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JP5560343B2 - Methane fermentation treatment equipment - Google Patents

Methane fermentation treatment equipment Download PDF

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JP5560343B2
JP5560343B2 JP2012536037A JP2012536037A JP5560343B2 JP 5560343 B2 JP5560343 B2 JP 5560343B2 JP 2012536037 A JP2012536037 A JP 2012536037A JP 2012536037 A JP2012536037 A JP 2012536037A JP 5560343 B2 JP5560343 B2 JP 5560343B2
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methane fermentation
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JPWO2012042581A1 (en
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敏機 吉村
和哉 河野
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • C02F11/04Anaerobic treatment; Production of methane by such processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2866Particular arrangements for anaerobic reactors
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F2003/008Biological treatment of water, waste water, or sewage using anaerobic baffled reactors
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/005Black water originating from toilets
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/32Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2203/00Apparatus and plants for the biological treatment of water, waste water or sewage
    • C02F2203/006Apparatus and plants for the biological treatment of water, waste water or sewage details of construction, e.g. specially adapted seals, modules, connections
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Treatment Of Sludge (AREA)

Description

本発明は、食品工業等の有機性廃水に代表される産業廃水、又は下水、し尿等の廃水をメタン醗酵処理してメタンガス,炭酸ガスなどに分解するメタン発酵処理装置に関する。   The present invention relates to a methane fermentation treatment apparatus that decomposes industrial wastewater represented by organic wastewater such as food industry, or wastewater such as sewage and human waste into methane gas, carbon dioxide gas, etc. by methane fermentation.

食品工業廃水等の産業廃水や、有機性汚泥、生ごみ等の有機性廃棄物を処理するために、メタン発酵処理が注目され、実用化されている。メタン発酵処理は、活性汚泥処理に比べて省エネルギーであり、バイオガスとしてのメタンガスをエネルギーとして生み出すことができる。   In order to treat industrial wastewater such as food industry wastewater and organic waste such as organic sludge and garbage, methane fermentation treatment has attracted attention and has been put to practical use. Methane fermentation treatment is energy saving compared to activated sludge treatment, and can produce methane gas as biogas as energy.

メタン醗酵処理の例として、嫌気性消化法やUASB(上向流式嫌気性汚泥床)法によるものが普及している。UASB法のメタン醗酵処理においては、有機性廃棄物は2段階の分解過程を経て、メタンガス、水および炭酸ガスとなる。すなわち、有機性廃棄物は酸発酵過程で酢酸等の低級脂肪酸に分解され、続いてメタン細菌の働きによりメタンガスに分解される。   As an example of the methane fermentation treatment, an anaerobic digestion method or a UASB (upward flow type anaerobic sludge bed) method is widely used. In UASB methane fermentation treatment, organic waste is converted into methane gas, water, and carbon dioxide through a two-stage decomposition process. That is, organic waste is decomposed into lower fatty acids such as acetic acid during the acid fermentation process, and then decomposed into methane gas by the action of methane bacteria.

このようなメタン発酵処理において、特許文献1に記載されるようなスラッジブランケット型のメタン醗酵処理装置が知られている。この装置は、顆粒状態のグラニュールを乱流状態で滞留させる乱流反応層を反応槽の槽内に下方から2段以上に縦型に積層して形成したものであり、処理水を上方から槽外部に溢流させると共に、グラニュールを含む水を乱流反応層に戻すようにした層流層(スラッジブランケット)が設けられている。   In such a methane fermentation treatment, a sludge blanket type methane fermentation treatment apparatus as described in Patent Document 1 is known. In this apparatus, a turbulent reaction layer that retains granular granules in a turbulent state is formed by stacking vertically in two or more stages from below in the tank of the reaction tank. A laminar bed (sludge blanket) is provided which overflows outside the tank and returns water containing granules to the turbulent reaction layer.

特開2005−342691号公報JP 2005-342691 A

特許文献1に記載されるメタン発酵処理装置においては、各段の乱流反応層は、上方に向かって凸形に設けられた円錐型の第一隔壁の外側に形成される狭い流路を通じてつながっている。そして、槽中央上部の自由水面付近の反応水を槽最下部の第一乱流層201に下降させる第一貫通筒4と、第一乱流層201の水を槽中央上部の自由水面付近に上昇させる第二貫通筒6が設けられることにより、第一乱流層201の水は槽中央上部の自由水面付近を経由して循環する。このような槽内構造のために、下段の乱流反応層から上段の乱流反応層へと被処理水が順次移動するに際し、本来は槽中央上部の自由水面付近を経由して循環しながら径方向に均一に広がって流れるべき被処理水が片流れを生じ、反応効率を低減させる恐れがある。   In the methane fermentation treatment apparatus described in Patent Document 1, the turbulent reaction layers in each stage are connected through a narrow flow path formed outside a conical first partition wall provided in a convex shape upward. ing. And the 1st penetration cylinder 4 which descends the reaction water near the free water surface of the tank center upper part to the 1st turbulent flow layer 201 of the tank bottom, and the water of the 1st turbulent flow layer 201 near the free water surface of the tank center upper part By providing the second through cylinder 6 to be raised, the water in the first turbulent layer 201 circulates through the vicinity of the free water surface at the upper center of the tank. Because of this internal structure of the tank, when the water to be treated moves sequentially from the lower turbulent reaction layer to the upper turbulent reaction layer, it is normally circulated through the vicinity of the free water surface at the upper center of the tank. There is a risk that the water to be treated that should flow evenly in the radial direction will flow in one direction and reduce the reaction efficiency.

