JP5364226B2 - Adhesive composition, double-sided adhesive tape and adhesion method - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an adhesive composition usable for obtaining a double sided adhesive tape excellent in adhesion and impact resistance, to provide a double sided adhesive tape having adhesive layer comprising the adhesive composition, and to provide an adhesive method using the double sided adhesive tape. <P>SOLUTION: The adhesive composition comprises a polymer comprising (a) a 4-12C alkyl (meth)acrylate as a main component monomer and (b) a monomer having carboxy in 5-50 wt.% molecule per 100 wt.% whole monomer and giving a homopolymer having &le;70&deg;C glass transition temperature, the double sided adhesive tape is formed an adhesive layer on at least one side surface of a substrate, and the method adhering the coated surface with elements by using the double sided adhesive tape comprises using the double sided adhesive tape as its double sided adhesive tape, adhering a coated surface on the side of the adhesive layer comprising the double sided adhesive tape and adhering elements on the other adhesive layer. <P>COPYRIGHT: (C)2006,JPO&amp;NCIPI

Description

  The present invention relates to a pressure-sensitive adhesive composition, a double-sided pressure-sensitive adhesive tape having a pressure-sensitive adhesive layer comprising the pressure-sensitive adhesive composition, and an adhesion method using the double-sided pressure-sensitive adhesive tape.

  The double-sided pressure-sensitive adhesive tape can be punched into an arbitrary shape before being attached to an article, and has good workability. Therefore, the double-sided adhesive tape is used for fixing articles in various industrial fields. In particular, since display parts and nameplates of portable electronic devices such as PDAs and mobile phones have small and complicated parts to be fixed, double-sided adhesive tape is used to fix these small parts. There are many.

  A portable electronic device may fall from the desk due to its usage. Even in such a case, the portable electronic device is required to have durability that does not cause damage. However, conventionally, a double-sided pressure-sensitive adhesive tape used for fixing a small article such as a portable electronic device may not be durable because the small article may fall off when dropped. In order to improve the durability, it is conceivable to increase the adhesion area of the double-sided pressure-sensitive adhesive tape. However, there is a problem that a large bonding area cannot be secured due to restrictions on the design and functions of portable electronic devices.

  In recent years, portable electronic devices tend to be coated with water- and oil-repellent paints for design and antifouling properties. Since a conventional double-sided pressure-sensitive adhesive tape is difficult to adhere to a painted surface coated with such a paint, a double-sided pressure-sensitive adhesive tape that can be adhered to the painted surface is desired.

  The present invention allows the small parts to be removed even when an impact is applied to an object (even when the object is a water-repellent or oil-repellent painted surface) fixed with a double-sided adhesive tape. A pressure-sensitive adhesive composition that can be used for a double-sided pressure-sensitive adhesive tape excellent in adhesion and impact resistance that does not occur, a double-sided pressure-sensitive adhesive tape having a pressure-sensitive adhesive layer comprising such a pressure-sensitive adhesive composition, and such a double-sided pressure-sensitive adhesive tape An object is to provide an adhesion method to be used.

  As a result of intensive studies to solve the above problems, the present inventors have found that the pressure-sensitive adhesive composition contains a polymer composed of a specific (meth) acrylic acid alkyl ester and a specific carboxyl group-containing monomer. In order to obtain a double-sided pressure-sensitive adhesive tape excellent in heat resistance and impact resistance, it has been found that it can be suitably used, and the present invention has been completed.

That is, the present invention is as follows.
(1) In a double-sided pressure-sensitive adhesive tape in which a pressure-sensitive adhesive layer made of a pressure-sensitive adhesive composition is formed on both surfaces of a base material for bonding a painted surface and a part, the pressure-sensitive adhesive used for the pressure-sensitive adhesive layer that bonds the painted surface A composition comprising:
a) As a main component monomer, a (meth) acrylic acid alkyl ester having 4 to 12 carbon atoms of an alkyl group;
b) 5 to 50% by weight of monomers with respect to 100% by weight of the total monomers, having a carboxyl group in the molecule and having a glass transition temperature of 70 ° C. or less as a homopolymer thereof,
Containing a polymer consisting of
In the viscoelasticity measurement, the temperature was changed from −70 ° C. to 150 ° C. at a rate of temperature increase of 5 ° C./min while giving a shear strain with a frequency of 1 Hz, and data (loss tangent) every 12 seconds (every 1 ° C.) during this time. captures the value), the sum of the values of the loss tangent of each temperature 20 points 1 ± 0.2 ° C. increments in the temperature range of -61 ℃ ~-40 ℃ is characterized 10-40 der Rukoto, adhesive Agent composition.
( 2 ) A double-sided pressure-sensitive adhesive tape in which a pressure-sensitive adhesive layer made of a pressure-sensitive adhesive composition is formed on both surfaces of a base material for bonding a painted surface and a component,
Pressure-sensitive adhesive layer for bonding the coated surface is characterized the Turkey such from above (1) Symbol placement of the adhesive composition, the double-sided adhesive tape.
(3) the coated surface and the part to a method of adhering using double-sided adhesive tape, using double-sided adhesive tape of the above (2) wherein a double-sided adhesive tape, the above (1) Symbol placement of the pressure-sensitive adhesive composition An adhesion method, comprising: adhering a painted surface to the pressure-sensitive adhesive layer side, and adhering a component to the other pressure-sensitive adhesive layer side.

