JP5862107B2 - Liquid composition - Google Patents
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- JP5862107B2 JP5862107B2 JP2011179264A JP2011179264A JP5862107B2 JP 5862107 B2 JP5862107 B2 JP 5862107B2 JP 2011179264 A JP2011179264 A JP 2011179264A JP 2011179264 A JP2011179264 A JP 2011179264A JP 5862107 B2 JP5862107 B2 JP 5862107B2
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- egg yolk
- liquid composition
- calcium
- sodium alginate
- milk
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- 239000000203 mixture Substances 0.000 title claims description 62
- 239000007788 liquid Substances 0.000 title claims description 60
- 102000002322 Egg Proteins Human genes 0.000 claims description 68
- 108010000912 Egg Proteins Proteins 0.000 claims description 68
- 210000002969 egg yolk Anatomy 0.000 claims description 64
- 235000013345 egg yolk Nutrition 0.000 claims description 63
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 38
- 239000011575 calcium Substances 0.000 claims description 38
- 229910052791 calcium Inorganic materials 0.000 claims description 38
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 34
- 239000000661 sodium alginate Substances 0.000 claims description 34
- 235000010413 sodium alginate Nutrition 0.000 claims description 34
- 229940005550 sodium alginate Drugs 0.000 claims description 34
- 239000006071 cream Substances 0.000 claims description 17
- 102000014171 Milk Proteins Human genes 0.000 claims description 15
- 108010011756 Milk Proteins Proteins 0.000 claims description 15
- 235000021239 milk protein Nutrition 0.000 claims description 15
- 235000013336 milk Nutrition 0.000 claims description 14
- 239000008267 milk Substances 0.000 claims description 14
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- 235000013351 cheese Nutrition 0.000 claims description 12
- 235000018102 proteins Nutrition 0.000 claims description 9
- 102000004169 proteins and genes Human genes 0.000 claims description 9
- 108090000623 proteins and genes Proteins 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 5
- 235000010443 alginic acid Nutrition 0.000 claims description 4
- 229920000615 alginic acid Polymers 0.000 claims description 4
- 229960001126 alginic acid Drugs 0.000 claims description 2
- 239000000783 alginic acid Substances 0.000 claims description 2
- 150000004781 alginic acids Chemical class 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
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- 229960005069 calcium Drugs 0.000 description 34
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- 238000011156 evaluation Methods 0.000 description 3
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- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- 244000203593 Piper nigrum Species 0.000 description 2
- 235000008184 Piper nigrum Nutrition 0.000 description 2
- 239000005862 Whey Substances 0.000 description 2
- 102000007544 Whey Proteins Human genes 0.000 description 2
- 108010046377 Whey Proteins Proteins 0.000 description 2
- 229940072056 alginate Drugs 0.000 description 2
- 235000015241 bacon Nutrition 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 235000011148 calcium chloride Nutrition 0.000 description 2
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 2
- 239000001527 calcium lactate Substances 0.000 description 2
- 235000011086 calcium lactate Nutrition 0.000 description 2
- 229960002401 calcium lactate Drugs 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000005018 casein Substances 0.000 description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
- 235000021240 caseins Nutrition 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 235000011950 custard Nutrition 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 238000003505 heat denaturation Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000020183 skimmed milk Nutrition 0.000 description 2
- ZIIUUSVHCHPIQD-UHFFFAOYSA-N 2,4,6-trimethyl-N-[3-(trifluoromethyl)phenyl]benzenesulfonamide Chemical compound CC1=CC(C)=CC(C)=C1S(=O)(=O)NC1=CC=CC(C(F)(F)F)=C1 ZIIUUSVHCHPIQD-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 239000004278 EU approved seasoning Substances 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 241000237503 Pectinidae Species 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 241000286209 Phasianidae Species 0.000 description 1
- 102000015439 Phospholipases Human genes 0.000 description 1
- 108010064785 Phospholipases Proteins 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000013614 black pepper Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
- 239000001354 calcium citrate Substances 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 235000013330 chicken meat Nutrition 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 235000021567 cream sauce Nutrition 0.000 description 1
- 235000015140 cultured milk Nutrition 0.000 description 1
- 235000021185 dessert Nutrition 0.000 description 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 235000019688 fish Nutrition 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- -1 for example Proteins 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 239000000416 hydrocolloid Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 230000031787 nutrient reservoir activity Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Chemical class 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 235000013594 poultry meat Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000014059 processed cheese Nutrition 0.000 description 1
- 235000020185 raw untreated milk Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000020637 scallop Nutrition 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000020097 white wine Nutrition 0.000 description 1
Landscapes
- Seeds, Soups, And Other Foods (AREA)
- Jellies, Jams, And Syrups (AREA)
- Meat, Egg Or Seafood Products (AREA)
Description
本発明は、生卵黄の特有の食感を楽しむ料理に有用な液状組成物に関する。 The present invention relates to a liquid composition useful for cooking that enjoys the unique texture of raw egg yolk.
