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JP5000463B2 - Oil and fat-containing emulsion composition and production method thereof, and food containing oil and fat-containing emulsion composition - Google Patents

Oil and fat-containing emulsion composition and production method thereof, and food containing oil and fat-containing emulsion composition Download PDF

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JP5000463B2
JP5000463B2 JP2007302569A JP2007302569A JP5000463B2 JP 5000463 B2 JP5000463 B2 JP 5000463B2 JP 2007302569 A JP2007302569 A JP 2007302569A JP 2007302569 A JP2007302569 A JP 2007302569A JP 5000463 B2 JP5000463 B2 JP 5000463B2
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oil
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emulsion composition
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JP2008148692A (en
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知文 木村
朋子 木庭
茂樹 川崎
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Kewpie Corp
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Description

本発明は、透明感を有しかつ風味がよい油脂含有乳化組成物及びその製造方法、並びに油脂含有乳化組成物を含有する食品に関する。   TECHNICAL FIELD The present invention relates to an oil-containing emulsion composition having transparency and a good flavor, a method for producing the same, and a food containing the oil-containing emulsion composition.

マヨネーズ等の乳化食品は、水相原料の風味と油脂原料の風味とが合わさったまろやかな風味と、乳化によるなめらかな口当たりのよい食感とを有する人気食品である。一方、前記乳化食品は、水相中に分散する油脂粒子が光を散乱するため、一般に、白濁した白い色調を有するという性質を有する。   Emulsified foods such as mayonnaise are popular foods that have a mellow flavor that combines the flavor of the water phase raw material and the flavor of the fat and oil raw material, and a smooth and pleasant texture by emulsification. On the other hand, the emulsified food generally has the property of having a white color that is cloudy because the fat particles dispersed in the aqueous phase scatter light.

近年、嗜好の多様化に伴って、様々な新しいメニュー及び加工食品の開発が行われており、メニュー及び加工食品の外観を引き立て、かつ風味を向上させるために使用することができる、透明感を有しかつ風味が良好な乳化食品が求められている。   In recent years, with the diversification of tastes, various new menus and processed foods have been developed, and the transparency that can be used to enhance the appearance of menus and processed foods and improve the flavor. There is a need for emulsified foods that have good flavor.

油脂を含有する乳化組成物に透明感を付与する方法としては、例えば、水相と油相の屈折率を一致させる方法が特開平11−18709号公報(特許文献1)に提案されている。また、乳化剤として非イオン性界面活性剤及びリゾレシチンを用いる脂溶性物質含有液剤が特開平7−17860号公報(特許文献2)に提案されている。しかしながら、これらの方法はいずれも、透明感を付与するために使用される乳化剤の種類や配合等に制約があるため、風味が劣るという問題があった。
特開平11−18709号公報 特開平7−17860号公報
As a method for imparting transparency to an emulsified composition containing fats and oils, for example, a method for matching the refractive indexes of an aqueous phase and an oil phase has been proposed in JP-A-11-18709 (Patent Document 1). Further, a fat-soluble substance-containing liquid agent using a nonionic surfactant and lysolecithin as an emulsifier has been proposed in JP-A-7-17860 (Patent Document 2). However, all of these methods have a problem that the flavor is inferior because there are restrictions on the types and blends of emulsifiers used for imparting transparency.
Japanese Patent Laid-Open No. 11-18709 Japanese Patent Laid-Open No. 7-17860

本発明は、透明感を有しかつ風味が良好な油脂含有乳化組成物及びその製造方法、並びに油脂含有乳化組成物を含有する食品を提供する。   The present invention provides a fat-containing emulsion composition having transparency and good flavor, a method for producing the same, and a food containing the fat-containing emulsion composition.

本発明者は、上記目的を達成すべく鋭意研究を重ねた結果、卵黄、卵白及び動物性蛋白から選ばれる1種又は2種以上の成分及び多価アルコールを含む混合液と油脂とを50℃以上で乳化処理するならば、意外にも、透明感を有しかつ風味がよい油脂含有乳化組成物が得られること、並びに、前記油脂含有乳化組成物を用いた水中油型乳化飲食品が油脂の分散性が優れていることを見出し、遂に本発明を完成するに至った。   As a result of intensive studies to achieve the above object, the present inventor obtained a mixture solution containing one or more components selected from egg yolk, egg white and animal protein, and a polyhydric alcohol, and fats and oils at 50 ° C. If emulsification treatment is performed as described above, a fat-and-oil-containing emulsified composition having a transparent feeling and a tasty flavor can be surprisingly obtained, and an oil-in-water emulsified food and drink using the oil-and-fat-containing emulsion composition As a result, the present invention was finally completed.

本発明の一態様に係る油脂含有乳化組成物は、
卵黄、卵白及び動物性蛋白から選ばれる1種又は2種以上の成分を含み、積分球式光電光度法を用いた濁度測定により得られた全光線透過率が40%以上である。
The oil-and-fat-containing emulsion composition according to one aspect of the present invention comprises:
It contains one or more components selected from egg yolk, egg white and animal protein, and has a total light transmittance of 40% or more obtained by turbidity measurement using an integrating sphere photoelectric photometry method.

上記油脂含有乳化組成物において、前記成分の含有量が固形分換算で0.1質量%以上であることができる。ここで、「前記成分の含有量」は、前記成分が卵黄、卵白及び動物性蛋白から選ばれる2種以上の成分からなる場合、前記2種以上の成分の合計の含有量を意味する。   In the oil-and-fat-containing emulsion composition, the content of the component can be 0.1% by mass or more in terms of solid content. Here, "content of the said component" means the total content of the said 2 or more types of component, when the said component consists of 2 or more types of components chosen from egg yolk, egg white, and animal protein.

上記油脂含有乳化組成物において、多価アルコールをさらに含むことができる。この場合、前記成分の含有量と前記多価アルコールの含有量との比率が、固形分換算で前記成分100質量部に対して多価アルコールが1質量部以上であることができる。   The oil-and-fat-containing emulsion composition may further contain a polyhydric alcohol. In this case, the ratio of the content of the component and the content of the polyhydric alcohol may be 1 part by mass or more of the polyhydric alcohol with respect to 100 parts by mass of the component in terms of solid content.

上記油脂含有乳化組成物において、脂溶性成分をさらに含むことができる。   The fat-and-oil-containing emulsion composition may further contain a fat-soluble component.

本発明の一態様に係る食品は、上記油脂含有乳化組成物を含有する。   The foodstuff which concerns on 1 aspect of this invention contains the said oil-and-fat containing emulsion composition.

本発明の一態様に係る水中油型乳化飲食品は、上記油脂含有乳化組成物が配合され、前記油脂含有乳化組成物の油脂が油滴として分散していることができる。   The oil-in-water type emulsion food / beverage product which concerns on 1 aspect of this invention is mix | blended with the said oil-and-fat containing emulsion composition, and the fats and oils of the said oil-and-fat containing emulsion composition can be disperse | distributing as an oil droplet.

本発明の一態様に係る油脂含有乳化組成物の製造方法は、
卵黄、卵白、及び動物性蛋白から選ばれる1種又は2種以上の成分及び多価アルコールを含む混合液と油脂とを50℃以上で乳化処理することを含む。
The method for producing an oil-containing emulsion composition according to one aspect of the present invention,
It includes emulsifying a mixed solution containing one or more components selected from egg yolk, egg white, and animal protein and a polyhydric alcohol, and fats and oils at 50 ° C. or higher.

本発明の一態様に係る油脂含有乳化組成物の製造方法は、
卵黄、卵白、及び動物性蛋白から選ばれる1種又は2種以上の成分及び多価アルコールを含む混合液と油脂とを乳化処理する際の温度を調整することにより、得られる油脂含有乳化組成物の透明度を調整することを含む。
The method for producing an oil-containing emulsion composition according to one aspect of the present invention,
Fat and oil-containing emulsion composition obtained by adjusting the temperature at the time of emulsifying a mixed liquid containing one or more components selected from egg yolk, egg white, and animal protein and a polyhydric alcohol and fats and oils Including adjusting the transparency.

上記油脂含有乳化組成物の製造方法において、前記乳化処理により、積分球式光電光度法を用いた濁度測定により得られた全光線透過率が40%以上である油脂含有乳化組成物を得ることができる。   In the method for producing an oil-containing emulsion composition, an oil-containing emulsion composition having a total light transmittance of 40% or more obtained by turbidity measurement using an integrating sphere photoelectric photometry method is obtained by the emulsion treatment. Can do.

上記油脂含有乳化組成物の製造方法において、前記混合液の前記成分と多価アルコールとの混合比率が、固形分換算で前記成分の合計量100質量部に対して多価アルコールが1質量部以上であることができる。   In the method for producing the oil-and-fat-containing emulsion composition, the mixing ratio of the component and the polyhydric alcohol in the mixed solution is 1 part by mass or more of polyhydric alcohol with respect to the total amount of 100 parts by mass in terms of solid content. Can be.

上記油脂含有乳化組成物は、透明感を有しかつ風味が良好である。したがって、白濁した白い色調の一般的な乳化食品では得られなかった、まったく新しい外観及び風味のメニューや加工食品を得ることができる。これにより、食品産業の新たな市場形成が期待できる。また、上記油脂含有乳化組成物は食品由来の前記成分を含むため、安全性が高い。   The oil-and-fat-containing emulsion composition has a clear feeling and a good flavor. Therefore, it is possible to obtain a menu or processed food with a completely new appearance and flavor that could not be obtained with a general emulsified food having a cloudy white color. This can be expected to create a new market for the food industry. Moreover, since the said oil-and-fat containing emulsion composition contains the said component derived from a foodstuff, its safety | security is high.

上記水中油型乳化飲食品は、油脂の分散性に優れている。より具体的には、上記油脂含有乳化組成物を水系媒体と軽く混合するだけで、風味を損なうことなく、水系媒体中での油脂の分散性に優れた水中油型油脂含有乳化飲食品を容易に得ることができる。   The oil-in-water type emulsified food or drink is excellent in fat and oil dispersibility. More specifically, an oil-in-water type oil-and-fat-containing emulsified food and drink excellent in dispersibility of fats and oils in an aqueous medium can be easily obtained without lightly losing the flavor by simply mixing the oil-and-fat emulsion composition with an aqueous medium. Can get to.

以下、本発明の一実施形態に係る油脂含有乳化組成物及びその製造方法、並びに油脂含有乳化組成物を含む食品について説明する。   Hereinafter, the fat and oil-containing emulsion composition according to an embodiment of the present invention, a method for producing the same, and a food product containing the fat and oil-containing emulsion composition will be described.

