JP4919543B2 - Water-in-oil emulsified cosmetic - Google Patents
Water-in-oil emulsified cosmetic Download PDFInfo
- Publication number
- JP4919543B2 JP4919543B2 JP2001163883A JP2001163883A JP4919543B2 JP 4919543 B2 JP4919543 B2 JP 4919543B2 JP 2001163883 A JP2001163883 A JP 2001163883A JP 2001163883 A JP2001163883 A JP 2001163883A JP 4919543 B2 JP4919543 B2 JP 4919543B2
- Authority
- JP
- Japan
- Prior art keywords
- oil
- water
- group
- carbon atoms
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002537 cosmetic Substances 0.000 title claims description 76
- 239000000843 powder Substances 0.000 claims description 55
- 229920001296 polysiloxane Polymers 0.000 claims description 24
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- 229920005989 resin Polymers 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 11
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 238000000605 extraction Methods 0.000 claims description 6
- 229920002545 silicone oil Polymers 0.000 claims description 5
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 125000000962 organic group Chemical group 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 241001553290 Euphorbia antisyphilitica Species 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 6
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
- 239000003921 oil Substances 0.000 description 70
- -1 polyethylene Polymers 0.000 description 44
- 235000019198 oils Nutrition 0.000 description 26
- 235000014113 dietary fatty acids Nutrition 0.000 description 16
- 239000000194 fatty acid Substances 0.000 description 16
- 229930195729 fatty acid Natural products 0.000 description 16
- 239000004204 candelilla wax Substances 0.000 description 15
- 235000013868 candelilla wax Nutrition 0.000 description 15
- 229940073532 candelilla wax Drugs 0.000 description 15
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 15
- 239000000839 emulsion Substances 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 10
- 150000002430 hydrocarbons Chemical group 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 8
- 239000010445 mica Substances 0.000 description 8
- 229910052618 mica group Inorganic materials 0.000 description 8
- 239000004166 Lanolin Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 235000019388 lanolin Nutrition 0.000 description 7
- 229940039717 lanolin Drugs 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 238000004945 emulsification Methods 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000001993 wax Substances 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 5
- 239000003349 gelling agent Substances 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- 230000002688 persistence Effects 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 229960003237 betaine Drugs 0.000 description 4
- 239000000284 extract Substances 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 230000000475 sunscreen effect Effects 0.000 description 4
