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JP5005165B2 - Water treatment method - Google Patents

Water treatment method Download PDF

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JP5005165B2
JP5005165B2 JP2004097811A JP2004097811A JP5005165B2 JP 5005165 B2 JP5005165 B2 JP 5005165B2 JP 2004097811 A JP2004097811 A JP 2004097811A JP 2004097811 A JP2004097811 A JP 2004097811A JP 5005165 B2 JP5005165 B2 JP 5005165B2
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water
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reverse osmosis
osmosis membrane
silica
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JP2005279460A (en
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剛 米田
敦行 真鍋
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Miura Co Ltd
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Description

本発明は、原水を不純物の無い水に効率よく処理する水処理方法に関する。   The present invention relates to a water treatment method for efficiently treating raw water into water free of impurities.

半導体製造、電子部品の洗浄、医療器具の洗浄等に不純物を含まない水(純水)が多く使用されている。   Water that does not contain impurities (pure water) is often used in semiconductor manufacturing, electronic component cleaning, medical device cleaning, and the like.

従来、原水を不純物の無い水に処理する水処理方法として、一般に逆浸透膜を使用し、原水を逆浸透膜で濾過して、原水に含まれている非不動態化金属体腐食促進成分やその他の不純物を除去する方法がある。   Conventionally, as a water treatment method for treating raw water into water free of impurities, a reverse osmosis membrane is generally used, and the raw water is filtered through a reverse osmosis membrane, and a non-passivated metal body corrosion promoting component contained in the raw water or There is a method for removing other impurities.

かかる水処理に逆浸透膜を利用したのは、逆浸透膜は、溶媒は透過するが溶質は透過させないという性質があるからであり、この性質を利用して、被処理水の浸透圧より高い圧力をかけて、溶媒としての水だけを選択的に透過させ、水中の不純物を濾過することにより処理している(例えば、特許文献1参照。)。   The reason why the reverse osmosis membrane is used for such water treatment is that the reverse osmosis membrane has a property of permeating the solvent but not allowing the solute to permeate. Using this property, the osmotic pressure of the water to be treated is higher. Processing is performed by applying pressure and selectively allowing only water as a solvent to pass through and filtering impurities in the water (for example, see Patent Document 1).

この水処理にあって、原水中に溶解しているシリカ濃度が高い場合、逆浸透膜で発生する濃縮排水を含む逆浸透膜付近の被処理水のシリカ濃度が飽和濃度を超えると被処理水中にシリカスケールが析出し、これが逆浸透膜に沈着し、逆浸透膜に目詰まりが発生し、この結果処理水の回収率が低下する。原水中のシリカスケールの析出は、原水のシリカ濃度が原水のシリカ溶解度、即ち、シリカ飽和濃度を超える状態となったとき発生し易く、また、原水中のシリカ溶解度は、原水の温度と正比例の関係、即ち、温度が高くなると溶解度が高くなり、温度が低くなると溶解度が低くなるといった関係にある。   In this water treatment, when the concentration of silica dissolved in the raw water is high, if the silica concentration of the water to be treated near the reverse osmosis membrane including the concentrated drainage generated in the reverse osmosis membrane exceeds the saturation concentration, Silica scale is deposited on the reverse osmosis membrane, and the reverse osmosis membrane is clogged. As a result, the recovery rate of treated water decreases. Precipitation of silica scale in the raw water is likely to occur when the silica concentration of the raw water exceeds the silica solubility of the raw water, that is, the silica saturation concentration, and the silica solubility in the raw water is directly proportional to the temperature of the raw water. The relationship is that the solubility increases as the temperature increases, and the solubility decreases as the temperature decreases.

そこで、前記シリカ濃度が高くなった逆浸透膜付近の被処理水中に析出したシリカスケールによる逆浸透膜の目詰まりを防止する手段として、定期的に薬剤を投入し逆浸透膜を洗浄するといったことや、被処理水を逆浸透膜に送る前に加温し、シリカの溶解度を上げておく、或いは被処理水の温度を低い温度に設定し、被処理水のシリカ濃度が前記設定した水温による溶解度を超えないような運転をすることにより、被処理水中にシリカスケールが析出することを抑制するといったことにより、逆浸透膜の目詰まりを防止することが知られている。
特開平5−220480号公報
Therefore, as a means for preventing clogging of the reverse osmosis membrane due to the silica scale deposited in the water to be treated in the vicinity of the reverse osmosis membrane where the silica concentration is high, the reverse osmosis membrane is periodically washed to wash the reverse osmosis membrane. Or, heat the treated water before sending it to the reverse osmosis membrane, increase the solubility of silica, or set the temperature of the treated water to a low temperature, and the silica concentration of the treated water depends on the set water temperature It is known to prevent clogging of the reverse osmosis membrane by suppressing the precipitation of silica scale in the water to be treated by operating so as not to exceed the solubility.
Japanese Patent Laid-Open No. 5-220480

しかし、上記の水処理方法によれば、逆浸透膜の目詰まりを防止することはできるが、薬剤を投入し逆浸透膜を洗浄する手段では、この薬剤の一部が処理水に取り込まれる可能性があり、処理水の利用の障害となる場合があり、また、処理水の利用後の排水に際し、前記薬剤を除去するための特別な処理を施さない限り、そのまま下水等に排水すると、環境汚染を引き起こすおそれがある、といった問題があった。また、被処理水を逆浸透膜に送る前に加温する手段では、給水加温設備等が必要となり、コストアップとなるといった問題があった。また、被処理水の温度を低い温度に設定し、被処理水のシリカ濃度が前記設定した水温による溶解度を超えないような運転をするといった手段では、処理水の回収率が低くなり、水資源の無駄遣いとなる、といった問題があった。   However, according to the water treatment method described above, clogging of the reverse osmosis membrane can be prevented, but a part of the chemical can be taken into the treated water by the means for supplying the chemical and washing the reverse osmosis membrane. If there is no special treatment for removing the chemicals when draining after using the treated water, it will be an environmental hazard. There was a problem that could cause contamination. Further, the means for heating the water to be treated before sending it to the reverse osmosis membrane has a problem that a water supply heating facility or the like is required and the cost is increased. Further, when the temperature of the water to be treated is set to a low temperature and the operation is performed such that the silica concentration of the water to be treated does not exceed the solubility due to the set water temperature, the recovery rate of the treated water is low, There was a problem that wasted money.

そこで、本願発明者等は、試験研究を重ねた結果、シリカスケールの析出を抑制し、処理水の高い回収率を確保できる水処理方法を開発した。   Accordingly, the inventors of the present application have developed a water treatment method capable of suppressing precipitation of silica scale and ensuring a high recovery rate of treated water as a result of repeated research.

即ち、本発明の目的とするところは、被処理水を不純物の無い水に効率よく処理する水処理方法を提供することにある。   That is, an object of the present invention is to provide a water treatment method for efficiently treating water to be treated into water free of impurities.

