JP6103193B2 - Double glazing - Google Patents

Description

  The present invention relates to a double glazing.

  General multilayer glass is constituted by separating at least two glass plates through a spacer and sealing the periphery with a sealing material.

  By the way, fire-proof and semi-fire-proof buildings (such as various buildings), which are positioned as buildings with high fire resistance, are obliged to install fire prevention equipment (fire doors, etc.) with flame-shielding performance in areas where there is a risk of spreading the outer wall opening. It has been.

  In addition, from the viewpoint of urban fire prevention, in fire prevention and semi-fire prevention areas, buildings other than fire-resistant and semi-fire-resistant buildings (such as detached houses) are also equipped with fire prevention equipment with semi-flame-proofing performance at the part where the outer wall opening may spread. Installation is mandatory.

  Therefore, when using a double glazing for such an opening of the outer wall, it is necessary to have a certain fireproof performance.

  Conventionally, as a multi-layer glass having fireproof performance, at least one of the glass plates constituting the multi-layer glass uses a heat-resistant and fire-resistant glass plate such as netted glass, heat-resistant tempered glass, low expansion tempered glass, transparent crystallized glass, etc. Multilayer glass is known (for example, Patent Document 1).

  However, since the cost increases when using a heat-resistant and fire-proof glass plate, in Patent Document 2, the glass plate on the outdoor side is made of double-strength glass or plate glass having a lower thermal strengthening degree than double-strength glass, It has been proposed that the inner glass plate is made of a plate glass having a higher degree of thermal strengthening than double-strength glass. Moreover, in this patent document 2, the low radiation | emission comprised by the heat ray shielding laminated body (Low-E (Low Emissivity: low emission) film | membrane, a metal, and its oxide on the at least one surface of the glass plate which comprises a multilayer glass. It has been proposed to improve the fire protection performance.

  Similarly, Patent Document 3 proposes that a transparent film having a low emissivity is formed on at least one surface of a glass plate constituting a multilayer glass to improve fire prevention performance.

JP-A-8-67536 JP 2000-109349 A JP-A-8-40747

  By the way, normally, a Low-E film | membrane is provided to a multilayer glass for the purpose of improving the efficiency of indoor air conditioning. For this reason, use under a high temperature environment is not assumed, and there is a problem that the reflection performance of the heat rays deteriorates when heated at a high temperature for a long time. Therefore, there is a possibility that a sufficient improvement in fireproof performance cannot be expected only by applying a normal Low-E film to the multilayer glass.

  On the other hand, a Low-E film mainly composed of tin oxide is also known as a Low-E film having heat resistance, but the Low-E film mainly composed of tin oxide has low heat ray reflection performance (emissivity). However, there is a problem that improvement in heat insulation performance and heat insulation performance cannot be expected so much.

  This invention is made | formed in view of such a situation, and it aims at providing the multilayer glass excellent in fireproofing property, heat insulation, and heat insulation.

  Means for solving the above problems are as follows.

  The first aspect is a multi-layer glass configured such that a plurality of glass plates are spaced apart via a spacer and a peripheral edge portion is sealed with a sealing material, and at least one of the plurality of glass plates is A heat-resistant and low-emission film having a heat emissivity of 0.1 or less is formed on a surface that is made of a glass plate that is not a fireproof glass plate and faces at least one other glass plate among a plurality of glass plates. This is a double-glazed glass characterized by that.

  According to this aspect, at least one glass plate among the plurality of glass plates constituting the multilayer glass is constituted by a glass plate that is not a fireproof glass plate. A heat-resistant and low-emission film (a low-emission film having heat resistance and an emissivity of 0.1 or less) is formed on the surface of the plurality of glass plates facing at least one other glass plate. Thereby, even if it is a case where the glass plate which is not a fire prevention glass plate is used, fire prevention performance can be acquired. That is, by forming a film (heat resistant low radiation film) that maintains high heat ray reflection performance without deterioration even in a high temperature environment on at least one surface, it is farther than this heat resistant low radiation film from the heating surface. It is possible to make it difficult to transmit heat to the glass plate, and it is possible to prevent the glass plate from being broken by heat. Thereby, a predetermined fireproof performance can be obtained. In addition, the heat-resistant and low-radiation film is formed on the surface facing at least one other glass plate among the plurality of glass plates, that is, the surface disposed on the inner side (intermediate layer side). Can be prevented from being damaged or peeled off.

