JP5245440B2 - Manufacturing method of membrane-electrode assembly for fuel cell - Google Patents

Description

  The present invention relates to a method for producing a membrane-electrode assembly for a fuel cell.

In a polymer electrolyte fuel cell, various methods are conventionally known as a method for producing a membrane-electrode assembly comprising an electrolyte membrane and electrodes formed on both surfaces of the electrolyte membrane. For example, after an electrode material is attached to the surface of the electrolyte membrane, the electrode material is fixed on the electrolyte membrane by pressurizing the electrolyte membrane while spraying high temperature steam toward the attachment surface, and the membrane-electrode assembly Has been proposed (see Patent Document 1). Thus, by supplying the high-temperature steam, the adhesion surface for fixing the electrolyte membrane and the electrode material can be easily softened.

JP2007-103122A JP 2006-203851 A JP 2005-203308 A

  However, if vapor is supplied onto the electrolyte membrane when forming the electrode on the electrolyte membrane, the electrolyte membrane swells, and when the electrolyte membrane is dried, the electrolyte membrane contracts and stress is generated at the interface between the electrolyte membrane and the electrode. As a result, the adhesion between the electrolyte membrane and the electrode may be reduced. In contrast, an electrode material is formed on a predetermined base material in advance to prepare a porous electrode that is separate from the electrolyte membrane, and then heated while the electrolyte membrane and the electrode are heated. A pressure bonding method is also known. In such a case, it is possible to suppress the inconveniences described above due to the supply of moisture to the electrolyte membrane, but the electrode formed as a porous body is crushed by heating and pressurization, and the fuel In some cases, battery performance deteriorated.

  The present invention has been made in order to solve the above-described conventional problems. When joining the electrolyte membrane and the electrode, it is possible to suppress a decrease in the adhesion between the electrolyte membrane and the electrode, and to suppress the collapse of the electrode. It aims at making both compatible.

In order to achieve the above object, the present invention provides a method for producing a membrane-electrode assembly for a fuel cell, comprising:
A first step of preparing an electrolyte membrane part including an electrolyte membrane;
A second step of forming a porous first electrode comprising a mixture of a catalyst and an electrolyte;
The first electrode and the electrolyte membrane are overlapped to form a laminate including the first electrode and the electrolyte membrane portion, and the electrolyte membrane portion and the first electrode are pressed by pressing the laminate. A third step of joining the first electrode;
With
In the third step, the multilayer body is heated so that the other surface of the multilayer body has a higher temperature than the one surface of the multilayer body on which the first electrode is disposed. The gist is to include a step of performing pressure bonding.

  According to the method of manufacturing a membrane-electrode assembly for a fuel cell of the present invention configured as described above, when the electrolyte membrane and the first electrode are joined, the laminate in which the first electrode is disposed Since the laminate is heated and bonded so that the temperature of the other surface is higher than that of the other surface, the electrode film is crushed with pressure while the electrolyte membrane and the first electrode are in close contact with each other. Can be suppressed. As described above, by bringing the electrolyte membrane and the first electrode into close contact with each other, the contact resistance between the electrolyte membrane and the first electrode can be suppressed, and by suppressing the collapse of the first electrode, Crushing of the pores included in the first electrode can be suppressed.

  In the method for producing a membrane-electrode assembly for a fuel cell according to the present invention, the third step is the first electrode disposed on the one surface side, wherein the interface in contact with the electrolyte membrane portion is the electrolyte. The laminated body is heated so as to generate a temperature gradient at a temperature lower than the glass transition point of the electrolyte in the vicinity of the surface on the side not in contact with the electrolyte membrane part. However, a step of performing pressure bonding may be included. With such a configuration, in the first electrode, the electrolyte constituting the interface in contact with the electrolyte membrane is softened, but the softening of the electrolyte constituting the portion separated from the interface is suppressed. As described above, since the electrolyte at the interface with the electrolyte membrane is softened, the adhesion between the electrolyte membrane and the electrode is enhanced, and the softening of the electrolyte at a portion away from the interface is suppressed, so that the first The strength against pressure of the electrode can be increased.