  The pressure-sensitive adhesive composition of the present invention provides a double-sided pressure-sensitive adhesive tape excellent in adhesiveness (especially on a coated surface coated with a water-repellent or oil-repellent paint, etc., on which the pressure-sensitive adhesive tape is difficult to adhere) and impact resistance. Therefore, it can be used suitably. Therefore, the double-sided pressure-sensitive adhesive tape of the present invention having a pressure-sensitive adhesive layer made of such a pressure-sensitive adhesive composition, and the bonding method of the present invention using such a double-sided pressure-sensitive adhesive tape are applied to various fields in which the double-sided tape is used. be able to. For example, it is useful for fixing small and complicated parts such as display parts and nameplates of portable electronic devices such as PDAs and mobile phones.

The present invention is described in detail below.
First, the pressure-sensitive adhesive composition will be described.
The pressure-sensitive adhesive composition of the present invention includes: a) (meth) acrylic acid alkyl ester having 4 to 12 carbon atoms as an alkyl group, and b) 5 to 50% by weight based on 100% by weight of all monomers And a polymer having a carboxyl group in the molecule and having a glass transition temperature (Tg) as a homopolymer of 70 ° C. or less (hereinafter abbreviated as a carboxyl group-containing monomer).

  Examples of the (meth) acrylic acid alkyl ester include, for example, n-butyl (meth) acrylate, isobutyl (meth) acrylate, sec-butyl (meth) acrylate, t-butyl (meth) acrylate, (meth) Pentyl acrylate, isopentyl (meth) acrylate, neopentyl (meth) acrylate, hexyl (meth) acrylate, heptyl (meth) acrylate, octyl (meth) acrylate, isooctyl (meth) acrylate, (meth) Examples include 2-ethylhexyl acrylate, nonyl (meth) acrylate, isononyl (meth) acrylate, decyl (meth) acrylate, isodecyl (meth) acrylate, undecyl (meth) acrylate, dodecyl (meth) acrylate, and the like. One of these can be used alone or in combination of two or more Rukoto can. Preferably, it is a C4-C9 (meth) acrylic acid alkyl ester of an alkyl group, More preferably, they are n-butyl acrylate, 2-ethylhexyl acrylate, isooctyl acrylate, and isononyl acrylate.

  The term “main component monomer” means that the (meth) acrylic acid alkyl ester is used in a proportion of 50 to 95% by weight based on 100% by weight of the total monomers. Preferably, the (meth) acrylic acid alkyl ester is used in a proportion of 55 to 95% by weight, more preferably 60 to 90% by weight. When the amount of the above (meth) acrylic acid alkyl ester is less than 50% by weight, when the obtained pressure-sensitive adhesive composition is applied to a pressure-sensitive adhesive tape as a pressure-sensitive adhesive layer, the pressure-sensitive adhesive force and cohesive force required for the pressure-sensitive adhesive tape can be obtained. On the other hand, when the amount is more than 95% by weight, the amount of the carboxyl group-containing monomer used in combination is less than 5% by weight, resulting in insufficient crosslinking and adhesion by the carboxyl group.

  The carboxyl group-containing monomer has a glass transition temperature as a homopolymer of 70 ° C. or lower, preferably 60 ° C. or lower, more preferably 50 ° C. or lower. When the glass transition temperature is higher than 70 ° C., the cohesive force of the obtained polymer becomes too high, and therefore, the pressure-sensitive adhesive tape to which the obtained pressure-sensitive adhesive composition is applied as a pressure-sensitive adhesive layer is inferior in impact resistance.

