JP5268127B2 - Manufacturing method of magnesium sheet for stretch - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a magnesium thin sheet for flattening having excellent formability, and to provide a method for producing the same. <P>SOLUTION: A magnesium alloy having a composition comprising, by weight, 3.5 to 8.0% aluminum (Al), 0.1 to 0.5% manganese (Mn) and &le;0.5% calcium (Ca), and the balance magnesium (Mg) with inevitable impurities is subjected to rolling treatment at a rolling ratio in the range of &gt;35% and also in the temperature range of &le;300&deg;C, and the magnesium alloy is formed, so as to be the shape of a thin sheet with a sheet thickness of &le;3 mm and a crystal grain size of &le;10 &mu;m. <P>COPYRIGHT: (C)2008,JPO&amp;INPIT

Description

The present invention relates to a manufacturing method of excellent exhibition Shenyang magnesium thin plate formability.

  This type of magnifying magnesium sheet is generally formed by forming a magnesium alloy into a thick sheet with a thickness of several to several tens of millimeters by casting slab or extrusion, and then forming it into a thin sheet by repeated heat treatment or rolling. (For example, JP-A-2005-281848, JP-A-6-52788, etc.).

  By the way, magnesium (Mg) has a smaller specific gravity than aluminum (Al) (the lightest among the structural metal materials), is easy to reduce in weight, has a high specific rigidity, is rich in natural resources, and is easy to recycle. Since it has such advantages as richness, it is strongly desired to develop a thin magnesium sheet for extending excellent in formability (rollability) based on magnesium.

  However, this type of wrought magnesium alloy produced by repeated heat treatment and rolling treatment as described above has a drawback of poor formability in the temperature range from room temperature to warm, and thus has been widely put into practical use. Therefore, there is a need for further practical improvement of this type of magnesium sheet for extension.

JP 2005-281848 A JP-A-6-52788

The present invention achieves the above-mentioned demands, and is intended to improve the tensile properties in the room temperature region, improve the elongation at break and reduce the plastic anisotropy particularly in the high temperature region (warm) region, and achieve high strength and high strength. in the ductility and to provide a manufacturing method of moldability and practicality excellent breakthrough wrought magnesium thin plate.

  The gist of the present invention will be described with reference to the accompanying drawings.

  It contains 3.5-8.0 wt% aluminum (Al), 0.1-0.5 wt% manganese (Mn), and 0.5 wt% or less calcium (Ca), with the balance being A magnesium alloy composed of magnesium (Mg) and inevitable impurities is subjected to rough rolling in a temperature range of 450 ° C. to 350 ° C., intermediate rolling is performed at a temperature range lower than this rough rolling and over 300 ° C., and lower than this intermediate rolling. In addition, finish rolling and two-stage roll straightening are performed at a temperature range of 300 ° C. or lower until the rolling rate finally reaches a range exceeding 35%, and the magnesium alloy has a uniform thickness of 3 mm or less and a crystal grain size of 10 μm or less. The present invention relates to a method for producing a magnesium thin plate for stretching, which is formed into a thin plate shape composed of fine particles.

  As described above, 3.5 to 8.0 wt% aluminum (Al), 0.1 to 0.5 wt% manganese (Mn), and 0.5 wt% or less calcium (Ca) And the remainder of the magnesium alloy consisting of magnesium (Mg) and inevitable impurities is subjected to a rolling treatment at a rolling rate exceeding 35% and a temperature range of 300 ° C. or less, and the magnesium alloy has a thickness of 3 mm. In the following, the expanded magnesium thin plate formed into a thin plate having a crystal grain size of 10 μm or less is excellent in tensile properties in the room temperature (25 ° C.) region, and particularly in the high temperature region (150 ° C. to 250 ° C. In the temperature range), this type of magnesium sheet for extension has an extremely high elongation at break compared to a general sheet made of AZ31 alloy, and has low plastic anisotropy and excellent isotropic deformation. Also with To become.

  Further, by containing calcium, the combustion start temperature can be increased, and for example, when the magnesium alloy of the present invention is heated, the magnesium alloy can be prevented from igniting. That is, at the initial stage of rolling, for example, when performing casting slab or extrusion, it is necessary to heat the magnesium alloy, but the magnesium alloy is prevented from igniting during this heating, and the above rolling is performed more safely and reliably. Processing can be performed, and a magnesium thin plate for extension having excellent characteristics as described above can be manufactured and realized more easily and satisfactorily.

