JP5323444B2 - Composite substrate for oxide superconducting wire, manufacturing method thereof, and superconducting wire - Google Patents

Description

  The present invention relates to a composite substrate for an oxide superconducting wire, a method for producing the same, and a superconducting wire using such a composite substrate for an oxide superconducting wire, and in particular, a composite substrate for an oxide superconducting wire having a low magnetic property and a high orientation. About.

As a high-temperature superconducting wire using a metal substrate, for example, an oxide layer such as CeO ₂ , YSZ, Y ₂ O ₃ is oriented and laminated on a biaxially oriented polycrystalline metal substrate to form an intermediate layer, and YBCO or the like is formed thereon. An oxide superconducting layer formed by orientation is known (see, for example, Patent Documents 1 and 2).

  As a metal substrate used for such a high-temperature superconducting wire, an alloy substrate mainly made of Ni-W or a composite substrate formed by cladding (for example, see Patent Documents 3 and 4) is used. When a substrate is used, there are problems that (1) high saturation magnetization, (2) high superconducting characteristics, and (3) it is difficult to obtain a low-cost superconducting wire.

  With respect to the problem of saturation magnetization in (1), the substrate of the Y-based superconducting wire is required to be non-magnetic or have as low magnetic properties as possible. Ni-3 atomic% W to Ni-5 atomic% W alloys are used for conventional metal substrates having high orientation characteristics such as Ni-W alloy and alloy clad, and the influence of magnetization of the substrate itself is affected. There is a problem that it cannot be ignored.

  In addition, as a method of manufacturing a Y-based oxide superconducting wire, there is a method of forming an intermediate layer on a Hastelloy (registered trademark) substrate, which is a nonmagnetic metal, using the IBAD method, but the manufacturing cost is high because a vacuum process is used. There is a problem.

  The RABiTS method of laminating an intermediate layer on an alignment substrate made of Ni-3at% W or Ni-5at% W alloy is a non-vacuum process and is a promising technique for obtaining a low-cost wire. Is affected by saturation magnetization. In order to make the substrate magnetic low or non-magnetic, it is necessary to increase the concentration of W and to reduce the thickness of the Ni layer.

  However, when W is increased in concentration, the superconducting characteristics are deteriorated due to a decrease in orientation, and the thinning of the Ni layer has a limit in the alloy cladding process, which prevents the demagnetization and the lowering of magnetism. is there.

Next, regarding the problem of the superconducting characteristics of (2), in order to manufacture a Y-type oxide superconducting wire having high superconducting characteristics, the degree of orientation of the crystal grains of the metal substrate is high, and the surface is intermediate. It is required that an oxide layer such as CeO ₂ , YSZ, or Y ₂ O ₃ can be epitaxially grown as a layer, and the degree of orientation of the oxide intermediate layer is equal to or higher than that of the substrate.

  In the Ni-W alloy substrate, high orientation characteristics are obtained by the Ni-3 atomic% W or Ni-5 atomic% W alloy, but in terms of low magnetism and non-magnetism, a high concentration of W is required. . However, in a high W concentration alloy of Ni-5 atomic% W alloy or higher, the orientation is remarkably lowered.

Further, regarding the cost problem of (3), that is, the productivity of the substrate, in the manufacturing process of the Ni—W alloy substrate and the Ni—alloy clad, there is a high demand for surface roughness on the finished surface of the roll, and Ra is 10 nm. The following is required. At this time, high quality control is required from the raw material to all rolling processes and heat history processes, which limits the material yield and hinders cost reduction.
Japanese Patent Application No. 2005-100635 Japanese Patent Application No. 11-3620 Japanese Patent Application No. 2001-236834 Japanese Patent Application No. 2006-286212

  The present invention has been made under the circumstances as described above, and an object thereof is to provide a composite substrate for oxide superconducting wire having low magnetism, high strength, and high orientation, a method for producing the same, and a superconducting wire.

