyethylene resin (B) is dispersed in the polyethylene resin (A),
In the resin material, the porous silica impregnated with the silicone oil is contained in an amount of 35 to 40% by mass with respect to the entire resin material,
A sliding bearing , wherein the resin layer has a thickness of 0.1 to 0.5 mm .   The sliding bearing according to claim 1, wherein the polyethylene resin (A) that can be injection-molded has an MFR of 1 to 30 g / 10 min when measured at a load of 10 kg and 190 ° C based on JIS K 7210. . The plain bearing according to claim 1 or 2, wherein the metal base material is a sintered metal base material. The sliding bearing according to any one of claims 1 to 3 , wherein the sliding bearing is a bearing used in a temperature atmosphere of 80 ° C or lower.

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