JP6382937B2 - 向上された材料特性を有する空気硬化性ベイナイト系鋼 - Google Patents
向上された材料特性を有する空気硬化性ベイナイト系鋼 Download PDFInfo
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- JP6382937B2 JP6382937B2 JP2016504346A JP2016504346A JP6382937B2 JP 6382937 B2 JP6382937 B2 JP 6382937B2 JP 2016504346 A JP2016504346 A JP 2016504346A JP 2016504346 A JP2016504346 A JP 2016504346A JP 6382937 B2 JP6382937 B2 JP 6382937B2
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- 229910000831 Steel Inorganic materials 0.000 title claims description 103
- 239000010959 steel Substances 0.000 title claims description 103
- 239000000463 material Substances 0.000 title description 9
- 229910001563 bainite Inorganic materials 0.000 claims description 71
- 238000001816 cooling Methods 0.000 claims description 55
- 238000010438 heat treatment Methods 0.000 claims description 32
- 238000005242 forging Methods 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 27
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 230000006698 induction Effects 0.000 claims description 11
- 239000012535 impurity Substances 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 238000009863 impact test Methods 0.000 claims description 2
- 238000010791 quenching Methods 0.000 description 21
- 230000000171 quenching effect Effects 0.000 description 19
- 230000008569 process Effects 0.000 description 18
- 238000005496 tempering Methods 0.000 description 16
- 229910000742 Microalloyed steel Inorganic materials 0.000 description 14
- 229910001562 pearlite Inorganic materials 0.000 description 12
- 238000003303 reheating Methods 0.000 description 12
- 229910000859 α-Fe Inorganic materials 0.000 description 11
- 238000003754 machining Methods 0.000 description 10
- 229910000734 martensite Inorganic materials 0.000 description 10
- 239000010936 titanium Substances 0.000 description 9
- 238000010586 diagram Methods 0.000 description 8
- 239000011572 manganese Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910001566 austenite Inorganic materials 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000011651 chromium Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 230000009466 transformation Effects 0.000 description 7
- 229910000851 Alloy steel Inorganic materials 0.000 description 6
- 238000005096 rolling process Methods 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 238000005275 alloying Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 229910001567 cementite Inorganic materials 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 150000001247 metal acetylides Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000004881 precipitation hardening Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
- C21D1/20—Isothermal quenching, e.g. bainitic hardening
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D7/00—Modifying the physical properties of iron or steel by deformation
- C21D7/13—Modifying the physical properties of iron or steel by deformation by hot working
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/005—Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2261/00—Machining or cutting being involved
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Articles (AREA)
- Forging (AREA)
Description
C:0.25〜0.40重量%、
Mn:1.50〜3.00重量%、
Si:0.30〜2.00重量%、
V:0.00〜0.15重量%、
Ti:0.02〜0.06重量%、
S:0.010〜0.04重量%、
N:0.0050〜0.0150重量%、
Cr:0.00〜1.00重量%、
Mo:0.00〜0.30重量%、
B:0.00〜0.005重量%、及び
残部としてFe及び不可避的不純物
を含む組成を有する鋼ビレットを提供するステップ;
前記鋼ビレットを約1150℃〜1350℃のオーステナイト化温度に加熱するステップ;
前記鋼ビレットを熱間鍛造して鋼部品を形成するステップ;及び
熱間鍛造後に前記鍛造鋼部品に対して制御空冷を行うステップを含む。
C:0.25〜0.40重量%、
Mn:1.50〜3.00重量%、
