JP5708860B1 - Battery packaging materials - Google Patents

Abstract

The present invention provides a battery packaging material that has chemical resistance, moldability, and interlayer adhesion between a barrier layer and a coating layer, and can shorten lead time. In a battery packaging material comprising a laminate having a laminate having a coating layer, a barrier layer, and a sealant layer in this order, the coating layer comprises a first coating layer and a second coating. The first coating layer, the third coating layer 1c, and the first coating layer, the third coating layer 1c are arranged so that the first coating layer is located on the outermost layer and the third coating layer is located on the barrier layer side. A battery packaging material in which the second coating layer and the third coating layer are each formed of a cured product of a resin composition containing a thermosetting resin and a curing accelerator, and satisfy a specific hardness. A battery packaging material in which the first coating layer has an elastic modulus of 3000 to 6000 MPa, and the second coating layer and the third coating layer have an elastic modulus of 1500 to 6000 MPa. [Selection] Figure 2

Description

  The present invention relates to a battery-like packaging material for a battery that is thinned by providing a coating layer as an outermost layer on a barrier layer, and relates to a packaging material for a battery that can shorten the lead time.

  Conventionally, various types of batteries have been developed. In any battery, a packaging material is an indispensable member for sealing battery elements such as electrodes and electrolytes. Conventionally, metal packaging materials have been frequently used as battery packaging.

  On the other hand, as the performance of electric vehicles, hybrid electric vehicles, personal computers, cameras, mobile phones, and the like increases, the batteries are required to have various shapes, as well as to be thinner and lighter. However, metal battery packaging materials that have been widely used in the past have the disadvantages that it is difficult to follow the diversification of shapes and that there is a limit to weight reduction.

  Therefore, a film-like laminate in which a base material layer / adhesive layer / barrier layer / sealant layer are sequentially laminated is proposed as a battery packaging material that can be easily processed into various shapes and can be made thinner and lighter. (For example, refer to Patent Document 1). Such a film-shaped battery packaging material is formed so that the battery element can be sealed by causing the sealant layers to face each other and heat-sealing the peripheral portion by heat sealing.

  On the other hand, in recent years, there has been an increasing demand for smaller and thinner batteries, and further thinning of film-like battery packaging materials is required to follow the demand. As a method for thinning the whole film packaging material for a battery, there is a method of thinning a base material layer in which a resin film having a thickness of about 10 to 20 μm is used. However, there is a problem in that the reduction in the thickness of the resin film has a manufacturing limit, and the manufacturing cost of the battery packaging material increases due to the processing cost required to reduce the thickness of the resin film.

  In addition, the coating layer formed by coating the thermosetting resin compared to the resin film can greatly reduce the film thickness. It is also effective to replace the adhesive layer and the base material layer laminated on each other with a coating layer formed of a thermosetting resin. Thus, when providing a coating layer instead of an adhesive layer and a base material layer, the coating layer is required to be a thick film capable of imparting insulating properties in order to ensure its basic performance. Therefore, as a method of providing a coating layer capable of imparting insulating properties on the barrier layer using a conventional technique, a method of coating a thick thermosetting resin on the barrier layer, or a method of forming a thermosetting resin on the barrier layer. A method of laminating a plurality of coating layers by repeating thin film coating a plurality of times can be mentioned. However, the former method has a drawback that bubbles are easily generated in the coating layer by the thick film coating, and it is difficult to form a coating layer having no pinhole. In both the former and the latter methods, when a coating layer is formed using a thermosetting resin using conventional techniques, it is necessary to perform aging under high temperature conditions for several days to several weeks in the curing process. For this reason, there is a problem that the lead time is prolonged, and the product defect is caused by being exposed to high temperature conditions and temperature changes for a long time. In particular, in the latter method, in order to form a plurality of coating layers, it is necessary to carry out the curing step a plurality of times, and a very long lead time is required, which is not practical.

  Furthermore, in the case of a film-like battery packaging material, when a coating layer is provided as the outermost layer instead of the adhesive layer and the base material layer, in addition to insulation, the coating layer has an electrolyte, It is also important to provide resistance (chemical resistance) against adhesion of chemicals such as acids, alkalis and organic solvents. In addition, it is also important for the film-shaped battery packaging material to have excellent formability and to have slip properties on the surface in order to improve the formability / workability and operability in press molding and embossing.

  With such a conventional technology as a background, a film-like battery packaging material that is thinned by providing a coating layer as an outermost layer on the barrier layer, which can shorten the lead time, and can further improve moldability, The development of battery packaging materials that can be provided with functionality such as chemical properties and slip properties is eagerly desired.

JP 2001-202927 A

  The present invention is a film-like battery packaging material that can realize thinning by providing a coating layer as the outermost layer instead of the adhesive layer and the base material layer in the conventional film-like battery packaging material, It aims at providing the film-form packaging material for batteries which can aim at shortening.

  The inventors of the present invention have conducted intensive studies to solve the above problems, and at least in a battery packaging material comprising a laminate having in this order a coating having a coating layer, a barrier layer, and a sealant layer in this order, The coating layer has a multilayer structure of two or more layers, and each layer constituting the coating layer is formed of a cured product of a resin composition containing a thermosetting resin and a curing accelerator, It was found that the film can be made thin, and the lead time is shortened to enable efficient production.

  Moreover, in the said packaging material for batteries, it discovered that the outstanding moldability could be provided when the elasticity modulus of each layer which comprises the said coating layer satisfy | fills 1500-6000 MPa. Furthermore, it has been found that, when the elastic modulus of at least one of the coating layers satisfies 2500 to 6000 MPa, excellent chemical resistance can be provided. It has also been found that excellent slip properties can be imparted by incorporating a slip agent, particularly a reactive slip agent, into the outermost layer of the coating layer.

  Furthermore, in the battery packaging material having the above-described configuration, by including a pigment and / or dye in at least one layer of the coating layer, the battery packaging material can be given distinctiveness, and the thermal conductivity can be increased. It has been found that the heat dissipation can be improved.

  The present invention has been completed by further studies based on such knowledge. That is, this invention provides the invention of the aspect hung up below.

Item 1. It consists of a laminate having at least a coating layer, a barrier layer, and a sealant layer in this order,
The coating layer has a multilayer structure of two or more layers,
Each layer constituting the coating layer is made of a cured product of a resin composition containing a thermosetting resin and a curing accelerator.
A battery packaging material characterized by the above.
Item 2. Item 2. The battery packaging material according to Item 1, wherein the elastic modulus of each layer constituting the coating layer is 1500 to 6000 MPa.
Item 3. Item 3. The battery packaging material according to Item 1 or 2, wherein an elastic modulus of at least one of the layers constituting the coating layer is 2500 to 6000 MPa.
Item 4. The coating layer has a two-layer structure,
Item 4. The battery according to any one of Items 1 to 3, wherein among the layers constituting the coating layer, the elastic modulus of a layer in contact with the barrier layer is 1500 to 6000 Mpa, and the elastic modulus of the outermost layer is 3000 to 6000 Mpa. Packaging materials.
Item 5. The coating layer has a three-layer structure,
Among the layers constituting the coating layer, the elastic modulus of the layer in contact with the barrier layer is 1500 to 6000 Mpa, and the elastic modulus of the layer located between the layer in contact with the barrier layer and the outermost layer is 1500 to 6000 Mpa. The battery packaging material according to any one of Items 1 to 3, wherein the outermost layer has an elastic modulus of 3000 to 6000 Mpa.
Item 6. Item 6. The battery packaging material according to any one of Items 1 to 5, wherein the outermost layer of the coating layer comprises a cured product of a resin composition containing a curable resin, a curing accelerator, and a reactive slip agent.
Item 7. Item 7. The battery packaging material according to any one of Items 1 to 6, wherein the resin composition used for forming at least one layer of the coating layer contains a pigment and / or a dye.
Item 8. Item 8. The battery packaging material according to Item 7, wherein the resin composition used for forming at least one layer of the coating layer contains an inorganic pigment.
Item 9. Item 9. The battery packaging material according to any one of Items 1 to 8, wherein each layer constituting the coating layer has a thickness of 1 to 5 µm.
Item 10. Item 10. The battery packaging material according to any one of Items 1 to 9, wherein the entire thickness of the battery packaging material is 40 to 120 μm.
Item 11. Any one of Items 1 to 10, wherein the thermosetting resin is at least one selected from the group consisting of an epoxy resin, an amino resin, an acrylic resin, a urethane resin, a phenol resin, an unsaturated polyester resin, and an alkyd resin. A packaging material for a battery as described in 1.
Item 12. Item 1-11, wherein the curing accelerator is at least one selected from the group consisting of an amidine compound, a carbodiimide compound, a ketimine compound, a hydrazine compound, a sulfonium salt, a benzothiazolium salt, and a tertiary amine compound. The battery packaging material according to any one of the above.
Item 13. A coating layer having a multilayer structure of two or more layers is formed on the barrier layer by repeatedly applying the resin composition containing the thermosetting resin and the curing accelerator and curing by heating twice or more to the barrier layer. Including a coating layer forming step to form,
Before, during or after the coating layer forming step, a sealant layer is laminated on a surface of the barrier layer opposite to the surface on which the coating layer is laminated,
A method for producing a battery packaging material.
Item 14. Item 13. A battery in which a battery element including at least a positive electrode, a negative electrode, and an electrolyte is accommodated in the battery packaging material according to any one of Items 1 to 12.

