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JP6303719B2 - How to add a lasting flavor - Google Patents

How to add a lasting flavor Download PDF

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JP6303719B2
JP6303719B2 JP2014070655A JP2014070655A JP6303719B2 JP 6303719 B2 JP6303719 B2 JP 6303719B2 JP 2014070655 A JP2014070655 A JP 2014070655A JP 2014070655 A JP2014070655 A JP 2014070655A JP 6303719 B2 JP6303719 B2 JP 6303719B2
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flavor
oil
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average particle
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JP2015188434A (en
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乃梨子 梶本
乃梨子 梶本
和寛 林
和寛 林
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Ajinomoto Co Inc
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Description

本発明は、持続性のある風味の付与方法、及び当該方法によって持続性のある風味を付与された食品等に関する。   The present invention relates to a method for imparting a persistent flavor, and a food or the like to which a persistent flavor is imparted by the method.

食品に所望の風味を付与するために、従来より、様々な香料組成物が用いられている。持続性・保留性を訴求する香料組成物としては、例えば、強い香味を持続して発現させることができる粉末香味料(特許文献1)、香気、香味が長く持続する油性香料含有粉末製剤(特許文献2)、呈味持続性の粉末香料(特許文献3)等が報告されている。また、特許文献4には、乳化安定性等に優れる低油分の水中油型乳化物が報告され、特許文献5には、風味及び口どけが良好なアイスクリームが報告されている。   Conventionally, various flavor compositions have been used to impart a desired flavor to foods. Examples of the fragrance composition that appeals for sustainability and retention are, for example, a powder fragrance (Patent Document 1) that can continuously develop a strong fragrance, and an oily fragrance-containing powder formulation that maintains a long fragrance and flavor (patent) Document 2), a taste-sustained powder flavor (Patent Document 3) and the like have been reported. Patent Document 4 reports a low-oil oil-in-water emulsion excellent in emulsification stability and the like, and Patent Document 5 reports an ice cream with good flavor and mouthfeel.

特開2012−115205号公報JP 2012-115205 A 特開2011−74306号公報JP 2011-74306 A 特開2001−149019号公報JP 2001-149019 A 特開2010−193811号公報JP 2010-193811 A 特開2001−231457号公報JP 2001-231457 A

しかしながら、上述した従来の技術を用いてもなお、風味の持続性(後伸び)を向上させる点で改善の余地があった。   However, even if the conventional technology described above is used, there is still room for improvement in terms of improving the sustainability (post elongation) of the flavor.

従って、本発明の目的は、持続性のある風味を食品に付与する方法等を提供することにある。   Accordingly, an object of the present invention is to provide a method for imparting a sustained flavor to foods.

本発明者らは、風味素材を含み、平均粒子径が風味素材のlogP値に応じた所定の範囲内に調整された油滴を含有する液状水中油型乳化組成物を、食品全量に対する油相成分量が、風味素材のlogP値に応じた所定の範囲内になるよう食品に添加することにより、該食品に持続性の高い風味を付与できることを見出し、本発明を完成するに至った。
即ち、本発明は以下の通りである。
The inventors include a liquid oil-in-water emulsified composition containing oil droplets containing a flavor material and having an average particle size adjusted within a predetermined range in accordance with the log P value of the flavor material. It has been found that by adding the amount of ingredients to a food so as to be within a predetermined range according to the log P value of the flavor material, the food can be given a sustained flavor, and the present invention has been completed.
That is, the present invention is as follows.

[1] 風味素材を含み、平均粒子径が1.2μm以上80μm以下である油滴を含有する液状水中油型乳化組成物を食品に添加することを含み、
該乳化組成物の油相成分量は、該食品全量に対して10%(v/v)未満であり、
風味素材のlogP値が下記(1)〜(3)の各場合に、前記油滴の平均粒子径及び/又は前記油相成分量が、更に下記の要件を充足する、持続性のある風味の付与方法(以下、「本発明の方法」とも称する)。
(1)風味素材のlogP値が1未満である場合;
油滴の平均粒子径が15μm以上、且つ、油相成分量が食品全量に対して0.05%(v/v)以上
(2)風味素材のlogP値が1以上3未満である場合;
油滴の平均粒子径が15μm以上、且つ/又は、油相成分量が食品全量に対して0.5%(v/v)以上
(3)風味素材のlogP値が3以上である場合;
油滴の平均粒子径が15μm以上、且つ/又は、油相成分量が食品全量に対して0.05%(v/v)以上
[2] 油滴の平均粒子径が15μm以上80μm以下、且つ、油相成分量が食品全量に対して0.05%(v/v)以上10%(v/v)未満である、上記[1]記載の方法。
[3] 乳化組成物が、HLBが10以上である乳化剤を含有する、上記[1]又は[2]記載の方法。
[4] 上記[1]〜[3]のいずれか1つに記載の方法によって持続性のある風味が付与された食品。
[5] 液状水中油型乳化組成物を含む食品であって、
該乳化組成物は、風味素材を含み、平均粒子径が1.2μm以上80μm以下である油滴を含有し、
該乳化組成物の油相成分量は、該食品全量に対して10%(v/v)未満であり、
風味素材のlogP値が下記(1)〜(3)の各場合に、前記油滴の平均粒子径及び/又は前記油相成分量が、更に下記の要件を充足する、食品(以下、「本発明の食品」とも称する)。
(1)風味素材のlogP値が1未満である場合;
油滴の平均粒子径が15μm以上、且つ、油相成分量が食品全量に対して0.05%(v/v)以上
(2)風味素材のlogP値が1以上3未満である場合;
油滴の平均粒子径が15μm以上、且つ/又は、油相成分量が食品全量に対して0.5%(v/v)以上
(3)風味素材のlogP値が3以上である場合;
油滴の平均粒子径が15μm以上、且つ/又は、油相成分量が食品全量に対して0.05%(v/v)以上
[6] 持続性のある風味を有する、上記[5]記載の食品。
[1] comprising adding a liquid oil-in-water emulsion composition containing a flavor material and containing oil droplets having an average particle size of 1.2 μm or more and 80 μm or less to a food,
The amount of the oil phase component of the emulsion composition is less than 10% (v / v) based on the total amount of the food,
In each case where the log P value of the flavor material is the following (1) to (3), the average particle diameter of the oil droplets and / or the amount of the oil phase component further satisfies the following requirements. Application method (hereinafter also referred to as “method of the present invention”).
(1) When the log P value of the flavor material is less than 1;
When the average particle size of the oil droplets is 15 μm or more and the amount of the oil phase component is 0.05% (v / v) or more with respect to the total amount of food (2) The log P value of the flavor material is 1 or more and less than 3;
When the average particle diameter of oil droplets is 15 μm or more and / or the amount of oil phase components is 0.5% (v / v) or more with respect to the total amount of food (3) When the log P value of the flavor material is 3 or more;
The average particle size of oil droplets is 15 μm or more and / or the amount of oil phase component is 0.05% (v / v) or more with respect to the total amount of food [2] The average particle size of oil droplets is 15 μm or more and 80 μm or less, and The method according to [1] above, wherein the amount of the oil phase component is 0.05% (v / v) or more and less than 10% (v / v) based on the total amount of food.
[3] The method according to [1] or [2] above, wherein the emulsion composition contains an emulsifier having an HLB of 10 or more.
[4] A food provided with a persistent flavor by the method according to any one of [1] to [3] above.
[5] A food comprising a liquid oil-in-water emulsion composition,
The emulsified composition contains a flavor material and contains oil droplets having an average particle size of 1.2 μm or more and 80 μm or less,
The amount of the oil phase component of the emulsion composition is less than 10% (v / v) based on the total amount of the food,
In each case where the log P value of the flavor material is the following (1) to (3), the average particle diameter of the oil droplets and / or the amount of the oil phase component further satisfies the following requirements (hereinafter referred to as “this” Also referred to as “food of the invention”).
(1) When the log P value of the flavor material is less than 1;
When the average particle size of the oil droplets is 15 μm or more and the amount of the oil phase component is 0.05% (v / v) or more with respect to the total amount of food (2) The log P value of the flavor material is 1 or more and less than 3;
When the average particle diameter of oil droplets is 15 μm or more and / or the amount of oil phase components is 0.5% (v / v) or more with respect to the total amount of food (3) When the log P value of the flavor material is 3 or more;
The average particle size of oil droplets is 15 μm or more, and / or the amount of oil phase components is 0.05% (v / v) or more with respect to the total amount of food [6] The above-mentioned [5], having a persistent flavor Food.

