JP4938044B2 - Display element and display device - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a display element whose viewing angle property is greatly improved without deteriorating transmissivity. <P>SOLUTION: The display element 70 includes a pair of substrates, at least one of which is transparent; a medium that held by the substrates and that shows an optical anisotropy when an electric field is applied; and an electrode made of a transparent electrode material for applying an electric field to the medium. The medium contains a liquid crystal material, which shows an optical isotropy when no electric field is applied and which shows an optical anisotropy when an electric field is applied. In each pixel 71 in the display element 70, at least two domains D<SB>M</SB>&times;D<SB>M</SB>' exist wherein the directions of optical anisotropies shown by the longitudinal direction of a refractive index ellipsoid of the liquid crystal material are different when an electric field is applied. The directions of the optical anisotropies in each domain D<SB>M</SB>&times;D<SB>M</SB>' when an electric field is applied make 90 degrees &plusmn;20 degrees. <P>COPYRIGHT: (C)2009,JPO&amp;INPIT

Description

  The present invention relates to a display element and a display device having high-speed response and display performance with a wide field of view.

  Liquid crystal display elements have the advantage of being thin, light and low in power consumption among various display elements, and are suitable for OA (Office Automation) equipment such as TV, video and other image display devices, monitors, word processors and personal computers. Widely used.

  Conventionally, as a liquid crystal display method of a liquid crystal display element, for example, a display mode using a TN (twisted nematic) mode using a nematic liquid crystal, a ferroelectric liquid crystal (FLC), or an antiferroelectric liquid crystal (AFLC). A polymer dispersion type liquid crystal display mode is known.

  Among them, conventionally used liquid crystal display elements include, for example, TN (twisted nematic) mode liquid crystal display elements using nematic liquid crystal, and the liquid crystal display elements using the TN mode. Have drawbacks such as a slow response and a narrow viewing angle. These disadvantages greatly hinder CRT (cathode ray tube) from surpassing.

  In addition, the display mode using FLC or AFLC has advantages such as quick response and wide viewing angle, but it has major drawbacks in terms of shock resistance, temperature characteristics, etc. It has not yet been realized.

  Furthermore, the polymer dispersion type liquid crystal display mode using light scattering does not require a polarizing plate and can display a high luminance, but the viewing angle cannot be controlled by the phase plate, and the response characteristic is not necessary. There is little advantage over the TN mode.

  In any of these display methods, the liquid crystal molecules are aligned in a certain direction, and the appearance differs depending on the angle with respect to the liquid crystal molecules. Each of these display systems uses rotation of liquid crystal molecules due to application of an electric field, and the liquid crystal molecules rotate in an aligned manner, so that it takes time to respond. In the case of a display mode using FLC or AFLC, although it is advantageous in terms of response speed and viewing angle, irreversible alignment breakage due to external force becomes a problem.

  On the other hand, a display method based on electronic polarization using a secondary electro-optic effect has been proposed in contrast to these display methods utilizing the rotation of molecules by applying an electric field.

  The electro-optic effect is a phenomenon in which the refractive index of a substance is changed by an external electric field. The electro-optic effect includes an effect proportional to the first order of the electric field and an effect proportional to the second order, which are called the Pockels effect and the Kerr effect, respectively. In particular, the secondary electro-optic effect called the Kerr effect has been applied to high-speed optical shutters from an early stage, and has been put to practical use in special measuring instruments. The Kerr effect was discovered by J. Kerr in 1875. So far, materials such as organic liquids such as nitrobenzene and carbon disulfide have been known as materials showing the Kerr effect. These materials are used for, for example, high electric field strength measurement of power cables and the like in addition to the optical shutter described above.

After that, it was shown that the liquid crystal material has a large Kerr constant, and a basic study for application to a light modulation element, a light polarization element, and an optical integrated circuit was conducted, and the Kerr constant exceeding 200 times that of the nitrobenzene was shown. Liquid crystal compounds have also been reported.

  In such a situation, application to a display device of the Kerr effect is being studied. Since the Kerr effect is proportional to the second order of the electric field, it can be expected to drive at a relatively low voltage, and essentially exhibits a response characteristic of several microseconds to several milliseconds. Application is expected.

  Under such circumstances, for example, in Patent Document 1, Patent Document 2, and Non-Patent Document 1, a medium made of a liquid crystal substance is sealed between a pair of substrates, and an electric field parallel or perpendicular to the substrates is applied. It has been proposed to induce the Kerr effect and apply it as a display element.

  In such a display element, polarizing plates whose absorption axes are orthogonal to each other are arranged outside each of the substrates, and the medium is optically isotropic when no electric field is applied to achieve black display. When applied, birefringence occurs, resulting in a change in transmittance, thereby performing gradation display. For this reason, the contrast in the normal direction of the substrate can realize a very high value.

JP 2001-249363 A (published September 14, 2001) Japanese Patent Laid-Open No. 11-183937 (published July 9, 1999)

Shiro Matsumoto, 3 others, “Fine droplets of liquid crystals in a transparent polymer and their response to an electric field”, Appl. Phys. Lett. 1996, vol. 69, p. 1044-1046 Takashi Kato and two others, “Fast and High-Contrast Electro-optical Switching of Liquid-Crystalline Physical Gels: Formation of Oriented Microphase-Separated Structures”, Adv. Funct. Mater., April 2003, vol. 13. No. 4, p313-317 Kazuya Saito, 1 other person, “Thermodynamics of unusual thermotropic liquid crystals that are optically isotropic”, Liquid Crystals, 2001, Vol. 5, No. 1. p.20-27 Jun Yamamoto, “Liquid Crystal Microemulsion”, Liquid Crystal, 2000, Vol. 3, No. 3, p.248-254 Yukihide Shiraishi, 4 others, “Palladium nanoparticles protected with liquid crystal molecules—Preparation and application to guest-host mode liquid crystal display devices”, Polymer Papers, December 2002, Vol. 59, No. 12, p. .753-759 Hirotsugu kikuchi, 4 others, "Polymer-stabilized liquid crystal blue phases", p. 64-68, [online], September 2, 2002, Nature Materials, vol. 1, [Search July 10, 2003], Internet <URL: http://www.nature.com/naturematerials> Makoto Yoneya, “Searching for Nanostructured Liquid Crystal Phases by Molecular Simulation”, Liquid Crystals, 2003, Vol. 7, No. 3, p.238-245 D. Demus, 3 others, "Handbook of Liquid Crystals Low Molecular Weight Liquid Crystal", Wiley-VCH, 1998, vol. 2B, p. 887-900 D. Demus, 3 others, "Handbook of Liquid Crystals Low Molecular Weight Liquid Crystal", Wiley-VCH, 1998, vol. 1, p. 484-485 Eric Grelet, 3 others, “Structural Investigations on Smectic Blue Phases”, PHYSICAL REVIEW LETTERS, The American Physical Society, April 23, 2001, vol. 86, no. 17, p3791-3794 Jun Yamamoto, "Liquid Crystal Science Laboratory 1st: Identification of Liquid Crystal Phase: (4) Lyotropic Liquid Crystal", Liquid Crystal, 2002, Vol. 6, No. 1, p.72-83 Junichi Yamamoto, 1 outside, “Organic electro-optic material”, National Technical Report, December 1976, vol. 22, no. 6, p. 826-834

  However, according to a detailed examination by the inventors of the present application, when the display element having the above-described conventional configuration is viewed from an oblique direction, there is an orientation that is colored blue or yellow, and in such an orientation, the display quality is greatly increased. It was confirmed that This means that the viewing angle by the display element is narrow, and for example, it becomes a problem in terms of practicality as a television or a personal computer monitor using the display element.

  Note that Patent Document 1 describes using a “<”-shaped electrode in order to improve viewing angle characteristics. However, according to the study by the inventors of the present application, it has been found that the transmittance described in the configuration described in Patent Document 1 is reduced and that the viewing angle characteristics are hardly improved.

  The present invention has been made in view of the above-described conventional problems, and an object of the present invention is to provide a display element and a display device that can improve viewing angle characteristics as compared with the related art by compensating for the coloring phenomenon of the oblique viewing angle. It is to provide. A further object of the present invention is to provide a display element and a display device that greatly improve the viewing angle characteristic without impairing the transmittance by suppressing the decrease in the transmittance and compensating for the coloring phenomenon of the oblique viewing angle. It is in.

  In order to solve the above problems, a display element according to the present invention has a pair of substrates at least one of which is transparent and a degree of optical anisotropy sandwiched between the pair of substrates and an electric field that is an external field. And a medium composed of a transparent electrode material that applies an electric field to the medium, the medium including a liquid crystalline substance, and the liquid crystalline substance exhibits optical isotropy when no electric field is applied. A display element that displays an optical anisotropy when an electric field is applied, wherein each pixel has an optical anisotropy indicated in the major axis direction of the refractive index ellipsoid of the liquid crystalline substance when the electric field is applied. Characterized in that there are at least two domains having different directions of properties, and the directions of the optical anisotropy when the electric field is applied in the at least two domains form an angle within a range of 90 ° ± 20 ° to each other. Yes.

  In the present invention, the degree of optical anisotropy changes with the application of an external field (electric field) means that the magnitude of optical anisotropy changes with the application of an external field, more specifically, It shows that the shape of the refractive index ellipsoid changes with the application of an external field. That is, in the display element of the present invention, different display states can be realized by utilizing the change in the shape of the refractive index ellipsoid when no external field is applied and when an external field is applied.

That is, the refractive index in a substance is generally not isotropic and varies depending on the direction. This anisotropy of the refractive index, that is, the optical anisotropy of the substance is usually in a refractive index ellipsoid. Shown. In general, for light traveling in an arbitrary direction, the plane that passes through the origin and is perpendicular to the traveling direction of the light wave is considered to be the cut surface of the refractive index ellipsoid, and the principal axis direction of this ellipse is the component direction of the polarization of the light wave. Yes, half the length of the main axis corresponds to the refractive index in that direction. Therefore, if the optical anisotropy is captured by such a refractive index ellipsoid, in a conventional liquid crystal display device, when an external field is applied and when no external field is applied (in addition, in the driving method of the conventional liquid crystal display device) In other words, when the electric field is applied and when no electric field is applied, the shape of the refractive index ellipsoid of the liquid crystal molecules (the shape of the cut surface of the refractive index ellipsoid) remains an ellipse, and its major axis direction changes. In contrast, the present invention realizes a different display form by (rotating), but in the present invention, the shape of the refractive index ellipsoid of the molecules constituting the medium (refracted) when no external field is applied and when an external field is applied. Different display states are realized by utilizing the change in the shape of the cut surface of the ellipsoid.

  As described above, the conventional liquid crystal display element performs display using only the change of the alignment direction due to the rotation of the liquid crystal molecules accompanying the application of the electric field, and the liquid crystal molecules are aligned and rotated together. Therefore, the inherent viscosity of the liquid crystal greatly affects the response speed. On the other hand, according to the present invention, display is performed using a change in the degree of optical anisotropy in the medium. Therefore, according to the present invention, unlike the conventional liquid crystal display element, there is no problem that the viscosity inherent to the liquid crystal greatly affects the response speed, so that a high-speed response can be realized. In addition, since the display element of the present invention has high-speed response, for example, it can be used for a field sequential color display device.

  Further, the conventional liquid crystal display element has a problem that the driving temperature range is limited to a temperature in the vicinity of the phase transition point of the liquid crystal phase, and extremely accurate temperature control is required. On the other hand, according to the present invention, it is only necessary to maintain the medium at a temperature at which the degree of optical anisotropy is changed by application of an external field, so that temperature control can be facilitated. There is an effect.

  In addition, according to the present invention, since the display is performed using the change in the degree of optical anisotropy in the medium, the viewing angle is wider than that of the conventional liquid crystal display element that performs the display by changing the orientation direction of the liquid crystal molecules. Characteristics can be realized.

  According to the present invention, each pixel includes at least two domains having different optical anisotropy directions indicated by the major axis direction of the refractive index ellipsoid of the liquid crystalline substance when an electric field is applied. For example, since the color change of display within the range of polar angle ± 60 degrees can be suppressed, the coloring phenomenon of the oblique viewing angle can be compensated for each other, and the viewing angle characteristics can be improved as compared with the conventional case. It also has the effect of being able to. Further, according to the present invention, the direction of optical anisotropy (domain direction) when an electric field is applied in the at least two domains is an angle within a range of 90 degrees ± 20 degrees (preferably 90 degrees ± (An angle within a range of less than 20 degrees) suppresses a decrease in transmittance and, for example, has the effect of greatly improving viewing angle characteristics within a polar angle range of ± 60 degrees. . The medium exhibits optical isotropy when no electric field is applied, and exhibits optical anisotropy when an electric field is applied. In this case, the shape of the refractive index ellipsoid is spherical when no electric field is applied, and changes to an ellipse when an external field, that is, an electric field is applied. According to the above configuration, by applying an electric field, the shape of the refractive index ellipsoid of the medium can be changed between when no electric field is applied and when the electric field is applied, and the direction of optical anisotropy remains constant, Display can be performed by changing the degree of optical anisotropy (degree of alignment order, refractive index). Therefore, according to the above configuration, it is possible to realize a display element that has different display states between when no electric field is applied and when an electric field is applied, has a wide driving temperature range, and has a wide viewing angle characteristic and a high-speed response characteristic. Play.

  Note that, by using an electric field as described above as the external field, the design and drive control of the display element can be easily performed.

  In addition, the display element includes a polarizing plate disposed on the opposite side of the pair of substrates from the surface facing the medium in at least one substrate, and the optical difference at the time of applying an electric field in each domain. The angle formed by the direction of isotropic and the absorption axis of the polarizing plate is preferably within a range of 45 degrees ± 10 degrees, and more preferably within a range of less than 45 degrees ± 10 degrees.

That is, the direction of the optical anisotropy when the electric field is applied in each domain or when no electric field is applied (when the electric field is applied in the display device having the above structure) is 45 degrees with respect to the absorption axis of the polarizing plate. When giving maximum transmittance. Therefore, the direction of the optical anisotropy when the electric field is applied to each domain or when no electric field is applied (when the electric field is applied in the display device having the above structure) is 45 degrees with respect to the absorption axis of the polarizing plate. Although it is most desirable, if the transmittance when the angle is 45 degrees is 100%, it is felt that the human eye has the maximum luminance if it is approximately 90% or more. If the angle is in the range of 35 degrees ≦ θ ≦ 55 degrees, it is perceived by the human eye as having almost the maximum brightness or a brightness close to the maximum brightness. In this case, in particular, when the angle is within a range of 35 degrees <θ <55 degrees, it is felt that the human eye has the maximum luminance.

  Therefore, according to said structure, there exists an effect that a viewing angle characteristic can be improved significantly, without impairing the transmittance | permeability.

  In particular, the angle formed by the direction of the optical anisotropy when the electric field is applied in each domain and the absorption axis of the polarizing plate is within a range of 45 ° ± 10 °, preferably less than 45 ° ± 10 °. The direction of the optical anisotropy in each domain is within the range of 90 ° ± 20 °, preferably less than 90 ° ± 20 °, for example, The color change of the display within the range of polar angle ± 60 degrees can be sufficiently suppressed, the coloring phenomenon of the oblique viewing angle can be surely compensated, and the bright display with almost the maximum luminance can be performed. Therefore, there is an effect that it is possible to provide a display element in which the viewing angle characteristic is further improved without causing a decrease in transmittance.

  Examples of means for generating optical anisotropy in each of the domains in the display element include an electric field, a magnetic field, and light. Among them, the electric field is easy to design and drive control the display element. Therefore, it is preferable.

  In the display element, the electrode applies an electric field substantially parallel to the substrate to the medium in each pixel, and the electrode applies an electric field in a partially different direction to the medium in each pixel. It may be a thing.

  The electric field is also used as means for forming (domain division) at least two domains having different directions of optical anisotropy of the medium.

  Therefore, in each pixel of the display element, an electrode pair group including at least two electrode pairs for applying an electric field substantially parallel to the substrate to the medium is provided as the electrode. The pairs preferably apply to the medium an electric field that forms an angle with each other within a range of 90 ° ± 20 °, preferably within a range of less than 90 ° ± 20 °.

  Further, each of the electrode pairs is composed of a pair of comb-shaped electrodes, and is provided so as to face each other in a direction in which the comb-tooth portions are engaged with each other. It is preferable that the comb-tooth portion in the other electrode pair is arranged so as to form an angle within a range of 90 ° ± 20 °, preferably within a range of less than 90 ° ± 20 °.

  According to each of the above configurations, the direction of the optical anisotropy when the electric field is applied to each domain is easily different from each other within a range of 90 ° ± 20 °, preferably within a range of less than 90 ° ± 20 °. Thus, the coloring phenomenon of the oblique viewing angle can be compensated for each other, and the viewing angle characteristic can be greatly improved without impairing the transmittance.

  Further, the medium may have an ordered structure exhibiting cubic symmetry.

  The medium may be composed of molecules exhibiting a cubic phase or a smectic D phase.

  In any of the above substances, the degree of optical anisotropy changes when an electric field is applied. Therefore, any of the above substances can be used as the medium.

  Further, in order to solve the above-described problems, a display device according to the present invention includes the display element according to the present invention having any one of the above-described configurations.