  The battery packaging material of the present invention is composed of a laminate having at least a coating layer, a barrier layer, and a sealant layer in this order, and an adhesive layer is formed on the barrier layer like a conventional film-shaped battery packaging material. Since the base material layer is not provided, the film thickness can be reduced, and the battery can be reduced in size and thickness.

  In the battery packaging material of the present invention, each layer constituting the coating layer provided on the barrier layer is formed of a cured product of a resin composition containing a thermosetting resin and a curing accelerator. In the curing process of the coating layer, it can be cured in a short time without requiring aging under high temperature conditions, the lead time can be shortened, and further, product defects caused by exposure to high temperature conditions for a long time can be prevented. You can also.

  In the battery packaging material of the present invention, the coating layer provided on the barrier layer has two or more layers, and each layer constituting the coating layer can be provided with various functions. For example, excellent moldability and chemical resistance can be provided by setting the elastic modulus of each layer constituting the coating layer within a predetermined range. Moreover, the outstanding slip property can also be provided by containing a slip agent in the outermost layer which comprises a coating layer.

  In addition, since the battery packaging material of the present invention can form a coating layer by laminating a plurality of layers having the same or different functionalities, the battery packaging materials having various functionalities can be easily obtained. It becomes possible to provide.

  Moreover, in the conventional film-shaped battery packaging material, when providing distinctiveness by color tone for each type of battery, it is necessary to add a pigment and / or dye to either the adhesive layer or the base material layer. However, when a pigment and / or dye is added to the adhesive layer, the adhesive strength of the adhesive layer is reduced, and when a pigment and / or dye is added to the base layer, the manufacturing cost of the base layer is increased. There was a drawback of inviting. On the other hand, in the battery packaging material of the present invention, since the battery packaging material can be given distinctiveness by including a pigment and / or dye in at least one layer constituting the coating layer, the conventional film-like material is used. It is also possible to overcome the disadvantages of imparting distinguishability to the battery packaging material. Furthermore, when a pigment and / or dye (particularly inorganic pigment) is contained in at least one layer constituting the coating layer, the thermal conductivity of the battery packaging material can be increased and the heat dissipation can be improved. It can also contribute to the improvement of safety.

It is a figure which shows an example of the cross-section of the packaging material for batteries of this invention. It is a figure which shows an example of the cross-section of the packaging material for batteries of this invention.

  The battery packaging material of the present invention comprises a laminate having at least a coating layer, a barrier layer, and a sealant layer in this order. The coating layer has a multilayer structure of two or more layers, and constitutes the coating layer. Each layer to be formed is formed of a cured product of a resin composition containing a thermosetting resin and a curing accelerator. Hereinafter, the battery packaging material of the present invention will be described in detail.

1. Laminated Structure of Battery Packaging Material As shown in FIGS. 1 and 2, the battery packaging material of the present invention has a laminated structure composed of a laminate having at least a coating layer 1, a barrier layer 2, and a sealant layer 3 in this order. Have.
In the battery packaging material of the present invention, the coating layer 1 has a multilayer structure of two or more layers. The number of layers constituting the coating layer 1 may be appropriately set according to the functionality to be imparted, and is, for example, 2 to 8 layers, preferably 2 to 5, more preferably 2 or 3 layers. FIG. 1 shows a cross-sectional structure of the battery packaging material of the present invention in which the coating layer 1 has a two-layer structure (a first coating layer 1a and a second coating layer 1b), and FIG. The cross-sectional structure of the battery packaging material of the present invention which is (first coating layer 1a, second coating layer 1b, and third coating layer 1c) is shown.

  In the battery packaging material of the present invention, the coating layer 1 is the outermost layer and the sealant layer 3 is the innermost layer. That is, when the battery is assembled, the sealant layers 3 positioned at the periphery of the battery element are thermally welded to seal the battery element, thereby sealing the battery element.

  Moreover, in the battery packaging material of the present invention, an adhesive layer 4 may be provided between the barrier layer 2 and the sealant layer 3 as necessary for the purpose of enhancing the adhesion.

2. Composition and physical properties of each layer forming battery packaging material [Coating layer 1]
In the battery packaging material of the present invention, the coating layer 1 is a layer that is provided on the barrier layer 2 and forms the outermost layer of the battery packaging material. The coating layer 1 has a multilayer structure of two or more layers, and each layer constituting the coating layer is formed of a cured product of a resin composition containing a thermosetting resin and a curing accelerator. In this way, the coating layer 1 has a laminated structure of two or more layers, and each layer constituting the coating layer 1 is formed of a cured product of a resin composition containing a thermosetting resin and a curing accelerator. It is possible to cure in time, and as a result, the lead time can be shortened, and further, product defects due to exposure to high temperature conditions for a long time can be prevented.

<Composition of each layer constituting coating layer 1>
(Thermosetting resin)
The resin composition used for forming each layer constituting the coating layer 1 includes a thermosetting resin. Any thermosetting resin may be used as long as it causes polymerization upon heating to form a polymer network structure and cure. Specific examples of the thermosetting resin include epoxy resins, amino resins (melamine resins, benzoguanamine resins, etc.), acrylic resins, urethane resins, phenol resins, unsaturated polyester resins, alkyd resins, and the like.

  Among these thermosetting resins, from the viewpoints of further shortening the curing time, improving moldability and chemical resistance, etc., preferably urethane resin, epoxy resin, more preferably two-component curable urethane resin, two-component A curable epoxy resin, particularly preferably a two-component curable urethane resin is used.

  Specific examples of the two-component curable urethane resin include a combination of a polyol compound (main agent) and an isocyanate compound (curing agent). As the two-component curable epoxy resin, specifically, an epoxy resin (main agent) and , Acid anhydrides, amine compounds, or combinations of amino resins (curing agents).

  In the two-component curable urethane resin, the polyol compound used as the main agent is not particularly limited, and examples thereof include polyester polyol, polyester polyurethane polyol, polyether polyol, and polyether polyurethane polyol. These polyol compounds may be used individually by 1 type, and may be used in combination of 2 or more type.

  In the two-part curable urethane resin, the isocyanate compound used as a curing agent is not particularly limited. For example, polyisocyanate, its adduct, its isocyanurate-modified, its carbodiimide-modified, and its allophanate. A modified body, its burette modified body, etc. are mentioned. Specific examples of the polyisocyanate include diphenylmethane diisocyanate (MDI), polyphenylmethane diisocyanate (polymeric MDI), toluene diisocyanate (TDI), hexamethylene diisocyanate (HDI), and bis (4-isocyanatocyclohexyl) methane (H12MDI). , Aromatic diisocyanates such as isophorone diisocyanate (IPDI), 1,5-naphthalene diisocyanate (1,5-NDI), 3,3′-dimethyl-4,4′-diphenylene diisocyanate (TODI), xylene diisocyanate (XDI) Aliphatic diisocyanates such as tramethylene diisocyanate, hexamethylene diisocyanate, trimethylhexamethylene diisocyanate, isophorone diisocyanate DOO; 4,4'-methylenebis (cyclohexyl isocyanate), alicyclic diisocyanates such as isophorone diisocyanate; 1,5-naphthalene diisocyanate (1, 5-NDI) polycyclic aromatic diisocyanates such as are exemplified. Specific examples of the adduct include those obtained by adding trimethylolpropane, glycol and the like to the polyisocyanate. These isocyanate compounds may be used individually by 1 type, and may be used in combination of 2 or more type.

  These thermosetting resins may be crosslinkable elastomers. A crosslinkable elastomer is a thermosetting resin that can impart a soft segment to a cured product. For example, in the case of a two-component curable urethane resin or a two-component curable epoxy resin among crosslinkable elastomers, the main agent described above may have a structure capable of imparting a soft segment. The crosslinkable elastomer can be used as a part of the thermosetting resin used for forming the layer constituting the coating layer 1 so that the layer constituting the coating layer 1 has a desired elastic modulus.

  These thermosetting resins may be used alone or in combination of two or more in one layer constituting the coating layer 1. In addition, the thermosetting resin used in each layer constituting the coating layer 1 may be the same or different, and the type of the thermosetting resin depends on the function or physical property to be provided in each layer. May be selected as appropriate. For example, among the layers constituting the coating layer 1, the layer forming the outermost layer (the outermost layer located on the side opposite to the barrier layer) has a polycyclic aromatic skeleton from the viewpoint of having excellent chemical resistance. In addition, a thermosetting resin having a heterocyclic skeleton is preferably used. Specific examples of the thermosetting resin having a polycyclic aromatic skeleton include an epoxy resin having a polycyclic aromatic skeleton and a urethane resin having a polycyclic aromatic skeleton. Examples of the thermosetting resin having a heterocyclic skeleton include amino resins such as melamine resin and benzoguanamine resin. These thermosetting resins having a polycyclic aromatic skeleton and / or a heterocyclic skeleton may be either a one-component curable type or a two-component curable type.

  More specifically, as an epoxy resin having a polycyclic aromatic skeleton, a reaction product of dihydroxynaphthalene and epihalohydrin; a condensate of naphthol and aldehydes (naphthol novolak resin) and a reaction product of epihalohydrin; dihydroxy Condensate of naphthalene and aldehydes and reaction product of epihalohydrin; condensate of mono or dihydroxynaphthalene and xylylene glycol and reaction product of epihalohydrin; adduct of mono or dihydroxynaphthalene and diene compound, and epihalohydrin A reaction product of polynaphthols in which naphthols are directly coupled with epihalohydrin, and the like.

  More specifically, examples of the urethane resin having a polycyclic aromatic skeleton include a reaction product of a polyol compound and an isocyanate compound having a polycyclic aromatic skeleton.