生卵黄の特有のねっちょりした食感を楽しむ料理として、例えば、イタリアの家庭で通常食されている卵黄タイプのカルボナーラパスタ料理や同様のソースをかけたドリア、更に卵かけご飯などの米飯料理が挙げられる。卵黄タイプのカルボナーラパスタ料理では、卵黄、チーズ、パンチェッタ、胡椒を主原料とした混合液を茹でたパスタと和えて余熱で温めることにより、ソースのねっちょりした食感が得られる。このような料理に使用するソースでは、熱凝固性を有する卵黄が煮えてボソボソした食感とならないようにすると共に、生卵黄特有のねっちょりした食感を得られるようにすることが望ましい。 As a dish that enjoys the unique texture of raw egg yolk, for example, egg yolk type carbonara pasta dishes usually eaten in Italian homes, doria with similar sauce, and rice dishes such as egg over rice Is mentioned. In egg yolk type carbonara pasta dishes, the mixture of egg yolk, cheese, pancetta and pepper is mixed with boiled pasta and warmed with residual heat, resulting in a chewy texture of the sauce. In the sauce used for such cooking, it is desirable to prevent the egg yolk having heat coagulation property from being boiled and becoming a rough texture, and to obtain a firm texture unique to raw egg yolk.
また、パスタ、米飯料理等に使用するソース類は、市場においては加熱調理され、レトルトパウチ等の容器に充填されて販売されることが多い。そこで、卵黄を用いたクリーム系のソース類の製品には、レトルト時の加熱によっても熱凝固性を有する卵黄が煮えてボソボソした食感とならず、生卵黄特有のねっちょりした食感を有することが望まれる。 In addition, sauces used for pasta, cooked rice dishes and the like are often cooked and filled in containers such as retort pouches in the market. Therefore, cream-based sauce products that use egg yolk do not have the texture of heat-coagulated egg yolk simmered and boiled by heating during retort, but the texture that is characteristic of raw egg yolk. It is desirable to have.
従来、熱凝固性を低下させた卵黄液として、卵黄とアルギン酸塩とを混合し、冷却したものが提案されている(特許文献1)。この卵黄液によれば、熱凝固性が低下しているので、卵黄本来の風味を損なうことなく殺菌処理を行うことができ、この卵黄液を用いて加熱調理したカスタードクリームは、ざらつきのない滑らかな食感であったとされている。 Conventionally, as an egg yolk liquid with reduced heat coagulation properties, a mixture of egg yolk and alginate and cooled is proposed (Patent Document 1). According to this egg yolk liquid, since the heat coagulation property is lowered, it can be sterilized without impairing the original flavor of the egg yolk, and the custard cream cooked with this egg yolk liquid has a smooth and smooth surface. It is said that it was a pleasant texture.
また、卵黄タンパク又は乳タンパクを含有するクリーム類、ペースト類、ドレッシング類などにおいて、タンパクの熱変性を防止するなどのために、卵黄タンパク又は乳タンパクに、低粘性アルギン酸塩、脱脂粉乳等のカルシウム含有素材及び油脂を加えて乳化させることが提案されている(特許文献2)。 In addition, in creams, pastes, dressings, etc. containing egg yolk protein or milk protein, calcium yolk protein or milk protein, calcium such as low-viscosity alginate, skim milk powder, etc. is used to prevent heat denaturation of the protein. It has been proposed to emulsify by adding a raw material and fats and oils (Patent Document 2).
しかしながら、上述の特許文献1の卵黄液や特許文献2の乳化物を加熱調理しても、本来の卵黄タイプのカルボナーラパスタ料理やドリア等の米飯料理が有する生卵黄特有のねっちょりした食感をだすことができない。ねっちょりした食感をだすためには、卵黄の含有量を高めることが考えられる。しかしながら、卵黄の含有量を高めることは製造コストの上昇をもたらす。また、近年、健康面からコレステロールの過剰摂取を抑えることが推奨されており、卵黄含有量を低減させた食品を製造することが望まれている。 However, even if the egg yolk liquid of Patent Document 1 or the emulsion of Patent Document 2 is cooked, the texture that is characteristic of raw egg yolk in original rice yolk-type carbonara pasta dishes and cooked rice dishes such as Doria I can't start. In order to produce a firm texture, it is conceivable to increase the content of egg yolk. However, increasing the yolk content results in an increase in manufacturing costs. In recent years, it has been recommended to suppress excessive intake of cholesterol from the viewpoint of health, and it is desired to produce a food with a reduced egg yolk content.