本発明によれば、持続性のある風味を食品に付与する方法を提供できる。
また本発明によれば、持続性のある風味を有する食品を提供できる。
According to the present invention, it is possible to provide a method for imparting a persistent flavor to food.
Moreover, according to this invention, the foodstuff which has a lasting flavor can be provided.

試験例1における、風味素材としてメチオナールを使用した場合の、持続性のある風味の付与効果の評価結果を示す。The evaluation result of the impartment effect of the persistent flavor at the time of using methional as a flavor raw material in the test example 1 is shown. 試験例1における、風味素材としてイソ吉草酸を使用した場合の、持続性のある風味の付与効果の評価結果を示す。The evaluation result of the impartation effect of the persistent flavor at the time of using isovaleric acid as a flavor raw material in the test example 1 is shown. 試験例1における、風味素材として1−オクテン−3−オールを使用した場合の、持続性のある風味の付与効果の評価結果を示す。The evaluation result of the imparting effect of the persistent flavor at the time of using 1-octen-3-ol as a flavor raw material in the test example 1 is shown. 試験例1における、風味素材としてオクタン酸を使用した場合の、持続性のある風味の付与効果の評価結果を示す。The evaluation result of the impartment effect of the persistent flavor at the time of using octanoic acid as a flavor raw material in the test example 1 is shown. 試験例1における、風味素材としてデカン酸を使用した場合の、持続性のある風味の付与効果の評価結果を示す。The evaluation result of the impartment effect of the persistent flavor at the time of using a decanoic acid as a flavor raw material in the test example 1 is shown.

1.本発明の方法
本発明の方法は、風味素材を含み、平均粒子径が所定の範囲である油滴を含有する液状水中油型乳化組成物(以下、「本発明の乳化組成物」とも称する)を食品に添加することを特徴の一つとする。
本発明において「液状水中油型乳化組成物」とは、油相成分が油滴として水相中に略均一に分散している水中油型の乳化構造を有し、且つ第十六改正日本薬局方に規定される常温(例、25℃)において液状である組成物をいう。当該乳化組成物には、水相中に略均一に分散した油滴の中に、更に水相が分散しているものも含まれる。
1. Method of the Invention The method of the present invention is a liquid oil-in-water emulsified composition containing a flavor material and containing oil droplets having an average particle diameter in a predetermined range (hereinafter also referred to as “emulsified composition of the present invention”). Is added to food.
In the present invention, the “liquid oil-in-water emulsion composition” means an oil-in-water emulsion structure in which oil phase components are dispersed almost uniformly in the water phase as oil droplets, and the 16th revised Japanese pharmacy Refers to a composition that is liquid at room temperature (eg, 25 ° C.). The emulsified composition includes those in which an aqueous phase is further dispersed in oil droplets dispersed substantially uniformly in the aqueous phase.

油滴に含まれる風味素材は特に制限されず、食品の種類等に応じて、食品香料の分野において通常用いられる風味素材を適宜選択して使用できる。該風味素材は食品に使用できるものであれば、例えば合成品又は抽出品等であってよい。また市販品も利用でき、簡便であることから好ましい。該風味素材の具体例としては、メチオナール、メチオノール、ジメチルスルフィド、チアゾール等の含硫化合物類;酪酸、イソ吉草酸、オクタン酸、デカン酸等の有機酸類;ノナノール、1−オクテン−3−オール、メントール等のアルコール類;2−メチルピラジン、2、3−ジメチルピラジン等の含窒素化合物類;ヘキサナール、trans,trans−2,4−デカジエナール等のアルデヒド類;バラ油、ラベンダー油、ベルガモット油、シナモン油、レモン油、ハッカ油、各種フレーバー(例、ペパーミントフレーバー、オレンジフレーバー、ゴマフレーバー、ジンジャーフレーバー、ガーリックフレーバー等)等が挙げられ、好ましくは含硫化合物類、有機酸類、アルコール類、含窒素化合物類、アルデヒド類であり、より好ましくはメチオナール、イソ吉草酸、1−オクテン−3−オール、オクタン酸、デカン酸、2−メチルピラジン、2−エチル−4−メチルチアゾール、trans,trans−2,4−デカジエナールである。これらの風味素材は単独で用いても2種以上を併用してもよい。   The flavor material contained in the oil droplet is not particularly limited, and a flavor material usually used in the field of food fragrance can be appropriately selected and used according to the type of food. The flavor material may be, for example, a synthetic product or an extract as long as it can be used for food. Moreover, a commercial item can also be used and it is preferable because it is simple. Specific examples of the flavor material include sulfur-containing compounds such as methional, methionol, dimethyl sulfide, and thiazole; organic acids such as butyric acid, isovaleric acid, octanoic acid, and decanoic acid; nonanol, 1-octen-3-ol, Alcohols such as menthol; nitrogen-containing compounds such as 2-methylpyrazine, 2,3-dimethylpyrazine; aldehydes such as hexanal, trans, trans-2,4-decadienal; rose oil, lavender oil, bergamot oil, cinnamon Oil, lemon oil, peppermint oil, various flavors (eg, peppermint flavor, orange flavor, sesame flavor, ginger flavor, garlic flavor, etc.), preferably sulfur-containing compounds, organic acids, alcohols, nitrogen-containing compounds Aldehydes, more preferred Ku is methional, isovaleric acid, 1-octen-3-ol, octanoic acid, decanoic acid, 2-methyl pyrazine, 2-ethyl-4-methylthiazole, trans, trans-2,4-decadienal. These flavor materials may be used alone or in combination of two or more.

風味素材を含む油滴を含有する乳化組成物は、例えば、油相成分と水相成分とを混合する前に予め油相成分に風味素材を添加し、当該風味素材が添加された油相成分と水相成分とを混合した後、得られた混合物に対し乳化処理を施すこと等により調製できる。   An emulsified composition containing oil droplets containing a flavor material is, for example, an oil phase component in which the flavor material is added to the oil phase component in advance before the oil phase component and the aqueous phase component are mixed, and the flavor material is added. And the aqueous phase component can be mixed, and then the resulting mixture can be prepared by emulsification.

油相成分に風味素材を予め添加する際、油相成分における風味素材の濃度は特に制限されず、風味素材の種類等に応じて適宜設定すればよいが、通常0.01〜500000ppm(v/v)であり、好ましくは0.05〜400000ppm(v/v)であり、より好ましくは0.1〜300000ppm(v/v)であり、特に好ましくは0.2〜200000ppm(v/v)である。   When the flavor material is added to the oil phase component in advance, the concentration of the flavor material in the oil phase component is not particularly limited, and may be appropriately set according to the type of the flavor material, but is usually 0.01 to 500,000 ppm (v / v), preferably 0.05 to 400,000 ppm (v / v), more preferably 0.1 to 300000 ppm (v / v), and particularly preferably 0.2 to 200000 ppm (v / v). is there.