  Specific examples of the carboxyl group-containing monomer include, for example, ω-carboxy-polycaprolactone mono (meth) acrylate, monohydroxymethyl (meth) acrylate phthalate, monohydroxyethyl phthalate (meth) acrylate, and monohydroxypropyl phthalate. (Meth) acrylate, monohydroxybutyl phthalate (meth) acrylate, monohydroxypentyl phthalate (meth) acrylate, monohydroxyhexyl phthalate (meth) acrylate, monohydroxyheptyl phthalate (meth) acrylate, monohydroxy phthalate Octyl (meth) acrylate, monohydroxy 2-ethylhexyl phthalate (meth) acrylate, monohydroxynonyl phthalate (meth) acrylate, monohydroxydecyl phthalate Meth) acrylate, monohydroxyundecyl phthalate (meth) acrylate, monohydroxydodecyl phthalate (meth) acrylate, monohydroxymethyl (meth) acrylate succinate, monohydroxyethyl succinate (meth) acrylate, monohydroxypropyl succinate (Meth) acrylate, monohydroxybutyl (meth) acrylate succinate, monohydroxypentyl (meth) acrylate succinate, monohydroxyhexyl (meth) acrylate succinate, monohydroxyheptyl succinate (meth) acrylate, monohydroxy succinate Octyl (meth) acrylate, succinic acid monohydroxy 2-ethylhexyl (meth) acrylate, succinic acid monohydroxynonyl (meth) acrylate, succinic acid monohydro Xyldecyl (meth) acrylate, monohydroxyundecyl (meth) acrylate succinate, monohydroxydodecyl (meth) acrylate succinate, acrylic dimer, trimer acrylate, monohydroxymethyl (meth) acrylate hexahexaphthalate, hexahydrophthal Acid monohydroxyethyl (meth) acrylate, hexahydrophthalic acid monohydroxypropyl (meth) acrylate, hexahydrophthalic acid monohydroxybutyl (meth) acrylate, hexahydrophthalic acid monohydroxypentyl (meth) acrylate, hexahydrophthalic acid mono Hydroxyhexyl (meth) acrylate, hexahydroxyphthalic acid monohydroxyheptyl (meth) acrylate, hexahydrophthalic acid monohydroxyoctyl ) Acrylate, hexahydroxyphthalic acid monohydroxy 2-ethylhexyl (meth) acrylate, hexahydrophthalic acid monohydroxynonyl (meth) acrylate, hexahydrophthalic acid monohydroxydecyl (meth) acrylate, hexahydrophthalic acid monohydroxyun Examples thereof include decyl (meth) acrylate and hexahydrophthalic acid monohydroxydodecyl (meth) acrylate, and one of these can be used alone or in combination of two or more. Preferred are ω-carboxy-polycaprolactone monoacrylate, acrylic acid dimer, succinic acid monohydroxyethyl acrylate, and hexahydrophthalic acid monohydroxyethyl acrylate.

  The amount of the carboxyl group-containing monomer is 5 to 50% by weight, preferably 5 to 45% by weight, and more preferably 10 to 40% by weight with respect to 100% by weight of the total monomers. When the amount of the carboxyl group-containing monomer is less than 5% by weight, the carboxyl group-containing monomer cannot sufficiently function as a crosslinking point in the obtained polymer (reaction with an optional crosslinking agent described later). Insufficient points or lack of pseudo-crosslinking due to hydrogen bonding between carboxyl groups). Therefore, when the obtained pressure-sensitive adhesive composition is applied to a pressure-sensitive adhesive tape as a pressure-sensitive adhesive layer, the cohesive force necessary for the pressure-sensitive adhesive tape is obtained. If the amount is more than 50% by weight, the viscosity of the resulting polymer increases, and therefore it becomes substantially difficult to make the resulting pressure-sensitive adhesive composition into a pressure-sensitive adhesive layer.

  As a monomer constituting the polymer contained in the pressure-sensitive adhesive composition of the present invention, if necessary, a copolymerizable monomer other than the above a) (meth) acrylic acid alkyl ester and b) carboxyl group-containing monomer may be used in combination. May be. The amount of such a copolymerizable monomer used may be appropriately selected according to the type of each monomer within a range of less than 45% by weight with respect to 100% by weight of the total monomers, but good pressure-sensitive adhesiveness. In order to express the above, it is desirable to determine the use amount so that the glass transition temperature of the obtained polymer is usually −30 ° C. or lower.

  Examples of the copolymerizable monomer include 1 to 1 carbon atoms of an alkyl group such as methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, and isopropyl (meth) acrylate. 3 (meth) acrylic acid alkyl esters, tridecyl methacrylate, (meth) acrylic acid stealyl (meth) acrylic acid alkyl ester having 13 to 18 carbon atoms, hydroxyalkyl (meth) acrylic acid, glycerin di Functional monomers such as methacrylate, glycidyl (meth) acrylate, methyl glycidyl methacrylate, 2-methacryloyloxyethyl isocyanate, (meth) acrylic acid, itaconic acid, maleic anhydride, crotonic acid, maleic acid, fumaric acid, triethylene Glycol diacrylate, Polyfunctional monomers such as lenglycol dimethacrylate, trimethylolpropane tri (meth) acrylate, vinyl acetate, styrene, cyclohexyl (meth) acrylate, (meth) acrylonitrile, n-vinylpyrrolidone, (meth) acryloylmorpholine, cyclohexylmaleimide, Examples thereof include isopropylmaleimide and (meth) acrylamide. One of these can be used alone, or two or more can be used in combination. Preferred are methyl methacrylate, ethyl acrylate, 2-hydroxyethyl acrylate, vinyl acetate, n-vinylpyrrolidone, acryloylmorpholine, cyclohexylmaleimide, and acrylamide.