  In order to solve the above-described problems, a first aspect of the present invention is an oxide superconducting wire having a non-oriented metal layer made of a metal core material and a surface alignment layer provided on one or both surfaces of the metal layer. A composite substrate for an oxide, comprising an element contained in the metal layer, wherein the concentration of the element decreases from the interface with the metal layer toward the surface of the surface alignment layer. A composite substrate for physical superconducting wires is provided.

  In such a composite substrate for oxide superconducting wires, the thickness of the surface alignment layer can be 0.01 to 10 μm, and can be 1/10 or less of the total thickness of the composite substrate.

  As the metal core material, a Ni alloy having a saturation magnetization of 0.2 T or less can be used. Further, the metal core material is an alloy of Ni and at least one additive element selected from the group consisting of W, Mo, Cr, V, Fe, and Cu, and the additive element is 1 in the alloy. Those containing ˜80 atomic% can be used. The alloy can further contain Nb and / or Ta.

  As the surface alignment layer, Ni or a material obtained by adding at least one element selected from the group consisting of W, Ag, Au, Cr, Cu, Mo, and V to Ni can be used.

  In this case, the surface alignment layer may further include P and / or S.

  The outermost surface layer of the surface alignment layer does not include a diffusion element from the metal layer, and a diffusion layer including a diffusion element from the metal layer is formed at the interface between the metal layer and the surface alignment layer. It can be configured. Alternatively, the surface alignment layer may include a diffusion element from the metal layer up to the surface. In any case, the concentration of the diffusing element in the surface alignment layer can be 0.1 to 12 atomic%.

  In a second aspect of the present invention, a step of forming a composite substrate by plating one or both sides of a non-oriented metal layer made of a metal core material, and the composite substrate subjected to the plating at 400 ° C. to 1200 ° C. A first heat treatment step in which heat treatment is performed, a step in which the heat treated composite substrate is rolled and the plating layer is used as a surface orientation layer, and a step in which the rolled composite substrate is heat treated at 400 ° C. to 1200 ° C. The surface alignment layer includes an element contained in the metal layer by diffusion from the metal layer by the first and second heat treatment, and the concentration of the element is different from that of the metal layer. A method for producing a composite substrate for an oxide superconducting wire, characterized by having a concentration gradient that decreases from the interface to the surface of the surface alignment layer.

  In such a method of manufacturing a composite substrate for oxide superconducting wires, the rolling step can be performed at a rolling rate of 40% to 99%.

  The second heat treatment can be performed by holding at 400 ° C. to 1200 ° C. for 0.5 hours or more in an argon gas atmosphere containing 2 to 5% by volume of hydrogen.

  A third aspect of the present invention provides a superconducting wire characterized by forming a superconducting layer directly or via an intermediate layer on the surface alignment layer of the composite substrate described above.

  According to the present invention, a composite substrate for oxide superconducting wire having low magnetism, high strength, and high orientation can be obtained at low cost, and the superconducting properties are excellent using this composite substrate for oxide superconducting wire. Superconducting wire can be realized.

  Hereinafter, embodiments of the invention will be described.

  FIG. 1 is a cross-sectional view showing a superconducting wire composite substrate according to an embodiment of the present invention. As shown in FIG. 1, the superconducting wire composite substrate 1 includes a non-oriented metal layer 2 and a surface alignment layer 3 provided on one or both surfaces of the metal layer 2. The surface alignment layer 3 includes the same element as the element included in the metal layer 2 and has a concentration gradient in which the concentration of the element decreases from the interface with the metal layer 2 toward the surface of the surface alignment layer 3. Here, the surface alignment layer 3 means a layer having a biaxial orientation degree ΔΦ = 10.0 or less.