  In the method of manufacturing a fuel cell membrane-electrode assembly according to the present invention, the third step includes a step of heating the other surface of the laminate so as to generate the temperature gradient. Also good. With such a configuration, the effect of ensuring the adhesion between the electrolyte membrane and the electrode and suppressing the collapse of the electrode can be obtained by a simple method in which only one surface of the laminate is pressurized during pressurization. be able to.

  In such a method for producing a membrane-electrode assembly for a fuel cell according to the present invention, in the third step, the laminate is heated while heating the other surface of the laminate so as to generate the temperature gradient. It is good also as including the process of cooling the said one surface. With such a configuration, a desired temperature gradient can be formed with higher accuracy in the laminate.

  In the method for manufacturing a fuel cell membrane-electrode assembly according to the present invention, the second step includes a step of forming a second electrode together with the first electrode, and the third step includes the step of A step of sandwiching the electrolyte membrane between the first electrode and the second electrode to form the stacked body may be included. With such a configuration, both electrodes can be simultaneously bonded to the electrolyte membrane by pressure bonding, and the first electrode is crushed while ensuring adhesion between the first electrode and the electrolyte membrane. Can be suppressed.

  In the method for manufacturing a membrane-electrode assembly for a fuel cell of the present invention, the electrolyte membrane portion prepared in the first step forms a second electrode on the other surface side of the electrolyte membrane. Thus, the third step may include a step of forming the first electrode on the one surface side of the electrolyte membrane portion on which the second electrode is formed. With such a configuration, an effect of suppressing the collapse of the electrode can be obtained at least in the first electrode.

  Alternatively, in the method for manufacturing a membrane-electrode assembly for a fuel cell according to the present invention, the first and the second steps may further include forming the first membrane on one surface of the electrolyte membrane portion comprising the electrolyte membrane. After the electrode is formed, a fourth step of forming the second electrode on the other surface of the electrolyte membrane by a method not involving pressurization may be provided. With such a configuration, when the second electrode is formed, a method that does not involve pressurization is used, so that the first electrode formed earlier can be prevented from being crushed.

  The present invention can be realized in various forms other than those described above, and includes, for example, a membrane-electrode assembly manufactured by the method for manufacturing a membrane-electrode assembly of the present invention, and such a membrane-electrode assembly. It can be realized in the form of a fuel cell or the like.

A. Fuel cell configuration:
FIG. 1 is a schematic cross-sectional view showing a schematic configuration of a single cell 10 constituting a fuel cell as a preferred embodiment of the present invention. The unit cell 10 includes an electrolyte membrane 20, an anode 21 and a cathode 22 that are electrodes formed on each surface of the electrolyte membrane 20, and a gas diffusion layer 23 that sandwiches the electrolyte membrane 20 on which the electrode is formed from both sides, 24 and gas separators 25 and 26 disposed further outside the gas diffusion layers 23 and 24.

  The fuel cell of this example is a solid polymer type fuel cell, and the electrolyte membrane 20 is a proton conductive ion exchange membrane formed of a solid polymer material, for example, a fluororesin containing perfluorocarbon sulfonic acid. Good electrical conductivity when wet. The anode 21 and the cathode 22 include, for example, platinum or a platinum alloy as a catalyst. More specifically, the anode 21 and the cathode 22 include carbon particles carrying the catalyst and an electrolyte similar to the polymer electrolyte that constitutes the electrolyte membrane 20. The electrolyte membrane 20, the anode 21, and the cathode 22 constitute an MEA (membrane-electrode assembly) 30. The manufacturing process of the MEA 30 will be described in detail later.

  The gas diffusion layers 23 and 24 can be formed of a conductive member having gas permeability, such as carbon paper or carbon cloth, metal mesh, or foam metal. The gas diffusion layers 23 and 24 of the present embodiment are both formed as flat plate members. Such a gas diffusion layer 24 serves as a flow path for a gas used for an electrochemical reaction and collects current.