本発明の方法によって持続性のある風味が付与された食品における、風味素材の濃度は特に制限されず、風味素材の種類や食品の種類等に応じて適宜設定すればよいが、通常0.01ppb(v/v)〜100ppm(v/v)であり、好ましくは0.05ppb(v/v)〜50ppm(v/v)であり、より好ましくは0.1ppb(v/v)〜30ppm(v/v)であり、特に好ましくは0.2ppb(v/v)〜20ppm(v/v)である。ここで、当該風味素材の濃度は、本発明の乳化組成物に含まれる風味素材の濃度を意味し、本発明の乳化組成物を添加する前の食品に風味素材が含まれていても、その量は、当該風味素材の濃度に算入しない。   The concentration of the flavor material in the food provided with a persistent flavor by the method of the present invention is not particularly limited, and may be set as appropriate according to the type of the flavor material, the type of food, etc., but is usually 0.01 ppb. (V / v) to 100 ppm (v / v), preferably 0.05 ppb (v / v) to 50 ppm (v / v), more preferably 0.1 ppb (v / v) to 30 ppm (v / V), particularly preferably 0.2 ppb (v / v) to 20 ppm (v / v). Here, the concentration of the flavor material means the concentration of the flavor material contained in the emulsified composition of the present invention, and even if the flavor material is contained in the food before adding the emulsified composition of the present invention, The amount is not included in the concentration of the flavor material.

本発明の乳化組成物は、油滴の平均粒子径が、少なくとも1.2μm以上(好ましくは2.0μm以上、より好ましくは3.0μm以上)80μm以下(好ましくは70μm以下、より好ましくは60μm以下)であることが好ましい。油滴の平均粒子径が当該範囲外であると、風味の持続性(後伸び)が低下する傾向があり、好ましくない。
本発明において「油滴の平均粒子径」とは、レーザー回折粒度分布測定装置(LA−920、株式会社堀場製作所製、攪拌速度:3)を用いて測定されるメジアン径をいう。
In the emulsion composition of the present invention, the average particle size of the oil droplets is at least 1.2 μm or more (preferably 2.0 μm or more, more preferably 3.0 μm or more) 80 μm or less (preferably 70 μm or less, more preferably 60 μm or less). ) Is preferable. If the average particle size of the oil droplets is outside this range, the flavor sustainability (post elongation) tends to decrease, such being undesirable.
In the present invention, the “average particle diameter of oil droplets” refers to a median diameter measured using a laser diffraction particle size distribution analyzer (LA-920, manufactured by Horiba, Ltd., stirring speed: 3).

本発明において、油滴の平均粒子径の調整は、自体公知の方法により適宜行い得る。例えば、風味素材を添加した油相成分と水相成分とを混合し、得られた混合物に対し乳化処理を施す際、その乳化条件を、後述の実施例に示される条件等に適宜設定することにより、油滴の平均粒子径を所望の範囲内に調整できる。乳化処理に用いられる乳化機は特に制限されず、乳化香料の分野において通常用いられる乳化機(例えば、高圧乳化機、ポンピングコネクタ、マイクロチャネル乳化装置、コロイドミル、ホモミキサー、スティックミキサー、ディスパーミキサー、ホモジナイザー、膜乳化等)を適宜用いることができる。   In the present invention, the adjustment of the average particle diameter of the oil droplets can be appropriately performed by a method known per se. For example, when an oil phase component and a water phase component to which a flavor material has been added are mixed, and the resulting mixture is emulsified, the emulsification conditions should be set appropriately to the conditions shown in the examples described later. Thus, the average particle diameter of the oil droplets can be adjusted within a desired range. The emulsifier used for the emulsification treatment is not particularly limited, and is an emulsifier usually used in the field of emulsified fragrance (for example, a high-pressure emulsifier, a pumping connector, a microchannel emulsifier, a colloid mill, a homomixer, a stick mixer, a disper mixer, Homogenizer, membrane emulsification, etc.) can be used as appropriate.

本発明の乳化組成物の油相成分及び水相成分は、本発明の目的を損なわない限り特に制限されず、食品香料の分野において通常用いられる成分を使用してよい。そのような油相成分としては、例えば、食用油脂、香味油等が挙げられ、また水相成分としては、例えば、水、食塩、酸味料、食酢、醤油、味噌、調味料、糖類、たん白加水分解物、香辛料、増粘剤等が挙げられるが、これらに限定されない。これらの油相成分及び水相成分は単独で用いても2種以上を併用してもよい。   The oil phase component and the aqueous phase component of the emulsified composition of the present invention are not particularly limited as long as the object of the present invention is not impaired, and components usually used in the field of food fragrances may be used. Examples of such oil phase components include edible fats and oils, flavor oils, and the like, and examples of water phase components include water, salt, acidulant, vinegar, soy sauce, miso, seasoning, saccharides, protein, and the like. Examples include hydrolysates, spices, thickeners, but are not limited thereto. These oil phase components and aqueous phase components may be used alone or in combination of two or more.

食用油脂の具体例としては、サフラワー油、ぶどう油、大豆油、ひまわり油、とうもろこし油、綿実油、ごま油、なたね油、こめ油、落花生油、オリーブ油、パーム油、パーム核油、やし油、キャノーラ油、サラダ油等の植物油脂;牛脂、豚脂、鶏脂、羊脂、鯨油等の動物油脂;等が挙げられ、好ましくは植物油脂である。また、上記食用油脂をエステル交換したエステル交換油、上記食用油脂に水素添加した硬化油等も用いることができる。これらの食用油脂は、単独で用いても2種以上を併用してもよい。   Specific examples of edible oils include safflower oil, grape oil, soybean oil, sunflower oil, corn oil, cottonseed oil, sesame oil, rapeseed oil, rice bran oil, peanut oil, olive oil, palm oil, palm kernel oil, palm oil, canola Vegetable oils and fats such as oil and salad oil; animal fats and oils such as beef tallow, pork tallow, chicken tallow, sheep fat and whale oil; and the like, preferably vegetable oils and fats. Moreover, the transesterified oil which transesterified the said edible oil and fat, the hardened oil which hydrogenated the said edible fat and oil, etc. can be used. These edible fats and oils may be used alone or in combination of two or more.

香味油の具体例としては、生姜、にんにく、たまねぎ、ねぎ、ニラ、セリ、茗荷、セロリ、しそ、みつば、わさび等の香味野菜を上記の食用油脂に漬け込んで(必要に応じて加熱してもよい)、香味を移しこんだもの等が挙げられる。これらの香味油は、単独で用いても2種以上を併用してもよい。   Specific examples of flavor oil include ginger, garlic, onion, green onion, leek, celery, sardine, celery, shiso, mitsuba, wasabi, etc. Good), and those with a flavor transferred. These flavor oils may be used alone or in combination of two or more.