(Curing accelerator)
The resin composition used for forming each layer constituting the coating layer 1 contains a curing accelerator. In this way, by coexisting a curing accelerator together with the thermosetting resin, each layer constituting the coating layer 1 is cured in a short time without requiring aging under high temperature conditions during production, thereby reducing the lead time. It becomes possible.

  Here, the “curing accelerator” is a substance that does not form a crosslinked structure by itself, but promotes a crosslinking reaction of a thermosetting resin, and has an action of promoting a crosslinking reaction of a thermosetting resin. Is also a substance that may form a crosslinked structure.

  The type of curing accelerator is appropriately selected according to the thermosetting resin to be used so that the hardness described above can be satisfied. For example, an amidine compound, a carbodiimide compound, a ketimine compound, a hydrazine compound, a sulfonium salt, a benzoic acid Examples include thiazolium salts and tertiary amine compounds.

  The amidine compound is not particularly limited, and examples thereof include imidazole compounds, 1,8-diazabicyclo [5.4.0] undec-7ene (DBU), 1,5-diazabicyclo [4.3.0] none. 5-ene (DBN), a guanidine compound, etc. are mentioned. Specific examples of the imidazole compound include 2-methylimidazole, 2-ethylimidazole, 2-undecylimidazole, 2,4-dimethylimidazole, 2-heptadecylimidazole, 1,2-dimethylimidazole, 1,2 -Diethylimidazole, 2-ethyl-4-methylimidazole, 2-phenylimidazole, 1-benzyl-2-phenylimidazole, 1-cyanoethyl-2-methylimidazole, 1-cyanoethyl-2-undecylimidazole, 1-benzyl- 2-methylimidazole, 2,4-diamino-6- [2′-methylimidazolyl- (1) ′]-ethyl-S-triazine, 2,4-diamino-6- [2′-ethyl-4′-methyl Imidazolyl- (1) ′]-ethyl-S-triazine, 2,4-diamino- -[2'-undecylimidazolyl] -ethyl-S-triazine, 2,4-diamino-6- [2'-methylimidazolyl- (1) ']-ethyl-S-triazine isocyanurate oxidation adduct, 2- Examples include phenyl-4-methyl-5-hydroxymethylimidazole, 2-phenyl-4,5-dihydroxymethylimidazole, 2-aryl-4,5-diphenylimidazole and the like. These amidine compounds may be used individually by 1 type, and may be used in combination of 2 or more type.

  The carbodiimide compound is not particularly limited. For example, N, N′-dicyclohexylcarbodiimide, N, N′-diisopropylcarbodiimide, 1-ethyl-3- (3-dimethylaminopropyl) carbodiimide, N- [3- ( Dimethylamino) propyl] -N'-ethylcarbodiimide, N- [3- (dimethylamino) propyl] -N'-ethylcarbodiimide methiodide, N-tert-butyl-N'-ethylcarbodiimide, N-cyclohexyl-N Examples include '-(2-morpholinoethyl) carbodiimide meso-p-toluenesulfonate, N, N'-di-tert-butylcarbodiimide, N, N'-di-p-tolylcarbodiimide, and the like. These carbodiimide compounds may be used individually by 1 type, and may be used in combination of 2 or more type.

  The ketimine compound is not particularly limited as long as it has a ketimine bond (N = C), and examples thereof include a ketimine compound obtained by reacting a ketone with an amine. Specific examples of the ketone include methyl ethyl ketone, methyl isopropyl ketone, methyl tertiary butyl ketone, methyl cyclohexyl ketone, diethyl ketone, ethyl propyl ketone, ethyl butyl ketone, dipropyl ketone, dibutyl ketone, and diisobutyl ketone. Specific examples of the amine include o-phenylenediamine, m-phenylenediamine, p-phenylenediamine, m-xylylenediamine, diaminodiphenylmethane, diaminodiphenylsulfone, and diaminodiethyldiphenylmethane; ethylenediamine , Propylenediamine, butylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, pentaethylenehexamine, hexamethylenediamine, trimethylhexamethylenediamine, 1,2-propanediamine, iminobispropylamine, methyliminobispropylamine, etc. Aliphatic polyamines; N-aminoethylpiperazine, 3-butoxyisopropylamine and the like monoamines and polyesters having an ether bond in the main chain Terpone diamines; cyclophoric amines such as isophorone diamine, 1,3-bisaminomethylcyclohexane, 1-cyclohexylamino-3-aminopropane, 3-aminomethyl-3,3,5-trimethylcyclohexylamine: norbornane skeleton Polyamide amine having an amino group at the molecular end of polyamide; 2,5-dimethyl-2,5-hexamethylenediamine, mensendiamine, 1,4-bis (2-amino-2-methylpropyl) piperazine, etc. Is given as a specific example. These ketimine compounds may be used individually by 1 type, and may be used in combination of 2 or more type.

  The hydrazine compound is not particularly limited, and examples thereof include dipic acid dihydrazide and isophthalic acid dihydrazide. These hydrazine compounds may be used individually by 1 type, and may be used in combination of 2 or more type.

  The sulfonium salt is not particularly limited. For example, 4-acetophenyldimethylsulfonium hexafluoroantimonate, 4-acetophenyldimethylsulfonium hexafluoroarsenate, dimethyl-4- (benzyloxycarbonyloxy) phenylsulfonium hexafluoroantimony , Alkylsulfonium salts such as dimethyl-4- (benzoyloxy) phenylsulfonium hexafluoroantimonate, dimethyl-4- (benzoyloxy) phenylsulfonium hexafluoroarsenate; benzyl-4-hydroxyphenylmethylsulfonium hexafluoroantimonate, 4-acetoxyphenylbenzylmethylsulfonium hexafluoroantimonate, benzyl-4-methoxypheny Benzylsulfonium salts such as methylsulfonium hexafluoroantimonate, benzyl-3-chloro-4-hydroxyphenylmethylsulfonium hexafluoroarsenate, 4-methoxybenzyl-4-hydroxyphenylmethylsulfonium hexafluorophosphate; dibenzyl-4-hydroxyphenyl Dibenzylsulfonium such as sulfonium hexafluoroantimonate, dibenzyl-4-hydroxyphenylsulfonium hexafluorophosphate, dibenzyl-4-methoxyphenylsulfonium hexafluoroantimonate, benzyl-4-methoxybenzyl-4-hydroxyphenylsulfonium hexafluorophosphate Salt; p-chlorobenzyl-4-hydroxyphenylmethylsulfonium hexa Luoantimonate, p-nitrobenzyl-4-hydroxyphenylmethylsulfonium hexafluoroantimonate, 3,5-dichlorobenzyl-4-hydroxyphenylmethylsulfonium hexafluoroantimonate, o-chlorobenzyl-3-chloro-4- Examples thereof include substituted benzylsulfonium salts such as hydroxyphenylmethylsulfonium hexafluoroantimonate. These sulfonium salts may be used individually by 1 type, and may be used in combination of 2 or more type.

  The benzothiazolium salt is not particularly limited. For example, 3-benzylbenzothiazolium hexafluoroantimonate, 3-benzylbenzothiazolium hexafluorophosphate, 3-benzylbenzothiazolium tetrafluoroborate, Such as 3- (p-methoxybenzyl) benzothiazolium hexafluoroantimonate, 3-benzyl-2-methylthiobenzothiazolium hexafluoroantimonate, 3-benzyl-5-chlorobenzothiazolium hexafluoroantimonate Benzylbenzothiazolium salt. These benzothiazolium salts may be used individually by 1 type, and may be used in combination of 2 or more type.

  The tertiary amine compound is not particularly limited, and examples thereof include trimethylamine, triethylamine, tripropylamine, tributylamine, triethylenediamine, 1,4-diazabicyclo [2.2.2] octane, quinuclidine, and 3-quinuclidinol. And aliphatic tertiary amines; aromatic tertiary amines such as dimethylaniline; and heterocyclic tertiary amines such as isoquinoline, pyridine, collidine, and betapicoline. These tertiary amine compounds may be used individually by 1 type, and may be used in combination of 2 or more type.

  As a suitable example of the said hardening accelerator, what functions as a thermal acid generator is mentioned. A thermal acid generator is a substance that generates an acid by heating and functions as a curing accelerator. Specific examples of the curing accelerator that can function as a thermal acid generator include sulfonium salts and benzothiazolium salts.

  In addition, another suitable example of the curing accelerator is a thermal latent that is activated under a predetermined heating condition (for example, 80 to 2000 ° C., preferably 100 to 160 ° C.) to promote the crosslinking reaction of the thermosetting resin. The thing with sex is mentioned. Among the above-mentioned curing accelerators, specific examples of the heat-latent substance include an epoxy adduct obtained by adding an epoxy compound to an amidine compound, a hydrazine compound, a tertiary amine compound, or the like.

  Furthermore, as another preferable example of the curing accelerator, it does not function as a curing agent in a sealed state, that is, in a moisture blocking state, but the sealed state is opened and hydrolyzed under the presence of moisture as a curing agent. Those having a hydrolytic potential that functions. Among the above-mentioned curing accelerators, specific examples of the hydrolytic latent substance include an epoxy adduct obtained by adding an epoxy compound to an amidine compound, a hydrazine compound, a tertiary amine compound, or the like.

  These hardening accelerators may be used individually by 1 type, and may be used in combination of 2 or more type. Among these curing accelerators, an amidine compound and a sulfonium salt are preferable, and an amidine compound is more preferable.

  These curing accelerators may be used alone or in combination of two or more in one layer constituting the coating layer 1. Moreover, the hardening accelerator used by each layer which comprises the coating layer 1 may be the same, or may differ, The kind of hardening accelerator is suitably according to the function with which each layer should be equipped, a physical property, etc. Just choose.