  The method for polymerizing the monomer is not particularly limited, and examples thereof include a solution polymerization method, an emulsion polymerization method, a UV polymerization method, and the like. It is preferable to use a solution polymerization method from the viewpoint of water resistance and cost.

  Examples of the initiator used in the polymerization method include 2,2′-azobisisobutyronitrile, 2,2′-azobis (4-methoxy-2,4-dimethylvaleronitrile), and 2,2′-azobis. (2,4-dimethylvaleronitrile), 2,2′-azobis (2-methylbutyronitrile), 1,1′-azobis (cyclohexane-1-carbonitrile), 2,2′-azobis (2,4 , 4-trimethylpentane), dimethyl-2,2′-azobis (2-methylpropionate), etc., benzoyl peroxide, t-butyl hydroperoxide, di-t-butyl peroxide, t-butyl Peroxybenzoate, dicumyl peroxide, 1,1-bis (t-butylperoxy) -3,3,5-trimethylcyclohexane, 1,1- Scan (t-butylperoxy) - include oil-soluble initiators such as peroxide-based, such as cyclododecane, can be used alone or in combination of two or more, one of these. The amount of the initiator used may be an amount usually used in the polymerization method, and is, for example, 0.01 to 1 part by weight with respect to 100 parts by weight of the monomer.

  In addition, a chain transfer agent can be used in the polymerization so that the obtained polymer has an appropriate molecular weight. Examples of the chain transfer agent include conventional chain transfer agents such as lauryl mercaptan, glycidyl mercaptan, 2-mercaptoethanol, mercaptoacetic acid, 2-ethylhexyl thioglycolate, 2,3-dimercapto-1-propanol, and α-methyl. A styrene dimer etc. are mentioned, One of these can be used individually or in combination of 2 or more types. The amount of the chain transfer agent used may be an amount usually used in the polymerization method, and is, for example, about 0.01 to 15 parts by weight with respect to 100 parts by weight of the monomer.

  The solvent used in the above polymerization method may be any solvent that is generally used in a polymerization reaction, and examples thereof include ethyl acetate, toluene, n-butyl acetate, n-hexane, cyclohexane, methyl ethyl ketone, and methyl isobutyl ketone. One of these can be used alone, or two or more can be used in combination. The amount of the solvent used may be an amount usually used in the polymerization method, and is, for example, about 50 to 600 parts by weight with respect to 100 parts by weight of the monomer.

  Moreover, in order to improve the cohesion force of the adhesive layer which consists of this adhesive composition, the crosslinking agent can be mix | blended with the said adhesive composition as an additive. The crosslinking agent is not particularly limited, and conventionally known crosslinking agents can be used. For example, polyfunctional melamine compounds such as methylated methylol melamine and butylated hexamethylol melamine, diglycidyl aniline, glycerin Multifunctional epoxy compounds such as diglycidyl ether, polyfunctional isocyanate compounds such as tolylene diisocyanate, hexamethylene diisocyanate, polymethylene polyphenyl isocyanate, diphenylmethane diisocyanate, trimethylolpropane tolylene diisocyanate, polyether polyisocyanate, polyester polyisocyanate One of these can be used alone, or two or more can be used in combination. The usage-amount of a crosslinking agent is 0.001-20 weight part normally with respect to 100 weight part of polymers, Preferably it is 0.001-10 weight part. When the amount of the crosslinking agent used is less than 0.001 part by weight, the effect of improving the cohesive force of the target pressure-sensitive adhesive layer cannot be obtained, and when it is more than 20 parts by weight, sufficient cohesive force can be obtained. Power is reduced.

  In addition to the crosslinking agent, the adhesive composition includes general additives such as UV absorbers, light stabilizers, release modifiers, tackifiers, plasticizers, softeners, fillers, and coloring. You may mix | blend an agent (a pigment, dye, etc.), anti-aging agent, surfactant, etc.