そこで本発明の課題は、多段式反応槽内における被処理水の流動状態が改善された反応効率の高いメタン発酵処理装置を提供することにある。   Then, the subject of this invention is providing the methane fermentation processing apparatus with high reaction efficiency in which the flow state of the to-be-processed water in a multistage reaction tank was improved.

上記課題を解決するために、本発明に係るメタン発酵処理装置は、槽内部が隔壁により複数の反応室に区画された多段式反応槽からなり、該多段式反応槽内で被処理水とグラニュール汚泥とを接触させるメタン発酵処理装置であって、前記隔壁には被処理水が上流側反応室から下流側反応室に向けて通過する開口部が設けられ、最下流側の反応室にはグラニュール汚泥から分離された処理水を越流させて排出する越流部が設けられ、一の反応室内において発生したガスを前記越流部の越流面と同じ高さの水面下に導いて気中に抜き出すガス抜き手段と、該ガス抜き手段により前記ガスとともに前記水面下に導かれたグラニュール汚泥を前記一の反応室よりも下流側の他の反応室に返送する汚泥返送手段とを備えていることを特徴とするものからなる。   In order to solve the above-mentioned problems, a methane fermentation treatment apparatus according to the present invention comprises a multistage reaction tank in which the inside of the tank is partitioned into a plurality of reaction chambers by partition walls, and water to be treated and granulated in the multistage reaction tank. The partition is provided with an opening through which the treated water passes from the upstream reaction chamber toward the downstream reaction chamber, and the most downstream reaction chamber has An overflow section is provided to discharge the treated water separated from the granular sludge, and guides the gas generated in one reaction chamber below the surface of the water at the same height as the overflow surface of the overflow section. Degassing means for extracting into the air, and sludge returning means for returning the granular sludge guided below the water surface together with the gas to the other reaction chamber downstream from the one reaction chamber by the degassing means. Is it characterized by having It made.

このような本発明のメタン発酵処理装置によれば、一の反応室内において発生したガスとともに水面下に導かれたグラニュール汚泥を、下流側の他の反応室に返送するので、グラニュール汚泥が複数の反応室間を流動し、良好なスラッジブランケットが形成可能となる。また、グラニュール汚泥を含む汚泥水が隣り合う反応室間を流動することにより、多段式反応槽内が攪拌混合されて被処理水の片流れが防止され、メタン発酵反応の促進が図られる。   According to such a methane fermentation treatment apparatus of the present invention, the granular sludge guided below the water surface together with the gas generated in one reaction chamber is returned to the other reaction chamber on the downstream side. A good sludge blanket can be formed by flowing between a plurality of reaction chambers. In addition, the sludge water containing granule sludge flows between adjacent reaction chambers, whereby the inside of the multistage reaction tank is stirred and mixed to prevent a single flow of water to be treated, thereby promoting the methane fermentation reaction.

本発明のメタン発酵処理装置において、前記隔壁が、頂部を下方に向けて配置された錐面状(例えば円錐面状、四角錐面状)に形成されていることが好ましい。隔壁をいわゆる逆錐面形状に形成することにより、反応室内で発生したガスは、反応室内に浮遊するグラニュール汚泥を随伴しながら反応室の径方向外向きに移動して、越流面と同じ高さの自由水面から気中に排出される。このようにして、多段式反応槽内におけるグラニュール汚泥の流動状態の改善が図られる。   In the methane fermentation treatment apparatus of the present invention, it is preferable that the partition wall is formed in a conical surface shape (for example, a conical surface shape or a quadrangular pyramid surface shape) arranged with the top portion facing downward. By forming the partition wall into a so-called inverted conical surface shape, the gas generated in the reaction chamber moves outward in the radial direction of the reaction chamber with the granular sludge floating in the reaction chamber, and is the same as the overflow surface It is discharged into the air from a free surface of height. In this way, the flow state of the granular sludge in the multistage reaction tank is improved.

前記開口部は、前記頂部に形成されていることが好ましい。このように、逆錐面形状をなす隔壁の錐体頂部に開口部が形成され、当該開口部を通じて被処理水が上流側反応室から下流側反応室に向けて通過することにより、被処理水の主流れが反応室の径方向内側に形成されるので、被処理水の層流と、発生ガスの流れに随伴する汚泥水の循環流とが互いに干渉することなく安定した流動状態が形成可能となる。   The opening is preferably formed at the top. In this way, an opening is formed at the top of the cone of the partition wall having an inverted conical surface shape, and the water to be treated passes through the opening from the upstream reaction chamber toward the downstream reaction chamber. Is formed inside the reaction chamber in the radial direction, so that the laminar flow of water to be treated and the circulating flow of sludge water accompanying the flow of generated gas can form a stable flow state without interfering with each other It becomes.