  The non-oriented metal layer 2 is desirably a metal core material made of a Ni alloy having a saturation magnetization of 0.2 T or less. Using a Ni alloy having a saturation magnetization exceeding 0.2 T is not preferable because the AC loss of the superconducting wire increases. Examples of such Ni alloys include alloys of Ni and at least one additional element selected from the group consisting of W, Mo, Cr, V, Fe, and Cu. Also, such alloys can further include Nb and / or Ta.

  These additive elements are preferably contained in the alloy in an amount of 1 to 80 atomic%, and can be appropriately adjusted so as to obtain a saturation magnetization of 0.2 T or less within this range. If the concentration of the additive element in the alloy is less than 1 atomic%, the strength of the composite substrate decreases and the magnetism increases. If it exceeds 80 atomic%, the rolling processability decreases and the base material manufacturing cost increases. Absent.

  As the metal core material, Hastelloy (registered trademark), Inconel (registered trademark), and stainless steel can be used. When a Ni-W alloy is used as the metal core material, the W concentration is preferably 6 to 12 atomic%.

  As the surface alignment layer, Ni or a material obtained by adding at least one element selected from the group consisting of W, Ag, Au, Cr, Cu, Mo, and V to Ni can be used.

  The surface alignment layer 3 has a thickness of 0.01 to 10 μm. If the thickness of the surface alignment layer 3 is less than 0.01, it is not preferable because the thermal history is likely to be affected by significant diffusion contamination of the metal core material element, and the orientation is lowered. If it exceeds 10 μm, the magnetism increases. It is not preferable.

  The thickness of the surface alignment layer is desirably 1/10 or less of the total thickness of the composite substrate. Thus, by setting the thickness of the surface alignment layer to 1/10 or less of the total thickness of the composite substrate, it is possible to reduce the magnetic properties of the composite substrate, and the alignment substrate maintaining high orientation is rolled. In a plating process for forming a surface alignment layer, which will be described later, which is obtained by a process with a short process history, the range of manufacturing conditions is expanded to about 500 mm width, and the cost can be reduced.

  Next, a process for manufacturing the superconducting wire composite substrate shown in FIG. 1 will be described with reference to the process diagram of FIG.

  First, a surface alignment layer is formed by plating on one or both surfaces of the metal core material. The plating method is not limited to the wet plating method, and a dry plating method such as sputtering can also be used. The plating may be glossy or matte.

  The surface alignment layer is not limited to a single layer but may be a plurality of layers. For example, an Ag layer can be alternately formed by sputtering and a Ni—W alloy layer can be alternately formed by wet plating, or a plurality of layers can be formed by dry plating or wet plating. In addition, Mo layers are alternately formed by sputtering and Ni—W alloy layers are formed by wet plating, and Mo is diffused from the Mo layer to the Ni—W alloy layer by subsequent heat treatment. Multi-element alloying is possible. By performing multi-element alloying in this way, the use of rare metals such as W can be dispersed, and economic effects can be expected.

  When the surface alignment layer is formed by plating, the surface alignment layer contains P and S as impurities.

  The thickness of the plating layer is preferably 1 to 200 μm, more preferably 25 to 75 μm. If the thickness of the plating layer is less than 1 μm, the final thickness of the composite substrate is not easily affected by significant diffusion contamination from the non-oriented metal layer, and the orientation deteriorates. This increases the cost and is not economically preferable.

  After forming a metal film constituting the surface alignment layer by plating on one or both sides of the non-oriented metal layer made of the metal core material, the composite substrate is heated at a temperature of 400 ° C. to 1200 ° C. 1 is subjected to the heat treatment. By this first heat treatment, the additive element in the metal core material diffuses into the surface alignment layer. As a result, the concentration of the additive element in the surface alignment layer becomes a concentration distribution that decreases toward the surface alignment layer surface. In this manner, the metal core material and the surface alignment layer are diffusion bonded, and the diffusion layer is interposed at the interface.

  When the temperature of the first heat treatment is relatively low within the above range, no additive element is present on the surface of the surface alignment layer. When the temperature of the first heat treatment is relatively high within the above range, The additive element is present at a predetermined concentration on the surface. In the latter case, the concentration of the additive element diffused from the metal layer as a whole is preferably 0.1 to 12 atomic%, more preferably 9 atomic% or less.