- 239000000516 sunscreening agent Substances 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 239000010702 perfluoropolyether Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Natural products C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000008406 cosmetic ingredient Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229920002674 hyaluronan Polymers 0.000 description 2
- 229960003160 hyaluronic acid Drugs 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 2
- 239000012860 organic pigment Substances 0.000 description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 235000019271 petrolatum Nutrition 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002884 skin cream Substances 0.000 description 2
- 229910021647 smectite Inorganic materials 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 description 1
- WFXHUBZUIFLWCV-UHFFFAOYSA-N (2,2-dimethyl-3-octanoyloxypropyl) octanoate Chemical compound CCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCC WFXHUBZUIFLWCV-UHFFFAOYSA-N 0.000 description 1
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- PDHSAQOQVUXZGQ-JKSUJKDBSA-N (2r,3s)-2-(3,4-dihydroxyphenyl)-3-methoxy-3,4-dihydro-2h-chromene-5,7-diol Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2OC)=CC=C(O)C(O)=C1 PDHSAQOQVUXZGQ-JKSUJKDBSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- DMBUODUULYCPAK-UHFFFAOYSA-N 1,3-bis(docosanoyloxy)propan-2-yl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCCCCCC DMBUODUULYCPAK-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- WHQOKFZWSDOTQP-UHFFFAOYSA-N 2,3-dihydroxypropyl 4-aminobenzoate Chemical compound NC1=CC=C(C(=O)OCC(O)CO)C=C1 WHQOKFZWSDOTQP-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical class NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 244000144927 Aloe barbadensis Species 0.000 description 1
- 235000002961 Aloe barbadensis Nutrition 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229940123150 Chelating agent Drugs 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 241000252100 Conger Species 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 229920002148 Gellan gum Polymers 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241000208690 Hamamelis Species 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Natural products OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 1
- 241001558929 Sclerotium <basidiomycota> Species 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- LDDUCKDUDZVHLN-UHFFFAOYSA-N [2-hydroxy-3-[2-hydroxy-3-(16-methylheptadecanoyloxy)propoxy]propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)COCC(O)COC(=O)CCCCCCCCCCCCCCC(C)C LDDUCKDUDZVHLN-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229940023476 agar Drugs 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 229940069521 aloe extract Drugs 0.000 description 1
- 235000011399 aloe vera Nutrition 0.000 description 1
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- JECUDTNJDOAEOR-UHFFFAOYSA-K aluminum;16-methylheptadecanoate Chemical compound [Al+3].CC(C)CCCCCCCCCCCCCCC([O-])=O.CC(C)CCCCCCCCCCCCCCC([O-])=O.CC(C)CCCCCCCCCCCCCCC([O-])=O JECUDTNJDOAEOR-UHFFFAOYSA-K 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- BLFLLBZGZJTVJG-UHFFFAOYSA-N benzocaine Chemical compound CCOC(=O)C1=CC=C(N)C=C1 BLFLLBZGZJTVJG-UHFFFAOYSA-N 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- SODJJEXAWOSSON-UHFFFAOYSA-N bis(2-hydroxy-4-methoxyphenyl)methanone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=C(OC)C=C1O SODJJEXAWOSSON-UHFFFAOYSA-N 0.000 description 1