本発明のメタン発酵処理装置において、前記汚泥返送手段が、前記グラニュール汚泥を前記他の反応室に重力で返送する下向き配管からなることが好ましい。このような下向き配管からなる汚泥返送手段を介して、越流面と同じ高さの自由水面下に導かれたグラニュール汚泥を、返送先の反応室内における所望の位置に返送することができる。   In the methane fermentation treatment apparatus of the present invention, it is preferable that the sludge returning means is composed of a downward piping that returns the granular sludge to the other reaction chamber by gravity. Granule sludge guided under the free water surface at the same height as the overflow surface can be returned to a desired position in the reaction chamber of the return destination through the sludge return means comprising such downward piping.

本発明のメタン発酵処理装置において、前記ガス抜き手段が、前記ガスを浮力で前記水面下に導く上向き配管からなることが好ましい。このように、一の反応室内で発生したガスを集めて浮力で上方に移送し、越流面と同じ高さの自由水面下に導くことにより、特段の動力を使用せずにガス抜きを行うことができる。また、上昇するガスのリフトアップ作用を利用して汚泥水を上昇させることができるので、簡素な機構にて多段式反応槽内を適切な流動状態に保持することが可能である。また、前記上向き配管は、前記一の反応室の周縁側に設けられて、発生したガスが取り込まれやすく配置されていることが好ましい。   In the methane fermentation treatment apparatus of the present invention, it is preferable that the degassing means is an upward pipe that guides the gas below the water surface by buoyancy. In this way, gas generated in one reaction chamber is collected, transferred upward by buoyancy, and guided to the free water surface at the same height as the overflow surface, thereby degassing without using special power. be able to. Moreover, since sludge water can be raised using the lift-up action of the rising gas, it is possible to keep the inside of the multistage reaction tank in an appropriate fluid state with a simple mechanism. Moreover, it is preferable that the upward piping is provided on the peripheral side of the one reaction chamber and is arranged so that the generated gas is easily taken in.

また、本発明のメタン発酵処理装置には、前記上向き配管内または/および反応室内に気体を吹き込むブロワが設けられていることが好ましい。メタン発酵反応が活発に生じているときは、外部から気体を吹き込まなくても多段式反応槽内が十分に攪拌されて適切な流動状態を形成可能である。しかしメタンガスの発生量が少ないときは、外部からメタンガス等を上向き配管や反応室内に吹き込むことで流動状態を調整することが可能である。また、外部から吹き込まれた気体により、上向き配管内を上昇するグラニュール汚泥をほぐして小粒径化することが可能である。このようにして汚泥表面積を高めることで、グラニュール汚泥の持つメタン発酵反応性の向上を図ることも可能である。   Moreover, it is preferable that the methane fermentation processing apparatus of this invention is provided with the blower which blows gas in the said upward piping or / and reaction chamber. When the methane fermentation reaction is actively occurring, the inside of the multistage reaction tank can be sufficiently agitated to form an appropriate fluid state without blowing gas from the outside. However, when the amount of methane gas generated is small, the flow state can be adjusted by blowing methane gas or the like from the outside into the upward piping or the reaction chamber. Further, it is possible to reduce the particle size by loosening the granular sludge rising in the upward pipe by the gas blown from the outside. By increasing the sludge surface area in this way, it is possible to improve the methane fermentation reactivity of the granular sludge.

本発明に係るメタン発酵処理装置において、前記複数の反応室が上下方向に積層されていることが好ましい。このようないわゆる縦型の多段式反応槽においては、本発明のガス抜き手段および汚泥返送手段を備えたメタン発酵処理装置をコンパクトに形成することが容易である。   In the methane fermentation treatment apparatus according to the present invention, the plurality of reaction chambers are preferably stacked in the vertical direction. In such a so-called vertical multistage reactor, it is easy to form a compact methane fermentation treatment apparatus equipped with the degassing means and sludge return means of the present invention.

本発明のメタン発酵処理装置において、前記多段式反応槽に被処理水が断続的に供給されることが好ましい。被処理水が断続的に供給されることにより、被処理水の流入停止時にグラニュール汚泥を自重で沈降させ、開口部を通じて上方の反応室から下方の反応室内へとグラニュール汚泥を流入させることができる。このようにして、下方の反応室に流入したグラニュール汚泥が下方の反応室内のガス流れに乗ってガス抜き手段へと誘導されることにより、多段式反応槽内に汚泥水の循環流を形成することができる。   In the methane fermentation treatment apparatus of the present invention, it is preferable that treated water is intermittently supplied to the multistage reaction tank. By supplying the treated water intermittently, the granular sludge is settled by its own weight when the treated water stops flowing, and the granular sludge flows from the upper reaction chamber to the lower reaction chamber through the opening. Can do. In this way, the granular sludge that has flowed into the lower reaction chamber rides on the gas flow in the lower reaction chamber and is guided to the degassing means, thereby forming a circulating flow of sludge water in the multistage reaction tank. can do.