  A 2nd aspect is an aspect by which at least 1 sheet | seat is comprised with a fire prevention glass board among the several glass plates in the multilayer glass of the said 1st aspect.

  According to this aspect, at least one of the plurality of glass plates constituting the multilayer glass is constituted by the fireproof glass plate. Thereby, fireproof performance can be improved further.

  A 3rd aspect is an aspect by which all the glass plates of a multilayer glass of the said 1st aspect are comprised with the glass plate which is not a fire prevention glass plate.

  According to this aspect, all of the plurality of glass plates constituting the multilayer glass are constituted by glass plates that are not fire glass plates. Thereby, fireproof performance can be provided, suppressing cost.

  A 4th aspect is an aspect in which the heat-resistant low radiation film | membrane has a silver layer in the multilayer glass of any one aspect of the said 1st to 3rd.

  According to this aspect, the heat resistant low radiation film has a silver layer. That is, the heat-resistant and low radiation film is mainly composed of silver (Ag). By forming a heat-resistant and low radiation film mainly composed of silver, high heat ray reflection performance (emissivity of 0.1 or less) can be obtained.

  A fifth aspect is the multi-layer glass of the fourth aspect, wherein the heat-resistant and low-radiation film is laminated in the order of an oxide dielectric layer, a barrier layer, a silver layer, a barrier layer, and an oxide dielectric layer. The barrier layer is made of metal, and the thickness of the barrier layer is 2 nm or more.

  According to this aspect, the heat-resistant and low-emission film is composed of a laminated body in which an oxide dielectric layer, a barrier layer, a silver layer, a barrier layer, and an oxide dielectric layer are laminated in this order. The barrier layer is made of metal, and the barrier layer has a thickness of 2 nm or more. In a low-emission film configured such that the silver layer is sandwiched between oxide dielectric layers, a metal barrier layer is interposed between the silver layer and the oxide dielectric layer, so that the oxidation of silver can be suppressed and the heat ray reflection performance is improved. Deterioration can be prevented. Further, the heat resistance can be improved by increasing the thickness of the metal barrier layer. As the metal constituting the barrier layer, for example, a zinc alloy (Zn alloy) or titanium (Ti) can be used.

  According to a sixth aspect, in the multilayer glass of the fourth aspect, the heat-resistant and low-emission film is laminated in the order of a non-oxide dielectric layer, a barrier layer, a silver layer, a barrier layer, and a non-oxide dielectric layer. It is the aspect comprised by the laminated body.

  According to this aspect, the heat-resistant and low-emission film is composed of a laminated body in which a non-oxide dielectric layer, a barrier layer, a silver layer, a barrier layer, and a non-oxide dielectric layer are laminated in this order. By using a low radiation film with a silver layer sandwiched between non-oxide dielectric layers, high heat resistance can be ensured while ensuring high heat ray reflection performance.

  A seventh aspect is an aspect in which the barrier layer is made of metal in the multilayer glass of the sixth aspect.

  According to this aspect, the barrier layer is made of metal. By forming the barrier layer from a metal, the heat resistance can be improved. As the metal constituting the barrier layer, for example, a zinc alloy (Zn alloy) or titanium (Ti) can be used.

  The eighth aspect is an aspect in which, in the multilayer glass of the sixth aspect, the barrier layer is made of the same material as that constituting the non-oxide dielectric layer.

  According to this aspect, the barrier layer is made of the same material as that constituting the non-oxide dielectric layer.

  A ninth aspect is an aspect having a plurality of silver layers in the multilayer glass of any one of the fourth to eighth aspects.

  According to this aspect, the heat-resistant and low-radiation film has a plurality of silver layers. Thereby, heat ray reflective performance can be improved more (emissivity can be reduced more).

  According to the present invention, fireproof performance can be obtained.