Si:0.30〜2.00重量%、
V:0.00〜0.15重量%、
Ti:0.02〜0.06重量%、
S:0.010〜0.04重量%、
N:0.0050〜0.0150重量%、
Cr:0.00〜1.00重量%、
Mo:0.00〜0.30重量%、
B:0.00〜0.003重量%、及び
残部としてFe及び不可避的不純物を含む組成を有し、また鋼部品全体にわたって50体積%超のベイナイト微細組織である微細組織を有する。
C:0.25〜0.40重量%、
Mn:1.50〜3.00重量%、
Si:0.30〜2.00重量%、
V:0.00〜0.15重量%、
Ti:0.02〜0.06重量%、
S:0.010〜0.04重量%、
N:0.0050〜0.0150重量%、
Cr:0.00〜1.00重量%、
Mo:0.00〜0.30重量%、
B:0.00〜0.003重量%、及び
残部としてFe及び不可避的不純物を含む化学組成、及び鋼部品全体にわたって50体積%超のベイナイト微細組織である微細組織を有するように製造され、前記鍛造鋼部品は、熱間鍛造、鍛造鋼部品全体にわたって50%超のベイナイトを有するベイナイト微細組織が生成されるように熱間鍛造後に行われる制御空冷、及び最終機械加工で製造される。
Claims (10)
- 鋼部品全体で50体積%超のベイナイト微細組織である微細組織を有する、鍛造鋼部品の製造方法であって、
C:0.25〜0.40重量%、
Mn:1.50〜3.00重量%、
Si:0.30〜2.00重量%、
V:0.00〜0.15重量%、
Ti:0.02〜0.06重量%、
S:0.010〜0.040重量%、
N:0.0050〜0.0150重量%、
Cr:0.00〜1.00重量%、
Mo:0.00〜0.30重量%、
B:0.00〜0.005重量%、及び
残部としてFe及び不可避的不純物
を含む組成を有する鋼ビレットを提供するステップ;
前記鋼ビレットを1150℃〜1350℃のオーステナイト化温度に加熱するステップ;
前記鋼ビレットを熱間鍛造して前記鋼部品を形成するステップ;及び
熱間鍛造後に前記鍛造鋼部品に対して制御空冷を行うステップを含む鍛造鋼部品の製造方法。 - 前記制御空冷は、該制御空冷後に前記鋼部品の胴体硬度が35〜45ロックウェルC硬度(HRC)となる速度で行われる請求項1に記載の鍛造鋼部品の製造方法。
- 前記制御空冷は、該制御空冷後に前記鋼部品の降伏強度が1000MPa超となる速度で行われる請求項1に記載の鍛造鋼部品の製造方法。
- 前記制御空冷は、前記鍛造鋼部品を周辺温度でコンベヤーに沿って移動させて行われる請求項1に記載の鍛造鋼部品の製造方法。
- 前記鋼ビレットの組成は、前記鍛造鋼部品に対する前記制御空冷及び異なる厚さを有する前記鍛造鋼部品のセクションの結果としての異なる冷却速度により、前記制御空冷後に前記鍛造鋼部品全体での微細組織が50体積%超のベイナイト微細組織になるように選択される請求項1に記載の鍛造鋼部品の製造方法。
- 前記鋼ビレットの組成は、前記鍛造鋼部品に対する前記制御空冷及び異なる厚さを有する前記鍛造鋼部品のセクションの結果としての異なる冷却速度により、前記制御空冷後に前記鍛造鋼部品全体での硬度水準が35〜45HRCより大きくなるように選択される請求項1に記載の鍛造鋼部品の製造方法。
- 前記制御空冷後に前記鋼部品の胴体の少なくとも内部の靱性がシャルピー衝撃試験により室温で20ジュール以上である請求項1に記載の鍛造鋼部品の製造方法。
- 前記鍛造鋼部品の選択された部分の硬度を増加させるために前記制御空冷後に該鍛造鋼部品の選択された部分を誘導加熱するステップをさらに含む請求項1に記載の鍛造鋼部品の製造方法。
- 前記誘導加熱後における前記鍛造鋼部品の選択された部分の硬度は50HRC超である請求項8に記載の鍛造鋼部品の製造方法。
- 空気硬化性ベイナイト系鋼部品であって、
C:0.25〜0.40重量%、
Mn:1.50〜3.00重量%、
Si:0.30〜2.00重量%、
V:0.00〜0.15重量%、
Ti:0.02〜0.06重量%、
S:0.010〜0.040重量%、
N:0.0050〜0.0150重量%、
Cr:0.00〜1.00重量%、
Mo:0.00〜0.30重量%、
B:0.00〜0.005重量%、及び
残部としてFe及び不可避的不純物を含む組成を有し、また鋼部品全体で50体積%超のベイナイト微細組織である微細組織を有する、空気硬化性ベイナイト系鋼部品。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/848,829 US20140283960A1 (en) | 2013-03-22 | 2013-03-22 | Air-hardenable bainitic steel with enhanced material characteristics |
US13/848,829 | 2013-03-22 | ||
PCT/US2014/031201 WO2014153398A1 (en) | 2013-03-22 | 2014-03-19 | Air-hardenable bainitic steel with enhanced material characteristics |
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Publication Number | Publication Date |
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JP2016518521A JP2016518521A (ja) | 2016-06-23 |
JP6382937B2 true JP6382937B2 (ja) | 2018-08-29 |
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JP2016504346A Active JP6382937B2 (ja) | 2013-03-22 | 2014-03-19 | 向上された材料特性を有する空気硬化性ベイナイト系鋼 |
Country Status (8)
Country | Link |
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US (2) | US20140283960A1 (ja) |
EP (1) | EP2976437B1 (ja) |
JP (1) | JP6382937B2 (ja) |
KR (1) | KR20150132320A (ja) |
CN (1) | CN105143474A (ja) |
AU (1) | AU2014235986B2 (ja) |
RU (1) | RU2015143271A (ja) |
WO (1) | WO2014153398A1 (ja) |
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- 2014-03-19 JP JP2016504346A patent/JP6382937B2/ja active Active
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US20140283960A1 (en) | 2014-09-25 |
RU2015143271A (ru) | 2017-04-27 |
KR20150132320A (ko) | 2015-11-25 |
WO2014153398A1 (en) | 2014-09-25 |
JP2016518521A (ja) | 2016-06-23 |
CN105143474A (zh) | 2015-12-09 |
EP2976437A4 (en) | 2016-12-14 |
EP2976437A1 (en) | 2016-01-27 |
US20150376750A1 (en) | 2015-12-31 |
AU2014235986A1 (en) | 2015-11-05 |
EP2976437B1 (en) | 2019-05-15 |
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