Therefore, the present invention is a revolutionary material that is lightweight, has a high specific rigidity, is inexpensive, has high strength, high ductility, and high rolling properties, and is extremely suitable as a wrought material used in rolling processes such as pressing. a method for producing superior practicality exhibition Shenyang magnesium thin plate.

  Embodiments of the present invention that are considered suitable (how to carry out the invention) will be briefly described with reference to the drawings, illustrating the operation of the present invention.

  The magnifying magnesium sheet according to the present invention comprises 3.5 to 8.0% by weight of aluminum (Al), 0.1 to 0.5% by weight of manganese (Mn), and 0.5% by weight or less. A magnesium alloy containing calcium (Ca) and the balance being magnesium (Mg) and inevitable impurities is subjected to a rolling treatment in a temperature range of over 35% and a temperature range of 300 ° C. or less to form.

  Specifically, for example, the temperature is lowered stepwise from a temperature range exceeding 300 ° C. to a temperature range of 300 ° C. or less until a rolling rate finally exceeds 35%. Do. That is, rolling is repeated while gradually lowering the temperature from a temperature range exceeding 300 ° C., and finally the rolling treatment is performed in a temperature range where the rolling rate exceeds 35% and not more than 300 ° C.

  In this way, the magnesium alloy is formed into a thin plate shape having a plate thickness of 3 mm or less and a crystal grain size of 10 μm or less to obtain a magnesium plate for stretching.

  The expanded magnesium thin plate obtained as described above can not only achieve properties such as strength and elongation by containing aluminum (Al) and manganese (Mn) which improve properties such as strength and elongation, For example, the effect of dynamic recrystallization that occurs during the rolling treatment by performing repeated rolling treatment (so-called cold rolling) while gradually lowering the temperature stepwise from a temperature range exceeding 300 ° C. to a temperature range of 300 ° C. or less. The crystal grains are uniformized and refined as shown in FIG. 1, and the uniform fine grains as shown in FIG. 1 are promoted. This promotes the intergranular slip, further enhances the elongation at break, and the plate thickness deformation due to the contribution of the intergranular slip. A decrease in plastic anisotropy (improvement of isotropic deformation) occurs due to an increase in the amount.

  As a result, it is possible to improve tensile properties at room temperature, improve elongation at break and reduce plastic anisotropy, especially at high temperatures (warm), and achieve high formability (rolling workability) with high strength and high ductility. An excellent wrought magnesium thin plate is obtained.

  Further, by containing calcium, the combustion start temperature can be increased, and for example, when the magnesium alloy of the present invention is heated, ignition of the magnesium alloy can be prevented. That is, in the initial stage of rolling, for example, when a casting slab or extrusion is performed, the magnesium alloy needs to be heated. However, the magnesium alloy can be prevented from igniting during this heating.

  Specific embodiments of the present invention will be described with reference to the drawings.

  In this example, 3.5 to 8.0% by weight of aluminum (Al), 0.1 to 0.5% by weight of manganese (Mn), and 0.5% by weight or less of calcium (Ca). The magnesium alloy containing the remaining magnesium (Mg) and inevitable impurities is subjected to a rolling treatment at a rolling rate exceeding 35% and in a temperature range of 300 ° C. or less, and the magnesium alloy has a plate thickness of 3 mm or less, This is a magnesium thin plate for drawing formed into a thin plate shape having a crystal grain size of 10 μm or less.

  The rolling process for forming a magnesium alloy into a thin plate shape is performed by gradually decreasing the temperature from a temperature range exceeding 300 ° C. to a temperature range not exceeding 300 ° C. The rolling process (so-called temperature-falling rolling) is repeatedly performed in a plurality of times until it exceeds the range. Specifically, rough rolling is performed in a temperature range of 450 ° C. to 350 ° C., intermediate rolling is performed in a temperature range lower than the rough rolling and higher than 300 ° C., and the temperature is lower than the intermediate rolling and not higher than 300 ° C. Finish rolling is performed, and the magnesium alloy is cold-rolled until the rolling rate reaches a range exceeding 35%, and is formed into a thin plate having a plate thickness of 3 mm or less and a crystal grain size of 10 μm or less.

  In this example, by containing calcium, the combustion start temperature is increased, and the magnesium alloy does not ignite under any of the above-described temperature conditions at the time of rolling. The above rolling process can be performed.