1.油脂含有乳化組成物及びその製造方法、並びに油脂含有乳化組成物を含有する食品
1.1.油脂含有乳化組成物
本発明において、油脂含有乳化組成物とは、少なくとも油脂と水を含み、これらが略均一に混合されて乳化状態となっている組成物である。
1. Oil and fat-containing emulsion composition and method for producing the same, and food containing oil and fat-containing emulsion composition 1.1. Oil and fat-containing emulsion composition In the present invention, the oil and fat-containing emulsion composition is a composition that contains at least oil and water and is substantially uniformly mixed to form an emulsified state.

本実施形態に係る油脂含有乳化組成物は、卵黄、卵白、及び動物性蛋白から選ばれる1種又は2種以上の成分(以下、「特定成分」ともいう。)を含む。   The fat-and-oil-containing emulsion composition according to this embodiment includes one or more components selected from egg yolk, egg white, and animal protein (hereinafter also referred to as “specific component”).

本実施形態に係る油脂含有乳化組成物は、特定成分を含むことにより、風味がよいものとなる。本実施形態に係る油脂含有乳化組成物において、特定成分は乳化材として機能することができる。   The fat-and-oil-containing emulsion composition according to the present embodiment has a good flavor by including a specific component. In the oil-containing emulsion composition according to the present embodiment, the specific component can function as an emulsifying material.

また、本実施形態に係る油脂含有乳化組成物は多価アルコールを含むことができる。この場合、多価アルコールは乳化材として機能することができる。   Moreover, the fat-and-oil containing emulsion composition which concerns on this embodiment can contain a polyhydric alcohol. In this case, the polyhydric alcohol can function as an emulsifying material.

なお、本実施形態に係る油脂含有乳化組成物においては、卵黄等の特定成分及び多価アルコール以外の乳化材を実質的に含まなくてもよい。ここで、「特定成分及び多価アルコール以外の乳化材を実質的に含まない」とは、特定成分及び多価アルコール以外の乳化材の含有量が0.01質量%以下であることをいう。特定成分及び多価アルコール以外の乳化材とは、例えば、食品用乳化材として一般的に使用されている物質(例えば、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、レシチン、リゾレシチン、水添レシチン)が挙げられる。   In addition, in the oil-and-fat containing emulsion composition which concerns on this embodiment, emulsification materials other than specific components and polyhydric alcohol, such as egg yolk, may not be included substantially. Here, “substantially no emulsifying material other than the specific component and polyhydric alcohol” means that the content of the emulsifying material other than the specific component and the polyhydric alcohol is 0.01% by mass or less. Emulsifiers other than specific components and polyhydric alcohols are, for example, substances generally used as food emulsifiers (for example, glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, lecithin , Lysolecithin, hydrogenated lecithin).

本実施形態に係る油脂含有乳化組成物は、特定成分及び多価アルコール以外の乳化材を実質的に含まないことにより、風味が良好である。   The fat-and-oil-containing emulsion composition according to the present embodiment has a good flavor by not substantially containing an emulsifying material other than the specific component and the polyhydric alcohol.

特定成分として使用可能な卵黄としては特に制限は無く、例えば、鶏卵を割卵し卵白液と分離して得られた生卵黄をはじめ、当該生卵黄に殺菌処理、冷凍処理、スプレードライ又はフリーズドライ等の乾燥処理、ホスフォリパーゼA1、ホスフォリパーゼA2、ホスフォリパーゼC、ホスフォリパーゼD又はプロテアーゼ等による酵素処理、酵母又はグルコースオキシダーゼ等による脱糖処理、超臨界二酸化炭素処理等の脱コレステロール処理、食塩又は糖類等の混合処理等の1種又は2種以上の処理を施したもの等が挙げられる。   The egg yolk that can be used as the specific component is not particularly limited. For example, raw egg yolk obtained by splitting a chicken egg and separating it from egg white liquid, the raw egg yolk is sterilized, frozen, spray-dried or freeze-dried. Dehydration treatment such as phospholipase A1, phospholipase A2, phospholipase C, phospholipase D or protease, desugaring treatment with yeast or glucose oxidase, supercritical carbon dioxide treatment, etc. The thing which performed 1 type, or 2 or more types of processes, such as a process, mixing processes, such as salt or saccharides, is mentioned.

本実施形態に係る油脂含有乳化組成物は、卵黄を含むことにより、風味が特によいものとなる。本実施形態に係る油脂含有乳化組成物において、卵黄は乳化材として良好に機能することができる。   The fat-and-oil-containing emulsion composition according to the present embodiment has particularly good flavor by including egg yolk. In the oil-and-fat-containing emulsion composition according to this embodiment, egg yolk can function well as an emulsifying material.

特定成分として使用可能な卵白としては、特に制限は無く、例えば、鶏卵を割卵し卵黄液と分離して得られた生卵白をはじめ、当該生卵白に殺菌処理、冷凍処理、スプレードライ又はフリーズドライ等の乾燥処理、プロテアーゼ等による酵素処理、酵母又はグルコースオキシダーゼ等による脱糖処理、食塩又は糖類等の混合処理等の1種又は2種以上の処理を施したもの等が挙げられる。   The egg white that can be used as the specific component is not particularly limited, and includes, for example, raw egg white obtained by splitting a chicken egg and separating it from egg yolk liquid, and sterilizing, freezing, spray drying, or freezing the raw egg white. Examples thereof include those subjected to one or more treatments such as drying treatment such as drying, enzyme treatment with protease, etc., desugaring treatment with yeast or glucose oxidase, etc., and mixed treatment with salt or saccharide.

また、特定成分として、卵黄と卵白との混合物を用いてもよい。この場合、上記混合物は、鶏卵を割卵して得られる全卵、卵黄と卵白とを任意の割合で混合したもの、あるいはこれらに上記処理を施したもの等であってもよい。   Moreover, you may use the mixture of egg yolk and egg white as a specific component. In this case, the mixture may be a whole egg obtained by splitting a chicken egg, a mixture of egg yolk and egg white in an arbitrary ratio, or a mixture obtained by performing the above-described treatment.

特定成分として使用可能な動物性蛋白としては、卵や乳等の動物性の蛋白含有原料の構成成分から蛋白以外の成分を除去したものをいい、蛋白が90質量%以上含まれるものをいう。例えば、卵蛋白としては脱脂卵等が、乳蛋白としては、ホエー蛋白、カゼイン及びこれらの混合物等が挙げられ、これらの1種以上を使用することができる。   Animal protein that can be used as a specific component refers to a component obtained by removing components other than protein from the constituent components of animal protein-containing raw materials such as eggs and milk, and that includes 90% by mass or more of protein. For example, defatted eggs and the like are exemplified as egg proteins, and whey protein, casein and a mixture thereof are exemplified as milk proteins, and one or more of these can be used.

なお、特定成分には、溶解度が増したりして使い易い点から、卵黄、卵白及び動物性蛋白から選ばれる1種又は2種以上の成分の部分分解物が含まれるものとする。このような部分分解物としては、具体的には、特定成分を酵素あるいは酸等を用いて部分的に分解することにより得られる水溶性蛋白質の部分分解物が挙げられる。前記蛋白質の部分分解物としては、あまり分解しすぎたりすると乳化力が低下したりすることから、その平均分子量が好ましくは500〜50,000、より好ましくは500〜10,000程度のものが好ましい。   The specific component includes a partially decomposed product of one or more components selected from egg yolk, egg white, and animal protein from the viewpoint of increasing the solubility and ease of use. Specific examples of such a partially decomposed product include a partially decomposed product of a water-soluble protein obtained by partially decomposing a specific component using an enzyme or an acid. As the partial degradation product of the protein, since the emulsifying power is lowered when it is decomposed too much, the average molecular weight is preferably 500 to 50,000, more preferably about 500 to 10,000. .

本実施形態に係る油脂含有乳化組成物は、より透明度の高い油脂含有乳化組成物が得られ易いことから、特定成分として卵黄又は乳蛋白を含むことがより好ましい。   The fat-and-oil-containing emulsion composition according to the present embodiment more preferably contains egg yolk or milk protein as a specific component because an oil-and-fat-containing emulsion composition with higher transparency is easily obtained.

特定成分の含有量は、本実施形態に係る油脂含有乳化組成物に対して固形分換算で好ましくは0.1質量%以上であり、より好ましくは0.1〜15質量%であり、更に好ましくは0.5〜10質量%である。特定成分の含有量が0.1質量%より少ないと、風味の点から好ましくなく、また、該組成物において油の分離が生じ易い。一方、特定成分の含有量が15質量%より多いと、透明感を有する油脂含有乳化組成物が得られ難い傾向がある。   The content of the specific component is preferably 0.1% by mass or more, more preferably 0.1 to 15% by mass, more preferably 0.1% by mass in terms of solid content with respect to the oil / fat-containing emulsion composition according to this embodiment. Is 0.5 to 10% by mass. When the content of the specific component is less than 0.1% by mass, it is not preferable from the viewpoint of flavor, and oil separation tends to occur in the composition. On the other hand, when there is more content of a specific component than 15 mass%, there exists a tendency for the fat-containing emulsion composition which has a transparent feeling to be hard to be obtained.

特定成分を乳化材として含むマヨネーズ等の一般的な乳化食品は、水相中に分散した油脂粒子等が光を散乱するため、白濁した白い色調を有する。これに対して、本実施形態に係る油脂含有乳化組成物は透明感を有する。すなわち、本実施形態に係る油脂含有乳化組成物は、積分球式光電光度法を用いた濁度測定により得られた全光線透過率が40%以上(通常40〜98%)、好ましくは50%以上、より好ましくは60%以上、更に好ましくは70%以上、特に好ましくは80%以上である。   A general emulsified food such as mayonnaise containing a specific component as an emulsifying material has a white color that is cloudy because oil particles dispersed in an aqueous phase scatter light. On the other hand, the fat and oil-containing emulsion composition according to this embodiment has a transparency. That is, the oil-containing emulsion composition according to this embodiment has a total light transmittance of 40% or more (usually 40 to 98%), preferably 50%, obtained by turbidity measurement using an integrating sphere photoelectric photometry method. Above, more preferably 60% or more, still more preferably 70% or more, particularly preferably 80% or more.

本発明において、積分球式光電光度法を用いた濁度測定により得られる、サンプルの全光線透過率は、清水の全光線透過率に対する値である。すなわち、全光線透過率は、サンプルに全光線を照射した時の透過率であり、対照である清水の透過率を100%とした場合のサンプルの透過率(%)を示す。したがって、積分球式光電光度法を用いた濁度測定により得られた、本実施形態に係る油脂含有乳化組成物の全光線透過率は、本実施形態に係る油脂含有乳化組成物の透明度を示す指標であり、全光線透過率の値が高いほど、透明度が高いことを意味する。   In the present invention, the total light transmittance of the sample obtained by turbidity measurement using an integrating sphere photoelectric photometry is a value relative to the total light transmittance of fresh water. That is, the total light transmittance is the transmittance when the sample is irradiated with all the light, and indicates the transmittance (%) of the sample when the transmittance of fresh water as a control is 100%. Therefore, the total light transmittance of the oil-containing emulsion composition according to this embodiment, obtained by turbidity measurement using an integrating sphere photoelectric photometry, indicates the transparency of the oil-containing emulsion composition according to this embodiment. It is an index, and the higher the value of the total light transmittance, the higher the transparency.