Sectional drawing which shows one Embodiment of multilayer glass The figure which shows the fire prevention performance of the multilayer glass in which the normal Low-E film | membrane was formed The figure which shows the fireproof performance of the multilayer glass in which the heat-resistant Low-E film | membrane was formed. The figure which shows the fire prevention performance of the multilayer glass in which the normal Low-E film | membrane was formed The figure which shows the fireproof performance of the multilayer glass in which the heat-resistant Low-E film | membrane was formed. Graph showing the temperature change of each glass plate Sectional drawing which shows other embodiment of a multilayer glass Sectional drawing which shows other embodiment of a multilayer glass

  Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

<< First Embodiment >>
FIG. 1 is a cross-sectional view showing an embodiment of a multilayer glass according to the present invention.

  As shown in the figure, the multi-layer glass 10 of the present embodiment is composed of two glass plates 12A and 12B that are opposed to each other with a certain distance.

  In the two glass plates 12A and 12B, one glass plate 12A is constituted by a “fireproof glass plate”, and the other glass plate 12B is constituted by a “glass plate that is not a fireproof glass plate”.

  Here, “fireproof glass” refers to plate glass that is one of the main materials constituting fireproof equipment approved by the Minister of Land, Infrastructure, Transport and Tourism, and is roughly divided into “sheet glass plate” and “heat-resistant plate glass”. .

  “Meshed plate glass” refers to a meshed glass plate defined by JIS R3204 (netted glass plate and lined glass plate).

  “Heat-resistant plate glass” refers to a plate glass defined by the “heat-resistant plate glass quality standard” established by the Association of Curtain Walls and Fire Protection Openings. The heat-resistant plate glass is a so-called single plate glass without a net, and there are three types of “low-expansion fireproof glass”, “heat-resistant tempered glass”, and “heat-resistant crystallized glass”.

  Both the flat sheet glass and the heat-resistant glass sheet are glass sheets having a flame shielding performance of 20 minutes or more by a test method according to the evaluation work method document of the designated performance evaluation organization approved by the Minister of Land, Infrastructure, Transport and Tourism.

  “A glass plate that is not a fireproof glass plate” refers to a glass plate other than the fireproof glass plate defined as described above. Therefore, in addition to ordinary float glass, tempered glass, double-strength glass, chemically tempered glass, and the like are included in the “glass plate that is not a fireproof glass plate”.

It should be noted that a glass plate having a strength increased by forming a compressive stress layer on the surface of the glass, such as tempered glass, double-strength glass, or chemically strengthened glass (the surface compressive stress of the glass is 20 [MN / m ² ] or more The glass plate) is not fire glass, but has a certain heat resistance. Therefore, in the present specification, these glass plates are referred to as “quasi-fire glass plates” and are distinguished from other glass plates among glass plates that are not fire glass plates.

  “Tempered glass” refers to glass defined by JIS R3206 (tempered glass), and “double strength glass” refers to glass defined by JIS R3222 (double strength glass). Further, “chemically tempered glass” refers to glass whose strength is increased by forming a compressive stress layer on the surface of the glass by a chemical tempering method.

In addition, among glass plates that are not fire-resistant glass plates, glass plates that are not semi-fire-resistant glass plates, that is, the surface of glass regardless of so-called wind-cooling strengthening method (also called physical strengthening method or heat strengthening method) or chemical strengthening method. For a glass plate that is not a glass plate having a strength increased by forming a compressive stress layer on it (in terms of glass surface compressive stress, a glass plate of less than 20 [MN / m ² ]), It is referred to as “non-fire-proof glass plate” and is distinguished from the semi-fire-proof glass plate among glass plates that are not fire-proof glass plates. This non-fireproof glass plate includes ordinary float glass and the like.

  As described above, in the multi-layer glass 10 of the present embodiment, one glass plate 12A is constituted by a “fire glass plate” and the other glass plate 12B is constituted by a “glass plate that is not a fire glass plate”. .

  The two glass plates 12 </ b> A and 12 </ b> B are spaced via the spacer 16 so that the intermediate layer 14 is formed therebetween. The spacer 16 is disposed along the periphery of the glass plates 12A and 12B so that the distance between the two glass plates 12A and 12B is kept constant.