  Therefore, according to the present invention, the driving temperature range is wide, the wide viewing angle characteristic and the high-speed response characteristic are provided, and the coloring phenomenon of the oblique viewing angle can be compensated for each other, and the viewing angle characteristic is improved as compared with the conventional case. The display device can be provided. The display device can be suitably used, for example, as a field sequential color display device.

  As described above, the display element according to the present invention is sandwiched between a pair of substrates at least one of which is transparent, and the degree of optical anisotropy is changed by applying an electric field as an external field. A medium and an electrode made of a transparent electrode material that applies an electric field to the medium, the medium including a liquid crystal substance, and the liquid crystal substance exhibits optical isotropy when no electric field is applied. It is a display element that displays by sometimes showing optical anisotropy, and each pixel has an optical anisotropy direction indicated by a major axis direction of a refractive index ellipsoid of the liquid crystalline substance when an electric field is applied. Due to the presence of at least two different domains, it has a wide driving temperature range, a wide viewing angle characteristic and a high-speed response characteristic, and can compensate each other for the coloring phenomenon of the oblique viewing angle. Can improve There is an effect that. Further, according to the present invention, the direction of optical anisotropy (domain direction) when an electric field is applied in the at least two domains is an angle within a range of 90 degrees ± 20 degrees (preferably 90 degrees ± (An angle within a range of less than 20 degrees) suppresses a decrease in transmittance and, for example, has the effect of greatly improving viewing angle characteristics within a polar angle range of ± 60 degrees. .

  Further, as described above, the display device according to the present invention includes the display element according to the present invention, and thus has a wide driving temperature range, a wide viewing angle characteristic, a high-speed response characteristic, and an oblique viewing angle. The coloring phenomenon can be compensated for each other, and the viewing angle characteristics can be improved as compared with the conventional case.

It is a figure explaining the relationship between the electric field application direction of each domain in the display element concerning one Embodiment of this invention, and a polarizing plate absorption-axis direction. (A) is sectional drawing which shows typically the schematic structure of the principal part of the said display element in an electric field no application state, (b) shows typically the schematic structure of the principal part of the said display element in an electric field application state. It is sectional drawing. (A) is sectional drawing which shows typically the medium of the said display element in an electric field no application state, (b) is sectional drawing which shows typically the medium of the said display element in an electric field application state. It is a graph which shows the relationship between the applied voltage and the transmittance | permeability in the said display element. The difference in display principle between the display element and the conventional liquid crystal display element is a cross-sectional view schematically showing the shape of the average refractive index ellipsoid of the medium when no electric field is applied and when the electric field is applied, and its principal axis direction. (A) is a cross-sectional view of the display element according to the present embodiment when no electric field is applied, (b) is a cross-sectional view of the display element according to the present embodiment when an electric field is applied, and (c) Is a cross-sectional view of a conventional TN liquid crystal display element when no electric field is applied, (d) is a cross-sectional view of a conventional TN liquid crystal display element when an electric field is applied, and (e) is a conventional VA system. 2 is a cross-sectional view of the liquid crystal display element when no electric field is applied, (f) is a cross-sectional view of the conventional VA liquid crystal display element when an electric field is applied, and (g) is a conventional IPS liquid crystal display element. It is sectional drawing at the time of no electric field application, (h) is the liquid crystal display element of the conventional IPS system It is a cross-sectional view of when an electric field is applied. 2 is a graph showing the transmittance when the orientation in which optical anisotropy appears in two domains in the display element shown in FIG. 1 exists at an angle of ± θ on one of the polarizing plate absorption axes. It is a schematic diagram which shows an example of the reverse micelle phase mixing system of liquid crystal microemulsion. It is a schematic diagram which shows the other example of the reverse micelle phase mixing system of liquid crystal microemulsion. It is a classification diagram of a lyotropic liquid crystal phase. It is a figure explaining the relationship between the electric field application direction and polarizing plate absorption axis direction of each domain in the display element used by the comparative example. (A) schematically shows the rotation of liquid crystal molecules in a conventional SIPS mode in which “<”-shaped electrodes are provided such that the electric field application direction between adjacent domains forms an angle of 90 degrees. (B) shows the rotation of the liquid crystal molecules in the conventional SIPS mode when the “<”-shaped electrodes are provided so that the electric field application direction between adjacent domains forms an angle of 35 degrees. It is a figure shown typically. It is sectional drawing which shows an example of schematic structure of the principal part in the reflection type display element concerning this Embodiment. (A) is sectional drawing which shows typically schematic structure of the principal part of the display element concerning the other form of this Embodiment in an electric field no application state, (b) is another embodiment of this Embodiment in an electric field application state. It is sectional drawing which shows typically schematic structure of the principal part of the display element concerning. It is a figure explaining the orientation process direction of each domain in 1 pixel in the display element concerning further another embodiment of this invention. It is a figure explaining the orientation processing direction of each pixel in the conventional display element. It is a top view which shows typically an example of the electrode structure of each pixel in the display element concerning the further another form of this invention. It is another top view which shows typically an example of the electrode structure of each pixel in the display element concerning the further another form of this invention. The result of measuring the chromaticity of the oblique viewing angle in the case where two domains having different directions of optical anisotropy of the medium generated by applying an electric field are provided in one pixel and in the case where domain division is not performed. It is a graph to show. In each pixel of each cell used for measurement of chromaticity and Y value, an angle formed by the orientations of optical anisotropy generated by applying an electric field in each domain, and an optical difference generated by applying an electric field in each domain. It is explanatory drawing which shows the angle which a direction of orientation and each polarizing plate absorption axis make. In each pixel of each cell used for measurement of chromaticity and Y value, an angle formed by the orientations of optical anisotropy generated by applying an electric field in each domain, and an optical difference generated by applying an electric field in each domain. It is another explanatory drawing which shows the angle which a direction of orientation and each polarizing plate absorption axis make. In each pixel of each cell used for measurement of chromaticity and Y value, an angle formed by the orientations of optical anisotropy generated by applying an electric field in each domain, and an optical difference generated by applying an electric field in each domain. It is another explanatory drawing which shows the angle which a direction of orientation and each polarizing plate absorption axis make. In each pixel of each cell used for measurement of chromaticity and Y value, an angle formed by the orientations of optical anisotropy generated by applying an electric field in each domain, and an optical difference generated by applying an electric field in each domain. It is another explanatory drawing which shows the angle which a direction of orientation and each polarizing plate absorption axis make. It is a block diagram which shows schematic structure of the principal part of the display apparatus using the display element concerning one embodiment of this invention. It is a schematic diagram which shows the shape of the refractive index ellipsoid of one molecule at the time of the electric field application in the display element shown in FIG. FIG. 2 is a plan view schematically showing an electrode structure of each pixel in the display element shown in FIG. 1 according to an embodiment of the present invention.

[Embodiment 1]
An embodiment of the present invention will be described below with reference to FIGS. 1 to 12 and FIGS. 18 to 25.

  FIG. 1 is a diagram for explaining the relationship between the electric field application direction of each domain and the polarizing plate absorption axis direction in the display element according to the present embodiment. FIG. 2A is a cross-sectional view schematically showing a schematic configuration of the main part of the display element according to the present embodiment in an electric field non-application state (OFF state), and FIG. It is sectional drawing which shows typically schematic structure of the principal part of the display element concerning this Embodiment in an ON state. FIG. 23 is a block diagram showing a schematic configuration of a main part of a display device using the display element according to the present embodiment. The display element according to this embodiment is used in a display device together with a drive circuit.

  As shown in FIG. 23, the display device 60 according to the present embodiment includes a display element 70 in which pixels 71 are arranged in a matrix, a source driver 61 and a gate driver 62 as drive circuits, a power supply circuit 63, and the like. And.

  Further, the display element 70 includes a plurality of data signal lines SL1 to SLv (v represents an arbitrary integer of 2 or more) and a plurality of scanning signal lines GL1 to GLw that respectively intersect the data signal lines SL1 to SLv. (W represents an arbitrary integer equal to or greater than 2), and the pixels 71 are provided for each combination of the data signal lines SL1 to SLv and the scanning signal lines GL1 to GLw.

  The power supply circuit 63 supplies a voltage for performing display on the display element 70 to the source driver 61 and the gate driver 62, whereby the source driver 61 causes the data signal line SL1 of the display element 70 to be displayed. ˜SLv are driven, and the gate driver 62 drives the scanning signal lines GL <b> 1 to GLw of the display element 70.

  Each pixel 71 is provided with a switching element (not shown). As the switching element, for example, an FET (field effect transistor) or a TFT (thin film transistor) is used. The gate electrode of the switching element is the scanning signal line GLw, the source electrode is the data signal line SLv, and the drain electrode. Are connected to a pixel electrode (not shown). Thereby, in each pixel 71, when the scanning signal line GLu (u represents an arbitrary integer equal to or greater than 1) is selected, the switching element becomes conductive, and a controller (display control unit, display control device) (not shown). ) Is applied to the display element 70 via the data signal line SLu (u represents an arbitrary integer equal to or greater than 1) by the source driver 61. The display element 70 ideally continues to hold the voltage at the time of interruption while the selection period of the scanning signal line GLu ends and the switching element is interrupted.

  In the present embodiment, the display element 70 is optically isotropic (macroscopic, specifically, a visible light wavelength region, that is, a visible light wavelength region when an electric field (voltage) is applied or no electric field (voltage) is applied. Display is performed using a medium (a liquid crystalline medium (liquid crystal material), a dielectric substance) indicating a wavelength scale or a larger scale.

  An example of the configuration of the display element 70 according to the present embodiment will be described in detail below.

  As shown in FIGS. 2 (a) and 2 (b), the display element 70 according to the present embodiment is a pair of substrates 1 and 2 arranged opposite to each other as medium holding means (optical modulation layer holding means). A medium layer 3 made of a medium that is optically modulated by applying an electric field (hereinafter referred to as medium A) is sandwiched between the pair of substrates 1 and 2 as a pair of substrates. The polarizing plates 6 and 7 are provided on the outer sides of the substrates 1 and 2, that is, on the surface opposite to the opposing surfaces of the substrates 1 and 2, respectively.

  Of the pair of substrates 1 and 2, at least one substrate is made of a transparent substrate such as a glass substrate having translucency, and the other substrate of the pair of substrates 1 and 2 is the other substrate. 2 is an electric field applying means (electric field applying member) for applying an electric field (lateral electric field) substantially parallel to the substrate 1 to the medium layer 3 as shown in FIG. As shown in FIG. 1, the comb-shaped electrodes 4 and 5 are arranged to face each other in the direction in which the comb-tooth portions 4a and 5a (comb-tooth electrodes) of the comb-shaped electrodes 4 and 5 mesh with each other.

  The comb electrodes 4 and 5 are made of an electrode material such as a transparent electrode material such as ITO (indium tin oxide). In the present embodiment, for example, the line width is 5 μm, the distance between electrodes (electrode interval) is 5 μm, and the thickness is 0 .3 μm. However, the electrode material, the line width, the distance between the electrodes, and the thickness are merely examples, and are not limited thereto.

  The display element 70 includes, for example, a substrate 1 provided with the comb-shaped electrodes 4 and 5 and a substrate 2 with a sealing agent (not shown) and a spacer such as a plastic bead or a glass fiber spacer (not shown) as necessary. And the medium A is sealed in the gap.

The medium A used in this embodiment is a medium whose degree of optical anisotropy changes when an electric field is applied. When an electric field E _j is applied to the material from the outside, an electric displacement D _ij = ε _ij · E _j is generated, and at that time, a slight change is also seen in the dielectric constant (ε _ij ). Since the square of the refractive index (n) is equivalent to the dielectric constant at the frequency of light, the medium A can also be said to be a substance whose refractive index changes when an electric field is applied. The medium A may be liquid, gas, or solid.

  As described above, the display element 70 according to the present embodiment has a phenomenon in which the degree of optical anisotropy of a substance is changed by application of an electric field, for example, a phenomenon in which the refractive index of a substance is changed by an external electric field (electrooptic effect ), Which is different from conventional liquid crystal display elements that utilize the fact that molecules (orientation directions of molecules) are aligned in a certain direction and rotate together when an electric field is applied. The direction of anisotropy hardly changes, and display is performed by changing the degree of optical anisotropy (mainly electronic polarization or orientation polarization).

  Note that the conventional liquid crystal display element performs display using only the change in the alignment direction due to the rotation of the liquid crystal molecules accompanying the application of an electric field, and the liquid crystal molecules are aligned in a certain direction. Therefore, the inherent viscosity of the liquid crystal greatly affects the response speed. In contrast, the display element 70 according to the present embodiment performs display using a change in the degree of optical anisotropy in the medium A as described above. Therefore, according to the display element 70 according to the present embodiment, unlike the conventional liquid crystal display element, there is no problem that the inherent viscosity of the liquid crystal greatly affects the response speed, so that a high-speed response can be realized. In addition, since the display element 70 according to the present embodiment uses the above-described display method and has high-speed response, it can also be used for, for example, a field sequential color display device.

Further, the conventional liquid crystal display element has a problem that the driving temperature range is limited to a temperature in the vicinity of the phase transition point of the liquid crystal phase, and extremely accurate temperature control is required. On the other hand, according to the display element 70 according to the present embodiment, the medium A only needs to be maintained at a temperature at which the degree of optical anisotropy changes due to the application of an electric field. Can be easily.

  Further, according to the display element 70 according to the present embodiment, since display is performed using the change in the degree of optical anisotropy in the medium A, the conventional liquid crystal that performs display by changing the orientation direction of the liquid crystal molecules. A wider viewing angle characteristic can be realized than a display element.

  As the medium A used in the present embodiment, a substance exhibiting the Pockels effect or the Kerr effect is optically isotropic at the time of no application of an electric field (if it is viewed from the macroscopic viewpoint), the electric field It may be a substance that exhibits optical anisotropy when applied, has optical anisotropy when no electric field is applied, disappears when applied with an electric field, and is optically isotropic ( It may be a substance that shows an isotropic view in a macroscopic manner). The medium A may exhibit optical anisotropy when no electric field is applied, and the degree of optical anisotropy may be changed by applying an electric field. Typically, it is optically isotropic when no electric field is applied (it should be isotropic when viewed macroscopically), and optical modulation (especially, it is desirable that birefringence is increased by applying an electric field) by applying an electric field. It is a medium to express.

  The Pockels effect and the Kerr effect (which are themselves observed in the isotropic phase state) are electro-optic effects proportional to the primary or secondary electric field, respectively, and are in the isotropic phase when no electric field is applied. Although optically isotropic, in the state where an electric field is applied, the long axis direction of the compound molecules is oriented in the direction of the electric field in the region where the electric field is applied, and birefringence is expressed, thereby modulating the transmittance. be able to. For example, in the case of a display method using a substance exhibiting the Kerr effect, by controlling the bias of electrons within one molecule by applying an electric field, each randomly arranged individual molecule rotates and becomes oriented. Is advantageous in that the response speed is very fast and the molecules are arranged randomly, and there is no viewing angle limitation. The medium A that is roughly proportional to the primary or secondary electric field can be treated as a substance exhibiting the Pockels effect or the Kerr effect.

  Examples of the substance exhibiting the Pockels effect include, but are not limited to, organic solid materials such as hexamine. As the medium A, various organic materials and inorganic materials exhibiting the Pockels effect can be used.

  Examples of the substance exhibiting the Kerr effect include PLZT (a metal oxide obtained by adding lanthanum to a solid solution of lead zirconate and lead titanate) and the following structural formulas (1) to (4).

Although the liquid crystalline substance shown by these is mentioned, it does not specifically limit.

  The Kerr effect is observed in a medium transparent to incident light. For this reason, the substance showing the Kerr effect is used as a transparent medium. Usually, a liquid crystalline substance shifts from a liquid crystal phase having a short-range order to an isotropic phase having random orientation at a molecular level as the temperature rises. In other words, the Kerr effect of a liquid crystalline substance is a phenomenon that is observed in a liquid in an isotropic phase state above the liquid crystal phase-isotropic phase transition temperature, not in the nematic phase, and the liquid crystalline substance is a transparent dielectric liquid. used.

  A dielectric liquid such as a liquid crystal substance is in an isotropic phase state as the use environment temperature (heating temperature) by heating is higher. Therefore, when a dielectric liquid such as a liquid crystal substance is used as the medium, in order to use the dielectric liquid in a liquid state that is transparent, that is, transparent to visible light, for example, (1) medium layer 3 may be provided with heating means such as a heater (not shown), and the dielectric liquid may be heated to the clearing point or higher by the heating means. (2) Thermal radiation from the backlight, The dielectric liquid may be used by heating it above its clearing point by light conduction and / or heat conduction from the peripheral driving circuit (in this case, the backlight or the peripheral driving circuit functions as a heating means). (3) A sheet heater (heating means) may be bonded to at least one of the substrates 1 and 2 as a heater and heated to a predetermined temperature. Furthermore, in order to use the dielectric liquid in a transparent state, a material having a clearing point lower than the lower limit of the operating temperature range of the display element 70 may be used.

  The medium A preferably contains a liquid crystalline substance. When a liquid crystalline substance is used as the medium A, the liquid crystalline substance is a transparent liquid that shows a macroscopic isotropic phase. However, microscopically, it is desirable to include a cluster which is a molecular group having a short-range order arranged in a certain direction. Since the liquid crystalline substance is used in a state transparent to visible light, the cluster is also used in a state transparent (optically isotropic) to visible light.

