JP6219331B2 - Cosmetic preparation for makeup and makeup method - Google Patents

Description

The present invention relates to a cosmetic for remake that is very excellent in the remake effect of a makeup cosmetic. More specifically, the present invention does not require removal work such as cleansing or wiping off makeup cosmetics whose effects have been reduced by sweat, sebum, etc. over time after application, and further requires repainting and tingling of the base. The present invention relates to an emulsifying composition for re-dressing and a method for re-dressing that makes it possible to easily, quickly and cleanly re-make up.

Conventionally, various makeup cosmetics have been marketed for the purpose of expressing skin beautifully. However, makeup cosmetics are subject to makeup reversal due to sweat, sebum, etc. over time after application, and are forced to remake. Therefore, “retouching cosmetics” for the purpose of correcting makeup are generally used.

There are two main types of re-dressing methods. One is to remove the makeup makeup and the sebum that causes it, and then apply the makeup again, and the other is to apply a regular foundation over the makeup makeup. Is the method.

Cosmetics for re-dressing that are used when makeup is once removed and then re-applied are those that have a cleansing effect that removes makeup cosmetics that have collapsed, those that have both a cleansing effect and a base effect, and are applied again And the like using a film-forming agent having an effect of preventing the makeup cosmetics from being broken. As what has a cleansing effect, a cleansing sheet (refer patent document 1), a degreasing paper (refer patent document 2, patent document 3, and patent document 4) etc. are mentioned, for example. However, these have had to be applied with a base or foundation again after removal of the makeup makeup, and lacked convenience. Examples of those having both a cleansing effect and a base effect include those of an emulsification type (see Patent Document 5). These cosmetics do not require repainting of the undercoat after removal of the twisted makeup cosmetic. However, since the foundation had to be repainted afterwards, it was not convenient.

On the other hand, there is a powder type as a makeup retouching cosmetic that is applied over the makeup cosmetic that has been twisted (see Patent Document 6 and Patent Document 7). These products are designed to reduce the unevenness that tends to occur when the foundation is piled up, aiming for a natural finish. However, with these powder-type cosmetics for makeup retouching, makeup makeup that has collapsed on the skin, such as foundations that have fallen into skin grooves and pores, cannot be fully blended in, so makeup collapse is difficult to improve, The effect of re-dressing was insufficient. In addition, as a type to be applied over the makeup cosmetic, there is a powder type, but an emulsion type such as a liquid type or a cream type has not been used. The reason for this is that even if an emulsion type foundation is applied on top of a makeup cosmetic that has broken the emulsion type makeup, the makeup will deteriorate or become uneven. It was mentioned that it was originally unsuitable for makeup.

While it seems that it is difficult to remake using an emulsion type product, the idea to complete a beautiful remake by unfitting and spreading the broken makeup cosmetics has never been made before. .

The (dimethicone / vinyl dimethicone) crosspolymer, polymethylsilsesquioxane, and (HDI / trimethylolhexyllactone) crosspolymer used in the present invention have examples of incorporation into cosmetics. For example, a (dimethicone / vinyl dimethicone) crosspolymer is mainly used as an emulsifier, a touch modifier or the like. Polymethylsilsesquioxane and (HDI / trimethylol hexyl lactone) crosspolymer are also mainly used as a feeling improver for powder products, but the effect of remake is not known.

JP 2001-2528 A JP 2003-204824 A JP 2003-183125 A JP 2002-255737 A JP 2008-247785 A JP 2012-193128 A JP 2009-286733 A

That is, an object of the present invention is to provide an emulsifying composition for remake that can quickly and easily remake without removing makeup makeup, eliminating wrinkles, makeup floats, shine, etc. after make-up makeup. There is to do.

As a result of intensive investigations to provide an emulsifying composition for retouching that can make makeup cosmetics easier and more beautiful, the present inventors have obtained (dimethicone / vinyl dimethicone) crosspolymer, polymethylsilsesquioxane, (HDI / trimethylol hexyl lactone) The emulsion composition containing all of the crosspolymer is applied from above the makeup cosmetic that has already been twisted, so that it is fixed in a collapsed state by blending with the makeup cosmetic. It has been found that the bias of makeup cosmetics can be improved, makeup breakup is effectively improved, and remakeup is finished more neatly. That is, it has been found that makeup retouching is finished beautifully in a quick and simple operation without requiring removal of makeup cosmetics or application of new makeup cosmetics. In particular, it has been found that all the above problems can be solved, and the present invention has been completed.

That is, the present invention
The following components (A) to (C),
(A) (Dimethicone / vinyl dimethicone) cross polymer (B) Polymethylsilsesquioxane (C) (HDI / trimethylol hexyl lactone) cross polymer is provided. Is.