  The gas separators 25 and 26 are formed of a gas impermeable conductive member, for example, a member made of compressed carbon or stainless steel. Each of the gas separators 25 and 26 has a predetermined uneven shape. Due to this uneven shape, an in-cell fuel gas channel 47 through which a fuel gas containing hydrogen flows is formed between the gas separator 25 and the gas diffusion layer 23. In addition, due to the uneven shape, an in-single cell oxidizing gas channel 48 through which an oxidizing gas containing oxygen flows is formed between the gas separator 26 and the gas diffusion layer 24.

  Further, a sealing member such as a gasket is disposed on the outer peripheral portion of the single cell 10 in order to ensure gas sealing performance in the single-cell fuel gas flow channel 47 and the single-cell oxidizing gas flow channel 48 (FIG. Not shown). In addition, the fuel cell of this embodiment has a stack structure in which a plurality of single cells 10 are stacked. The outer periphery of the stack structure is parallel to the stacking direction of the single cells 10 and is fuel gas or oxidation. A plurality of gas manifolds through which gas flows are provided (not shown). The fuel gas flowing through the fuel gas supply manifold among the plurality of gas manifolds is distributed to each single cell 10 and passes through each single cell fuel gas flow channel 47 while being subjected to an electrochemical reaction. Collect in the gas exhaust manifold. Similarly, the oxidizing gas flowing through the oxidizing gas supply manifold is distributed to each single cell 10 and passes through each single cell oxidizing gas flow path 48 while being subjected to an electrochemical reaction, and then gathers in the oxidizing gas discharge manifold. To do.

B. Manufacturing method of MEA30:
FIG. 2 is a process diagram showing a method for manufacturing the MEA 30. FIG. 3 is an explanatory view schematically showing a state in the process of manufacturing the MEA 30. When manufacturing the MEA 30, first, a membrane made of a solid polymer electrolyte to be the electrolyte membrane 20 is prepared (step S100, FIG. 3A). In this embodiment, as described above, a fluorine-based solid polymer film is used.

  Next, a catalyst paste for forming the anode 21 and the cathode 22 as electrodes is prepared (step S110). The catalyst paste contains carbon particles carrying platinum and a fluorine-based polymer electrolyte similar to the electrolyte membrane 20. For example, carbon particles comprising platinum are dispersed in a platinum compound solution (for example, a tetraammine platinum salt solution, a dinitrodiammine platinum solution, a platinum nitrate solution, or a chloroplatinic acid solution). It is produced by an impregnation method, a coprecipitation method or an ion exchange method. The thus-prepared platinum-supported carbon particles are dispersed in an appropriate solvent composed of water and an organic solvent, and an electrolyte solution containing the above-described fluorine-based polymer electrolyte (for example, Nafion solution, manufactured by Aldrich). Is further mixed to obtain a catalyst paste.

  Next, the catalyst paste is applied to a predetermined substrate, and an electrode (catalyst layer) to be the anode 21 or the cathode 22 is formed on the substrate (step S120, FIG. 3B). As a base material on which the catalyst paste is applied, heat resistance at the temperature at the time of heating press to be described later may be used as long as peelability from the electrode is good. For example, polyethylene terephthalate (PET) or polytetrafluoroethylene A substrate made of (PTFE) can be used. The application of the catalyst paste onto the substrate can be performed by, for example, a spray method, screen printing, a doctor blade method, or an ink jet method. By using these methods, the catalyst paste can be applied to a desired thickness. After applying the catalyst paste as described above, the applied catalyst paste is dried to evaporate the solvent, thereby forming a porous electrode having fine pores therein.

  Thereafter, the electrode formed on the substrate in step S120 and the electrolyte membrane 20 prepared in step S100 are overlaid to form a laminate, and the laminate is heated and pressed to place the electrode on the electrolyte membrane 20. Thermal pressure transfer is performed (step S130, FIG. 3C). Then, the MEA 30 is completed by peeling and removing the substrate from the pressed laminate. FIG. 4 is an explanatory diagram showing the state of heating when pressing is performed in step S130. 3 shows a state in which the members constituting the MEA 30 are arranged in parallel in the horizontal direction, but FIG. 4 shows a state in which the members are arranged in parallel in the vertical direction and stacked. .