これに対し、本発明は、上述したパスタ料理や米飯料理等の生卵黄特有の食感を楽しむ料理に有用な液状組成物であって、従来品に比して卵黄の含有量を高めることなく、加熱によりねっちょりした食感を呈するものを提供すること目的とする。 On the other hand, the present invention is a liquid composition useful for cooking that enjoys the texture unique to raw egg yolk such as the above-mentioned pasta dishes and cooked rice dishes, without increasing the content of egg yolk compared to conventional products. The object is to provide a product that exhibits a firm texture upon heating.
本発明者は、卵黄、乳又は乳製品、及びアルギン酸ナトリウムを用いて、生卵黄特有の食感を楽しむ料理に使用する卵黄様液状物等を製造するにあたり、アルギン酸ナトリウムとカルシウムを含有させ、特定の粘度に調整すると、その卵黄様液状物の製造時の加熱で熱変性したタンパクが、アルギン酸ナトリウムとカルシウムによって形成されるゲルを適度に崩すためか、生卵黄特有のねっちょりした食感を呈することを見出した。 The present inventor, using egg yolk, milk or dairy products, and sodium alginate, contains sodium alginate and calcium in producing an egg yolk-like liquid used for cooking that enjoys the texture unique to raw egg yolk. If the viscosity of the egg yolk-like liquid is adjusted, the heat-denatured protein will cause the gel formed by sodium alginate and calcium to break down moderately, or the sticky texture unique to raw egg yolk I found out that it was present.
即ち、本発明は、少なくとも固形分換算で0.1〜5質量%の卵黄、乳又は乳タンパクを含有する乳製品、及びアルギン酸ナトリウムを配合してなり、カルシウムを含有し、タンパク質が熱変性し、製品の粘度(60℃)が1〜20Pa・sである液状組成物を提供する。 That is, the present invention comprises at least 0.1 to 5% by mass of egg yolk, milk or milk protein containing sodium alginate in terms of solid content, and contains calcium, the protein is heat denatured, A liquid composition having a viscosity (60 ° C.) of 1 to 20 Pa · s is provided.
本発明の液状組成物は、加熱により、生卵黄特有のねっちょりした食感を有する。したがって、この液状組成物を、卵黄を用いたクリーム系パスタ料理や米飯料理等の生卵黄特有の食感を楽しむ料理に使用すると、従来に比して卵黄の使用量を増やすことなく、生卵黄特有の食感を呈する美味しいパスタ、米飯料理等を得ることができる。 The liquid composition of the present invention has a sticky texture unique to raw egg yolk by heating. Therefore, when this liquid composition is used in a dish that enjoys the texture unique to raw egg yolk, such as cream-based pasta dishes or cooked rice dishes using egg yolk, the amount of egg yolk used is increased without increasing the amount of egg yolk compared to the prior art. Delicious pasta with a unique texture, cooked rice, etc. can be obtained.
以下、本発明を詳細に説明する。なお、本発明において、「部」は「質量部」を意味し、「%」は「質量%」を意味する。 Hereinafter, the present invention will be described in detail. In the present invention, “part” means “part by mass” and “%” means “mass%”.
本発明の液状組成物は、少なくとも固形分換算で0.1〜5質量%の卵黄、乳又は乳タンパクを含有する乳製品、及びアルギン酸ナトリウムを配合してなり、カルシウムを含有している。また、本発明の液状組成物においては、加熱によりタンパクが熱変性し、アルギン酸ナトリウムとカルシウムによりゲルが形成されている。このゲルは均一には形成されておらず、本発明の液状組成物にねっちょりした食感を付与している。 The liquid composition of the present invention contains at least 0.1 to 5% by mass of egg yolk, milk or milk protein in terms of solid content, and sodium alginate, and contains calcium. In the liquid composition of the present invention, the protein is thermally denatured by heating, and a gel is formed from sodium alginate and calcium. This gel is not formed uniformly and imparts a firm texture to the liquid composition of the present invention.
前記液状組成物を使用した料理としては、パスタ料理、米飯料理、デザート用ソース、ドレッシング等が挙げられる。 Examples of the dish using the liquid composition include pasta dishes, cooked rice dishes, dessert sauces, dressings and the like.
本発明の液状組成物を製造するにあたり、配合する卵黄としては、鶏、うずら、あひる等の家禽卵より得られる生卵黄もしくは該生卵黄を殺菌したもの、冷凍もしくは冷蔵したもの、スプレードライもしくはフリーズドライ等で乾燥したもの、又はホスフォリパーゼAにて酵素処理したもの等をあげることができる。 In producing the liquid composition of the present invention, the egg yolks to be blended include raw egg yolks obtained from poultry eggs such as chickens, quail and duck, or those sterilized, frozen or refrigerated, spray dried or frozen. Examples thereof include those dried by drying or the like, or those subjected to enzyme treatment with phospholipase A.
