JP5242193B2 - Method for producing hydrogen reduced water - Google Patents

Description

  The present invention relates to a method for producing hydrogen-reduced water, and more particularly to a method for producing hydrogen-reduced water that can efficiently produce hydrogen-reduced water whose oxidation-reduction potential is maintained negative for a long time.

As an index for judging the redox property of water, the redox potential is known. It is known that water whose oxidation-reduction potential is negative is called reduced water and has reducibility. In general, the redox potential of tap water is +400 to +800 mV, and the redox potential of well water and commercially available mineral water is 0 to +500 mV, which are water having oxidizing properties.
On the other hand, reduced water having a negative oxidation-reduction potential has an effect of suppressing metal oxidation and food spoilage. In addition, if you take in drinking water that has a negative oxidation-reduction potential as drinking water, the active oxygen in the body, which is the cause of aging and disease, is removed, and allergic diseases such as hay fever, atopy, asthma, gastrointestinal It has been pointed out that it can also improve gastrointestinal diseases such as hypertension and health disorders such as hypertension.

  Up to now, several generation methods such as an electrolytic method and a high-frequency current application method have been proposed as a method for reducing the redox potential of water in a mixed state of an oxidant and a reductant, for example, tap water. . However, there is a problem that it is not easy to maintain a proper balance between the value of redox potential and pH. On the other hand, besides the electrolytic method and the high-frequency current application method, a method of supplying activated hydrogen gas into water has been proposed.

  For example, in order to dissolve a large amount of hydrogen gas in water and obtain highly reducible reduced water suitable for drinking that exceeds conventional reduced water, the hydrogen gas is added to the hydrogen gas under a pressure of 2 to 10 atm. Production of hydrogen water in which raw water containing minerals such as calcium is brought into contact and hydrogen gas is dissolved in the raw water, which is then filled and sealed in a highly airtight container, and subjected to heat sterilization treatment in that state. A method is disclosed (see Patent Document 1).

  In addition, for the purpose of providing hydrogenated water containing a large amount of hydrogen fine bubbles, a diffusion chamber is provided in a double tube structure in a sealed tube at both ends, and a stainless steel porous element is provided in the diffusion chamber. A method for obtaining hydrogenated water containing a large amount of fine bubbles by supplying tap water to a sealed tube, supplying hydrogen gas, mixing with raw material water, passing through a porous element and diffusing into a diffusion chamber Is disclosed (see Patent Document 2).

Japanese Patent No. 3606466 (full text) Patent No. 3984279 (full text)

However, active hydrogen, which is the basis for reducing properties, is very unstable, and when left undisturbed, it is released into the atmosphere, and the redox potential of water changes in the positive direction. There was a problem of doing. In other words, after the hydrogen water is produced, it must be immediately transferred to a highly sealed container, and when the consumer uses the hydrogen water, it should be used as little as possible after opening. There was a risk that efficiency would deteriorate.
Moreover, although the manufacturing method of the hydrogen water of patent document 1 is described so that the hydrogen water which can maintain an oxidation-reduction potential to a negative value for a comparatively long time can be manufactured, it is large-scale. This is a method for producing hydrogen water by using an apparatus having a configuration, and there is a problem that the cost burden of the production facility increases and the installation space for the production facility must be secured.

  Therefore, the inventors of the present invention have made diligent efforts to find out that such a problem can be solved by mixing water and hydrogen and passing the nozzle through a nozzle having a predetermined structure to derive a high-speed swirling flow. The invention has been completed. That is, according to the present invention, hydrogen-reduced water that can efficiently and stably generate hydrogen fine bubbles and can maintain hydrogen at a low oxidation-reduction potential by allowing hydrogen to exist for a long time can be efficiently produced. It aims at providing the manufacturing method of hydrogen reduction water which can be manufactured.

According to the present invention, hydrogen-reduced water in which a large amount of fine hydrogen bubbles are present in water is produced from water using a swirl flow formed through the first cylindrical space and the second cylindrical space. A method for producing hydrogen-reduced water that includes a housing having a first cylindrical space and a water introduction path leading to an inner peripheral surface of the first cylindrical space, and a first cylindrical space of the housing. is arranged, one end open to the second cylinder space and the peripheral wall of the second cylindrical space formed by the opening to the outside, a cylindrical member having a plurality of holes of circular or oval, provided with a, The arrangement direction of the hole is shifted by inclining a predetermined angle toward the axis of the cylindrical member, and the nozzle is provided with the hole inclined toward the opening direction of the housing. and introduced into the nozzle, together with generating the swirling flow, or the opposite end of the end , By introducing hydrogen, with mixing water and hydrogen, is a manufacturing method of the hydrogen-reduced water, characterized in that to derive a swirling flow to the outside of the nozzle.
In carrying out such a method for producing hydrogen-reduced water, it is preferable that the water introduction path of the housing is provided along the tangential direction of the inner peripheral surface of the first cylindrical space.
Similarly, the casing is configured to include a main body portion and a lid portion, and the main body portion is a cylindrical member having one end opened, and the lid portion is formed at the tip. It is preferable that the taper is tapered toward the end of the main body that is open.
Furthermore, similarly, a pump for introducing water is connected to the water introduction path of the housing, and a pre-purge tank for removing gaseous components other than hydrogen in the water is provided upstream of the pump. It is preferable.