The emulsifying composition for retouching of the present invention is excellent in usability and feeling of use, and in particular, a retouching that can be quickly and neatly finished by a simple operation of applying from the top of a makeup cosmetic whose effect has been reduced over time. The present invention relates to an emulsified composition.

  Hereinafter, the present invention will be described in more detail.

The (dimethicone / vinyl dimethicone) crosspolymer of component (A) used in the present invention is a known compound, and can be used alone or in combination of two or more. Component (A) can be produced according to a conventional method. For example, after dealcohol condensation of dimethoxydimethylsiloxane and vinyldimethylmethoxysiloxane, addition polymerization is performed using a polymerization initiator such as azobisisobutyronitrile. Can be manufactured. In the present invention, it mainly contributes to suppressing the stickiness and pore conspicuousness after remake, but the combination of the component (B) and the component (C) is well-familiar with makeup cosmetics on the skin, Remake effect can be brought about.

As (A) (dimethicone / vinyl dimethicone) crosspolymer, there are generally powdery powders with different particle diameters and gelled ones obtained by swelling powder in silicone oil. The compounding is possible without particular limitation. Among these, those having a high soft focus effect, that is, having a high haze value and a property of diffusing light more are preferable from the viewpoint of finishing after retouching. Moreover, generally a commercial item can be mix | blended, and specifically, there exists KSG-016F, KSG-19 (made by Shin-Etsu Chemical Co., Ltd.), etc.

The blending amount of the (A) (dimethicone / vinyl dimethicone) cross polymer is preferably 0.15 to 1.6% by mass, more preferably 0.2 to 1.2% by mass in the emulsifying composition for retouching. Good. Since it blends well with the makeup cosmetics on the skin in this blending amount, it can be applied over the makeup cosmetics that have collapsed on the skin. In addition, it can sufficiently improve makeup collapse such as makeup makeup, floats, and shine, resulting in a good finish. However, if the blending amount is less than 0.15% by mass, it may not be well blended with the makeup cosmetics on the skin, so that the overcoating cannot be performed, and a sufficient retouching effect may not be exhibited. On the other hand, if the amount exceeds 1.6% by mass, the weight of the cosmetics will be increased and will not blend well with the makeup cosmetics on the skin, and the pores will be conspicuous and the finish will be insufficient. There is.

The component (B) polymethylsilsesquioxane used in the present invention is a spherical powder obtained by emulsion polymerization of methyltrimethoxysiloxane in an alkaline aqueous solution, and may be used alone or in combination of two or more. it can. In the present invention, it mainly contributes to suppressing the stickiness and pores conspicuous after remake, but it can be applied over the makeup cosmetics on the skin by combining with the components (A) and (C), Moreover, it is possible to bring about a good retouching effect.

As (B) polymethylsilsesquioxane, those generally blended into cosmetics are powdery and have different particle diameters, but can be blended without particular limitation. Among these, those having a spherical shape are more preferable from the viewpoint of finishing after retouching. In addition, it is generally possible to mix commercial products, such as Tospearl 145A (made by Momentive).

(B) As for the compounding quantity of polymethylsilsesquioxane, 1-14 mass% is preferable in the emulsification composition for makeup | decoration, More preferably, it is good that it is 5-13 mass%. In this blending amount, it can be used well with the make-up cosmetics on the skin, and it can sufficiently improve the makeup collapse and bring about a good remake effect. However, if the blending amount is less than 1% by mass, it becomes sticky, and the finish as a makeup retouch may be insufficient. On the other hand, if it exceeds 14% by mass, the cosmetic material is weighted, and it may not work well with the makeup cosmetic material on the skin.

The component (C) (HDI / trimethylol hexyl lactone) crosspolymer used in the present invention is a urethane resin obtained by powdering a polymer obtained by reacting trimethylolpropane and hexamethylene diisocyanate. Two or more species can be used in appropriate combination. In the present invention, it mainly contributes to the improvement of stickiness, but by combining with the components (A) and (B), it can be used well with the make-up cosmetics on the skin, and can provide a good remake effect. It is.

(C) (HDI / trimethylol hexyl lactone) crosspolymers are generally blended into cosmetics in powder form and have different particle diameters, but can be blended without particular limitation. Among these, a spherical shape is more preferable from the viewpoint of finishing. Moreover, generally a commercial item can be mix | blended and there exist plastic powder D-400 (made by Togo Pigment).

(C) The blending amount of (HDI / trimethylolhexyl lactone) crosspolymer is preferably 0.75 to 6% by mass, more preferably 2 to 5% by mass, in the emulsifying composition for makeup. In this blending amount, it can be applied over the makeup cosmetics on the skin at the time of remake, making it possible to make a simple and good finished remake. However, if the blending amount is less than 0.75% by mass, it becomes difficult to become familiar with the makeup cosmetics on the skin, and makeup collapse may not be sufficiently improved. On the other hand, if it exceeds 6% by weight, the cosmetics will be weighted and will not blend well with the makeup cosmetics on the skin. May not be improved.