The method for preparing the pressure-sensitive adhesive composition is not particularly limited. For example, a) (meth) acrylic acid alkyl ester, b) carboxyl group-containing monomer and other copolymerizable monomer as necessary. Polymerization is performed by the above polymerization method, and the mixture after the polymerization reaction is used as it is as an adhesive composition, and various additives described above may be added as necessary. After separation and purification, this isolated / purified polymer is dissolved or suspended in a solvent to form a pressure-sensitive adhesive composition, and the above-mentioned various additives may be added as necessary. The polymer itself may be mixed with the above-mentioned various additives as necessary to form a pressure-sensitive adhesive composition.
In addition, when isolating / purifying the produced polymer, the isolation / purification method is not particularly limited, and an isolation / purification method usually performed in the field of polymer synthesis can be used.

In a preferred embodiment of the present invention, the pressure-sensitive adhesive composition has a loss tangent (tan δ) at a temperature of 20 points in increments of 1 ± 0.2 ° C. in a temperature range of −61 ° C. to −40 ° C. in viscoelasticity measurement. The sum of the values is 10 to 40, more preferably 11 to 35, and still more preferably 12 to 30. When this total is less than 10, when the pressure-sensitive adhesive composition is applied as a pressure-sensitive adhesive layer of a double-sided pressure-sensitive adhesive tape, it is inferior in impact resistance, and when larger than 40, the pressure-sensitive adhesive composition is too soft and the pressure-sensitive adhesive layer. When it does, it is inferior to cohesion.
The total of the loss tangent values at 20 points of each temperature in increments of 1 ± 0.2 ° C. in the temperature range of −61 ° C. to −40 ° C. of the pressure-sensitive adhesive composition is, for example, a) containing a main component monomer and b) containing a carboxyl group By appropriately selecting the type and content of the monomer, the above range can be specified.

  Conventionally, as a method for improving the impact resistance of a double-sided pressure-sensitive adhesive tape, for example, JP-A-2001-72951, JP-A-2002-188061, JP-A-2004-59853, etc. A method of using a pressure-sensitive adhesive in which the maximum value and the temperature indicating the maximum value are specified in a specific range is described. However, in order to improve the impact resistance of the double-sided pressure-sensitive adhesive tape, the present inventors have determined that the loss tangent in the temperature range of −61 ° C. to −40 ° C. is higher than the maximum value of the loss tangent and the temperature indicating the maximum value. We found that the value of is a more important factor. That is, as a measure corresponding to the so-called area of the loss tangent in the measurement of the viscoelasticity of the pressure-sensitive adhesive composition, the value of the loss tangent at 20 points of each temperature in increments of 1 ± 0.2 ° C. in the temperature range of −61 ° C. to −40 ° C. It was found that the impact resistance of the double-sided pressure-sensitive adhesive tape is remarkably improved by defining the total of the above in the above range.

  In addition, although the viscoelasticity of an adhesive composition is described in detail in the following examples, using a viscoelasticity tester, a temperature rising rate of 5 ° C./min is applied while giving a shear strain of a frequency of 1 Hz to a test sample. Then, the temperature is changed from -70 ° C to 150 ° C. During this measurement, data (loss tangent value) is taken every 12 seconds (every 1 ° C), and the loss tangent value at each temperature (20 points) in increments of 1 ° C in the temperature range of -61 ° C to -40 ° C. To sum.

  The pressure-sensitive adhesive composition of the present invention is useful for adhesive applications in various fields, and is particularly useful as a pressure-sensitive adhesive composition for forming a pressure-sensitive adhesive layer of a pressure-sensitive adhesive tape, particularly a double-sided pressure-sensitive adhesive tape.

Next, the double-sided adhesive tape will be described.
As for the double-sided adhesive tape of this invention, the adhesive layer which consists of the said adhesive composition (adhesive composition of this invention) is formed in the at least single side | surface of a base material.

  The substrate is not particularly limited as long as it is generally used for double-sided adhesive tapes. For example, synthetic resin films such as polyethylene, polypropylene, polyethylene terephthalate, rubber sheets, paper, cloth, nonwoven fabric, foam Examples thereof include a sheet, a metal foil, and a composite thereof. Among these, a synthetic resin film and a non-woven fabric are preferably used from the viewpoints of strength, workability, dimensional stability, and the like. Although the thickness of a base material is not specifically limited, Usually, it is about 5-500 micrometers.

  The method for forming the pressure-sensitive adhesive layer is not particularly limited, and a method generally employed in the production of pressure-sensitive adhesive tapes can be used. For example, a method in which a solution obtained by dissolving a pressure-sensitive adhesive composition in a solvent such as toluene is applied onto a release liner, dried to form a pressure-sensitive adhesive layer, and the pressure-sensitive adhesive layer is transferred to a substrate. The method of apply | coating this solution directly on a base material, and drying and forming an adhesive layer etc. are mentioned. Although the thickness of an adhesive layer is not specifically limited, Preferably it is about 3-100 micrometers, More preferably, it is about 5-90 micrometers, More preferably, it is about 10-80 micrometers. If the pressure-sensitive adhesive layer is thinner than 3 μm, sufficient adhesive strength cannot be obtained. If it is thicker than 100 μm, glue sticking out or defective punching tends to occur when punching for fixing small parts. Inferior to sex.