Further, another aspect of the present invention is to use a swirling flow formed from a dissolved water obtained by dissolving hydrogen in water in advance through the first cylindrical space portion and the second cylindrical space portion, into the water. A method for producing hydrogen-reduced water in which a large amount of dissolved hydrogen is present, comprising the steps of supplying hydrogen into water to create hydrogen-mixed water, pressurizing the hydrogen-mixed water, and dissolving at least part of the hydrogen in water Forming a hydrogen-dissolved water, a housing having a water introduction path that leads the dissolved water to the first cylindrical space and the inner peripheral surface of the first cylindrical space, and a first of the housing disposed in the cylindrical space portion, one end open to the second cylinder space and the peripheral wall of the second cylindrical space formed by the opening to the outside, a cylindrical member having a plurality of holes of circular or elliptical, And inclining the direction in which the holes are arranged toward the axial center of the cylindrical member by a predetermined angle. Yes shifted by, and, introduced into the nozzle comprising tilted toward a hole in the opening direction of the housing, together to generate a swirling flow, out of the nozzle, comprise a step of deriving a swirling flow Is a method for producing hydrogen-reduced water.

  According to the method for producing hydrogen-reduced water of the present invention, hydrogen-reduced water is produced by using a nozzle capable of efficiently generating a high-speed swirling flow and generating hydrogen fine bubbles efficiently and stably. As a result, hydrogen-reduced water can be efficiently produced with simple production equipment. In addition, since the hydrogen-reduced water produced has fine hydrogen bubbles held in the water for a long time, the redox potential of the hydrogen-reduced water can be maintained negative for a relatively long time after opening to the atmosphere. .

Hereinafter, embodiments according to the method for producing hydrogen-reduced water of the present invention will be specifically described with reference to the drawings as appropriate. However, this embodiment shows one aspect of the present invention and does not limit the present invention, and can be arbitrarily changed within the scope of the present invention.
In addition, in each figure, what has attached | subjected the same code | symbol has shown the same member, and description is abbreviate | omitted suitably.

[First Embodiment]
The method for producing hydrogen-reduced water according to the first embodiment of the present invention includes a step of supplying hydrogen into water to create hydrogen-mixed water, the hydrogen-mixed water, the first cylindrical space, and the first A casing provided with a water introduction path leading to the inner peripheral surface of the cylindrical space section, a second cylindrical space section disposed in the first cylindrical space section of the casing and having at least one end opened to the outside, and the second A cylindrical member having a hole opening in the peripheral wall of the cylindrical space portion, and a step of introducing into a nozzle provided with the cylindrical member and deriving it as a swirling flow. This is referred to as “first manufacturing method”.
More specifically, hydrogen-reduced water in which a large amount of fine hydrogen bubbles are present in water is produced from water using a swirl flow formed through the first cylindrical space and the second cylindrical space. A method for producing hydrogen-reduced water that includes a housing having a first cylindrical space and a water introduction path that communicates with an inner peripheral surface of the first cylindrical space, and in the first cylindrical space of the housing And a cylindrical member having a plurality of circular or elliptical holes that are open to the peripheral wall of the second cylindrical space part, and a second cylindrical space part having one end open to the outside. The arrangement direction of the hole is shifted by inclining by a predetermined angle toward the axis of the cylindrical member, and the nozzle is provided with the hole inclined toward the opening direction of the housing, Water is introduced into the nozzle to generate a swirling flow, and the end opposite to one end From the introduction of hydrogen, as well as mixing water and hydrogen, it is a manufacturing method of the hydrogen-reduced water, characterized in that to derive a swirling flow to the outside of the nozzle.

1. Configuration Example of Manufacturing Apparatus (1) Basic Configuration FIG. 1 shows a configuration example of a manufacturing apparatus 100 for hydrogen reduced water for carrying out the first method for manufacturing hydrogen reduced water.
This hydrogen-reduced water production apparatus 100 includes a tank 101 that contains water, a pump 103 that sucks up and pumps the water in the tank 101, and a swirl flow generation nozzle 10 that guides the pumped water into the tank 101. These are connected by flow paths 107a to 107c. The swirl flow generation nozzle 10 is connected to a hydrogen supply unit 120 for supplying hydrogen into the swirl flow generation nozzle 10.

  A filter 111, a solenoid valve 113, and a pre-purge tank 115 are provided in the flow paths 107 a to 107 b on the upstream side of the pump 103. The filter 111 is used to collect and remove foreign matters in the water being pumped. Further, as the electromagnetic valve 113, for example, a known electromagnetic proportional control valve or on / off valve is used, and the flow rate of water pumped by the pump 103 can be adjusted by controlling the opening degree and opening / closing time thereof. Yes.

The pre-purge tank 115 is a tank for removing gaseous components in water. The upstream and downstream sides of the pre-purge tank 115 are provided with flow path switching valves 105 and 106, and both ends of a bypass flow path 108 disposed in parallel with the pre-purge tank 115 are connected to the flow path switching valves 105, 106. The flow path is switched so that the circulating water does not pass through the pre-purge tank 115. The pre-purge tank 115 is used in an initial stage of circulating water, and gas components other than hydrogen contained in the water are removed in advance. A temperature adjusting means (not shown) may be attached to the pre-purge tank 115 to increase the gas removal efficiency.
The pre-purge tank 115 is not essential in the present invention and may be omitted.

  In addition, a relief valve 89 for discharging the gas accumulated in the passage 107c to the outside is connected to the passage 107c between the pump 103 and the swirling flow generating nozzle 10. Then, the relief valve 89 is opened at an appropriate timing so that the gas accumulated in the flow path 107c is discharged. As described above, by discharging the gas accumulated in the flow path 107c, it is possible to prevent a large bubble such as an air reservoir from being derived from the swirl flow generation nozzle 10 and to stably generate fine bubbles. Can do. Moreover, the amount of the gas introduced into the swirl flow generation nozzle 10 from the flow path 107c can be reduced by bringing the mounting position of the relief valve 89 as close as possible to the swirl flow generation nozzle 10.