具体的には、後述する試験例に示すように、サンプルの全光線透過率が40%以上である場合、透明感を有し半透明であり、サンプルの全光線透過率が大きいほど透明度が高い。一方、サンプルの全光線透過率が40%未満であると、白濁した白い色調である。   Specifically, as shown in a test example described later, when the total light transmittance of the sample is 40% or more, the sample has transparency and is translucent, and the greater the total light transmittance of the sample, the higher the transparency. . On the other hand, if the total light transmittance of the sample is less than 40%, the color tone is white and cloudy.

積分球式光電光度法を用いた濁度測定によるサンプルの全光線透過率の測定は、粒子に光を照射した場合の散乱光の強度と透過光の強度との比から、サンプルの全光線透過率を求めることにより行われ、JIS K 0101に準じて行うことができる。例えば、濁度測定器(型名「WA 2000N」、日本電色工業(株)製)を用いて、積分球式光電光度法を用いた濁度測定により、サンプルの全光線透過率を得ることができる。   The measurement of the total light transmittance of a sample by turbidity measurement using the integrating sphere photoelectric photometry method is based on the ratio of the intensity of scattered light and the intensity of transmitted light when the particle is irradiated with light, and the total light transmission of the sample. It is performed by obtaining the rate, and can be performed according to JIS K 0101. For example, using a turbidity measuring device (model name “WA 2000N”, manufactured by Nippon Denshoku Industries Co., Ltd.), the total light transmittance of the sample is obtained by turbidity measurement using an integrating sphere photoelectric photometry method. Can do.

本実施形態に係る油脂含有乳化組成物において使用可能な多価アルコールは、分子内に2個以上の水酸基を有するアルコールのことであり、例えば、グルコース、ガラクトース、マンノース、フルクトース、キシロースなどの単糖類、シュークロース、マルトース、ラクトース、トレハロースなどの二糖類、オリゴ糖、デキストリン、マルトトリオース、サイクロデキストリンなどの多糖類、キシリトール、マルチトール、イノシトール、ペンタエリスリトール、ソルビトール、スレイトール、ラクチトール、マンニトール、還元デキストリンなどの糖アルコールの他、グリセリン等のポリグリセリンを挙げることができ、このうち、直鎖の糖アルコールやグリセリン等のポリグリセリンが好ましく、炭素数3〜6の糖アルコールまたはポリグリセリンがより好ましい。   The polyhydric alcohol that can be used in the oil-and-fat-containing emulsion composition according to this embodiment is an alcohol having two or more hydroxyl groups in the molecule, for example, monosaccharides such as glucose, galactose, mannose, fructose, and xylose. , Sucrose, maltose, lactose, trehalose and other disaccharides, oligosaccharides, dextrin, maltotriose, cyclodextrin and other polysaccharides, xylitol, maltitol, inositol, pentaerythritol, sorbitol, threitol, lactitol, mannitol, reduced dextrin In addition to sugar alcohols such as glycerin, polyglycerin such as glycerin can be mentioned. Of these, linear sugar alcohols and polyglycerins such as glycerin are preferable, and sugar alcohols having 3 to 6 carbon atoms or polyglycerin are preferred. Glycerin is more preferable.

本実施形態に係る油脂含有乳化組成物における多価アルコールの含有量は、固形分換算で好ましくは10〜70質量%、好ましくは15〜60質量%である。本実施形態に係る油脂含有乳化組成物における多価アルコールの含有量が10質量%より少ない場合または70質量%より多い場合、透明感を有する油脂含有乳化組成物が得られ難い傾向がある。また、本実施形態に係る油脂含有乳化組成物において、特定成分及び多価アルコールの含有比率は、固形分換算で特定成分100質量部に対して多価アルコールが1質量部以上であることが好ましく、10質量部以上であることがより好ましい。   The content of the polyhydric alcohol in the oil-and-fat-containing emulsion composition according to this embodiment is preferably 10 to 70% by mass, and preferably 15 to 60% by mass in terms of solid content. When the content of the polyhydric alcohol in the oil-containing emulsion composition according to this embodiment is less than 10% by mass or more than 70% by mass, it is difficult to obtain an oil-containing emulsion composition having a transparency. Moreover, in the oil-and-fat-containing emulsion composition according to this embodiment, the content ratio of the specific component and the polyhydric alcohol is preferably 1 part by mass or more of polyhydric alcohol with respect to 100 parts by mass of the specific component in terms of solid content. More preferably, it is 10 parts by mass or more.

本実施形態に係る油脂含有乳化組成物で用いる油脂は特に制限は無く、ヤシ油、菜種油、コーン油、綿実油、サフラワー油、オリーブ油、紅花油、大豆油、パーム油、ゴマ油、エゴマ油、魚油、卵黄油等の動植物油又はこれらの精製油(サラダ油)、あるいはMCT(中鎖脂肪酸トリグリセリド)、ジグリセリド、硬化油、エステル交換油等のような化学的処理や酵素的処理等を施して得られる油脂等が挙げられる。   The fats and oils used in the fat and oil-containing emulsion composition according to this embodiment are not particularly limited, and are coconut oil, rapeseed oil, corn oil, cottonseed oil, safflower oil, olive oil, safflower oil, soybean oil, palm oil, sesame oil, sesame oil, fish oil. , Animal and vegetable oils such as egg yolk oil, or these refined oils (salad oil), or obtained by chemical treatment or enzymatic treatment such as MCT (medium chain fatty acid triglyceride), diglyceride, hydrogenated oil, transesterified oil, etc. Examples include oils and fats.

本実施形態に係る油脂含有乳化組成物における油脂の含有量は、好ましくは1〜80質量%、より好ましくは10〜80質量%、更に好ましくは30〜80質量%である。本実施形態に係る油脂含有乳化組成物における油脂の含有量が1質量%より少ない場合、風味やなめらかな口当たりの点から好ましくなく、一方、80質量%より多い場合、透明感のある油脂含有乳化組成物が得られ難い傾向がある。   The content of fats and oils in the fat and oil-containing emulsion composition according to this embodiment is preferably 1 to 80% by mass, more preferably 10 to 80% by mass, and still more preferably 30 to 80% by mass. When the content of fats and oils in the fat-containing emulsion composition according to this embodiment is less than 1% by mass, it is not preferable from the viewpoint of flavor and smooth mouthfeel, while when it is more than 80% by mass, the fat-containing emulsification with transparency is transparent. The composition tends to be difficult to obtain.

本実施形態に係る油脂含有乳化組成物は食品由来の特定成分を含むため、安全性が高く、例えば、食品由来の特定成分、油脂、及び糖アルコールを含む場合、安全性が特に高い。   Since the oil-and-fat-containing emulsion composition according to the present embodiment includes a specific component derived from food, the safety is high. For example, when a specific component derived from food, fat and sugar, and a sugar alcohol are included, the safety is particularly high.

また、本実施形態に係る油脂含有乳化組成物は、前記油脂の他に種々の脂溶性成分を含有させることができる。本実施形態に係る油脂含有乳化組成物が脂溶性成分を含有する場合、水系媒体と混合するだけで風味を損なわずに、脂溶性成分を含む油脂を水中油型の油滴として、水系媒体中に良好に分散させることができる。したがって、例えば、本実施形態に係る油脂含有乳化組成物を、脂溶性成分が乳化しにくい液状の水中油型乳化飲食品に用いることにより、脂溶性成分を油脂とともに水系媒体中に良好に分散させることができる。   Moreover, the fat-and-oil-containing emulsion composition which concerns on this embodiment can contain a various fat-soluble component other than the said fats and oils. When the fat and oil-containing emulsion composition according to the present embodiment contains a fat-soluble component, the fat and oil containing the fat-soluble component is used as an oil-in-water oil droplet in an aqueous medium without losing the flavor just by mixing with the aqueous medium. Can be dispersed well. Therefore, for example, by using the oil-and-fat-containing emulsion composition according to the present embodiment in a liquid oil-in-water emulsion food or drink that is difficult to emulsify the fat-soluble component, the fat-soluble component is well dispersed in the aqueous medium together with the fat and oil. be able to.

脂溶性成分は、本実施形態に係る油脂含有乳化組成物100質量部に対して1質量部以上含まれることが好ましく、5〜50質量部含まれることがより好ましい。   The fat-soluble component is preferably contained in an amount of 1 part by mass or more, more preferably 5 to 50 parts by mass, with respect to 100 parts by mass of the fat-and-oil-containing emulsion composition according to this embodiment.

脂溶性成分としては、例えば、トコフェロール類等の脂溶性抗酸化剤、ビタミンA、ビタミンD、ビタミンE、ビタミンK等の脂溶性ビタミン、α−カロチン、β−カロチン、アスタキサンチン、リコピン、ルテイン等のカロチノイド、エイコサペンタエン酸、ドコサヘキサエン酸、アラキドン酸、コエンザイムQ10、ポリフェノール類、ステロール類、ステロールエステル類、ハーブ類等の脂溶性抽出物、脂溶性香料、脂溶性着色料等が挙げられる。   Examples of the fat-soluble component include fat-soluble antioxidants such as tocopherols, fat-soluble vitamins such as vitamin A, vitamin D, vitamin E and vitamin K, α-carotene, β-carotene, astaxanthin, lycopene, lutein and the like. Examples include carotenoids, eicosapentaenoic acid, docosahexaenoic acid, arachidonic acid, coenzyme Q10, fat-soluble extracts such as polyphenols, sterols, sterol esters, herbs, fat-soluble fragrances, and fat-soluble colorants.

1.2.油脂含有乳化組成物の製造
本実施形態に係る油脂含有乳化組成物は、特定成分及び多価アルコールを含む混合液と油脂とを50℃以上で乳化処理することにより製造することができる。
1.2. Manufacture of fat-and-oil-containing emulsion composition The fat-and-oil-containing emulsion composition which concerns on this embodiment can be manufactured by emulsifying the liquid mixture and fat containing a specific component and a polyhydric alcohol at 50 degreeC or more.