本発明のメタン発酵処理装置において、前記開口部の上流側近傍に、前記上流側反応室内のガスが前記下流側反応室内に流入することを阻止する阻止板が設けられていることが好ましい。例えば、開口部からわずかに上流側の反応室内に、開口部よりも大きな断面積を有する浮上ガス阻止板を設けることにより、上流側反応室内で発生したメタンガスが開口部を通じて下流側反応室内に流入することを阻止し、ガスをガス抜き手段へと効果的に誘導することが可能となる。このような浮上ガス阻止板は、上方に頂点を有するように配置された円錐面状に構成することができる。   In the methane fermentation treatment apparatus of the present invention, it is preferable that a blocking plate for preventing the gas in the upstream reaction chamber from flowing into the downstream reaction chamber is provided in the vicinity of the upstream side of the opening. For example, by providing a floating gas blocking plate having a cross-sectional area larger than the opening in the reaction chamber slightly upstream from the opening, methane gas generated in the upstream reaction chamber flows into the downstream reaction chamber through the opening. And the gas can be effectively guided to the degassing means. Such a levitation gas blocking plate can be configured as a conical surface disposed so as to have an apex on the upper side.

本発明に係るメタン発酵処理装置によれば、反応室内で発生するガスを利用して多段式反応槽内に循環流を形成させることにより、反応室内における片流れを防止しつつメタン発酵を効果的に行うことができる。また、ブロワを介して外部からメタンガス等の気体を導入することにより、リフトアップされる汚泥水の流動を促進することができる。   According to the methane fermentation treatment apparatus according to the present invention, methane fermentation is effectively performed while preventing a single flow in the reaction chamber by forming a circulation flow in the multistage reaction tank using the gas generated in the reaction chamber. It can be carried out. In addition, by introducing a gas such as methane gas from the outside through a blower, the flow of sludge water to be lifted up can be promoted.

本発明の一実施態様に係るメタン発酵処理装置における多段式反応槽の概略縦断面図である。It is a schematic longitudinal cross-sectional view of the multistage reaction tank in the methane fermentation processing apparatus which concerns on one embodiment of this invention. 図1の多段式反応槽をL−L方向から見た概略平面図である。It is the schematic plan view which looked at the multistage type reaction tank of Drawing 1 from the LL direction. 図1の多段式反応槽を含むメタン発酵処理装置の概略フロー図である。It is a schematic flowchart of the methane fermentation processing apparatus containing the multistage reaction tank of FIG.

以下に、本発明の望ましい実施の形態を、図面を参照して説明する。
図1は本発明の一実施態様に係るメタン発酵処理装置における多段式反応槽の概略縦断面図であり、図2は図1のL−L方向から見た概略平面図である。
Hereinafter, preferred embodiments of the present invention will be described with reference to the drawings.
FIG. 1 is a schematic longitudinal sectional view of a multistage reaction tank in a methane fermentation treatment apparatus according to an embodiment of the present invention, and FIG. 2 is a schematic plan view seen from the LL direction of FIG.

多段式反応槽1内には、頂部を下方に向けた円錐面状の三つの隔壁2(2A、2B、2C)が設置され、各隔壁2の外周縁は多段式反応槽1の円筒内周面と水密状態で接合されており、多段式反応槽1内を反応室10(10Z、10A、10B、10C)に区画している。また各隔壁2の頂部には開口部3(3A、3B、3C)が形成されており、各開口部3によって各反応室10は連通している。また、開口部3の下方側近傍には、円錐面状の浮上ガス阻止板12が設けられ、図示されない支持手段によって各隔壁2に固定されている。多段式反応槽1の最下部には被処理水の流入部8が設けられ、多段式反応槽1の最上部には処理水を越流させる越流樋4が設けられ、越流樋4を越流した処理水は、流出管9を通して多段式反応槽1の外部に流出されるようになっている。さらに多段式反応槽1の最上部には、多段式反応槽1内で発生したメタンガスを多段式反応槽1外に放出するガス放出管11の一端が接続されている。   In the multistage reaction tank 1, three conical surface partition walls 2 (2 </ b> A, 2 </ b> B, 2 </ b> C) with the top facing downward are installed, and the outer peripheral edge of each partition wall 2 is the cylindrical inner periphery of the multistage reaction tank 1. It is joined to the surface in a watertight state, and the inside of the multistage reaction tank 1 is partitioned into reaction chambers 10 (10Z, 10A, 10B, 10C). Moreover, the opening part 3 (3A, 3B, 3C) is formed in the top part of each partition 2, and each reaction chamber 10 is connected by each opening part 3. FIG. Further, a conical floating gas blocking plate 12 is provided in the vicinity of the lower side of the opening 3 and is fixed to each partition wall 2 by a support means (not shown). An inflow portion 8 of the water to be treated is provided at the lowermost portion of the multistage reaction tank 1, and an overflow basin 4 for overflowing the treated water is provided at the uppermost portion of the multistage reaction tank 1. The treated water that has overflowed flows out of the multistage reaction tank 1 through the outflow pipe 9. Furthermore, one end of a gas discharge pipe 11 that discharges methane gas generated in the multistage reaction tank 1 to the outside of the multistage reaction tank 1 is connected to the top of the multistage reaction tank 1.