  However, in consideration of the sanitary aspect of the resulting hydrogen-reduced water, when the water is not circulated, the flow path 107a, the filter 111 and the electromagnetic valve 113 are omitted, and the upstream side of the pre-purge tank 115 is supplied with water. It can be configured to be connected to a passage or the like.

  The hydrogen supply unit 120 includes a hydrogen tank 123 and a flow rate adjustment valve 127 for adjusting the flow rate of hydrogen, and is connected to the end of the swirl flow generation nozzle 10 by a gas flow path 121. The hydrogen tank 123 is, for example, a hydrogen cylinder filled with compressed hydrogen. For example, a throttle valve can be used as the flow rate adjusting valve 127, and the flow rate of supplied hydrogen is adjusted by adjusting the throttle amount of the gas flow path 121. In addition to this, a means for adjusting the temperature of hydrogen may be provided to adjust the particle size and generation efficiency of the generated hydrogen fine bubbles.

This hydrogen-reduced water production apparatus 100 includes a control control unit (not shown) and controls each control element including the above-described pump 103, electromagnetic valve 113, relief valve 89, and the like. In particular, in the example of the apparatus 100 for producing hydrogen reduced water in FIG. 1, the pressure sensor 119 is provided in the flow path 107 c between the pump 103 and the swirling flow generation nozzle 10, and the detected sensor value becomes a predetermined value. Each control element is controlled by the control unit while feedback is maintained.
In addition to this, it is also possible to attach a temperature sensor at an appropriate location and control the pump and each electromagnetic valve in consideration of the detected sensor value.

(2) Swirl flow generation nozzle FIGS. 2A to 2C show configuration examples of the swirl flow generation nozzle provided in the apparatus for producing hydrogen reduced water of the present embodiment. 2A is a perspective view of the swirl flow generating nozzle 10, and FIG. 2B is a cross-sectional view of the swirl flow generation nozzle 10 cut along the axial direction of the housing 11. FIG. FIG. 4 is a cross-sectional view of the swirling flow generating nozzle 10 cut along a direction orthogonal to the axial direction of the housing 11 at a position where the hole 23 of the cylindrical member 21 is formed. Moreover, the housing | casing 11 and the cylindrical member 21 which comprise the rotational flow production | generation nozzle 10 of Fig.2 (a)-(c) are shown to Fig.3 (a)-(c) and Fig.4 (a)-(c), respectively. .

  2 (a) to 2 (c), FIGS. 3 (a) to (c), and FIGS. 4 (a) to 4 (c), the swirling flow generating nozzle 10 includes a housing 11 and a cylindrical member 21. It has. The casing 11 includes a cylindrical space portion 11a that is open at one end, and the casing 11 includes a water introduction path 11b that is open to face the cylindrical space portion 11a, and an open end. And a hydrogen inlet 165 provided at the end opposite to the part. The cylindrical member 21 is disposed in the cylindrical space portion 11a of the housing 11, and is provided with a cylindrical space portion 21a having both ends opened and a hole portion 23 opened in the peripheral wall of the cylindrical space portion 21a.

The housing 11 used in the present embodiment includes a main body 13 and a lid 12. The main body 13 is a cylindrical member having one end opened, and includes a cylindrical space portion 11a in which the cylindrical member 21 is accommodated. Moreover, the housing | casing 11 is provided with the protrusion part 14 protrudingly provided from the outer peripheral surface, and the protrusion part 14 is provided with the water introduction path 11b which faces the inner peripheral surface of the cylindrical space part 11a. The water introduction path 11b is formed such that the arrangement direction is shifted from the axial center of the cylindrical space portion 11a (see FIG. 2C).
In the example of FIGS. 2A to 2C, the water introduction path 11b is provided at a position closer to the derivation direction than the arrangement position of the hole 23 of the cylindrical member 21, but is not particularly limited. However, it can be appropriately set according to the purpose of use of the obtained hydrogen-reduced water, the use environment of the apparatus, the state of the generated fine bubbles, and the like.

  The lid portion 12 has a shape that tapers toward the tip, and is attached to an end portion where the cylindrical space portion 11a of the main body portion 13 is opened. The lid portion 12 is provided with an opening 15 smaller than the diameter of the cylindrical space portion 11a of the main body portion 13, and the cylindrical member 21 is inserted therein. Further, a concave portion 16 that matches the outer shape of the cylindrical member 21 is provided on the inner surface of the end portion of the main body portion 13 of the housing 11 where the lid portion 12 is not mounted, and the end portion of the cylindrical member 21 is inserted. It has become so. A hydrogen inlet 165 is provided at the end of the main body 13 on the side where the lid 12 is not mounted, and a gas flow path 121 leading to the hydrogen supply unit 120 is connected.

  A hydrogen introduction port 165 communicating with the gas flow path 121 is provided with a check valve 169. This check valve 169 is normally closed, and when a high-speed swirling flow is generated in the swirling flow generating nozzle 10, it is opened by the negative pressure generated in the central portion of the swirling and hydrogen is introduced. Yes. The introduced hydrogen appears as a gas phase in the central portion of the swirling flow, and becomes fine bubbles when it is led out from the swirling flow generating nozzle 10.