本発明の乳化組成物は、乳化剤を含有してよい。当該乳化剤は、本発明の目的を損なわない限り特に制限されず、食品香料の分野において通常用いられる乳化剤を使用できる。そのような乳化剤としては、例えば、オクテニルコハク酸デンプンナトリウム、キラヤ抽出物、グリセリン脂肪酸エステル、酵素処理レシチン、酵素分解レシチン、植物性ステロール、植物レシチン(例、大豆レシチン等)、スフィンゴ脂質、ショ糖脂肪酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、ソルビタン脂肪酸エステル、大豆サポニン、胆汁末、プロピレングリコール脂肪酸エステル、分別レシチン、ユッカフォーム抽出物、卵黄レシチン、ポリソルベート20/60/65/80等が挙げられ、植物レシチン(例、大豆レシチン等)、ショ糖脂肪酸エステルが好ましい。これらの乳化剤は、単独で用いても2種以上を併用してもよい。   The emulsified composition of the present invention may contain an emulsifier. The emulsifier is not particularly limited as long as the object of the present invention is not impaired, and an emulsifier usually used in the field of food fragrances can be used. Examples of such emulsifiers include starch octenyl succinate sodium, kiraya extract, glycerin fatty acid ester, enzyme-treated lecithin, enzyme-degraded lecithin, plant sterol, plant lecithin (eg, soy lecithin, etc.), sphingolipid, sucrose fatty acid Ester, calcium stearoyl lactate, sodium stearoyl lactate, sorbitan fatty acid ester, soybean saponin, bile powder, propylene glycol fatty acid ester, fractionated lecithin, yuccafoam extract, egg yolk lecithin, polysorbate 20/60/65/80, etc., plant Lecithin (eg, soy lecithin) and sucrose fatty acid ester are preferred. These emulsifiers may be used alone or in combination of two or more.

本発明の乳化組成物に用いられる乳化剤は、HLBが10以上であることが好ましい。HLBが10以上である乳化剤を用いることにより、本発明の方法によって付与される風味の持続性が、より向上する。当該HLBは、11以上がより好ましく、13以上が特に好ましく、15以上が最も好ましい。HLBの上限は特に制限されないが、20(より好ましくは18、特に好ましくは16)が好ましい。
ここで「HLB」とは、親水親油バランス(hydrophile−lipophile balance)を意味し、基本的にW.C.Griffinによって提唱された計算式(W.C.Griffin,J.Soc.Cosmetic Chemists,1,311(1949)参照)に従って求められる。
The emulsifier used in the emulsified composition of the present invention preferably has an HLB of 10 or more. By using an emulsifier having an HLB of 10 or more, the sustainability of the flavor imparted by the method of the present invention is further improved. The HLB is more preferably 11 or more, particularly preferably 13 or more, and most preferably 15 or more. The upper limit of HLB is not particularly limited, but 20 (more preferably 18, particularly preferably 16) is preferable.
Here, “HLB” means a hydrophile-lipophile balance. C. It is determined according to a calculation formula proposed by Griffin (see WC Griffin, J. Soc. Cosmetic Chemist, 1, 311 (1949)).

本発明の乳化組成物が乳化剤を含有する場合、該乳化物は、油相成分と水相成分とを混合する前に、予め水相成分に含まれていることが好ましい。水相成分中の乳化剤の濃度は特に制限されず、使用する乳化剤の種類等に応じて適宜設定すればよいが、通常0.1〜3.0%(v/v)であり、好ましくは0.5〜2.0%(v/v)である。   When the emulsion composition of the present invention contains an emulsifier, the emulsion is preferably contained in the aqueous phase component in advance before mixing the oil phase component and the aqueous phase component. The concentration of the emulsifier in the aqueous phase component is not particularly limited, and may be appropriately set according to the type of the emulsifier to be used, but is usually 0.1 to 3.0% (v / v), preferably 0. 0.5 to 2.0% (v / v).

本発明の乳化組成物のpHは特に制限されないが、通常1〜13程度であり、食品に用いる観点から、好ましくは3〜8である。   The pH of the emulsified composition of the present invention is not particularly limited, but is usually about 1 to 13, and preferably 3 to 8 from the viewpoint of use in foods.

本発明の乳化組成物に含まれる油相成分は、乳化組成物に対して、0.1〜50%(v/v)であることが好ましく、より風味の持続性を付与する観点から、1.0〜30%(v/v)がより好ましく、2.0〜20%(v/v)が特に好ましい。   The oil phase component contained in the emulsified composition of the present invention is preferably 0.1 to 50% (v / v) with respect to the emulsified composition. From the viewpoint of imparting more flavor sustainability, 1 0.0 to 30% (v / v) is more preferable, and 2.0 to 20% (v / v) is particularly preferable.

本発明の乳化組成物に含まれる水相成分は、乳化組成物に対して、50〜99.9%(v/v)であることが好ましく、より風味の持続性を付与する観点から、70〜99%(v/v)がより好ましく、80〜98%(v/v)が特に好ましい。   The aqueous phase component contained in the emulsified composition of the present invention is preferably 50 to 99.9% (v / v) with respect to the emulsified composition, and from the viewpoint of imparting more flavor sustainability, 70 -99% (v / v) is more preferable, and 80-98% (v / v) is particularly preferable.

本発明の乳化組成物は、該乳化組成物の油相成分量が、食品全量に対して、少なくとも10%(v/v)未満(好ましくは5%(v/v)以下、より好ましくは3%(v/v)以下)であることが好ましい。乳化組成物の油相成分量が、食品全量に対して10%(v/v)以上であると、油相成分によって風味がマスキングされる傾向があり、好ましくない。尚、該乳化組成物の油相成分量の下限は特に限定されないが、食品全量に対して、0.001%(v/v)であることが好ましい。
ここで「食品全量」とは、乳化組成物が添加された後の食品の量であり、乳化組成物の量を含むものである。
In the emulsion composition of the present invention, the amount of the oil phase component of the emulsion composition is at least less than 10% (v / v) (preferably 5% (v / v) or less, more preferably 3%, based on the total amount of food. % (V / v) or less). If the amount of the oil phase component of the emulsified composition is 10% (v / v) or more based on the total amount of food, the flavor tends to be masked by the oil phase component, which is not preferable. The lower limit of the oil phase component amount of the emulsion composition is not particularly limited, but is preferably 0.001% (v / v) based on the total amount of food.
Here, the “total amount of food” is the amount of food after the emulsion composition is added, and includes the amount of the emulsion composition.

上述する通り、本発明の乳化組成物は、油滴の平均粒子径が、少なくとも1.2μm以上80μm以下であることが好ましく、また乳化組成物の油相成分量が、食品全量に対して、少なくとも10%(v/v)未満であることが好ましいが、これらの油滴の平均粒子径及び/又は油相成分量は、風味素材のlogP値に応じて、更に所定の要件を充足することが好ましい。油滴の平均粒子径及び/又は油相成分量が、更なる所定の要件を充足することにより、本発明の方法は、持続性に優れる風味を食品に付与することができる。   As described above, the emulsion composition of the present invention preferably has an average particle size of oil droplets of at least 1.2 μm or more and 80 μm or less, and the amount of the oil phase component of the emulsion composition is based on the total amount of food. The average particle diameter and / or the amount of oil phase components of these oil droplets should satisfy further predetermined requirements depending on the log P value of the flavor material, although it is preferable that the oil droplets are at least less than 10% (v / v). Is preferred. When the average particle diameter of the oil droplets and / or the amount of the oil phase component satisfies further predetermined requirements, the method of the present invention can impart a flavor with excellent sustainability to the food.

具体的には、油滴の平均粒子径及び/又は油相成分量は、風味素材のlogP値が下記(1)〜(3)の各場合に、下記の要件を更に充足することが好ましい。   Specifically, it is preferable that the average particle diameter of the oil droplets and / or the amount of the oil phase component further satisfy the following requirements when the log P value of the flavor material is (1) to (3) below.