- 229940073609 bismuth oxychloride Drugs 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 229940008396 carrot extract Drugs 0.000 description 1
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 description 1
- 235000005487 catechin Nutrition 0.000 description 1
- 150000001766 catechin derivatives Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000012185 ceresin wax Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 229940119217 chamomile extract Drugs 0.000 description 1
- 235000020221 chamomile extract Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 229940006423 chondroitin sulfate sodium Drugs 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 description 1
- 229950001002 cianidanol Drugs 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 229960005188 collagen Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical class C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 238000012812 general test Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- 239000003676 hair preparation Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- OIKBVOIOVNEVJR-UHFFFAOYSA-N hexadecyl 6-methylheptanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCC(C)C OIKBVOIOVNEVJR-UHFFFAOYSA-N 0.000 description 1
- 229960004881 homosalate Drugs 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 229940069445 licorice extract Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- 229960001173 oxybenzone Drugs 0.000 description 1
- 125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229960000292 pectin Drugs 0.000 description 1
- BPHQIXJDBIHMLT-UHFFFAOYSA-N perfluorodecane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F BPHQIXJDBIHMLT-UHFFFAOYSA-N 0.000 description 1
- YVBBRRALBYAZBM-UHFFFAOYSA-N perfluorooctane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YVBBRRALBYAZBM-UHFFFAOYSA-N 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- 229940067631 phospholipid Drugs 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920003217 poly(methylsilsesquioxane) Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229940092258 rosemary extract Drugs 0.000 description 1
- 235000020748 rosemary extract Nutrition 0.000 description 1
- 239000001233 rosmarinus officinalis l. extract Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- KJCLYACXIWMFCC-UHFFFAOYSA-M sodium;5-benzoyl-4-hydroxy-2-methoxybenzenesulfonate Chemical compound [Na+].C1=C(S([O-])(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 KJCLYACXIWMFCC-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
【０００１】
【発明の属する技術分野】
本発明は、キャンデリラワックスより分別抽出して得られた樹脂分、疎水化処理粉体及びシリコーン系界面活性剤を含有する油中水型乳化化粧料に関し、更に詳しくは、肌への密着性に優れながら、化粧膜の柔軟性にも優れ、化粧持続性及び粉体分散性が良好な油中水型乳化化粧料に関するものである。
【０００２】
【従来の技術】
従来より、油中水型乳化化粧料は、肌上に疎水性の化粧膜を形成できるため、化粧持続性に優れた化粧料として、ファンデーション、口紅、日焼け止め料等に汎用されていた。また、汗等による化粧崩れや色沈みを防止するために、油中水型乳化化粧料に配合する粉体は、予め疎水化処理された粉体が用いられていた。更に、配合された粉体の肌への密着性を高めるために、キャンデリラワックス等の固形油や、ロジン酸ペンタエリスリット等の油溶性樹脂が配合されていた。