The cylindrical member 21 includes a cylindrical space portion 21a having both ends opened, and a plurality of holes (four in FIG. 4C) 23 opened in the peripheral wall of the cylindrical space portion 21a. In 11 cylindrical space portions 11a, they are arranged and fixed around a predetermined gap S. This gap S functions as a passage for water to be introduced.
As described above, in the swirl flow generating nozzle 10 of the present embodiment, the cylindrical member 21 is inserted into the cylindrical space portion 11a of the main body 13, and the opening 15 and the main body of the lid 12 mounted on one end side. The cylindrical member 21 is held and fixed by the recess 16 in the inside 13.

The material constituting these casings and cylindrical members is not particularly limited, and examples include metal materials such as iron alloys, aluminum alloys, and zinc alloys or non-ferrous metal materials, sintered bodies such as ceramics, plastics, Polyvinyl chloride (PVC), thermoplastic polyolefin resin (TPO), thermoplastic polyurethane resin (TPU), polypropylene (PP), acrylic-butadiene-styrene resin (ABS), polycarbonate (PC), polyethylene (PE), fluororesin Various materials such as resin materials such as wood, recycled raw materials such as wood, waste plastic and waste wood are listed.
For example, when the casing and the cylindrical member are made of a transparent resin material, it is possible to easily check the inside, and to use it while confirming the swirling flow and the generation state of the gas phase. However, in order to efficiently generate a high-speed swirling flow, it is preferable to select a material in consideration of wettability with water to be introduced and the degree of swirling flow to be generated.

Moreover, it is preferable to make the surface roughness of the inner peripheral surface of the cylindrical space part of the housing, the inner surface of the water introduction path, the outer peripheral surface of the cylindrical member, and the inner peripheral surface of the cylindrical space part uniform. By making the surface roughness of the water contact surface uniform in each of these members, it is possible to prevent a decrease in the generation efficiency of the swirling flow due to partial resistance of the water flow.
For example, the surface roughness can be easily made uniform by coating the surface of each member with a predetermined material. However, even when coating is performed, it is preferable to select a coating material in consideration of wettability with water to be introduced and the degree of swirling flow to be generated.

The housing 11 shown in FIGS. 2A to 2C and FIGS. 3A to 3C is composed of two members, a main body 13 and a lid 12, but is configured as a separate body. This is not essential, and can be configured as a single body in which the main body portion and the lid portion are integrated.
The casing 11 used in the swirl flow generation nozzle 10 shown in FIGS. 2A to 2C has a cylindrical outer shape, but is not limited thereto, and a cylindrical space portion 11a is formed inside. If possible, a box or any other shape can be selected.

  In the example of the swirl flow generation nozzle 10 shown in FIGS. 2A to 2C, the water introduction path 11 b of the casing 11 is provided so as to be shifted from the axial direction of the cylindrical space portion 11 a of the casing 11. However, the arrangement direction of the water introduction path 11b is not particularly limited. In the swirl flow generation nozzle 10 of the present embodiment, the water that has flowed into the cylindrical space portion 11a of the housing 11 via the water introduction path 11b passes through the hole portion 23 provided in the peripheral wall of the cylindrical member 21, and the cylindrical member. Since the swirl flow is generated by flowing into the cylindrical space portion 21a inside 21, the swirl flow can be generated basically regardless of the arrangement direction of the water introduction path 11b of the housing 11. it can. However, in consideration of the positional relationship with the hole of the cylindrical member, which will be described later, and the relationship with the arrangement direction, the water introduced into the cylindrical space of the housing maintains the flow direction as it is. As shown in FIG. 2C, it is more preferable to provide the water introduction path 11b along the tangential direction of the cylindrical space portion 11a so as to flow into the space portion and generate a swirling flow.

  In addition, the cylindrical member 21 provided in the swirl flow generation nozzle 10 of FIGS. 2A to 2C has an axial cross-sectional diameter smaller than the diameter of the cylindrical space portion 11 a of the housing 11. . The size of the gap S formed between the inner peripheral surface of the cylindrical space portion 11a of the housing 11 and the outer peripheral surface of the cylindrical member 21 can be set according to the degree of the swirl flow to be generated. .

  Moreover, as shown to Fig.5 (a)-(b), it can also comprise by making the diameter of the both ends of the cylindrical member 21 differ. By comprising in this way, the internal diameter of the cylindrical space part 21a can be varied, and the expression state of the gas phase in the center of the swirling flow produced inside can be adjusted. As a result, the degree of swirling flow to be generated and the state of the generated fine bubbles can be adjusted.

Moreover, the cylindrical member 21 shown in FIGS. 2A to 2C and FIGS. 4A to 4C includes a plurality of holes 23.
By providing a plurality of holes as described above, water introduced from the water introduction path of the housing flows into the cylindrical member from a plurality of locations, and therefore a predetermined flow is formed by continuously flowing water for a predetermined time. Thus, a swirl flow can be generated.

  Further, as shown in FIGS. 2A to 2C, the holes 23 are provided such that the arrangement direction is shifted from the axial direction to a predetermined direction. By providing the hole 23 in this manner, it is possible to efficiently generate a swirling flow using the momentum when water flows into the cylindrical member 21. In addition, when a plurality of hole portions 23 are provided, all the hole portions 23 are displaced from the axial direction and inclined at a predetermined angle, thereby avoiding the collision of water flows and increasing the flow momentum. It is possible to flow into the cylindrical space 21a of the cylindrical member 21 without weakening. As a result, a high-speed swirling flow can be generated efficiently.

  Moreover, it is preferable to arrange | position the hole part 23 inclining toward the derivation | leading-out direction of water. By arranging in this way, the water flowing into the cylindrical member 21 can be made to advance in the direction of derivation while swirling, and the generation of swirling flow can be reduced by colliding with the flow of water. Can do.