上記目的を達成するために、請求項記載の発明に係る水処理方法は、被処理水を軟水処理した後、逆浸透膜部で濾過し、逆浸透膜部に発生する濃縮排水を所定間隔でブローする水処理方法であって、前記濃縮排水をブローする所定間隔は、予め想定した被処理水の温度と、その温度における被処理水のシリカ溶解度を基に設定した一定時間となっていることを特徴とする。 To achieve the above object, the water treatment method according to the invention of claim 1, wherein, after soft water treated water to be treated, filtered through a reverse osmosis membrane unit, predetermined intervals concentrated wastewater generated in the reverse osmosis membrane unit The predetermined interval for blowing the concentrated waste water is a predetermined time set based on the temperature of the water to be treated and the silica solubility of the water to be treated at that temperature. It is characterized by that.

このように、被処理水を軟水処理することにより、被処理水中のカルシウム等の硬度分が除去され、カルシウム等の硬度分とシリカとの結合によるスケールの析出が防止されるので、被処理水のシリカ溶解度が高くなり、その分被処理水のシリカ濃度が高い状態でもシリカスケールの析出が抑制され、被処理水の高いシリカ濃度での水処理運転が可能となる。
更に、前記軟水処理した被処理水を逆浸透膜部で濾過し、発生した濃縮排水を所定間隔でブローすることにより、逆浸透膜部による濾過でシリカ濃度が高くなった被処理水が定期的に濃縮排水の排水側に流れるので、逆浸透膜部付近における被処理水のシリカ濃度の上昇が押さえられることになり、シリカスケールの析出が抑制され、逆浸透膜部の目詰まりが防止でき、長期的に安定した水処理運転を継続して行うことができ、処理水の回収率の一層の向上を図ることができる
そして、前記濃縮排水をブローする所定間隔は、予め想定した被処理水の温度と、その温度における被処理水のシリカ溶解度を基に設定した一定時間となっているので、シリカスケールの析出の抑制に必要な間隔で濃縮排水をブローし、必要以上の濃縮排水のブローを抑制でき、シリカスケールの析出を効果的に抑制し、逆浸透膜部の目詰まりを防止できるとともに、処理水の回収率の一層の向上が図れ、供給水の節水を図ることができる。
In this way, by treating the water to be treated with soft water, hardness components such as calcium in the water to be treated are removed, and precipitation of scale due to the combination of the hardness components such as calcium and silica is prevented. The silica solubility of the water to be treated is increased, and the silica scale is prevented from being precipitated even in a state where the silica concentration of the water to be treated is high, and water treatment operation at a high silica concentration of the water to be treated becomes possible.
Furthermore, the treated water whose silica concentration has been increased by filtration through the reverse osmosis membrane part is periodically obtained by filtering the treated water subjected to the soft water treatment through the reverse osmosis membrane part and blowing the generated concentrated waste water at predetermined intervals. Since it flows to the drainage side of the concentrated drainage, an increase in the silica concentration of the water to be treated in the vicinity of the reverse osmosis membrane part will be suppressed, precipitation of silica scale is suppressed, and clogging of the reverse osmosis membrane part can be prevented, Long-term stable water treatment operation can be continued, and the recovery rate of treated water can be further improved .
The predetermined interval for blowing the concentrated wastewater is a predetermined time set based on the temperature of the treated water assumed in advance and the silica solubility of the treated water at that temperature. Concentrated wastewater can be blown at intervals necessary for the control, and blowout of more concentrated wastewater can be suppressed, silica scale precipitation can be effectively suppressed, clogging of the reverse osmosis membrane can be prevented, and the recovery rate of treated water Can be further improved and water supply can be saved.

請求項記載の発明に係る水処理方法は、被処理水を軟水処理した後、逆浸透膜部で濾過し、逆浸透膜部に発生する濃縮排水を所定間隔でブローする水処理方法であって、前記濃縮排水をブローする所定間隔は、被処理水の温度を検知し、水温が高いときは長く、低いときは短くなるように設定されていることを特徴とする。 The water treatment method according to the second aspect of the present invention is a water treatment method in which water to be treated is treated with soft water, filtered through a reverse osmosis membrane portion, and concentrated drainage generated in the reverse osmosis membrane portion is blown at predetermined intervals. The predetermined interval for blowing the concentrated drainage is set so as to detect the temperature of the water to be treated and to be long when the water temperature is high and short when the water temperature is low.

このように、被処理水を軟水処理することにより、被処理水中のカルシウム等の硬度分が除去され、カルシウム等の硬度分とシリカとの結合によるスケールの析出が防止されるので、被処理水のシリカ溶解度が高くなり、その分被処理水のシリカ濃度が高い状態でもシリカスケールの析出が抑制され、被処理水の高いシリカ濃度での水処理運転が可能となる。
更に、前記軟水処理した被処理水を逆浸透膜部で濾過し、発生した濃縮排水を所定間隔でブローすることにより、逆浸透膜部による濾過でシリカ濃度が高くなった被処理水が定期的に濃縮排水の排水側に流れるので、逆浸透膜部付近における被処理水のシリカ濃度の上昇が押さえられることになり、シリカスケールの析出が抑制され、逆浸透膜部の目詰まりが防止でき、長期的に安定した水処理運転を継続して行うことができ、処理水の回収率の一層の向上を図ることができる
そして、前記濃縮排水をブローする所定間隔は、被処理水の温度を検知し、水温が高いときは長く、低いときは短くなるように設定されているので、逆浸透膜部付近の被処理水のシリカ濃度を、この被処理水の溶解度近くとする運転が可能となり、被処理水中にシリカスケールの析出を抑制し、逆浸透膜の目詰まりを防止することができるとともに、より一層効率よく水処理を行うことができ、処理水の回収率のより一層の向上が図れ、供給水の節水を図ることができる。
In this way, by treating the water to be treated with soft water, hardness components such as calcium in the water to be treated are removed, and precipitation of scale due to the combination of the hardness components such as calcium and silica is prevented. The silica solubility of the water to be treated is increased, and the silica scale is prevented from being precipitated even in a state where the silica concentration of the water to be treated is high, and water treatment operation at a high silica concentration of the water to be treated becomes possible.
Furthermore, the treated water whose silica concentration has been increased by filtration through the reverse osmosis membrane part is periodically obtained by filtering the treated water subjected to the soft water treatment through the reverse osmosis membrane part and blowing the generated concentrated waste water at predetermined intervals. Since it flows to the drainage side of the concentrated drainage, an increase in the silica concentration of the water to be treated in the vicinity of the reverse osmosis membrane part will be suppressed, precipitation of silica scale is suppressed, and clogging of the reverse osmosis membrane part can be prevented, Long-term stable water treatment operation can be continued, and the recovery rate of treated water can be further improved .
The predetermined interval for blowing the concentrated waste water is set so that the temperature of the water to be treated is detected and is long when the water temperature is high and short when the water temperature is low. The silica concentration of the water to be treated is close to the solubility of the water to be treated, the silica scale can be prevented from being precipitated in the water to be treated, and the reverse osmosis membrane can be prevented from being clogged. The treatment can be performed, the recovery rate of the treated water can be further improved, and the water supply can be saved.