  The surface of the spacer 16 facing the glass plates 12A and 12B is bonded to the glass plates 12A and 12B by the primary sealing materials 18A and 18B. Further, the secondary sealant 20 is filled outside the spacer 16 (on the side opposite to the intermediate layer 14). The secondary sealing material 20 is filled in a concave space formed between the spacer 16 and the two glass plates 12A and 12B, and is disposed in contact with the primary sealing materials 18A and 18B. The intermediate layer 14 is sealed (sealed) by the secondary sealing material 20 and the primary sealing materials 18A and 18B.

  The spacer 16 is formed in a hollow shape. Vent holes 22 are formed at a constant pitch along the longitudinal direction of the spacer 16 (the direction perpendicular to the paper surface) on the inner surface (on the intermediate layer 14 side) of the spacer 16. The vent hole 22 is formed so as to penetrate the hollow portion 24 of the spacer 16 and communicates the hollow portion 24 and the intermediate layer 14. The hollow portion 24 of the spacer 16 is filled with a desiccant 26 such as granular zeolite. Thereby, the air of the intermediate layer 14 is dried.

  As the spacer 16, a metal spacer mainly made of aluminum is used. However, when it is necessary to reduce the heat conduction in the periphery of the multilayer glass, stainless steel, which is a metal having a relatively low thermal conductivity, is used. It is preferable to use a material made of a material or a hard resin.

  Further, as the primary sealing materials 18A and 18B, butyl rubber which is not usually subjected to crosslinking treatment or a material based on polyisobutylene and containing a filler such as carbon black for the purpose of coloring and reinforcement is suitable.

  Further, as the secondary sealing material 20, a material based on a curable elastomer such as polysulfide, silicone, urethane, or the like, which has been appropriately modified in order to develop adhesiveness with glass, is suitable.

  The multi-layer glass 10 configured as described above has a heat-resistant Low-E film (heat-resistant low radiation film) 28 on the inner surface (surface on the intermediate layer side) of a glass plate 12B formed of a glass plate that is not a fireproof glass plate. It is formed. This heat-resistant Low-E film 28 has heat resistance, and Low-E whose vertical emissivity εn defined by JIS R3107 (a method for calculating the thermal resistance of sheet glass and the thermal conductivity of buildings) is 0.1 or less. A membrane (low emission membrane) is used.

  The heat-resistant Low-E film 28 is mainly composed of silver (Ag) so that the vertical emissivity εn is 0.1 or less. The heat resistant Low-E film mainly composed of silver (Ag) will be described in detail later.

  By providing such a heat-resistant Low-E film 28 on the inner surface (intermediate layer side) of a glass plate 12B made of a glass plate that is not a fireproof glass plate, a predetermined fireproof performance is imparted to the multilayer glass 10. Can do. That is, by providing such a heat-resistant Low-E film 28, when the glass plate 12A side becomes the fire side (heating side), the glass plate 12B (a glass plate constituted by a glass plate that is not a fireproof glass plate). ) Can be made difficult to transmit heat, and breakage of the glass plate 12B due to heat can be effectively prevented.

  FIG. 2A and FIG. 2B are diagrams for comparing fire resistance performance of a multilayer glass on which a normal Low-E film is formed and a multilayer glass on which a heat-resistant Low-E film is formed, and a heating curve based on ISO834 It shows a change in the state of each glass plate when heated for 20 minutes at (T = 345 log10 (8t + 1) +20, T: furnace temperature (° C.), t: time (minutes)).

  Note that FIG. 2A shows the fire performance of the multilayer glass on which a normal Low-E film is formed, and FIG. 2B shows the fire performance of the multilayer glass on which a heat-resistant Low-E film is formed.

  As shown in FIG. 2A, in the multilayer glass 10N on which a normal Low-E film is formed, one glass plate 12A is made of fireproof glass, and the other glass plate 12B is made of a non-fireproof glass plate. Moreover, the normal Low-E film | membrane 28N is formed in the inner surface (intermediate layer side) surface of the glass plate 12B comprised with a non-fireproof glass plate. Here, a low-E film (vertical emissivity of 0.1 or less) mainly composed of silver (Ag) and having no heat resistance is formed.