  If the concentration of the additive element exceeds 9 atomic%, the rolling processability deteriorates, and an intermetallic compound that hinders the processability tends to be formed on the high concentration range side. An increase in element concentration is likely to occur, and the orientation characteristics of the substrate are degraded.

  The first heat treatment can be performed in a reducing atmosphere, for example, a mixed gas of argon and hydrogen.

  After the first heat treatment, the composite substrate is rolled. This rolling process is performed at a rolling rate of 40% to 99%, for example. As a result of this rolling, the thickness of the surface alignment layer becomes 0.01 to 10 μm. If the thickness of the surface alignment layer is less than 0.01 μm, it is not preferred because it is susceptible to the significant diffusion contamination of the elements from the non-oriented metal layer and the orientation is lowered, and if it exceeds 10 μm, the thickness of the surface layer is not preferable. Fluctuation tends to occur and magnetism increases, which is not preferable.

  A rolling rate of less than 40% is not preferable because a sufficient rolling texture cannot be obtained.

  The composite substrate is subjected to a second heat treatment at a temperature of 400 ° C. to 1200 ° C. after being rolled. By this second heat treatment, the surface alignment layer is biaxially aligned, and a composite substrate for oxide superconducting wire is obtained.

  The second heat treatment can also be performed in a reducing atmosphere, for example, a mixed gas of argon and hydrogen. The proportion of hydrogen in the mixed gas is preferably 2 to 5% by volume. If the proportion of hydrogen in the mixed gas is less than 2% by volume, the surface layer becomes insufficiently reduced and the cleanliness is lowered. It becomes deep and is not preferable.

  As described above, a composite substrate for a superconducting wire having low magnetism, high strength, and high orientation can be manufactured.

  In addition, a superconducting wire having excellent superconducting properties can be obtained by forming a superconducting layer directly or via an intermediate layer on the composite substrate thus obtained.

  Examples of the present invention will be shown below, and the present invention will be specifically described.

  However, application of the present invention is not limited to the following examples. The concentration gradient shown below was evaluated by line analysis by energy dispersive X-ray spectrometer (EDX).

Example 1
Matte Ni plating is applied to one side of a metal tape made of a nickel alloy of Ni-9 atomic% W having a thickness of 1.0 mm, a width of 100 mm and a length of 500 m by a wet plating method to a thickness of 30 μm. It was. Here, the composition of the nickel alloy is not limited to 9 atomic% W, and can be used in the range of 6 atomic% to 12 atomic%.

  The composite substrate was subjected to a first heat treatment by being held at 900 ° C. for 1 hour in a mixed gas atmosphere of argon gas and hydrogen. By this first heat treatment, W atoms in the nickel alloy diffused into the Ni plating layer, and showed a concentration gradient that decreased toward the surface of the plating layer. The outermost surface layer of the plating layer did not contain W atoms from the nickel alloy.

  The results of EDX line analysis are shown in FIG. FIG. 3A is a cross-sectional photograph of the composite substrate for oxide superconducting wire obtained in Example 1 using a scanning electron microscope (SEM), and shows the result of the line analysis obtained by EDX ray analysis. It shows the correspondence. EDX ray analysis was performed at the line analysis position shown in FIG. The result at this time is shown in FIG.

  In FIG. 3B, the vertical axis indicates the X-ray intensity, and the horizontal axis indicates the line analysis position when the surface of the post-attached copper layer of the composite substrate shown in FIG. As can be seen from the result of FIG. 3B, the thickness t of the surface alignment layer is about 3 μm, and in the surface alignment layer, W, which is an additive element in the non-oriented metal layer, is the surface alignment layer and the metal. It can be seen that the concentration decreases from the interface of the layer toward the surface of the surface alignment layer (interface with the retrofitted copper layer). It can also be seen that the W concentration is zero on the surface of the surface alignment layer (interface with the retrofitted copper layer).