The form of the present invention is good for an emulsified composition having an appropriate viscosity, and by taking this form, the makeup cosmetics that have collapsed on the skin, such as foundations that have fallen into skin grooves and pores, are sufficiently adapted. Is possible. Moreover, the function as makeup cosmetics can fully be given, and the outstanding effect as makeup cosmetics can be exhibited.

The emulsifying composition for retouching of the present invention can be stored in a container used in a paste-like, cream-like or gel-like product. Examples of containers include tubes, jars, bottles and the like.

The viscosity of the emulsifying composition for retouching of the present invention was measured using a B-type viscometer (VISCOMETER TVB-10, manufactured by Toki Sangyo Co., Ltd.) at 20 ° C. TF 3.0 rpm Under conditions of 3 minutes, 50,000 mPa · s or more and 300,000 mPa · s or less is preferable. Within this range, when applied to the skin, it is well-familiar with the makeup product and has a good stretch spread, so that the finish is beautiful and an appropriate feeling of adhesion can be obtained without stickiness.

The following examples further illustrate the present invention. In addition, these do not limit this invention at all. A compounding quantity is the mass% with respect to the composition whole quantity.

First, the evaluation method used in this example will be described.

[Evaluation method]
Have 5 skilled sensory evaluators make regular makeup in the morning and apply the emulsifying compositions for the makeup and makeup of the examples and comparative examples to the areas where the makeup, float and shine of the makeup cosmetics are worrisome. The coating was applied, and four levels of evaluation were performed according to the following evaluation criteria. Further, an average of five persons was taken and determined according to the following determination criteria. In addition, regarding the “finish”, three items were further provided, and each of the four grades was evaluated according to the following evaluation criteria. The average of the three items was taken, and the average of five people was further determined according to the following criteria.
[Evaluation item]
1. "Familiarity with make-up cosmetics on the skin"
2. "Improvement of makeup collapse"
3. "finish"
3-1. "Pore conspicuous"
3-2. "Sticky"
3-3. "Covering power"

Evaluation criteria for “Familiarity with Makeup Cosmetics on Skin”: In order to apply makeup on top of makeup cosmetics on the skin, first, the emulsifying composition for makeup rejuvenation must be applied to makeup cosmetics on the skin. You have to get used to it. Therefore, evaluation and determination were performed according to the following criteria.
<Evaluation criteria>
4 points: very familiar 3 points: familiar 2 points: not very familiar 1 point: unfamiliar

Criteria for “Familiarity with Makeup Cosmetics on Skin”:
<Criteria>
◎: 3.5 points or more ○: 2.5 points or more and less than 3.5 points ×: Less than 2.5 points

Evaluation criteria for "Improvement of makeup break-up": Whether the makeup, makeup, makeup, etc. caused by break-up of makeup cosmetics, such as foundations that have fallen into the crevice and pores, have been improved through re-makeup. Evaluation / determination was performed based on the above criteria.
<Evaluation criteria>
4 points: well improved 3 points: improved 2 points: not improved 1 point: not improved

Criteria for "Improvement of makeup loss":
<Criteria>
◎: 3.5 points or more ○: 2.5 points or more and less than 3.5 points ×: Less than 2.5 points

Judgment criteria for “finish”: It was determined by taking the average of the following three items to determine whether or not the re-makeup with the re-makeup composition produced a sufficient finish as a makeup cosmetic after re-makeup.
[Evaluation item]
3-1. "Pore conspicuous"
3-2. "Sticky"
3-3. "Covering power"
"Finish" criteria:
<Criteria>
◎: 3.5 points or more ○: 2.5 points or more and less than 3.5 points ×: Less than 2.5 points

Evaluation criteria of “pore conspicuity”: The pore conspicuity was evaluated based on the finish after retouching.
<Evaluation criteria>
4 points: inconspicuous 3 points: inconspicuous 2 points: slightly conspicuous 1 point: conspicuous

Evaluation criteria for “stickiness”: The stickiness after application was evaluated by the finish after retouching.
<Evaluation criteria>
4 points: smooth 3 points: non-sticky 2 points: slightly sticky 1 point: sticky

Evaluation criteria for “covering power”: It was evaluated whether there was sufficient covering power in the finish after retouching.
<Evaluation criteria>
4 points: Sufficient cover power 3 points: Cover power 2 points: Slight cover power is insufficient 1 point: Cover power is insufficient