  As shown in FIG. 2B, in the multilayer glass 10R on which the heat-resistant Low-E film is formed, one glass plate 12A is made of fireproof glass, and the other glass plate 12B is made of a non-fireproof glass plate. Further, the heat-resistant Low-E film 28R is formed on the inner surface (intermediate layer side) of the glass plate 12B made of a non-fire-proof glass plate. That is, a low-E film (vertical emissivity of 0.1 or less) that is mainly composed of silver (Ag) and has heat resistance is formed.

  In both cases, since one glass plate 12A is composed of a fire-proof glass plate, even if it is heated from the fire-proof glass plate side, the fire-proof glass plate (glass plate 12A) does not have a flame within a certain time (20 minutes from the start of heating). There will be no damage such as cracks and gaps passing through.

  However, when heated, both of them are damaged by heat and the air enters the intermediate layer. When air enters the intermediate layer, the Low-E film deteriorates (silver (Ag) is oxidized) in the multi-layer glass 10N on which the normal Low-E film 28N is formed. Moreover, the homogeneity of the silver layer which comprises a Low-E film | membrane is impaired with a heat | fever, and the emissivity of a Low-E film | membrane changes (increases). As a result, the multi-layer glass 10N on which the normal Low-E film 28N is formed cannot reflect the heat transmitted to the glass plate 12B constituted by the non-fire-proof glass plate, and the glass plate 12B constituted by the non-fire-proof glass plate. May be damaged.

  On the other hand, in the multi-layer glass 10R formed with the heat-resistant Low-E film 28R, even if air enters the intermediate layer, the Low-E film has heat resistance. Can be maintained. Moreover, since the heat-resistant Low-E film 28R has high heat ray reflection performance (the vertical emissivity εn is 0.1 or less), it effectively blocks heat transmitted to the glass plate 12B composed of a non-fire-proof glass plate. (Reflection). Thereby, it can prevent that the glass plate 12B comprised with a non-fire prevention glass plate breaks. Therefore, when the glass plate 12B is broken, the flammable gas generated from the primary sealing materials 18A and 18B and the secondary sealing material 20 which are sealing materials leaks to the outside, and air is supplied to cause a flame on the non-heated surface side. Although it may occur, in the case of the multi-layer glass 10R, the glass plate 12B is not damaged, so there is no fear thereof.

  Thus, by forming the heat-resistant Low-E film, a predetermined fireproof performance can be obtained even for a multi-layer glass including a glass plate composed of a glass plate that is not a fireproof glass plate.

  In addition, in said example, although the case where a fireproof glass plate and a non-fireproof glass plate were combined was demonstrated, the same effect can be acquired also when combining a fireproof glass plate and a semi-fireproof glass plate.

<< Second Embodiment >>
In the said 1st Embodiment, in the multilayer glass comprised by two glass plates, one glass plate is comprised with a "fireproof glass plate", and the other glass plate is "a glass plate which is not a fireproof glass plate." ”Is described.

  In the present embodiment, a case will be described in which both glass plates are composed of “glass plates that are not fire-resistant glass plates”.

  In addition, except the point from which the structure of a glass plate differs, it is the same as the structure of the multilayer glass of 1st Embodiment mentioned above. Therefore, the description of the specific configuration of the multilayer glass is omitted.

  In the double-glazed glass of the present embodiment, in the double-glazed glass having the configuration shown in FIG. And the heat-resistant Low-E film | membrane 28 is formed in the inner side (intermediate monk side) surface of one glass plate 12B.

  As described above, even in the double-layer glass composed of both “glass plates that are not fire-proof glass plates”, the predetermined heat-proof performance can be obtained by forming the heat-resistant Low-E film 28 on the inner surface (intermediate layer side). Can be obtained. Hereinafter, this point will be described.

  FIG. 3A and FIG. 3B are diagrams for comparing fire resistance performance of a multilayer glass with a normal Low-E film and a multilayer glass with a heat-resistant Low-E film, and a heating curve in accordance with ISO834. The change of the state of each glass plate when heated for 20 minutes is shown.

  Note that FIG. 3A shows the fireproof performance of a multilayer glass on which a normal Low-E film is formed, and FIG. 3B shows the fireproof performance of the multilayer glass on which a heat-resistant Low-E film is formed.