【０００３】
【発明が解決しようとする課題】
しかしながら、粉体を予め疎水化処理して油中水型乳化化粧料に配合する方法では、粉体の分散性はある程度向上するが、肌への密着性が低く、化粧持続性が満足できる水準ではなかった。また、キャンデリラワックス等の固形油や、ロジン酸ペンタエリスリット等の油溶性樹脂を配合する方法では、化粧持続性は向上するものの、多く配合した場合は化粧膜が硬くなり、化粧膜の柔軟性が低下する場合があった。
このため、肌への密着性に優れながら、化粧膜の柔軟性にも優れ、化粧持続性及び粉体分散性が良好な油中水型乳化化粧料の開発が望まれていた。
【０００４】
【課題を解決するための手段】
かかる実情において、本発明者らは鋭意研究を重ねた結果、キャンデリラワックスより分別抽出して得られた樹脂分、疎水化処理粉体及びシリコーン系界面活性剤を含有する油中水型乳化化粧料が、上記課題を解決することを見出し本発明を完成させた。
【０００５】
すなわち本発明は、次の成分（ａ）〜（ｃ）；
（ａ）キャンデリラワックスより分別抽出して得られた樹脂分
（ｂ）疎水化処理粉体
（ｃ）シリコーン系界面活性剤
を含有することを特徴とする油中水型乳化化粧料を提供するものである。また、更に成分（ｄ）としてシリコーン油を含有することを特徴とする前記油中水型乳化化粧料を提供するものである。更に、成分（ａ）の軟化点が３５〜５５℃であることを特徴とする前記何れかの油中水型乳化化粧料を提供するものである。
【０００６】
【発明の実施の形態】
以下、本発明を詳細に説明する。
本発明に用いられる成分（ａ）は、キャンデリラワックスから有機溶剤で分別抽出して得られる樹脂分である。キャンデリラワックスは、通常１５〜３０質量％（以下、単に「％」と略す。）の樹脂分を含有するが、本発明に用いられる成分（ａ）の樹脂分濃度は６５％以上が好ましく、８５％以上がより好ましい。このキャンデリラワックスから樹脂分を分別抽出する方法は、例えば、キャンデリラワックスに有機溶剤を添加して水浴上等で加熱し、該キャンデリラワックスを溶解し、次いで、これを常温まで冷却して、ワックスの結晶を析出させ、濾過により結晶を除去し、この濾液から有機溶剤を蒸留除去する方法が挙げられる。尚、ここで用いられる有機溶剤としては、エタノール、イソプロピルアルコール等のアルコール類、ケトン類、エステル類が挙げられる。このようにして得られた樹脂分は、淡黄色〜琥珀色の透明な樹脂分である。本発明の成分（ａ）の樹脂分は、従来のキャンデリラワックスの融点（約７２℃）と比較して非常に低い軟化点を有するものであり、軟化点は３５〜５５℃が好ましい。（軟化点の測定方法：化粧品原料基準一般試験法、試料０．５ｇ、昇温速度０．２℃／分、１２ｍｍφ、１０ｇの鉛球を用いる。）
【０００７】
成分（ａ）のキャンデリラワックスから分別抽出して得られる樹脂分は、ＩＮＣＩ（Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｎｏｍｅｎｃｌａｔｕｒｅ Ｃｏｓｍｅｔｉｃ Ｉｎｇｒｅｄｉｅｎｔ）にキャンデリラワックスエキストラクトという名称で登録されているもの等が挙げられ、市販品としては、該樹脂分を油剤やアルコール等に溶解されたものであるキャンデリラレジン（日本ナチュラル社製）等が挙げられる。
【０００８】
本発明の油中水型乳化化粧料における成分（ａ）の含有量は、０．１〜１５％が好ましい。この範囲で用いると、化粧膜の柔軟性と肌への密着性が特に優れる油中水型乳化化粧料を得ることができる。
【０００９】
本発明に用いられる成分（ｂ）は、粉体を通常公知の技術により疎水化処理を施したものである。成分（ｂ）に用いられる粉体は、通常化粧料に使用される粉体であればよく、球状，板状，針状等の形状、煙霧状，微粒子，顔料級等の粒子径、多孔質，無孔質等の粒子構造等により特に限定されず、無機粉体類、光輝性粉体類、有機粉体類、色素粉体類、複合粉体類等が挙げられる。具体的には、酸化チタン，低次酸化チタン，コンジョウ，群青，ベンガラ，黄酸化鉄，黒酸化鉄，酸化亜鉛，酸化アルミニウム，二酸化珪素，酸化マグネシウム，酸化ジルコニウム，炭酸マグネシウム，炭酸カルシウム、酸化クロム，水酸化クロム，カーボンブラック，ケイ酸アルミニウム，ケイ酸マグネシウム，ケイ酸アルミニウムマグネシウム，雲母，合成雲母，合成セリサイト，セリサイト，タルク，カオリン，炭化珪素，硫酸バリウム，ベントナイト，スメクタイト，窒化硼素等の無機粉体類、オキシ塩化ビスマス，雲母チタン，酸化鉄コーティング雲母，酸化鉄雲母チタン，有機顔料処理雲母チタン，アルミニウムパウダー等の光輝性粉体類、ナイロンパウダー，ポリメチルメタクリレート，ポリエチレンパウダー，ポリスチレンパウダー，オルガノポリシロキサンエラストマーパウダー，ポリメチルシルセスキオキサンパウダー，ウールパウダー，シルクパウダー，結晶セルロース，Ｎ−アシルリジン等の有機粉体類、有機タール系顔料、有機色素のレーキ顔料等の色素粉体類、微粒子酸化チタン被覆雲母チタン，微粒子酸化亜鉛被覆雲母チタン，硫酸バリウム被覆雲母チタン，酸化チタン含有二酸化珪素，酸化亜鉛含有二酸化珪素等の複合粉体等が挙げられ、これらを一種又は二種以上用いることができる。
【００１０】
成分（ｂ）における、前記粉体を撥水処理する処理剤としては、例えば、ジメチルポリシロキサン，メチルハイドロジェンポリシロキサン，高粘度シリコーン，架橋型シリコーン，フッ素変性シリコーン，アクリル変性シリコーン，シリコーン樹脂等のシリコーン化合物、パーフルオロアルキルシラン、アニオン界面活性剤，カチオン界面活性剤，非イオン界面活性剤等の界面活性剤、ラウリン酸亜鉛，ステアリン酸亜鉛等の金属石鹸、ポリイソブチレン，ワックス，高級脂肪酸，高級アルコール等の油剤、Ｎ−アシルアミノ酸、パーフルオロアルキルリン酸及びこの塩，パーフルオロポリエーテル，パーフルオロポリエーテルアルキルリン酸及びこの塩等のフッ素化合物、ポリビニルピロリドン−ヘキサデセンのコポリマー等のポリビニルピロリドン変性ポリマー等が挙げられ、これらを一種又は二種以上用いることができる。
【００１１】
成分（ｂ）において、前記処理剤を前記粉体に処理する方法は通常公知の方法が用いられ、特に限定されるものではないが、例えば、溶媒を使用する湿式法、気相法、メカノケミカル法等が挙げられる。また、成分（ｂ）における前記処理剤と前記粉体との処理比は、質量比として、０．１〜２０：９９．９〜８０が好ましい。
【００１２】
本発明の油中水型乳化化粧料における成分（ｂ）の含有量は、０．１〜６０％が好ましい。この範囲で用いると、粉体分散性がより優れる油中水型乳化化粧料を得ることができる。
【００１３】
本発明に用いられる成分（ｃ）は、本発明の油中水型乳化化粧料において、乳化剤として用いられるものであり、例えば、下記一般式（１）で示されるポリオキシアルキレン変性オルガノポリシロキサン、下記平均組成式（２）又は（３）で示される長鎖アルキル含有ポリオキシアルキレン変性オルガノポリシロキサン等が挙げられ、これらを一種又は二種以上用いることができる。また、成分（ｃ）は、乳化安定性の観点より、ＨＬＢが６以下であることが好ましい。