Therefore, as described above, the display element 70 may perform temperature control using a heating unit such as a heater, or as described in Patent Document 2, the medium layer 3 may be The liquid crystalline substance may be divided into small areas using a molecular material or the like, and the liquid crystalline substance may have a diameter smaller than a visible light wavelength, for example, a diameter of 0.1 μm or less. It is possible to use a liquid crystal compound that exhibits a transparent isotropic phase at a use environment temperature (room temperature) or the like. Light scattering can be ignored when the diameter of the liquid crystalline substance, and further, the diameter (major axis) of the cluster is 0.1 μm or less, that is, smaller than the visible light wavelength (incident light wavelength). Therefore, for example, if the diameter of the cluster is 0.1 μm or less, the cluster is also transparent to visible light.

  The medium A is not limited to a substance exhibiting the Pockels effect or the Kerr effect as described above. For this reason, the medium A has a cubic structure in which the molecular arrangement has a cubic symmetry with a scale less than the visible light wavelength (for example, nanoscale), and is optically isotropic (non-patent document). You may have literature 3 * 6-8). The cubic phase is one of the liquid crystal phases of the liquid crystalline substance that can be used as the medium A. As the liquid crystalline substance exhibiting the cubic phase, for example, the following structural formula (5)

BABH8 etc. which are shown by these. When an electric field is applied to such a liquid crystalline substance, the fine structure is distorted and optical modulation can be induced.

  BABH8 is cubic symmetries (cubic symmetries) in the temperature range of 136.7 ° C. or higher and 161 ° C. or lower, with a lattice constant of about 6 nm, which is one order of magnitude smaller than the optical wavelength and less than the visible light wavelength. The cubic phase (cubic phase) which consists of an ordered structure which has is shown. Thus, BABH8 has an ordered structure with a scale less than the visible light wavelength in the above temperature range, and exhibits optical isotropy (if it is macroscopically isotropic) when no electric field is applied. Thus, good black display can be performed under crossed Nicols.

  On the other hand, when an electric field (voltage) is applied between the comb-shaped electrodes 4 and 5 while controlling the temperature of the BABH 8 to 136.7 ° C. or more and 161 ° C. or less using, for example, the heating means described above, cubic symmetry is obtained. Distortion occurs in the structure (ordered structure). That is, the BABH8 is isotropic in the above temperature range when no electric field is applied, and exhibits optical anisotropy when an electric field (voltage) is applied.

  Thereby, birefringence occurs in the medium layer 3, and thus the display element 70 can perform good white display. Note that the direction in which birefringence occurs is constant, and its magnitude changes with the application of an electric field (voltage). The voltage transmittance curve showing the relationship between the voltage applied between the comb electrodes 4 and 5 and the transmittance is stable in a temperature range of 136.7 ° C. or higher and 161 ° C. or lower, that is, a wide temperature range of about 20K. It becomes a curve. For this reason, when the BABH 8 is used as the medium A, temperature control can be performed very easily. That is, since the medium layer 3 made of BABH8 is a thermally stable phase, it does not exhibit abrupt temperature dependence and is extremely easy to control the temperature.

Further, as the medium A, it is possible to realize a system that is optically isotropic, in which liquid crystal molecules are filled with aggregates that are radially aligned with a size less than the visible light wavelength. As a method, the liquid crystal microemulsion described in Non-Patent Document 4, the liquid crystal / fine particle dispersion system described in Non-Patent Document 5 (mixed system in which fine particles are mixed in a solvent (liquid crystal), hereinafter simply referred to as a liquid crystal fine particle dispersion system) It is also possible to apply the method described below. When an electric field is applied to these, a set of radial orientations is distorted, and optical modulation can be induced.

  Any of these liquid crystalline substances may be liquid crystalline as a single substance, or may be liquid crystalline by mixing a plurality of substances. Other non-liquid crystalline substances may be mixed. Furthermore, a polymer / liquid crystal dispersion material as described in Non-Patent Document 1 can also be applied. Further, a gelling agent as described in Non-Patent Document 2 may be added.

  The medium A preferably contains a polar molecule. For example, nitrobenzene or the like is suitable as the medium A. Nitrobenzene is also a type of medium that exhibits the Kerr effect.

  Hereinafter, examples of the substance or the form of the substance that can be used as the medium A will be shown, but the present invention is not limited to the following examples.

[Smectic D phase (SmD)]
The smectic D phase (SmD) is one of liquid crystal phases of a liquid crystalline material that can be used as the medium A, has a three-dimensional lattice structure, and has a lattice constant of less than a visible light wavelength. For this reason, the smectic D phase is optically isotropic.

  Examples of liquid crystalline substances exhibiting a smectic D phase include the following general formulas (6) and (7) described in Non-Patent Document 3 or Non-Patent Document 8.

ANBC16 represented by the following. In the general formulas (6) and (7), m represents an arbitrary integer, specifically, m = 16 in the general formula (6), m = 15 in the general formula (7), and X Represents a —NO ₂ group.

The ANBC16 exhibits a smectic D phase in a temperature range of 171.0 ° C. to 197.2 ° C. In the smectic D phase, a plurality of molecules form a three-dimensional lattice such as jungle gym (registered trademark), and the lattice constant thereof is several tens of nm or less, which is less than the visible light wavelength. That is, the smectic D phase has cubic symmetry and has an orientation order (ordered structure) less than the visible light wavelength. In addition, the lattice constant of ANBC16 shown in this embodiment is about 6 nm. For this reason, the smectic D phase is optically isotropic. However, in the above temperature range where the ANBC 16 exhibits a smectic D phase, the ANBC
When an electric field is applied to 16, the ANBC 16 molecules themselves have dielectric anisotropy, and the molecules are oriented in the direction of the electric field, so that the lattice structure is distorted. That is, the optical anisotropy appears in ANBC16. Note that the material of the display element 70 according to the present embodiment is not limited to ANBC16, and any material exhibiting a smectic D phase changes the degree of optical anisotropy between when an electric field is applied and when no electric field is applied. It can be applied as A.

[Liquid crystal microemulsion]
The liquid crystal microemulsion is an O / W type microemulsion proposed in Non-Patent Document 4 (a system in which water is dissolved in oil in the form of water droplets in an oil, and the oil becomes a continuous phase). Is a generic term for a system (mixed system) in which oil molecules are replaced with thermotropic liquid crystal molecules.

  Specific examples of the liquid crystal microemulsion include, for example, pentylcyanobiphenyl (5CB), which is a thermotropic liquid crystal showing a nematic liquid crystal phase, and a lyotropic (lyotropic) showing a reverse micelle phase, as described in Non-Patent Document 4. There is a mixed system with an aqueous solution of didodecyl ammonium bromide (DDAB) which is a liquid crystal. This mixed system has a structure represented by schematic diagrams as shown in FIGS.

  In this mixed system, the diameter of reverse micelles is typically about 50 mm, and the distance between the reverse micelles is about 200 mm. These scales are about an order of magnitude smaller than the wavelength of light. That is, the above mixed system (liquid crystal microemulsion) has an alignment order (ordered structure) less than the visible light wavelength. In addition, reverse micelles exist randomly in three-dimensional space, and 5CB are radially oriented around each reverse micelle. Therefore, this mixed system is optically isotropic.

  When an electric field is applied to a medium composed of this mixed system, the molecule itself tends to move in the direction of the electric field because there is dielectric anisotropy in 5CB. That is, orientation anisotropy appears in a system that is optically isotropic because it is oriented radially around a reverse micelle, and optical anisotropy appears. The display element 70 according to the present embodiment is not limited to the above mixed system as long as it is a liquid crystal microemulsion that is optically isotropic when no electric field is applied and exhibits optical anisotropy when an electric field is applied. It can be applied as medium A.

[Lyotropic LCD]
The lyotropic liquid crystal means a liquid crystal of another component system in which the main molecules forming the liquid crystal are dissolved in a solvent having other properties (such as water or an organic solvent). In the present embodiment, a lyotropic liquid crystal having a specific phase can be applied as the lyotropic liquid crystal. Here, the specific phase is a phase in which the degree of optical anisotropy changes between when an electric field is applied and when no electric field is applied. For example, a phase that is optically isotropic when no electric field is applied. It is. Examples of such a specific phase include a micelle phase, a sponge phase, a cubic phase, and a reverse micelle phase described in Non-Patent Document 11. FIG. 9 shows a classification diagram of the lyotropic liquid crystal phase.

  Surfactants that are amphiphilic substances include substances that develop a micelle phase. For example, an aqueous solution of sodium decyl sulfate, which is an ionic surfactant, an aqueous solution of potassium palmitate, and the like form spherical micelles. Further, in a mixed solution of polyoxyethylene nonylphenyl ether, which is a nonionic surfactant, and water, micelles are formed by the nonylphenyl group acting as a hydrophobic group and the oxyethylene chain acting as a hydrophilic group. In addition, micelles are formed even in an aqueous solution of a styrene-ethylene oxide block copolymer.

For example, spherical micelles exhibit a spherical shape by packing molecules (forming molecular aggregates) in all spatial directions. Moreover, since the size of the spherical micelle is less than the visible light wavelength, it does not show optical anisotropy and looks isotropic. That is, the spherical micelle has an ordered structure (orientation order) less than the visible light wavelength. However, when an electric field is applied to such spherical micelles, the spherical micelles are distorted, so that optical anisotropy is expressed. Therefore, a lyotropic liquid crystal having a spherical micelle phase can also be applied as the medium A of the display element 70 according to the present embodiment. The same effect can be obtained by using not only the spherical micelle phase but also other micelle phases, that is, string-like micelle phase, elliptical micelle phase, rod-like micelle phase, and the like as the medium A.

  Further, it is generally known that reverse micelles in which a hydrophilic group and a hydrophobic group are exchanged are formed depending on the conditions of concentration, temperature, and surfactant. Such reverse micelles optically show the same effects as micelles. Therefore, by applying the reverse micelle phase as the medium A, an effect equivalent to that obtained when the micelle phase is used is obtained. The liquid crystal microemulsion described above is an example of a lyotropic liquid crystal having a reverse micelle phase (reverse micelle structure).

  Further, an aqueous solution of pentaethylene glycol-dodecyl ether, which is a nonionic surfactant, has a concentration and temperature range showing a sponge phase and a cubic phase as shown in FIG. Such a sponge phase or cubic phase is a transparent substance because it has an order (orientation order, ordered structure) less than the visible light wavelength. That is, a medium composed of these phases is optically isotropic. When an electric field (voltage) is applied to a medium composed of these phases, the orientation order (ordered structure) changes and optical anisotropy appears. Therefore, a lyotropic liquid crystal having a sponge phase or a cubic phase can also be applied as the medium A of the display element 70 according to the present embodiment.

[Liquid crystal fine particle dispersion]
The medium A may be, for example, a liquid crystal fine particle dispersion system in which latex particles having a diameter of about 100 mm whose surface is modified with a sulfate group are mixed in an aqueous solution of a nonionic surfactant pentaethylene glycol-dodecyl ether. Good. In the liquid crystal fine particle dispersion system, a sponge phase is expressed. As the medium A used in the present embodiment, the liquid crystal fine particle dispersion system expressing the above-described micelle phase, cubic phase, reverse micelle phase, etc., that is, when an electric field is applied. It may be a liquid crystal fine particle dispersion system showing a phase in which the degree of optical anisotropy changes when no electric field is applied. In addition, by using the DDAB in place of the latex particles, an alignment structure similar to the liquid crystal microemulsion described above can be obtained.

[Dendrimer]
A dendrimer is a three-dimensional hyperbranched polymer having a branch for each monomer unit. Since dendrimers have many branches, they have a spherical structure when the molecular weight exceeds a certain level. Since this spherical structure has an order (ordered structure, orientation order) less than the visible light wavelength, it is a transparent material, and the orientation order is changed by application of an electric field (voltage), and optical anisotropy appears. (The degree of optical anisotropy changes). Therefore, a dendrimer can also be applied as the medium A of the display element 70 according to the present embodiment. Further, by using the dendrimer in place of DDAB in the liquid crystal microemulsion described above, an alignment structure similar to that of the liquid crystal microemulsion described above can be obtained. The medium thus obtained can also be applied as the medium A.

[Cholesteric blue phase]
It is known that the cholesteric blue phase has a three-dimensional periodic structure in the helical axis, and the structure has high symmetry (for example, see Non-Patent Documents 6 and 7). . The cholesteric blue phase is an almost transparent substance because it has an order (ordered structure, orientation order) less than the visible light wavelength, and the degree of orientation order is changed by application of an electric field, and optical anisotropy appears. That is, the cholesteric blue phase is almost optically isotropic, and the liquid crystal molecules are oriented in the direction of the electric field when an electric field is applied, so that the lattice is distorted and exhibits optical anisotropy (the degree of optical anisotropy is Change).

  As a substance showing a cholesteric blue phase, for example, “JC1041” (trade name, mixed liquid crystal manufactured by Chisso Corporation) is 48.2 mol%, “5CB” (4-cyano-4′-pentylbiphenyl, nematic liquid crystal). A composition obtained by mixing 47.4 mol% and “ZLI-4572” (trade name, chiral dopant manufactured by Merck & Co., Inc.) at a ratio of 4.4 mol% is known. The composition exhibits a cholesteric blue phase in the temperature range of 330.7K to 331.8K.

[Smectic blue phase]
Similar to the cholesteric blue phase, the smectic blue (BP _Sm ) phase has a highly symmetric structure (for example, see Non-Patent Documents 7 and 10, etc.) and has an order less than the visible light wavelength (ordered structure, orientation order). Therefore, it is a substantially transparent substance, and the degree of orientational order is changed by application of an electric field to develop optical anisotropy (the degree of optical anisotropy changes). That is, the smectic blue phase is optically substantially isotropic, and the liquid crystal molecules are oriented in the direction of the electric field when an electric field is applied, so that the lattice is distorted and optical anisotropy is exhibited.

In addition, as a substance which shows a smectic blue phase, FH / FH / HH-14BTMHC etc. which are described in the said nonpatent literature 10 are mentioned, for example. The material exhibits a BP _Sm 3 phase at 74.4 ° C. to 73.2 ° C., a BP _Sm 2 phase at 73.2 ° C. to 72.3 ° C., and a BP _Sm 1 phase at 72.3 ° C. to 72.1 ° C. . Since the BP _Sm phase has a highly symmetric structure as shown in Non-Patent Document 7, it generally exhibits optical isotropy. Further, when an electric field is applied to the substance FH / FH / HH-14BTMHC, the lattice is distorted by the liquid crystal molecules being directed in the electric field direction, and the substance exhibits optical anisotropy. Therefore, the same substance can be used as the medium A of the display element 70 according to the present embodiment.

  As described above, the substance that can be used as the medium A in the display element 70 according to the present embodiment is one whose optical anisotropy (refractive index, orientational order) changes even when an electric field is applied. In other words, it may be a substance exhibiting the Pockels effect or the Kerr effect, and may be composed of molecules exhibiting any of a cubic phase, a smectic D phase, a cholesteric blue phase, and a smectic blue phase. A lyotropic liquid crystal or a liquid crystal fine particle dispersion system showing any of a micelle phase, a sponge phase, and a cubic phase may be used. The medium A may be a liquid crystal microemulsion, a dendrimer (dendrimer molecule), an amphiphilic molecule, a copolymer, or a polar molecule other than the above.

  The medium A is not limited to a liquid crystal substance, and preferably has an ordered structure (orientation order) less than the visible light wavelength when an electric field is applied or when no electric field is applied. If the ordered structure is less than the visible light wavelength, it is optically isotropic. Therefore, by using a medium whose ordered structure is less than the visible light wavelength when an electric field is applied or when no electric field is applied, the display state can be reliably changed between when no electric field is applied and when an electric field is applied.

  Hereinafter, in this embodiment, pentylcyanobiphenyl (5CB) represented by the structural formula (1) is used as the medium A. However, the medium A is not limited to this. Instead of the above 5CB, the various substances described above can be applied.

According to the present embodiment, ITO is used as the comb-shaped electrodes 4 and 5, the line width is 5 μm, the distance between the electrodes is 5 μm, the layer thickness of the medium layer 3 (that is, the distance between the substrates 1 and 2) is 10 μm, 5CB is used as A, and the above 5CB is maintained at a temperature immediately above the phase transition of the nematic isotropic phase (a temperature slightly higher than the phase transition temperature, for example, +0.1 K) by an external heating device (heating means) The transmittance could be changed by applying (voltage). The above 5
CB exhibits a nematic phase at a temperature lower than 33.3 ° C. and an isotropic phase at a temperature higher than that.

In the present embodiment, directions of optical anisotropy at the time of applying an electric field are different from each other on domains D _M and D _M ′ (minute regions) described later on the opposing surfaces of the substrates 1 and 2. A dielectric thin film (alignment film) (not shown) that has been subjected to rubbing treatment may be formed as necessary. Since the dielectric thin film is formed inside at least one of the pair of substrates 1 and 2, the degree of the order of orientation (ordered structure, orientation order) can be improved. An electro-optical effect, for example, a larger Kerr effect can be obtained.