As can be seen from Tables 1 and 2, the emulsifying compositions for retouching of the inventive products 1 to 9 of the present invention are: It was excellent in “familiarity with make-up cosmetics on the skin”, and by applying over the broken makeup cosmetics, the bias of the broken makeup cosmetics could be improved. In addition, 2. It was also excellent in "improving makeup breakup", and was able to improve makeup breakup such as twisting, lifting, and lighting by preparing makeup cosmetics on already broken skin. Furthermore, 3. It is also excellent in “finish” and brought a good finish as a makeup cosmetic. In other words, the emulsifying composition for retouching of the inventive products 1 to 9 of the present invention can be broken by applying over the makeup cosmetics on the skin that has already collapsed, such as foundations that have fallen into skin grooves and pores. Make-up cosmetics can be rearranged evenly on the skin, resulting in a good finish, enabling easy, quick and clean makeup. On the other hand, in Comparative Example 8 in which the component (A) was not blended, even when the cosmetic was overcoated, the skin did not fit well with the makeup cosmetic on the skin, and further twist occurred. In addition, the makeup collapse could not be improved, and the foundation that fell into the skin grooves and pores remained. Also, the finish as a makeup cosmetic was insufficient. In Comparative Example 5 in which the component (B) was not blended, the results of the familiarity with the makeup cosmetics on the skin and the improvement of the makeup collapse were good, but the finish was insufficient, especially in terms of stickiness and covering power It was not good. In Comparative Example 1 in which component (C) was not blended, the finish was good, but it did not fit well with the makeup cosmetics on the skin, and the makeup collapse could not be sufficiently improved.

<Example 3> Reconstitution emulsifying composition blending component Blending amount (% by mass)
1. Titanium oxide 6.5
2. Pigment 0.7
3. Zinc oxide 7.5
4). PEG-9 polydimethylsiloxyethyl dimethicone 3.5
5. Tocopherol 0.1
6). Cross-linked polyether-modified silicone mixture 0.5
7). Cross-linked methylpolysiloxane 0.8
8). Dimethicone 7.0
9. (HDI / trimethylol hexyl lactone) cross polymer 4.0
10. Polymethylsilsesquioxane 12.0
11. (Dimethicone / vinyl dimethicone) Cross polymer 0.2
12 Cyclopentasiloxane remaining amount 13. Isotridecyl isononanoate 6.0
14 Glycerin fatty acid ester 0.5
15. Glycerin 2.0
16.1,3-butylene glycol 1.0
17. Purified water 35.0
18. Moisturizer 1.0
Total 100

(Production method)
A: Components 1 to 12 are mixed and dispersed at 80 ° C.
B: Components 13 to 14 are dissolved at 80 ° C.
C: B is charged into A and cooled to 30 ° C.
D: Components 15 to 18 are mixed.
E: D was added to C and emulsified to obtain an emulsified composition.
This example is an emulsifying composition for retouching that is excellent in familiarity with makeup cosmetics on the skin, improvement in makeup collapse, and finish, and enables simple, quick and beautiful retouching.

<Example 10> Reconstitution emulsifying composition blending component Blending amount (% by mass)
1. PEG-9 polydimethylsiloxyethyl dimethicone 3.5
2. Tocopherol 0.1
3. Cross-linked polyether-modified silicone mixture 0.5
4). Cross-linked methylpolysiloxane 0.8
5. Dimethicone 12.6
6). (HDI / trimethylol hexyl lactone) cross polymer 6.0
7). Polymethylsilsesquioxane 12.0
8). (Dimethicone / Vinyl Dimethicone) Crosspolymer 1.6
9. Cyclopentasiloxane remaining amount 10. Isotridecyl isononanoate 6.0
11. Glycerin fatty acid ester 0.5
12 Glycerin 2.0
13.1,3-Butylene glycol 1.0
14 Purified water 35.0
15. Moisturizer 1.0
Total 100

(Production method)
A: Components 1 to 9 are mixed and dispersed at 80 ° C.
B: Components 10 to 11 are dissolved at 80 ° C.
C: B is charged into A and cooled to 30 ° C.
D: Components 12 to 15 are mixed.
E: D was added to C and emulsified to obtain an emulsified composition.
This example was well-familiar with the make-up cosmetics on the skin, and the rejuvenated make-up cosmetics were sufficiently rearranged, with good results.

Claims (2)

The following components (A) to (C),
(A) (Dimethicone / vinyl dimethicone) The amount of the cross polymer blended is 0.15 to 1.6% by mass.
(B) The blending amount of polymethylsilsesquioxane is 1 to 14% by mass.
(C) (HDI / trimethylol hexyl lactone) The amount of the cross polymer blended is 0.75 to 6% by mass.
An emulsifying composition for retouching, characterized by containing.
A makeup method in which makeup is removed by applying the emulsifying composition for makeup repair according to claim 1 from above the makeup cosmetic on the skin without removing the makeup cosmetic whose effect has been reduced over time.