卵黄の配合量は、生卵黄特有のねっちょり感を有すると共に、卵黄の加熱凝固を防止する点から固形分換算で0.1〜5%、好ましく0.1〜4%とする。従来のクリームソースにおける一般的な卵黄の配合量は、5〜20%であり、この配合量で生卵黄特有のねっちょり感を出すことはできなかったが、本発明によれば、卵黄の配合量を従来例より少なくしても、生卵黄特有のねっちょり感を出すことができる。 The blending amount of egg yolk is 0.1-5%, preferably 0.1-4% in terms of solid content from the viewpoint of having a sticky feeling peculiar to raw egg yolk and preventing heat-coagulation of egg yolk. The general blending amount of egg yolk in the conventional cream sauce is 5 to 20%, and this blending amount could not give a sticky feeling peculiar to raw egg yolk, but according to the present invention, Even if the blending amount is less than that of the conventional example, a sticky feeling peculiar to raw egg yolk can be obtained.
乳又は乳タンパクを含有する乳製品としては、例えば、生乳、生クリーム、脱脂乳、ホエー、脱塩ホエー、カゼイン及び、これらの濃縮物、乾燥物、チーズなどの発酵物、化学的処理を施して得られる加水分解物、プロテアーゼ、リパーゼ等の酵素的処理等を施して得られる加水分解物等を挙げることができる。なかでも、チーズ、生クリーム、牛乳、乳発酵物、チーズ加工品等を使用することが好ましく、特に、チーズと生クリームを併用することが好ましい。 Examples of dairy products containing milk or milk protein include raw milk, fresh cream, skim milk, whey, desalted whey, casein, and concentrates, dried products, fermented products such as cheese, and chemical treatment. The hydrolyzate obtained by performing enzymatic treatment etc., such as a hydrolyzate obtained by this, protease, lipase, etc. can be mentioned. Especially, it is preferable to use cheese, fresh cream, milk, fermented milk, processed cheese products, etc., and it is particularly preferable to use cheese and fresh cream in combination.
乳又は乳製品の配合量は、乳又は乳製品由来の乳タンパクと、上述の卵黄由来の卵黄タンパクとが、加熱変性により、アルギン酸ナトリウムとカルシウムとのゲルの形成を適度に阻害し、それによりねっちょりした食感を得られるように定める。本発明は、乳タンパクの含有量を、製品に対して好ましくは0.1〜5%、より好ましくは0.5〜3%とする。なお、乳又は乳製品中の乳タンパク含量は、五訂日本食品標準成分表により算出することができる。 The amount of milk or dairy product is such that milk protein derived from milk or dairy product and egg yolk protein derived from the above-mentioned egg yolk moderately inhibits the gel formation of sodium alginate and calcium by heat denaturation. Establish a tight texture. In the present invention, the milk protein content is preferably 0.1 to 5%, more preferably 0.5 to 3%, based on the product. In addition, the milk protein content in milk or dairy products can be calculated according to the 5th Japan Food Standard Composition Table.
アルギン酸ナトリウムは、海草から抽出して得られる親水コロイド性多糖類であるアルギン酸の水酸基をナトリウムイオンで置換したものである。 Sodium alginate is obtained by replacing the hydroxyl group of alginic acid, which is a hydrocolloid polysaccharide obtained by extraction from seaweed, with sodium ions.
アルギン酸ナトリウムの配合量は、アルギン酸ナトリウムと、卵黄タンパクと乳タンパクの合計との含有比率として、タンパク1部に対して、アルギン酸ナトリウムを好ましくは0.1〜2部、より好ましくは0.5〜1.5部とする。これにより、ねっちょりした食感を得やすくなる。 The amount of sodium alginate is preferably 0.1 to 2 parts, more preferably 0.5 to 1.5 parts, with respect to 1 part of protein as the content ratio of sodium alginate and the total of egg yolk protein and milk protein. . This makes it easier to get a sticky texture.
一方、本発明の液状組成物は、カルシウムを含有している。カルシウムとしては、清水への溶解度が1%以上(25℃)の水溶性カルシウム塩が好ましい。このようなカルシウムとしては、例えば、焼成カルシウム、塩化カルシウム、乳酸カルシウム、クエン酸カルシウム、硫酸カルシウム、リン酸カルシウム、炭酸カルシウム、カゼインカルシウム等が挙げられる。これらは単独で含有されてもよく、2種類以上で含有されてもよい。 On the other hand, the liquid composition of the present invention contains calcium. As calcium, a water-soluble calcium salt having a solubility in fresh water of 1% or more (25 ° C.) is preferable. Examples of such calcium include calcined calcium, calcium chloride, calcium lactate, calcium citrate, calcium sulfate, calcium phosphate, calcium carbonate, and casein calcium. These may be contained alone or in combination of two or more.