【００１４】
【化１】
［式中、Ｒ１；水素原子又は炭素数１〜５の一価炭化水素基。Ｒ２；−（ＣＨ２）ｌ−Ｏ−（Ｃ２Ｈ４Ｏ）ｘ−（Ｃ３Ｈ６Ｏ）ｙ−Ｒ３。Ｒ３；水素原子、低級アルキル基。ａ，ｂ；０，１，２，３から選ばれる数。但し、ａ＋ｂ＝３である。ｍ，ｎ；０又は正の整数。ｌ；正の整数。ｘ；０又は正の整数、ｙ；０又は正の整数で示され、ｘ及びｙが同時に０では無い。但し、ｎ＋ｂは１以上の整数。
］
【００１６】
このようなポリオキシアルキレン変性オルガノポリシロキサンは、市販品として、シリコンＫＦ−６０１１，ＫＦ６０１２，ＫＦ−６０１３，ＫＦ−６０１５，ＫＦ−６０１６，ＫＦ−６０１７，Ｘ−２２−４９９１（何れも、信越化学工業社製）、ＮＵＣシリコンＬ７００２（日本ユニカー社製）、ＳＨ−３７７２Ｃ、ＳＨ−３７７５Ｃ（何れも、東レ・ダウコーニング・シリコーン社製）等が挙げられる。また、成分（ｃ）は、乳化安定性の観点より、ＨＬＢが６以下であることが好ましい。
【００１７】
Ｒ４ aＲ５ bＲ６ cＳｉＯ(4-a-b-c)/2 …（２）
［式中、Ｒ４；同一又は異なってもよく、炭素数１〜１０のアルキル基、水素原子、アリール基、アラルキル基、フッ素置換アルキル基。Ｒ５；−ＣmＨ2m−Ｏ−（Ｃ2Ｈ4Ｏ）d−（Ｃ3Ｈ6Ｏ）e−Ｒ７で示される基（式中、ｍ；１〜５の整数、ｄ、ｅは０以上の整数、且つ、ｄ＋ｅ≧１〜２００であり、Ｒ７；水素原子若しくは炭素数１〜５の一価炭化水素基又は−（ＣＯ）−Ｒ８で示される有機基、Ｒ８；炭素数１〜５の一価炭化水素基）。Ｒ６；炭素数１０〜３０の一価炭化水素基。ａ、ｂ、ｃはそれぞれ１．０≦ａ≦２．５、０．００１≦ｂ≦１．５、０．００１≦ｃ≦１．５である。］
【００１８】
Ｒ９ aＲ１０ bＲ１１ cＳｉＯ(4-a-b-c)2 …（３）
［式中、Ｒ９；同一又は異なってもよく、炭素数１〜１０のアルキル基、水素原子、アリール基、アラルキル基、フッ素置換アルキル基。Ｒ１０；−ＣmＨ2m−Ｏ−（Ｃ2Ｈ4Ｏ）d−（Ｃ3Ｈ6Ｏ）e−Ｒ１２で示される基（式中、ｍは１〜５の整数、ｄ、ｅは０以上の整数、且つ、ｄ＋ｅ≧１〜２００であり、Ｒ１２は水素原子若しくは炭素数１〜５の一価炭化水素基又は−（ＣＯ）−Ｒ１３で示される有機基、Ｒ１３は炭素数１〜５の一価炭化水素基）。Ｒ１１；−ＣnＨ2n−Ｏ−（Ｃ2Ｈ4Ｏ）f−（Ｃ3Ｈ6Ｏ）g−Ｒ１４（式中、ｎは１〜５の整数、ｆ、ｇは０以上の整数、且つ、ｆ＋ｇ≧０〜２００であり、Ｒ１４は炭素数１０〜３０の一価炭化水素基）。ａ、ｂ、ｃはそれぞれ１．０≦ａ≦２．５、０．００１≦ｂ≦１．５、０．００１≦ｃ≦１．５である。］
【００１９】
このような長鎖アルキル含有ポリオキシアルキレン変性オルガノポリシロキサンは、市販品として、ＡＢＩＬ ＥＭ−９０、ＡＢＩＬ Ｂ９８０６（何れも、ゴールドシュミット社製）、シリコンＫＦ−６０２６（信越化学工業社製）等が挙げられる。
【００２０】
本発明の油中水型乳化化粧料における成分（ｃ）の含有量は、０．１〜１０％が好ましい。この範囲で用いると、乳化安定性に優れる油中水型乳化化粧料を得ることができる。尚、本発明の油中水型乳化化粧料には、乳化助剤として、成分（ｃ）以外の界面活性剤を併用することも可能である。
【００２１】
本発明の油中水型乳化化粧料には、上記成分の他に水を含有する。本発明の油中水型乳化化粧料における水の含有量は、５〜８０％が好ましく、１０〜７０％が特に好ましい。この範囲で用いると、使用感と乳化安定性がより優れる油中水型乳化化粧料を得ることができる。
【００２２】
本発明の油中水型乳化化粧料には、更に、成分（ｄ）としてシリコーン油を含有させることができる。本発明に用いられるシリコ−ン油は、通常化粧料に用いられるものであり、例えば、ジメチルポリシロキサン、メチルフェニルポリシロキサン等の鎖状シリコーン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン等の環状シリコーン、フッ素変性ポリシロキサン、アミノ変性ポリシロキサン、脂肪酸変性ポリシロキサン、高級アルコール変性ポリシロキサン、アルキル変性ポリシロキサン等の変性シリコーン等が挙げられ、これらを一種又は二種以上用いることができる。この中でも、成分（ｄ）として、低分子量の鎖状シリコーン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン等の揮発性のシリコーン油を選択すると、化粧持続性が特に優れる油中水型乳化化粧料を得ることができる。本発明の油中水型乳化化粧料に成分（ｄ）を含有する場合の含有量は、油相中の５０〜１００％が好ましい。
【００２３】
本発明の油中水型乳化化粧料には、上記成分に加え、目的に応じて本発明の効果を損なわない量的、質的範囲において、成分（ｄ）以外の油剤、成分（ｃ）以外の界面活性剤、油ゲル化剤、未処理粉体、水性成分、水溶性高分子、紫外線吸収剤、ベントナイト，ヘクトライト，スメクタイト等の水性ゲル化剤、酸化防止剤、パラオキシ安息香酸誘導体，フェノキシエタノール等の防腐剤、ビタミンＡ，Ｂ６，Ｂ１２，Ｃ，Ｅ等のビタミン類、キレート剤、ローズマリーエキス，カミツレエキス，ニンジン抽出物，センブリ抽出物，カテキン，カテキン誘導体，カンゾウ抽出物，ソウハクヒ抽出物，ホップ抽出物，コラーゲン，ヒアルロン酸，ヒアルロン酸誘導体，トレハロース，アロエエキス等の美容成分、メントール，カンファ，ソルビトール等の清涼剤、香料等の通常化粧料に汎用される成分を含有することができる。
【００２４】
本発明の油中水型乳化化粧料には、上記成分の他に、成分（ａ）を希釈するためや、粉体の粉っぽさを低減するため、感触調整剤、エモリエント剤等の目的で、通常化粧料に用いられる油剤を含有することができる。ここで用いられる油剤としては、動物油、植物油、合成油等の起源及び、固形油、半固形油、液体油、揮発性油等の性状を問わず、炭化水素類、油脂類、ロウ類、硬化油類、エステル油類、脂肪酸類、高級アルコール類、フッ素系油類、ラノリン誘導体類等の油剤が挙げられる。具体的には、流動パラフィン，スクワラン，ワセリン，パラフィンワックス，セレシンワックス，マイクロクリスタリンワックス，モクロウ，モンタンワックス，フィッシャートロプシュワックス等の炭化水素類、オリーブ油，ヒマシ油，ホホバ油，ミンク油，マカデミアンナッツ油等の油脂類、ミツロウ，カルナウバワックス，キャンデリラワックス，ゲイロウ等のロウ類、セチルイソオクタネート，ミリスチン酸イソプロピル，パルミチン酸イソプロピル，ミリスチン酸オクチルドデシル，トリオクタン酸グリセリル，ジイソステアリン酸ジグリセリル，トリイソステアリン酸ジグリセリル，トリベヘン酸グリセリル，ロジン酸ペンタエリスリットエステル，ジオクタン酸ネオペンチルグリコール，コレステロール脂肪酸エステル，Ｎ−ラウロイル−Ｌ−グルタミン酸ジ（コレステリル・ベヘニル・オクチルドデシル）等のエステル類、ステアリルアルコール，セチルアルコール，ラウリルアルコール，オレイルアルコール，イソステアリルアルコール，ベヘニルアルコール等の高級アルコール類、パーフルオロポリエーテル，パーフルオロデカン，パーフルオロオクタン等のフッ素系油剤類、ラノリン，酢酸ラノリン，ラノリン脂肪酸イソプロピル，ラノリンアルコール等のラノリン誘導体類等が挙げられ、これらを一種又は二種以上用いることができる。本発明の水中油型化粧料における油剤の含有量は、乳化安定性、使用感の観点より、１〜５０％が好ましく、５〜４０％がより好ましい。