このように、被処理水を軟水処理することにより、被処理水中のカルシウム等の硬度分が除去され、カルシウム等の硬度分とシリカとの結合によるスケールの析出が防止されるので、被処理水のシリカ溶解度が高くなり、その分被処理水のシリカ濃度が高い状態でもシリカスケールの析出が抑制され、被処理水の高いシリカ濃度での水処理運転が可能となる。
更に、前記軟水処理した被処理水を逆浸透膜部で濾過し、発生した濃縮排水を所定間隔でブローすることにより、逆浸透膜部による濾過でシリカ濃度が高くなった被処理水が定期的に濃縮排水の排水側に流れるので、逆浸透膜部付近における被処理水のシリカ濃度の上昇が押さえられることになり、シリカスケールの析出が抑制され、逆浸透膜部の目詰まりが防止でき、長期的に安定した水処理運転を継続して行うことができ、処理水の回収率の一層の向上を図ることができる
そして、前記濃縮排水をブローする所定間隔は、逆浸透膜部に送られた被処理水又は濃縮排水のシリカ濃度を検出し、濃度が高いときは短く、低いときは長くなるように設定されているので、逆浸透膜部付近の被処理水のシリカ濃度を、この被処理水の溶解度近くとする運転が可能となり、被処理水中にシリカスケールの析出を抑制し、逆浸透膜の目詰まりを防止することができるとともに、より一層効率よく水処理を行うことができ、処理水の回収率のより一層の向上が図れ、供給水の節水を図ることができる。
In this way, by treating the water to be treated with soft water, hardness components such as calcium in the water to be treated are removed, and precipitation of scale due to the combination of the hardness components such as calcium and silica is prevented. The silica solubility of the water to be treated is increased, and the silica scale is prevented from being precipitated even in a state where the silica concentration of the water to be treated is high, and water treatment operation at a high silica concentration of the water to be treated becomes possible.
Furthermore, the treated water whose silica concentration has been increased by filtration through the reverse osmosis membrane part is periodically obtained by filtering the treated water subjected to the soft water treatment through the reverse osmosis membrane part and blowing the generated concentrated waste water at predetermined intervals. Since it flows to the drainage side of the concentrated drainage, an increase in the silica concentration of the water to be treated in the vicinity of the reverse osmosis membrane part will be suppressed, precipitation of silica scale is suppressed, and clogging of the reverse osmosis membrane part can be prevented, Long-term stable water treatment operation can be continued, and the recovery rate of treated water can be further improved .
The predetermined interval for blowing the concentrated drainage is set so as to detect the silica concentration of the water to be treated or the concentrated drainage sent to the reverse osmosis membrane part, and is short when the concentration is high and long when the concentration is low. Therefore, it is possible to operate the silica concentration of the water to be treated near the reverse osmosis membrane near the solubility of the water to be treated, thereby suppressing the precipitation of silica scale in the water to be treated, and clogging the reverse osmosis membrane. In addition, the water treatment can be performed more efficiently, the recovery rate of the treated water can be further improved, and the water supply can be saved.

請求項記載の発明に係る水処理方法は、請求項1又は2に記載の、前記逆浸透膜部に発生する濃縮排水をブローするときは、処理水側の弁を閉じて行うことを特徴とする。 A water treatment method according to a third aspect of the invention is characterized in that when the concentrated drainage generated in the reverse osmosis membrane part is blown according to the first or second aspect , the valve on the treated water side is closed. And

このようにすると、被処理水は全て濃縮排水の排水側に流れるので、被処理水のシリカ濃度を短時間で低くすることができるとともに、濃縮排水の排水側に流れる被処理水の流速が早くなり、その流圧により逆浸透膜部に沈着したシリカスケールは逆浸透膜部から剥離することになり、逆浸透膜部の目詰まりを早期に解消することができるものとなる。   In this way, all of the treated water flows to the drain side of the concentrated waste water, so that the silica concentration of the treated water can be lowered in a short time and the flow rate of the treated water flowing to the drain side of the concentrated waste water is high. Thus, the silica scale deposited on the reverse osmosis membrane portion by the flow pressure is peeled off from the reverse osmosis membrane portion, and the clogging of the reverse osmosis membrane portion can be eliminated at an early stage.

本発明によれば、逆浸透膜を使用し、被処理水を逆浸透膜で濾過する水処理に際し、被処理水におけるシリカスケールの析出を抑制し、逆浸透膜部の目詰まりを防止でき、長期的に安定した水処理運転を継続して行うことができ、処理水の回収率の向上を図ることができる。   According to the present invention, using a reverse osmosis membrane, in water treatment of filtering the treated water through the reverse osmosis membrane, it is possible to suppress silica scale precipitation in the treated water and prevent clogging of the reverse osmosis membrane part, A long-term stable water treatment operation can be continued, and the recovery rate of treated water can be improved.

以下、本発明に係る水処理方法を実施するための最良の形態を説明する。   Hereinafter, the best mode for carrying out the water treatment method according to the present invention will be described.

(実施の形態1)
本例の水処理方法は、被処理水を軟水処理した後、逆浸透膜部で濾過するようにした。
(Embodiment 1)
In the water treatment method of this example, water to be treated was treated with soft water and then filtered through a reverse osmosis membrane portion.

このように、被処理水を軟水処理すると被処理水中のカルシウム等の硬度分が除去される。カルシウム等の硬度分はシリカと結合してスケールの発生を促進させる要因となるものであり、被処理水の軟水処理により被処理水中のカルシウム等の硬度分が除去されることにより、カルシウム等の硬度分とシリカとの結合によるスケールの発生が防止される。この結果、被処理水のシリカ溶解度が高くなり、その分、被処理水のシリカ濃度が高い状態でもシリカスケールの析出が抑制され、被処理水の高いシリカ濃度での水処理運転が可能となり、これにより、処理水の回収率の向上を図ることができることになる。   As described above, when the water to be treated is softened, hardness such as calcium in the water to be treated is removed. The hardness component such as calcium is a factor that promotes the generation of scale by combining with silica, and by removing the hardness component such as calcium in the treated water by the soft water treatment of the treated water, Generation of scale due to bonding between the hardness and silica is prevented. As a result, the silica solubility of the water to be treated is increased, and accordingly, precipitation of silica scale is suppressed even when the silica concentration of the water to be treated is high, and water treatment operation at a high silica concentration of the water to be treated is possible. Thereby, the recovery rate of treated water can be improved.

(実施の形態2)
本例の水処理方法は、被処理水を逆浸透膜部で濾過し、逆浸透膜部に発生する濃縮排水を所定間隔でブローするようにした。
(Embodiment 2)
Water treatment method of this example, was filtered through a reverse osmosis membrane unit water to be treated, and the concentrated water discharge that occurs in the reverse osmosis membrane unit to blow at predetermined intervals.