(1)風味素材のlogP値が1未満である場合;
油滴の平均粒子径は、15μm以上(より好ましくは16μm以上、特に好ましくは17μm以上)であり、且つ、油相成分量は、食品全量に対して0.05%(v/v)以上(より好ましくは0.07%(v/v)以上、特に好ましくは0.1%(v/v)以上)であることが好ましい。
(1) When the log P value of the flavor material is less than 1;
The average particle diameter of the oil droplets is 15 μm or more (more preferably 16 μm or more, particularly preferably 17 μm or more), and the amount of the oil phase component is 0.05% (v / v) or more with respect to the total amount of food ( More preferably, it is 0.07% (v / v) or more, particularly preferably 0.1% (v / v) or more.

(2)風味素材のlogP値が1以上3未満である場合;
油滴の平均粒子径は、15μm以上(より好ましくは16μm以上、特に好ましくは17μm以上)であり、且つ/又は、油相成分量は、食品全量に対して、0.5%(v/v)以上(より好ましくは0.7%(v/v)以上、特に好ましくは1%(v/v)以上)であることが好ましい。
また、油滴の平均粒子径は、15μm以上(より好ましくは16μm以上、特に好ましくは17μm以上)であり、且つ、油相成分量は、食品全量に対して、0.5%(v/v)以上(より好ましくは0.7%(v/v)以上、特に好ましくは1%(v/v)以上)であることが更に好ましい。
(2) When the log P value of the flavor material is 1 or more and less than 3;
The average particle diameter of the oil droplets is 15 μm or more (more preferably 16 μm or more, particularly preferably 17 μm or more), and / or the amount of the oil phase component is 0.5% (v / v) with respect to the total amount of food. ) Or more (more preferably 0.7% (v / v) or more, particularly preferably 1% (v / v) or more).
The average particle diameter of the oil droplets is 15 μm or more (more preferably 16 μm or more, particularly preferably 17 μm or more), and the amount of the oil phase component is 0.5% (v / v) with respect to the total amount of food. ) Or more (more preferably 0.7% (v / v) or more, particularly preferably 1% (v / v) or more).

(3)風味素材のlogP値が3以上である場合;
油滴の平均粒子径は、15μm以上(より好ましくは16μm以上、特に好ましくは17μm以上)であり、且つ/又は、油相成分量は、食品全量に対して、0.05%(v/v)以上(より好ましくは0.07%(v/v)以上、特に好ましくは0.1%(v/v)以上)であることが好ましい。
また、油滴の平均粒子径は、15μm以上(より好ましくは16μm以上、特に好ましくは17μm以上)であり、且つ、油相成分量は、食品全量に対して、0.05%(v/v)以上(より好ましくは0.07%(v/v)以上、特に好ましくは0.1%(v/v)以上)であることが更に好ましい。
(3) When the log P value of the flavor material is 3 or more;
The average particle diameter of the oil droplets is 15 μm or more (more preferably 16 μm or more, particularly preferably 17 μm or more), and / or the amount of the oil phase component is 0.05% (v / v) with respect to the total amount of food. ) Or more (more preferably 0.07% (v / v) or more, particularly preferably 0.1% (v / v) or more).
The average particle diameter of the oil droplets is 15 μm or more (more preferably 16 μm or more, particularly preferably 17 μm or more), and the amount of the oil phase component is 0.05% (v / v) with respect to the total amount of food. ) Or more (more preferably 0.07% (v / v) or more, particularly preferably 0.1% (v / v) or more).

本発明において「logP値」とは、オクタノール/水分配係数の対数値を意味し、JIS規格(JIS Z7260−107、JIS Z7260−117)に規定される方法によって測定される。   In the present invention, the “log P value” means a logarithmic value of an octanol / water partition coefficient, and is measured by a method defined in JIS standards (JIS Z7260-107, JIS Z7260-117).

油滴の平均粒子径が15μm以上80μm以下(好ましくは、17μm以上60μm以下)、且つ、油相成分量が食品全量に対して0.05%(v/v)以上10%(v/v)以下(好ましくは、0.1%(v/v)以上1%(v/v)以下)であると、風味素材のlogP値にかかわらず、食品に持続性のある風味を付与でき好ましい。   The average particle diameter of the oil droplets is 15 μm or more and 80 μm or less (preferably 17 μm or more and 60 μm or less), and the oil phase component amount is 0.05% (v / v) or more and 10% (v / v) with respect to the total amount of food. The following (preferably 0.1% (v / v) or more and 1% (v / v) or less) is preferable because the food can be provided with a sustainable flavor regardless of the logP value of the flavor material.

本発明の乳化組成物が添加される食品は特に制限されないが、例えば、スープ類(例、鶏がらスープ、コンソメスープ、野菜スープ、中華スープ等)、シチュー類、ドレッシング類、だし、調味料等が挙げられ、好ましくはスープ類であり、より好ましくは鶏がらスープ及びコンソメスープである。
本発明において「食品」とは、経口摂取し得るものを広く包含する概念であり、飲料等も含まれる。
The food to which the emulsified composition of the present invention is added is not particularly limited. For example, soups (eg, chicken broth soup, consomme soup, vegetable soup, Chinese soup, etc.), stews, dressings, dashi, seasonings, etc. And preferably soups, more preferably chicken soup and consomme soup.
In the present invention, “food” is a concept that broadly encompasses those that can be taken orally, and includes beverages and the like.

本発明の乳化組成物を食品に添加する時期は特に制限されず、例えば、食品の喫食前に添加できる。また喫食の直前や、喫食中に添加してもよい。あるいは、食品を調理又は製造する間に、その原料と併せて添加してもよい。   There is no particular limitation on the timing of adding the emulsified composition of the present invention to food, and for example, it can be added before eating food. Further, it may be added immediately before eating or during eating. Or you may add together with the raw material during cooking or manufacturing food.

本発明の方法により、持続性のある風味が付与された食品を提供できる。本発明において、「持続性のある」風味とは、食品を嚥下し、口を閉じて5回呼吸したとき、5回目の呼気中に感じられる風味をいう。   By the method of this invention, the foodstuff with the persistent flavor can be provided. In the present invention, the “persistent” flavor refers to a flavor felt during the fifth exhalation when the food is swallowed, the mouth is closed, and breathing is performed five times.

2.本発明の食品
本発明の食品は、所定の液状水中油型乳化組成物を含むことを特徴の一つとする。本発明の食品は、当該乳化組成物を含むことにより、持続性のある風味を有することができる。
2. Food of the present invention The food of the present invention includes a predetermined liquid oil-in-water emulsion composition. The foodstuff of this invention can have a lasting flavor by including the said emulsion composition.

本発明の食品が含む乳化組成物は、上述の本発明の方法において用いられる「本発明の乳化組成物」と同様のものであり、充足すべき要件や好適な態様等も同様である。   The emulsion composition contained in the food of the present invention is the same as the “emulsion composition of the present invention” used in the above-mentioned method of the present invention, and the requirements to be satisfied and the preferred embodiments are also the same.

本発明の食品の種類は特に制限されず、その具体例としては、本発明の方法の説明において例示した食品と同様のものが挙げられ、好適な態様も同様である。   The kind in particular of the foodstuff of this invention is not restrict | limited, As the specific example, the thing similar to the foodstuff illustrated in description of the method of this invention is mentioned, A suitable aspect is also the same.

本発明の食品は、自体公知の方法で調製された食品に、本発明の乳化組成物を添加することにより製造できる。   The food of the present invention can be produced by adding the emulsion composition of the present invention to a food prepared by a method known per se.

以下の実施例において本発明を更に具体的に説明するが、本発明はこれらの例によってなんら限定されるものではない。   The present invention will be described more specifically in the following examples, but the present invention is not limited to these examples.