As shown in FIG. 4, when performing the heat press, the superimposed electrolyte membrane 20 and each electrode are disposed between a first pressure plate and a second pressure plate provided in the press machine. At this time, a catalyst layer to be the anode 21 is disposed on the first pressure platen side, and a catalyst layer to be the cathode 22 is disposed on the second pressure platen side. Here, the 1st pressurization board is provided with the heater which is not illustrated, The 1st pressurization board can be heated to arbitrary temperature. In addition, a refrigerant passage (not shown) is provided inside the second pressurizing plate so that the second pressurizing plate can be cooled to an arbitrary temperature. In this embodiment, when the MEA 30 is formed by pressing, the anode 21 side is heated while the cathode 22 side is cooled to form a temperature gradient between the anode 21 surface and the cathode 22 surface. Specifically, as shown in FIG. 4, the first pressure plate is heated to a temperature T <b> 2 that is higher than the glass transition temperature Tg of the polymer electrolyte constituting the electrolyte membrane 20. The second pressure plate circulates the refrigerant so that the temperature T1 is lower than the glass transition temperature Tg. The temperature T2 that is the reference temperature for heating in the first pressure platen or the reference temperature T1 that is the cooling temperature in the second pressure platen is such that the temperature of the interface in contact with the electrolyte membrane 20 in the catalyst layer that becomes the cathode 22. The temperature gradient is set so as to be higher than Tg. More specifically, the reference temperature T 2 and the cooling temperature T 1 of the heating, the glass transition temperature Tg of the polymer electrolyte, the thickness a of the electrolyte membrane 20, and the thickness b of the catalyst layer to be an electrode, between the The relationship of inequality shown as equation (1) below is established.

  T1 <Tg <T1 + b / (a + 2b) × (T2-T1) (1)

  For example, it is assumed that the glass transition temperature of the polymer electrolyte is 110 ° C., the thickness a of the electrolyte membrane is 20 μm, and the thickness b of the catalyst layer is 10 μm. At this time, when the pressurizing temperature T2 in the first pressurizing plate is set to 140 ° C., the above formula (1) is satisfied if the refrigerant is circulated so that the temperature of the second pressurizing plate is less than 100 ° C. The cooling in the second pressurizing plate is for removing heat transmitted from the first pressurizing plate to be heated and maintaining the second heating plate in a certain temperature range. This includes the operation of keeping the temperature of the platen at a temperature higher than the environmental temperature.

  According to the method of manufacturing the MEA 30 included in the fuel cell of the present example configured as described above, the electrolyte membrane 20 in the cathode 22 is formed by forming a temperature gradient when the electrolyte membrane 20 and the catalyst layer are joined. And the vicinity of the other surface of the cathode 22 is set to a temperature lower than the glass transition temperature. Therefore, when the electrolyte membrane 20 and the catalyst layer are joined, the polymer electrolyte constituting the interface is softened at the cathode 22, but the softening of the polymer electrolyte constituting the portion separated from the interface is suppressed. . As described above, the polymer electrolyte constituting the interface is softened, so that the adhesion between the electrolyte membrane 20 and the cathode 22 can be secured and the effect of suppressing the contact resistance at the interface can be enhanced. Further, at this time, by suppressing the softening of the polymer electrolyte constituting the portion that is separated from the interface, the strength of the catalyst layer formed as a porous body can be maintained, and the pores provided in the catalyst layer Can be prevented from being crushed during pressure bonding. In the following description, the crushing of the pores of the catalyst layer during pressure bonding is referred to as electrode crushing. In addition, according to the manufacturing method of the MEA 30 of the present embodiment, the electrode formed separately from the electrolyte membrane 20 is press-bonded, so that it is caused by moisture supplied to the electrolyte membrane when the electrolyte membrane 20 and the electrode are bonded. It is possible to suppress a decrease in adhesion between the electrolyte membrane 20 and the electrode.