このように、逆浸透膜部に発生する濃縮排水をブローすると、濃縮排水の排水側が負圧となり、ブローされた分被処理水が排水側に流れる結果、逆浸透膜部付近でシリカ濃度が高くなっている被処理水のシリカ濃度が低下する。かかる濃縮排水を所定間隔でブローすることにより、逆浸透膜部による濾過でシリカ濃度が高くなった被処理水が定期的に濃縮排水の排水側に流れるので、逆浸透膜部付近における被処理水のシリカ濃度の上昇を押さえ、シリカスケールの析出を抑制し、また、シリカスケールが析出していてもこれを濃縮排水の排水側に流し、また、析出したシリカスケールが逆浸透膜部に沈着していたときは、逆浸透膜部に沈着しているシリカスケールを濃縮排水の排水側に流れる流圧により剥離して排水側に流すことができる。これにより、逆浸透膜部の目詰まりを防止でき、長期的に安定した水処理運転を継続して行うことができ、処理水の回収率の向上を図ることができる。 Thus, when blown concentrated wastewater that occur in the reverse osmosis membrane unit, the drainage side of the concentrated waste water becomes negative, results the blown minute treatment water flows through the drainage side, the silica concentration in the vicinity of the reverse osmosis membrane unit The silica concentration of the to-be-processed water which becomes high falls. By blowing such concentrated waste water at predetermined intervals, the treated water whose silica concentration has been increased by filtration through the reverse osmosis membrane part periodically flows to the drain side of the concentrated waste water, so that the treated water near the reverse osmosis membrane part. Suppresses the increase in silica concentration, suppresses silica scale deposition, and even if silica scale is deposited, it flows to the drain side of the concentrated drainage, and the deposited silica scale is deposited on the reverse osmosis membrane. When it is, the silica scale deposited on the reverse osmosis membrane portion can be peeled off by the flow pressure flowing to the drainage side of the concentrated drainage and flowed to the drainage side. Thereby, clogging of the reverse osmosis membrane part can be prevented, a long-term stable water treatment operation can be continued, and the recovery rate of treated water can be improved.

前記濃縮排水をブローする所定間隔にあっては、予め想定した被処理水の温度と、その温度における被処理水のシリカ溶解度を基に、被処理水のシリカ濃度が飽和濃度になる時間を求めて、一定の時間を設定するとよい。   In the predetermined interval for blowing the concentrated waste water, the time for the silica concentration of the water to be treated to be saturated is obtained based on the temperature of the water to be preliminarily assumed and the silica solubility of the water to be treated at that temperature. And set a certain time.

このように、濃縮排水をブローする所定間隔を、予め想定した被処理水の温度と、その温度における被処理水のシリカ溶解度を基に設定することにより、シリカスケールの析出の抑制に必要な間隔で濃縮排水をブローし、必要以上の濃縮排水のブローを抑制できるので、シリカスケールの析出を効果的に抑制し、逆浸透膜部の目詰まりを防止できるとともに、処理水の回収率の一層の向上が図れ、供給水の節水を図ることができる。   In this way, by setting the predetermined interval for blowing the concentrated waste water based on the temperature of the water to be treated that is assumed in advance and the silica solubility of the water to be treated at that temperature, the interval necessary for suppressing the precipitation of silica scale. In this case, it is possible to control the concentration of wastewater and to prevent the concentration of wastewater from blowing more than necessary, effectively suppressing silica scale deposition and preventing clogging of the reverse osmosis membrane, and further improving the recovery rate of treated water. Improvements can be made and water can be saved.

或いはまた、前記濃縮排水をブローする所定間隔として、被処理水の温度を検知し、被処理水のシリカ濃度が飽和濃度になる時間を限界に、水温が高いときは長く、低いときは短くなるように設定するとよい。   Alternatively, as the predetermined interval for blowing the concentrated waste water, the temperature of the water to be treated is detected, and the time when the silica concentration of the water to be treated is saturated becomes the limit. It is good to set as follows.

このように、濃縮排水をブローする所定間隔を、被処理水の温度を検知し、水温が高いときは長く、低いときは短くなるように設定することにより、逆浸透膜部付近の被処理水のシリカ濃度を、この被処理水の溶解度近くとする運転が可能となり、被処理水中にシリカスケールの析出を抑制し、逆浸透膜の目詰まりを防止することができるとともに、より一層効率よく水処理を行うことができ、処理水の回収率のより一層の向上が図れ、供給水の節水を図ることができる。   In this way, the predetermined interval for blowing the concentrated drainage is set so that the temperature of the water to be treated is detected and is long when the water temperature is high and short when the water temperature is low. The silica concentration of the water to be treated is close to the solubility of the water to be treated, the silica scale can be prevented from being precipitated in the water to be treated, and the reverse osmosis membrane can be prevented from being clogged. The treatment can be performed, the recovery rate of the treated water can be further improved, and the water supply can be saved.

或いはまた、前記濃縮排水をブローする所定間隔として、逆浸透膜部に送られた被処理水のシリカ濃度を検出し、被処理水のシリカ濃度の飽和濃度を限界に、濃度が高いときは短く、低いときは長くなるように設定するとよい。   Alternatively, as the predetermined interval for blowing the concentrated waste water, the silica concentration of the water to be treated sent to the reverse osmosis membrane part is detected, and the saturation concentration of the silica concentration of the water to be treated is limited, and when the concentration is high, it is short. If it is low, it should be set to be long.

このように、濃縮排水をブローする所定間隔を、逆浸透膜部に送られた被処理水のシリカ濃度を検出し、濃度が高いときは短く、低いときは長くなるように設定することにより、逆浸透膜部付近の被処理水のシリカ濃度を、この被処理水の溶解度近くとする運転が可能となり、被処理水中にシリカスケールの析出を抑制し、逆浸透膜の目詰まりを防止することができるとともに、より一層効率よく水処理を行うことができ、処理水の回収率のより一層の向上が図れ、供給水の節水を図ることができる。   Thus, by detecting the silica concentration of the treated water sent to the reverse osmosis membrane part, the predetermined interval for blowing the concentrated drainage is set to be short when the concentration is high, and long when the concentration is low, It is possible to operate the silica concentration of the water to be treated near the reverse osmosis membrane near the solubility of the water to be treated, to suppress silica scale precipitation in the water to be treated, and to prevent clogging of the reverse osmosis membrane. In addition, the water treatment can be performed more efficiently, the recovery rate of the treated water can be further improved, and the water supply can be saved.

また、本例では、前記逆浸透膜部に発生する濃縮排水をブローするときに、処理水側の弁を閉じて行うこともできる。 Further, in this example, when blown concentrated wastewater that occur to the reverse osmosis membrane unit may be performed by closing the valve of the processing water side.