隔壁2Aの外周縁付近(反応室10Z周縁側の上部)には、上向き配管5Aの一端が隔壁2Aを貫通して取り付けられている。上向き配管5Aの他端は、多段式反応槽1の越流水面と略同じ高さにその水面が存するように形成されたガス抜き槽7(7A)に連通しており、反応室10Z内で発生するメタンガスを上向き配管5Aによってガス抜き槽7Aに導くようになっている。   One end of the upward pipe 5A is attached to the vicinity of the outer peripheral edge of the partition wall 2A (the upper part on the peripheral side of the reaction chamber 10Z) through the partition wall 2A. The other end of the upward pipe 5A communicates with a degassing tank 7 (7A) formed so that the water surface exists at substantially the same height as the overflow water surface of the multistage reaction tank 1, and in the reaction chamber 10Z. The generated methane gas is guided to the degassing tank 7A by the upward pipe 5A.

ガス抜き槽7Aには下向き配管6Aの一端が連通しており、下向き配管6Aの他端部は隔壁2Aの円錐面上側に沿って設置されており、メタンガスの上昇流によるガスリフトアップ効果によってメタンガスとともに上昇する汚泥水をガス抜き槽7Aを介して下向き配管6Aの他端から反応室10Aに返送するようになっている。   One end of the downward piping 6A communicates with the degassing tank 7A, and the other end of the downward piping 6A is installed along the upper side of the conical surface of the partition wall 2A, and together with methane gas by the gas lift-up effect due to the upward flow of methane gas The rising sludge water is returned to the reaction chamber 10A from the other end of the downward piping 6A through the degassing tank 7A.

隔壁2Bの外周縁付近(反応室10A周縁側の上部)には、上向き配管5Bの一端が隔壁2Bを貫通して取り付けられている。上向き配管5Bの他端はガス抜き槽7Aと同一水平面上に設置されたガス抜き槽7Bに連通しており、反応室10A内で発生するメタンガスを上向き配管5Bによってガス抜き槽7Bに導くようになっている。   In the vicinity of the outer peripheral edge of the partition wall 2B (upper part on the peripheral edge side of the reaction chamber 10A), one end of the upward pipe 5B is attached through the partition wall 2B. The other end of the upward pipe 5B communicates with a gas vent tank 7B installed on the same horizontal plane as the gas vent tank 7A so that methane gas generated in the reaction chamber 10A is guided to the gas vent tank 7B by the upward pipe 5B. It has become.

ガス抜き槽7Bにも下向き配管6Bの一端が連通しており、下向き配管6Bの他端部は隔壁2Bの円錐面上側に沿って設置されており、メタンガスの上昇流によるガスリフトアップ効果によってメタンガスとともに上昇する汚泥水をガス抜き槽7Bを介して下向き配管6Bの他端から反応室10Bに返送するようになっている。   One end of the downward piping 6B is also communicated with the gas venting tank 7B, and the other end of the downward piping 6B is installed along the upper side of the conical surface of the partition wall 2B. The rising sludge water is returned to the reaction chamber 10B from the other end of the downward piping 6B through the gas venting tank 7B.

なお、図2に示すように、各ガス抜き槽7(7A、7B)は多段式反応槽1内の最上部周縁側に隣合わせになるように設置されている。   In addition, as shown in FIG. 2, each degassing tank 7 (7A, 7B) is installed so that it may adjoin with the uppermost periphery side in the multistage reaction tank 1. As shown in FIG.

このように構成された本発明のメタン発酵処理装置は、以下のように機能する。   The methane fermentation treatment apparatus of the present invention configured as described above functions as follows.

被処理水は流入部8から断続的に流入し、上昇しながら、各開口部3(3A、3B、3C)を通して各反応室10(10Z、10A、10B、10C)間を移動する。この過程で被処理水が各反応室10内に存在するグラニュール汚泥と接触することにより、被処理水中の有機物が分解される。被処理水は、最終的に反応室10Cの上部でグラニュール汚泥と分離され、越流樋4を介して流出管9から多段式反応槽1の外部へ処理水として取り出される。   The water to be treated flows in intermittently from the inflow portion 8 and moves between the reaction chambers 10 (10Z, 10A, 10B, 10C) through the openings 3 (3A, 3B, 3C) while rising. In this process, when the water to be treated comes into contact with the granular sludge present in each reaction chamber 10, the organic matter in the water to be treated is decomposed. The treated water is finally separated from the granular sludge at the upper part of the reaction chamber 10C and taken out from the outflow pipe 9 to the outside of the multistage reaction tank 1 through the overflow tank 4 as treated water.