  Each of the dielectric thin films may be an organic film or an inorganic film, and is not particularly limited as long as the orientation effect can be obtained. When the thin film is formed of an organic thin film, it exhibits a good alignment effect, and therefore it is more desirable to use an organic thin film as the dielectric thin film. Among such organic thin films, polyimide has high stability and reliability, and exhibits an extremely excellent alignment effect. Therefore, a display element 70 exhibiting better display performance can be obtained by using polyimide as the dielectric thin film material. Can be provided.

  The dielectric thin film may be formed so as to cover the comb-shaped electrodes 4 and 5 on the inner side of at least one of the pair of substrates 1 and 2, for example, on the substrate 1. It is not limited. In addition, the dielectric thin film provided on the substrate 1 and the dielectric thin film provided on the substrate 2 are, for example, opposite to each other along the comb-tooth portions 4a and 5a of the comb-shaped electrodes 4 and 5 A rubbing process is performed.

  Next, the display principle of the display element (display element 70) according to the present exemplary embodiment will be described below with reference to FIGS. 3 (a) and 3 (b) to FIGS. 5 (a) to 5 (h) and FIG. .

  In the following description, a transmissive display element is mainly used as the display element 70 according to the present embodiment, which is optically isotropic and preferably isotropic when no electric field is applied. The case where a substance that exhibits optical anisotropy by application is used will be described as an example, but the present invention is not limited to this.

  FIG. 3A is a cross-sectional view schematically showing a medium of the display element 70 in an electric field non-application state (OFF state), and FIG. 3B is a cross-sectional view of the display element 70 in an electric field application state (ON state). It is a figure which shows a cross section typically. FIG. 4 is a graph showing the relationship between the applied voltage and the transmittance in the display element 70. FIGS. 5A to 5H show the display element (display element 70) according to the present embodiment and a conventional liquid crystal. The difference between the display principle and the display element is shown by the average refractive index ellipsoid shape of the medium when no electric field is applied (OFF state) and when an electric field is applied (ON state) (the shape of the cut surface of the refractive index ellipsoid). And FIG. 5A to FIG. 5H sequentially show the display element (display element 70) according to the present embodiment when no electric field is applied (OFF state). ), A cross-sectional view of the display element (display element 70) when an electric field is applied (ON state), a cross-sectional view of a conventional TN (Twisted Nematic) type liquid crystal display element when no electric field is applied, and the TN type Cross-sectional view of liquid crystal display element when electric field is applied, conventional VA (Vertical Alignment) Sectional view when no electric field is applied to the liquid crystal display element of the VA mode, sectional view when the electric field is applied to the VA liquid crystal display element, and sectional view of the conventional IPS (In Plane Switching) liquid crystal display element when no electric field is applied FIG. 3 is a cross-sectional view of the IPS liquid crystal display element when an electric field is applied.

In general, the refractive index in a material is not isotropic and varies depending on the direction. This refractive index anisotropy (optical anisotropy) is a direction parallel to the substrate surface (in-plane direction), a direction opposite to the comb electrodes 4 and 5, and a direction parallel to the substrate surface (in-substrate surface). Direction) and a direction perpendicular to the opposing direction of the comb electrodes 4 and 5 and a direction perpendicular to the substrate surface (substrate normal direction) are x, y, and z directions, respectively, and an arbitrary orthogonal coordinate system (X ₁ , X ₂ , X ₃ )

(N _ji = n _ij , i, j = 1,2,3)
(Refractive index ellipsoid) (for example, refer nonpatent literature 12). Here, when the above equation (1) is rewritten using the coordinate system (Y ₁ , Y ₂ , Y ₃ ) in the principal axis direction of the ellipsoid, the following equation (2)

Indicated by n ₁ , n ₂ , n ₃ (hereinafter referred to as nx, ny, nz) are called main refractive indexes, and correspond to half the length of the three main axes in the ellipsoid. Considering a light wave traveling in a direction perpendicular to the Y ₃ = 0 plane from the origin, this light wave has polarization components in the directions of Y ₁ and Y _2, and the refractive indexes of the respective components are nx and ny, respectively. . In general, for light traveling in an arbitrary direction, the plane that passes through the origin and is perpendicular to the traveling direction of the light wave is considered to be the cut surface of the refractive index ellipsoid, and the principal axis direction of this ellipse is the component direction of the polarization of the light wave. Yes, half the length of the main axis corresponds to the refractive index in that direction.

  First, the difference in display principle between the display element 70 according to the present embodiment and the conventional liquid crystal display element will be described by taking a TN system, a VA system, and an IPS system as examples of the conventional liquid crystal display element.

  As shown in FIGS. 5C and 5D, in the conventional TN liquid crystal display element, a liquid crystal layer 105 is sandwiched between a pair of substrates 101 and 102 arranged opposite to each other. Are provided with transparent electrodes 103 and 104 (electrodes), respectively, and when no electric field is applied, the major axis direction of the liquid crystal molecules in the liquid crystal layer 105 is twisted and aligned. Sometimes, the major axis direction of the liquid crystal molecules is aligned along the electric field direction. The average refractive index ellipsoid 105a in this case has a direction (major axis direction) in which the principal axis direction (major axis direction) is parallel to the substrate surface (in-plane direction) as shown in FIG. 5C when no electric field is applied. When the direction and the electric field are applied, as shown in FIG. 5D, the principal axis direction faces the normal direction of the substrate surface. That is, the shape of the refractive index ellipsoid 105a is an ellipse between when no electric field is applied and when an electric field is applied, and the major axis direction (major axis direction, direction of the refractive index ellipsoid 105a) is changed by the electric field application. That is, the refractive index ellipsoid 105a rotates. Note that the shape and size of the refractive index ellipsoid 105a are almost the same between when no electric field is applied and when an electric field is applied.

As shown in FIGS. 5E and 5F, a conventional VA liquid crystal display element has a liquid crystal layer 205 sandwiched between a pair of substrates 201 and 202 arranged opposite to each other. Are provided with transparent electrodes (electrodes) 203 and 204. When no electric field is applied, the major axis direction of the liquid crystal molecules in the liquid crystal layer 205 is aligned in a direction substantially perpendicular to the substrate surface. However, when an electric field is applied, the major axis direction of the liquid crystal molecules is aligned in a direction perpendicular to the electric field. As shown in FIG. 5E, the average refractive index ellipsoid 205a in this case has its principal axis direction (major axis direction) oriented in the normal direction of the substrate surface when no electric field is applied. As shown in FIG. 4, when an electric field is applied, the principal axis direction is in a direction parallel to the substrate surface (in-plane direction of the substrate). That is,
Also in the case of a VA liquid crystal display element, the shape of the refractive index ellipsoid 205a is an ellipse when no electric field is applied and when an electric field is applied, as in the case of the TN liquid crystal display element. The direction changes (refractive index ellipsoid 205a rotates). Further, the shape and size of the refractive index ellipsoid 205a are almost the same between when no electric field is applied and when an electric field is applied.

  In addition, as shown in FIGS. 5G and 5H, the conventional IPS liquid crystal display element has a configuration in which a pair of electrodes 302 and 303 are disposed opposite to each other on the same substrate 301. By applying an electric field (voltage) to the liquid crystal layer sandwiched between a counter substrate (not shown) by the electrodes 302 and 303, the alignment direction of liquid crystal molecules in the liquid crystal layer (the principal axis direction of the refractive index ellipsoid 305a) (Major axis direction) is changed, and different display states can be realized when no electric field is applied and when an electric field is applied. That is, in the case of the IPS mode liquid crystal display element, similarly to the TN mode and VA mode liquid crystal display elements, when no electric field is applied as shown in FIG. 5G and when an electric field is applied as shown in FIG. The shape and size of the refractive index ellipsoid 305a are not substantially changed (that is, the ellipsoid remains in the shape of an ellipse), and the principal axis direction is changed by applying an electric field (the refractive index ellipsoid 305a rotates).

  As described above, in the conventional liquid crystal display element, the liquid crystal molecules are aligned in some direction (typically one direction) even when no electric field is applied, and the alignment direction of each molecule is aligned by applying the electric field. In the state, the orientation direction is changed to perform display (modulation of transmittance). That is, the electric field is applied only to the principal axis (major axis) direction of the refractive index ellipsoid while maintaining the shape and size of the refractive index ellipsoid (that is, the elliptical shape) when no electric field is applied and when an electric field is applied. The display is performed by using the rotation (change) by. Therefore, the major axis direction of the refractive index ellipsoid is not always perpendicular or parallel to the electric field application direction. That is, in the conventional liquid crystal display element, the degree of alignment order of liquid crystal molecules is substantially constant, and display (modulation of transmittance) is performed by changing the alignment direction. That is, in the conventional liquid crystal display element, the direction of the easy alignment axis changes with the application of an electric field while the degree of alignment order remains substantially constant.

  On the other hand, in the display element 70 according to the present embodiment, as shown in FIGS. 5A and 5B, the shape of the refractive index ellipsoid 3a when no electric field is applied is spherical, that is, optically equal. (Nx = ny = nz, degree of orientational order at a scale of visible light wavelength or more≈0 (almost zero)), and anisotropy (nx> ny, scale of visible light wavelength or more by applying an electric field) The degree of orientation order of> 0) develops, and the refractive index ellipsoid 3a becomes elliptic (shows optical anisotropy). At this time, the major axis direction of the refractive index ellipsoid 3a is perpendicular to the electric field direction. That is, when the dielectric anisotropy of the dielectric material is negative (negative type liquid crystal), the major axis direction of the refractive index ellipsoid 3a is perpendicular to the electric field direction (orthogonal state) at all voltage values, and the dielectric anisotropic When the property is positive (positive type liquid crystal), the major axis direction of the refractive index ellipsoid 3a is parallel to the electric field direction at all voltage values. In the present invention, the electric field direction and at least one of the principal axis directions of the refractive index ellipsoid 3a are always parallel or orthogonal. In the present invention, the degree of orientation order on a scale longer than the visible light wavelength ≈ 0 (there is almost no order of orientation) means that the liquid crystal molecules are in a certain direction when viewed on a scale smaller than visible light. However, when viewed on a scale larger than visible light, it means that the orientation direction is averaged and there is no orientation order. That is, the degree of orientational order is so small that it does not have any influence on the visible light wavelength region and light having a wavelength larger than the visible light wavelength region. For example, a state where black display is realized under crossed Nicols is shown. On the other hand, in the present invention, the degree of orientation order at a scale of visible light wavelength or more> 0 indicates that the degree of orientation order at a scale of visible light wavelength or more is larger than a substantially zero state. The state where white display is realized under the collar is shown. (In this case, gray which is a gradation display is also included).

That is, in the display element 70 according to the present embodiment, the molecules 8 are oriented in all directions when no electric field is applied. However, since these molecules 8 have an order (ordered structure, orientation order) lower than the visible light wavelength scale, optical anisotropy does not appear (the degree of orientation order at a scale longer than the visible light wavelength). As shown in FIG. 5A, the refractive index ellipsoid 3a has a spherical shape. However, as shown in FIG. 5B, when an electric field is applied, each molecule 8 has a negative dielectric anisotropy, so that it is oriented in the direction in the substrate plane (direction parallel to the substrate surface). Changes. At this time, the order structure below the visible light wavelength is distorted and optical anisotropy (degree of orientation order> 0 on the scale of visible light wavelength or more) is exhibited. As described above, in the display element 70 according to the present embodiment, the refractive index ellipsoid 3a has an isotropic shape (nx = ny = nz) when no electric field is applied. Anisotropy in shape (near lower interface (that is, interface with lower substrate 1 in FIG. 5B)): nx> ny, upper interface (that is, upper substrate 2 in FIG. 5B) )> Vicinity: ny> nx) is expressed in this way, for example. That is, in the display element 70 according to the present embodiment, the shape and size of the refractive index ellipsoid 3a are changed by applying an electric field. Here, nx, ny, and nz are the main refractive index in the direction parallel to the substrate surface (in-plane direction of the substrate) and the opposing direction of the comb electrodes 4 and 5, and the direction parallel to the substrate surface (substrate surface). The main refractive index in the direction perpendicular to the opposing direction of the comb electrodes 4 and 5 and the main refractive index in the direction perpendicular to the substrate surface (substrate normal direction).

  FIG. 24 is a schematic diagram showing the shape of the refractive index ellipsoid 3a of one molecule (molecule 8) of the medium A when an electric field is applied in the display element 70 shown in FIG. Thus, the shape of the refractive index ellipsoid 3a is indicated by the shape of the refractive index ellipsoid (ellipse) cut out from the plane passing through the origin and perpendicular to the traveling direction of the light wave, as described above. In addition, the principal axis direction of the ellipse is the component direction of the polarization of the light wave, and half the length of the principal axis corresponds to the refractive index in that direction.

  The medium A according to the present embodiment exhibits optical isotropy (isotropic phase) when no electric field is applied as described above, and exhibits optical anisotropy by applying an electric field. For this reason, the shape of the refractive index ellipsoid 3a when no electric field is applied is spherical, that is, optically isotropic, and anisotropy is manifested by applying an electric field.

  Therefore, as shown in FIG. 24, refraction in the principal axis direction of the ellipse (that is, the polarization component direction of the light wave) at the time of electric field application due to the development of optical anisotropy indicated by the refractive index in the direction perpendicular to the electric field direction. The refractive index in the major axis direction of the molecule 8 (abnormal light refractive index) is ne, the refractive index in the direction perpendicular to the major axis direction of the ellipse, that is, the refractive index in the minor axis direction of the molecule 8 (ordinary light). When the refractive index is no, the refractive index anisotropy (Δn) (birefringence change) is represented by Δn = ne−no.

  That is, in the present invention, the refractive index anisotropy (Δn) indicates a birefringence change represented by Δn = ne−no (ne: extraordinary light refractive index, no: ordinary light refractive index). While ne and no change, the conventional liquid crystal display device does not change ne and no.

  The major axis direction of the refractive index ellipsoid 3a when the electric field is applied is parallel to the electric field direction (in the case of a medium having a positive dielectric anisotropy) or perpendicular (in a medium having a negative dielectric anisotropy). When using).

  On the other hand, in the conventional liquid crystal display element, display is performed by rotating the major axis direction of the refractive index ellipsoid by applying an electric field, so that the major axis direction of the refractive index ellipsoid is parallel or perpendicular to the electric field direction. It does not always become.

As described above, the display element 70 according to the present embodiment modulates the degree of orientational order on a scale of, for example, a visible light wavelength or longer while the direction of optical anisotropy is constant (the electric field application direction does not change). The display is performed, and the degree of optical anisotropy of the medium A itself (for example, orientation order on a scale of visible light wavelength or more) is changed. Therefore, the display principle is greatly different from that of the conventional liquid crystal display element.

  The medium A enclosed in the medium layer 3 may be any medium as long as the degree of optical anisotropy changes with the application of an electric field, and is optically approximately isotropic when an electric field is applied or when no electric field is applied ( It may be a medium that has an orientational order degree on a scale of visible light or higher, and induces optical modulation by applying an electric field (that is, exhibits optical anisotropy by applying an electric field). Further, the medium A has an increased degree of orientational order at a scale of visible light or higher of the molecules 8 or molecular aggregates (clusters) with application of an electric field (a state in which optical modulation has already been induced (higher than visible light). It may be a substance (medium) in which the degree of orientational order of the molecules 8 on the scale of visible light or higher is further increased from the degree of orientational order on the scale> 0). In addition, the medium A is a medium in which the degree of orientational order (degree of optical anisotropy) of the molecules 8 at a scale of visible light or higher is reduced with the application of an electric field as compared with that before the application of the electric field. Well, for example, a state showing optical anisotropy from a state showing optical anisotropy by applying an electric field (degree of orientation order on a scale of visible light or higher> 0) (degree of orientation order on a scale of visible light or higher) ≈ The medium may change to 0).

  In the present invention, the change in the degree of optical anisotropy of the medium A due to the application of an electric field indicates that the shape of the refractive index ellipsoid 3a changes with the application of the electric field, as described above. If the optical anisotropy changes when no electric field is applied, and the degree of optical anisotropy changes when an electric field is applied, that is, if the optical anisotropy is manifested when an electric field is applied, The shape of the rate ellipsoid 3a changes from a spherical shape to an ellipse by applying an electric field. When the medium A exhibits optical anisotropy when no electric field is applied and exhibits optical isotropy when an electric field is applied, the shape of the refractive index ellipsoid 3a changes from an ellipse to a sphere when an electric field is applied. . The medium A exhibits optical anisotropy when no electric field is applied, and the degree of optical anisotropy increases or decreases by applying an electric field as compared to before applying the electric field. The length of the refractive index ellipsoid 3a in the major axis direction or the minor axis direction expands and contracts by the application of the electric field, and the ratio of the major axis and the minor axis changes before and after the electric field application (as a result, for example, the curvature changes). For example, when the degree of optical anisotropy is greater after application of an electric field, the ratio of the length in the major axis direction to the length in the minor axis direction than when the electric field is applied (when no electric field is applied) Becomes a larger ellipse. In addition, when the degree of optical anisotropy is smaller after application of an electric field, the ratio of the length in the major axis direction to the length in the minor axis direction is greater due to application of the electric field than before application of the electric field (when no electric field is applied). It becomes a small ellipse (that is, the ratio approaches 1 (including a substantially spherical shape)).