  Examples of the release liner include the materials exemplified for the substrate. The surface of the release liner may be subjected to release treatment such as silicone treatment, long-chain alkyl treatment, fluorine treatment, etc., as necessary, in order to enhance the peelability from the pressure-sensitive adhesive layer.

  When the pressure-sensitive adhesive layer made of the pressure-sensitive adhesive composition of the present invention is formed only on one side of the substrate, the double-sided pressure-sensitive adhesive tape constitutes a pressure-sensitive adhesive that forms the pressure-sensitive adhesive layer formed on the other side of the substrate. As described above, various pressure-sensitive adhesives can be used depending on the adherend. Such various pressure-sensitive adhesives are not particularly limited, and examples thereof include acrylic pressure-sensitive adhesives and rubber-based pressure-sensitive adhesives. An acrylic adhesive is particularly preferably used from the viewpoints of cost, durability, adhesive properties and the like. As a method for forming such a pressure-sensitive adhesive layer made of various pressure-sensitive adhesives, the method exemplified in the method for forming a pressure-sensitive adhesive layer made of the pressure-sensitive adhesive composition of the present invention can be employed. Although the thickness of the adhesive layer which consists of various adhesives is not specifically limited, For example, it is preferable to set it as about 3-100 micrometers.

  The double-sided pressure-sensitive adhesive tape of the present invention is useful for fixing parts and the like in various fields, and is particularly useful for fixing parts to a painted surface (particularly, a water- and oil-repellent painted surface).

Next, a method for bonding a painted surface and a part using a double-sided adhesive tape will be described.
In the bonding method of the present invention, the double-sided pressure-sensitive adhesive tape (double-sided pressure-sensitive adhesive tape of the present invention) is used as the double-sided pressure-sensitive adhesive tape, and the coated surface is on the side of the pressure-sensitive adhesive layer comprising the pressure-sensitive adhesive composition (pressure-sensitive adhesive composition of the present invention). And adhere the part to the other side of the pressure-sensitive adhesive layer.

  The painted surface refers to various object surfaces on which coatings made of various resins such as silicone, polyester, acrylic, urethane, amide, and epoxy are formed. Examples of the parts include articles made of polycarbonate, acrylic, polyester, polyurethane, glass, metal, etc., which are general plastic materials.

  The bonding method of the present invention can be applied to the bonding of various painted surfaces and components, but in particular, a painted surface on which a coating made of a silicone resin is formed (a painted surface that is difficult to bond with conventional double-sided adhesive tapes). ) And the parts are useful.

  EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples. In the following, “part” means “part by weight” unless otherwise specified.

[Preparation of acrylic polymer solution A]
In a reactor equipped with a thermometer, stirrer, nitrogen inlet tube and reflux condenser, 94 parts of 2-ethylhexyl acrylate, 6 parts of acrylic acid dimer (Tg as homopolymer thereof: 45 ° C.), azobisisobutyronitrile 0.2 part and 100 parts of ethyl acetate as a polymerization solvent were added and stirred for 1 hour while introducing nitrogen gas. After removing oxygen in the polymerization system in this way, the temperature was raised to 63 ° C. and reacted for 10 hours. Next, after cooling to room temperature, 135 parts of ethyl acetate was added to obtain an acrylic polymer solution A having a solid concentration of 30% by weight.

[Preparation of acrylic polymer solution B]
The initial charge was 70 parts 2-ethylhexyl acrylate, 30 parts ω-carboxy-polycaprolactone monoacrylate (Tg as its homopolymer: −40 ° C.), 0.2 part azobisisobutyronitrile and 235 ethyl acetate. An acrylic polymer solution B having a solid content concentration of 30% by weight was obtained in the same manner as in [Preparation of acrylic polymer solution A] except that ethyl acetate was not added after cooling to room temperature.

[Preparation of acrylic polymer solution C]
The initial charge was 64 parts of 2-ethylhexyl acrylate, 30 parts of n-butyl acrylate, 6 parts of acrylic acid dimer (Tg as its homopolymer: 45 ° C.), 0.2 part of azobisisobutyronitrile and acetic acid. An acrylic polymer solution C having a solid concentration of 30% by weight was obtained in the same manner as in [Preparation of acrylic polymer solution A] except that 100 parts of ethyl was used.