反応室10Zで発生したメタンガスの一部分は、開口部3Aの下方にある浮上ガス阻止板12に捕捉されて反応室10Aへの流入が阻止され、阻止されたメタンガスを含めた反応室10Zで発生したメタンガスは隔壁2Aの円錐面下側に沿って上昇し、隔壁2Aと多段式反応槽1との接合部の周囲に滞留する。その接合部付近には上向き配管5Aの一端が開口しているので、当該接合部の周囲に滞留したメタンガスは、上向き配管5Aを通ってガス抜き槽7Aの水面下に導かれ、その水面から気中に放出されたメタンガスはガス放出管11を介して多段式反応槽1外に排出される。   A part of the methane gas generated in the reaction chamber 10Z is captured by the floating gas blocking plate 12 below the opening 3A and is prevented from flowing into the reaction chamber 10A, and is generated in the reaction chamber 10Z including the blocked methane gas. The methane gas rises along the lower side of the conical surface of the partition wall 2 </ b> A and stays around the junction between the partition wall 2 </ b> A and the multistage reaction tank 1. Since one end of the upward pipe 5A is opened in the vicinity of the joint, the methane gas staying around the joint is guided under the water surface of the degassing tank 7A through the upward pipe 5A, and is discharged from the water surface. The methane gas released therein is discharged out of the multistage reaction tank 1 through the gas discharge pipe 11.

一方、メタンガスが上向き配管5Aを通過する際に、そのリフトアップ効果によって反応室10Z内に存在するグラニュールを含む汚泥水も上昇してガス抜き槽7Aに流入する。その結果、ガス抜き槽7A内の水面mは多段式反応槽1内の水面nより高くなるが、そのヘッド差(m−n)によって汚泥水は下向き配管6Aを通して落下し反応室10A内に流入する。かくして、反応室10Z内のグラニュールの一部は反応室10Aに移送されることになる。また、被処理水の流入が断続的に停止するタイミングで、被処理水流れの方向に抗して、グラニュールが反応室10Aから落下し10Z内に流入することも並行して行われる。このような運転を続行することにより、反応室10Zと反応室10Aとの間でグラニュール汚泥の循環混合が達成され、反応が効果的に行われる。   On the other hand, when methane gas passes through the upward pipe 5A, sludge water containing granules present in the reaction chamber 10Z rises due to the lift-up effect and flows into the gas vent tank 7A. As a result, the water level m in the degassing tank 7A is higher than the water level n in the multistage reaction tank 1, but due to the head difference (mn), sludge water falls through the downward piping 6A and flows into the reaction chamber 10A. To do. Thus, a part of the granules in the reaction chamber 10Z is transferred to the reaction chamber 10A. Further, at the timing when the inflow of the water to be treated is intermittently stopped, the granules fall from the reaction chamber 10A and flow into the 10Z against the direction of the water to be treated. By continuing such an operation, circulation and mixing of granular sludge is achieved between the reaction chamber 10Z and the reaction chamber 10A, and the reaction is effectively performed.

一方、反応室10A内で発生したメタンガスも、同じように隔壁2Bの円錐面下側に沿って上昇し、隔壁2Bと多段式反応槽1との接合部の周囲に滞留するが、その接合部付近には上向き配管5Bの開口部が存在するので、メタンガスは上向き配管5Bを通ってガス抜き槽7Bの水面下に導かれ、そしてその水面から気中に放出されたメタンガスはガス放出管11を介して多段式反応槽1外に放出される。メタンガスが上向き配管5Bを通過する際には、そのリフトアップ効果によって反応室10Aに存在するグラニュールを含む汚泥水も、同じように上昇してガス抜き槽7B内に流入する。その結果、同じようにガス抜き槽7B内の水面mは多段式反応槽1内の水面nよりも高く上昇し、そのヘッド差(m−n)によって、汚泥水が下向き配管6Bから落下し反応室10B内に流入する。   On the other hand, the methane gas generated in the reaction chamber 10A also rises along the lower side of the conical surface of the partition wall 2B and stays around the joint portion between the partition wall 2B and the multistage reaction tank 1, but the joint portion. Since there is an opening of the upward pipe 5B in the vicinity, the methane gas is guided through the upward pipe 5B under the water surface of the degassing tank 7B, and the methane gas released from the water surface into the air passes through the gas discharge pipe 11. Through the multistage reaction tank 1. When methane gas passes through the upward pipe 5B, sludge water containing granules existing in the reaction chamber 10A rises in the same manner and flows into the degassing tank 7B due to the lift-up effect. As a result, similarly, the water level m in the degassing tank 7B rises higher than the water level n in the multistage reaction tank 1, and sludge water falls from the downward piping 6B due to the head difference (mn) and reacts. It flows into the chamber 10B.

このようにして反応室10A内のグラニュールの一部が反応室10Bに移送されることになる。また、被処理水の流入が断続的に停止するタイミングで、被処理水流れの方向に抗して、グラニュールが反応室10Bから落下し10A内に流入することも並行して行われる。このような運転を続行することにより、反応室10Aと反応室10Bとの間でグラニュール汚泥の循環混合が達成され、反応が効果的に行われる。   In this way, a part of the granules in the reaction chamber 10A is transferred to the reaction chamber 10B. Further, at the timing when the inflow of the treated water is intermittently stopped, the granule falls from the reaction chamber 10B and flows into the 10A in parallel with the direction of the treated water flow. By continuing such an operation, circulation and mixing of granular sludge is achieved between the reaction chamber 10A and the reaction chamber 10B, and the reaction is effectively performed.