  The collapse of the electrode during the pressure bonding will be further described. FIG. 5 shows two types of MEAs having different pressures when the electrolyte membrane and the catalyst layer are joined by a hot press as models of MEAs having different degrees of electrode collapse. It is explanatory drawing which shows a mode that it observed with the same magnification. FIG. 5 (A) shows a MEA with a high degree of crushing bonded at a higher pressure of 3 MPa, and FIG. 5 (B) shows a MEA with a low degree of crushing without applying pressure. Yes. Here, the temperature at the time of joining is unified to a relatively low temperature close to the glass transition point, and the degree of collapse of the electrode is varied only by the difference in pressure while suppressing deterioration of the polymer electrolyte due to heat.

FIG. 6 is an explanatory diagram showing a result of actually generating power by assembling a single cell using each MEA as a performance evaluation of the fuel cell including the two types of MEAs shown in FIG. 6A shows the result of using the MEA having a large degree of electrode collapse shown in FIG. 5A, and FIG. 6B shows the degree of electrode collapse shown in FIG. 5B. The result using MEA with small is shown. Here, for each single cell, a large excess of hydrogen gas and air is supplied to generate power at a constant current value (1.6 A / cm ² ), and the operating temperature of the fuel cell is gradually increased from 60 ° C. The results of measuring the output voltage value and the resistance value are shown.

  As shown in FIG. 6, a fuel cell having an MEA with a small degree of electrode collapse has a higher output voltage value over the entire measured temperature range than a fuel cell with an MEA with a large degree of electrode collapse. The battery performance was excellent. This is because the crushing of the electrode is small and the pores in the electrode are well maintained, so that the gas supply efficiency to the catalyst in which the electrochemical reaction proceeds increases, and the liquid water in the gas flow path It is considered that one of the factors is that the resulting pore clogging in the electrode (so-called flooding) hardly occurs. In addition, as shown in FIG. 6, in the fuel cell including the MEA with a small degree of electrode collapse, the output voltage is increased even when the operating temperature is increased as compared with the fuel cell including the MEA with a large degree of electrode collapse. The value was kept high and the battery performance during high temperature operation was excellent. During high-temperature operation, liquid water in the gas flow path and water in the polymer electrolyte are vaporized to generate more water vapor, but the electrode is less crushed and the pores in the electrode are well maintained. In such a case, it is considered that one of the factors is that the gas diffusion is prevented from being hindered by water vapor and the gas supply to the catalyst is easily maintained.

  In this example, by providing a temperature gradient at the time of joining the electrolyte membrane and the electrode, the collapse of one electrode is effectively suppressed, and the electrode on the side where the collapse is suppressed is similar to the electrode of FIG. In addition, the gas supply efficiency to the catalyst is ensured to improve battery performance. At this time, in particular, since the collapse of the cathode is suppressed, in the fuel cell, when using high-purity hydrogen gas as the fuel gas and air as the oxidizing gas, the effect of improving the cell performance is remarkably obtained. be able to. In other words, by suppressing the collapse of the cathode side of the electrode active material that is subjected to the electrochemical reaction on the cathode side, the effect of ensuring the gas supply to the catalyst and improving the battery performance is significantly obtained. be able to.

  Here, as shown in FIG. 5B, in the case of using an MEA that suppresses the collapse of both electrodes by lowering the pressure at the time of bonding, the gas supply efficiency can be increased in both electrodes. it can. However, if the pressure at the time of bonding is lowered in order to suppress the collapse of the electrode, the adhesion between the electrolyte membrane and the electrode becomes insufficient, or the reliability that maintains the above adhesion when the fuel cell generates power for a long period of time. May be insufficient. In the case of using the MEA manufactured by the manufacturing method of the present embodiment, the effect of ensuring the gas supply efficiency is high, and the reliability of the suppression of the collapse in the cathode and the maintenance of the adhesion between the electrolyte membrane and the electrode are improved. Improvement can be achieved at the same time.