  As shown in FIG. 3A, the display element 70 according to the present embodiment has a medium A sealed between the substrates 1 and 2 when no electric field (voltage) is applied to the comb electrodes 4 and 5. Indicates an isotropic phase and is optically isotropic, so that black is displayed.

  On the other hand, as shown in FIG. 3B, when an electric field (voltage) is applied to the comb electrodes 4 and 5, each molecule 8 of the medium A is formed between the comb electrodes 4 and 5 in the major axis direction. The birefringence phenomenon appears because it is oriented along the electric field. Due to this birefringence phenomenon, the transmittance of the display element 70 can be modulated in accordance with the voltage between the comb electrodes 4 and 5, as shown in FIG.

  Note that the voltage required to modulate the transmittance of the display element 70 becomes large at a temperature sufficiently far from the phase transition temperature (transition point), but at a temperature just above the transition point, the voltage is around 0 to 100 V. It becomes possible to modulate the transmittance sufficiently.

For example, according to Non-Patent Document 9 and Non-Patent Document 12, if the refractive index in the electric field direction and the refractive index in the direction perpendicular to the electric field direction are n // and n⊥, respectively, the birefringence change (Δn = N // − n⊥) and the external electric field, that is, the electric field E (V / m), is expressed by Δn = λ · B _k · E ² . Λ is the wavelength (m) of incident light in vacuum, B _k is the Kerr constant (m / V ² ), E
Is the applied electric field strength (V / m).

The Kerr constant B _k is known to decrease with a function proportional to 1 / (T−Tni) as the temperature (T) increases, and it can be driven with a weak electric field strength in the vicinity of the transition point (Tni). However, as the temperature (T) rises, the required electric field strength increases rapidly. For this reason, the voltage necessary for modulating the transmittance increases at a temperature sufficiently far from the transition point (a temperature sufficiently higher than the transition point), but at a temperature immediately above the phase transition, the transmission is performed at a voltage of about 100 V or less. The rate can be modulated sufficiently.

As shown in FIG. 1, the display element 70 according to the present embodiment has a configuration in which at least two electrode pairs 10 including the comb electrodes 4 and 5 are provided in each pixel 71. In the pair 10, the comb-tooth portions 4 a and 5 a in the comb-shaped electrodes 4 and 5 constituting each electrode pair 10 are not parallel to the comb-tooth portions 4 a and 5 a in the other electrode pairs 10 adjacent in each pixel 71. In each pixel 71, an electric field is applied to the medium A in a partially different direction. Specifically, in the display element 70 according to the present embodiment, the comb-tooth portions 4a and 5a in each electrode pair 10 provided in each pixel 71 are in the other electrode pairs 10 adjacent in each pixel 71. The comb-tooth portions 4a and 5a are arranged so as to form an angle of 90 degrees, and an electric field substantially orthogonal to each other is applied. Thereby, in the display element 70 according to the present embodiment, in each pixel 71, at least two domains D _M · D _M ′ in which the directions of optical anisotropy at the time of applying an electric field form an angle of 90 degrees with each other are formed. (Micro area).

According to the study by the inventors of the present application, since each pixel 71 has at least two domains D _M · D _M ′ having different directions of optical anisotropy of the medium A when an electric field is applied, Display within a range of 60 ° polar angle (that is, within the range of optical axis ± 60 ° centered on the optical axis), which greatly exceeds the 45 ° polar angle called a wide viewing angle and is highly reliable in measurement. The color change can be suppressed, and the coloring phenomenon of the oblique viewing angle can be compensated for each other. As a result, the viewing angle characteristic can be greatly improved without impairing the transmittance.

  Further, as shown in FIG. 1, the polarizing plates 6 and 7 provided on both the substrates 1 and 2 are formed so that their absorption axes 6a and 7a, that is, the polarizing plate absorption axis directions are orthogonal to each other. . Further, the absorption axes 6a and 7a in the respective polarizing plates 6 and 7 and the electrode extending directions of the comb-tooth portions 4a and 5a in the comb-shaped electrodes 4 and 5 are formed at an angle of 45 degrees. For this reason, the absorption axes 6a and 7a of the polarizing plates 6 and 7 are formed so as to form an angle of 45 degrees with respect to the electric field application direction of the comb electrodes 4 and 5.

  The medium layer 3 can function as a shutter-type display element that exhibits optical anisotropy due to an increase in the degree of alignment order in the direction of electric field application, and changes in transmittance. Therefore, the direction of the optical anisotropy gives the maximum transmittance when the direction of the optical anisotropy forms an angle of 45 degrees with respect to the polarizing plate absorption axis directions orthogonal to each other.

In FIG. 6, the orientation in which the optical anisotropy appears in the two domains D _M and D _M ′ is ± θ (degrees) on the absorption axis 6 a of one of the polarizing plates 6 and 7. It shows the transmittance when it is assumed to exist at an angle of.

The transmittance (P) is estimated from P (%) = Sin ² (2θ), and as shown in FIG. 6, it can be seen that the θ has the maximum luminance when it is 45 degrees. If the transmittance when the θ is 45 degrees is 100%, it is felt that the human eye has the maximum luminance when the transmittance is approximately 90% or more. Therefore, the θ is 35 degrees. If it is within the range of ≦ θ ≦ 55 degrees, it is perceived that the human eye has almost the maximum luminance or luminance close to the maximum luminance, and if it is within the range of 35 degrees <θ <55 degrees, The human eye feels it has maximum brightness.

In order to form two domains D _M · D _M ′ that mutually compensate for the coloring phenomenon of the oblique viewing angle, the direction of the optical anisotropy in the domain D _M · D _M ′ is determined by the polarizing plate absorption axis. The preferred angle is ± 45 degrees with respect to the direction and 90 degrees as the angle between the domain directions.

  However, as described above, in order that θ is not in the range of 35 ° ≦ θ ≦ 55 ° with respect to the polarizing plate absorption axis, particularly in the range of 35 ° <θ <55 °, a large luminance difference is not felt. Even in the compensation of the coloring phenomenon, if the brightness of the domain regions of each other is about 10%, the difference in color is hardly felt, and a practically sufficient effect can be obtained in this range. That is, the angle formed by the optical anisotropy of each domain region is preferably within a range of 90 ° ± 20 ° (that is, within a range of 70 ° or more and 110 ° or less) from FIG. More preferably, it is within the range of less than ± 20 degrees (that is, within the range of more than 70 degrees and less than 110 degrees), and within the range of 90 degrees ± 10 degrees (that is, the range of 80 degrees to 100 degrees). Inner), and the most desirable angle is 90 degrees.

Therefore, considering the error of the human eye, the angle formed between the direction of optical anisotropy when the electric field is applied to each domain D _M · D _M ′ and the absorption axes 6a and 6b of the polarizing plates 6 and 7 is as follows. Each about 45 degrees (in the range of 45 degrees ± 10 degrees, preferably in the range of less than 45 degrees ± 10 degrees, more preferably in the range of 45 degrees ± 5 degrees, most preferably 45 degrees), The direction of optical anisotropy of each domain D _M · D _M ′ when an electric field is applied is about 90 degrees (within a range of 90 ° ± 20 °, preferably within a range of less than 90 ° ± 20 °, more The angle is preferably within a range of 90 ° ± 10 °, and most preferably 90 °. In particular, the angle formed by the absorption axes 6a and 6b of the polarizing plates 6 and 7 is within a range of less than 45 ° ± 10 ° and / or optical when the electric field is applied to each domain D _M · D _M ′. If the direction of anisotropy is within a range of less than 90 ° ± 20 °, the human eye feels that the maximum luminance can be obtained. In addition, the angle formed by the absorption axes 6a and 6b of the polarizing plates 6 and 7 is within a range of less than 45 degrees ± 5 degrees, and / or the optical characteristics of the domains D _M and D _M ′ when an electric field is applied. If the anisotropy direction is within a range of less than 90 ° ± 10 °, for example, the result shown in FIG. 6 shows that a luminance of 97% or more can be obtained as a measured value. If the angle formed by the absorption axes 6a and 6b of the polarizing plates 6 and 7 is 45 degrees, that is, the direction of the optical anisotropy when the electric field is applied to each of the domains D _M and D _M ′ is 90 degrees. For example, from the result shown in FIG. 6, a luminance of 100% can be obtained as a measurement value.

Therefore, as shown in FIG. 1, the absorption axis direction of each polarizing plate 6, 7 forms an angle of 45 degrees with respect to the electric field application direction of the comb-shaped electrodes 4, 5, and the comb-tooth portion of each electrode pair 10 4a and 5a create a display element 70 having an angle of 90 degrees with the comb-tooth portions 4a and 5a in the other adjacent electrode pairs 10 in each pixel 71, and the electric field of the display element 70 is set with white as a reference. When the color in the direction of 60 ° polar angle at the time of application was observed, no coloring phenomenon was observed at any viewing angle (viewing angles A ′, B ′, C ′, D ′, A, B, C, D). The viewing angles A ′, B ′, C ′, and D ′ are polarizing plate absorption axis directions, the viewing angles A and C are electric field application directions, and the viewing angles B and D are directions orthogonal to the electric field application directions. In the display device 70 shown in FIG. 1, a visual A, the electric field application direction indicated by C is intended to indicate by the electric field application direction in the domain D _{M ',} visual B, D is the electric field application direction in the domain D _M The visual sights A and C are perpendicular to the electric field application direction, but the observation results are the same in any case.

On the other hand, for comparison, as shown in FIG. 10, a comparative display element 80 in which the comb-tooth portions 4a and 5a of the comb-shaped electrodes 4 and 5 are formed in parallel in each pixel 81 was manufactured. . That is, in the comparative example using the comparative display element 80, each pixel 81 has a structure of one domain, and the same measurement (observation of coloring phenomenon) as described above is performed. As a result, viewing angles A ′ and B ′ are obtained. , C ′ and D ′ were hardly colored, but the viewing angles A and C were observed to be colored blue, and the viewing angles B and D were observed to be colored yellow, resulting in a decrease in display quality. Although this cause is not certain, it is considered that when the domain division is not performed as described above, there is chromatic dispersion in the optical anisotropy that the medium A develops by applying an electric field. In this comparative example, viewing angles A ′, B ′, C ′, and D ′ are polarizing plate absorption axis directions, viewing angles A and C are electric field application directions, and viewing angles B and D are directions orthogonal to the electric field application directions.

Further, as the display element 70 according to the present invention, when domain division is performed as shown in FIG. 1, that is, at least two different directions of the optical anisotropy of the medium A generated by applying an electric field are different in one pixel. FIG. 18 shows the result of measuring the chromaticity at an oblique viewing angle when two domains D _M · D _M ′ are provided and as a comparison, when domain division is not performed as shown in FIG.

18 is a graph (xy chromaticity diagram) showing chromaticity data in the display element 70 shown in FIG. 1 and the comparative display element 80 shown in FIG. 10, and the horizontal axis represents chromaticity (color) in the x-axis direction. The ordinate indicates chromaticity (chromaticity coordinates) in the y-axis direction. Note that the x-axis direction of the chromaticity of the display device 70 shown in FIG. 1, the x-direction, that is, for example, Domain D and a direction parallel to the substrate surface (substrate plane direction) in _M both comb-shaped electrodes 4 and 5 10 indicates the chromaticity (chromaticity coordinates) in the opposing direction of the comb-tooth portions 4a and 5a, and the chromaticity in the x-axis direction of the display element 80 shown in FIG. 10 is the substrate surface of one pixel 81 in the display element 80 The chromaticity (chromaticity coordinates) in the direction parallel to the substrate (in-plane direction of the substrate) and in the opposing direction of the comb-tooth portions 4a and 5a in the comb-shaped electrodes 4 and 5 is shown. Further, the y-axis direction of the chromaticity of the display device 70 shown in FIG. 1, the y-direction, for example direction parallel to the substrate surface in the domain D _M (substrate plane direction) at and between both comb-shaped electrodes 4 and 5 Comb The chromaticity (chromaticity coordinates) in the direction perpendicular to the opposing direction of the tooth portions 4a and 5a is shown. The chromaticity in the y-axis direction of the display element 80 shown in FIG. The chromaticity (chromaticity coordinates) in the direction parallel to the substrate surface (direction in the substrate surface) and in the opposing direction of the comb-tooth portions 4a and 5a in both comb-shaped electrodes 4 and 5 is shown.

  For the measurement of the chromaticity data, as the display elements 70 and 80, for example, as shown in FIGS. 2A and 2B, a pair of glass substrates 1 and 2 arranged to face each other. A medium A made of the mixture (I) shown below is sandwiched between the two substrates 2 as a medium layer 3, and polarizing plates 6 and 7 are respectively provided outside the pair of substrates 1 and 2. Cells (1), (2) in which comb electrodes 4, 5 are arranged opposite to each other on the surface of the substrate 1 facing the other substrate 2 in the direction in which the comb teeth 4 a, 5 a of the comb electrodes 4, 5 are engaged with each other. )It was used.

  Here, the medium layer 3 is composed of 44.7 mol% of “JC-1041xx” (trade name, manufactured by Chisso Corporation) which is a nematic liquid crystal mixture, and “5CB” (4-cyano-4′-pentylbiphenyl) which is a nematic liquid crystal. (Manufactured by Aldrich) 43.4 mol%, “ZLI-4572” (trade name, manufactured by Merck) 4.9 mol% as a chiral agent, a photopolymerizable monomer that forms an alignment aid by polymerization "EHA" (2-ethylhexyl acrylate, monoacrylate manufactured by Aldrich) 4.0 mol% and "RM257" (trade name, diacrylate monomer manufactured by Merck) 2.6 mol% as a photopolymerization initiator "DMPAP" (2,2-dimethoxy-2-pentylacetophenone, manufactured by Aldrich) 0.3 Mixture consisting mol% of (I), always with the temperature adjusted to cholesteric blue phase, is formed by performing ultraviolet irradiation without applying an electric field.

  The cholesteric blue phase is confirmed by adjusting the temperature of the mixture (I) to 260.0K to 326.4K with a temperature controller “FP90” (trade name) manufactured by METTLER TOLEDO. This was done by checking the texture specific to the blue phase.

  In the cells (1) and (2), comb electrodes 4 and 5 having the pattern shown in FIG. 1 or FIG. 10 are formed on the surface of the one substrate 1, respectively, with an electrode width of 9 μm and an interelectrode space of 10 μm. After that, the substrates 1 and 2 on which the comb-shaped electrodes 4 and 5 are formed are spaced by a distance of 5 μm (the thickness of the medium layer 3) through a spacer (not shown) such as plastic beads. After the substrates 1 and 2 are bonded together by sealing the periphery with a sealing material (not shown) except for the injection port of the mixture (I), The mixture (I) is injected to seal the injection port, and the polarizing plates 6 and 7 are bonded to the outside of the substrates 1 and 2 so that the absorption axes 6a and 7a are orthogonal to each other. As mentioned above, the mixture (I) is always cholesteric blue. While the temperature adjusted to phases, it was formed by performing ultraviolet irradiation without applying an electric field.

  For measurement of chromaticity, an optical measuring instrument “EZContrast” manufactured by ELDIM was used, the measurement temperature was 20 ° C., and the applied voltage was 84.3V.

  In FIG. 18, the chromaticity of the front is indicated by “x”. Further, the chromaticity at a polar angle of 60 degrees in the comparative cell (2) is determined based on one of the absorption axes 6a and 7a of the polarizing plates 6 and 7 (for example, the absorption axis 7a of the polarizing plate 7). When the azimuth angle with respect to the plate absorption axis (for example, the absorption axis 7a of the polarizing plate 7) is 45 degrees (that is, the azimuth angle is 45 degrees and the polar angle is 60 degrees (hereinafter referred to as (45, 60))) When the azimuth angle is 135 degrees (that is, the azimuth angle is 135 degrees (45 degrees + 90 degrees) and the polar angle is 60 degrees (hereinafter, referred to as (135, 60))), “Δ” is shown. In the cell (1) of the present invention, when the polar angle is 60 degrees and the azimuth angles are 45 degrees and 135 degrees (that is, (45, 60) and (135, 60)), ". That is, when the cell (1) of the present invention was used, the same chromaticity was obtained when the azimuth angle was 45 degrees and 135 degrees.

From the results shown in FIG. 18, when the domain division is not performed, when the display element 80 (cell (2)) is observed within the polar angle of ± 60 degrees, the color is within the range from “▲” to “Δ”. When the domain division (two domains per pixel in the cell (1)) is performed, the display element 70 (cells within the range of the polar angle ± 60 degrees is the same as the cell (2). Observing (1)), it can be seen that the color changes between “×” and “●”. Therefore, by performing the domain division, as shown in FIG. 18, color change within the range of polar angle ± 60 degrees (color change when the same image is viewed from different angles (chromaticity coordinate distance √ {Δ It can be seen that the range of the chromaticity coordinate change represented by x ² + Δy ² } can be accommodated in about half of the case where the domain division is not performed.