  About content of the hardening accelerator in the resin composition used for formation of the coating layer 1, although it sets suitably according to the kind of thermosetting resin to be used, the kind of hardening accelerator, etc., for example, thermosetting The curing accelerator is 0.01 to 6 parts by mass, preferably 0.05 to 5 parts by mass, and more preferably 0.1 to 2 parts by mass with respect to 100 parts by mass of the conductive resin.

(Pigments and / or dyes)
The at least one layer constituting the coating layer 1 may contain a pigment and / or a dye as necessary. By including a pigment and / or dye in at least one layer constituting the coating layer 1, the battery packaging material can be given distinctiveness (colored by the pigment and / or dye), and further the battery packaging material. The heat conductivity can be increased to improve the heat dissipation.

  The material of the pigment is not particularly limited and may be either an inorganic pigment or an organic pigment. Specific examples of inorganic pigments include carbon black, carbon nanotube, graphite, talc, silica, kaolin, montmorillonite, montmorillonite, synthetic mica, hydrotalcite, zeolite, aluminum hydroxide, magnesium hydroxide, zinc oxide, and oxidation. Examples include magnesium, aluminum oxide, neodymium oxide, antimony oxide, titanium oxide, cerium oxide, calcium sulfate, barium sulfate, calcium carbonate, calcium silicate, lithium carbonate, gold, aluminum, copper, nickel, and the like. Specific examples of the organic pigment include azo pigments, polycyclic pigments, lake pigments, and fluorescent pigments. These pigments may be used alone or in combination of two or more.

  The shape of the pigment is not particularly limited, and examples thereof include a spherical shape, a fiber shape, a plate shape, an indefinite shape, and a balloon shape. Further, the average particle diameter of the pigment is not particularly limited, but for example, 0.01 to 3 μm, preferably 0.05 to 1 μm. The average particle size of the pigment is determined by using the Shimadzu laser diffraction particle size distribution analyzer SALD-2100-WJA1 and using compressed air to inject the powder to be measured from the nozzle and dispersing it in the air. It is a value measured by the jet type dry measurement method to be measured.

  If necessary, the pigment may be subjected to various surface treatments such as insulation treatment and high dispersibility treatment (resin coating treatment) on the surface.

  The type of the dye is not particularly limited as long as it can be dissolved and dispersed in the resin composition used for forming the coating layer 1. For example, nitro dye, azo dye, stilbene dye, carbonium dye, quinoline Examples thereof include dyes, methine dyes, thiazole dyes, quinimine dyes, anthraquinone dyes, indigoid dyes, and phthalocyanine dyes, and preferred examples include azo dyes, carbonium dyes, and anthraquinone dyes. These dyes may be used alone or in combination of two or more.

  Among these pigments and dyes, from the viewpoint of further improving the heat dissipation of the battery packaging material, preferably a pigment, more preferably an inorganic pigment, more preferably a carbon material such as carbon black, carbon nanotube, and graphite, particularly Preferably, carbon black is used.

  In order to include a pigment when the coating layer 1 has a multilayer structure composed of two or more layers, the pigment and / or the dye is contained in any one of these two or more layers. It may be contained, and may be contained in two or more layers. From the viewpoint of reducing the difference in color tone between the molded part and the non-molded part after the battery packaging material is molded, the coating layer 1 has a multi-layer structure composed of two or more layers. It is preferable to contain a pigment and / or dye in this layer, and it is more preferable that the coating layer 1 has a three-layer structure composed of three layers, and that all three layers contain the pigment and / or dye.

  When the pigment and / or dye is contained in at least one layer constituting the coating layer 1, the content of the pigment and / or the dye used, the distinguishability to be imparted to the battery packaging material, and heat dissipation It may be set as appropriate according to the properties, etc., for example, the pigment and / or dye is 1 to 30 parts by mass in total with respect to 100 parts by mass of the thermosetting resin contained in the layer containing the pigment and / or dye. Is mentioned. From the viewpoint of imparting even better discrimination, the total amount of pigment and / or dye is 3 to 20 parts by mass with respect to 100 parts by mass of the thermosetting resin contained in the layer containing the pigment and / or dye. Can be mentioned. Moreover, from the viewpoint of suppressing the deterioration of the moldability caused by the pigment and / or dye together with the further excellent discrimination, with respect to 100 parts by mass of the thermosetting resin contained in the layer containing the pigment and / or dye. In addition, the total amount of pigment and / or dye is 5 to 15 parts by mass.

(Other additives)
The resin composition used for forming each layer constituting the coating layer 1 includes an organic filler, a slip agent, a solvent, as necessary, in addition to the components described above, depending on the functionality to be provided in each layer. Other additives such as elastomer resins may be included.

  The surface of the battery packaging material of the present invention, when an organic filler or slip agent is contained in the layer forming the outermost layer (the outermost layer located on the side opposite to the barrier layer) among the layers constituting the coating layer 1 It is possible to impart a slip effect to the film, improve the formability / workability in press forming and embossing, and improve the operability.

  The type of the organic filler is not particularly limited, and examples thereof include high melting point nylon, crosslinked acrylic, crosslinked styrene, crosslinked polyethylene, and benzoguanamine. The shape of the organic filler is not particularly limited, and examples thereof include a spherical shape, a fiber shape, a plate shape, an indeterminate shape, and a balloon shape.

  Moreover, it does not restrict | limit especially as a slip agent, A non-reactive slip agent may be sufficient and a reactive slip agent may be sufficient. In particular, the reactive slip agent is less likely to lose bleed from the outermost layer constituting the coating layer 1, and can suppress the occurrence of powder blowing or set-off during use, or a reduction in slip effect over time. Among these slip agents, a reactive slip agent is preferable.

  Here, the non-reactive slip agent is a compound that does not have a functional group that chemically reacts with the thermosetting resin and can impart slip properties (slip properties). The reactive slip agent is a compound that has a functional group that reacts with the thermosetting resin and chemically binds, and can impart slip properties (slip properties).

  Specific examples of the non-reactive slip agent include fatty acid amide, metal soap, hydrophilic silicone, silicone-grafted acrylic, silicone-grafted epoxy, silicone-grafted polyether, silicone-grafted polyester, Examples thereof include block type silicone acrylic copolymer, polyglycerol-modified silicone, paraffin and the like. These non-reactive slip agents may be used individually by 1 type, and may be used in combination of 2 or more type.

  In the reactive slip agent, the type of functional group is appropriately set according to the type of thermosetting resin to be used. For example, hydroxyl group, mercapto group, hydrolyzable silyl group, isocyanate group, epoxy group A polymerizable vinyl group, a (meth) acryloyl group, and the like. In the reactive slip agent, the number of functional groups per molecule is not particularly limited, and examples thereof include 1 to 3, preferably 1 or 2.

  Specific examples of reactive slip agents include modified silicones having the above functional groups; modified fluororesins having the above functional groups; fatty acid amides such as stearic acid amide, oleic acid amide, erucic acid amide, and ethylene bis-stearic acid amide. On the other hand, there can be mentioned compounds having the functional group introduced therein; metal soaps having the functional group introduced therein; paraffins having the functional group introduced therein. These reactive slip agents may be used individually by 1 type, and may be used in combination of 2 or more type. Among these reactive slip agents, the modified silicone having the functional group, the fluororesin having the functional group, and the silicone-modified resin having the functional group are preferable. As the modified silicone, specifically, a modified silicone obtained by block polymerization of a polymer having the functional group, such as a modified silicone obtained by block polymerization of an acrylic resin; a modified silicone obtained by graft polymerization of an acrylate, or the like, Examples thereof include modified silicone obtained by graft polymerization of a monomer having a functional group. Further, as the modified fluororesin, specifically, a modified fluororesin in which a monomer having the functional group is graft-polymerized, such as a fluororesin in which acrylate is graft-polymerized; modified fluorine in which an acrylic resin is block-polymerized Examples of the resin include a fluororesin in which a polymer having the functional group is block polymerized. Further, as the silicone-modified resin, specifically, the silicone having a functional group and the silicone having undergone graft polymerization, such as a silicone-modified acrylic resin in which silicone is graft-polymerized to the acrylic resin having the functional group. Examples include silicone-modified resins. Further, as the modified fluororesin, specifically, a modified fluororesin in which a monomer having the functional group is graft-polymerized, such as a fluororesin in which acrylate is graft-polymerized; modified fluorine in which an acrylic resin is block-polymerized Examples of the resin include a fluororesin in which a polymer having the functional group is block polymerized. Among these, as a particularly preferable reactive slip agent, a modified silicone in which the monomer or polymer having the functional group is polymerized at one terminal of the silicone; the monomer or polymer having the functional group is fluorine. Examples thereof include a modified fluororesin that is polymerized at one end of the resin. As such modified silicone and modified fluororesin, for example, “Modiper (registered trademark) F / FS series” (manufactured by NOF Corporation), “Symac (registered trademark) series” (manufactured by Toagosei Co., Ltd.) and the like are commercially available. These commercial products can also be used.

  When the slip agent is contained in the resin composition used to form the outermost layer in the coating layer 1, the content is not particularly limited. For example, for 100 parts by mass of the thermosetting resin The total amount of the slip agent is 1 to 12 parts by mass, preferably 3 to 10 parts by mass, and more preferably 5 to 8 parts by mass.