[Preparation of acrylic polymer solution D]
The initial charge was 97 parts 2-ethylhexyl acrylate, 3 parts acrylic acid (Tg as its homopolymer: 106 ° C.), 0.2 part azobisisobutyronitrile and 100 parts ethyl acetate, In the same manner as in [Preparation of acrylic polymer solution A], an acrylic polymer solution D having a solid concentration of 30% by weight was obtained.

Example 1
A pressure-sensitive adhesive solution was prepared by adding 0.02 part of a tetrafunctional epoxy-based crosslinking agent to 100 parts of acrylic polymer solution A (in terms of solid content). This pressure-sensitive adhesive solution was cast and applied on a polyethylene terephthalate film (release liner: thickness 38 μm) having a release treatment on the surface so that the thickness after drying was 35 μm, and heated at 100 ° C. for 3 minutes. It dried and the adhesive layer was formed. Two sheets of these were prepared, bonded to a polyethylene terephthalate film (base material: thickness 12 μm) from both sides, and further aged at 50 ° C. for 48 hours to prepare a double-sided PSA sheet.

(Example 2)
A double-sided pressure-sensitive adhesive sheet was prepared in the same manner as in Example 1 except that 0.01 part of a tetrafunctional epoxy-based crosslinking agent was added to 100 parts of acrylic polymer solution B (in terms of solid content) to prepare a pressure-sensitive adhesive solution.

(Example 3)
A double-sided pressure-sensitive adhesive sheet was prepared in the same manner as in Example 1 except that 0.005 part of a tetrafunctional epoxy-based crosslinking agent was added to 100 parts (converted to solid content) of an acrylic polymer solution C to prepare a pressure-sensitive adhesive solution.

(Comparative Example 1)
A double-sided pressure-sensitive adhesive sheet was prepared in the same manner as in Example 1 except that 0.02 part of a tetrafunctional epoxy-based crosslinking agent was added to 100 parts of an acrylic polymer solution D (in terms of solid content) to prepare a pressure-sensitive adhesive solution.

(Comparative Example 2)
Double-sided adhesion in the same manner as in Example 1 except that 0.02 part of tetrafunctional epoxy-based crosslinking agent and 25 parts of rosin ester were added to 100 parts of acrylic polymer solution D (in terms of solid content) to prepare an adhesive solution. A sheet was produced.

  About the double-sided adhesive sheet produced as mentioned above, according to the method shown below, the impact resistance test, the adhesive force test, and viscoelasticity evaluation were done. The obtained results are shown in Table 1.

[Impact resistance test]
The double-sided pressure-sensitive adhesive sheet was punched into a frame shape having an outer shape of 40 mm × 30 mm and a width of 2 mm. Next, a polycarbonate plate of the same size is attached to the other surface of a polyethylene terephthalate film (external dimensions 45 mm × 35 mm, thickness 2 mm) having a silicone-based hard coating formed on one side to produce an adherend 1 did. Furthermore, a metal plate (outer shape 90 mm × 70 mm, thickness 2 mm, weight 100 g) was attached to one side of a polycarbonate plate (outer shape 80 mm × 60 mm, thickness 2 mm) to produce an adherend 2. Next, the adherend 1 and the adherend 2 are bonded together using the frame-shaped double-sided pressure-sensitive adhesive sheet so that the silicone hard coating of the adherend 1 and the polycarbonate plate of the adherend 2 face each other. A sample for impact resistance test was prepared.
The sample was allowed to stand at 23 ° C. for 24 hours, then dropped onto the concrete from a height of 1.5 m at 23 ° C., and the number of times until the adherend 1 was removed was measured. As for the method of dropping, the sample was dropped in a horizontal state so that the metal plate of the sample received a surface impact against the concrete. This is because the conditions are severer than when the sample is dropped in a vertical state (the force applied to the pressure-sensitive adhesive layer is in the shear direction) (the number of drops until the polycarbonate plate is dropped) is reduced. .

[Adhesion test]
A test piece was prepared by attaching a polyethylene terephthalate film having a thickness of 25 μm to one side of a double-sided PSA sheet having a width of 20 mm and a length of 120 mm. According to JIS Z-0237, this test piece was bonded to a SUS304BA plate by reciprocating a 19.6 N-weight roller in an atmosphere of 23 ° C. After 30 minutes, the peel adhesive strength was measured at a peel speed of 300 mm / min using a Tensilon peel tester.