The size of the hole 23 formed in the cylindrical member 21 is not particularly limited, and can be appropriately set in consideration of the flow rate of water to be introduced and the state of the swirling flow to be generated. That is, the generation efficiency of the swirling flow of water changes depending on the ratio of the area of the hole 23 to the opening area of the end portion of the cylindrical space 21a (the total area when there are a plurality of holes). It also changes depending on the flow rate. Further, the optimum swirl state for efficiently and stably generating fine bubbles varies depending on the flow rate of hydrogen mixed in water. Therefore, from these viewpoints, it is preferable to set the size of the hole 23 and the size of the end opening. Further, the shape of the hole can be appropriately selected from a circle, an ellipse, a square, a rectangle, a triangle, and other irregular shapes, but is characterized by a circle or an ellipse.

  Further, as shown in FIG. 6, the length L of the gas phase generation region can be increased by disposing the hole portion 23 along the axial direction of the cylindrical space portion 11 a so as to be shifted to the water outlet direction side. it can. As the length of the gas phase generation region L increases, for example, the time for applying electrostatic friction to the generated fine bubbles can be increased. That is, the time for applying electrostatic friction can be adjusted so as to be optimized for the purification action using hydrogen-reduced water.

2. 1st manufacturing method of hydrogen reduction water Hereinafter, an example of the 1st manufacturing method of hydrogen reduction water using the manufacturing apparatus 100 of hydrogen reduction water shown in FIG. 1 is demonstrated about FIG.1 and FIG.2 (a)-(c). Will be described with reference to FIG.
First, the pump 103 is operated in a state where water flows through the pre-purge tank 115 by the flow path switching valves 105 and 106 provided upstream and downstream of the pre-purge tank 115. The water stored in the tank 101 is sucked up by a pump and pumped to the swirl flow generation nozzle 10 side. At this time, if foreign matter is mixed in the water sucked from the tank 101, it is collected by the filter 111. Further, gas components contained in the water are gradually removed in the pre-purge tank 115. At this time, the flow rate of the water sucked up and pumped is adjusted by the output of the pump 103 and the throttle valve 113 on the downstream side of the filter 111.

  After a predetermined time has elapsed since the operation of the pump 103, the flow path switching valves 105 and 106 provided upstream and downstream of the pre-purge tank 115 are switched so that water flows through the bypass passage 108, and the flow rate of the hydrogen supply unit 120 The control valve 127 is opened, and a predetermined flow rate of hydrogen is supplied to the swirl flow generation nozzle 10 side. The supply of hydrogen may be performed from the start of the operation of the pump 103, but immediately after the operation of the pump 103 starts, since the circulating water passes through the pre-purge tank 115, the hydrogen supplied to the water is degassed and not supplied. In view of efficiency, it is preferable to start supplying hydrogen after a predetermined time has elapsed.

The water pumped by the pump 103 and introduced into the swirl flow generation nozzle 10 passes through the hole 23 and is discharged from the swirl flow generation nozzle 10 as a high-speed swirl flow. At this time, since the water is directed toward the outer periphery of the swirl by centrifugal force, a negative pressure is generated at the center of the high-speed swirl flow, and the hydrogen inlet provided at the end opposite to the end from which the water is led out The check valve 169 provided at 165 is opened, and hydrogen is sucked into the swivel center.
In this state, when water is led out from the swirl flow generation nozzle 10, the swirl is suddenly weakened, the gas phase present in the swirl center is cut into fine bubbles, and discharged into the water. It will be. At this time, in the swirl flow generation nozzle 10 of the present embodiment, the difference in swirl speed before and after being derived from the nozzle becomes remarkably large, so that hydrogen fine bubbles can be generated efficiently and stably. it can.

Thereafter, by continuing the operation of the pump 103 and continuously circulating water, the hydrogen fine bubbles present in the tank 101 gradually increase, while the redox potential of water is gradually lowered. This makes it possible to efficiently produce hydrogen-reduced water in which a large amount of hydrogen fine bubbles are present. Then, since the hydrogen fine bubbles in the hydrogen-reduced water thus obtained remain for a long time, the hydrogen bubbles are kept until sealed in the sealed container or after the sealed container is opened. The redox potential of the reduced water becomes negative for a relatively long time.
Moreover, since hydrogen reduction water is efficiently manufactured using the swirl | flow flow production | generation nozzle of the above structures, a manufacturing facility does not become large and the raise of manufacturing cost is also suppressed.

  In addition, the 1st manufacturing method of hydrogen reduction water demonstrated so far is the structure which circulates the water in a tank, and manufactures hydrogen reduction water, However, When using the swirl | flow generation nozzle mentioned above, water is circulated. Even if it is made to pass only in one direction without making it, the hydrogen reduction water which can be maintained for a relatively long time while the oxidation-reduction potential remains negative can be produced.