【００２５】
本発明の油中水型乳化化粧料には、上記成分の他に、乳化助剤及び分散剤として界面活性剤を含有させることができる。このような界面活性剤としては、陰イオン性界面活性剤、陽イオン性界面活性剤、両性界面活性剤、非イオン性界面活性剤等が挙げられ、これらを一種又は二種以上用いることができる。具体的には、陰イオン性界面活性剤として、ステアリン酸，ラウリン酸，ミリスチン酸，ベヘン酸，イソステアリン酸，オレイン酸，１２−ヒドロキシステアリン酸等の脂肪酸とナトリウム，カリウム，トリエタノールアミン等のアルカリ物質により形成される脂肪酸石鹸類、アシルグルタミン酸塩類、アルキルリン酸塩、ポリオキシアルキレン付加アルキルリン酸塩等が挙げられる。陽イオン性界面活性剤としては、アルキルアミン塩、アルキル四級アンモニウム塩等が挙げられる。両性界面活性剤としては、Ｎ，Ｎ−ジメチル−Ｎ−アルキル−Ｎ−カルボキシルメチルアンモニウムベタイン、Ｎ，Ｎ−ジアルキルアミノアルキレンカルボン酸、Ｎ，Ｎ，Ｎ−トリアルキル−Ｎ−スルフォアルキレンアンモニウムベタイン、Ｎ，Ｎ−ジアルキル−Ｎ，Ｎ−ビス（ポリオキシエチレン硫酸）アンモニウムベタイン、２−アルキル−１−ヒドロキシエチル−１−カルボキシメチルイミダゾリニウムベタイン、レシチン、リン脂質等が挙げられる。非イオン性界面活性剤としては、グリセリン脂肪酸エステル及びそのアルキレングリコール付加物、ポリグリセリン脂肪酸エステル及びそのアルキレングリコール付加物、プロピレングリコール脂肪酸エステル及びそのアルキレングリコール付加物、ソルビタン脂肪酸エステル及びそのアルキレングリコール付加物、ソルビトールの脂肪酸エステル及びそのアルキレングリコール付加物、ポリアルキレングリコール脂肪酸エステル、蔗糖脂肪酸エステル、ポリオキシアルキレンアルキルエーテル、グリセリンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレン硬化ヒマシ油、ラノリンのアルキレングリコール付加物等が挙げられ、これらを一種又は二種以上用いることができる。本発明の油中水型乳化化粧料に前記界面活性剤を含有する場合の含有量は、界面活性剤の種類、油剤の量及び質により変動するが、概ね０．０１〜２０％が好ましい。
【００２６】
本発明の油中水型乳化化粧料には、上記成分の他に、安定化剤及び感触調整剤として、油ゲル化剤を含有させることができる。このような油ゲル化剤としては、デキストリン脂肪酸エステル、蔗糖脂肪酸エステル、デンプン脂肪酸エステル、イソステアリン酸アルミニウム，ステアリン酸カルシウム，部分架橋型オルガノポリシロキサン、有機変性ベントナイト、煙霧状無水ケイ酸等が挙げられ、これらを一種又は二種以上用いることができる。本発明の油中水型乳化化粧料に前記油ゲル化剤を含有する場合の含有量は、概ね０．１〜１０％が好ましい。
【００２７】
本発明の油中水型乳化化粧料には、上記成分の他に、感触調整剤、保湿剤、清涼剤、防腐剤等として、水性成分を含有することができる。このような水性成分としては、プロピレングリコール，１，３−ブチレングリコール，ジプロピレングリコール等の多価アルコール類、グリセリン，ジグリセリン，ポリグリセリン等のグリセロール類、ソルビトール，マルチトール，ショ糖，デンプン糖等の糖類、グアーガム，スクレロチウムガム，ジェランガム，ペクチン，寒天，コンドロイチン硫酸ナトリウム，ヒアルロン酸，アラビアガム，アルギン酸ナトリウム，カラギーナン，キサンタンガム，ローカストビーンガム，メチルセルロース，ヒドロキシエチルセルロース，カルボキシメチルセルロース，カルボキシビニルポリマー，アルキル変性カルボキシビニルポリマー，ポリビニルアルコール，ポリビニルピロリドン，ポリアクリル酸ナトリウム等の水溶性高分子、塩化ナトリウム，塩化マグネシウム，乳酸ナトリウム等の塩類、アロエベラ，ハマメリス，キュウリ，レモン，ラベンダー，ローズ等の植物抽出液等が挙げられ、これらを一種又は二種以上用いることができる。本発明の油中水型乳化化粧料に前記水性成分を含有する場合の含有量は、概ね０．１〜３０％が好ましい。
【００２８】
本発明の油中水型乳化化粧料には、上記成分の他に、紫外線吸収剤を含有することができる。このような紫外線吸収剤としては、２−ヒドロキシ−４−メトキシベンゾフェノン、２−ヒドロキシ−４−メトキシベンゾフェノン−５−スルホン酸、２−ヒドロキシ−４−メトキシベンゾフェノン−５−スルホン酸ナトリウム、２，２’−ジヒドロキシ−４，４’−ジメトキシベンゾフェノン、２，２’−ジヒドロキシ−４，４’−ジメトキシベンゾフェノン−５−スルホン酸ナトリウム、２，４−ジヒドロキシベンゾフェノン、２，２’４，４’−テトラヒドロキシベンゾフェノン、２，４，６−トリアニリノ−パラ−（カルボ−２’−エチルヘキシル−１’−オキシ）−１、３、５−トリアジン等のベンゾフェノン系、サリチル酸−２−エチルヘキシル、サリチル酸フェニル、サリチル酸ホモメンチル等のサリチル酸系、パラアミノ安息香酸、パラアミノ安息香酸エチル、パラアミノ安息香酸グリセリル、パラジメチルアミノ安息香酸アミル、パラジメチルアミノ安息香酸アミル−２−エチルヘキシル、パラジヒドロキシプロピル安息香酸エチル等のＰＡＢＡ系、ｐ−メトキシ桂皮酸−２−エチルヘキシル、４−メトキシ桂皮酸−２−エトキシエチル等のシンナメート系、２−（２−ヒドロキシ−５−メチルフェニル）ベンゾトリアゾール、４−ｔｅｒｔ−４’−メトキシジベンゾイルメタン等のジベンゾイルメタン系、オキシベンゾン系、ジメトキシベンジリデンジオキソイミダゾリシンプロピオン酸−２−エチルヘキシル等が挙げられ、これらを一種又は二種以上用いることができる。
【００２９】
本発明の油中水型乳化化粧料は、スキンケア化粧料、メーキャップ化粧料、頭髪化粧料の何れの化粧料にも応用可能であるが、本発明の効果が顕著に発揮される化粧料は、ファンデーション、下地料、コントロールカラー、コンシーラー、アイカラー、口紅等のメーキャップ化粧料や日焼け止め化粧料である。また、本発明の油中水型乳化化粧料の形態は、液状、乳液状、クリーム状、ゲル状、固形状の何れでも良い。
【００３０】
【実施例】
以下に実施例を挙げて、本発明を更に詳細に説明する。尚、これらは本発明を何ら限定するものではない。
【００３１】
実施例１〜９及び比較例１〜５：クリーム状ファンデーション
表１〜３に示す組成のクリーム状ファンデーションを以下に示す製造方法により調製し、「粉体の分散性」、「肌への密着性」、「化粧膜の柔軟性」、「化粧持続性」の各項目について以下に示す評価方法及び判定基準により評価し、結果を併せて表１〜３に示した。
【００３２】
【表１】
【表２】
【表３】