本実施形態に係る油脂含有乳化組成物の製造においては、まず、上述の特定成分及び多価アルコールを攪拌混合して混合液を製造する。攪拌混合に用いる装置は、特に制限は無く、攪拌タンクやミキサー等の他、ホモミキサー、コロイドミル、高圧ホモゲナイザー等の均質機を用い、全体が均一になるまで行うとよい。なお、後述のように、本発明においては、加温した状態で前記混合液と油脂を乳化処理するが、前記特定成分と多価アルコールとを混合して混合液を得る前に、特定成分のみを加温して蛋白成分等を熱変性させてしまうと乳化物が得られなくなる。したがって、混合に用いる前記特定成分及び多価アルコールは、品温が蛋白成分の熱変性温度以下、好ましくは60℃以下、より好ましくは50℃以下としておくことが好ましい。   In the production of the oil and fat-containing emulsion composition according to this embodiment, first, the above-mentioned specific component and polyhydric alcohol are stirred and mixed to produce a mixed solution. The apparatus used for stirring and mixing is not particularly limited, and it is preferable to use a homogenizer such as a homomixer, a colloid mill, and a high-pressure homogenizer in addition to a stirring tank and a mixer until the whole becomes uniform. As will be described later, in the present invention, the mixed solution and the fats and oils are emulsified in a heated state, but only the specific component is obtained before mixing the specific component and the polyhydric alcohol to obtain a mixed solution. If the protein component and the like are heat denatured by heating, an emulsion cannot be obtained. Therefore, it is preferable that the specific component and polyhydric alcohol used for mixing have a product temperature not higher than the heat denaturation temperature of the protein component, preferably not higher than 60 ° C, more preferably not higher than 50 ° C.

上記混合液における特定成分及び多価アルコールの混合比率は、固形分換算で特定成分100質量部に対して多価アルコールが好ましくは1質量部以上、より好ましくは10質量部以上である。上記混合液における特定成分及び多価アルコールの混合比率は、特定成分に対する多価アルコールの混合比率が1質量部未満であると、加温により蛋白成分等が変性して乳化物が得られないとなる場合がある。また、上記混合液における特定成分及び多価アルコールの混合比率は、固形分換算で特定成分100質量部に対して多価アルコールは通常1〜1000質量部、好ましくは10〜500質量部である。   The mixing ratio of the specific component and the polyhydric alcohol in the mixed solution is preferably 1 part by mass or more, and more preferably 10 parts by mass or more with respect to 100 parts by mass of the specific component in terms of solid content. When the mixing ratio of the specific component and the polyhydric alcohol in the mixed solution is less than 1 part by mass of the polyhydric alcohol with respect to the specific component, the protein component or the like is denatured by heating and an emulsion cannot be obtained. There is a case. Moreover, the mixing ratio of the specific component and the polyhydric alcohol in the mixed solution is usually 1 to 1000 parts by mass, preferably 10 to 500 parts by mass with respect to 100 parts by mass of the specific component in terms of solid content.

特に、特定成分が卵黄である場合、上記混合液における卵黄及び多価アルコールの混合比率は、卵黄に対する多価アルコールの混合比率が1質量部未満であると、後述するように、加温した状態で油脂と乳化処理する際に卵黄が熱変性する場合がある。したがって、前記混合液の卵黄及び多価アルコールの混合比率は、加温する温度にもよるが、固形分換算で卵黄100質量部に対して多価アルコールが好ましくは1質量部以上、より好ましくは10質量部以上である。   In particular, when the specific component is egg yolk, the mixture ratio of the egg yolk and the polyhydric alcohol in the mixed solution is a heated state as will be described later when the mixture ratio of the polyhydric alcohol to the egg yolk is less than 1 part by mass. The egg yolk may be heat denatured when emulsified with oil. Accordingly, the mixing ratio of egg yolk and polyhydric alcohol in the mixed solution depends on the temperature to be heated, but the polyhydric alcohol is preferably 1 part by mass or more, more preferably 100 parts by mass in terms of solid content. It is 10 parts by mass or more.

また、前記混合液の水分含量は、該混合液の0.1質量%未満または70質量%以上であると、油脂と乳化して透明感のある油脂含有乳化組成物が得られ難いことから、前記混合液の水分含量は、好ましくは0.1〜70質量%であり、より好ましくは1〜50質量%である。前記混合液の水分含量が0.1〜70質量%となるように水分含量を調整するには、用いる卵黄や多価アルコールの水分含量を調製したり、清水を加えたりすればよい。   In addition, since the water content of the mixed solution is less than 0.1% by mass or 70% by mass or more of the mixed solution, it is difficult to obtain a fat-containing emulsion composition that is emulsified with fats and oils and is transparent. The water content of the mixed solution is preferably 0.1 to 70% by mass, more preferably 1 to 50% by mass. In order to adjust the water content so that the water content of the mixed solution becomes 0.1 to 70% by mass, the water content of the egg yolk or polyhydric alcohol to be used may be prepared or fresh water may be added.

次に、前記混合液に油脂を叙々に加えて乳化処理し、前記混合液中に油脂を融解又は分散させて略均一に混合された状態となるようにすればよいが、本実施形態に係る油脂含有乳化組成物の製造においては、当該乳化処理を好ましくは50℃以上(例えば50〜95℃)、より好ましくは60℃以上、更に好ましくは70℃以上(例えば70〜90℃)で行う。このように加温した状態で乳化処理することにより、透明感のある油脂含有乳化組成物が得られる。なお、温度が高すぎると卵黄が熱変性し易いことから、前記乳化処理は、好ましくは95℃以下、より好ましくは90℃以下で行うことが好ましい。   Next, oil and fat are added to the mixed solution and emulsified, and the fat and oil are melted or dispersed in the mixed solution so as to be in a substantially uniform state. In the production of the oil / fat-containing emulsion composition, the emulsification treatment is preferably performed at 50 ° C. or higher (for example, 50 to 95 ° C.), more preferably 60 ° C. or higher, and further preferably 70 ° C. or higher (for example, 70 to 90 ° C.). By emulsifying in such a heated state, a transparent oil-containing emulsion composition can be obtained. In addition, since the egg yolk is easily heat-denatured when the temperature is too high, the emulsification treatment is preferably performed at 95 ° C. or less, more preferably 90 ° C. or less.

加温した状態で乳化処理する方法は、特に制限は無く、例えば、常法により、加温装置を有するジャケット付きタンク等に入れた状態でホモミキサー、コロイドミル、高圧ホモゲナイザー等の均質機を用いて、あるいは、予め加温した前記混合液と油脂とをこれら均質機を用いて乳化処理すればよい。   There is no particular limitation on the method of emulsification treatment in a heated state. For example, using a homogenizer such as a homomixer, a colloid mill, or a high-pressure homogenizer in a conventional manner with a jacketed tank having a heating device. Alternatively, the premixed mixture and fats and oils may be emulsified using these homogenizers.

以上のように加温した状態で乳化処理した後、冷却装置の付いた配管に流す等して冷却することにより、本実施形態に係る油脂含有乳化組成物が得られる。   After the emulsification treatment in the heated state as described above, the oil-containing emulsion composition according to the present embodiment is obtained by cooling by, for example, flowing through a pipe with a cooling device.

本実施形態に係る油脂含有乳化組成物の製造方法によれば、特定成分及び多価アルコールを含む混合液と油脂とを50℃以上で乳化処理することにより、得られる油脂含有乳化組成物に煮えが生じることなく、透明度が高くかつ風味が良好な油脂含有乳化組成物を得ることができる。   According to the method for producing an oil-containing emulsion composition according to the present embodiment, the oil-containing emulsion composition obtained by emulsifying the mixture and fat containing the specific component and the polyhydric alcohol at 50 ° C. or higher is boiled. The oil-and-fat-containing emulsion composition having high transparency and good flavor can be obtained.

また、本実施形態に係る油脂含有乳化組成物の製造においては、特定成分及び多価アルコールを含む混合液と油脂とを乳化処理する際の温度を調整することにより、得られる油脂含有乳化組成物の透明度を調整することができる。すなわち、特定成分及び多価アルコールを含む混合液と油脂とを所定の温度にて乳化処理することにより、所望の透明度を有する油脂含有乳化組成物を得ることができる。   Moreover, in the manufacture of the fat-and-oil-containing emulsion composition according to this embodiment, the oil-and-fat-containing emulsion composition obtained by adjusting the temperature at the time of emulsifying the mixture and the fat and oil containing the specific component and the polyhydric alcohol. The transparency of can be adjusted. That is, an oil-containing emulsion composition having a desired transparency can be obtained by emulsifying a mixed solution containing the specific component and the polyhydric alcohol and the oil at a predetermined temperature.

なお、本実施形態に係る油脂含有乳化組成物には、本発明の効果を損なわない範囲で上述の原料以外の各種原料を適宜選択し含有させることができる。例えば、グルタミン酸ナトリウム、食塩、砂糖、醤油、味噌等の各種調味料、キサンタンガム、タマリンドシードガム、ジェランガム、アラビアガム、馬鈴薯澱粉、トウモロコシ澱粉、うるち米澱粉、小麦澱粉、タピオカ澱粉、ワキシコーンスターチ、もち米澱粉等の澱粉、湿熱処理澱粉、化工澱粉等の増粘材、アスコルビン酸又はその塩、ビタミンE等の酸化防止剤、色素、香辛料等が挙げられる。   In addition, the oil-and-fat containing emulsion composition which concerns on this embodiment can select and contain suitably various raw materials other than the above-mentioned raw material in the range which does not impair the effect of this invention. For example, various flavorings such as sodium glutamate, salt, sugar, soy sauce, miso, xanthan gum, tamarind seed gum, gellan gum, gum arabic, potato starch, corn starch, glutinous rice starch, wheat starch, tapioca starch, waxy corn starch, sticky rice Examples thereof include starches such as starches, thickeners such as wet heat-treated starches and modified starches, ascorbic acid or salts thereof, antioxidants such as vitamin E, pigments, spices and the like.

1.3.油脂含有乳化組成物を含有する食品
本実施形態に係る油脂含有乳化組成物は、透明感を有することから、種々の食品に用いることで、白濁した白い色調の一般的な乳化組成物を用いた場合に比べて、当該食品の外観(例えば色調)が保持された好ましい外観の食品を得ることができる。したがって、本実施形態に係る油脂含有乳化組成物は例えば、食品の外観を改善するために使用することができる。しかも、風味がよいことから、一般的な乳化組成物を用いた場合と同様の好ましい風味が得られる。
1.3. Food containing oil-containing emulsion composition The oil-containing emulsion composition according to this embodiment has a transparent feeling, and therefore, when used for various foods, a general emulsified composition with a cloudy white color tone was used. Compared to the case, it is possible to obtain a food product having a preferable appearance while maintaining the appearance (for example, color tone) of the food product. Therefore, the oil-containing emulsion composition according to this embodiment can be used, for example, to improve the appearance of food. And since the flavor is good, the same preferable flavor as the case where a general emulsion composition is used is obtained.