  Adhesion between the electrolyte membrane and the electrode is determined by a combination of pressure and temperature during bonding. The higher the temperature and the higher the degree of softening of the polymer electrolyte, the easier it is to obtain adhesiveness even when the pressure during bonding is lowered, and the lower the temperature and the lower the degree of softening of the polymer electrolyte, the better In order to obtain adhesion, a high pressure is required at the time of joining. In this example, while suppressing the temperature increase of the entire cathode, the temperature at the interface with the electrolyte membrane in the cathode is maintained at a temperature higher than the glass transition point at which the polymer electrolyte can be softened. It is possible to secure the adhesion between the electrolyte membrane and the electrode while suppressing the pressure. In addition, by securing a temperature at which the polymer electrolyte can be softened at the interface between the electrolyte membrane and the electrode, the press time for obtaining adhesion can be shortened, which is caused by heat in the electrolyte membrane. Damage can be suppressed. In addition, since the temperature above the glass transition point of the polymer electrolyte is secured at the interface with the electrolyte membrane in the cathode, the pressure applied at the time of joining is the pressure that can sufficiently secure the adhesion between the cathode and the electrolyte membrane. Can be, for example, 1 to 5 MPa.

  Further, in the above description relating to the temperature gradient based on FIG. 4, the base material on which the catalyst layer is formed in step S120 is not considered to be sufficiently thin. However, when the heat capacity of the base material cannot be ignored due to the thickness of the base material and the constituent materials, the interface temperature with the electrolyte membrane at the cathode is higher than the glass transition point of the polymer electrolyte in consideration of the heat conduction in the base material. What is necessary is just to set heat press conditions so that the temperature gradient used as this temperature may be formed.

  Further, in the above-described equation (1), the thermal conductivity of the electrolyte membrane and the catalyst layer is assumed to be the same, and the relationship between the temperature T1, T2 of each pressure platen and the glass transition temperature Tg of the polymer electrolyte is shown. If the difference in thermal conductivity between the electrolyte membrane and the catalyst layer cannot be ignored, a more rigorous calculation may be performed. In this case, for example, the thermal conductivity is experimentally measured for each of the electrolyte membrane and the catalyst layer, and a temperature gradient is simulated based on the measured values, and the interface temperature with the electrolyte membrane at the cathode is the glass transition temperature. What is necessary is just to set heat press conditions so that the temperature gradient used as the above may be formed.

C. Variations:
The present invention is not limited to the above-described examples and embodiments, and can be implemented in various modes without departing from the gist thereof. For example, the following modifications are possible.

C1. Modification 1:
In the embodiment, both the cathode 22 and the anode 21 are joined at one time when performing the heat press in step S130, but different configurations may be adopted. That is, the heating press of the catalyst layer to be the anode 21 and the heating press of the catalyst layer to be the cathode 22 may be performed separately. In this case, for example, the catalyst layer to be the cathode 22 is heated and pressed later, and at the time of cathode bonding, the temperature of the interface with the electrolyte membrane in the cathode becomes equal to or higher than the glass transition temperature of the polymer electrolyte. A temperature gradient may be formed so that the vicinity of the other surface that is not in contact with the electrolyte membrane is less than the glass transition temperature. What is necessary is just to make the mode of the concrete temperature gradient at this time the same as that of the modification 2 mentioned later. With such a configuration, the electrode (cathode) that suppresses crushing while ensuring adhesiveness with the electrolyte membrane by forming a temperature gradient during pressing is prevented from being crushed by the subsequent pressing process. The same effect as the example can be obtained. In the case where the heat pressing is performed twice, it is desirable to form a temperature gradient similar to that in the subsequent pressing step also in the press bonding of the electrode (anode) performed earlier. If it does in this way, in the electrode used twice for the process of a press, the crushing resulting from a press can be controlled.