カルシウムを、本発明の液状組成物に含有させるためには、乳酸カルシウム、塩化カルシウム等のカルシウム製剤や、卵黄、乳又は乳製品等のカルシウムを含む食品素材を本発明の液状組成物の原材料として使用すればよい。なかでも、乳タンパクを含有する上述のチーズ、生クリームを併用することが、、カルシウム製剤を使用することなく、好ましいカルシウム含有量を達成できる点から好ましい。なお、本発明の液状組成物は、卵黄を含有することにより卵黄由来のカルシウムを含有することになるが、卵黄由来のカルシウムだけでは、次に説明するアルギン酸ナトリウムとカルシウムとの好ましい含有比率を達成することができない。 In order to contain calcium in the liquid composition of the present invention, calcium preparations such as calcium lactate and calcium chloride and food materials containing calcium such as egg yolk, milk or dairy products are used as raw materials for the liquid composition of the present invention. Use it. Especially, it is preferable to use together the above-mentioned cheese and fresh cream containing milk protein from the point which can achieve a preferable calcium content, without using a calcium formulation. In addition, although the liquid composition of the present invention contains egg yolk by containing egg yolk, the egg yolk-derived calcium alone achieves a preferable content ratio of sodium alginate and calcium described below. Can not do it.
本発明において、アルギン酸ナトリウムとカルシウムとの含有比率は、アルギン酸ナトリウム1質量部に対して、カルシウム0.01〜3質量部、好ましくは0.05〜2とする。アルギン酸ナトリウムとカルシウムは、混合することにより速やかにゲルを形成するが、この範囲よりもカルシウムが少ないとゲル化が不十分でねっちょりした食感を得られず、反対に、この範囲よりカルシウムが多すぎると過度にゲル化が進行してねっちょりした食感が得られない。
なお、アルギン酸ナトリウムとカルシウムとの含有比率を求めるにあたり、卵黄、乳又は乳製品中のカルシウムのカルシウムとしての含量は、五訂日本食品標準成分表により算出することができる。
In the present invention, the content ratio of sodium alginate and calcium is 0.01 to 3 parts by weight, preferably 0.05 to 2 parts by weight with respect to 1 part by weight of sodium alginate. Sodium alginate and calcium quickly form a gel when mixed. However, if the amount of calcium is less than this range, gelation is insufficient and a firm texture cannot be obtained. If there is too much, gelation will advance excessively and a firm texture cannot be obtained.
In addition, when calculating | requiring the content ratio of sodium alginate and calcium, the content as calcium of calcium in egg yolk, milk, or dairy products can be calculated from the 5th Japanese food standard ingredient table.
本発明の液状組成物には、必要に応じて、菜種油、大豆油、パーム油等の植物油脂、キサンタンガム、グアーガム等の増粘剤、食塩、砂糖、グルタミン酸ナトリウム、動植物エキス類、香辛料等の調味料、香味野菜、白ワイン等の風味付け原料、その他乳化剤等の添加剤を含有させることができる。
また、ベーコン等の肉類、ホタテ等の魚介類等の具材も適宜含有させることができる。
In the liquid composition of the present invention, as necessary, vegetable oils such as rapeseed oil, soybean oil and palm oil, thickeners such as xanthan gum and guar gum, salt, sugar, sodium glutamate, animal and plant extracts, spices and other seasonings Additives such as ingredients, flavoring ingredients such as flavored vegetables and white wine, and other emulsifiers can be added.
In addition, ingredients such as meat such as bacon and fish and shellfish such as scallops can be appropriately contained.
本発明の液状組成物の製造方法としては、例えば、(i)卵黄、(ii)乳タンパク源及びカルシウム源となる、チーズ、生クリーム、及び牛乳など、(iii)アルギン酸ナトリウム、(iv)その他必要に応じて配合される食材を混合して加熱し、卵黄タンパク及び乳タンパクを変性させることにより得ることができる。 Examples of the method for producing the liquid composition of the present invention include (i) egg yolk, (ii) cheese, fresh cream, and milk that serve as a milk protein source and calcium source, (iii) sodium alginate, (iv) other It can be obtained by mixing and heating ingredients blended as necessary to denature egg yolk protein and milk protein.
この場合、加熱条件は、80〜140℃で1〜60分とし、卵黄タンパクと乳タンパクを熱変性させることが好ましい。これにより、本発明の液状組成物は、粘度(60℃)が1〜20Pa・s、好ましくは1.5〜15Pa・s、より好ましくは5〜15Pa・sとなる。粘度(60℃)を1Pa・s以上とすることにより、液状組成物のねっちょりとした食感が得られにくくなり、また、20Pa・s以下とすることにより、皿への盛りつけが容易になる。 In this case, the heating condition is preferably 80 to 140 ° C. for 1 to 60 minutes, and the egg yolk protein and milk protein are preferably heat denatured. Thereby, the liquid composition of the present invention has a viscosity (60 ° C.) of 1 to 20 Pa · s, preferably 1.5 to 15 Pa · s, more preferably 5 to 15 Pa · s. By setting the viscosity (60 ° C) to 1 Pa · s or more, it becomes difficult to obtain a firm texture of the liquid composition, and by setting the viscosity to 20 Pa · s or less, it can be easily placed on a plate. Become.