[試験例1]logP値、油相成分量、平均粒子径の検討
(評価サンプルの調製)
異なるlogP値を有する5種の風味素材を選定し、各風味素材を油滴中に含み、油滴の平均粒子径が0.15〜60μmである液状水中油型乳化組成物を調製した後、これらを所定の呈味溶液に添加して、乳化組成物の油相成分量がサンプル全量に対して0.01〜10%(v/v)である評価サンプルを調製した。
使用した5種の風味素材を下表1に示す。
[Test Example 1] Examination of log P value, oil phase component amount, average particle size (preparation of evaluation sample)
After selecting five flavor materials having different log P values, including each flavor material in the oil droplets, and preparing a liquid oil-in-water emulsion composition in which the average particle size of the oil droplets is 0.15 to 60 μm, These were added to a predetermined taste solution to prepare an evaluation sample in which the amount of the oil phase component of the emulsion composition was 0.01 to 10% (v / v) based on the total amount of the sample.
The five flavor materials used are shown in Table 1 below.

Figure 0006303719
Figure 0006303719

乳化組成物は、風味素材を食用油脂(製品名:さらさらキャノーラ油、味の素社製)に所定の濃度で添加して調製した風味素材添加油と、乳化剤(商品名:エマゾールO−120V、花王社製、HLB:15)を所定の濃度で含む乳化剤水溶液とを、所定の混合比率で混合した後、所定の乳化条件で乳化処理を施すことにより調製した。
風味素材添加油中の風味素材の濃度、乳化剤水溶液中の乳化剤の濃度、及び風味素材添加油と乳化剤水溶液との混合比率(風味素材添加油と乳化剤水溶液との合計量に対する、風味素材添加油の量の割合)を、それぞれ「油中風味素材濃度」、「乳化剤濃度」及び「油混合比率」として、下表2及び3に示す。表2は、風味素材としてメチオナール、イソ吉草酸又は1−オクテン−3−オールを使用した場合の各濃度及び比率を示し、表3は、風味素材としてオクタン酸又はデカン酸を使用した場合の各濃度及び比率を示す。尚、各表中の「油相成分量」は、最終的に調製される評価サンプル全量に対する、乳化組成物の油相成分の割合である。
The emulsified composition comprises a flavor material-added oil prepared by adding a flavor material to edible fats and oils (product name: Sarasara Canola Oil, Ajinomoto Co., Inc.) and an emulsifier (trade name: Emazole O-120V, Kao Corporation). An aqueous emulsifier solution containing HLB: 15) manufactured at a predetermined concentration was mixed at a predetermined mixing ratio and then emulsified under predetermined emulsification conditions.
The concentration of the flavor material in the flavor material-added oil, the concentration of the emulsifier in the aqueous emulsifier solution, and the mixing ratio of the flavor material-added oil and the emulsifier solution (the amount of the flavor material-added oil relative to the total amount of the flavor material-added oil and the emulsifier solution) The ratios of the amounts are shown in Tables 2 and 3 below as “flavor material concentration in oil”, “emulsifier concentration” and “oil mixing ratio”, respectively. Table 2 shows each concentration and ratio when methional, isovaleric acid or 1-octen-3-ol is used as a flavor material, and Table 3 shows each case when octanoic acid or decanoic acid is used as a flavor material. Concentrations and ratios are shown. The “oil phase component amount” in each table is the ratio of the oil phase component of the emulsion composition to the total amount of the evaluation sample finally prepared.

Figure 0006303719
Figure 0006303719

Figure 0006303719
Figure 0006303719

また、油滴の平均粒子径及び乳化条件(乳化装置、pass回数、その他の条件)を、下表4に示す。   The average particle diameter of oil droplets and emulsification conditions (emulsification device, number of passes, other conditions) are shown in Table 4 below.

Figure 0006303719
Figure 0006303719

油滴の平均粒子径として、レーザー回折粒度分布測定装置(LA−920、株式会社堀場製作所製、攪拌速度:3)を用いてメジアン径を測定した。   As the average particle diameter of the oil droplets, the median diameter was measured using a laser diffraction particle size distribution measuring device (LA-920, manufactured by Horiba, Ltd., stirring speed: 3).

所定の呈味溶液への液状水中油型乳化組成物の添加は、下表5に示す割合で行った。尚、必要により乳化剤水溶液も添加した。   The liquid oil-in-water emulsion composition was added to the predetermined taste solution at the ratio shown in Table 5 below. If necessary, an aqueous emulsifier solution was also added.

Figure 0006303719
Figure 0006303719

所定の呈味溶液の組成は、下表6に示す通りである。   The composition of the predetermined taste solution is as shown in Table 6 below.

Figure 0006303719
Figure 0006303719

以上の手順で製造された評価サンプル中の風味素材の濃度は、風味素材がメチオナール、イソ吉草酸又は1−オクテン−3−オールである場合、10ppm(v/v)であり、風味素材がオクタン酸又はデカン酸である場合、20ppm(v/v)であった。また評価サンプル中の乳化剤の濃度は、0.50%(v/v)であった。   The concentration of the flavor material in the evaluation sample produced by the above procedure is 10 ppm (v / v) when the flavor material is methional, isovaleric acid or 1-octen-3-ol, and the flavor material is octane. In the case of acid or decanoic acid, it was 20 ppm (v / v). The concentration of the emulsifier in the evaluation sample was 0.50% (v / v).

(持続性のある風味の付与効果の評価)
持続性のある風味の付与効果の評価は、2名の専門評価パネルが、各評価サンプル10mlを嚥下した後、口を閉じて5回呼吸し、該5回目の呼気中に感じられる風味強度を評価することにより行った。
具体的には、未乳化の組成物を添加したコントロール(呈味溶液に、風味素材添加油及び乳化剤水溶液を単に添加したもの)の風味の持続性を1とした5段階の評価基準(下記)により、風味の持続性を評価した。
[評価基準]
5:非常に持続性の高い風味が確認された
4:持続性の高い風味が確認された
3:持続性のやや低い風味が確認された(コントロールよりは強い)
2:持続性の低い風味が確認された(コントロールよりは強い)
1:未乳化のコントロール(未乳化cont)
×:油の風味にマスキングされた
(−:評価サンプルなし)
(Evaluation of the effect of imparting persistent flavor)
The evaluation of the effect of imparting a sustainable flavor was conducted by two expert evaluation panels swallowing 10 ml of each evaluation sample, then closing their mouths and breathing 5 times to determine the flavor intensity felt during the fifth exhalation. This was done by evaluating.
Specifically, a five-stage evaluation standard with the flavor sustainability of 1 (as shown below) of the control to which the non-emulsified composition was added (the flavor solution added oil and the emulsifier aqueous solution was simply added to the taste solution) Based on this, the sustainability of the flavor was evaluated.
[Evaluation criteria]
5: A very long-lasting flavor was confirmed. 4: A long-lasting flavor was confirmed. 3: A slightly low-savory flavor was confirmed (stronger than the control).
2: Low persistent flavor was confirmed (stronger than control)
1: Non-emulsified control (non-emulsified cont)
×: Masked by oil flavor (-: No evaluation sample)

結果を図1〜5に示す。   The results are shown in FIGS.

図1〜5に示される結果から明らかなように、風味素材のlogP値によって、持続性のある風味が得られる油滴の平均粒子径及び油相成分量の範囲は、3種(例、風味素材のlogP値が(1)1未満である場合、(2)1以上3未満である場合、(3)3以上である場合)に分けられた。風味素材のlogP値が大きい程、持続性のある風味が得られる油滴の平均粒子径及び油相成分量の範囲は広い結果となった。   As is apparent from the results shown in FIGS. 1 to 5, the range of the average particle diameter and the amount of the oil phase component of the oil droplets from which a sustainable flavor can be obtained depends on the log P value of the flavor material (for example, flavor) The log P value of the material was (1) less than 1, (2) 1 to less than 3, and (3) 3 or more). The larger the log P value of the flavor material, the wider the range of the average particle diameter and the amount of oil phase component of the oil droplets with which a sustained flavor can be obtained.