<Physical properties of each layer constituting the coating layer 1>
The physical properties of each layer constituting the coating layer 1 are not particularly limited, and may be appropriately set according to the functionality to be imparted, but the viewpoint of providing the battery packaging material of the present invention with excellent moldability. Therefore, it is preferable that the elastic modulus of all the layers constituting the coating layer satisfy 1500 to 6000 MPa. From the viewpoint of further improving the moldability, the elastic modulus of all layers constituting the coating layer is further preferably 2000 to 5500 MPa.

  In addition, at least one of the layers constituting the coating layer 1 is preferably a layer having an elastic modulus of 2500 to 6000 MPa (hereinafter sometimes referred to as “high elastic modulus layer”). By having at least one such high elastic modulus layer in the layer constituting the coating layer 1, it is possible to provide excellent resistance to chemicals such as electrolytes, acids, alkalis and organic solvents. . From the viewpoint of providing even more excellent chemical resistance, the elastic modulus of the high elastic modulus layer is more preferably 3000 to 6000 Mpa. From the viewpoint of chemical resistance, the high elastic modulus layer may be provided in at least one layer constituting the coating layer 1, but two or more or all the layers constituting the coating layer 1 have a high elastic modulus. It may be a layer. The high elastic modulus layer is not particularly limited with respect to the portion disposed in the coating layer 1, and is the outermost layer (the outermost surface located on the side opposite to the barrier layer), the layer in contact with the barrier layer, the coating When the layer 1 has a multilayer structure of three or more layers, it may be disposed between the outermost layer and the layer in contact with the barrier layer, but the viewpoint of effectively providing chemical resistance. Therefore, the outermost layer is preferable.

Moreover, the following aspect is illustrated as a suitable example of the coating layer 1 from a viewpoint of providing the moldability and chemical-resistance which were excellent in the battery packaging material of this invention:
When the coating layer 1 has a two-layer structure: the elastic modulus of the layer in contact with the barrier layer is 1500 to 6000 Mpa, preferably 2000 to 3500 Mpa; the elastic modulus of the outermost layer is 3000 to 6000 MPMpa, preferably 3000 to 5500 Mpa.
When the coating layer 1 has a three-layer structure: the elastic modulus of the layer in contact with the barrier layer is 1500 to 6000 Mpa, preferably 2000 to 3500 Mpa; the elasticity of the layer between the outermost layer and the layer in contact with the barrier layer The rate is 1500 to 6000 Mpa, preferably 2200 to 4500 Mpa; the elastic modulus of the outermost layer is 3000 to 6000 Mpa, preferably 3000 to 5500 Mpa, more preferably 3000 to 5500.

  In order to set the elastic modulus of each layer constituting the coating layer 1 within the above-described range, it is performed by appropriately adjusting the type of thermosetting resin used for forming each layer, the type and amount of the curing accelerator, and the like. Can do. Specifically, a desired elastic modulus can be set by appropriately adjusting the amount and type of the crosslinkable elastomer in the thermosetting resin used for forming each layer.

  In this specification, the elastic modulus is a value measured by a nanoindentation method. Specifically, using a nanoindenter, the tip shape is a regular triangular pyramid (Berkovic type) composed of a diamond tip. This is obtained by using the obtained load-indentation depth curve by pushing the indenter into the layer to be measured and continuously measuring the indentation depth during loading and unloading.

<Thickness of coating layer 1>
As thickness of each layer which comprises the coating layer 1, 1-5 micrometers is mentioned, for example, Preferably 2-4 micrometers is mentioned.

  The thickness of the coating layer 1 as a whole varies depending on the number of layers constituting the coating layer 1 and cannot be uniformly defined, but is usually 2 to 25 μm, preferably 4 to 20 μm.

[Barrier layer 2]
In the battery packaging material of the present invention, the barrier layer 2 is a layer that functions as a barrier layer for preventing moisture, oxygen, light, and the like from entering the battery, in addition to improving the strength of the packaging material. Specific examples of the material of the barrier layer 2 include metal foils such as aluminum, stainless steel, and titanium; films obtained by vapor deposition of inorganic compounds such as silicon oxide and alumina. Among these, metal foil is preferable, and aluminum foil is more preferable. In order to prevent wrinkles and pinholes during the production of battery packaging materials, the barrier layer 2 in the present invention is a soft aluminum foil, for example, annealed aluminum (JIS A8021P-O) or (JIS A8079P-O) foil. Etc. are preferably used.

  Although it does not restrict | limit especially about the thickness of the barrier layer 2, For example, when using metal foil, 10-200 micrometers normally, Preferably 20-100 micrometers is mentioned.

  Further, when a metal foil is used as the barrier layer 2, at least one surface, preferably at least the surface on the sealant layer side, and more preferably both surfaces are subjected to chemical conversion treatment in order to stabilize adhesion, prevent dissolution and corrosion, and the like. It is preferable. Here, the chemical conversion treatment is a treatment for forming an acid-resistant film on the surface of the barrier layer 2. Chemical conversion treatment is, for example, chromate chromate treatment using a chromic acid compound such as chromium nitrate, chromium fluoride, chromium sulfate, chromium acetate, chromium oxalate, chromium biphosphate, chromic acetyl acetate, chromium chloride, potassium sulfate chromium, etc. ; Phosphoric acid chromate treatment using phosphoric acid compounds such as sodium phosphate, potassium phosphate, ammonium phosphate, polyphosphoric acid; aminated phenol heavy consisting of repeating units represented by the following general formulas (1) to (4) Examples thereof include chromate treatment using a coalescence.

In general formulas (1) to (4), X represents a hydrogen atom, a hydroxyl group, an alkyl group, a hydroxyalkyl group, an allyl group or a benzyl group. R ₁ and R ₂ are the same or different and represent a hydroxyl group, an alkyl group, or a hydroxyalkyl group. In the general formulas (1) to (4), examples of the alkyl group represented by X, R ₁ and R ₂ include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, an isobutyl group, C1-C4 linear or branched alkyl groups, such as a tert- butyl group, are mentioned. Examples of the hydroxyalkyl group represented by X, R ₁ and R ₂ include a hydroxymethyl group, a 1-hydroxyethyl group, a 2-hydroxyethyl group, a 1-hydroxypropyl group, a 2-hydroxypropyl group, 3- A linear or branched chain having 1 to 4 carbon atoms substituted with one hydroxy group such as hydroxypropyl group, 1-hydroxybutyl group, 2-hydroxybutyl group, 3-hydroxybutyl group, 4-hydroxybutyl group An alkyl group is mentioned. be able to. In the general formulas (1) to (4), X is preferably any one of a hydrogen atom, a hydroxyl group, and a droxyalkyl group. The number average molecular weight of the aminated phenol polymer composed of the repeating units represented by the general formulas (1) to (4) is, for example, about 500 to about 1,000,000, preferably about 1000 to about 20,000.

  Further, as a chemical conversion treatment method for imparting corrosion resistance to the metal foil, a metal oxide such as aluminum oxide, titanium oxide, cerium oxide, tin oxide or the like, in which fine particles of barium sulfate are dispersed in phosphoric acid, is coated. A method of forming a corrosion-resistant treatment layer on the surface of the metal foil by performing a baking treatment at a temperature of 0 ° C. or higher can be mentioned. A resin layer obtained by crosslinking a cationic polymer with a crosslinking agent may be formed on the corrosion-resistant treatment layer. Here, as the cationic polymer, for example, polyethyleneimine, an ionic polymer complex composed of a polymer having polyethyleneimine and a carboxylic acid, a primary amine-grafted acrylic resin in which a primary amine is grafted on an acrylic main skeleton, polyallylamine, or Examples thereof include aminophenols and derivatives thereof. These cationic polymers may be used individually by 1 type, and may be used in combination of 2 or more type. Examples of the crosslinking agent include compounds having at least one functional group selected from the group consisting of isocyanate groups, glycidyl groups, carboxyl groups, and oxazoline groups, silane coupling agents, and the like. These crosslinking agents may be used alone or in combination of two or more.

  These chemical conversion treatments may be performed alone or in combination of two or more chemical conversion treatments. Furthermore, these chemical conversion treatments may be carried out using one kind of compound alone, or may be carried out using a combination of two or more kinds of compounds. Among these, chromic acid chromate treatment is preferable, and chromate treatment in which a chromic acid compound, a phosphoric acid compound, and the aminated phenol polymer are combined is more preferable.

The amount of the acid-resistant film to be formed on the surface of the metal foil in the chemical conversion treatment is not particularly limited. For example, if the chromate treatment is performed by combining a chromic acid compound, a phosphoric acid compound, and the aminated phenol polymer, for example. The chromic acid compound is about 0.5 to about 50 mg, preferably about 1.0 to about 40 mg in terms of chromium, and the phosphorus compound is about 0.5 to about 50 mg in terms of phosphorus per 1 m ² of the surface of the metal foil. About 1.0 to about 40 mg, and the aminated phenol polymer is desirably contained in an amount of about 1 to about 200 mg, preferably about 5.0 to 150 mg.

  In the chemical conversion treatment, a solution containing a compound used for forming an acid-resistant film is applied to the surface of the metal foil by a bar coating method, a roll coating method, a gravure coating method, a dipping method or the like, and then the temperature of the metal foil is 70. It is carried out by heating to about 200 ° C. In addition, before the chemical conversion treatment is performed on the barrier layer 2, the metal foil may be subjected to a degreasing treatment by an alkali dipping method, an electrolytic cleaning method, an acid cleaning method, an electrolytic acid cleaning method, or the like in advance. By performing the degreasing treatment in this way, it becomes possible to more efficiently perform the chemical conversion treatment on the surface of the metal foil.