  As shown in FIG. 3A, in the multilayer glass 10N on which the normal Low-E film 28N is formed, both the glass plates 12A and 12B are made of non-fire-proof glass plates. Further, a normal Low-E film 28N is formed on the inner side (intermediate layer side) of the non-heated glass plate 12B. Here, a low-E film (vertical emissivity of 0.1 or less) mainly composed of silver (Ag) and having no heat resistance is formed.

  As shown in FIG. 3B, both the glass plates 12A and 12B of the multi-layer glass 10R on which the heat-resistant Low-E film 28R is formed are formed of non-fire-proof glass plates. In addition, the heat-resistant Low-E film 28R is formed on the inner side (intermediate layer side) surface of the glass plate 12B on the non-heating side. That is, a low-E film (vertical emissivity of 0.1 or less) that is mainly composed of silver (Ag) and has heat resistance is formed.

  FIG. 4 is a graph schematically showing a temperature change of each glass plate.

  In both cases, the glass plate 12A on the heating side is composed of a non-fire-proof glass plate, so it breaks when a certain temperature difference occurs within the plane of the glass including the glass edge (points ● in FIG. 4). To do.

  In the multi-layer glass 10N on which the normal Low-E film 28N is formed, if the glass plate 12A on the heating side is damaged, the Low-E film immediately deteriorates. As a result, the temperature of the non-heating-side glass plate 12B rises rapidly immediately after the heating-side glass plate 12A is broken (see curve (4) in FIG. 4). And in this glass plate 12B on the non-heating side, the glass plate 12B on the non-heating side is damaged when a certain temperature difference or more in the plane of the glass including the glass edge occurs (point of ○ in FIG. 4). .

  On the other hand, in the multilayer glass 10R on which the heat-resistant Low-E film 28R is formed, even if the glass plate 12A on the heating side is broken, the Low-E film has heat resistance, so that a rapid temperature rise can be suppressed. (See curve (5) in FIG. 4). As a result, the breakage of the non-heated glass plate 12B can be extended for a certain period of time.

  As described above, by forming the heat-resistant Low-E film, a predetermined fireproof performance can be obtained even in a multi-layer glass composed of a glass plate that is not a fireproof glass plate.

  In addition, in the above example, the case where both of the non-fireproof glass plates are used to form the multilayer glass has been described, but when the non-fireproof glass and the semi-fireproof glass plate are combined, or both are made of the semi-fireproof glass The same effect can be obtained for.

<< Other Embodiments >>
<Mode of Forming Low-E Film on Each Glass Plate>
In the said embodiment, although the heat-resistant Low-E film | membrane is formed in the surface of one inner side (intermediate layer side) of the two glass plates which comprise a multilayer glass, as shown in FIG. The heat-resistant Low-E films 28A and 28B may be formed on the inside (intermediate layer side) surfaces of the glass plates 12A and 12B. Thereby, fireproof performance can be improved further.

  In addition, when forming a heat-resistant Low-E film | membrane only on one glass plate, it is preferable to form a heat-resistant Low-E film | membrane on the surface of the inner side (intermediate layer side) of the glass plate which is not a heating side (flame side).

  Moreover, when forming a Low-E film | membrane on both of two glass plates, it is good also considering either one as a heat-resistant Low-E film | membrane and the other as a normal Low-E film | membrane. In this case, it is preferable to form a heat-resistant Low-E film on the inner side (intermediate layer side) of the glass plate that is not on the heating side (flame side).

<Aspect of constituting a multilayer glass with three or more glass plates>
In the said embodiment, although the case where a multilayer glass was comprised with two glass plates was demonstrated to the example, application of this invention is not limited to this. Multi-layer glass can also be constituted by three or more glass plates. In this case, a heat-resistant Low-E film is formed on at least one surface on the inner side (intermediate layer side).

  FIG. 6 is a cross-sectional view of a multi-layer glass composed of three glass plates.

  As shown in the figure, the multilayer glass 10 is composed of three glass plates (a first glass plate 12A, a second glass plate 12B, and a third glass plate 12C).