Further, as shown in FIGS. 19 to 22, in the cells (1) and (2), the orientations of optical anisotropy generated by applying an electric field of each domain D _M · D _M ′ in each pixel 71 are formed. angle ( _'the angle between the arrow d1-d2 in, and each domain D _M - D M each domain D _M & D _M)' orientation and the polarizers 6-optically anisotropic generated by application of an electric field Chromaticity (chromaticity coordinates) in the x-axis direction and the y-axis direction when viewed from the front of each cell (1) and (2), when the angle formed by the absorption axes 6a and 7a in FIG. The polarizing plate absorption axis (for example, the absorption axis of the polarizing plate 7 described above) with reference to either one of the absorption axes 6a or 7a of the polarizing plates 6 or 7 (for example, the absorption axis 7a of the polarizing plate 7) at a polar angle of 60 degrees. Each chromaticity (chromaticity coordinates) when the azimuth angle with respect to 7a) is 45 degrees and 135 degrees, In each direction, brightness when the Y value when the medium layer 3 is empty (when only air) is 1 (Y = 1) (relative Y value; hereinafter simply referred to as Y value) And measured.

19 to 22, arrows d1 and d2 are directions of optical anisotropy generated by applying an electric field in each of the domains D _M and D _M ′, and one domain (hereinafter referred to as “domain”) in the cell (1) of the present invention. For convenience of explanation, the direction of optical anisotropy generated by applying an electric field in “domain 1” and the direction of optical anisotropy generated by applying an electric field in comparative cell (2) are indicated by arrows. This is indicated by d1. In the cell (1), the direction of the optical anisotropy generated by the application of an electric field in the domain adjacent to the “domain 1” (hereinafter referred to as “domain 2” for convenience of description) is indicated by an arrow d2. In the following description, the ratio of “domain 1” and “domain 2” has the same ratio (1: 1) unless otherwise specified.

  19 to 22, the direction of optical anisotropy indicated by arrows d1 and d2 is symmetric with respect to any one of the polarizing plate absorption axes, or the absorption axes of the respective polarizing plates 6 and 7. The angles formed between 6a and 7a are equal. That is, each angle formed by the orientation of the optical anisotropy indicated by the arrow d1 and the orientation of the two polarizing plate absorption axes (absorption axis direction), the orientation of the optical anisotropy indicated by the arrow d2, and the two directions Each angle formed by the orientation of the polarizing plate absorption axis (absorption axis direction) is set to be the same angle.

  The Y value was measured using the above-mentioned ELDIM optical measuring instrument “EZContrast”, the measurement temperature was 20 ° C., and the applied voltage was 84.3 V.

As shown in FIG. 19, in the cells (1) and (2), the polarizing plate 6a and 7a with respect to one of the absorption axes 6a and 7a (here, the absorption axis 7a of the polarizing plate 7). An angle formed by the absorption axis (the absorption axis 7a of the polarizing plate 7) and the orientation of the optical anisotropy indicated by the arrow d1 (hereinafter referred to as angle (1) for convenience of explanation), and the other polarization Each angle formed by the plate absorption axis (here, the absorption axis 6a of the polarizing plate 6) and the orientation of the optical anisotropy indicated by the arrow d1 (hereinafter referred to as angle (2) for convenience of explanation) is 45 degrees. And an angle formed by the orientations of optical anisotropy generated by applying an electric field in each domain D _M · D _M ′ (“domain 1”, “domain 2”) indicated by arrows d1 and d2 (hereinafter, described) For the sake of convenience, the angle (3) is 90 degrees, that is, in the cell (1). The polarizing plate absorption axis (absorption axis 7a of the polarizing plate 7) with respect to any one of the absorption axes 6a and 7a of the polarizing plates 6 and 7 (here, the absorption axis 7a of the polarizing plate 7), and the above An angle formed by the orientation of the optical anisotropy indicated by the arrows d1 and d2 (hereinafter, for convenience of explanation, the polarizing plate absorption axis (the absorption axis 7a of the polarizing plate 7) and the optical anisotropy indicated by the arrow d2) The angle formed by the azimuth of each of the cells (denoted as angle (4)) is 45 degrees and 135 degrees (angle (1) = 45 degrees, angle (4) = 135 degrees), respectively. 2) When viewed from the front, the chromaticity (chromaticity coordinates) in the x-axis direction and the y-axis direction and the polar angle of 60 degrees, one of the absorption axes 6a and 7a of the polarizing plates 6 and 7 (for example, polarized light) With respect to the absorption axis 7a) of the plate 7, the azimuth angle with respect to the polarizing plate absorption axis (for example, the absorption axis 7a of the polarizing plate 7) is 45 degrees. Preliminary 135 degrees each chromaticity coordinate of the (that is, the chromaticity coordinates in the (45, 60) and (135,60)) shown in Table 1 together with Y values, at each chromaticity coordinates.

  In the measurement, when the cell (1) of the present invention was used, the same chromaticity was obtained when the azimuth angle was 45 degrees and 135 degrees. The chromaticity coordinates at (45, 60) and (135, 60) in FIG. Moreover, the chromaticity coordinate distance in the cell (1) and the cell (2) at this time was 0.0303 in the cell (1) of the present invention and 0.0887 in the cell (2) for comparison. .

  Further, as shown in FIG. 20, the angle (1) is 55 degrees and the angle (2) is 35 degrees (that is, the orientation of the optical anisotropy in each domain represented by d1 and d2 and the absorption axes of both polarizing plates). (When the angle (3) is 90 degrees, that is, the angle (1) = 55 degrees and the angle (4) = 145 degrees) 1) Chromaticity (chromaticity coordinates) in the x-axis direction and y-axis direction when viewed from the front of (2), chromaticity coordinates in (45, 60) and (135, 60), and each chromaticity coordinate Table 2 summarizes the Y values.

  In the above measurement, when the cell (1) of the present invention was used, the same chromaticity was obtained when the azimuth angle was 45 degrees and when the angle was 135 degrees. The chromaticity coordinates at (45, 60) and (135, 60) in FIG. Further, the chromaticity coordinate distance in the cell (1) and the cell (2) at this time was 0.0318 in the cell (1) of the present invention and 0.0862 in the cell (2) for comparison. .

  Further, as shown in FIG. 21, the angle (1) is 35 degrees and the angle (2) is 55 degrees (that is, the orientation of the optical anisotropy in each domain indicated by d1 and d2 and both polarizing plate absorption axes) 22 is 35 degrees or 55 degrees), and when the angle (3) is 110 degrees, that is, when the angle (1) = 35 degrees and the angle (4) = 145 degrees, FIG. As shown, the angle (1) is 55 degrees and the angle (2) is 35 degrees (that is, the angle formed between the orientation of optical anisotropy in each domain indicated by d1 and d2 and both polarizing plate absorption axes is When the angle (3) is 70 degrees, that is, when the angle (1) = 55 degrees and the angle (4) = 125 degrees, the cells (1), ( 2) Chromaticity (chromaticity coordinates) in the x-axis direction and y-axis direction when viewed from the front, (45 60) and (135,60 and the chromaticity coordinates in), a result of measuring a Y value of each chromaticity coordinates, both, the same results were obtained with the results shown in Figure 19. That is, in the case shown in FIG. 21 and the case shown in FIG. 22, the chromaticity coordinate distance by the cell (1) and the cell (2) is 0.0318 in the cell (1) of the present invention, and is for comparison. Of the above cell (2).

From the above measurement results, according to the present invention, the angle formed by the orientations of the optical anisotropy generated by the electric field application of each domain D _M · D _M ′ in each pixel 71 by dividing the domain as described above. (An angle formed between the arrows d1 and d2 in each domain D _M and D _M ′), and
As shown in FIGS. 19 to 22, various angles are formed between the orientation of optical anisotropy generated by applying an electric field of each domain D _M · D _M ′ and the absorption axes 6 a and 7 a of the polarizing plates 6 and 7. It can be seen that the chromaticity coordinate distance can be reduced even when the change is made, compared to the case where domain division is not performed. Therefore, according to the present invention, by dividing the domain as described above, the color change due to the difference in the viewing angle with respect to the same image can be made smaller than before (that is, the effect of improving the chromaticity coordinates can be obtained). You can).

  Further, from the above measurement results, it can be seen that when the front Y value (relative value) is compared in each case shown in FIGS. 19 to 22, the case shown in FIG. 19 is the largest (lightest). That is, the angle formed by the direction of optical anisotropy generated by applying an electric field in each domain and the polarizing plate absorption axis is 45 degrees, and the angle formed by the direction of optical anisotropy generated by applying an electric field in each domain is mutually It can be seen that the best results are obtained when the angle is 90 degrees.

  20 to 22, the orientations (d1, d2) of the optical anisotropy with respect to the absorption axes 6a and 7a of the polarizing plates 6 and 7 in the domains 1 and 2 are the orientations shown in FIG. Although rotated by ± 10 degrees, as shown in FIGS. 20 to 22, the symmetry of the angle formed by these d1 and d2 and the respective polarizing plate absorption axes (absorption axes 6a and 7a of the polarizing plates 6 and 7). From this point, even when the orientation of the optical anisotropy (d1, d2) is rotated in any direction with respect to the respective polarizing plate absorption axes (absorption axes 6a and 7a of the polarizing plates 6 and 7), The same result can be obtained.

  For comparison, as shown in FIG. 2 of Patent Document 1, a display element having a comb-shaped electrode having comb-shaped portions in a square shape in a plan view is manufactured for each pixel. Was measured. The angle (bending angle (bending angle)) formed by the “<”-shaped electrodes, that is, the electric field application direction between adjacent domains was set to 35 degrees from the structure shown in FIG. As a result, in the case of the above electrode structure, the transmittance was reduced to about 33% as compared with the comparative example (that is, the case where the domain was not divided (see FIG. 10)). However, although the coloring phenomenon depending on the viewing angle was not greatly improved, it was found that an improvement effect can be obtained as compared with the case where domain division is not performed.

  However, although the said patent document 1 is disclosing using the electrode of a square shape "<" shape in order to improve a viewing angle characteristic, the display element of the said cited reference 1 is the said electrode. It has a structure in which a polyimide film as a dielectric thin film is formed on the surface and the surface of the counter substrate, and these polyimide films are subjected to orientation treatment to orient molecular groups called clusters located on the polyimide film surface in a certain direction. However, the above cited reference 1 does not perform domain division and is different from the present invention.

  In Patent Document 1, it is considered that the SIPS mode technique in the liquid crystal display element is simply applied as it is. However, according to the examination by the inventors of the present application, in the above-described display element having a completely different display principle from the liquid crystal display element, the optimum shape in the SIPS mode is not preferable, and the domain division structure in the SIPS mode is applied as described above. In this case, it has been found that the problem of the present invention is not solved.

  In addition, as a result of examination by the inventors of the present application, in the SIPS (Super In Plane Switching) mode which is a kind of display method in the liquid crystal display element, the direction of the optical anisotropy generated by the electric field application of each domain is reversed, 90 degrees is not an appropriate angle, but is preferably closer to 0 degrees. The reason for this will be described below with reference to FIGS. 11 (a) and 11 (b).

FIG. 11 (a) shows that each of the "<"-shaped electrodes 51 and 52 in the SIPS mode has a bending angle (bending angle) of 90 degrees, that is, an angle at which the electric field application direction between adjacent domains is 90 degrees. It is a figure which shows typically rotation of the liquid crystal molecule 53 in the case of providing so that it may form. FIG. 11B shows that each of the “<”-shaped electrodes 51 and 52 in the SIPS mode has a bending angle (bending angle) of 35 degrees, that is, the electric field application direction between adjacent domains is 35 degrees. It is a figure which shows typically rotation of the liquid crystal molecule 53 in the case where it provides so that the angle may be made.

  As described above, in order to maximize the transmittance, the liquid crystal molecules 53 in each domain need to be rotated 45 degrees by the application of an electric field, and these liquid crystal molecules 53 rotate in the direction of the electric field application. In the case shown in FIG. 11A, the direction of electric field application and the direction of the liquid crystal molecules 53 must completely coincide with each other, and a large electric field application is required. On the other hand, in the case of FIG. 11B, the rotation of 45 degrees is merely a passing point, so that a large voltage is not required for the rotation up to 45 degrees. That is, in the domain division in the SIPS mode in the liquid crystal display element, it is only necessary that the electric field application directions are different from each other. The reason why the alignment direction and the electrodes 51 and 52 are slightly shifted from 0 degrees in the SIPS mode is to select one of two directions in which the liquid crystal molecules 53 are rotated by the electric field. In particular, a few degrees to about 20 degrees is sufficient.

As described above, according to the present embodiment, in the display element 70 using the medium A in which the degree of optical anisotropy changes with the application of an electric field, as shown in FIG. By providing the comb-shaped electrodes 4 and 5 so as to form two regions (domains D _M and D _M ′) whose application directions are orthogonal to each other, a visual field in which coloring phenomenon is suppressed in all directions without impairing transmittance. A display element 70 having a wide corner can be obtained. Although the reason why the coloring phenomenon is not observed at any viewing angle with the above-described configuration is not clear, the results are obtained by compensating the characteristics in the viewing angles A and C and the characteristics in the viewing angles B and D with each other. It is considered that the coloring phenomenon could be suppressed.

As described above, according to the display element 70 according to the present embodiment, the coloring phenomenon can be compensated for each other by two domains (domains D _M and D _M ′) having different optical anisotropy directions. The direction of optical anisotropy differs from the case where each pixel 71 has only a domain (for example, domain D _M ) in which the direction of optical anisotropy is only one direction (ie, domain D _M ). If other domains (for example, domain D _M ′) are mixed in each pixel 71 even at a small ratio, it is effective in suppressing the coloring phenomenon. In this case, the direction of the optical anisotropy when the electric field is applied in each domain D _M · D _M ′ preferably forms an angle within the range of 90 ° ± 20 ° as described above, and 90 ° ± It is more preferable to make an angle within a range of less than 20 degrees, and it is even more preferable to make an angle within a range of 90 ± 10 degrees.

  Here, in the arrangement of cell (1) shown in FIG. 19 (angle (1) = angle (2) = 45 degrees, angle (3) = 90 degrees, angle (4) = 135 degrees), “domain 1” And the ratio (ratio) between “domain 2” and “domain 2” in each pixel 71 when the ratio is changed (that is, the ratio of domains having different optical anisotropy in each pixel 71), (45 , 60) and (135, 60), the chromaticity coordinates (the chromaticity coordinates in the x-axis direction and the chromaticity coordinates in the y-axis direction), the Y value in each chromaticity coordinate, and the chromaticity in each cell having the above ratios. Table 3 summarizes the coordinate distance.

As is clear from the results shown in Tables 1 and 3, the chromaticity coordinates in the above (45, 60) and (135, 60) and the Y value in each chromaticity coordinate are different in optical anisotropy in each pixel 71. The smaller the domain ratio is, the smaller the value of the cell (2) (45, 60) shown in Table 1 becomes, and as the ratio approaches 0.5, the value of the cell (1) shown in Table 1 increases. Approaching the value. Then, the chromaticity coordinates in (45, 60) and (135, 60) and the Y value in each chromaticity coordinate are the same values as the cell (1) shown in Table 1 when the ratio is 0.5, As the ratio exceeds 0.5 and approaches 1, the value of cell 2 (135, 60) shown in Table 1 approaches. In this case, the chromaticity coordinate distance also decreases as the ratio approaches 0.5 (that is, “domain 1”: “domain 2” = 1: 1). The closer it is to the better. Further, from the above measurement results, it can be seen that when the ratio is in the range of 0.1 to 0.9, the improvement (compensation) effect of coloring is large visually.

  In the present embodiment, the transmissive display element is mainly described as an example of the display element 70. However, the present invention is not limited to this, and the display element 70 may be a reflective element. A display element of a type may be used.

  FIG. 12 shows an example of a schematic configuration of a reflective display element according to the present embodiment, to which the present invention is applied, as the display element 70 according to the present embodiment.

  In the reflective display element 70, for example, a reflective layer 41 is provided on one substrate 1 made of a glass substrate or the like, and a comb electrode 4 or the like such as ITO is provided on the reflective layer 41 via an insulating layer 42. 5 is provided. Other configurations are as described above. As the insulating layer 42, an organic film such as an acrylic resin; an inorganic film such as silicon nitride or silicon oxide can be used. As the reflective layer 41, an aluminum or silver thin film can be applied. In the above configuration, the reflective layer 41 can reflect light incident from the other substrate 2 made of a transparent substrate such as a glass substrate, and thus functions as a reflective display element.

  When the display element 70 according to the present embodiment is used as a reflective display element, the comb electrodes 4 and 5 are not limited to a transparent electrode material such as ITO as in the case of using as a transmissive display element. Moreover, conventionally well-known various materials can be used as electrode materials, such as metal electrode materials, such as aluminum. Further, the line width and inter-electrode distance (electrode interval) of the comb-shaped electrodes 4 and 5 are not particularly limited, and can be arbitrarily set according to the gap between the substrate 1 and the substrate 2, for example. it can.

  Furthermore, in the present embodiment, the case where a glass substrate is used as the substrate 1 or 2 has been described as an example. However, the present invention is not limited to this, and at least of the substrates 1 and 2, One substrate may be a transparent substrate, and various conventionally known substrates can be used, for example.

  The substrates 1 and 2 are not limited to those conventionally used as substrates, and may be, for example, in the form of a film or may have flexibility, at least As long as one side is transparent and the medium A can be held (clamped) between the substrates, that is, in the inside, various materials should be used depending on the type of the medium A, the state of the phase, and the like. Can do.

  In this embodiment, as a specific example, a case where a material that is optically isotropic when no electric field is applied and that exhibits optical anisotropy when an electric field is applied is used as a medium A will be described as an example. However, the present invention is not limited to this, and the medium A may be a substance that loses optical anisotropy by application of an electric field and exhibits optical isotropy as described above. Street.