[Viscoelasticity evaluation]
In the same manner as in Examples 1 to 3 and Comparative Examples 1 and 2, an adhesive layer having a thickness of 35 μm was formed on the release liner. The plurality of pressure-sensitive adhesive layers formed in this manner were superposed so that the total thickness was about 2 mm, to prepare a test sample. Next, this test sample was punched out into a disk shape having a diameter of 7.9 mm, sandwiched between parallel plates, and heated at 5 ° C./min while applying a shear strain of a frequency of 1 Hz using a rheometrics viscoelasticity tester ARES. Viscoelasticity was measured by changing the temperature from -70 ° C to 150 ° C at a speed. Data (loss tangent value) was taken every 12 seconds (every 1 ° C.), and the loss tangent values at each temperature (20 points) in increments of 1 ° C. in the temperature range of −61 ° C. to −40 ° C. were summed.

*: Indicates that the adherend 1 did not fall off even after 60 drop tests.
In addition, the value of the loss tangent of each temperature in Example 1 is as follows.
−60.2 ° C .: 0.30, −59.0 ° C .: 0.33, −57.8 ° C .: 0.33, −56.8 ° C .: 0.38, −55.7 ° C .: 0.45, -54.7 ° C: 0.53, -53.7 ° C: 0.61, -52.7 ° C: 0.69, -51.7 ° C: 0.76, -50.7 ° C: 0.85, -49.7 ° C: 0.92, -48.7 ° C: 1.00, -47.7 ° C: 1.07, -46.7 ° C: 1.15, -45.7 ° C: 1.23, -44.7 ° C: 1.29, -43.7 ° C: 1.35, -42.8 ° C: 1.41, -41.7 ° C: 1.46, -40.7 ° C: 1.50

From Table 1, it can be seen that the double-sided PSA sheets of Examples 1 to 3 using a carboxyl group-containing monomer having a Tg of 70 ° C. or less as the homopolymer are excellent in impact resistance and adhesive strength.
On the other hand, the double-sided pressure-sensitive adhesive sheets of Comparative Examples 1 and 2 using a carboxyl group-containing monomer having a Tg of more than 70 ° C. as the homopolymer are inferior in impact resistance. Was also inferior.

  The pressure-sensitive adhesive composition of the present invention is useful as a pressure-sensitive adhesive composition for bonding in various fields, particularly for forming a pressure-sensitive adhesive layer of a double-sided pressure-sensitive adhesive tape. Further, the double-sided pressure-sensitive adhesive tape of the present invention having a pressure-sensitive adhesive layer made of the pressure-sensitive adhesive composition is excellent in adhesiveness and impact resistance, and is used for fixing parts and the like in various fields, particularly on a painted surface (especially, water repellency). Useful for fixing parts to oil-repellent painted surfaces). Furthermore, the adhesion method of the present invention using the double-sided pressure-sensitive adhesive tape is useful for adhesion between various painted surfaces and parts, in particular, adhesion between a painted surface on which a coating made of a silicone resin is formed and the parts. .

Claims (3)

In a double-sided pressure-sensitive adhesive tape in which a pressure-sensitive adhesive layer made of a pressure-sensitive adhesive composition is formed on both sides of a base material for bonding the painted surface on which a silicone hard coating is formed and the part, A pressure-sensitive adhesive composition used,
a) As a main component monomer, a (meth) acrylic acid alkyl ester having 4 to 12 carbon atoms of an alkyl group;
b) 5 to 50% by weight of monomers with respect to 100% by weight of the total monomers, having a carboxyl group in the molecule and having a glass transition temperature of 70 ° C. or less as a homopolymer thereof,
A polymer consisting of , and
The polymer contains 0.001 to 20 parts by weight of a crosslinking agent with respect to 100 parts by weight of the polymer , and the viscoelasticity measurement is performed at a temperature rising rate of 5 ° C./min while giving a shear strain of a frequency of 1 Hz. The temperature was changed from −70 ° C. to 150 ° C. During this time, data (loss tangent value) was taken every 12 seconds (every 1 ° C.), and 1 ± 0.2 ° C. in the temperature range of −61 ° C. to −40 ° C. The pressure-sensitive adhesive composition is characterized in that the total of the loss tangent values at 20 points of each step is 10 to 40. A double-sided pressure-sensitive adhesive tape in which a pressure-sensitive adhesive layer made of a pressure-sensitive adhesive composition is formed on both surfaces of a substrate for bonding a painted surface on which a silicone hard coating is formed and a component
A double-sided pressure-sensitive adhesive tape, characterized in that a pressure-sensitive adhesive layer for adhering a painted surface comprises the pressure-sensitive adhesive composition according to claim 1. A silicone hard coating coated surface and the component formed by a method of adhering using double-sided adhesive tape, using double-sided adhesive tape according to claim 2, wherein the double-sided adhesive tape, according to claim 1 The pressure-sensitive adhesive composition according An adhesive method comprising adhering a painted surface to the pressure-sensitive adhesive layer side, and bonding a component to the other pressure-sensitive adhesive layer side.