  Next, the heat-treated composite substrate was finished into a tape having a thickness of 100 μm and a width of 10 mm × 9 by slitting with roll rolling and finished size. At this time, the thickness of the Ni plating layer on the surface was about 3 μm. Thereby, 90% or more of the rolling processing rate was ensured.

  Thus, by making the thickness of the plating film on the surface about 1/30 of the total thickness of the metal tape, it is possible to reduce the magnetism. The metal tape was held in a mixed gas atmosphere of argon gas and hydrogen at 600 ° C. for 2 hours to perform a second heat treatment (orientation heat treatment), and the outermost Ni plating layer was biaxially oriented.

  When the degree of orientation of the Ni plating layer was examined, in the X-ray pole figure, the biaxial orientation degree ΔΦ = 8.8 and the surface roughness of 10 μm square by an atomic force microscope (AFM) was Ra = 7.9.

  When the tensile test of this metal tape was performed at room temperature, the 0.2% yield strength was 590 MPa. The saturation magnetization was 0.022T. Therefore, according to this example, a metal tape which is a composite substrate having high strength, high orientation, and low magnetic property could be manufactured.

On this metal tape, an oxide intermediate layer made of CeO ₂ was formed to a thickness of about 200 nm using an electron beam evaporation apparatus. At this time, with the CeO ₂ X-ray diffraction meter, the degree of orientation P = 93% in the ratio of the (200) crystal axis to the (111) crystal axis, and in the X-ray pole figure, the biaxial orientation degree ΔΦ = 8.6. According to the atomic force microscope (AFM), the surface roughness was Ra = 7.2.

Further, a YBCO superconductor was deposited to a thickness of about 400 nm on the oxide intermediate layer made of CeO ₂ by a pulse laser deposition method. Then, on the YBCO superconductor, silver was vapor-deposited to a thickness of about 1 μm using a high frequency sputtering apparatus to form an electrode portion and a superconducting wire.

  With respect to the superconducting wire thus obtained, the critical current was measured using the four-terminal method while immersed in liquid nitrogen. As a result, the conduction characteristic of the superconducting wire was a critical current of 90 A with a definition of 1 μV / cm.

Example 2
Matte Ni plating is applied to one side of a metal tape made of a nickel alloy of Ni-9 atomic% W having a thickness of 1.0 mm, a width of 100 mm and a length of 500 m by a wet plating method to a thickness of 30 μm. It was. Here, the composition of the nickel alloy is not limited to 9 atomic% W, and can be used in the range of 6 atomic% to 12 atomic%.

  The composite substrate was subjected to a first heat treatment by being held at 1050 ° C. for 3 hours in a mixed gas atmosphere of argon gas and hydrogen. By this first heat treatment, W atoms in the nickel alloy diffused into the Ni plating layer, and showed a concentration gradient that decreased toward the surface of the plating layer. As a result of the EDX line analysis, it was confirmed that the W concentration decreased from the interface between the surface alignment layer and the metal layer toward the surface of the surface alignment layer, similarly to the result of Example 1 (FIG. 3). .

  The plating layer became a Ni-0.5 atomic% W alloy layer due to the diffusion of W atoms in the nickel alloy into the plating layer. In this case, the W concentration of the plating layer is preferably 0.1 to 12 atomic%, and more preferably 0.5 to 7 atomic%.

  Next, the heat-treated composite substrate was finished into a tape having a thickness of 100 μm and a width of 10 mm × 9 by slitting with roll rolling and finished size. At this time, the thickness of the Ni-0.5 atomic% W alloy layer was about 3 μm. Thereby, 90% or more of the rolling processing rate was ensured.