[試験例2]乳化剤のHLBの検討
(評価サンプルの調製)
乳化剤(商品名:エマゾールO−120V、花王社製、HLB:15)を下表7に示す各乳化剤に変更した以外は、上記試験例1と同様の手順により評価サンプルを調製した。風味素材には、1−オクテン−3−オールを使用した。また油滴の平均粒子径は17μmに調整し、乳化組成物の油相成分量は、評価サンプル全量に対して1%(v/v)に調整した。
[Test Example 2] Examination of HLB of emulsifier (preparation of evaluation sample)
An evaluation sample was prepared by the same procedure as in Test Example 1 except that the emulsifier (trade name: Emazole O-120V, manufactured by Kao Corporation, HLB: 15) was changed to each emulsifier shown in Table 7 below. 1-octen-3-ol was used as a flavor material. The average particle diameter of the oil droplets was adjusted to 17 μm, and the amount of the oil phase component of the emulsion composition was adjusted to 1% (v / v) with respect to the total amount of the evaluation sample.

(持続性のある風味の付与効果の評価)
上記試験例1と同様の方法及び評価基準により、持続性のある風味の付与効果の評価を行った。
(Evaluation of the effect of imparting persistent flavor)
By the same method and evaluation criteria as in Test Example 1, the effect of imparting a sustainable flavor was evaluated.

結果を表7に示す。   The results are shown in Table 7.

Figure 0006303719
Figure 0006303719

表7に示される結果から明らかなように、いずれの乳化剤を使用した場合も一定の効果を奏することが確認されたが、HLBが高い乳化剤(例、HLBが11〜16である乳化剤)を使用したときの効果が、より好適であった。   As is clear from the results shown in Table 7, it was confirmed that any emulsifier used had a certain effect, but an emulsifier having a high HLB (eg, an emulsifier having an HLB of 11 to 16) was used. The effect when doing was more suitable.

[試験例3]鶏がらスープ及びコンソメスープにおける効果の評価
(評価サンプルの調製)
下表8に示す4種の風味素材(鶏だしの風味素材)の混合物を、食用油脂(製品名:さらさらキャノーラ油、味の素社製)に各風味素材の濃度が表8に示す通りになるよう添加して調製した風味素材添加油5mlと、1%(v/v)乳化剤水溶液(乳化剤の製品名:エマゾールO−120V、花王社製)45mlとを混合した後、所定の乳化条件で乳化処理を行い、風味素材を油滴中に含む液状水中油型乳化組成物(以下、風味素材添加乳化組成物という)を調製した。当該風味素材添加乳化組成物に含まれる油滴の平均粒子径は、17μmであった。
[Test Example 3] Evaluation of effects in chicken broth soup and consomme soup (preparation of evaluation sample)
The mixture of the four flavor materials (chicken stock flavor materials) shown in Table 8 below is used as an edible oil (product name: Sarasara Canola Oil, Ajinomoto Co., Inc.) so that the concentration of each flavor material is as shown in Table 8. 5 ml of flavor material added oil prepared by addition and 45 ml of 1% (v / v) emulsifier aqueous solution (product name of emulsifier: Emazole O-120V, manufactured by Kao Corporation) are mixed and then emulsified under predetermined emulsification conditions. And a liquid oil-in-water emulsion composition (hereinafter referred to as a flavor material-added emulsion composition) containing a flavor material in oil droplets was prepared. The average particle diameter of the oil droplets contained in the flavor material-added emulsion composition was 17 μm.

Figure 0006303719
Figure 0006303719

乳化条件(乳化装置、ポアサイズ、pass回数)を、下表9に示す。   The emulsifying conditions (emulsifying device, pore size, number of passes) are shown in Table 9 below.

Figure 0006303719
Figure 0006303719

また、風味素材を使用しなかったこと以外は上記と同様の手順で、風味素材を含まない液状水中油型乳化組成物(以下、風味素材無添加乳化組成物という)を調製した。   Moreover, the liquid oil-in-water type emulsion composition (henceforth a flavor material additive-free emulsion composition) which does not contain a flavor raw material was prepared in the same procedure as the above except not using the flavor raw material.

風味素材無添加乳化組成物、上記の風味素材添加油、及び風味素材添加乳化組成物を、鶏がらスープ(「丸鶏がらスープ」(製品名、味の素社製)の1.5%水溶液)にそれぞれ下表10に示す量で添加し、評価サンプルA〜Cを調製した。風味素材無添加乳化組成物、風味素材添加油、及び風味素材添加乳化組成物に含まれる食用油脂の量は、評価サンプル全量(100.1ml又は101ml)に対し、約0.1%(v/v)である。   Add flavor material-free emulsified composition, flavor material-added oil, and flavor material-added emulsified composition to chicken garage soup (1.5% aqueous solution of Maru chicken garage soup (product name, manufactured by Ajinomoto Co., Inc.)) Each was added in the amounts shown in Table 10 below to prepare evaluation samples A to C. The amount of edible fats and oils contained in the flavor material-free emulsion composition, flavor material-added oil, and flavor material-added emulsion composition was about 0.1% (v / v) relative to the total amount of the evaluation sample (100.1 ml or 101 ml). v).

Figure 0006303719
Figure 0006303719

風味素材無添加乳化組成物、上記の風味素材添加油、及び風味素材添加乳化組成物を、コンソメスープ(「クノールチキンコンソメ」(製品名、クノール社製)の2%水溶液)にそれぞれ下表11に示す量で添加し、評価サンプルD〜Fを調製した。風味素材無添加乳化組成物、風味素材添加油、及び風味素材添加乳化組成物に含まれる食用油脂の量は、評価サンプル全量(100.1ml又は101ml)に対し、約0.1%(v/v)である。   Table 11 below shows the flavor material-free emulsion composition, the flavor material-added oil, and the flavor material-added emulsion composition in a consomme soup (2% aqueous solution of “Kunol Chicken Consomme” (product name, manufactured by Knorr)). Were added in the amounts shown in the above to prepare evaluation samples D to F. The amount of edible fats and oils contained in the flavor material-free emulsion composition, flavor material-added oil, and flavor material-added emulsion composition was about 0.1% (v / v) relative to the total amount of the evaluation sample (100.1 ml or 101 ml). v).

Figure 0006303719
Figure 0006303719

評価サンプルB、C、E及びFにおける、各風味素材の濃度(喫食時濃度)は、下表12に示す通りである。   The concentrations (flavor concentrations during eating) of the flavor materials in the evaluation samples B, C, E, and F are as shown in Table 12 below.