このように、頂部を下方に向けた錐面状の隔壁2を形成し、その頂部に開口部3を設け、上向き配管5からなるガス抜き手段を設け、ガス抜き槽7と下向き配管6からなる汚泥返送手段を設けたことによって、多段式反応槽1内の片流れを防止し、さらに多段式反応槽1内においてグラニュール汚泥を十分に循環混合することができる。従って、従来のメタン発酵処理装置に比較してその処理効果を飛躍的に増加させることができる。すなわち、同一処理容量での比較においては、従来装置より処理装置の設置面積や設置コストを大幅に減少させることができ、また同一の設置面積あるいは装置の大きさでの比較では、処理容量を大幅に増加させるという効果を発揮することが可能となる。   In this way, the conical surface-like partition wall 2 with the top portion facing downward is formed, the opening portion 3 is provided at the top portion, the gas venting means including the upward pipe 5 is provided, and the gas vent tank 7 and the downward pipe 6 are provided. By providing the sludge return means, it is possible to prevent a single flow in the multistage reaction tank 1 and to sufficiently circulate and mix the granular sludge in the multistage reaction tank 1. Therefore, compared with the conventional methane fermentation treatment apparatus, the treatment effect can be dramatically increased. In other words, in the comparison with the same processing capacity, the processing equipment installation area and installation cost can be greatly reduced compared to the conventional equipment, and in the comparison with the same installation area or equipment size, the processing capacity is greatly increased. It is possible to exert the effect of increasing the number of times.

図3は、メタンガスの貯留タンク12を含めた本発明のメタン発酵処理装置の概略フロー図である。多段式反応槽1の最上部に連通したガス放出管11の他端は貯留タンク12に接続されている。また、貯留タンク12にはガス吹き込み管13の一端が連通し、その他端は、反応室10Z内の上向き配管5A直下に開口され、ガス吹き込み管13を通してガスを吹き込み可能なブロワ14がガス吹き込み管13の中途部分に設置されている。   FIG. 3 is a schematic flow diagram of the methane fermentation treatment apparatus of the present invention including the methane gas storage tank 12. The other end of the gas discharge pipe 11 communicated with the uppermost part of the multistage reaction tank 1 is connected to a storage tank 12. Further, one end of a gas blowing pipe 13 communicates with the storage tank 12, and the other end is opened directly below the upward pipe 5A in the reaction chamber 10Z, and a blower 14 capable of blowing gas through the gas blowing pipe 13 is provided with the gas blowing pipe. 13 is installed in the middle.

貯留タンク12に、ブロワ14を有するガス吹き込み管13を接続することにより、貯留タンク12内に貯留されたメタンガスを、ガス吹き込み管13を介して多段式反応槽1内に吹き込むことができる。このようなガスの吹き込みにより、メタンガスが上向き配管5A内を高流速で上昇するので、ガスリフトアップ効果をより顕著に発生させ、反応室10Z内の汚泥水を高流速でガス抜き槽7A内に流入させることができる。このようにしてグラニュールの攪拌混合を促進し、メタン発酵処理の効果を大幅に増大させることが可能となる。さらに、多段式反応槽1の外部からメタンガスを吹き込むことにより、メタンガスの気泡発生の際に生じる振動によって粒子径の大きなグラニュールがほぐされ、より小粒子径のグラニュールへと分散されるので、グラニュールの表面積を増加させ、メタン発酵処理の効果をさらに増大させることができる。   By connecting the gas blowing pipe 13 having the blower 14 to the storage tank 12, the methane gas stored in the storage tank 12 can be blown into the multistage reaction tank 1 through the gas blowing pipe 13. By blowing such gas, the methane gas rises in the upward pipe 5A at a high flow rate, so that the gas lift-up effect is more prominently generated and the sludge water in the reaction chamber 10Z flows into the gas vent 7A at a high flow rate. Can be made. In this way, stirring and mixing of the granules can be promoted, and the effect of the methane fermentation treatment can be greatly increased. Further, by blowing methane gas from the outside of the multistage reaction tank 1, the granules having a large particle size are loosened by vibrations generated when bubbles of the methane gas are generated, and dispersed into granules having a smaller particle size. The surface area of the granules can be increased and the effect of the methane fermentation treatment can be further increased.

なお、図3ではガス吹き込み管13の他端を上向き配管5Aの直下に開口させているが、これに限定されず、反応室10Z内あるいは上向き配管5A内の任意の場所に開口させてもよい。   In FIG. 3, the other end of the gas blowing pipe 13 is opened directly below the upward pipe 5A. However, the present invention is not limited to this, and the gas blowing pipe 13 may be opened at any place in the reaction chamber 10Z or the upward pipe 5A. .

また、図3ではガス吹き込み管13の他端を反応室10Z内のみに開口させているが、ガス吹き込み管13の他端を分岐して反応室10A内にも開口させることにより、グラニュールの攪拌混合の増加をより広範囲に及ぼすことができる。   Further, in FIG. 3, the other end of the gas blowing tube 13 is opened only in the reaction chamber 10Z, but the other end of the gas blowing tube 13 is branched and opened in the reaction chamber 10A, so that the granule The increase in stirring and mixing can be affected more widely.