このようにすると、被処理水は全て濃縮排水の排水側に流れるので、被処理水のシリカ濃度を短時間で低くすることができるとともに、濃縮排水の排水側に流れる被処理水の流速が早くなり、その流圧により逆浸透膜部に沈着したシリカスケールは逆浸透膜部から剥離することになり、逆浸透膜部の目詰まりを早期に解消することができるものとなる。この方法は、シリカ濃度がシリカ溶解度を大きく超えシリカスケールが析出しやすい状態になったときや逆浸透膜部にシリカスケールが沈着し目詰まりを起こし始めたときに、効果的である。   In this way, all of the treated water flows to the drain side of the concentrated waste water, so that the silica concentration of the treated water can be lowered in a short time and the flow rate of the treated water flowing to the drain side of the concentrated waste water is high. Thus, the silica scale deposited on the reverse osmosis membrane portion by the flow pressure is peeled off from the reverse osmosis membrane portion, and the clogging of the reverse osmosis membrane portion can be eliminated at an early stage. This method is effective when the silica concentration greatly exceeds the silica solubility and the silica scale is likely to precipitate, or when the silica scale is deposited on the reverse osmosis membrane portion and clogging starts.

(実施の形態3)
本例の水処理方法は、被処理水を軟水処理した後、逆浸透膜部で濾過し、逆浸透膜部に発生する濃縮排水を所定間隔でブローするようにした。
(Embodiment 3)
Water treatment method of the present embodiment, after soft water treated water to be treated, filtered through a reverse osmosis membrane unit, and adapted to blow at predetermined intervals concentrated wastewater that occur in the reverse osmosis membrane unit.

このように、被処理水を軟水処理することにより、被処理水中のカルシウム等の硬度分が除去され、カルシウム等の硬度分とシリカとの結合によるスケールの析出が防止されるので、被処理水のシリカ溶解度が高くなり、その分被処理水のシリカ濃度が高い状態でもシリカスケールの析出が抑制され、被処理水の高いシリカ濃度での水処理運転が可能となる。   In this way, by treating the water to be treated with soft water, hardness components such as calcium in the water to be treated are removed, and precipitation of scale due to the combination of the hardness components such as calcium and silica is prevented. The silica solubility of the water to be treated is increased, and the silica scale is prevented from being precipitated even in a state where the silica concentration of the water to be treated is high, and water treatment operation at a high silica concentration of the water to be treated becomes possible.

更に、前記軟水処理した被処理水を逆浸透膜部で濾過し、発生した濃縮排水を所定間隔でブローすることにより、逆浸透膜部による濾過でシリカ濃度が高くなった被処理水が定期的に濃縮排水の排水側に流れるので、逆浸透膜部付近における被処理水のシリカ濃度の上昇を押さえ、シリカスケールの析出を抑制し、また、シリカスケールが析出していてもこれを濃縮排水の排水側に流し、また、発生したシリカスケールが逆浸透膜部に沈着していたときは、逆浸透膜部に沈着しているシリカスケールを濃縮排水の排水側に流れる流圧により剥離して排水側に流すことができ、これにより、逆浸透膜部の目詰まりを防止でき、長期的に安定した水処理運転を継続して行うことができ、処理水の回収率の一層の向上を図ることができる。   Furthermore, the treated water whose silica concentration has been increased by filtration through the reverse osmosis membrane part is periodically obtained by filtering the treated water subjected to the soft water treatment through the reverse osmosis membrane part and blowing the generated concentrated waste water at predetermined intervals. Since it flows to the drainage side of the concentrated wastewater, it suppresses the increase in the silica concentration of the water to be treated in the vicinity of the reverse osmosis membrane, suppresses silica scale precipitation, and even if silica scale is deposited, When the generated silica scale is deposited on the reverse osmosis membrane part, the silica scale deposited on the reverse osmosis membrane part is separated by the flow pressure flowing to the drain side of the concentrated waste water. This can prevent clogging of the reverse osmosis membrane part, and can continue to perform stable water treatment operation for a long period of time, thereby further improving the recovery rate of treated water. Can do.

前記濃縮排水をブローする所定間隔にあっては、前記実施の形態2と同様に、予め想定した被処理水の温度と、その温度における被処理水のシリカ溶解度を基に設定した一定時間とするとよい。   In the predetermined interval for blowing the concentrated waste water, as in the second embodiment, the temperature of the treated water assumed in advance and a fixed time set based on the silica solubility of the treated water at that temperature. Good.

このように、濃縮排水をブローする所定間隔を、予め想定した被処理水の温度と、その温度における被処理水のシリカ溶解度を基に設定することにより、シリカスケールの析出の抑制に必要な間隔で濃縮排水をブローし、必要以上の濃縮排水のブローを抑制できるので、シリカスケールの析出を効果的に抑制し、逆浸透膜部の目詰まりを防止できるとともに、処理水の回収率の一層の向上が図れ、供給水の節水を図ることができる。   In this way, by setting the predetermined interval for blowing the concentrated waste water based on the temperature of the water to be treated that is assumed in advance and the silica solubility of the water to be treated at that temperature, the interval necessary for suppressing the precipitation of silica scale. In this case, it is possible to control the concentration of wastewater and to prevent the concentration of wastewater from blowing more than necessary, effectively suppressing silica scale deposition and preventing clogging of the reverse osmosis membrane, and further improving the recovery rate of treated water. Improvements can be made and water can be saved.

或いはまた、前記濃縮排水をブローする所定間隔として、前記実施の形態2と同様に、前記濃縮排水をブローする所定間隔を、被処理水の温度を検知し、水温が高いときは長く、低いときは短くなるように設定するとよい。   Alternatively, as the predetermined interval for blowing the concentrated wastewater, as in the second embodiment, the predetermined interval for blowing the concentrated wastewater is detected when the temperature of the water to be treated is detected, and when the water temperature is high, it is long and low. Should be set to be shorter.

このように、濃縮排水をブローする所定間隔を設定することにより、逆浸透膜部付近の被処理水のシリカ濃度を、この被処理水の溶解度近くとする運転が可能となり、被処理水中にシリカスケールの析出を抑制し、逆浸透膜の目詰まりを防止することができるとともに、より一層効率よく水処理を行うことができ、処理水の回収率のより一層の向上が図れ、供給水の節水を図ることができる。   In this way, by setting a predetermined interval for blowing concentrated wastewater, it is possible to operate the silica concentration of the water to be treated near the reverse osmosis membrane near the solubility of the water to be treated. Sedimentation of scale can be suppressed, clogging of the reverse osmosis membrane can be prevented, water treatment can be performed more efficiently, and the recovery rate of treated water can be further improved, thereby saving water supply. Can be achieved.

或いはまた、前記濃縮排水をブローする所定間隔として、前記実施の形態2と同様に、前記濃縮排水をブローする所定間隔は、逆浸透膜部に送られた被処理水のシリカ濃度を検出し、濃度が高いときは短く、低いときは長くなるように設定するとよい。   Alternatively, as the predetermined interval for blowing the concentrated wastewater, as in the second embodiment, the predetermined interval for blowing the concentrated wastewater detects the silica concentration of the treated water sent to the reverse osmosis membrane part, It is better to set it to be short when the density is high and long when the density is low.