[Sealant layer 3]
In the battery packaging material of the present invention, the sealant layer 3 corresponds to the innermost layer and is a layer that seals the battery element by heat-sealing the sealant layers when the battery is assembled.

  The resin component used in the sealant layer 3 is not particularly limited as long as it can be thermally welded, and examples thereof include polyolefin, cyclic polyolefin, carboxylic acid-modified polyolefin, and carboxylic acid-modified cyclic polyolefin.

  Specific examples of the polyolefin include polyethylene such as low density polyethylene, medium density polyethylene, high density polyethylene, and linear low density polyethylene; homopolypropylene, polypropylene block copolymer (for example, block copolymer of propylene and ethylene), polypropylene Crystalline polypropylene or amorphous polypropylene such as a random copolymer of propylene and ethylene; an ethylene-butene-propylene terpolymer; and the like. Among these polyolefins, polyethylene and polypropylene are preferable.

  The cyclic polyolefin is a copolymer of an olefin and a cyclic monomer, and examples of the olefin that is a constituent monomer of the cyclic polyolefin include ethylene, propylene, 4-methyl-1-pentene, styrene, butadiene, and isoprene. Is mentioned. Examples of the cyclic monomer that is a constituent monomer of the cyclic polyolefin include cyclic alkenes such as norbornene; specifically, cyclic dienes such as cyclopentadiene, dicyclopentadiene, cyclohexadiene, and norbornadiene. Among these polyolefins, cyclic alkene is preferable, and norbornene is more preferable.

  The carboxylic acid-modified polyolefin is a polymer obtained by modifying the polyolefin with a carboxylic acid. Examples of the carboxylic acid used for modification include maleic acid, acrylic acid, itaconic acid, crotonic acid, maleic anhydride, itaconic anhydride and the like.

  The carboxylic acid-modified cyclic polyolefin is obtained by copolymerizing a part of the monomer constituting the cyclic polyolefin in place of the α, β-unsaturated carboxylic acid or its anhydride, or α, β with respect to the cyclic polyolefin. -A polymer obtained by block polymerization or graft polymerization of an unsaturated carboxylic acid or its anhydride. The cyclic polyolefin to be modified with carboxylic acid is the same as described above. The carboxylic acid used for modification is the same as that used for modification of the acid-modified cycloolefin copolymer.

  Among these resin components, preferably a crystalline or amorphous polyolefin, a cyclic polyolefin, and a blend polymer thereof; more preferably polyethylene, polypropylene, a copolymer of ethylene and norbornene, and two or more of these The blend polymer of these is mentioned.

  The sealant layer 3 may be formed of one kind of resin component alone or may be formed of a blend polymer in which two or more kinds of resin components are combined. Furthermore, the sealant layer may be formed of only one layer, but may be formed of two or more layers using the same or different resin components.

  Further, the thickness of the sealant layer 3 is not particularly limited, but may be 2 to 2000 μm, preferably 5 to 1000 μm, and more preferably 10 to 500 μm.

[Adhesive layer 4]
In the battery packaging material of the present invention, the adhesive layer 4 is a layer provided between the barrier layer 2 and the sealant layer 3 as necessary in order to firmly bond them.

  The adhesive layer 4 is formed of an adhesive resin composition that can adhere the barrier layer 2 and the sealant layer 3. The adhesive component used for forming the adhesive layer 4 is not particularly limited as long as the barrier layer 2 and the sealant layer 3 can be bonded, and may be a two-component curable adhesive. A curable adhesive may be used. Further, the adhesion mechanism of the adhesive component used for forming the adhesive layer 4 is not particularly limited, and may be any of a chemical reaction type, a solvent volatilization type, a heat melting type, a hot pressure type, and the like. Polyester resins such as polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polybutylene naphthalate, polyethylene isophthalate, polycarbonate, and copolyester; polyether adhesives; polyurethane adhesives; epoxy resins; phenol resin resins Polyamide resins such as nylon 6, nylon 66, nylon 12 and copolymerized polyamides; polyolefin resins such as polyolefins, carboxylic acid modified polyolefins, metal modified polyolefins, polyvinyl acetate resins; cellulose adhesives; (meth) acrylic Tree ; Polyimide resin; urea resins, amino resins such as melamine resins; - chloroprene rubbers, nitrile rubbers, styrene rubbers such as butadiene rubber, silicone-based resins.

  The adhesive resin composition used for forming the adhesive layer 4 from the standpoint of shortening the lead time by curing in a short time without requiring aging under high temperature conditions during production, and further improving moldability As a thing, Preferably, the thermosetting resin and the resin composition for contact bonding layers containing a hardening accelerator are mentioned. By using a thermosetting resin and a curing accelerator in combination, the lead time can be shortened by curing in a short time without requiring aging under high temperature conditions. Further, by further containing an elastomer resin, the adhesive layer 4 is imparted with appropriate flexibility while suppressing shrinkage of the adhesive layer 4 during curing, and the battery packaging material has excellent moldability. Is possible.

  The types and preferred types of thermosetting resins and curing accelerators used in the adhesive layer resin composition, the content thereof, and the like are the same as in the case of the coating layer 1.

  About the thickness of the contact bonding layer 4, 2-50 micrometers, for example, Preferably 3-25 micrometers is mentioned.

3. Thickness of Battery Packaging Material Since the battery packaging material of the present invention does not have a base layer made of an adhesive layer and a resin film on the barrier layer 3, it is made thinner than conventional film-like battery packaging materials. be able to. About the thickness of the whole battery packaging material of this invention, 40-120 micrometers is mentioned, for example, Preferably 50-100 micrometers is mentioned.

4). Method for Producing Battery Packaging Material The method for producing the battery packaging material of the present invention is not particularly limited as long as a laminate in which layers having a predetermined composition are laminated is obtained. For example, the following method is exemplified. :
Coating having a multilayer structure of two or more layers on the barrier layer 2 by repeatedly applying a resin composition containing a thermosetting resin and a curing accelerator to the barrier layer 2 and curing by heating twice or more. Including a coating layer forming step of forming layer 1;
Before, during or after the coating layer forming step, the sealant layer 3 is laminated on the surface of the barrier layer 2 opposite to the surface on which the coating layer 1 is laminated.

  Application | coating of the resin composition to the barrier layer 2 in the said coating layer process can be performed by application methods, such as a gravure coat method and a roll coat method. Moreover, as a heating condition at the time of hardening the resin composition apply | coated on the barrier layer 2, it is 90-200 degreeC, for example, Preferably it is 100-190 degreeC, 0.1 to 60 second, Preferably it is 1 to 30 second Is mentioned.

  As described above, in the present invention, the aging under the high temperature condition is not required in the coating layer forming step, and it can be sufficiently cured only by the heating condition, so that the lead time can be greatly shortened.

  Lamination of the sealant layer 3 on the barrier layer 2 may be performed at any timing before, during or after the coating layer forming step, but is preferably performed after the coating layer forming step. When the sealant layer 3 is directly laminated on the barrier layer 2, the resin component constituting the sealant layer 3 may be applied on the barrier layer 2 by a method such as a gravure coating method or a roll coating method. When the adhesive layer 4 is provided between the barrier layer 2 and the sealant layer 3, for example, (1) a method of laminating the adhesive layer 4 and the sealant layer 3 on the barrier layer 2 by coextrusion (co- Extrusion lamination method), (2) Separately, a laminate in which the adhesive layer 4 and the sealant layer 3 are laminated, and this is laminated on the barrier layer 2 by the thermal lamination method. (3) On the barrier layer 2, An adhesive for forming the adhesive layer 4 is laminated by an extrusion method, a solution-coated high temperature drying or baking method, and the sealant layer 3 previously formed into a sheet shape on the adhesive layer 4 by a thermal lamination method. (4) Laminate A and sealant layer 3 through adhesive layer 4 while pouring molten adhesive layer 4 between barrier layer 2 and sealant layer 3 formed into a sheet in advance. Be bonded method (sand lamination method), and the like.

  As described above, a laminate comprising coating layer 1 (two or more layers) / barrier layer 2 whose surface is subjected to chemical conversion treatment as necessary / adhesive layer 4 / sealant layer 3 provided as necessary It is formed.

  In the battery packaging material of the present invention, each layer constituting the laminate is improved or stabilized as necessary in terms of film-forming properties, lamination processing, suitability for final processing (pouching, embossing), etc. In order to do so, surface activation treatment such as corona treatment, blast treatment, oxidation treatment, ozone treatment, etc. may be performed.

5. Application of Battery Packaging Material The battery packaging material of the present invention is used by being molded into a desired shape as a packaging material for sealing and housing battery elements such as a positive electrode, a negative electrode, and an electrolyte.

  Specifically, a battery element including at least a positive electrode, a negative electrode, and an electrolyte is formed using the battery packaging material of the present invention, with the metal terminals connected to each of the positive electrode and the negative electrode protruding outward. A battery packaging material was used by covering the periphery of the element so that a flange portion (a region where the sealant layers 3 contact each other) can be formed, and heat sealing the sealant layers 3 of the flange portion together. A battery is provided. In addition, when accommodating a battery element using the battery packaging material of the present invention, the battery packaging material of the present invention is used such that the sealant portion is on the inner side (surface in contact with the battery element).

  The battery packaging material of the present invention may be used for either a primary battery or a secondary battery, but is preferably a secondary battery. The type of secondary battery to which the battery packaging material of the present invention is applied is not particularly limited. For example, a lithium ion battery, a lithium ion polymer battery, a lead battery, a nickel / hydrogen battery, a nickel / cadmium battery , Nickel / iron livestock batteries, nickel / zinc livestock batteries, silver oxide / zinc livestock batteries, metal-air batteries, polyvalent cation batteries, capacitors, capacitors and the like. Among these secondary batteries, lithium ion batteries and lithium ion polymer batteries are suitable applications for the battery packaging material of the present invention.