本実施形態に係る油脂含有乳化組成物を含有する食品としては、特に制限はないが、例えば、ポテトサラダ、タマゴサラダ等のサラダ、調理ソース、スープ等のソース類等の調理食品が挙げられる。更に、乳化組成物をコク味付与等の品質改良剤として用いる魚肉加工食品や畜肉加工食品等が挙げられる。また、本実施形態に係る油脂含有乳化組成物は例えば、食品の色彩を映えさせるために使用することができる。なお、前記食品中における油脂含有乳化組成物の含有量は通常1質量%以上であり、3〜98質量%であることが好ましい。   Although there is no restriction | limiting in particular as foodstuff containing the fat-and-oil containing emulsion composition which concerns on this embodiment, For example, cooked foods, such as salads, such as potato salad and egg salad, cooking sauces, sauces, such as soup. Furthermore, processed fish food, livestock meat processed food, etc. which use an emulsified composition as quality improvement agents, such as richness imparting, are mentioned. Moreover, the oil-and-fat containing emulsion composition which concerns on this embodiment can be used in order to make the color of foodstuffs reflect, for example. In addition, content of the fat-and-oil containing emulsion composition in the said foodstuff is 1 mass% or more normally, and it is preferable that it is 3-98 mass%.

1.4.水中油型乳化飲食品
1.4.1.構成成分および具体例
本発明の一実施形態は、水系媒体中での分散性に優れた本実施形態に係る油脂含有乳化組成物が配合され、前記油脂含有乳化組成物の油脂が油滴として分散している水中油型乳化飲食品である。
1.4. Oil-in-water emulsified food and drink 1.4.1. Constituent Components and Specific Examples In one embodiment of the present invention, an oil-containing emulsion composition according to this embodiment having excellent dispersibility in an aqueous medium is blended, and the oil and fat of the oil-containing emulsion composition is dispersed as oil droplets. It is an oil-in-water emulsified food and drink.

本実施形態に係る水中油型乳化飲食品に配合する油脂含有乳化組成物は、脂溶性成分を含有するものであってもよい。脂溶性成分を含有する本実施形態に係る油脂含有乳化組成物を水系媒体と混合させると、風味を損なわずに、脂溶性成分を含む油脂を水中油型の油滴として、水系媒体中に容易に分散させることができるため、油脂の分散性に優れた飲食品を得ることができる。   The fat-and-oil-containing emulsion composition to be blended in the oil-in-water type emulsion food or drink according to the present embodiment may contain a fat-soluble component. When the fat-and-oil-containing emulsion composition according to this embodiment containing a fat-soluble component is mixed with an aqueous medium, the fat and oil containing the fat-soluble component is easily added to the aqueous medium as oil-in-water oil droplets without losing the flavor. Therefore, it is possible to obtain a food or drink excellent in dispersibility of fats and oils.

本実施形態に係る水中油型乳化飲食品に含まれる食品としては、特に制限はないが、例えば、マヨネーズやサラダクリーム等の半固体状ドレッシング、サウザンドレッシングやフレンチドレッシング等の乳化液状ドレッシング、中華ドレッシング等の分離液状ドレッシング、青じそドレッシング等のノンオイルドレッシング、カルボナーラソース、デミグラスソース等のソース類、コーンスープ、コンソメスープ、ラーメンスープ、味噌汁等のスープ類、カスタードクリーム、オムレツ、茶碗蒸し、プリン等の卵加工食品、アイスクリーム、ソフトクリーム、アイスキャンディー等の冷菓、ゼリー、ババロアおよびヨーグルト等のデザート類、煮物等の惣菜類、おかゆ等が挙げられる。   The food contained in the oil-in-water emulsified food and drink according to the present embodiment is not particularly limited. For example, semi-solid dressings such as mayonnaise and salad cream, emulsified liquid dressings such as Southern dressing and French dressing, and Chinese dressings Non-oil dressings such as liquid dressings such as Aojiso dressing, sauces such as carbonara sauce, demiglace sauce, soups such as corn soup, consommé soup, ramen soup, miso soup, custard cream, omelet, steamed egg custard, pudding, etc. , Frozen desserts such as ice cream, soft cream and ice candy, desserts such as jelly, bavaroa and yogurt, side dishes such as boiled foods, and porridge.

また、本実施形態に係る水中油型乳化飲食品に含まれる飲料としては、特に制限はないが、例えば、オレンジジュース等の果汁飲料もしくは果肉飲料、トマトジュース等の野菜ジュース、コーラ等の清涼飲料、緑茶、ウーロン茶、麦茶、紅茶等の茶飲料、牛乳等の乳飲料、乳酸菌飲料、豆乳飲料、コーヒー飲料、ワイン等のアルコール飲料、栄養ドリンク、スポーツ飲料、高栄養濃厚流動食等の経口流動食等が挙げられる。   In addition, the beverage contained in the oil-in-water emulsified food and drink according to the present embodiment is not particularly limited. For example, fruit juice beverages such as orange juice or fruit beverages, vegetable juices such as tomato juice, and soft drinks such as cola. , Green tea, oolong tea, barley tea, tea drinks such as tea, milk drinks such as milk, lactic acid bacteria drinks, soy milk drinks, coffee drinks, wine drinks and other alcoholic drinks, nutrition drinks, sports drinks, high nutrition concentrated liquid foods, etc. Etc.

1.4.2.作用効果
本実施形態に係る水中油型乳化飲食品の作用効果について述べる前に、一般的な水中油型乳化飲食品について説明する。
1.4.2. Effects Before describing the effects of the oil-in-water emulsified food and drink according to this embodiment, a general oil-in-water emulsified food and drink will be described.

(i)一般的な水中油型乳化飲食品
水中油型乳化飲食品を製造するにあたり、油性成分を水系媒体中に分散させる一般的な方法としては、水系媒体および油性成分に乳化材を加えて撹拌混合して乳化させる方法が一般的である。この方法は、例えば、卵黄を乳化材として用いたマヨネーズ等のように食品製造の方法として広く行われているが、油滴が微粒子状に分散した安定した乳化状態とするためには、ホモミキサー等の大掛かりな乳化設備が必要となる。
(I) General oil-in-water emulsified food and drink In producing an oil-in-water emulsified food and drink, a general method for dispersing an oily component in an aqueous medium is to add an emulsifying material to the aqueous medium and the oily component. A method of stirring and mixing to emulsify is common. This method is widely used as a food production method such as mayonnaise using egg yolk as an emulsifying material. However, in order to achieve a stable emulsified state in which oil droplets are dispersed in fine particles, a homomixer is used. Such a large-scale emulsification facility is required.

その他の方法としては、乳化剤を含む多価アルコール中に油相を可溶化、あるいは、微粒子状に分散させて、いわゆる多価アルコール中油型乳化組成物を調製し、これを更に水と混合することにより、水中油型の乳化物を得る方法が知られている。この方法としては、例えば、特公昭63−61050号公報には、平均重合度が3以上のポリグリセリンと炭素数8以上の脂肪酸とのエステルであって、HLB9以上の親水性ポリグリセリン高級脂肪酸エステルを乳化剤とした多価アルコール中油型乳化組成物が、特開昭62−95132号公報には、リゾレシチンを乳化剤として用いた多価アルコール中油型乳化組成物が提案されている。また、特開2000−102356号公報には、D相乳化物を含有する鶏卵を用いた水中油型の乳化組成物、つまり、リゾレシチンやモノステアリン酸デカグリセリン等の界面活性剤と糖アルコールまたは液糖の混合液であるD相組成物に油脂を混合したD相乳化組成物を含有する鶏卵が提案されている。   Another method is to solubilize or disperse the oil phase in a polyhydric alcohol containing an emulsifier to prepare a so-called polyhydric alcohol-in-oil emulsion composition, which is further mixed with water. Thus, a method for obtaining an oil-in-water emulsion is known. As this method, for example, Japanese Patent Publication No. 63-61050 discloses an ester of a polyglycerin having an average degree of polymerization of 3 or more and a fatty acid having 8 or more carbon atoms and a hydrophilic polyglycerin higher fatty acid ester having an HLB of 9 or more. A polyhydric alcohol-in-oil emulsified composition using lysolecithin as an emulsifier is proposed in JP-A-62-95132. Japanese Patent Application Laid-Open No. 2000-102356 discloses an oil-in-water emulsion composition using eggs containing a D-phase emulsion, that is, a surfactant such as lysolecithin or decaglycerin monostearate and a sugar alcohol or liquid. Chicken eggs containing a D-phase emulsified composition obtained by mixing fats and oils with a D-phase composition that is a mixed solution of sugars have been proposed.

これら提案の方法によれば、大掛かりな乳化設備を使用することなく油滴が微粒子状に分散した水中油型乳化物が得られるものの、使用する乳化剤の種類に制約があり、風味が劣るという問題があった。また、コストや安全性の点からは、できるだけ加工工程の少ない食品素材を原料とした製品であることが望まれる。   According to these proposed methods, an oil-in-water emulsion in which oil droplets are dispersed in fine particles can be obtained without using a large-scale emulsification facility, but the type of emulsifier used is limited and the flavor is poor. was there. Further, from the viewpoint of cost and safety, it is desired that the product is made from a food material with as few processing steps as possible.

(ii)本実施形態に係る水中油型乳化飲食品
これに対して、本実施形態に係る水中油型乳化飲食品によれば、本実施形態に係る油脂含有乳化組成物が配合され、前記油脂含有乳化組成物の油脂が油滴として水系媒体中に分散していることにより、良好な風味を有し、かつ、油脂の分散性に優れている。すなわち、本実施形態に係る水中油型乳化飲食品を製造する際に、大掛かりな乳化設備を使用することなく、本実施形態に係る油脂含有乳化組成物と水系媒体とを混合するだけで、油性成分を水系媒体中に微粒子状に容易に分散させることができる。
(Ii) Oil-in-water emulsified food / drink according to the present embodiment On the other hand, according to the oil-in-water emulsified food / beverage according to the present embodiment, the oil-containing emulsion composition according to the present embodiment is blended, Since the fats and oils of the emulsified composition are dispersed as oil droplets in the aqueous medium, it has a good flavor and is excellent in fat and oil dispersibility. That is, when the oil-in-water type emulsion food and drink according to the present embodiment is produced, the oil-containing emulsion composition and the aqueous medium according to the present embodiment are simply mixed without using a large-scale emulsification facility. The components can be easily dispersed in fine particles in an aqueous medium.