C2. Modification 2:
In the embodiment, both the anode and the cathode are formed on the electrolyte membrane by press bonding, but they may have different configurations. That is, one electrode is formed by press bonding while providing a temperature gradient as in the example, and the other electrode is formed by a method other than press bonding, such as a spray method, using the catalyst paste prepared in step S110. It may be formed directly on the electrolyte membrane by screen printing, a doctor blade method or an ink jet method. In such a case, it is desirable to perform electrode formation by a method other than press bonding after electrode formation by press bonding with a temperature gradient. If it does in this way, the electrode formed in the porous will not be crushed by a subsequent press process, the crushed of both electrodes can be controlled and battery performance can be improved. At this time, since one electrode is formed by transfer accompanied by pressing, generation of soot in the electrolyte membrane due to moisture in the catalyst paste is suppressed, and it is caused by water supplied to the electrolyte membrane during electrode formation. An increase in contact resistance between the electrolyte membrane and the electrode can be suppressed.

  In this way, in the case where only one of the previously formed electrodes is press-bonded while forming a temperature gradient, the laminate composed of only the electrolyte membrane 20 and one of the electrodes is subjected to the same press-bonding as in FIG. You may provide. And when performing the press joining similar to FIG. 4, what is necessary is just to arrange | position an electrode only to the 2nd pressurization board side. At this time, the set temperature T2 of the first pressurizing plate and the set temperature T1 of the second pressurizing plate are, for example, the glass transition temperature Tg of the polymer electrolyte, the thickness a of the electrolyte membrane, and the thickness b of the catalyst layer serving as the electrode. , And the following inequality relationship shown as the equation (2) may be established.

  T1 <Tg <T1 + b / (a + b) × (T2-T1) (2)

C3. Modification 3:
In the embodiment, a desired temperature gradient is formed by flowing a refrigerant in the second pressure plate while heating the first pressure plate, but a different configuration may be used. For example, when the heat capacity of the second pressure plate is sufficiently large and the press time for electrode bonding can be set sufficiently short, the second pressure plate may not be actively cooled. That is, it is possible to form a temperature gradient such that the interface temperature of the electrode with the electrolyte membrane is equal to or higher than the glass transition temperature of the polymer electrolyte, and the vicinity of the surface of the electrode not contacting the electrolyte membrane is less than the glass transition temperature. For example, the second pressure plate may be cooled only by air cooling performed between successive press operations.

  In addition, when both of the pair of pressure plates provided in the press used for press-bonding the electrodes are provided with a heating device that operates simultaneously, an electrode (the cathode 22 in the embodiment) whose temperature should be set low, You may arrange | position the heat insulation sheet which suppresses the heat conduction from a pressurization board to an electrode between the pressurization boards by the side of an electrode. Even in such a configuration, the interface temperature with the electrolyte membrane in the electrode on the side where the heat insulating sheet is arranged is set to be higher than the glass transition temperature of the polymer electrolyte, and the vicinity of the surface in contact with the heat insulating sheet is lower than the glass transition temperature. If a simple temperature gradient can be formed, the same effect as in the embodiment can be obtained. The heat insulating sheet is a member having heat resistance at the temperature at the time of press bonding and having a strength that can withstand the pressure at the time of pressing, and preferably has a low thermal conductivity. For example, silicon rubber or polytetrafluoroethylene ( A sheet made of a fluororesin such as PTFE) can be used.

C4. Modification 4:
In the examples, the polymer electrolyte constituting the electrolyte membrane and the polymer electrolyte included in the electrode used the same fluorine-based electrolyte, but different types of polymer electrolyte may be used for the electrolyte membrane and the electrode. . For example, the electrolyte membrane is made of a hydrocarbon-based polymer electrolyte, and the same fluorine-based electrolyte as in the embodiment can be used as the polymer electrolyte included in the electrode. In this case, the interface temperature of the electrode with the electrolyte membrane is higher than the glass transition temperature of the fluorine-based electrolyte, and the vicinity of the surface not in contact with the electrolyte membrane of the electrode is less than the glass transition temperature of the fluorine-based electrolyte. By forming a temperature gradient in such a manner and performing press bonding, the same effect as in the embodiment can be obtained. With such a configuration, the hydrocarbon-based polymer electrolyte has a higher glass transition temperature than the fluorine-based polymer electrolyte. Therefore, the interface temperature of the electrode with the electrolyte membrane is set to the glass transition temperature of the fluorine-based electrolyte. Even when press-bonding as described above, the temperature of the electrolyte membrane can be kept lower than the glass transition temperature of the hydrocarbon-based electrolyte that is the constituent material. Therefore, it is possible to suppress deterioration of the electrolyte membrane due to heating during pressing.