  Hereinafter, a specific example in which the medium A is made of a material that loses optical anisotropy by application of an electric field and exhibits optical isotropy will be described.

In this specific example, transparent comb-shaped electrodes 4 and 5 made of ITO and an orientation made of polyimide are formed on the surface of one of the two transparent substrates 1 and 2 made of glass substrate facing the substrate 2. And a transparent dielectric substance 4′-n-alkoxy-3′-nitrobiphenyl-4-carboxylic acid (ANBC-22) is enclosed as a medium A between the substrates 1 and 2 did. The thickness of the medium layer 3 in the display element 70 was adjusted to 4 μm by previously spreading plastic beads on the opposing surfaces of the substrates 1 and 2.

  As described above, the polarizing plates 6 and 7 have the absorption axes 6a and 7a orthogonal to each other, and the absorption axes 6a and 7a of the polarizing plates 6 and 7 and the comb-tooth portions 4a and 4a of the comb-shaped electrodes 4 and 5, respectively. The electrodes 5a were provided on the outer sides of the substrates 1 and 2 (on the opposite side of the facing surface) so as to form an angle of 45 degrees with the electrode extending direction.

  The display element 70 thus obtained is maintained at a temperature near the phase transition of the smectic C phase to the cubic phase (up to about 10K on the low temperature side of the phase phase transition temperature) by an external heating device (heating means) When applied (an AC electric field of about 50 V (greater than 0 up to several hundred kHz)), the transmittance could be changed. That is, by applying an electric field to the smectic C phase (bright state) exhibiting optical anisotropy when no electric field was applied, it was possible to change to an isotropic cubic phase (dark state).

  Further, as shown in the second embodiment to be described later, substantially the same results were obtained even when electrodes were respectively provided on the substrates 1 and 2 to generate an electric field in the normal direction of the substrate surface. That is, substantially the same result was obtained not only in the horizontal direction of the substrate surface but also in the normal direction of the substrate surface.

  As described above, the medium A used in the display element 70 according to the present embodiment has optical anisotropy when no electric field is applied, and the optical anisotropy disappears when the electric field is applied. A medium exhibiting properties may be used.

  The medium A may have positive dielectric anisotropy or negative dielectric anisotropy. When a medium having a positive dielectric anisotropy is used as the medium A, the medium A needs to be driven by an electric field substantially parallel to the substrates 1 and 2, but a medium having a negative dielectric anisotropy is applied. This is not always the case. For example, it can be driven by an oblique electric field with respect to the substrates 1 and 2, and can also be driven by a vertical electric field. In this case, the electrode shape, material, and arrangement position may be changed as appropriate. If an electric field is applied vertically using a transparent electrode, it is advantageous in terms of aperture ratio.

  In the present embodiment, the case where at least two domains having different directions of the optical anisotropy of the medium when an electric field is applied exists as an example mainly in each pixel 71 is described. The embodiment is not limited to this, and the number of domains in each pixel 71 may be two or more. For example, an electrode arrangement (domain structure) as shown in FIG. 25 may be used. Considering the error of the human eye, the angle between the direction of optical anisotropy when the electric field is applied to each domain and the absorption axes 6a and 7a of the polarizing plates 6 and 7 is about 45 degrees (45 degrees), respectively. It is preferably within a range of ± 10 °, more preferably within a range of less than 45 ° ± 10 °, and even more preferably within a range of 45 ° ± 5 °. The directions of the optical anisotropy of adjacent domains when an electric field is applied are approximately 90 degrees (within a range of 90 degrees ± 20 degrees, preferably within a range of less than 90 degrees ± 20 degrees, more preferably 90 degrees). An angle within a range of ± 10 degrees, or almost the same direction (when the direction of optical anisotropy in one domain is a reference (0 degree), it is within a range of 0 degree ± 20 degrees, preferably 0 degrees. It is preferably within a range of less than ± 20 °, more preferably within a range of 0 ° ± 10 °.

That is, according to the present embodiment, two or more domains having an optical anisotropy direction at the time of applying an electric field having an angle of about 45 degrees with respect to the absorption axis of the polarizing plate are preferably about one another. By having an angle of 90 degrees (within a range of 90 ± 20 degrees, more preferably within a range of less than 90 ± 20 degrees, and even more preferably within a range of 90 ± 10 degrees), the domains Compensate for coloring. For this reason, as shown in FIG. 25, for example, the display element 70 according to the present embodiment has each pixel 71 about 45 degrees (45 degrees) with respect to one polarizing plate absorption axis (for example, the absorption axis 6a).
Domain having an optical anisotropy in the direction of an angle within a range of ± 10 °, more preferably within a range of less than 45 ° ± 10 °, and even more preferably within a range of 45 ° ± 5 °. About 45 degrees (within a range of 45 degrees ± 10 degrees, more preferably within a range of less than 45 degrees ± 10 degrees, with respect to the other polarizing plate absorption axis (for example, the absorption axis 7a), More preferably, it has at least one domain having optical anisotropy in a direction forming an angle of 45 ° ± 5 °.

  In the display element 70 shown in FIG. 25 as well, each pixel 71 has an optical anisotropy as compared with a case where only one domain (one domain) whose optical anisotropy direction is only one direction exists (that is, when the domain is not divided). If other domains having different anisotropy directions are mixed in each pixel 71 even in a small proportion, it is effective in suppressing the coloring phenomenon. In this case, the direction of the optical anisotropy when an electric field is applied in each domain preferably forms an angle within a range of 90 ° ± 20 ° as described above, and is within a range of less than 90 ° ± 20 °. It is more preferable that the angle is within the range of 90 ± 10 degrees.

Further, as described above, the ratio of each domain in each pixel 71 is the ratio of two domains having different optical anisotropy directions (“domain 1”: “domain 2”, eg, optically anisotropic in the x direction). The ratio of the domain having the property and the domain having the optical anisotropy in the y direction intersecting (orthogonal) in the same plane as the x direction (preferably about 1 to 9). 1: 1), and visually improved (compensation) effect of coloring is large. Therefore, for example, in FIG. 25, the area sum of domains having an angle of about 45 degrees with respect to the absorption axis 6a of one polarizing plate 6 (for example, D _M2 + D _M3 + D _M5 in FIG. If the direction of the optical anisotropy is the sum of the areas of the same domains, the domains may be provided separated (dispersed))) and the absorption axis 7a of the other polarizing plate 7 about the ratio of the 45-degree angle area sum of the domain _{D M} having a (e.g. _D M1 _{+ D M4} in FIG. 25) is 1: 9 to 1: 1 (preferably from about 1: 1) is preferably .

[Embodiment 2]
Another embodiment of the present invention will be described below with reference to FIGS. 13 (a) and 13 (b) to FIG. In the present embodiment, differences from the first embodiment will be mainly described, and components having the same functions as those used in the first embodiment are designated by the same reference numerals. A description thereof will be omitted.

  In the first embodiment, an electric field is applied in a direction parallel to the substrate surface. In the present embodiment, an example in which an electric field is applied in the normal direction of the substrate surface will be described.

  FIG. 13A is a cross-sectional view schematically showing a schematic configuration of a main part of the display element according to the present embodiment in an electric field non-application state (OFF state), and FIG. It is sectional drawing which shows typically schematic structure of the principal part of the display element concerning this Embodiment in an ON state. FIG. 14 is a diagram for explaining the orientation processing direction of each domain in one pixel in the display element according to the present embodiment, and FIG. 15 is for explaining the orientation processing direction of each pixel in the conventional display element. FIG.

  As shown in FIGS. 13A and 13B, the display element 70 according to the present embodiment includes transparent electrodes 21 and 22 instead of the comb electrodes 4 and 5 in the first embodiment. Each of the two opposing surfaces has a configuration provided.

  In such a display element 70 as well, the medium A is sealed between the substrates 1 and 2 when no electric field (voltage) is applied to the transparent electrodes 21 and 22 as shown in FIG. Since the medium A exhibits an isotropic phase and is optically isotropic, the display is black.

  On the other hand, as shown in FIG. 13B, when an electric field (voltage) is applied to the transparent electrodes 21 and 22, each molecule 8 of the medium A is formed between the transparent electrodes 21 and 22 in the major axis direction. The birefringence phenomenon appears because it is oriented in the direction perpendicular to the electric field. Due to this birefringence phenomenon, the transmittance of the display element 70 can be modulated in accordance with the voltage between the transparent electrodes 21 and 22.

  Even in the display element 70 having such a configuration, as in the first embodiment, the voltage necessary for modulating the transmittance increases at a temperature sufficiently higher than the phase transition temperature (transition point). At a temperature immediately above the transition point, the transmittance can be sufficiently modulated with a voltage of about 0 to 100 V.

  Further, as shown in FIGS. 13A and 13B, the display element 70 according to the present embodiment has a photofunctional functional group (hereinafter referred to as a photofunctional group) on the transparent electrodes 21 and 22. ) (That is, an alignment film (photo-alignment film) made of a material (compound) having a photofunctional group) is provided.

  In the present embodiment, transparent electrodes 21 and 22 made of ITO and alignment films 23 and 24 made of polyimide are formed on opposing surfaces of two transparent substrates 1 and 2 made of glass substrates, respectively. A transparent dielectric composed of a composition obtained by mixing the compounds represented by the structural formulas (2) to (4) in the ratio of 30% by weight, 40% by weight, and 30% by weight as the medium A between the two. Sex liquid was enclosed. It was confirmed that the dielectric liquid exhibits a negative nematic liquid crystal phase at a temperature lower than 113 ° C. and an isotropic phase at a temperature higher than that. Further, the thickness of the medium layer 3 in the display element 70 was adjusted to 5 μm by spreading plastic beads on the opposing surfaces of the substrates 1 and 2 in advance.

  The alignment films 23 and 24 were previously subjected to alignment treatment. The mutual orientation treatment directions were antiparallel, and the direction thereof was at an angle of 45 degrees with the polarizing plate absorption axis. Further, as shown in FIGS. 13 (a) and 13 (b), polarizing plates 6 and 7 were disposed outside the substrates 1 and 2, respectively. The display element 70 thus obtained is maintained at a temperature immediately above the nematic isotropic phase transition by an external heating device (heating means), and an electric field (voltage) is applied to change the transmittance. I was able to.

Further, in the present embodiment, as shown in FIG. 14, the surface of both substrates 1 and 2 (the alignment films 23 and 24) is irradiated with polarized ultraviolet light whose parallel polarization is parallel to express the alignment regulating force. By doing so, the two domains D _{M in} which the alignment regulating force directions (alignment processing directions) of both the substrates 1 and 2 are parallel to each other and the alignment regulating force directions (alignment processing directions) of the pixels 71 are orthogonal to each other. -Alignment treatment was performed so that D _M '(micro area) was formed.

Thereby, each pixel 71 has at least two domains D _M · D _M ′ (micro areas) in which the directions of the optical anisotropy of the medium A generated by applying an electric field make an angle of 90 degrees with each other, The angle formed between the direction of optical anisotropy generated by applying an electric field to each domain D _M · D _M ′ and the absorption axes 6a and 7a of the polarizing plates 6 and 7 is 45 degrees, and each domain D _A display element 70 was produced in which the directions of optical anisotropy generated by applying an electric field of _M · D _M ′ made an angle of 90 degrees with each other.

  When the color in the direction of the polar angle of 60 degrees at the time of applying an electric field of the display element 70 according to the present embodiment manufactured in this way (that is, subjected to the two-domain process) is observed, all viewing angles (viewing angles A ′) are observed. , B ′, C ′, D ′, A, B, C, D), no coloring phenomenon was observed.

  On the other hand, for comparison, as shown in FIG. 15, the two substrates 1, 2 can mutually interact with each other by developing a unidirectional alignment regulating force on the surfaces of both the substrates 1, 2 (the alignment films 23, 24). Measurements similar to those described above were performed with the alignment treatment performed such that the alignment regulating force direction (alignment processing direction) was parallel and each pixel (pixel 81) had one domain. As a result, blue and yellow coloring phenomena were observed at an orientation of 45 degrees from the polarizing plate absorption axis.

As described above, according to the present embodiment, each pixel 71 includes two domains D _M · D _M ′ having different directions of optical anisotropy of the medium A when an electric field is applied, and each domain D _The angles formed by the direction of optical anisotropy generated by applying an electric field of _M · D _M ′ and the absorption axes 6a and 7a of the polarizing plates 6 and 7 are within a range of less than 45 ° ± 10 °, respectively. In the display element 70 described above, the orientation directions are 90 ° in each pixel 71 so that the directions of the optical anisotropy generated by the application of the electric field in each domain D _M · D _M ′ form an angle of 90 degrees. By providing two regions subjected to different orientation treatments, it is possible to obtain a display element 70 with a wide viewing angle in which coloring phenomenon is suppressed in all directions without changing the electrode structure without impairing transmittance. Can do. Specifically, according to the present embodiment, as shown in FIG. 14, two regions (domains D _M and D _M ′) in which the orientation regulating force direction (orientation treatment direction) is orthogonal to each other are formed in the minute region. By providing the alignment films 23 and 24 that have been subjected to the alignment process as described above, it is possible to form regions in each pixel 71 that have been subjected to alignment processes that are 90 degrees different from each other.

  In addition, the alignment films 23 and 24 may be arranged on at least one of the substrates 1 and 2, and the alignment film has a photofunctional group because the alignment control is easy. However, the present invention is not limited to this. Examples of the photofunctional group include a cinnamate system and a chalcone system that perform a dimerization reaction, and an azo system that performs an isomerization reaction, but the present invention is not limited thereto.

Also in this embodiment, the number of domains in each pixel 71 may be two or more as in the first embodiment, and considering the human eye error, each domain D _M · D _M The angle formed between the direction of optical anisotropy when applying an electric field and the absorption axis of the polarizing plates 6 and 7 is about 45 degrees (preferably within a range of 45 degrees ± 10 degrees, more preferably May be within a range of less than 45 ° ± 10 °, and more preferably within a range of 45 ° ± 5 °), and the direction of optical anisotropy of each domain D _M · D _M ′ when an electric field is applied Are at an angle of about 90 degrees to each other (preferably within a range of 90 ± 20 degrees, more preferably within a range of less than 90 ± 20 degrees, and even more preferably within a range of 90 ± 10 degrees). It only has to be.

  Also in the present embodiment, the ratio of each domain in each pixel 71 is the ratio (area ratio) of two domains having different optical anisotropy directions, as in the first embodiment. It is preferably ˜1: 1 (preferably about 1: 1).

[Embodiment 3]
The following will describe another embodiment of the present invention with reference to FIGS. In the present embodiment, differences from the first embodiment will be mainly described, and components having the same functions as those used in the first embodiment are designated by the same reference numerals. A description thereof will be omitted.

  FIG. 16 and FIG. 17 are plan views each schematically showing an example of the electrode configuration of each pixel in the display element according to the present embodiment.

In this embodiment mode, a matrix pixel group is formed by using the display element structure described in Embodiment Mode 1 and providing switching elements, signal lines, scanning lines, and counter electrode lines. That is, in this embodiment, ITO is used as the comb-shaped electrodes 4 and 5, the line width is 5 μm, the distance between the electrodes is 5 μm, the layer thickness of the medium layer 3 (that is, the distance between the substrates 1 and 2) is 10 μm, and the medium A As described above, pentylcyanobiphenyl (5CB) represented by the structural formula (1) is used, and the above 5CB is maintained at a temperature immediately above the phase transition of the nematic isotropic phase by an external heating device (heating means). Display was performed by changing the transmittance.

As shown in FIGS. 16 and 17, the display element 70 according to the present embodiment includes a data signal line 31 (SLv) and a scanning signal line 32 (in each column and each row of a plurality of pixels 71 arranged in a matrix. GLw) is provided, and each pixel 71 has a configuration in which a comb-shaped pixel electrode including the comb-shaped electrode 4 and a counter electrode including the comb-shaped electrode 5 are provided. More specifically, the display element 70 according to the present embodiment includes a plurality of data signal lines 31 and scanning signal lines 32 arranged in a matrix, and intersections of the data signal lines 31 and the scanning signal lines 32. Between at least one TFT 33 (switching element) provided corresponding to each other, a comb-shaped electrode 4 which is a comb-shaped pixel electrode connected to the TFT 33, and the comb-tooth portions 4a and 4a of the comb-shaped electrode 4 A comb-shaped electrode 5 which is a comb-shaped counter electrode having a comb-tooth portion 5a formed so as to be engaged with the comb-tooth portion 4a. Each of the comb-shaped electrodes 4 and 5 is curved in a plane substantially parallel to the substrates 1 and 2 so that at least two domains D _M and D _M ′ to which electric fields forming an angle of 90 degrees are applied are formed. Corner (bending angle) 9 It has a configuration that is bent in a zigzag shape (wedge shape) at 0 degrees.