  Hereinafter, the present invention will be described in detail with reference to Examples and Comparative Examples. However, the present invention is not limited to the examples.

Example 1-87 and Comparative Example 1-15
[Manufacture of battery packaging materials]
A coating layer having a two- or three-layer structure was formed on a barrier layer made of an aluminum foil (thickness 40 μm) subjected to chemical conversion treatment on both sides. Specifically, in the embodiment shown in Tables 3 to 8 on the barrier layer, application and curing of the resin composition that forms the barrier layer side layer of the coating layer, application and curing of the resin composition that forms the intermediate layer, A coating layer having a two- or three-layer structure was laminated on the barrier layer by sequentially applying and curing the resin composition forming the outermost layer. In addition, about the composition of the resin composition used for formation of each layer which comprises a coating layer, and hardening conditions, it is as showing in Table 1 and 2. FIG. In addition, for each layer constituting the coating layer, using a nanoindenter, the tip shape of a regular triangular pyramid (Berkovic) indenter consisting of a diamond tip is pushed into the layer to be measured, and the indentation depth during loading and unloading Tables 1 and 2 show the elastic moduli obtained by continuously measuring.

In addition, the chemical conversion treatment of the aluminum foil used as the barrier layer was performed by roll coating a treatment liquid composed of a phenol resin, a chromium fluoride compound, and phosphoric acid so that the coating amount of chromium was 10 mg / m ² (dry weight). The coating was performed on both surfaces of the aluminum foil by the method and baked for 20 seconds under the condition that the film temperature was 180 ° C. or higher.

  Thereafter, the barrier layer is formed by co-extruding carboxylic acid-modified polypropylene (arranged on the barrier layer side, thickness 23 μm) and homopolypropylene (innermost layer, thickness 23 μm) on the side of the barrier layer where the coating layer is not laminated. A two-layer sealant layer was laminated on the layer. Thus, a battery packaging material comprising a laminate in which a coating layer / barrier layer 4 / sealant layer having a two- or three-layer structure was sequentially laminated was obtained.

In addition, the battery packaging materials of Comparative Examples 1 to 15 are layers in which at least one layer constituting the coating layer is cured with only a thermosetting resin without containing a curing accelerator.
Moreover, the battery packaging materials of Examples 1 to 87 have the following structure and physical properties of the coating layer.
Examples 1-3 : It has a two-layer structure, and the elastic modulus of both the barrier layer side layer and the outermost layer is 1500-2499 MPa.
Examples 4 to 7 : It has a two-layer structure, the elastic modulus of the layer on the barrier layer side is 1500 to 2499 MPa, and the elastic modulus of the outermost layer is 2500 to 5999 MPa.
Examples 5 to 7 : It has a two-layer structure, the elastic modulus of the layer on the barrier layer side is 1500 to 2499 MPa, and the elastic modulus of the outermost layer is 2500 to 5999 MPa.
Examples 8 and 9 : Two-layer structure, the elastic modulus of the layer on the barrier layer side is 1500 to 2499 MPa, and the elastic modulus of the outermost layer is 6000 MPa or more.
Examples 10-13 : It has a two-layer structure, the elastic modulus of the layer on the barrier layer side is 2500-5999 MPa, and the elastic modulus of the outermost layer is 1500-2499 MPa.
Examples 14 and 15 : Two-layer structure, the elastic modulus of the layer on the barrier layer side is 6000 MPa or more, and the elastic modulus of the outermost layer is 1500 to 2499 MPa.
Examples 16 to 23 : It has a two-layer structure, and both the barrier layer side layer and the outermost layer have an elastic modulus of 2500 to 5999 MPa.
Examples 24-26 : It has a two-layer structure, the elastic modulus of the layer on the barrier layer side is 2500 to 5999 MPa, and the elastic modulus of the outermost layer is 6000 MPa or more.
Example 27 : It has a two-layer structure, the elastic modulus of the layer on the barrier layer side is 6000 MPa or more, and the elastic modulus of the outermost layer is 1500 to 2499 MPa.
Examples 28 and 29 : It has a two-layer structure, the elastic modulus of the layer on the barrier layer side is 6000 MPa or more, and the elastic modulus of the outermost layer is 2500 to 5999 MPa.
Example 30 : It has a two-layer structure, and the elastic modulus of both the layer on the barrier layer side and the outermost layer is 6000 MPa or more.
Examples 31-33 : It has a three-layer structure, and all the elastic moduli of the layer on the barrier layer side, the intermediate layer, and the outermost layer are 1500 to 2499 MPa.
Examples 34-36 : It has a three-layer structure, the elastic modulus of the layer on the barrier layer side and the intermediate layer is 1500-2499 MPa, and the elastic modulus of the outermost layer is 2500-5999 MPa.
Examples 37-39 : It has a three-layer structure, and the elastic modulus of the layer on the barrier layer side and the outermost layer is 1500-2499 MPa, and the elastic modulus of the intermediate layer is 2500-5999 MPa.
Examples 40-44 : It has a three-layer structure, the elastic modulus of the layer on the barrier layer side is 1500-2499 MPa, and the elastic modulus of the intermediate layer and the outermost layer is 2500-5999 MPa.
Examples 45-49 : It has a three-layer structure, the elastic modulus of the layer on the barrier layer side is 2500-5999 MPa, and the elastic modulus of the intermediate layer and the outermost layer is 1500-2499 MPa.
Examples 50 to 54 : It has a three-layer structure, and the elastic modulus of the layer on the barrier layer side and the outermost layer is 2500 to 5999 MPa, and the elastic modulus of the intermediate layer is 1500 to 2499 MPa.
Examples 55-59 : It has a three-layer structure, and the elastic modulus of the barrier layer side layer and the intermediate layer is 2500 to 5999 MPa, and the elastic modulus of the outermost layer is 1500 to 2499 MPa.
Examples 60 to 63 : A three-layer structure, and all the elastic moduli of the layer on the barrier layer side, the intermediate layer, and the outermost layer are 2500 to 5999 MPa.
Examples 64-87 : a three-layer structure, the elastic modulus of the layer on the barrier layer side is 1500 to 2499 MPa, the elastic modulus of the intermediate layer and the outermost layer is 2500 to 5999 MPa, and the outermost layer contains a slip agent It is.

In addition, the component used for formation of the layer which comprises the coating layer shown in Table 1 and 2 is as follows.
Polyol compound A: Urethane polyol polyol compound B having a molecular weight of 8000 to 50000 and a hydroxyl value of less than 40: Aliphatic polyol epoxy resin A having a molecular weight of 500 to 3000 and a hydroxyl value of 70 or more A: Molecular weight of 200 to 1000, bisphenol A type epoxy resin epoxy resin B : Molecular weight 200-1000, phenol novolac epoxy resin aromatic isocyanate: MDI (diphenylmethane diisocyanate adduct)
Aliphatic isocyanate: IPDI (isophorone diisocyanate)
Imidazole compound: Imidazole compound that promotes the crosslinking reaction of thermosetting resin at 80-150 ° C
DBU salt: 1,8-diazabicyclo [5.4.0] undec-7ene octylate anhydride: methylhexahydrophthalic anhydride amino resin: benzoguanamine resin slip agent A: erucamide amide slip agent B: ethylene bis Oleic acid amide slip agent C: behenic acid amide slip agent D: terminal silicon block copolymer, trade name “Modiper FS710” (manufactured by NOF Corporation), block in which a compatible segment (containing functional group) is connected to the terminal of the silicon segment Copolymer slip agent E: terminal fluorine block polymer, trade name “Modiper F206” (manufactured by NOF Corporation), block copolymer slip agent with compatible segment (containing functional group) connected to the end of fluorine segment F: silicone-modified acrylic resin , Product name "Symac US270" (manufactured by NOF Corporation) Silicone-modified acrylic resin silicone acrylic resins containing functional group is graft polymerized

[Evaluation of wrinkle occurrence]
For each battery packaging material obtained above, visually check for the occurrence of wrinkles, and the ratio of the number of wrinkles generated per 50 battery packaging materials (thermal wrinkle defect rate:%) Calculated.

[Evaluation of formability]
Each battery packaging material obtained above was cut into 120 × 80 mm strips, which were used as test samples. Using a straight mold composed of a 30 × 50 mm rectangular male mold and a female mold with a clearance of 0.5 mm between the male mold and the above, the thermal adhesive resin layer side is positioned on the male mold side. A test sample was placed, the forming depth was set to 3.5 to 5.5 mm, and the test sample was pressed with a presser pressure (surface pressure) of 0.1 MPa, and cold-formed (one-step drawing). . The presence or absence of pinholes and cracks in the metal layer in each of the molded test samples was confirmed, and the pinhole and crack generation rates (%) were calculated. The incidence of pinholes and cracks was determined when molding was performed when 100 test samples were molded under the above-mentioned conditions by determining that pinholes or cracks were observed even at one location after molding as above. The proportion of defective products was determined, and the case where the proportion of molding defects was less than 5% was judged as acceptable, and the case where the proportion of molding defects was 5% or more was judged as unacceptable. The moldability was evaluated by classifying the obtained determination results according to the following criteria. In addition, if it is D or more according to the following criteria, the quality is satisfactory from a practical viewpoint.
(Evaluation criteria for moldability)
A: Passed with a molding depth of 5.5 mm B: Passed with a molding depth of 5.5 mm, Passed with a molding depth of 5.0 mm C: Passed with a molding depth of 5.0 mm, Passed with a molding depth of 4.5 mm D: Fail at a molding depth of 4.5 mm, pass at a molding depth of 4.0 mm E: fail at a molding depth of 4.0 mm, pass at a molding depth of 3.5 mm F: not acceptable at a molding depth of 3.5 mm Pass

[Evaluation of chemical resistance]
0.5 ml of chemicals (electrolyte, ethanol, methyl ethyl ketone (MEK), ethyl acetate, or toluene) was dropped on the chemical-resistant coating layer of each battery packaging material obtained above and covered with a watch glass. After standing at room temperature for 3 hours, each chemical on the chemical coating layer was wiped off with gauze, and the state of the chemical resistant coating layer surface of the battery packaging material was visually confirmed and evaluated according to the following criteria.
(Evaluation criteria for chemical resistance)
○: No trace was observed on the surface of all chemicals.
Δ: In at least one chemical, abnormalities such as whitening, swelling, and peeling were confirmed on the surface, but there were chemicals in which no trace was confirmed on the surface.
X: Abnormalities such as whitening, swelling, and peeling were confirmed on the surface of all chemicals.