[Second Embodiment]
A method for producing hydrogen-reduced water according to a second embodiment of the present invention is a method for producing hydrogen-reduced water in which a large amount of dissolved hydrogen exists in water, and hydrogen is supplied into water to create hydrogen-mixed water A step of pressurizing the hydrogen-mixed water, dissolving at least a part of the hydrogen in water to create hydrogen-dissolved water, and dissolving the dissolved water into the first cylindrical space portion and the first cylindrical space portion. A housing having a water introduction path leading to the inner peripheral surface of the housing, a second cylindrical space portion disposed in the first cylindrical space portion of the housing and having at least one end opened to the outside, and the second cylindrical space portion A cylindrical member provided with a hole opening in the peripheral wall of the nozzle, and a step of introducing into a nozzle provided with the cylindrical member and deriving it as a swirling flow. It is referred to as “manufacturing method”).
More specifically, hydrogen microbubbles in water using a swirl flow formed from dissolved water obtained by previously dissolving hydrogen in water through the first cylindrical space portion and the second cylindrical space portion. A method for producing hydrogen-reduced water that produces a large amount of hydrogen-reduced water, the step of supplying hydrogen into water to create hydrogen-mixed water, pressurizing the hydrogen-mixed water, and at least partly hydrogen A step of dissolving hydrogen in water to create dissolved hydrogen water, a housing having a water introduction path that leads the dissolved water to the first cylindrical space and the inner peripheral surface of the first cylindrical space, and the housing A second cylindrical space portion having one end opened to the outside, and a plurality of circular or elliptical holes that open to the peripheral wall of the second cylindrical space portion. A cylindrical member, and the direction of arrangement of the holes is predetermined toward the axial center of the cylindrical member A step of introducing a swirl flow into the nozzle that is shifted by tilting the tilt and tilting the hole portion toward the opening direction of the housing, and generating a swirl flow outside the nozzle; A method for producing hydrogen-reduced water, comprising:

1. Example of Configuration of Manufacturing Device FIG. 7 shows an example of the configuration of a manufacturing device 200 for hydrogen-reduced water for carrying out the second method for producing hydrogen-reduced water.
In the apparatus 100 for producing hydrogen reduced water shown in FIG. 1 described in the first embodiment, the gas flow path 121 connected to the hydrogen supply unit 120 is connected to the swirl flow generation nozzle 10, and hydrogen is directly contained in the nozzle. In the configuration example of the hydrogen-reduced water production apparatus 200 used in the present embodiment, the hydrogen-dissolved water is generated in a swirl flow after hydrogen is previously dissolved in water. It is configured to be introduced into the nozzle 10.

  The basic components such as the pump 103, the pre-purge tank 115, the swirl flow generation nozzle 10, and the hydrogen supply unit 120 that constitute the hydrogen reduced water production apparatus 200 are the same as those of the hydrogen reduced water production apparatus 100 of FIG. Is used. On the other hand, in the example of the hydrogen reduction water production apparatus 200 used in the present embodiment, a gas-liquid mixing chamber 135 is provided between the pre-purge tank 115 and the pump 103, and a dissolution tank 205 is provided downstream of the pump 103. It has been.

Among these, a gas flow path 121 connected to the hydrogen supply unit 120 is connected to the gas-liquid mixing chamber 135. Therefore, hydrogen is mixed in advance with water pumped by the pump 103 toward the dissolution tank 205.
The configuration of the gas-liquid mixing chamber 135 is not particularly limited as long as hydrogen can be supplied into water. In the case where hydrogen is directly supplied into the water flowing through the flow path 107b, the gas-liquid mixing chamber 135 may be omitted.

  Further, for example, as shown in FIG. 8, the dissolution tank 205 is provided on a tapered container body 81 whose sectional area is reduced downward, and on the upper wall surface of the container body 81 whose arrangement direction is shifted from the center. The water inlet 83 provided and the water outlet 85 provided at the bottom of the container body 81 can be used. The dissolution tank 205 uses a so-called cyclone system, and the hydrogen mixed water moving in the dissolution tank 205 is swirled, so that the dissolution efficiency of the mixed hydrogen can be remarkably increased. .

In addition, a bent portion 86 that bends in a right angle direction is provided at the water outlet 85 from the dissolution tank 205. Since the hydrogen-mixed water collides with the inner surface of the flow path at the bent portion 86, the hydrogen dissolution efficiency is improved. In order to improve the dissolution efficiency in this way, a collision plate of water is provided by providing a collision plate on a part of the wall surface in the dissolution tank 205 or by providing an area in which the horizontal sectional shape of the container body is rectangular. Can also be formed.
In addition, you may make it flow in the flow direction of water, turning from the lower part to the upper part.

  Further, an undissolved hydrogen retention portion 87 is formed at the center of the upper portion of the dissolution tank 205, and a relief valve for discharging undissolved hydrogen out of the dissolution tank 205 in the retention portion 87. 89 is connected. The dissolution tank 205 is provided with a level sensor 91 for monitoring the water level in the tank, and is used to discharge hydrogen from the relief valve 89 when the upper surface position is below a predetermined level. . In this way, by discharging undissolved hydrogen, it is possible to prevent a large bubble such as an air pool from being derived from the swirl flow generation nozzle 10 and to stably remove fine bubbles with a suppressed variation in diameter. Can be generated.

Further, as shown in FIG. 7, the gas discharge passage 208 connected to the relief valve 89 is connected to the upstream side of the pump 103 so that the discharged hydrogen is again supplied into the water. In this way, the undissolved hydrogen is circulated inside without being released to the outside, so that even when water is collected in the state of being collected from the dissolution tank 205, water leaks outside the apparatus. The risk of this is reduced.
In addition to this, water leakage outside the apparatus can also be prevented by connecting the gas discharge passage 208 to the tank 101 or the pre-purge tank 115.

  Further, when the water level in the dissolution tank 205 decreases and undissolved hydrogen is recovered and returned to the water again, the electromagnetic valve 127 of the hydrogen supply unit 120 is closed at the same time, and the amount of gas supplied to the water is reduced. It has come to be restricted. Therefore, after undissolved hydrogen appears, the amount of gas supplied into the water is adjusted so that undissolved components are not generated.