ここで、粘度の数値は、B形粘度計で、品温60℃、回転数20rpmの条件で、粘度が、0.375Pa・s以上1.5Pa・s未満のときローターNo.2、1.5Pa・s以上3.75Pa・s未満のときローターNo.3、3.75Pa・s以上7.5Pa・s未満のときローターNo.4、7.5Pa・s以上15Pa・s未満のときローターNo.5、15Pa・s以上のときローターNo.6を使用し、測定開始後ローターが3回転した時の示度により求めた値である。 Here, the numerical value of the viscosity is rotor No. 2, 1.5 Pa · s when the viscosity is 0.375 Pa · s or more and less than 1.5 Pa · s under the conditions of a B-type viscometer, a product temperature of 60 ° C., and a rotation speed of 20 rpm. When it is above 3.75 Pa · s, rotor No. 3, when it is 3.75 Pa · s and below 7.5 Pa · s, rotor No. 4, when it is 7.5 Pa · s and below 15 Pa · s, rotor No. 5, 15 Pa · s and above In this case, rotor No. 6 was used, and the value obtained from the reading when the rotor was rotated 3 times after the start of measurement.
また、本発明の液状組成物は、上述の加熱により、付着性が、好ましくは0.1〜2kg/sec、より好ましくは0.2〜1.5kg/secとなる。付着性がこの範囲外であると、生卵黄特有のねっちょり感を得られにくく好ましくない。 Moreover, the liquid composition of the present invention has an adhesiveness of preferably 0.1 to 2 kg / sec, more preferably 0.2 to 1.5 kg / sec by the above-described heating. If the adhesion is outside this range, it is difficult to obtain the sticky feeling peculiar to raw egg yolk.
ここで、付着性は、Texture Analyzer TA.XT. plus (Stable Micro Systems社)により次のように測定し、算出した値である。具体的には、液状組成物を容器にすり切りいっぱいまで入れ、直径35mm円柱プランジャを使用して、移動速度10mm/secで液状組成物を押し込み、次いで引き上げ、引き上げ時にプランジャにかかる重力方向の力(下向きの力)を測定する。この測定によると、まずプランジャが液状組成物を押しこむことによる応力がかかり、その後プランジャの上昇に合わせて液状組成物が元に戻ろうとする重力方向の力(下向きの力)が働く。この重力方向の力を、プランジャの上昇時間(sec)に対してプロットしたときの、重力方向の力の最大値から0点までの傾きを付着力(kg/sec)とした。 Here, the adhesiveness is a value calculated by measuring as follows using Texture Analyzer TA.XT. plus (Stable Micro Systems). Specifically, the liquid composition is put into a container to the full extent, and a 35 mm diameter cylindrical plunger is used to push the liquid composition at a moving speed of 10 mm / sec. Measure the downward force). According to this measurement, first, a stress is applied due to the plunger pushing in the liquid composition, and then a force in the direction of gravity (downward force) is applied to the liquid composition to return to the original as the plunger is raised. When the force in the gravitational direction was plotted against the ascending time (sec) of the plunger, the inclination from the maximum value of the force in the gravitational direction to 0 point was defined as the adhesion force (kg / sec).
本発明の液状組成物のより好ましい製造方法としては、例えば、まず、二重釜に清水を入れ、アルギン酸ナトリウム及びキサンタンガムを加えた後、卵黄と生クリームを配合して混合し、加熱する方法等が挙げられる。 As a more preferable production method of the liquid composition of the present invention, for example, first, fresh water is put into a double kettle, sodium alginate and xanthan gum are added, egg yolk and fresh cream are blended, mixed, and heated, etc. Is mentioned.
本発明の液状組成物は、レトルトパウチに充填密封し、115〜120℃で20〜60分、レトルト処理を施してもよい。本発明の液状組成物は、レトルト処理の前後を問わず、生卵黄特有のねっちょりした食感を有する。 The liquid composition of the present invention may be filled and sealed in a retort pouch and subjected to a retort treatment at 115 to 120 ° C. for 20 to 60 minutes. The liquid composition of the present invention has a sticky texture peculiar to raw egg yolk before and after the retort treatment.
こうして得られる本発明の液状組成物は、卵黄タイプのカルボナーラパスタ料理や同様のソースをかけたドリア、卵かけご飯等として有用である。また、本発明の液状組成物はレトルトパウチ詰めのソースとしても有用である。 The liquid composition of the present invention thus obtained is useful as an egg yolk type carbonara pasta dish, doria with a similar sauce, egg over rice or the like. The liquid composition of the present invention is also useful as a sauce for retort pouch filling.