[Evaluation results]
The obtained results are shown in Tables 3-8. From this result, when at least one layer constituting the coating layer is cured with only a thermosetting resin without containing a curing accelerator, it takes a long time to be cured, and wrinkles due to heat. The defect rate of the product was high due to the occurrence of (Comparative Examples 1 to 15). On the other hand, when all the layers constituting the coating layer are cured using a thermosetting resin and a curing accelerator, they can be cured in a short time, and furthermore, generation of wrinkles due to heat can be prevented. It was able to suppress (Examples 1-87).

  Moreover, from this result, in all the layers constituting the coating layer, when the elastic modulus satisfies 1500 to 6000 Mpa, the moldability is good, and when the slip agent is further included in the outermost layer. It became clear that it could have excellent formability. Furthermore, when the elastic modulus of the outermost layer of the coating layer was 3000 Mpa or more, it was confirmed that the coating layer had excellent chemical resistance.

Examples 88-157
[Manufacture of battery packaging materials]
In Examples 88 to 105, a coating layer / barrier layer / sealant layer having a two-layer structure was sequentially laminated under the same conditions as above except that the following resin composition was used as the resin composition for forming the coating layer. A battery packaging material comprising a laminate was produced.
Resin composition used for forming the layer on the barrier layer side of the coating layer : Carbon black (average particle size 0.2 μm) was added in the ratio shown in Table 9 to the resin composition used for forming the layer 13b. Resin composition
Resin composition used for forming outermost layer of coating layer : Resin composition in which carbon black (average particle size 0.2 μm) was added in the ratio shown in Table 9 to the resin composition used for forming layer 12b

In Examples 106 to 147, a coating layer / barrier layer / sealant layer having a three-layer structure was sequentially laminated under the same conditions as described above except that the following resin composition was used as the resin composition for forming the coating layer. A battery packaging material made of the laminated body was produced.
Resin composition used for forming the layer on the barrier layer side of the coating layer : Carbon black (average particle size 0.2 μm) in the ratio shown in Tables 10 and 11 with respect to the resin composition used for forming the layer 1b Added resin composition
Resin composition used for forming the intermediate layer of the coating layer : Resin obtained by adding carbon black (average particle size 0.2 μm) in the ratio shown in Tables 10 and 11 to the resin composition used for forming the layer 10b Composition
Resin composition used for forming the outermost layer of the coating layer : Resin in which carbon black (average particle size 0.2 μm) was added to the resin composition used for forming the layer 13b in the ratios shown in Tables 10 and 11 Composition

[Evaluation of distinguishability]
About each obtained battery packaging material and the battery packaging materials of Examples 23 and 41, the color tone of the coating layer side was observed visually, and the coloration (black) visibility by carbon black blended in the coating layer was confirmed. Confirmed and evaluated according to the following criteria.

(Evaluation criteria for distinguishability)
A: It can be clearly visually recognized that the color is black.
B: It can be visually recognized slightly that it is black.
C: It cannot visually recognize that it is black.

[Evaluation of moldability]
About each obtained battery packaging material and the battery packaging material of Examples 23 and 41, it shape | molded on the same conditions as the above, and evaluated the moldability and the color tone of the extending part by shaping | molding on the following references | standards.

(Formability)
A: The forming depth reaching the pass is the same as that of the control battery packaging material.
B: A reduction of 0.5 mm or less in the molding depth reaching the acceptance is recognized as compared with the control battery packaging material.
C: A reduction of more than 0.5 mm and 1.0 mm or less is observed in the molding depth that reaches the pass as compared with the control battery packaging material.
D: A decrease of more than 1.0 mm is observed in the molding depth that reaches the acceptable level as compared with the control battery packaging material.

  In addition, in the battery packaging materials of Examples 88 to 109, the battery packaging material of Example 23 was used as the control battery packaging material. Moreover, in the battery packaging materials of Examples 110 to 158, the battery packaging material of Example 41 was used as a control battery packaging material. The battery packaging material of Examples 88 to 109 and the battery packaging material of Examples 110 to 158 are respectively the battery packaging material of Example 23 and the battery of Example 41, except that carbon black is included. The packaging material has the same configuration.

(Color tone of stretched part by molding)
A: No difference in color tone is observed between the stretched part and the non-stretched part.
B: A slight difference in color tone is recognized between the stretched portion and the non-stretched portion.
C: A clear difference in color tone is recognized between the stretched portion and the non-stretched portion.

[Evaluation results]
The obtained results are shown in Tables 9-11. From this result, it was confirmed that by adding an inorganic pigment (carbon black) to at least one layer constituting the coating layer, a color tone can be imparted to the battery packaging material so as to have discriminability. Moreover, it was also confirmed that a decrease in moldability can be effectively suppressed by setting the amount of the inorganic pigment to be added to 30 parts by mass or less, particularly 15 parts by mass or less per 100 parts by mass of the thermosetting resin. Further, by adding an inorganic pigment to at least two of the layers constituting the coating layer, particularly three layers, it is effective to cause a color difference between the molded part and the non-molded part after molding. It was also revealed that it can be suppressed. Moreover, when the thermal conductivity of the battery packaging material in which carbon black was added to the coating layer was measured, it was confirmed that it had a thermal conductivity of about 60 W / m · K or more and had excellent heat dissipation. It was.

DESCRIPTION OF SYMBOLS 1 Coating layer 1a 1st coating layer 1b 2nd coating layer 1c 3rd coating layer 2 Barrier layer 3 Sealant layer

Claims (14)

It consists of a laminate having at least a coating layer, a barrier layer, and a sealant layer in this order,
The coating layer has a multilayer structure of two or more layers,
Each layer constituting the coating layer is made of a cured product of a resin composition containing a thermosetting resin and a curing accelerator.
A battery packaging material characterized by the above.   The battery packaging material according to claim 1, wherein an elastic modulus of each layer constituting the coating layer is 1500 to 6000 MPa.   The battery packaging material according to claim 1 or 2, wherein at least one of the layers constituting the coating layer has an elastic modulus of 2500 to 6000 MPa. The coating layer has a two-layer structure,
The elastic modulus of the layer which contacts the barrier layer among the layers constituting the coating layer is 1500 to 6000 Mpa, and the elastic modulus of the outermost layer is 3000 to 6000 Mpa. Battery packaging material. The coating layer has a three-layer structure,
Among the layers constituting the coating layer, the elastic modulus of the layer in contact with the barrier layer is 1500 to 6000 Mpa, and the elastic modulus of the layer located between the layer in contact with the barrier layer and the outermost layer is 1500 to 6000 Mpa. The battery packaging material according to claim 1, wherein the outermost layer has an elastic modulus of 3000 to 6000 Mpa.   The battery packaging material according to any one of claims 1 to 5, wherein the outermost layer of the coating layer comprises a cured product of a resin composition containing a curable resin, a curing accelerator, and a reactive slip agent. .   The battery packaging material according to any one of claims 1 to 6, wherein a pigment and / or a dye is contained in the resin composition used for forming at least one layer of the coating layer.   The battery packaging material according to claim 7, wherein the resin composition used for forming at least one layer of the coating layer contains an inorganic pigment.   The battery packaging material according to claim 1, wherein the thickness of each layer constituting the coating layer is 1 to 5 μm.   The battery packaging material according to claim 1, wherein the entire thickness of the battery packaging material is 40 to 120 μm.   The thermosetting resin is at least one selected from the group consisting of an epoxy resin, an amino resin, an acrylic resin, a urethane resin, a phenol resin, an unsaturated polyester resin, and an alkyd resin. A packaging material for a battery according to claim 1.   The curing accelerator is at least one selected from the group consisting of an amidine compound, a carbodiimide compound, a ketimine compound, a hydrazine compound, a sulfonium salt, a benzothiazolium salt, and a tertiary amine compound. The battery packaging material according to any one of 11. A coating layer having a multilayer structure of two or more layers is formed on the barrier layer by repeatedly applying the resin composition containing the thermosetting resin and the curing accelerator and curing by heating twice or more to the barrier layer. Including a coating layer forming step to form,
Before, during or after the coating layer forming step, a sealant layer is laminated on a surface of the barrier layer opposite to the surface on which the coating layer is laminated,
A method for producing a battery packaging material.   The battery by which the battery element provided with the positive electrode, the negative electrode, and the electrolyte is accommodated in the packaging material for batteries in any one of Claims 1-12.