  In the configuration of the hydrogen-reduced water production apparatus 200 shown in FIG. 7, the dissolution tank 205 is also provided with a cooling device 240 so that the efficiency of hydrogen dissolution in the dissolution tank 205 is enhanced.

Further, a three-way valve 217 is provided between the flow paths 107d and 107e between the dissolution tank 205 and the swirl flow generation nozzle 10, and the flow of water is directed to the flow path 107e side to the swirl flow generation nozzle 10. Switching to the circulation flow path 209 side leading to the pre-purge tank 115 is possible. The three-way valve 217 can be, for example, an on / off valve that is controlled to open and close depending on whether or not voltage is supplied. By providing such a three-way valve 217, the liquid fluid is circulated through the circulation flow path 209 without being supplied to the swirl flow generation nozzle 10 until the gas component is dissolved to a degree close to the saturation state, and is saturated It can be controlled to supply to the swirl flow generation nozzle 10 side when the gas component is dissolved to a level close to. Therefore, fine bubbles with reduced variation in diameter can be stably generated from the initial stage of derivation from the swirl flow generation nozzle 10.
In addition, by making the attachment position of the three-way valve 217 as close as possible to the swirl flow generation nozzle 10, the amount of gas staying in the swirl flow generation nozzle at an initial stage can be reduced.

2. Second Method for Producing Hydrogen Reduced Water Hereinafter, an example of a second method for producing hydrogen reduced water using the device 200 for producing hydrogen reduced water shown in FIG. 7 will be described with reference to FIGS. Will be described with reference to FIG.
First, similarly to the first manufacturing method, the flow switching valves 105 and 106 provided upstream and downstream of the pre-purge tank 115 are set to a state in which water flows through the pre-purge tank 115 side. Next, in the three-way valve 217 between the dissolution tank 205 and the swirl flow generation nozzle 10, the swirl flow generation nozzle 10 side is closed while the circulation flow path 209 side is opened.
By operating the pump 103 in this state, the water stored in the tank 101 is pumped and supplied to the circulation channel 209 side. At this time, foreign matters in the liquid fluid sucked up from the tank 101 are collected by the filter 111 and gas components are removed in the pre-purge tank 115. Further, the flow rate of the sucked water is adjusted by the output of the pump 103 and the electromagnetic valve 113 on the downstream side of the filter 111.

  After the predetermined time has elapsed, the pre-purge tank 115, the dissolution tank 205, the flow paths 107a to 107d, and the circulation flow path 209 are filled with water, so the solenoid valve 113 on the downstream side of the filter 111 is gradually controlled. The flow rate of water sucked from the tank 101 is decreased. As a result, the water is circulated through the closed path via the circulation channel 209. Further, the water circulating in the closed path is kept at a high pressure.

  In this state, the hydrogen supply unit 120 is operated to supply hydrogen to the gas-liquid mixing chamber 135 on the upstream side of the pump 103. Then, hydrogen mixed water mixed with hydrogen is pumped by the pump 103 and introduced into the dissolution tank 205. In the dissolution tank 205, the hydrogen-mixed water is swirled so that hydrogen is efficiently dissolved in the water, while surplus hydrogen is undissolved and enters an upper retention portion (not shown) in the dissolution tank 205. Stay. As the amount of staying hydrogen increases, the water level in the dissolution tank 205 decreases. The water level is monitored by a level sensor (not shown). When the water level falls below a predetermined water level, the relief valve 89 connected to the staying part is opened, and undissolved hydrogen is introduced upstream of the pump 103. At the same time, the hydrogen supply amount by the hydrogen supply unit 120 is decreased.

  In this way, after adjusting the supply amount of hydrogen and saturating the dissolved amount of hydrogen in the water that has passed through the dissolution tank 205, the three-way valve 217 is closed on the circulation flow path 209 side, Open the swirl flow generation nozzle 10 side. At the same time, the flow path switching valves 105, 106 provided upstream and downstream of the pre-purge tank 115 allow water to flow through the bypass passage 108 side, and also open the electromagnetic valve 113 downstream of the filter 111, The pump 103 and the solenoid valve 113 are controlled so that the pressure of the valve is kept constant.

  The water in which hydrogen is dissolved and saturated flows into the swirl flow generation nozzle 10 and passes through the hole 23 of the cylindrical member 21 whose flow path cross-sectional area is reduced. A part or all of appears as fine bubbles. Thereafter, when water in which a part of hydrogen is microbubbled and another part of hydrogen is dissolved is led out from the swirl flow generation nozzle 10, the swirl is rapidly weakened and is present in the water. The hydrogen that is present is further microbubbled and released into water. At this time, with the swirling flow generating nozzle 10 of the present embodiment, the difference in swirling speed before and after being derived from the nozzle becomes remarkably large. It can be generated stably.

Thereafter, by continuing the operation of the pump 103 and continuously circulating water, the hydrogen fine bubbles present in the tank 101 gradually increase, while the redox potential of water is gradually lowered. This makes it possible to efficiently produce hydrogen-reduced water in which a large amount of hydrogen fine bubbles are present. Then, since the hydrogen fine bubbles in the hydrogen-reduced water thus obtained remain for a long time, the hydrogen bubbles are kept until sealed in the sealed container or after the sealed container is opened. The redox potential of the reduced water becomes negative for a relatively long time.
Moreover, since hydrogen reduction water is efficiently manufactured using the swirl | flow flow production | generation nozzle of the above structures, a manufacturing facility does not become large and the raise of manufacturing cost is also suppressed.

  Hereinafter, an example is given and the manufacturing method of hydrogen reduction water of the present invention is explained.