  In this example, magnesium having a plate thickness of 45 mm, containing 6.0% by weight of aluminum, 0.15% by weight of manganese, and 0.5% by weight or less of calcium, with the balance being magnesium and inevitable impurities. The alloy is first roughly rolled at 400 ° C., then intermediate rolled at 350 ° C., then finish-rolled at 300 ° C., and further straightened (rolled) at 280 ° C. to form a thin plate of about 0.9 mm. The sheet was subjected to leveler correction and polishing, and the final plate thickness was formed to about 0.84 mm to produce a magnesium thin plate for extension (hereinafter referred to as this example sample). It is shown in 1. In addition, as a comparative sample shown in Table 1 below, a general AZ31 alloy (contained 3% aluminum and 1% zinc) which is currently used as a mainstream magnesium thin plate of this type is used. A magnesium sheet for extending (hereinafter referred to as a comparative sample) rolled by a magnesium alloy) is employed.

  As shown in Table 1, the sample of this example shows a higher numerical value than the comparative sample in the properties of tensile strength, 0.2% proof stress and breaking strain at room temperature.

  In particular, the improvement in characteristics of the breaking strain is remarkable in a high temperature range.

  Thus, not only Al or Mn which improves strength and elongation (particularly high Al), but also this high Al magnesium alloy is repeatedly rolled while gradually lowering the temperature as described above. It is rolled and formed into a thin plate by so-called cold rolling, and crystal grains are refined and homogenized by dynamic recrystallization during this rolling deformation, which is shown in FIG. 1 (enlarged photograph of this example sample). As described above, since the crystals become uniform fine particles, intergranular sliding is promoted and the elongation at break is further promoted, thereby obtaining a magnesium thin plate for extending with high strength, high ductility and excellent workability. .

  2 is an enlarged photograph of the comparative sample. Compared to the comparative sample shown in FIG. 2, it can be seen how the crystal grains of the sample of this embodiment shown in FIG. 1 are uniformly refined.

  Moreover, in FIG. 3, the test result of the plastic anisotropy of a present Example sample and a comparative sample is shown.

  The r value in the figure is (strain in the plate width direction / strain in the thickness direction).

  As can be seen from FIG. 3, the sample of this example has extremely low plastic anisotropy and has excellent isotropic deformation. As shown in FIG. 1, the excellent isotropic deformability due to such a decrease in the r value is due to the increase in the plate thickness deformation amount due to the grain boundary sliding of the uniform fine crystal grains of the sample of this example. It is guessed that.

  FIG. 4 shows the results of deep drawing tests of the sample of this example and the comparative sample in Table 1.

  The deep drawing test was performed at 200 ° C. and the punch temperature was set at 100 ° C.

  As can be seen from FIG. 4, the sample of this example has a limit drawing ratio (LDR) of 2.8, which is higher than that of the comparative sample. As described above, this is presumably due to the enhancement of break elongation due to the uniform refinement of the crystal grains of the sample of the present example by temperature reduction rolling, in addition to the improvement in break elongation due to the inclusion of Al and Mn.

  As described above, according to the present embodiment, light weight, high specific rigidity, low cost, high Al and repeated rolling treatment (temperature reduction rolling) improve the tensile properties in the room temperature range, and particularly the high temperature (warm) range. Can improve the elongation at break and reduce the plastic anisotropy, and has high strength and high ductility, excellent formability (rolling workability), and is revolutionary and practical as a material for this kind of rolling work. A magnesium sheet for stretching is obtained.

  Note that the present invention is not limited to this embodiment, and the specific configuration of each component can be designed as appropriate.

It is a description enlarged photograph of the magnesium thin plate for extension which concerns on a present Example. It is an explanatory enlarged photograph of the comparative sample of a present Example. It is a figure which shows the test result of the plastic anisotropy of the magnesium sheet for extending | stretching which concerns on a present Example, and a comparative sample. It is a figure which shows the deep drawing test result of the magnesium sheet for extending | stretching which concerns on a present Example, and a comparative sample.

Claims (1)

  It contains 3.5-8.0 wt% aluminum (Al), 0.1-0.5 wt% manganese (Mn), and 0.5 wt% or less calcium (Ca), with the balance being A magnesium alloy composed of magnesium (Mg) and inevitable impurities is subjected to rough rolling in a temperature range of 450 ° C. to 350 ° C., intermediate rolling is performed at a temperature range lower than this rough rolling and over 300 ° C., and lower than this intermediate rolling. In addition, finish rolling and two-stage roll straightening are performed at a temperature range of 300 ° C. or lower until the rolling rate finally reaches a range exceeding 35%, and the magnesium alloy has a uniform thickness of 3 mm or less and a crystal grain size of 10 μm or less. A method for producing a magnesium thin plate for stretching, comprising forming into a thin plate made of fine particles.