このように設定することにより、逆浸透膜部付近の被処理水のシリカ濃度を、この被処理水の溶解度近くとする運転が可能となり、被処理水中にシリカスケールの析出を抑制し、逆浸透膜の目詰まりを防止することができるとともに、より一層効率よく水処理を行うことができ、処理水の回収率のより一層の向上が図れ、供給水の節水を図ることができる。   By setting in this way, it is possible to operate the silica concentration of the water to be treated near the reverse osmosis membrane near the solubility of the water to be treated, thereby suppressing the precipitation of silica scale in the water to be treated, and reverse osmosis. Clogging of the membrane can be prevented and water treatment can be performed more efficiently, the recovery rate of treated water can be further improved, and water supply can be saved.

また、本例では、前記実施の形態2と同様に、前記逆浸透膜部に発生する濃縮排水をブローするときは、処理水側の弁を閉じて行うこともできる。 Further, in this embodiment, similarly to the second embodiment, when blown concentrated wastewater that occur to the reverse osmosis membrane unit may be performed by closing the valve of the processing water side.

このようにすると、被処理水は全て濃縮排水の排水側に流れるので、被処理水のシリカ濃度を短時間で低くすることができるとともに、濃縮排水の排水側に流れる被処理水の流速が早くなり、その流圧により逆浸透膜部に沈着したシリカスケールは逆浸透膜部から剥離することになり、逆浸透膜部の目詰まりを早期に解消することができるものとなる。この方法は、シリカ濃度がシリカ溶解度を大きく超えシリカスケールが析出しやすい状態になったときや逆浸透膜部にシリカスケールが沈着し目詰まりを起こし始めたときに、効果的である。   In this way, all of the treated water flows to the drain side of the concentrated waste water, so that the silica concentration of the treated water can be lowered in a short time and the flow rate of the treated water flowing to the drain side of the concentrated waste water is high. Thus, the silica scale deposited on the reverse osmosis membrane portion by the flow pressure is peeled off from the reverse osmosis membrane portion, and the clogging of the reverse osmosis membrane portion can be eliminated at an early stage. This method is effective when the silica concentration greatly exceeds the silica solubility and the silica scale is likely to precipitate, or when the silica scale is deposited on the reverse osmosis membrane portion and clogging starts.

次に本発明の具体的な一実施例を図面により詳細に説明する。図1は本発明の一実施例を示す水処理システムの概略説明図である。
図1に示す水処理システムは、被処理水を給水する給水ライン1に、上流側から、軟水処理部2、被処理水中のゴミ等を除去するフィルター3、被処理水中の不純物等を除去する逆浸透膜部4、逆浸透膜部4で処理された処理水中の溶存気体を透過する気体透過膜を用いて脱気する膜式脱気部5、膜式脱気部5を透過することにより得られた処理水を貯留する貯留タンク6とが、順番に配置され、更に、逆浸透膜部4の上流側には、被処理水を前記逆浸透膜部4に加圧して供給するポンプ7が配置されている。また、前記逆浸透膜部4には、不純物が濃縮された濃縮排水を排水する濃縮排水ライン8が接続されており、この濃縮排水ライン8には、排水ライン8aとブローライン8bが分岐して接続されている。更に、前記逆浸透膜部4で処理された処理水を流す処理水ライン1aに開閉弁9が配置され、また、前記排水ライン8aには排水弁10aが配置され、ブローライン8bにはブロー弁10bが配置されている。
Next, a specific embodiment of the present invention will be described in detail with reference to the drawings. FIG. 1 is a schematic explanatory view of a water treatment system showing an embodiment of the present invention.
The water treatment system shown in FIG. 1 removes impurities, etc. in the water to be treated, from the upstream side to the water supply line 1 for supplying the water to be treated, the soft water treatment unit 2, the filter 3 for removing dust and the like in the water to be treated. By permeating the reverse osmosis membrane part 4, the membrane type deaeration part 5 that deaerates using the gas permeable membrane that transmits the dissolved gas in the treated water treated by the reverse osmosis membrane part 4, and the membrane type deaeration part 5 A storage tank 6 for storing the obtained treated water is disposed in order, and further, a pump 7 that supplies the treated water to the reverse osmosis membrane unit 4 under pressure on the upstream side of the reverse osmosis membrane unit 4. Is arranged. The reverse osmosis membrane section 4 is connected to a concentrated drainage line 8 for draining concentrated drainage enriched with impurities. The drainage line 8a and the blow line 8b are branched into the concentrated drainage line 8. It is connected. Further, an on-off valve 9 is disposed in the treated water line 1a through which treated water treated by the reverse osmosis membrane section 4 flows, a drain valve 10a is disposed in the drain line 8a, and a blow valve is disposed in the blow line 8b. 10b is arranged.

前記軟水処理部2にあっては、イオン交換樹脂を用いた公知の軟水装置が使用される。また、前記逆浸透膜部4にあっては、逆浸透膜(図示せず)の、溶媒は透過するが溶質は透過させないという性質を利用して、不純物(溶解塩及びシリカ等)を含んだ被処理水の浸透圧より高い圧力をかけて、溶媒としての水だけを選択的に透過採取するものであり、前記膜式脱気部5にあっては、前記気体透過膜を多数備えた気体透過膜モジュール(図示せず)と被処理水中の溶存気体を気体透過膜モジュールを通して真空吸引する水封式真空ポンプ(図示せず)を備えている。   In the soft water treatment unit 2, a known soft water device using an ion exchange resin is used. Further, the reverse osmosis membrane portion 4 contains impurities (dissolved salt, silica, etc.) by utilizing the property that a reverse osmosis membrane (not shown) permeates the solvent but does not permeate the solute. A pressure higher than the osmotic pressure of the water to be treated is applied to selectively permeate and collect only water as a solvent. In the membrane type deaeration unit 5, a gas having a large number of the gas permeable membranes A permeable membrane module (not shown) and a water-sealed vacuum pump (not shown) for vacuuming the dissolved gas in the water to be treated through the gas permeable membrane module are provided.

更に、給水ライン1上には、逆浸透膜部4の上流側に被処理水の温度を検知する温度センサ11を備えている。また、同じく給水ライン1上、逆浸透膜部4の上流側で且つ逆浸透膜部4の付近に、当該部分を流れる被処理水中のシリカ濃度を検出する濃度測定装置12を備えている。   Furthermore, a temperature sensor 11 for detecting the temperature of the water to be treated is provided on the water supply line 1 on the upstream side of the reverse osmosis membrane portion 4. Similarly, a concentration measuring device 12 is provided on the water supply line 1 upstream of the reverse osmosis membrane portion 4 and in the vicinity of the reverse osmosis membrane portion 4 to detect the silica concentration in the water to be treated flowing through the portion.