本発明に係るメタン発酵処理装置は、各種有機性産業廃水、下水、し尿等の廃水を処理するために利用することができる。   The methane fermentation treatment apparatus according to the present invention can be used for treating various organic industrial wastewater, sewage, human waste and other wastewater.

1 多段式反応槽
2、2A、2B、2C 隔壁
3、3A、3B、2C 開口部
4 越流樋
5、5A、5B 上向き配管
6、6A、6B 下向き配管
7、7A、7B ガス抜き槽
8 流入部
9 流出管
10、10Z、10A、10B、10C 反応室
11 ガス放出管
12 浮上ガス阻止板
1 Multistage reaction tank 2, 2A, 2B, 2C Bulkhead 3, 3A, 3B, 2C Opening 4 Overflow tank 5, 5A, 5B Upward piping 6, 6A, 6B Downward piping 7, 7A, 7B Degassing tank 8 Inflow Part 9 Outflow pipe 10, 10Z, 10A, 10B, 10C Reaction chamber 11 Gas discharge pipe 12 Floating gas blocking plate

Claims (10)

槽内部が隔壁により複数の反応室に区画された多段式反応槽からなり、該多段式反応槽内で被処理水とグラニュール汚泥とを接触させるメタン発酵処理装置であって、前記隔壁には被処理水が上流側反応室から下流側反応室に向けて通過する開口部が設けられ、最下流側の反応室にはグラニュール汚泥から分離された処理水を越流させて排出する越流部が設けられ、一の反応室内において発生したガスを前記越流部の越流面と同じ高さの水面下に導いて気中に抜き出すガス抜き手段と、該ガス抜き手段により前記ガスとともに前記水面下に導かれたグラニュール汚泥を前記一の反応室よりも下流側の他の反応室に返送する汚泥返送手段とを備えていることを特徴とするメタン発酵処理装置。  A methane fermentation treatment apparatus comprising a multistage reaction tank in which the inside of the tank is partitioned into a plurality of reaction chambers by partition walls, wherein the water to be treated and granular sludge are brought into contact in the multistage reaction tank, There is an opening through which the water to be treated passes from the upstream reaction chamber toward the downstream reaction chamber, and the overflow from the treated water separated from the granular sludge is discharged to the most downstream reaction chamber. A gas venting means for guiding the gas generated in one reaction chamber under the water surface at the same height as the overflow surface of the overflow section and extracting it into the air; together with the gas by the gas venting means, A methane fermentation treatment apparatus, comprising: sludge returning means for returning granule sludge guided below the water surface to another reaction chamber downstream of the one reaction chamber. 前記隔壁が、頂部を下方に向けて配置された錐面状に形成されている、請求項1に記載のメタン発酵処理装置。  The methane fermentation treatment apparatus according to claim 1, wherein the partition wall is formed in a conical surface shape having a top portion directed downward. 前記開口部が、前記頂部に形成されている、請求項2に記載のメタン発酵処理装置。  The methane fermentation treatment apparatus according to claim 2, wherein the opening is formed at the top. 前記汚泥返送手段が、前記グラニュール汚泥を前記他の反応室に重力で返送する下向き配管からなる、請求項1〜3のいずれかに記載のメタン発酵処理装置。  The methane fermentation treatment apparatus according to any one of claims 1 to 3, wherein the sludge returning means includes a downward pipe that returns the granular sludge to the other reaction chamber by gravity. 前記ガス抜き手段が、前記ガスを浮力で前記水面下に導く上向き配管からなる、請求項1〜4のいずれかに記載のメタン発酵処理装置。  The methane fermentation treatment apparatus according to any one of claims 1 to 4, wherein the degassing means includes an upward pipe that guides the gas below the water surface by buoyancy. 前記上向き配管が、前記一の反応室の周縁側に設けられている、請求項5に記載のメタン発酵処理装置。  The methane fermentation treatment apparatus according to claim 5, wherein the upward pipe is provided on a peripheral side of the one reaction chamber. 前記上向き配管内または/および反応室内に気体を吹き込むブロワが設けられている、請求項5または6に記載のメタン発酵処理装置。  The methane fermentation treatment apparatus according to claim 5 or 6, wherein a blower for blowing gas into the upward pipe or / and the reaction chamber is provided. 前記複数の反応室が上下方向に積層されている、請求項1〜7のいずれかに記載のメタン発酵処理装置。  The methane fermentation treatment apparatus according to any one of claims 1 to 7, wherein the plurality of reaction chambers are stacked in the vertical direction. 前記多段式反応槽に被処理水が断続的に供給される、請求項1〜8のいずれかに記載のメタン発酵処理装置。  The methane fermentation treatment apparatus according to any one of claims 1 to 8, wherein water to be treated is intermittently supplied to the multistage reaction tank. 前記開口部の上流側近傍に、前記上流側反応室内のガスが前記下流側反応室内に流入することを阻止する阻止板が設けられている、請求項1〜9のいずれかに記載のメタン発酵処理装置。  The methane fermentation according to any one of claims 1 to 9, wherein a blocking plate is provided in the vicinity of the upstream side of the opening to prevent the gas in the upstream reaction chamber from flowing into the downstream reaction chamber. Processing equipment.
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