  The first glass plate 12A and the second glass plate 12B are spaced apart via the first spacer 16A, and the second glass plate 12B and the third glass plate 12C replace the second spacer 16B. Spaced apart.

  Between the first glass plate 12A and the second glass plate 12B, a first intermediate layer 14A is formed, and between the second glass plate 12B and the third glass plate 12C, the second The intermediate layer 14B is formed.

  12 A of 1st glass plates are comprised with a fire prevention glass plate, and the 2nd glass plate 12B and the 3rd glass plate 12C are glass plates (semi-fire prevention glass plate or non-fire prevention glass plate) which are not a fire prevention glass plate. Composed.

  Further, the heat-resistant Low-E film 28 is formed on the inner side (intermediate layer side) surface of the third glass plate 12C.

  By forming the heat-resistant Low-E film 28, for example, even when the sealing is damaged by heat and air (oxygen) enters the second intermediate layer 14B, it is applied to the glass plate far from the heating surface. Heat can be made difficult to transfer, and the glass plate far from the heating surface can be delayed from being damaged by heat.

  In this example, the heat-resistant Low-E film is formed on the inner surface (intermediate layer side) of the third glass plate 12C, but the inner surface (the surface in contact with the intermediate layer, that is, the multilayer glass) As long as it is a surface that does not constitute the outer surface, it may be formed on any surface. However, it is preferably formed on the inner surface of the glass plate that is not the heating side (flame side) glass plate.

  Moreover, in this example, although the 1st glass plate 12A is comprised with the fire prevention glass plate, all the glass plates are comprised with the glass plate (semi-fire prevention glass plate or non-fire prevention glass plate) which is not a fire prevention glass plate. Also good.

<< Heat-resistant Low-E film >>
Generally, Low-E films include those mainly composed of tin oxide or indium oxide and those mainly composed of silver (Ag).

  Although the Low-E film mainly composed of tin oxide or indium oxide has an advantage of less deterioration due to heat, the original emissivity is high (the vertical emissivity εn is about 0.15 or more). The improvement of heat insulation cannot be expected so much, and the heat insulation during a fire cannot be expected. That is, a significant improvement in fireproof performance cannot be expected.

  On the other hand, Low-E film mainly composed of silver (Ag) has low emissivity (vertical emissivity εn is about 0.1 or less) and has excellent heat insulation and heat shielding properties. If the emissivity is maintained, breakage of the glass plate can be effectively prevented.

  Therefore, it is preferable to use a Low-E film (a Low-E film having a silver (Ag) layer) mainly composed of silver (Ag) as the Low-E film used as the heat-resistant Low-E film.

  On the other hand, since silver (Ag) is easily oxidized by heating and its performance is easily deteriorated, a structure capable of withstanding heat (a structure in which silver is not easily deteriorated by heat) is required.

  Examples of the low-E film mainly composed of silver (Ag) and having heat resistance include the following structures.

<First embodiment>
The first aspect is a laminate in which an oxide dielectric layer, a barrier layer, a silver layer, a barrier layer, and an oxide dielectric layer are laminated on a glass plate in this order, and the barrier layer is made of a metal. And the thickness of the barrier layer is an aspect comprised by 2 nm or more.

  By interposing a barrier layer between the silver layer and the oxide dielectric layer, the oxidation of silver can be suppressed and the heat ray reflection performance can be prevented from deteriorating. Moreover, heat resistance can be improved by comprising the barrier layer with a metal and increasing the thickness (2 nm or more).

  As the metal constituting the barrier layer, for example, a zinc alloy (Zn alloy), titanium (Ti), or the like can be used.

  When a metal barrier layer is provided with a normal Low-E film, a zinc alloy (Zn alloy) barrier layer has a thickness of about 0.7 nm, and a titanium (Ti) barrier layer has a thickness of about 1.5 nm. It is.

  The thickness of the barrier layer is preferably 2 nm or more, but if it is too thick, the permeability is lowered. Therefore, it is preferable to adjust the thickness in consideration of the permeability.

<Second embodiment>
A 2nd aspect is an aspect comprised by the laminated body laminated | stacked on the glass plate in order of the non-oxide dielectric layer, the barrier layer, the silver layer, the barrier layer, and the non-oxide dielectric layer.