  Thus, by making the thickness of the plating film on the surface about 1/30 of the total thickness of the metal tape, it is possible to reduce the magnetism. The metal tape was subjected to a second heat treatment (orientation heat treatment) by holding it at 700 ° C. for 1 hour in a mixed gas atmosphere of argon gas and hydrogen, and the Ni-0.5 atomic% W alloy layer was biaxially oriented. I let you.

  When the degree of orientation of the plating layer was examined, in the X-ray pole figure, the biaxial orientation degree ΔΦ = 8.6 and the surface roughness of 10 μm square by an atomic force microscope (AFM) was Ra = 6.7.

  When this metal tape was subjected to a tensile test at room temperature, the 0.2% yield strength was 500 MPa. The saturation magnetization was 0.015T. Therefore, according to this example, as in Example 1, a metal tape, which is a composite substrate having high strength, high orientation, and low magnetic property, could be manufactured.

On this metal tape, an oxide intermediate layer made of CeO ₂ was formed to a thickness of about 200 nm using an electron beam evaporation apparatus. At this time, with the CeO ₂ X-ray diffraction meter, the degree of orientation P = 93% in the ratio of the (200) crystal axis to the (111) crystal axis, and in the X-ray pole figure, the biaxial orientation degree ΔΦ = 8.6. According to the atomic force microscope (AFM), the surface roughness was Ra = 6.7.

Further, a YBCO superconductor was deposited to a thickness of about 400 nm on the oxide intermediate layer made of CeO ₂ by a pulse laser deposition method. Then, on the YBCO superconductor, silver was vapor-deposited to a thickness of about 1 μm using a high frequency sputtering apparatus to form an electrode portion and a superconducting wire.

  With respect to the superconducting wire thus obtained, the critical current was measured using the four-terminal method while immersed in liquid nitrogen. As a result, the conduction characteristic of the superconducting wire was a critical current of 120 A with a definition of 1 μV / cm.

Example 3
A metal tape was manufactured in the same manner as in Example 1 except that a metal tape made of a nickel alloy of Ni-9 atom% Mo was used instead of the nickel alloy of Ni-9 atom% W.

  As confirmed by EDX line analysis, the concentration of Mo as an additive element decreased from the interface between the surface alignment layer and the metal layer toward the surface of the surface alignment layer, similarly to the result of Example 1 (FIG. 3). .

  When the degree of orientation of the Ni plating layer of this metal tape was examined, in the X-ray pole figure, the biaxial orientation degree ΔΦ = 8.7 and the surface roughness of 10 μm square by an atomic force microscope (AFM) was Ra = 7.5. Met.

  When this metal tape was subjected to a tensile test at room temperature, the 0.2% yield strength was 560 MPa. The saturation magnetization was 0.021T. Therefore, according to this example, a metal tape which is a composite substrate having high strength, high orientation, and low magnetic property could be manufactured.

On this metal tape, an oxide intermediate layer made of CeO ₂ was formed to a thickness of about 200 nm using an electron beam evaporation apparatus. At this time, with the CeO ₂ X-ray diffraction meter, the degree of orientation P = 93% in the ratio of the (200) crystal axis to the (111) crystal axis, and in the X-ray pole figure, the biaxial orientation degree ΔΦ = 8.7. According to the atomic force microscope (AFM), the surface roughness was Ra = 7.5.

Further, a YBCO superconductor was deposited to a thickness of about 400 nm on the oxide intermediate layer made of CeO ₂ by a pulse laser deposition method. Then, on the YBCO superconductor, silver was vapor-deposited to a thickness of about 1 μm using a high frequency sputtering apparatus to form an electrode portion and a superconducting wire.

  With respect to the superconducting wire thus obtained, the critical current was measured using the four-terminal method while immersed in liquid nitrogen. As a result, the conduction characteristic of the superconducting wire was a critical current of 95 A with a definition of 1 μV / cm.

Table 1 below collectively shows the characteristics of the composite substrates of Examples 1 to 3.