以下、実施例に基づいて、本発明を具体的に説明する。
実施例1
表1、表2の原材料を使用し、実施例のパスタ用液状組成物を次のように製造した。
二重釜に清水を入れ、アルギン酸ナトリウム0.5部及びキサンタンガム1.0部を加え、植物油脂45.0部、生卵黄9.0部、チーズ4.0部、生クリーム15.0部及び化工澱粉1.0部を加え均一に混合した。そしてこの混合物を撹拌しながら加熱し、80℃達温後加熱を停止し、液状組成物を得た。また、この液状組成物に拍子木切りのベーコン20.0部及びブラックペッパー0.2部を加え、仕上げ撹拌し、具材入り液状組成物を得た。
Hereinafter, based on an Example, this invention is demonstrated concretely.
Example 1
Using the raw materials shown in Tables 1 and 2, the liquid compositions for pasta of Examples were produced as follows.
Fresh water was put into a double kettle, 0.5 parts of sodium alginate and 1.0 part of xanthan gum were added, 45.0 parts of vegetable oil and fat, 9.0 parts of raw egg yolk, 4.0 parts of cheese, 15.0 parts of fresh cream and 1.0 part of modified starch were added and mixed uniformly. The mixture was heated with stirring, and after reaching 80 ° C., the heating was stopped to obtain a liquid composition. In addition, 20.0 parts of beaten bacon and 0.2 part of black pepper were added to this liquid composition and finished and stirred to obtain a liquid composition containing ingredients.
得られた具材入り液状組成物を140gずつ耐熱性のレトルトパウチに充填・密封した後、120℃で20分間レトルト処理し、冷却してレトルトパウチ詰めの液状組成物を得た。 The obtained liquid composition containing ingredients was filled and sealed in a heat-resistant retort pouch 140 g at a time, and then retorted at 120 ° C. for 20 minutes and cooled to obtain a retort pouch-packed liquid composition.
本実施例の液状組成物において、アルギン酸ナトリウムとカルシウムとの含有比率は、アルギン酸ナトリウム1部に対してカルシウム0.15部であった。液状組成物中の卵黄タンパク含有量は1.5%、乳タンパク含有量は0.5%、卵黄の含有量は固形分換算で4.7部であった。また、付着性を前述の方法で測定したところ、0.5kg/secであり、粘度は13Pa・sであった。 In the liquid composition of this example, the content ratio of sodium alginate and calcium was 0.15 part of calcium with respect to 1 part of sodium alginate. The egg yolk protein content in the liquid composition was 1.5%, the milk protein content was 0.5%, and the egg yolk content was 4.7 parts in terms of solid content. Further, when the adhesion was measured by the above-mentioned method, it was 0.5 kg / sec and the viscosity was 13 Pa · s.
比較例1〜3
実施例1に対して、原材料を表3のように変更した以外は、実施例1と同様にしてレトルトパウチ詰めの液状組成物を製造した。つまり、比較例1はアルギン酸ナトリウムを配合せず、比較例2はチーズ及び生クリームを配合せず、比較例3は卵黄を配合しなかった他は、実施例1と同様の方法で液状組成物を製造した。
Comparative Examples 1-3
A liquid composition packed in a retort pouch was produced in the same manner as in Example 1 except that the raw materials were changed as shown in Table 3 with respect to Example 1. That is, Comparative Example 1 does not contain sodium alginate, Comparative Example 2 does not contain cheese and fresh cream, Comparative Example 3 does not contain egg yolk, and the liquid composition is the same as Example 1. Manufactured.
また、得られたレトルトパウチ詰めの液状組成物の食感を以下の基準で3段階に評価した。
A:生卵黄特有のねっちょりとした食感であり、大変好ましい
B:やや生卵黄特有のねっちょりとした食感があり、好ましい
C:生卵黄特有のねっちょりとした食感にならず、好ましくない
結果を表3に示す。
In addition, the texture of the liquid composition filled with the retort pouch was evaluated in three stages according to the following criteria.
A: A texture that is peculiar to raw egg yolk, very favorable B: A texture that is slightly peculiar to raw egg yolk is preferable, and C: A texture that is peculiar to raw egg yolk Nonetheless, the unfavorable results are shown in Table 3.
実施例2、比較例4
実施例1において、アルギン酸ナトリウム1部に対するカルシウムの含有量を、卵黄、チーズ及び生クリームの配合量を変えることにより表4のように調整し、液状組成物を製造した。
Example 2 and Comparative Example 4
In Example 1, the content of calcium with respect to 1 part of sodium alginate was adjusted as shown in Table 4 by changing the blending amounts of egg yolk, cheese and fresh cream, and liquid compositions were produced.