また、前記ポンプ7に接続され該ポンプ7の回転数を出力周波数に応じて可変させるインバータ13と、前記温度センサ11、濃度測定装置12、ブロー弁10b、開閉弁9及び前記インバータ13に対するインターフェースを有し、前記温度センサ11からの温度検知信号或いは、濃度測定装置12からのシリカ濃度検出信号に基づいて前記ブローライン8bに配置されたブロー弁10bにブロー信号を出力し或いはブロー弁10bにブロー指令信号を出力するとともに逆浸透膜部4で処理された処理水を流す処理水ライン1aに配置された開閉弁9に開閉指令信号を出力し、また、前記ブロー弁10bへのブロー指令信号に基づいて前記インバータ13に指令信号を出力する制御部14を備えている。   In addition, an inverter 13 connected to the pump 7 and capable of varying the rotational speed of the pump 7 according to an output frequency, and an interface to the temperature sensor 11, the concentration measuring device 12, the blow valve 10b, the on-off valve 9, and the inverter 13 are provided. And outputs a blow signal to the blow valve 10b arranged in the blow line 8b based on a temperature detection signal from the temperature sensor 11 or a silica concentration detection signal from the concentration measuring device 12, or blows to the blow valve 10b. An opening / closing command signal is output to the opening / closing valve 9 disposed in the treated water line 1a that outputs the command signal and flows the treated water treated by the reverse osmosis membrane unit 4, and the blow command signal to the blow valve 10b Based on this, a control unit 14 is provided for outputting a command signal to the inverter 13.

前記制御部14は、被処理水の温度と、その温度における被処理水のシリカ溶解度及び特定の温度と、該特定の温度のときのシリカ溶解度と、該特定の温度で特定のシリカ濃度にあるときのシリカ析出時間と、高濃度となった被処理水のシリカ濃度を低濃度にするためのブロー時間等を記憶させた記憶部を備えている。   The controller 14 has a temperature of the water to be treated, a silica solubility and a specific temperature of the water to be treated at the temperature, a silica solubility at the specific temperature, and a specific silica concentration at the specific temperature. The storage unit stores the silica precipitation time and the blow time for reducing the silica concentration of the water to be treated having a high concentration.

そして前記温度センサ11からの信号に基づいて、被処理水のシリカ濃度が飽和濃度になる時間を限界に、水温が高いときは長く、低いときは短くなるように間隔時間を設定し、前記ブロー弁10bにブロー指令信号を設定した所定間隔で所定時間出力するプログラムと、濃度測定装置12からの信号に基づいて、被処理水のシリカ濃度の飽和濃度を限界に、濃度が高いときは短く、低いときは長くなるように間隔時間を設定し、前記ブロー弁10bにブロー指令信号を設定した所定間隔で所定時間出力するプログラムと、選択により、前記ブロー指令信号に基づいてブロー弁10bにブロー指令信号を出力している間、前記逆浸透膜部4で処理された処理水を流す給水ライン1aに配置された開閉弁9に閉指令信号を出力するプログラムを備えている。   Based on the signal from the temperature sensor 11, the interval time is set so that the silica concentration of the water to be treated reaches the saturation concentration, and is long when the water temperature is high and short when the water temperature is low. Based on the program that outputs the blow command signal to the valve 10b for a predetermined time at predetermined intervals and the signal from the concentration measuring device 12, the saturation concentration of the silica concentration of the water to be treated is limited, and when the concentration is high, it is short. When the time is low, the interval time is set to be long, and a program that outputs a blow command signal to the blow valve 10b for a predetermined time at a predetermined interval and a blow command to the blow valve 10b based on the blow command signal are selected. While outputting a signal, a program for outputting a close command signal to the on-off valve 9 disposed in the water supply line 1a through which the treated water treated by the reverse osmosis membrane section 4 flows. Eteiru.

更に、選択により、前記ブロー指令信号に基づいてブロー弁10bにブロー指令信号を出力している間、前記インバータ13に指令信号を出力し、インバータ13によりポンプ7の回転数を、被処理水の供給量を増量するように変更する指令信号を出力するプログラムを備えている。   Furthermore, by selection, while outputting the blow command signal to the blow valve 10b based on the blow command signal, the command signal is output to the inverter 13, and the inverter 13 sets the rotation speed of the pump 7 to be treated water. A program for outputting a command signal for changing the supply amount to increase is provided.

上記のように構成した水処理システムにより、本発明に係る水処理方法は次のように実施される。   With the water treatment system configured as described above, the water treatment method according to the present invention is implemented as follows.

供給された被処理水を軟水処理部2で軟水処理することにより、被処理水中のカルシウム等の硬度分が除去され、被処理水のシリカ溶解度が高くなった状態でフィルター3で被処理水中のゴミ等を除去し、該被処理水をポンプ7で加圧して逆浸透膜部4に供給する。逆浸透膜部4を透過し、不純物が除去された処理水は、膜式脱気部5で脱気され、貯留する貯留タンク6に貯留される。   The supplied treated water is subjected to soft water treatment in the soft water treatment unit 2 to remove hardness components such as calcium in the treated water, and the silica solubility in the treated water is increased in the treated water in the filter 3. Dust and the like are removed, and the water to be treated is pressurized by the pump 7 and supplied to the reverse osmosis membrane unit 4. The treated water that has passed through the reverse osmosis membrane unit 4 and from which impurities have been removed is deaerated by the membrane type deaeration unit 5 and stored in a storage tank 6 that stores the processed water.

そして、前記水処理運転の過程で、被処理水の温度が下がり、温度センサ11により被処理水のシリカ濃度が当該温度における処理水のシリカ溶解度を超える濃度になる温度となったことを検知したとき、温度センサ11からの温度検知信号に基づいて制御部14がプログラムに従い、前記ブローライン8bに配置されたブロー弁10bにブロー信号を出力し、ブロー弁10bを所定時間開きブローする。この動作は、プログラムで設定された所定間隔で行われる。   Then, in the course of the water treatment operation, the temperature of the water to be treated has decreased, and the temperature sensor 11 has detected that the silica concentration of the water to be treated has reached a temperature that exceeds the silica solubility of the treated water at that temperature. At this time, the control unit 14 outputs a blow signal to the blow valve 10b disposed in the blow line 8b based on the temperature detection signal from the temperature sensor 11, and opens and blows the blow valve 10b for a predetermined time. This operation is performed at predetermined intervals set by the program.

また、前記とは別に、前記水処理運転の過程で、被処理水のシリカ濃度が高くなり、濃度測定装置12により、シリカ濃度が当該被処理水のシリカ溶解度を超える濃度となったことを検出したとき、濃度測定装置12からのシリカ濃度検出信号に基づいて制御部14がプログラムに従い、前記濃縮排水ライン8に配置されたブロー弁10bにブロー信号を出力し、ブロー弁10bを所定時間開きブローする。この動作は、プログラムで設定された所定間隔で行われる。   In addition to the above, in the course of the water treatment operation, the silica concentration of the water to be treated is increased, and the concentration measuring device 12 detects that the silica concentration has exceeded the silica solubility of the water to be treated. Then, the control unit 14 outputs a blow signal to the blow valve 10b arranged in the concentrated drainage line 8 based on the silica concentration detection signal from the concentration measuring device 12, and opens the blow valve 10b for a predetermined time. To do. This operation is performed at predetermined intervals set by the program.