  According to this aspect, by adopting a configuration in which the silver layer is sandwiched between the non-oxide dielectric layers, it is possible to suppress silver oxidation in a high temperature environment, and to ensure high heat resistance while ensuring high heat ray reflection performance. Can do.

  Here, as in the first embodiment, the heat resistance can be further enhanced by forming the barrier layer with a metal (such as zinc alloy (Zn alloy) or titanium (Ti)).

  In addition, the barrier layer can be made of the same material as that of the non-oxide dielectric layer.

<Other aspects>
A plurality of silver (Ag) layers constituting the heat-resistant Low-E film can be formed. By forming a plurality of silver (Ag) layers, the emissivity can be further reduced (εn << 0.1).

  For example, in the Low-E film having a structure in which the silver layer is sandwiched between the oxide dielectric layers as in the first aspect, the oxide dielectric layer, the barrier layer, the silver layer, the barrier layer, the oxide dielectric layer, A barrier layer, a silver layer, a barrier layer, and an oxide dielectric layer can be laminated on the glass plate in this order.

<Heat-resistant>
As described above, when the double-glazed glass is used for an outer wall opening of a fireproof / quasi-fireproof building, it is required to have a certain fireproof performance.

  Therefore, the heat resistance required for the heat-resistant Low-E film maintains the high heat ray reflection performance without deterioration even in a high temperature environment, and the fire resistance performance required for the multilayer glass is obtained when the multilayer glass is used. At least satisfactory heat resistance is required.

  DESCRIPTION OF SYMBOLS 10 ... Multi-layer glass, 10N ... Multi-layer glass in which normal Low-E film was formed, 10R ... Multi-layer glass in which heat-resistant Low-E film was formed, 12A ... Glass plate, 12B ... Glass plate, 12C ... Glass Plate 14 ... Intermediate layer 14A ... First intermediate layer 14B ... Second intermediate layer 16 ... Spacer 16A ... First spacer 16B ... Second spacer 18A ... Primary sealing material 18B ... Primary Sealing material 20 ... secondary sealing material 22 ... ventilation hole 24 ... hollow part 26 ... desiccant 28 ... heat-resistant Low-E film 28A ... heat-resistant Low-E film 28B ... heat-resistant Low-E film 28N ... Normal Low-E film, 28R ... Heat-resistant Low-E film

Claims (8)

A plurality of glass plates are spaced apart via a spacer, and a peripheral glass is a multi-layer glass constituted by sealing with a sealing material,
At least one of the plurality of glass plates is composed of a glass plate that is not a fireproof glass plate,
A heat resistant low radiation film having an emissivity of 0.1 or less having heat resistance is formed on a surface facing at least one other glass plate among the plurality of glass plates,
At least one of the plurality of glass plates is composed of a fireproof glass plate ,
The heat-resistant and low-radiation film is composed of a laminate in which a barrier layer, a silver layer, and a barrier layer are laminated in this order,
The multilayer glass, wherein the barrier layer is made of metal, and the thickness of the barrier layer is 2 nm or more .   The multilayer glass according to claim 1, wherein the heat-resistant and low-radiation film is formed on a glass plate that is not the fire-proof glass plate. Claims wherein the heat-resistant low-E film, the oxide dielectric layer, the barrier layer, the silver layer, the barrier layer is formed of a laminate are laminated in this order oxide dielectric layer, wherein the Turkey The multilayer glass according to 1 or 2 . Claims wherein the heat-resistant low-E film, non-oxide dielectric layer, the barrier layer, the silver layer, the barrier layer, characterized in that it is composed of non-oxide dielectric layer sequentially in the laminated the laminate Item 3. The multilayer glass according to Item 1 or 2 . The multilayer glass according to claim 4 , wherein the barrier layer is made of the same material as that of the non-oxide dielectric layer. Double glazing according to claim 1, any one of 5, characterized in that a plurality of the silver layer. The multilayer glass according to any one of claims 1 to 6 , wherein the plurality of glass plates are three or more glass plates. The multi-layer glass according to any one of claims 1 to 7 , wherein the heat-resistant and low-radiation film is formed on two or more glass plates.

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