Accordingly, in the first embodiment, at least two electrode pairs 10 each including the comb-shaped electrodes 4 and 5 are provided in each pixel 71, and the comb-tooth portions 4a and 5a of the one electrode pair 10 are provided in each pixel. Are arranged so as to form an angle of 90 degrees with the comb-tooth portions 4a and 5a in the other electrode pair 10 adjacent to each other in the at least two domains D _M and D _M ′ formed by the electrode pair 10. Although electric fields that are substantially orthogonal to each other are applied, in this embodiment, each comb tooth portion 4a and 5a are bent at an angle of 90 degrees, and each comb tooth portion 4a and 5a are By being arranged so as to be engaged with each other, at least two domains D _M · D _M ′ (micro regions) to which electric fields substantially orthogonal to each other are applied are formed between the comb tooth portions 4a and 5a. Ru It has become.

That is, the display device 70 according to this embodiment, each comb tooth portion 4a · 5a, respectively, the bent portion _{4a 1,} 4a ₂ forming an angle of 90 degrees from each _{other, ... 4a r · 5a 1,} 5a 2, ... 5a _r (r is an arbitrary integer of optical anisotropy generated by applying an electric field in each pixel 71 by applying an electric field), and the bent portions 4a ₁ and 5a ₁ and the bent portions 4a ₂ A configuration in which at least two domains D _M and D _M ′ in which directions substantially orthogonal to each other at 5a ₂ form an angle of 90 degrees with each other is provided.

The display element 70 according to the present embodiment is also provided with polarizing plates 6 and 7 outside the substrates 1 and 2, and these polarizing plates 6 and 7 have absorption axes 6a and 7a, that is, polarizing plates. The absorption axis directions are orthogonal to each other, and the extension directions of the absorption shafts 6a and 7a in the respective polarizing plates 6 and 7 and the comb-tooth portions 4a and 5a in the comb-shaped electrodes 4 and 5, that is, the respective bent portions 4a _r. the electrode extension direction of · 5a _r is formed at an angle of 45 degrees. Therefore, the absorption axis 6a, 7a in the polarizers 6, 7, to the electric field application direction of the bent portions 4a _{r-5a r,} is formed at an angle of 45 degrees.

  According to the study by the inventors of the present application, it has been found that even with the above configuration, it is possible to obtain the display element 70 with a wide viewing angle in which the coloring phenomenon is suppressed in all directions without impairing the transmittance.

In the electrode structure shown in FIG. 16, the counter electrode in the data signal line 31 and the pixel 71,
That is, it can be seen that there is a large non-display area 34 between the data signal line 31 and the comb electrode 5 provided facing the data signal line 31.

  Therefore, in FIG. 17, when the data signal line 31 is formed not to be a straight line but to be parallel to the bending of the comb electrodes 4 and 5 in the pixel 71, the non-display area 34 is greatly reduced.

  That is, in the structure shown in FIG. 16, the display area was about 30%, but by applying the structure shown in FIG. 17, the display area could be increased to 40%.

  In the present embodiment, the comb-shaped portions 4a and 5a of the comb-shaped electrodes 4 and 5 are provided along the data signal line 31, and the data signal line 31 follows the shape of the comb-shaped portions 4a and 5a. However, the present invention is not limited to this, and the comb-tooth portions 4a and 5a may extend along the scanning signal line 32. At least one of the data signal line 31 and the scanning signal line 32 may be formed in a zigzag shape.

Also in the present embodiment, as in the first and second embodiments, the direction of the optical anisotropy of each domain D _M · D _M ′ when an electric field is applied and the absorption axis of the polarizing plates 6 and 7 are the same. Each angle formed is about 45 degrees (within a range of 45 degrees ± 10 degrees, more preferably within a range of less than 45 degrees ± 10 degrees, and even more preferably within a range of 45 degrees ± 5 degrees). Preferably, the direction of the optical anisotropy of each domain D _M · D _M ′ when an electric field is applied is about 90 degrees (within a range of 90 ° ± 20 °, more preferably less than 90 ° ± 20 °). Among them, it is more preferable that the angle is within a range of 90 ± 10 degrees.

Further, also in the present embodiment, the ratio of each domain D _M · D _M ′ in each pixel 71 is equal to two domains D _M · D having different optical anisotropy directions as in the first and second embodiments. It is preferable that the ratio of _M ′ (area ratio) is 1: 9 to 1: 1 (preferably about 1: 1).

In each of the above descriptions, the optical anisotropy of each domain D _M · D _M ′ when an electric field is applied has been mainly described as an example, but the present invention is not limited to this. As described above, as long as the degree of optical anisotropy changes with the application of an electric field, even if it exhibits optical anisotropy when an electric field is applied, it is optically anisotropic when no electric field is applied. In the state where the optical anisotropy is exhibited, each pixel 71 has at least two domains D _M and D _M ′ in which the direction of the optical anisotropy of the medium A is different. As long as it exists.

Further, in each of the above descriptions, the case where two types of domains having the same optical anisotropy direction are provided in each pixel 71 as an example has been described. It is not limited, and two or more types of domains having the same optical anisotropy direction may be provided. That is, as described above, the angle formed between the direction of the optical anisotropy when the electric field is applied in each domain or when no electric field is applied and the absorption axes 6a and 7a of the polarizing plates 6 and 7 is about 45 degrees. Preferably, the direction of the optical anisotropy in each domain when an electric field is applied or when no electric field is applied is about 90 degrees (range of 90 degrees ± 20 degrees). It is preferable to form the angle (inner). However, in the first embodiment, as shown in FIGS. 20 to 22, for example, each angle described above may be independently shifted from 45 degrees or 90 degrees. I do not care. That is, as can be seen from the above description, the direction of the optical anisotropy of the medium A in each pixel 71 is not limited to only two directions. As described above, It is sufficient that at least two domains D _M · D _M ′ having different directions of optical anisotropy of the medium when no electric field is applied exist.

As described above, the display element 70 according to the present invention is a display element that performs display using the medium A in which the degree of optical anisotropy changes due to the application of an electric field. Due to the presence of at least two domains D _M and D _M ′ in which the direction of optical anisotropy of the medium A is different when no electric field is applied, the drive temperature range is wide, and wide viewing angle characteristics and high-speed response characteristics are provided. Moreover, the coloring phenomenon of the oblique viewing angle can be compensated for each other, and the viewing angle characteristics can be improved as compared with the conventional case.

In particular, according to the present invention, each pixel 71 includes at least two domains D _M · D _M ′ having different directions of optical anisotropy of the medium A when an electric field is applied or when no electric field is applied. The angle formed between the direction of optical anisotropy of each domain D _M · D _M ′ when an electric field is applied or when no electric field is applied and the absorption axes 6a and 7a of the polarizing plates 6 and 7 is as described above. , Each within a range of 45 ° ± 10 °, preferably within a range of less than 45 ° ± 10 °, and optical anisotropy when an electric field is applied to each domain D _M · D _M ′ or when no electric field is applied As described above, the color directions of the oblique viewing angles are mutually compensated by forming angles within the range of 90 ° ± 20 °, preferably less than 90 ° ± 20 °, as described above. The viewing angle characteristics can be increased without compromising the transmittance. It is possible to above.

  Further, as described above, the display device 60 according to the present invention includes the display element 70 according to the present invention, and thus has a wide driving temperature range, a wide viewing angle characteristic, and a high-speed response characteristic. The coloring phenomenon of the oblique viewing angle can be compensated for each other, and the viewing angle characteristics can be improved as compared with the conventional case.

  In each of the above embodiments, the description has been mainly given of the application of an electric field as means for changing the degree of optical anisotropy of the medium A, but the present invention is limited to this. Instead of applying an electric field, a magnetic field may be applied, or the degree of optical anisotropy may be changed depending on whether a magnetic field is applied or not.

  That is, as an external field, a magnetic field can be used in the same manner as an electric field. In order to change the degree of optical anisotropy of the medium A by applying a magnetic field, the magnetic anisotropy of the medium A is used. Therefore, in this case, the medium A is preferably a medium having a large magnetic susceptibility anisotropy. In the case of organic molecules, most of the contribution to the magnetic susceptibility is due to the diamagnetic magnetic susceptibility, so that the absolute value becomes large when π electrons can move in a ring shape in the molecule due to the change of the magnetic field. Therefore, for example, when there is an aromatic ring in the molecule, the absolute value of the magnetic susceptibility increases when the aromatic ring (row of aromatic rings, aromatic ring-containing chain) is perpendicular to the direction of the magnetic field. In this case, since the absolute value of the magnetic susceptibility of the aromatic ring in the horizontal plane direction is smaller than the magnetic susceptibility in the vertical direction, the anisotropy of the magnetic susceptibility is increased. Therefore, the medium A preferably has a ring structure such as a 6-membered ring (for example, a benzene ring) in the molecule. In order to increase the anisotropy of the magnetic susceptibility, it is also preferable to arrange the electron spins in the medium A. By introducing electron spins of free radicals (radicals) such as N, O, and NO into the molecule, the molecule can have a stable spin. In this case, for example, spins can be arranged in parallel by stacking conjugated molecules on a plane. In this case, the medium A is preferably, for example, a discotic liquid crystal in which central core portions are stacked to form a column.

  When a magnetic field is used as the external field, for example, a magnetic field generating member such as an electromagnet is provided outside the cell, for example, on the outer surface of the display element 70 instead of the electric field applying member such as the electrodes 4 and 5. This method may be adopted. In this way, the same drive as described above can be performed by applying a magnetic field to the medium instead of the electric field.

Moreover, light can also be used as the outside field. In this case, the wavelength of light is
Although not particularly limited, the degree of optical anisotropy can be changed by, for example, oscillating 532 nm light with an Nd: YAG (yttrium aluminum garnet) laser and irradiating the medium A.

  The medium A that can be used in this case is not particularly limited, but in this case, a medium whose degree of optical anisotropy is changed by light irradiation is preferable in order to use the Kerr effect by light. . As the medium A, a medium similar to that used when an electric field is used as the external field, more specifically, the medium exemplified in the first embodiment can be used.

  In addition, when using light as the said external field, it is more preferable that the said medium A contains a small amount of pigment | dyes. By adding a small amount of a dye to the medium A, specifically, the liquid crystalline substance, the change in the degree of optical anisotropy becomes larger than before adding the dye. The pigment content in the medium A is preferably 0.01% by weight or more and less than 5% by weight. When the content is less than 0.01% by weight, the amount of the dye is small and the effect cannot be sufficiently exhibited. On the other hand, when the content is 5% by weight or more, excitation light is absorbed by the dye.

  In this case, examples of the medium A include a compound (liquid crystalline substance) represented by the structural formula (1). The liquid crystalline substance may be used as it is as the medium A, or a dye may be added to the liquid crystalline substance.

  The dye is not particularly limited, but preferably has an absorption band of the dye at the wavelength of the excitation light. For example, the following structural formula (8)

(1-amino-anthroquinone (hereinafter referred to as “1AAQ”), manufactured by Aldrich) may be added.

  With respect to the compound represented by the structural formula (1) (“5CB” (pentylcyanobiphenyl)), the content of “1AAQ” in the medium A composed of “5CB” and “1AAQ” is 0.03 wt. As a result, the change in the degree of optical anisotropy due to photoexcitation was about 10 times larger than that before adding the “1AAQ”.

  That is, a display element according to the present invention includes a pair of substrates, at least one of which is transparent, and a medium that is sandwiched between the pair of substrates and has a degree of optical anisotropy that changes when an external field is applied, The pixel may have at least two domains having different directions of optical anisotropy of the medium when an external field is applied or when no external field is applied.

In the display element, the means for generating optical anisotropy in each of the domains includes, for example, an electric field, a magnetic field, and light as described above. Among them, the electric field depends on the design of the display element. And it is preferable because drive control is easy.

  Therefore, the display element may include, for example, an electric field application unit such as an electrode or a magnetic field application unit such as an electromagnet as an external field application unit. The external field application unit may be a design of the display element. From the viewpoint of drive control, it is preferable to use an electric field applying means.

  In the present invention, the external field applying means is not particularly limited as long as it can change the degree of optical anisotropy of the medium before and after the application of the external field. As the field applying means, in addition to an electric field applying means such as an electrode and a magnetic field applying means such as an electromagnet, a laser device, for example, a light irradiation means (excitation light generating means) such as the Nd: YAG laser can be used. .

  Therefore, in the present invention, the display element has an optical difference in the medium when an external field is applied or when no external field is applied to each pixel, for example, the substrate surface is previously subjected to an alignment treatment for domain division. The display element itself is not necessarily provided with the external field applying unit as long as it has a configuration in which at least two domains having different directions of orientation are formed.

  That is, the external field applying means may be provided in the display element itself, or may be provided separately from the display element.

  That is, the display device according to the present invention may include a display element provided with the external field applying unit, or may include the external field applying unit separately from the display element. Good. In other words, in the display device, the display element according to the present invention, that is, each pixel has at least two domains having different directions of optical anisotropy of the medium when an external field is applied or when no external field is applied. You may have the structure provided with the display element which exists, and the external field application means which applies an external field to the medium in this display element.

  The present invention is not limited to the above-described embodiments, and various modifications are possible within the scope shown in the claims, and embodiments obtained by appropriately combining technical means disclosed in different embodiments. Is also included in the technical scope of the present invention.

  The display element of the present invention is a display element excellent in wide viewing angle characteristics and high-speed response characteristics in which coloring phenomenon is suppressed in all directions without impairing transmittance. For example, an image display apparatus such as a television or a monitor It can be widely applied to image display devices (display devices) provided in (display devices), office automation equipment such as word processors and personal computers, or information terminals such as video cameras, digital cameras, and mobile phones. Further, as described above, the display element of the present invention has a wide viewing angle characteristic and a high-speed response characteristic, and thus is suitable for a display device that performs large-screen display or moving image display. In addition, since the present display element has high-speed response, it is suitable for, for example, a field sequential color display device.

DESCRIPTION OF SYMBOLS 1 Substrate 2 Substrate 3 Medium layer 3a Refractive index ellipsoid 4 Comb electrode (electrode, electric field application means)
4a tooth portions 4a _{1, 4a} 2, ... 4a _r bent part 5 comb-shaped electrode (the electrode, the electric field applying means)
5a Comb portion 5a ₁ , 5a ₂ ,... 5a _r bent part 6 Polarizing plate 6a Absorption axis 7 Polarizing plate 7a Absorption axis 10 Electrode pair 21 Transparent electrode (electrode)
22 Transparent electrode (electrode)
23 Alignment film 24 Alignment film 31 Data signal line 32 Scanning signal line 33 TFT
34 Non-display area 41 Reflective layer 42 Insulating layer 60 Display device 70 Display element 71 Pixel D _M domain D _M 'domain A medium

Claims (12)

A pair of substrates at least one of which is transparent, a medium sandwiched between the pair of substrates and exhibiting optical anisotropy by application of an electric field, and an electrode made of a transparent electrode material that applies an electric field to the medium The medium includes a liquid crystal substance, and the liquid crystal substance exhibits optical isotropy when no electric field is applied, and displays an optical anisotropy when an electric field is applied.
Each pixel has at least two domains having different optical anisotropy directions indicated by the major axis direction of the refractive index ellipsoid of the liquid crystalline substance when an electric field is applied,
The display element according to claim 1, wherein the directions of the optical anisotropy when the electric field is applied in the at least two domains form an angle within a range of 90 ° ± 20 °. Of the pair of substrates, comprising a polarizing plate disposed on the opposite side to the surface facing the medium in at least one substrate,
2. The display according to claim 1, wherein an angle formed between the direction of the optical anisotropy when the electric field is applied in each domain and the absorption axis of the polarizing plate is within a range of 45 degrees ± 10 degrees. element.   The angle formed between the direction of the optical anisotropy when an electric field is applied in each domain and the absorption axis of the polarizing plate is within a range of less than 45 ° ± 10 °. Display element.   In each pixel, an electrode pair group consisting of at least two electrode pairs for applying an electric field substantially parallel to the substrate to the medium is provided as the electrode, and the electrode pairs adjacent to each other are 90 degrees from each other. The display element according to claim 1, wherein an electric field forming an angle within a range of ± 20 degrees is applied to the medium.   Each of the electrode pairs is composed of a pair of comb-shaped electrodes, and is provided so as to face each other in a direction in which the comb-tooth portions are engaged with each other. 5. The display element according to claim 4, wherein the display element is arranged so as to form an angle within a range of 90 degrees ± 20 degrees with the comb-tooth portion of the electrode pair.   The direction of the optical anisotropy when the electric field is applied in the at least two domains forms an angle within a range of less than 90 degrees ± 20 degrees with respect to each other. Display element.   In each pixel, an electrode pair group consisting of at least two electrode pairs for applying an electric field substantially parallel to the substrate to the medium is provided as the electrode, and the electrode pairs adjacent to each other are 90 degrees from each other. The display element according to claim 6, wherein an electric field having an angle within a range of less than ± 20 degrees is applied to the medium.   Each of the electrode pairs is composed of a pair of comb-shaped electrodes, and is provided so as to face each other in a direction in which the comb-tooth portions are engaged with each other. The display element according to claim 7, wherein the display element is arranged so as to form an angle within a range of less than 90 ° ± 20 ° with the comb-tooth portion of the electrode pair. The electrode applies an electric field substantially parallel to the substrate to the medium in each pixel,
The display element according to claim 1, wherein the electrode applies an electric field in a partially different direction with respect to the medium in each pixel. The medium has an ordered structure exhibiting cubic symmetry.
The display element according to any one of 9.   The display element according to claim 1, wherein the medium is composed of molecules exhibiting a cubic phase or a smectic D phase.   A display device comprising the display element according to claim 1.

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