ブローライン8bに配置されたブロー弁10bにブロー信号を出力するものとしては、操作者により、前記温度センサ11からの温度検知信号、或いは濃度測定装置12からのシリカ濃度検出信号のいずれかが選択される。   The operator selects either the temperature detection signal from the temperature sensor 11 or the silica concentration detection signal from the concentration measuring device 12 as the one that outputs a blow signal to the blow valve 10b disposed in the blow line 8b. Is done.

このようにすることにより、逆浸透膜部4による濾過でシリカ濃度が高くなった被処理水が定期的に濃縮排水を排水する側に流れるので、逆浸透膜部4付近における被処理水のシリカ濃度の上昇が押さえられ、シリカスケールの析出が抑制され、これにより、逆浸透膜部4の目詰まりを防止でき、長期的に安定した水処理運転を継続して行うことができ、処理水の回収率の一層の向上を図ることができる。   By doing in this way, since the to-be-processed water with which the silica density | concentration became high by filtration by the reverse osmosis membrane part 4 flows to the side which drains concentrated waste water regularly, the silica of to-be-processed water in the reverse osmosis membrane part 4 vicinity. The increase in concentration is suppressed, and the precipitation of silica scale is suppressed, whereby clogging of the reverse osmosis membrane portion 4 can be prevented, and stable water treatment operation can be continuously performed for a long time. The recovery rate can be further improved.

前記、ブロー弁10bを所定時間開き濃縮排水をブローする際に、選択により、前記ブロー指令信号に基づいてブロー弁10bにブロー指令信号を出力している間、前記逆浸透膜部4で処理された処理水を流す処理水ライン1aに配置された開閉弁9に閉指令信号を出力することができる。   When the blow valve 10b is opened for a predetermined time and concentrated drainage is blown, the reverse osmosis membrane unit 4 performs processing while outputting a blow command signal to the blow valve 10b based on the blow command signal. A close command signal can be output to the on-off valve 9 disposed in the treated water line 1a through which the treated water flows.

このようにすると、被処理水は全てブローライン8bに流れるので、被処理水のシリカ濃度を短時間で低くすることができるとともに、ブローライン8bに流れる被処理水の流速が早くなり、その流圧により逆浸透膜部4に沈着したシリカスケールは逆浸透膜部4から剥離することになり、逆浸透膜部4の目詰まりを早期に解消することができるものとなる。この方法は、シリカ濃度がシリカ溶解度を大きく超えシリカスケールが析出しやすい状態になったときや逆浸透膜部4にシリカスケールが沈着し目詰まりを起こし始めたときに、効果的である。   In this way, since all the water to be treated flows to the blow line 8b, the silica concentration of the water to be treated can be lowered in a short time, and the flow rate of the water to be treated flowing to the blow line 8b is increased. The silica scale deposited on the reverse osmosis membrane part 4 due to the pressure is peeled off from the reverse osmosis membrane part 4, so that the clogging of the reverse osmosis membrane part 4 can be eliminated at an early stage. This method is effective when the silica concentration greatly exceeds the silica solubility and the silica scale is likely to precipitate, or when the silica scale is deposited on the reverse osmosis membrane portion 4 and clogging starts.

また、選択により、前記ブロー指令信号に基づいてブロー弁10bにブロー指令信号を出力している間、前記インバータ13に指令信号を出力し、インバータ13によりポンプ7の回転数を、被処理水の供給量を増量するように変更する指令信号を出力することができる。   Further, by selection, while outputting the blow command signal to the blow valve 10b based on the blow command signal, the command signal is output to the inverter 13, and the rotation speed of the pump 7 is adjusted by the inverter 13 to the water to be treated. A command signal for changing the supply amount to be increased can be output.

このようにすると、逆浸透膜部4を透過する被処理水の流量はブロー前と変わらず、処理水の定量化を維持することができる。   If it does in this way, the flow volume of the to-be-processed water which permeate | transmits the reverse osmosis membrane part 4 will be the same as before blow, and can maintain the quantification of treated water.

本発明に係る水処理方法を実施する水処理システムの概略説明図。The schematic explanatory drawing of the water treatment system which enforces the water treatment method concerning the present invention.

符号の説明Explanation of symbols

2 軟水処理部
4 逆浸透膜部
7 ポンプ
8 濃縮排水ライン
8a 排水ライン
8b ブローライン
9 開閉弁
10a 排水弁
10b ブロー弁
11 温度センサ
12 濃度測定装置
13 インバータ
14 制御部
DESCRIPTION OF SYMBOLS 2 Soft water processing part 4 Reverse osmosis membrane part 7 Pump 8 Concentration drainage line 8a Drainage line 8b Blow line 9 Open / close valve 10a Drain valve 10b Blow valve 11 Temperature sensor 12 Concentration measuring device 13 Inverter 14 Control part

Claims (3)

被処理水を軟水処理した後、逆浸透膜部で濾過し、逆浸透膜部に発生する濃縮排水を所定間隔でブローする水処理方法であって、
前記濃縮排水をブローする所定間隔は、予め想定した被処理水の温度と、その温度における被処理水のシリカ溶解度を基に設定した一定時間となっていることを特徴とする水処理方法。
After water to be treated is treated with soft water, it is filtered through a reverse osmosis membrane part, and is a water treatment method for blowing concentrated wastewater generated in the reverse osmosis membrane part at predetermined intervals,
The water treatment method according to claim 1, wherein the predetermined interval for blowing the concentrated waste water is a predetermined time set based on a temperature of the water to be treated which is assumed in advance and a silica solubility of the water to be treated at the temperature.
被処理水を軟水処理した後、逆浸透膜部で濾過し、逆浸透膜部に発生する濃縮排水を所定間隔でブローする水処理方法であって、
前記濃縮排水をブローする所定間隔は、被処理水の温度を検知し、水温が高いときは長く、低いときは短くなるように設定されていることを特徴とする水処理方法。
After water to be treated is treated with soft water, it is filtered through a reverse osmosis membrane part, and is a water treatment method for blowing concentrated wastewater generated in the reverse osmosis membrane part at predetermined intervals,
The water treatment method is characterized in that the predetermined interval for blowing the concentrated waste water is set so as to detect the temperature of the water to be treated and to be long when the water temperature is high and short when the water temperature is low.
前記逆浸透膜部に発生する濃縮排水をブローするときは、処理水側の弁を閉じて行うことを特徴とする請求項1又は2に記載の水処理方法。 The water treatment method according to claim 1 or 2, wherein when the concentrated drainage generated in the reverse osmosis membrane part is blown, the valve on the treated water side is closed .
JP2004097811A 2004-03-30 2004-03-30 Water treatment method Expired - Fee Related JP5005165B2 (en)

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