また、比較例4として、特許文献1(特許3648993)の実施例6にしたがってカスタードクリームを製造した。 In addition, as Comparative Example 4, a custard cream was produced according to Example 6 of Patent Document 1 (Patent 3689993).
実施例2及び比較例4の各液状組成物の食感を次の基準で評価した。また、付着性を前述の方法で測定した。結果を表4に示す。なお、実施例2-1〜実施例2-5の液状組成物の粘度はいずれも1〜20Pa・sの範囲内であった。 The texture of each liquid composition of Example 2 and Comparative Example 4 was evaluated according to the following criteria. Adhesion was measured by the method described above. The results are shown in Table 4. The viscosities of the liquid compositions of Examples 2-1 to 2-5 were all in the range of 1 to 20 Pa · s.
食感の評価基準
A:生卵黄に酷似したねっちょりとした舌触りがあり大変好ましかった
B:生卵黄に近い舌触りがあり、好ましかった
C:生卵黄のねっちょりとした食感にならなかった
Criteria for evaluation of texture A: A texture that is very similar to a raw egg yolk and very preferred B: A texture similar to that of a raw egg yolk is preferred, and C: A food that is a healthy egg yolk I didn't feel
実施例3
表5の原材料を使用し、実施例のパスタ用液状組成物を次のように製造した。
つまり、二重釜に清水を入れ、アルギン酸ナトリウム2.0部及びキサンタンガム0.3部を加え、植物油脂8.0部、生卵黄5.0部、チーズ20.0部、生クリーム10.0部及び化工澱粉0.5部を加え均一に混合した。そしてこの混合物を攪拌させながら加熱し、80℃達温後加熱を停止し液状組成物を得た。
Example 3
Using the raw materials shown in Table 5, the liquid compositions for pasta of Examples were produced as follows.
That is, put fresh water into a double kettle, add 2.0 parts of sodium alginate and 0.3 part of xanthan gum, add vegetable oil and fat 8.0 parts, raw egg yolk 5.0 parts, cheese 20.0 parts, fresh cream 10.0 parts and modified starch 0.5 parts and mixed uniformly. . The mixture was heated while being stirred, and after reaching 80 ° C., the heating was stopped to obtain a liquid composition.
この液状組成物において、アルギン酸ナトリウムとカルシウムとの含有比率は、アルギン酸ナトリウム1部に対してカルシウム0.13部で、タンパク1部に対してアルギン酸ナトリウム0.2部であった。 In this liquid composition, the content ratio of sodium alginate and calcium was 0.13 parts of calcium with respect to 1 part of sodium alginate and 0.2 parts of sodium alginate with respect to 1 part of protein.
この液状組成物の食感を実施例1と同様の基準で評価したところ、A評価で良好であり、付着性は1.5kg/sec、粘度は1〜20Pa・sの範囲内であった。 When the texture of this liquid composition was evaluated according to the same criteria as in Example 1, it was good in A evaluation, the adhesion was 1.5 kg / sec, and the viscosity was in the range of 1 to 20 Pa · s.
実施例4
表6の原材料を使用し、実施例のドリア用液状組成物を次のように製造した。
つまり、二重釜に清水を入れ、アルギン酸ナトリウム2.0部及びキサンタンガム0.5部を加え、植物油脂2.0部、生卵黄3.0部、チーズ15.0部、生クリーム5.0部及び化工澱粉0.5部を加え均一に混合した。そしてこの混合物を攪拌させながら加熱し、80℃達温後加熱を停止し液状組成物を得た。
Example 4
Using the raw materials shown in Table 6, liquid compositions for doria of Examples were produced as follows.
That is, put fresh water into a double kettle, add 2.0 parts of sodium alginate and 0.5 parts of xanthan gum, add 2.0 parts of vegetable oil and fat, 3.0 parts of raw egg yolk, 15.0 parts of cheese, 5.0 parts of fresh cream and 0.5 parts of modified starch and mix uniformly. . The mixture was heated while being stirred, and after reaching 80 ° C., the heating was stopped to obtain a liquid composition.
この液状組成物において、アルギン酸ナトリウムとカルシウムとの含有比率は、アルギン酸ナトリウム1部に対してカルシウム0.1部で、タンパク1部に対してアルギン酸ナトリウム0.3部であった。 In this liquid composition, the content ratio of sodium alginate and calcium was 0.1 part of calcium with respect to 1 part of sodium alginate and 0.3 part of sodium alginate with respect to 1 part of protein.
この液状組成物を米飯にかけて食し、その食感を実施例1と同様の基準で評価したところ、A評価で良好であり、付着性は0.5kg/sec、粘度は1〜20Pa・sの範囲内であった。 When this liquid composition was eaten over cooked rice and the texture was evaluated according to the same criteria as in Example 1, the A evaluation was good, the adhesion was 0.5 kg / sec, and the viscosity was in the range of 1 to 20 Pa · s. Met.
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