Figure 0006303719
Figure 0006303719

(持続性のある風味の付与効果の評価)
持続性のある風味の付与効果の評価は、2名の専門評価パネルが、各評価サンプル10mlを嚥下した後、口を閉じて5回呼吸し、該5回目の呼気中に感じられる風味強度を評価することにより行った。
具体的には、コントロール(乳化組成物等を添加されていない鶏がらスープ又はコンソメスープ)の風味強度を1とした5段階の評価基準(下記)により、風味の持続性(後伸び)を評価した。
[評価基準]
5:非常に持続性の高い風味が確認された
4:持続性の高い風味が確認された
3:持続性のやや低い風味が確認された(コントロールよりは強い)
2:持続性の低い風味が確認された(コントロールよりは強い)
1:コントロール
(Evaluation of the effect of imparting persistent flavor)
The evaluation of the effect of imparting a sustainable flavor was conducted by two expert evaluation panels swallowing 10 ml of each evaluation sample, then closing their mouths and breathing 5 times to determine the flavor intensity felt during the fifth exhalation. This was done by evaluating.
Specifically, the sustainability (post elongation) of the flavor was evaluated based on a five-level evaluation standard (below) with a flavor strength of 1 (control) (chicken soup or consomme soup not added with an emulsified composition). did.
[Evaluation criteria]
5: A very long-lasting flavor was confirmed. 4: A long-lasting flavor was confirmed. 3: A slightly low-savory flavor was confirmed (stronger than the control).
2: Low persistent flavor was confirmed (stronger than control)
1: Control

結果を表13(鶏がらスープ)及び表14(コンソメスープ)に示す。   The results are shown in Table 13 (chicken soup) and Table 14 (consomme soup).

Figure 0006303719
Figure 0006303719

Figure 0006303719
Figure 0006303719

表13及び14に示される結果から明らかなように、食品として鶏がらスープを使用した場合(表13)とコンソメスープを使用した場合(表14)とは、ほぼ同様の結果になった。
香料添加油を添加したサンプル(評価サンプルB及びE)は、風味素材の風味が、トップにのみ付与され、持続性のある風味は付与されなかった。
風味素材無添加乳化組成物を添加したサンプル(評価サンプルA及びD)では、鶏がらスープ又はコンソメスープそのものの風味が少し伸びるようになったことが確認された。
風味素材添加乳化組成物を添加したサンプル(評価サンプルC及びF)では、鶏がらスープ又はコンソメスープの風味と風味素材の風味とが合わさり、全体として強い持続性のある風味が付与されたことが確認された。
As is apparent from the results shown in Tables 13 and 14, the results were almost the same when the chicken soup was used as the food (Table 13) and when the consomme soup was used (Table 14).
In the samples (evaluation samples B and E) to which the fragrance-added oil was added, the flavor of the flavor material was imparted only to the top, and the persistent flavor was not imparted.
In the samples (evaluation samples A and D) to which the flavor material-free added emulsion composition was added, it was confirmed that the flavor of the chicken broth soup or the consomme soup itself was slightly extended.
In the samples (evaluation samples C and F) to which the flavor material-added emulsion composition was added, the flavor of the chicken broth soup or consomme soup and the flavor of the flavor material were combined, giving a strong and sustained flavor as a whole. confirmed.

本発明によれば、持続性のある風味を食品に付与する方法を提供できる。
また本発明によれば、持続性のある風味を有する食品を提供できる。
According to the present invention, it is possible to provide a method for imparting a persistent flavor to food.
Moreover, according to this invention, the foodstuff which has a lasting flavor can be provided.

Claims (6)

風味素材を含み、平均粒子径が1.2μm以上80μm以下である油滴を含有する液状水中油型乳化組成物を食品に添加することを含み、
該乳化組成物の油相成分量は、該食品全量に対して10%(v/v)未満であり、
風味素材のlogP値が下記(1)〜(3)の各場合に、前記油滴の平均粒子径及び/又は前記油相成分量が、更に下記の要件を充足する、持続性のある風味の付与方法。
(1)風味素材のlogP値が1未満である場合;
油滴の平均粒子径が15μm以上、且つ、油相成分量が食品全量に対して0.05%(v/v)以上
(2)風味素材のlogP値が1以上3未満である場合;
油滴の平均粒子径が15μm以上、且つ/又は、油相成分量が食品全量に対して0.5%(v/v)以上
(3)風味素材のlogP値が3以上である場合;
油滴の平均粒子径が15μm以上、且つ/又は、油相成分量が食品全量に対して0.05%(v/v)以上
Adding a liquid oil-in-water emulsion composition containing oil droplets containing a flavor material and having an average particle size of 1.2 μm or more and 80 μm or less,
The amount of the oil phase component of the emulsion composition is less than 10% (v / v) based on the total amount of the food,
In each case where the log P value of the flavor material is the following (1) to (3), the average particle diameter of the oil droplets and / or the amount of the oil phase component further satisfies the following requirements. Grant method.
(1) When the log P value of the flavor material is less than 1;
When the average particle size of the oil droplets is 15 μm or more and the amount of the oil phase component is 0.05% (v / v) or more with respect to the total amount of food (2) The log P value of the flavor material is 1 or more and less than 3;
When the average particle diameter of oil droplets is 15 μm or more and / or the amount of oil phase components is 0.5% (v / v) or more with respect to the total amount of food (3) When the log P value of the flavor material is 3 or more;
The average particle size of oil droplets is 15 μm or more and / or the amount of oil phase components is 0.05% (v / v) or more with respect to the total amount of food.
油滴の平均粒子径が15μm以上80μm以下、且つ、油相成分量が食品全量に対して0.05%(v/v)以上10%(v/v)未満である、請求項1記載の方法。   The average particle diameter of oil droplets is 15 µm or more and 80 µm or less, and the amount of oil phase components is 0.05% (v / v) or more and less than 10% (v / v) with respect to the total amount of food. Method. 乳化組成物が、HLBが10以上である乳化剤を含有する、請求項1又は2記載の方法。   The method according to claim 1 or 2, wherein the emulsified composition contains an emulsifier having an HLB of 10 or more. 請求項1〜3のいずれか1項に記載の方法によって持続性のある風味が付与された食品。   The foodstuff to which the lasting flavor was provided by the method of any one of Claims 1-3. 液状水中油型乳化組成物を含む食品であって、
該乳化組成物は、風味素材を含み、平均粒子径が1.2μm以上80μm以下である油滴を含有し、
該乳化組成物の油相成分量は、該食品全量に対して10%(v/v)未満であり、
風味素材のlogP値が下記(1)〜(3)の各場合に、前記油滴の平均粒子径及び/又は前記油相成分量が、更に下記の要件を充足する、食品。
(1)風味素材のlogP値が1未満である場合;
油滴の平均粒子径が15μm以上、且つ、油相成分量が食品全量に対して0.05%(v/v)以上
(2)風味素材のlogP値が1以上3未満である場合;
油滴の平均粒子径が15μm以上、且つ/又は、油相成分量が食品全量に対して0.5%(v/v)以上
(3)風味素材のlogP値が3以上である場合;
油滴の平均粒子径が15μm以上、且つ/又は、油相成分量が食品全量に対して0.05%(v/v)以上
A food comprising a liquid oil-in-water emulsion composition,
The emulsified composition contains a flavor material and contains oil droplets having an average particle size of 1.2 μm or more and 80 μm or less,
The amount of the oil phase component of the emulsion composition is less than 10% (v / v) based on the total amount of the food,
Food in which the average particle diameter of the oil droplets and / or the amount of the oil phase component further satisfy the following requirements when the log P value of the flavor material is the following (1) to (3).
(1) When the log P value of the flavor material is less than 1;
When the average particle size of the oil droplets is 15 μm or more and the amount of the oil phase component is 0.05% (v / v) or more with respect to the total amount of food (2) The log P value of the flavor material is 1 or more and less than 3;
When the average particle diameter of oil droplets is 15 μm or more and / or the amount of oil phase components is 0.5% (v / v) or more with respect to the total amount of food (3) When the log P value of the flavor material is 3 or more;
The average particle size of oil droplets is 15 μm or more and / or the amount of oil phase components is 0.05% (v / v) or more with respect to the total amount of food.
持続性のある風味を有する、請求項5記載の食品。   6. The food product according to claim 5, having a persistent flavor.
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