Sectional drawing which shows the composite substrate for oxide superconducting wires which concerns on one Embodiment of this invention. The process drawing which shows the manufacturing process of the composite substrate for oxide superconducting wires which concerns on one Embodiment of this invention. The cross-sectional SEM photograph and EDX analysis result of the composite substrate for oxide superconducting wires which concern on one Embodiment of this invention.

Explanation of symbols

  DESCRIPTION OF SYMBOLS 1 ... Composite substrate for superconducting wires, 2 ... Metal layer, 3 ... Surface orientation layer.

Claims (9)

A non-oriented metal layer;
An oxide composite substrate for superconducting wire having a surface alignment layer on one surface or disposed on both surfaces of the metal layer,
The non-oriented metal layer is an alloy of Ni and at least one additive element selected from the group consisting of W, Mo, Cr, V, Fe, and Cu, and the additive element includes 1 to 80% by atom and having a saturation magnetization of 0.2T or less,
The surface alignment layer is made of Ni or a material obtained by adding at least one element selected from the group consisting of W, Ag, Au, Cr, Cu, Mo and V to Ni,
Containing the same element as the additional element contained in the non-oriented metal layer, the concentration of the same element having a concentration gradient that decreases from the interface with the metal layer toward the surface of the surface orientation layer ; and
The thickness of the surface alignment layer is a 0.01 to 10 [mu] m, an oxide superconducting wire composite substrate according to claim 1/10 der Rukoto thickness of the composite whole substrate. The surface alignment layer is an oxide superconducting wire composite substrate according to claim 1, further comprising a P and / or S. The outermost surface layer of the surface alignment layer does not include a diffusing element diffused from an element included in the non-oriented metal layer, and the interface between the non-oriented metal layer and the outermost surface layer is not aligned. oxide superconducting wire composite substrate according to claim 1 or 2, characterized in that the diffusion layer is formed comprising a diffusing element from the metal layer. The surface alignment layer is an oxide superconducting wire composite substrate according to any one of claims 1 to 3, characterized in that it comprises a diffusing element from the non-oriented metal layer up to the surface. The concentration of the diffusion element of the surface alignment layer is an oxide superconducting wire composite substrate according to claim 3 or 4, characterized in that a 0.1 to 12 atomic%. Plating one side or both sides of a non-oriented metal layer having a saturation magnetization of 0.2 T or less made of a metal core material to form a composite substrate;
A first heat treatment step of heat-treating the plated composite substrate at 400 ° C. to 1200 ° C., rolling the heat-treated composite substrate, and using the plated layer as a surface alignment layer;
Said rolled composite substrate and a second heat treatment step of heat-treating at 400 ° C. to 1200 ° C.,
The non-oriented metal layer is an alloy of Ni and at least one additive element selected from the group consisting of W, Mo, Cr, V, Fe, and Cu, and the additive element includes 1 to 80 atomic percent included,
The surface alignment layer is made of Ni or a material obtained by adding at least one element selected from the group consisting of W, Ag, Au, Cr, Cu, Mo and V to Ni,
The surface alignment layer contains the same element as the element contained in the non-oriented metal layer by the first and second heat treatment, and the concentration of the same element from the interface with the non-oriented metal layer is the surface orientation. method of manufacturing an oxide composite substrate for superconducting wire characterized by having a concentration gradient which decreases toward the surface of the layer. The rolling process, the production method of the oxide composite substrate for superconducting wire according to claim 6, characterized in that it is carried out by rolling ratio of 40% to 99%. The second heat treatment, according to claim 6 or 7, characterized in that is carried out by holding in an atmosphere of argon gas containing 2 to 5% by volume of hydrogen, 400 ° C. to 1200 ° C. at 0.5 hours method of manufacturing an oxide composite substrate for superconducting wire according to. Superconducting wire, characterized in that by forming a superconducting layer directly or via an intermediate layer on said surface alignment layer on the oxide composite substrate for superconducting wire according to any one of claims 1-5.

Images