（製造方法）
Ａ：成分１〜１２を混合溶解する。
Ｂ：Ａに成分１３〜２４を添加して、混合分散する。
Ｃ：成分２５〜２７を混合溶解する。
Ｄ：Ｂを攪拌しながら、Ｃを添加し、乳化する。
Ｅ：Ｄを容器に充填し、クリーム状ファンデーションを得た。
【００３６】
［評価方法：粉体の分散性］
上記実施例及び比較例のクリーム状ファンデーションを、ガラス板に厚さ２５μｍのアプリケーターを用いて薄膜を引き、粉体の凝集性を観察し、下記判定基準より判定した。
（観察結果） ：（判定）
粉体の凝集が観察されない ： ◎
僅かに粉体の凝集が観察される ： △
明らかに粉体の凝集が観察される： ×
【００３７】
［評価方法：肌への密着性、化粧膜の柔軟性、化粧持続性］
上記実施例及び比較例のクリーム状ファンデーションを、化粧品専門パネル２０名に使用してもらい、「肌への密着性」、「化粧膜の柔軟性」について、各パネルがファンデーション毎に以下の評価基準により評点を付し、各ファンデーション毎に全パネルの評点の平均点を算出し、以下の判定基準により判定した。尚、「化粧持続性」については、ファンデーション塗布後、５時間後の状態を評価した。
〔評価基準〕
使用感 ： 評点
非常に良好 ： ５点
良好 ： ４点
普通 ： ３点
やや不良 ： ２点
不良 ： １点
〔判定基準〕
全パネルの評点の平均点 ： 判定
４．５以上 ： ◎
３．５以上〜４．５未満 ： ○
２．０以上〜３．５未満 ： △
２．０未満 ： ×
【００３８】
表１〜３の結果から明らかなように、本発明に係わる実施例１〜９のクリーム状ファンデーションは、「粉体の分散性」、「肌への密着性」、「化粧膜の柔軟性」、「化粧持続性」の全ての項目に優れた油中水型乳化化粧料であった。一方、成分（ａ）を含有しない比較例１では、粉体の分散性と肌への密着性が劣っていた。また、成分（ｂ）を含有しない比較例２では、粉体の分散性と化粧持続性が劣っていた。更に、成分（ｃ）を含有しない比較例３では、粉体の分散性と肌への密着性、化粧持続性が劣っていた。そして、成分（ａ）の代わりにロジン酸ペンタエリスリットを含有した比較例４では、化粧膜の柔軟性に、成分（ａ）の代わりにキャンデリラワックスを含有した比較例５では、粉体の分散性、化粧膜の柔軟性等が劣っていた。
【００３９】
（製造方法）
Ａ：成分１〜６を混合する。
Ｂ：Ａに成分７〜１１を添加して、混合分散する。
Ｃ：成分１２〜１５を混合溶解する。
Ｄ：Ｂを攪拌しながら、Ｃを添加し、乳化する。
Ｅ：Ｄを容器に充填し、乳液状ファンデーションを得た。
実施例１０の乳液状ファンデーションは、「粉体の分散性」、「肌への密着性」、「化粧膜の柔軟性」、「化粧持続性」の全ての項目に優れた油中水型乳化化粧料であった。
【００４１】
（製造方法）
Ａ：成分１〜８を混合する。
Ｂ：Ａに成分９〜１１を添加して、混合分散する。
Ｃ：成分１２〜１５を混合溶解する。
Ｄ：Ｂを攪拌しながら、Ｃを添加し、乳化する。
Ｅ：Ｄを容器に充填し、振とう分散タイプ液状日焼け止め料を得た。
実施例１１の振とう分散タイプ液状日焼け止め料は、「粉体の分散性」、「肌への密着性」、「化粧膜の柔軟性」、「化粧持続性」の全ての項目に優れた油中水型乳化化粧料であった。
【００４３】
（製造方法）
Ａ：成分１〜１０を混合溶解する。
Ｂ：Ａに成分１１〜１５を添加して、混合分散する。
Ｃ：成分１６〜１８を混合溶解する。
Ｄ：Ｂを攪拌しながら、Ｃを添加し、乳化する。
Ｅ：Ｄを容器に溶融充填し、固形状ファンデーションを得た。
実施例１２の固形状ファンデーションは、「粉体分散性」、「肌への密着性」、「化粧膜の柔軟性」、「化粧持続性」の全ての項目に優れた油中水型乳化化粧料であった。
【００４５】
（製造方法）
Ａ：成分１〜９を混合溶解する。
Ｂ：Ａに成分１０〜１４を添加して、混合分散する。
Ｃ：成分１５〜１８を混合溶解する。
Ｄ：Ｂを攪拌しながら、Ｃを添加し、乳化する。
Ｅ：Ｄを容器に溶融充填し、スティック状コンシーラーを得た。
実施例１３のスティック状コンシーラーは、「粉体の分散性」、「肌への密着性」、「化粧膜の柔軟性」、「化粧持続性」の全ての項目に優れた油中水型乳化化粧料であった。
【００４７】
（製造方法）
Ａ：成分１〜１１を混合する。
Ｂ：Ａに成分１２〜１４を添加して、混合分散する。
Ｃ：成分１５〜１７を混合溶解する。
Ｄ：Ｂを攪拌しながら、Ｃを添加し、乳化する。
Ｅ：Ｄを容器に充填し、乳液状コントロールカラーを得た。
実施例１４の乳液状コントロールカラーは、「粉体の分散性」、「肌への密着性」、「化粧膜の柔軟性」、「化粧持続性」の全ての項目に優れた油中水型乳化化粧料であった。
【００４９】
（製造方法）
Ａ：成分１〜８を混合する。
Ｂ：Ａに成分９〜１３を添加して、混合分散する。
Ｃ：成分１４〜１７を混合溶解する。
Ｄ：Ｂを攪拌しながら、Ｃを添加し、乳化する。
Ｅ：Ｄを容器に充填し、乳液状下地料を得た。
実施例１５の乳液状下地料は、「粉体の分散性」、「肌への密着性」、「化粧膜の柔軟性」、「化粧持続性」の全ての項目に優れた油中水型乳化化粧料であった。
【００５１】
（製造方法）
Ａ：成分１〜８を混合する。
Ｂ：Ａに成分９〜１１を添加して、混合分散する。
Ｃ：成分１２〜１４を混合溶解する。
Ｄ：Ｂを攪拌しながら、Ｃを添加し、乳化する。
Ｅ：Ｄを容器に溶融充填し、固形状アイカラーを得た。
実施例１６の固形状アイカラーは、「粉体分散性」、「肌への密着性」、「化粧膜の柔軟性」、「化粧持続性」の全ての項目に優れた油中水型乳化化粧料であった。
【００５３】
（製造方法）
Ａ：成分１〜８を混合する。
Ｂ：Ａに成分９を添加して、混合分散する。
Ｃ：成分１０〜１４を混合溶解する。
Ｄ：Ｂを攪拌しながら、Ｃを添加し、乳化する。
Ｅ：Ｄを容器に充填し、スキンクリームを得た。
実施例１７のスキンクリームは、「粉体の分散性」、「肌への密着性」、「化粧膜の柔軟性」、「潤い感の持続性」の全ての項目に優れた油中水型乳化化粧料であった。
【００５５】
【発明の効果】
以上詳述したように、本発明の油中水型乳化化粧料は、肌への密着性に優れながら、化粧膜の柔軟性にも優れ、化粧持続性及び粉体分散性が良好な油中水型乳化であった。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a water-in-oil emulsified cosmetic containing a resin component obtained by fractional extraction from candelilla wax, a hydrophobized powder and a silicone surfactant, and more specifically, adhesion to the skin. The present invention relates to a water-in-oil emulsified cosmetic that has excellent cosmetic film flexibility and excellent makeup durability and powder dispersibility.