しかも、本実施形態に係る水中油型乳化飲食品は、乳化材として特定成分を含む本実施形態に係る油脂含有乳化組成物が配合されているため、風味を損なうことなく油性成分を水系媒体中に微粒子状に分散できる。   And since the oil-in-water type emulsion food / beverage products which concern on this embodiment are mix | blended with the fat-containing emulsion composition which concerns on this embodiment containing a specific component as an emulsifier, an oil-based component is contained in an aqueous medium, without impairing flavor. Can be dispersed in the form of fine particles.

また、本実施形態に係る水中油型乳化飲食品は、脂溶性成分を含む液状の水中油型乳化飲食品であることができる。一般に、水中油型乳化飲食品が脂溶性成分を含む液状の水中油型乳化飲食品である場合、脂溶性成分が乳化しにくい。これに対して、本実施形態に係る水中油型乳化飲食品は油脂の分散性に優れているため、液状の水中油型乳化飲食品であっても、乳化しにくい脂溶性成分を油脂とともに水系媒体中に良好に分散させることができる。   Moreover, the oil-in-water type emulsion food / beverage products which concern on this embodiment can be a liquid oil-in-water type emulsion food / beverage product containing a fat-soluble component. Generally, when the oil-in-water type emulsion food or drink is a liquid oil-in-water type emulsion food or drink containing a fat-soluble component, the fat-soluble component is difficult to emulsify. On the other hand, since the oil-in-water type emulsion food / beverage products which concern on this embodiment are excellent in the dispersibility of fats and oils, even if it is a liquid oil-in-water type emulsion food / beverage products, the fat-soluble component which is hard to emulsify is water-based with fats and oils It can be dispersed well in the medium.

更に、従来の特殊な乳化剤を使用する方法に比べて、加工工程の少ない蛋白質をそのまま乳化材として使用できることから、コストや安全性の点からも好ましい。   Furthermore, compared to the conventional method using a special emulsifier, a protein with fewer processing steps can be used as it is as an emulsifier, which is preferable from the viewpoint of cost and safety.

このように、本実施形態に係る水中油型乳化飲食品によれば、風味や設備等の点から制約の少ない新たな油性成分の水系媒体への分散状態を達成できる。   Thus, according to the oil-in-water type emulsion food / beverage products which concern on this embodiment, the dispersion state to the aqueous medium of the new oil-based component with few restrictions from points, such as flavor and equipment, can be achieved.

2.実施例
以下、実施例によって本発明を更に詳細に説明するが、本発明は実施例に限定されない。
2. EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to the examples.

2.1.実施例1
まず、本実施例の油脂含有乳化組成物を製造するために、表1に示す配合原料を用意した。次に、品温30℃の液卵黄及びソルビトールを容器に入れ、TKホモミキサーで攪拌混合(速度:5000rpm)して均一に混合した。次に、この容器を70℃の恒温水槽に入れて、TKホモミキサーで更に攪拌混合しながら、目標の70℃に達するまで恒温槽で加温した。続いて、品温が70℃に達温した混合液を、TKホモミキサーで攪拌混合(速度:5000rpm)しながら、20分間かけて菜種油を少量ずつ投入し、更に、菜種油を投入後5分間、攪拌混合を続けて乳化処理して均一な状態とした。乳化処理後、耐熱性パウチに充填密封した後、5℃の冷却水槽に浸漬して冷却し、実施例1の油脂含有乳化組成物を得た。
2.1. Example 1
First, in order to produce the oil-and-fat-containing emulsion composition of this example, the blending raw materials shown in Table 1 were prepared. Next, liquid egg yolk and sorbitol having a product temperature of 30 ° C. were placed in a container, and stirred and mixed (speed: 5000 rpm) with a TK homomixer to mix uniformly. Next, this container was put into a constant temperature water bath at 70 ° C., and further heated with a constant temperature bath until reaching the target 70 ° C. while further stirring and mixing with a TK homomixer. Subsequently, rapeseed oil was added little by little over 20 minutes while stirring and mixing (speed: 5000 rpm) with the TK homomixer, and the mixed liquid whose product temperature reached 70 ° C., and further 5 minutes after adding rapeseed oil. The stirring and mixing were continued and the mixture was emulsified to obtain a uniform state. After the emulsification treatment, the heat-resistant pouch was filled and sealed, then immersed in a cooling water bath at 5 ° C. and cooled to obtain the oil-containing emulsion composition of Example 1.

得られた油脂含有乳化組成物は透明感のある外観であった。また、得られた油脂含有乳化組成物を厚さ5mmの石英セルに入れ、清水を対照として濁度測定器(型名「WA 2000N」、日本電色工業(株)製)を用いて測定された全光線透過率は62.2%であった。   The obtained oil / fat-containing emulsion composition had a transparent appearance. Further, the obtained fat-and-oil-containing emulsion composition was put into a 5 mm thick quartz cell and measured using a turbidity measuring device (model name “WA 2000N”, manufactured by Nippon Denshoku Industries Co., Ltd.) with fresh water as a control. The total light transmittance was 62.2%.

Figure 0005000463
Figure 0005000463

2.2.試験例1
実施例1において乳化処理する際の加温温度を表2に示す温度に変えた他は、実施例1と同様にして試験例1の油脂含有乳化組成物を得た。そして、それぞれ得られた油脂含有乳化組成物について、実施例1と同様にして全光線透過率を測定した。また、それぞれ得られた油脂含有乳化組成物の外観を目視にて評価した。結果を下記表2に示す。表2によれば、乳化処理時の温度が高いほど透明度が高くなること、並びに、50℃以上で乳化処理を行うことにより、積分球式光電光度法を用いた濁度測定により得られた全光線透過率が40%以上である油脂含有乳化組成物が得られることが確認された。また、乳化処理する際の温度を調整することにより、所望の透明度を有する油脂含有乳化組成物を得られることが確認された。
2.2. Test example 1
The oil-containing emulsion composition of Test Example 1 was obtained in the same manner as in Example 1 except that the heating temperature at the time of emulsification treatment in Example 1 was changed to the temperature shown in Table 2. And about the obtained oil-and-fat containing emulsion composition, it carried out similarly to Example 1, and measured the total light transmittance. Moreover, the external appearance of each obtained fat-and-oil-containing emulsion composition was evaluated visually. The results are shown in Table 2 below. According to Table 2, the higher the temperature at the time of the emulsification treatment, the higher the transparency, and the emulsification treatment at 50 ° C. or higher gave the total obtained by turbidity measurement using an integrating sphere photoelectric photometry method. It was confirmed that an oil-containing emulsion composition having a light transmittance of 40% or more can be obtained. Moreover, it was confirmed that the fat and oil-containing emulsion composition which has desired transparency can be obtained by adjusting the temperature at the time of emulsification.

Figure 0005000463
Figure 0005000463

2.3.比較例1
実施例1において、液卵黄に代えてリゾレシチン0.5質量%を用い、その減少分はソルビトールの配合量を増やして補正した他は実施例1と同様にして、比較例1の油脂含有乳化組成物を得た。
2.3. Comparative Example 1
In Example 1, the fat-containing emulsion composition of Comparative Example 1 was used in the same manner as in Example 1 except that 0.5% by mass of lysolecithin was used instead of liquid egg yolk, and the decrease was corrected by increasing the blending amount of sorbitol. I got a thing.

2.4.試験例2
実施例1及び比較例1で得られた油脂含有乳化組成物を食して風味を評価した。結果を下記表3に示す。表3によれば、液卵黄を用いた場合(実施例1)、風味が良好であるのに対して、リゾレシチンを用いた場合(比較例1)、風味が劣ることがわかる。
2.4. Test example 2
The fat and oil-containing emulsion composition obtained in Example 1 and Comparative Example 1 was eaten to evaluate the flavor. The results are shown in Table 3 below. According to Table 3, when liquid egg yolk is used (Example 1), the flavor is good, whereas when lysolecithin is used (Comparative Example 1), the flavor is poor.

Figure 0005000463
Figure 0005000463

2.5.実施例2
実施例1において、特定成分として液卵黄の代わりに下記表4に示す成分を配合した他は実施例1と同様にして、油脂含有乳化組成物を得た。この際、各成分の配合量は、固形分換算で実施例1と同じになるようにし、これによる増減は、ソルビトールの配合量を調整した。また、それぞれ得られた油脂含有乳化組成物について、目視による外観の評価及び風味の評価を行った。結果を下記表4に示す。
2.5. Example 2
In Example 1, an oil-containing emulsion composition was obtained in the same manner as in Example 1 except that the components shown in Table 4 below were blended in place of liquid egg yolk as the specific component. Under the present circumstances, the compounding quantity of each component was made to become the same as Example 1 in conversion of solid content, and the increase / decrease by this adjusted the compounding quantity of sorbitol. Moreover, about the obtained oil-and-fat containing emulsion composition, visual appearance evaluation and flavor evaluation were performed. The results are shown in Table 4 below.

さらに、それぞれ得られた油脂含有乳化組成物について、乳化処理する際の加温温度を80℃にした以外は実施例1と同様の方法にて、全光線透過率、目視による外観の評価及び風味の評価を行った。その結果を表4に併せて示す。   Furthermore, with respect to each of the obtained fat-containing emulsion compositions, the total light transmittance, visual appearance evaluation and flavor were the same as in Example 1 except that the heating temperature during emulsification was 80 ° C. Was evaluated. The results are also shown in Table 4.

Figure 0005000463
Figure 0005000463

表4の結果から、実施例2によれば、特定成分(卵黄、卵白、動物性蛋白)及び多価アルコールを含む混合液と油脂とを50℃以上で乳化処理することにより、透明感を有し、良好な風味を有する油脂含有乳化組成物を得ることができることが理解できる。   From the results of Table 4, according to Example 2, the mixture and fats and oils containing specific components (egg yolk, egg white, animal protein) and polyhydric alcohol were emulsified at 50 ° C. or higher, so that there was transparency. It can be understood that an oil-containing emulsion composition having a good flavor can be obtained.

一方、大豆蛋白(比較例2)や小麦蛋白(比較例3)等の植物性蛋白及び多価アルコールを含む混合液と油脂とを50℃以上で乳化処理を行った場合、得られる油脂含有乳化組成物の透明感が低いことがわかる。   On the other hand, when a mixed solution containing vegetable protein such as soybean protein (Comparative Example 2) and wheat protein (Comparative Example 3) and a polyhydric alcohol is subjected to an emulsification treatment at 50 ° C. or higher, the resulting fat-containing emulsion It can be seen that the transparency of the composition is low.