2 is a schematic cross-sectional view illustrating a schematic configuration of a single cell 10. FIG. 5 is a process diagram illustrating a method for manufacturing MEA 30. FIG. It is explanatory drawing which represents typically the mode in the middle of the process of manufacturing MEA30. It is explanatory drawing showing the mode of the heating at the time of performing a press by step S130. It is explanatory drawing which shows the mode of two types of MEA from which the degree of the collapse of an electrode differs. It is explanatory drawing which shows the result of the performance evaluation of a fuel cell provided with two types of MEA shown in FIG.

Explanation of symbols

DESCRIPTION OF SYMBOLS 10 ... Single cell 20 ... Electrolyte membrane 21 ... Anode 22 ... Cathode 23, 24 ... Gas diffusion layer 25, 26 ... Gas separator 30 ... MEA
47 ... Fuel gas flow path in single cell 48 ... Oxidation gas flow path in single cell

Claims (5)

A method for producing a membrane-electrode assembly for a fuel cell, comprising:
A first step of preparing an electrolyte membrane part including an electrolyte membrane;
A second step of forming a porous first electrode comprising a mixture of a catalyst and an electrolyte;
The first electrode and the electrolyte membrane are overlapped to form a laminate including the first electrode and the electrolyte membrane portion, and the electrolyte membrane portion and the first electrode are pressed by pressing the laminate. A third step of joining the first electrode;
With
The second step includes a step of forming a second electrode together with the first electrode,
In the third step, the electrolyte membrane is sandwiched between the first electrode and the second electrode to form the laminate, and one of the laminates in which the first electrode is disposed. A method for producing a membrane-electrode assembly for a fuel cell, comprising a step of performing pressure bonding while heating the stacked body so that the other surface of the stacked body has a higher temperature than the surface. A method for producing a membrane-electrode assembly for a fuel cell, comprising:
A first step of preparing an electrolyte membrane part including an electrolyte membrane;
A second step of forming a porous first electrode comprising a mixture of a catalyst and an electrolyte;
The first electrode and the electrolyte membrane are overlapped to form a laminate including the first electrode and the electrolyte membrane portion, and the first electrode is formed on one surface side, A third step of joining the electrolyte membrane part and the first electrode by pressurizing the laminate;
With
The electrolyte membrane portion prepared in the first step is formed by forming a second electrode on a surface side of the electrolyte membrane that is different from the surface on which the first electrode is formed in the third step. ,
The third step, as compared to the one surface of the first electrode is arranged the laminate, towards the other surface of the laminate so that the hot, heating the laminate A method for producing a membrane-electrode assembly for a fuel cell, comprising a step of performing pressure bonding while carrying out the process. A method for producing a membrane-electrode assembly for a fuel cell, comprising:
A first step of preparing an electrolyte membrane part including an electrolyte membrane;
A second step of forming a porous first electrode comprising a mixture of a catalyst and an electrolyte;
The first electrode and the electrolyte membrane are overlapped to form a laminate including the first electrode and the electrolyte membrane portion, and the electrolyte membrane portion and the first electrode are pressed by pressing the laminate. A third step of joining the first electrode;
After forming the first electrode on one surface of the electrolyte membrane portion made of the electrolyte membrane by the second and third steps, pressure is applied to the other surface of the electrolyte membrane. A fourth step of forming the second electrode by a non-method;
With
In the third step, the multilayer body is heated so that the other surface of the multilayer body has a higher temperature than the one surface of the multilayer body on which the first electrode is disposed. A method for producing a membrane-electrode assembly for a fuel cell, comprising a step of performing pressure bonding. A fuel cell membrane-electrode assembly comprising:
A membrane-electrode assembly for a fuel cell produced by the method according to any one of claims 1 to 3 . A fuel cell comprising the fuel cell membrane-electrode assembly according to claim 4 .

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