[Example 1]
A water tank storing 40 liters of tap water having a water temperature of 6 ° C. was prepared. When the redox potential of this tap water was measured, it was 667 mV. Next, hydrogen reduced water bubbles were generated in tap water using the apparatus 100 for producing hydrogen reduced water shown in FIG. 1 to produce hydrogen reduced water having a temperature of 7 ° C. and an oxidation-reduction potential of −610 mV. At this time, the pumping amount of water by the pump was 4 liters / minute, and the time required for producing the hydrogen-reduced water was 4 minutes.
The oxidation-reduction potential was measured using RM-20P manufactured by Toa DKK Corporation.

[Example 2]
Under the same conditions as in Example 1, hydrogen-reduced water having a temperature of 7 ° C. and an oxidation-reduction potential of −610 mV is generated by using hydrogen-reduced water production apparatus 200 shown in FIG. Manufactured. In Example 2, the time required for producing the hydrogen-reduced water was 3 minutes.

It is a schematic diagram for demonstrating the structural example of the manufacturing apparatus of the hydrogen reduction water used for the manufacturing method of the hydrogen reduction water concerning 1st Embodiment. (A)-(c) is a figure for demonstrating the structure of a rotational flow production | generation nozzle. (A)-(c) is a figure which shows the housing | casing which comprises a rotational flow production | generation nozzle. (A)-(c) is a figure which shows the cylindrical member which comprises a rotational flow production | generation nozzle. (A)-(b) is a figure which shows the cylindrical member which varied the diameter by the both end part side. It is a figure for demonstrating the length of the gaseous phase to generate | occur | produce. It is a schematic diagram for demonstrating the structural example of the manufacturing apparatus of the hydrogen reduction water used for the manufacturing method of the hydrogen reduction water concerning 2nd Embodiment. It is a figure which shows the structural example of a dissolution tank.

Explanation of symbols

10: swirl flow generation nozzle, 11: housing, 11a: cylindrical space part, 11b: water introduction path, 12: lid part, 13: main body part, 19: introduction port, 21: cylindrical member, 21a: cylindrical space part, 23: Hole part, 31: Housing, 31a: Cylindrical space part, 81: Container body, 83: Inlet, 85: Outlet, 86: Bending part, 87: Retention part, 89: Relief valve, 91: Level sensor , 100/200: Hydrogen reduced water production apparatus, 101: Tank (storage tank), 103: Pump, 105/106: Channel switching valve, 107a / 107b / 107c / 107d / 107e: Channel, 108: Bypass passage , 111: filter, 113: solenoid valve, 115: pre-purge tank, 119: pressure sensor, 120: hydrogen supply unit, 121: gas flow path, 123: hydrogen cylinder, 127: solenoid valve, 135: gas-liquid mixing chamber, 205 Dissolving tank, 208: a gas discharge passage, 209: circulation passage, 217: three-way valve

Claims (5)

Production of hydrogen-reduced water that produces hydrogen-reduced water in which a large amount of hydrogen fine bubbles are present in water using a swirl flow formed from water through the first cylindrical space and the second cylindrical space A method,
A housing having a water introduction passage communicating with the inner peripheral surface of the first cylindrical space and said first cylinder space,
The housing is disposed in the first cylindrical space portion of the one end opening into said second cylinder space and the peripheral wall of the second cylindrical space formed by the opening to the outside, a plurality of circular or elliptical a cylindrical member having a hole section provided with a,
A nozzle is provided in which the direction in which the hole is disposed is shifted by inclining a predetermined angle toward the axis of the cylindrical member, and the hole is inclined toward the opening direction of the housing. And
The water is introduced into the nozzle, together with generating the swirling flow,
A method for producing hydrogen-reduced water, wherein the hydrogen is introduced from an end opposite to the one end, the water and the hydrogen are mixed and led out as a swirling flow outside the nozzle .   The method for producing hydrogen-reduced water according to claim 1, wherein the water introduction path of the housing is provided along a tangential direction of an inner peripheral surface of the first cylindrical space. The housing includes a main body portion and a lid portion, the main body portion is a cylindrical member having one end opened, and the lid portion faces the tip. The method for producing hydrogen-reduced water according to claim 1 or 2, wherein the method comprises a tapered shape and is attached to an open end of the main body. A pump for introducing water is connected to the water introduction path of the casing, and a pre-purge tank for removing gaseous components other than hydrogen in the water is provided upstream of the pump. The method for producing hydrogen-reduced water according to any one of claims 1 to 3. Hydrogen in which a large amount of fine hydrogen bubbles are present in water using a swirl flow formed from dissolved water obtained by previously dissolving hydrogen in water through the first cylindrical space and the second cylindrical space. a method of manufacturing a hydrogen-reduced water producing reduced water producing method of hydrogen-reduced water, characterized in that it comprises the following steps (1) to (3).
(1) supplying hydrogen to the water, creating a hydrogen mixed water step
(2) the hydrogen mixed water pressurizing step of creating a dissolved water at least part is dissolved in the water with the hydrogen of the hydrogen
(3) the dissolution water, a housing having a water introduction passage communicating with the inner peripheral surface of the first cylindrical space and said first cylinder space to said first cylinder space of the housing disposed one end open to the second cylinder space and the peripheral wall of the second cylindrical space formed by the opening to the outside, a cylindrical member having a plurality of holes of circular or elliptical, In addition, the hole is disposed in a direction that is inclined by a predetermined angle toward the axial center of the cylindrical member, and the hole is inclined toward the opening direction of the housing. was introduced into the nozzle, together with generating the swirling flow, out of the nozzle, the step of deriving a swirling flow

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