また、実施例2の油脂含有乳化組成物は、特定成分を含み、積分球式光電光度法を用いた濁度測定により得られた全光線透過率が40%以上であるため、透明感を有し、良好な風味を有することが理解できる。また、表4に示される特定成分のうち、高い透明感を有する点から、卵黄及び動物性蛋白が好ましいことがわかり、良好な風味を有する点から、卵黄および乳蛋白が好ましいことがわかる。特に卵黄はコクがあって大変好ましい風味であった。   In addition, the oil-and-fat-containing emulsion composition of Example 2 contains a specific component and has a translucency because the total light transmittance obtained by turbidity measurement using an integrating sphere photoelectric photometry is 40% or more. It can be understood that it has a good flavor. Moreover, it turns out that egg yolk and animal protein are preferable from the point which has a high transparency among the specific components shown by Table 4, and it turns out that egg yolk and milk protein are preferable from the point which has favorable flavor. In particular, egg yolk was rich and very favorable.

2.6.実施例3
実施例1において、ソルビトールに代えてグリセリンを用いた他は実施例1と同様にして、実施例3の油脂含有乳化組成物を得た。実施例3の油脂含有乳化組成物について、実施例1と同様の方法にて全光線透過率を測定した。
2.6. Example 3
In Example 1, the fat and oil-containing emulsion composition of Example 3 was obtained in the same manner as in Example 1 except that glycerin was used instead of sorbitol. About the fat-and-oil containing emulsion composition of Example 3, the total light transmittance was measured by the method similar to Example 1. FIG.

その結果、実施例3の油脂含有乳化組成物の全光線透過率は54.1%であり、透明感のある外観であった。   As a result, the total light transmittance of the oil-and-fat-containing emulsion composition of Example 3 was 54.1%, which was a transparent appearance.

2.7.実施例4
下記表5に示す配合の原料を用いた他は実施例1と同様にして、実施例4のマヨネーズ風味の油脂含有乳化組成物を得た。つまり、まず、液卵黄、ソルビトール、食酢、グルタミン酸ナトリウム、からし粉及び食塩を容器に入れ、TKホモミキサーで攪拌混合(速度:5000rpm)して均一に混合し、これを実施例1と同様にして70℃に加温しながら、菜種油を加えて乳化処理して、実施例4のマヨネーズ風味の油脂含有乳化組成物を得た。実施例4の油脂含有乳化組成物について、実施例1と同様の方法にて全光線透過率を測定した。
2.7. Example 4
The mayonnaise-flavored oil-and-fat-containing emulsion composition of Example 4 was obtained in the same manner as in Example 1 except that the raw materials having the formulations shown in Table 5 below were used. That is, first of all, liquid egg yolk, sorbitol, vinegar, sodium glutamate, mustard powder and salt are put in a container and mixed with stirring and mixing (speed: 5000 rpm) with a TK homomixer. The rapeseed oil was added and emulsified with heating to 70 ° C. to obtain a mayonnaise-flavored oil-containing emulsion composition of Example 4. About the fat-and-oil containing emulsion composition of Example 4, the total light transmittance was measured by the method similar to Example 1. FIG.

その結果、実施例4のマヨネーズ風味の油脂含有乳化組成物の全光線透過率は49.6%であり、透明感のある外観であった。   As a result, the total light transmittance of the mayonnaise-flavored oil-and-fat emulsion composition of Example 4 was 49.6%, which was a transparent appearance.

Figure 0005000463
Figure 0005000463

2.8.実施例5
下記表6に示す配合により、実施例4のマヨネーズ風味の油脂含有乳化組成物と乾燥たらことを混合して、実施例5のたらこマヨネーズ風味の調理ソースを製造した。また、一般的なマヨネーズ(植物油脂70質量%、液卵黄15質量%、食酢12質量%、調味、香辛料3質量%から常法により調製したもの、全光線透過率3.9%)を用いて同様に、比較例4のたらこマヨネーズ風味の調理ソースを製造した。
2.8. Example 5
According to the formulation shown in Table 6 below, the mayonnaise-flavored oil-containing emulsion composition of Example 4 was mixed with dried dried matter to produce a cooked sauce of Example 5 flavored with taco mayonnaise. In addition, using general mayonnaise (70% by mass of vegetable oil and fat, 15% by mass of liquid egg yolk, 12% by mass of vinegar, seasoning, 3% by mass of spices, prepared by a conventional method, total light transmittance of 3.9%) Similarly, a cooked sauce with a flavor of tako mayonnaise of Comparative Example 4 was produced.

次に、実施例5および比較例4の調理ソースについて、それぞれ外観を評価し、更に、赤さの指標であるa値を測色色差計(型名「ZE 2000」、日本電色工業(株)製)を測定した。結果を下記表7に示す。   Next, the appearance of each of the cooking sauces of Example 5 and Comparative Example 4 was evaluated, and the a value that is an index of redness was determined using a colorimetric color difference meter (model name “ZE 2000”, Nippon Denshoku Industries Co., Ltd.). )). The results are shown in Table 7 below.

Figure 0005000463
Figure 0005000463

Figure 0005000463
Figure 0005000463

表7によれば、実施例4のマヨネーズ風味の油脂含有乳化組成物を用いた実施例5のたらこマヨネーズ風味の調理ソースは、一般的なマヨネーズを用いた比較例4の調理ソースに比べて、赤い色調が強く、たらこ色の鮮やかな色調であることがわかる。   According to Table 7, the cooking sauce of the taco mayonnaise flavor of Example 5 using the mayonnaise-flavored oil-fat emulsion composition of Example 4 is compared to the cooking sauce of Comparative Example 4 using a general mayonnaise, It can be seen that the red color tone is strong and the color tone is vivid.

2.9.実施例6
実施例4のマヨネーズ風味の油脂含有乳化組成物を用いて、下記表8に示す配合にて常法により実施例6のポテトサラダを製造した。また、対照として、一般的なマヨネーズ(植物油脂70質量%、液卵黄15質量%、食酢12質量%、調味、香辛料3質量%から常法により調製したもの、全光線透過率3.9%)を用いて同様に、比較例5のポテトサラダを製造した。
2.9. Example 6
Using the mayonnaise-flavored oil-and-fat-containing emulsion composition of Example 4, the potato salad of Example 6 was produced by a conventional method with the composition shown in Table 8 below. As a control, general mayonnaise (70% by weight of vegetable oil and fat, 15% by weight of liquid egg yolk, 12% by weight of vinegar, seasoning, and 3% by weight of spices prepared in a conventional manner, total light transmittance of 3.9%) Similarly, the potato salad of Comparative Example 5 was produced.

その結果、実施例4のマヨネーズ風味の油脂含有乳化組成物を用いた実施例6のポテトサラダは、一般的なマヨネーズを用いた比較例5のポテトサラダに比べて、にんじん、きゅうり等の色が鮮やかで素材の色が生かされた色鮮やかな外観であった。   As a result, the potato salad of Example 6 using the mayonnaise-flavored oil-fat emulsion composition of Example 4 has colors such as carrots and cucumbers as compared to the potato salad of Comparative Example 5 using general mayonnaise. It was a vivid and colorful appearance that made use of the color of the material.

Figure 0005000463
Figure 0005000463

下記表9に示す配合の原料を用いた他は実施例1と同様にして、実施例7の卵黄油を含む油脂含有乳化組成物を得た。つまり、まず、液卵黄及びソルビトールを容器に入れ、TKホモミキサーで攪拌混合(速度:5000rpm)して均一に混合し、これを実施例1と同様にして70℃に加温しながら、予め混合した菜種油及び卵黄油を加えて乳化処理して、実施例7の卵黄油を含む油脂含有乳化組成物を得た。実施例7の油脂含有乳化組成物について、実施例1と同様の方法にて全光線透過率を測定した。   An oil-containing emulsion composition containing egg yolk oil of Example 7 was obtained in the same manner as Example 1 except that the raw materials having the formulations shown in Table 9 below were used. That is, first, liquid egg yolk and sorbitol are put in a container, and mixed by stirring and mixing (speed: 5000 rpm) with a TK homomixer, and mixed in advance while heating to 70 ° C. in the same manner as in Example 1. The rapeseed oil and egg yolk oil which were added and emulsified, and the fat-containing emulsion composition containing the egg yolk oil of Example 7 was obtained. About the fat-and-oil containing emulsion composition of Example 7, the total light transmittance was measured by the method similar to Example 1. FIG.

その結果、実施例7の卵黄油を含む油脂含有乳化組成物の全光線透過率は55.6%であり、透明感のある外観であった。   As a result, the total light transmittance of the oil-and-fat-containing emulsion composition containing egg yolk oil of Example 7 was 55.6%, which was a transparent appearance.

Figure 0005000463
Figure 0005000463

2.11.実施例8
下記表10に示す配合の原料を用いた他は実施例1と同様にして、実施例8の脂溶性成分(エイコサペンタエン酸)を含む油脂含有乳化組成物を得た。つまり、まず、液卵黄及びソルビトールを容器に入れ、TKホモミキサーで攪拌混合(速度:5000rpm)して均一に混合し、これを実施例1と同様にして70℃に加温しながら、予め混合した菜種油及びエイコサペンタエン酸を加えて乳化処理して、実施例8のエイコサペンタエン酸を含む油脂含有乳化組成物を得た。実施例8の油脂含有乳化組成物について、実施例1と同様の方法にて全光線透過率を測定した。
2.11. Example 8
An oil-containing emulsion composition containing the fat-soluble component (eicosapentaenoic acid) of Example 8 was obtained in the same manner as in Example 1 except that the raw materials having the formulations shown in Table 10 below were used. That is, first, liquid egg yolk and sorbitol are put in a container, and mixed by stirring and mixing (speed: 5000 rpm) with a TK homomixer, and mixed in advance while heating to 70 ° C. in the same manner as in Example 1. The rapeseed oil and eicosapentaenoic acid were added and emulsified to obtain an oil-containing emulsion composition containing eicosapentaenoic acid of Example 8. About the fat-and-oil containing emulsion composition of Example 8, the total light transmittance was measured by the method similar to Example 1. FIG.

その結果、実施例8のエイコサペンタエン酸を含む油脂含有乳化組成物の全光線透過率は52.6%であり、透明感のある外観であった。   As a result, the total light transmittance of the oil-containing emulsion composition containing eicosapentaenoic acid of Example 8 was 52.6%, which was a transparent appearance.

Figure 0005000463
Figure 0005000463

2.12.実施例9
実施例1の油脂含有乳化組成物を用いて、下記表11に示す配合にて実施例9の水中油型乳化飲食品(コールスロー風乳化ドレッシング)を製造した。つまり、まず、清水、食酢、グルタミン酸ナトリウム及び食塩をボールに入れ、スプーンで撹拌して均一に混合した後、これに油脂含有乳化組成物を加えて更に撹拌して、実施例9のコールスロー風乳化ドレッシングを得た。
2.12. Example 9
Using the oil and fat-containing emulsion composition of Example 1, the oil-in-water type emulsion food / beverage product (Cole Slow-style emulsion dressing) of Example 9 was produced with the formulation shown in Table 11 below. That is, first, fresh water, vinegar, sodium glutamate and sodium chloride were placed in a bowl, stirred with a spoon and mixed uniformly, and then the oil and fat-containing emulsion composition was added and further stirred to obtain the Coleslaw-style emulsification of Example 9. Got dressing.

得られた実施例9のコールスロー風乳化ドレッシングは、油滴が微粒子状に分散して白濁した乳化物となった。   The obtained Coleslaw-style emulsified dressing of Example 9 became an emulsion in which oil droplets were dispersed in the form of fine particles and became cloudy.

Figure 0005000463
Figure 0005000463

2.13.実施例10
実施例7の卵黄油を含む油脂含有乳化組成物を用いて、下記表12に示す配合にて実施例10の水中油型乳化飲食品(中華風スープ)を製造した。つまり、まず、清水、鶏がらスープの素(粉末品)及び食塩を鍋に入れ、加熱しながらおたまで均一に混合して品温80℃とした後、これに油脂含有乳化組成物を加えて更に撹拌して、実施例10の中華風スープを得た。
2.13. Example 10
Using the fat and oil-containing emulsion composition containing egg yolk oil of Example 7, the oil-in-water type emulsion food and drink (Chinese-style soup) of Example 10 was produced with the formulation shown in Table 12 below. That is, first, after putting fresh water, raw chicken broth soup (powdered product) and salt into a pan and uniformly mixing them with the heat up to the product temperature of 80 ° C., the fat and oil-containing emulsion composition is added to this. The mixture was further stirred to obtain a Chinese-style soup of Example 10.

得られた実施例10の中華風スープは、油滴が微粒子状に分散しており油の分離は見られなかった。   In the Chinese soup obtained in Example 10, oil droplets were dispersed in the form of fine particles, and no oil separation was observed.

Figure 0005000463
Figure 0005000463

2.14.実施例11
実施例8のエイコサペンタエン酸を含む油脂含有乳化組成物を用いて、下記表13に示す配合にて実施例11の乳酸菌飲料を製造した。つまり、ヨーグルト(ドリンクタイプ)をコップに入れ、これに油脂含有乳化組成物を加えてスプーンで撹拌して、実施例11の乳酸菌飲料を得た。
2.14. Example 11
Using the oil-containing emulsion composition containing eicosapentaenoic acid of Example 8, the lactic acid bacteria beverage of Example 11 was produced with the formulation shown in Table 13 below. That is, yoghurt (drink type) was put into a cup, an oil-containing emulsion composition was added thereto, and stirred with a spoon to obtain a lactic acid bacteria beverage of Example 11.

実施例11の乳酸菌飲料は、油滴が微粒子状に分散しており油の分離は見られなかった。   In the lactic acid bacteria beverage of Example 11, oil droplets were dispersed in the form of fine particles, and no oil separation was observed.

Figure 0005000463
Figure 0005000463

2.15.試験例3
試験例1において乳化処理温度がそれぞれ30℃及び70℃で得られた油脂含有乳化組成物について、以下の方法で清水への分散のし易さを評価した。
2.15. Test example 3
About the oil-and-fat containing emulsion composition obtained by the emulsification process temperature in Test Example 1 at 30 degreeC and 70 degreeC, respectively, the ease of dispersion | distribution to fresh water was evaluated with the following method.

つまり、100mLのビーカーに45gのイオン交換水を入れ、スターラーでゆるやかに撹拌しながら、それぞれ各5gの試料を投入し、塊状の資料が分散して見えなくなるまでの時間を測定した。更に、得られた分散液の外観を目視にて評価した。結果を下記表14に示す。   That is, 45 g of ion-exchanged water was put into a 100 mL beaker, and 5 g of each sample was added while gently stirring with a stirrer, and the time until the lump of material was dispersed and disappeared was measured. Furthermore, the appearance of the obtained dispersion was visually evaluated. The results are shown in Table 14 below.

表14によれば、乳化処理時の温度が高く透明度の高い本発明品の油脂含有乳化組成物(乳化処理温度が70℃で得られた油脂含有乳化組成物)は、乳化処理時の温度が低く白濁した比較品の油脂含有乳化組成物(乳化処理温度が30℃で得られた油脂含有乳化組成物)に比べて、油滴が短時間で水中に分散して乳化液が得られること、また、得られた乳化液は均一に油滴が分散していることが確認された。   According to Table 14, the oil-containing emulsion composition (oil-containing emulsion obtained at an emulsification treatment temperature of 70 ° C.) of the product of the present invention having a high temperature and high transparency during the emulsion treatment has a temperature during the emulsion treatment. Compared with a comparatively low-oiled oil-containing emulsion composition (an oil-containing emulsion composition obtained at an emulsification treatment temperature of 30 ° C.), oil droplets are dispersed in water in a short time to obtain an emulsion, Further, it was confirmed that oil droplets were uniformly dispersed in the obtained emulsion.

Figure 0005000463
Figure 0005000463

2.16.比較例6
実施例7において、液卵黄に代えてリゾレシチン0.5質量%を用い、その減少分はソルビトールの配合量を増やして補正した他は実施例7と同様にして、比較例6の油脂含有乳化組成物を得た。
2.16. Comparative Example 6
In Example 7, the fat-containing emulsion composition of Comparative Example 6 was used in the same manner as in Example 7 except that 0.5% by mass of lysolecithin was used instead of liquid egg yolk, and the decrease was corrected by increasing the amount of sorbitol. I got a thing.

2.17.比較例7
実施例10において、実施例7の油脂含有乳化組成物に代えて比較例6の油脂含有乳化組成物を用いた他は実施例10と同様にして、比較例7の水中油型乳化飲食品(中華風スープ)を得た。
2.17. Comparative Example 7
In Example 10, the oil-in-water emulsified food and drink of Comparative Example 7 was used in the same manner as in Example 10 except that the oil-containing emulsion composition of Comparative Example 6 was used instead of the oil-containing emulsion composition of Example 7 ( Chinese soup).

2.18.試験例4
実施例10及び比較例7で得られた中華風スープを食して卵黄油の風味を評価した。結果を下記表15に示す。表15によれば、液卵黄を用いた油脂含有乳化組成物に卵黄油を含有させた場合(実施例10)、卵黄油の風味が強く良好であるのに対して、リゾレシチンを用いた油脂含有乳化組成物に卵黄油を含有させた場合(比較例7)、卵黄油の風味が弱く劣ることがわかる。
2.18. Test example 4
The Chinese-style soup obtained in Example 10 and Comparative Example 7 was eaten to evaluate the flavor of egg yolk oil. The results are shown in Table 15 below. According to Table 15, when the yolk oil is contained in the fat-and-oil-containing emulsion composition using liquid egg yolk (Example 10), the yolk oil has a strong and good flavor, whereas the fat-containing composition using lysolecithin When egg yolk oil is contained in the emulsified composition (Comparative Example 7), it can be seen that the egg yolk oil has a weak and inferior flavor.

Figure 0005000463
Figure 0005000463

Claims (10)

油脂の含有量が30〜80質量%であり、
卵黄、卵白及び動物性蛋白から選ばれる1種又は2種以上の成分と多価アルコールとを含み、積分球式光電光度法を用いた濁度測定により得られた全光線透過率が40%以上であり、
前記成分および前記多価アルコール以外の乳化材の含有量が0.01質量%以下である油脂含有乳化組成物。
Oil content is 30 to 80% by mass,
Contains one or more components selected from egg yolk, egg white and animal protein and polyhydric alcohol, and has a total light transmittance of 40% or more obtained by turbidity measurement using an integrating sphere photoelectric photometry And
The fat-and-oil-containing emulsion composition whose content of emulsifiers other than the said component and the said polyhydric alcohol is 0.01 mass% or less.
前記成分及び前記多価アルコールを含む混合液と前記油脂とを乳化処理して得られ、
前記混合液の水分含量が0.1〜50質量%である請求項1に記載の油脂含有乳化組成物。
Obtained by emulsifying the mixture and the oil containing the component and the polyhydric alcohol,
The oil-and-fat-containing emulsion composition according to claim 1, wherein the mixed solution has a water content of 0.1 to 50% by mass.
前記成分の含有量が固形分換算で0.1〜15質量%である請求項1または2に記載の油脂含有乳化組成物。 The fat-and-oil-containing emulsion composition according to claim 1 or 2 , wherein the content of the component is 0.1 to 15% by mass in terms of solid content. 前記多価アルコールの含有量が10〜70質量%である、請求項1ないしのいずれか1項に記載の油脂含有乳化組成物。 The fat-and-oil-containing emulsion composition according to any one of claims 1 to 3 , wherein the content of the polyhydric alcohol is 10 to 70% by mass. 前記成分の含有量と前記多価アルコールの含有量との比率が、固形分換算で前記成分100質量部に対して前記多価アルコールが1質量部以上である請求項1ないしのいずれか1項に記載の油脂含有乳化組成物。 The ratio between the content and the content of the polyhydric alcohol of the component, either to the polyhydric alcohol claims 1 to 1 part by mass or more with respect to the 100 parts by weight of component on a solid basis of 4 1 The fat-and-oil-containing emulsified composition according to Item. 脂溶性成分をさらに含む、請求項1ないしのいずれかに記載の油脂含有乳化組成物。 The oil-containing emulsion composition according to any one of claims 1 to 5 , further comprising a fat-soluble component. 請求項1ないしのいずれかに記載の油脂含有乳化組成物を含有する食品。 The foodstuff containing the fat-and-oils containing emulsion composition in any one of Claims 1 thru | or 6 . 請求項1ないしのいずれかに記載の油脂含有乳化組成物が配合され、前記油脂含有乳化組成物の油脂が油滴として分散している水中油型乳化飲食品。 An oil-in-water emulsified food or drink comprising the oil / fat-containing emulsion composition according to any one of claims 1 to 6 , wherein the oil / fat of the oil / fat-containing emulsion composition is dispersed as oil droplets. 前記成分及び前記多価アルコールを含む混合液と前記油脂とを50℃以上で乳化処理することを含む、請求項1に記載の油脂含有乳化組成物の製造方法。   The manufacturing method of the oil-and-fat containing emulsion composition of Claim 1 including emulsifying the liquid mixture and the said fats and oils containing the said component and the said polyhydric alcohol at 50 degreeC or more. 前記混合液の前記成分と前記多価アルコールとの混合比率が、固形分換算で前記成分の合計量100質量部に対して前記多価アルコールが1質量部以上である請求項に記載の油脂含有乳化組成物の製造方法。 The fats and oils according to claim 9 , wherein the mixing ratio of the component and the polyhydric alcohol in the mixed solution is 1 part by mass or more with respect to 100 parts by mass of the total amount of the components in terms of solid content. The manufacturing method of a containing emulsion composition.
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