[0002]
[Prior art]
Conventionally, water-in-oil emulsified cosmetics can form a hydrophobic cosmetic film on the skin, so that they have been widely used as foundations, lipsticks, sunscreens and the like as cosmetics with excellent makeup sustainability. In addition, in order to prevent makeup collapse and color sink due to sweat and the like, powder that has been previously hydrophobized has been used as the powder to be blended in the water-in-oil emulsified cosmetic. Furthermore, in order to improve the adhesion of the blended powder to the skin, solid oils such as candelilla wax and oil-soluble resins such as rosin acid pentaerythritol have been blended.
[0003]
[Problems to be solved by the invention]
However, when the powder is hydrophobized in advance and blended into a water-in-oil emulsified cosmetic, the dispersibility of the powder is improved to some extent, but the adhesion to the skin is low and the makeup sustainability is satisfactory. It wasn't. In addition, the method of blending solid oils such as candelilla wax and oil-soluble resins such as rosinic acid pentaerythritol improves makeup sustainability, but when blended in a large amount, the makeup film becomes hard and the makeup film is flexible. In some cases, the sexiness decreased.
Therefore, it has been desired to develop a water-in-oil emulsified cosmetic with excellent adhesion to the skin, excellent flexibility of the cosmetic film, and good makeup sustainability and powder dispersibility.
[0004]
[Means for Solving the Problems]
Under such circumstances, the present inventors have conducted intensive research, and as a result, water-in-oil emulsified cosmetics containing a resin fraction obtained by fractional extraction from candelilla wax, a hydrophobized powder, and a silicone surfactant. The present invention has been found to solve the above problems.
[0005]
That is, the present invention provides the following components (a) to (c);
(A) Resin content obtained by fractional extraction from candelilla wax
(B) Hydrophobized powder
(C) Silicone surfactant
It is intended to provide a water-in-oil type emulsified cosmetic comprising Further, the present invention provides the water-in-oil emulsified cosmetic, which further contains silicone oil as the component (d). Furthermore, the water-in-oil emulsified cosmetic according to any one of the above, wherein the softening point of the component (a) is 35 to 55 ° C.
[0006]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, the present invention will be described in detail.
The component (a) used in the present invention is a resin component obtained by fractional extraction from candelilla wax with an organic solvent. The candelilla wax usually contains a resin content of 15 to 30% by mass (hereinafter simply referred to as “%”), but the resin content concentration of the component (a) used in the present invention is preferably 65% or more, 85% or more is more preferable. The method of fractionating and extracting the resin component from the candelilla wax is, for example, adding an organic solvent to the candelilla wax and heating it on a water bath or the like to dissolve the candelilla wax, and then cooling it to room temperature. There is a method in which a wax crystal is precipitated, the crystal is removed by filtration, and the organic solvent is distilled off from the filtrate. Examples of the organic solvent used here include alcohols such as ethanol and isopropyl alcohol, ketones, and esters. The resin component thus obtained is a light yellow to amber transparent resin component. The resin component of component (a) of the present invention has a very low softening point compared to the melting point (about 72 ° C.) of conventional candelilla wax, and the softening point is preferably 35 to 55 ° C. (Measurement method of softening point: Cosmetic raw material standard general test method, sample 0.5 g, temperature rising rate 0.2 ° C./min, 12 mmφ, 10 g lead sphere is used.)
[0007]
Examples of the resin component obtained by fractional extraction from the candelilla wax of component (a) include those registered under the name of Candelilla wax extract in INCI (International Nomenclature Cosmetic Ingredient). Examples thereof include candelilla resin (manufactured by Nippon Natural Co., Ltd.) in which the resin component is dissolved in an oil or alcohol.
[0008]
The content of the component (a) in the water-in-oil emulsified cosmetic of the present invention is preferably 0.1 to 15%. When used in this range, it is possible to obtain a water-in-oil emulsified cosmetic that is particularly excellent in the flexibility of the cosmetic film and the adhesion to the skin.
[0009]
Component (b) used in the present invention is obtained by subjecting powder to a hydrophobic treatment by a generally known technique. The powder used for component (b) may be any powder that is usually used in cosmetics, such as spherical, plate-like, needle-like shapes, fumes, fine particles, pigment grades, etc., porous There are no particular restrictions on the particle structure such as non-porous, and inorganic powders, glitter powders, organic powders, pigment powders, composite powders and the like can be mentioned. Specifically, titanium oxide, low-order titanium oxide, conger, ultramarine, bengara, yellow iron oxide, black iron oxide, zinc oxide, aluminum oxide, silicon dioxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, chromium oxide , Chromium hydroxide, carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, synthetic sericite, sericite, talc, kaolin, silicon carbide, barium sulfate, bentonite, smectite, boron nitride, etc. Inorganic powders, bismuth oxychloride, titanium mica, iron oxide-coated mica, iron oxide mica titanium, organic pigment-treated mica titanium, aluminum powder and other glittering powders, nylon powder, polymethyl methacrylate, polyethylene powder, polystyrene Uder, organopolysiloxane elastomer powder, polymethylsilsesquioxane powder, wool powder, silk powder, crystalline cellulose, organic powders such as N-acyl lysine, organic tar pigments, pigment powders such as organic pigment lake pigments And composite powders such as fine particle titanium oxide-coated mica titanium, fine particle zinc oxide-coated mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, and the like. Can be used.
[0010]
Examples of the treatment agent for subjecting the powder to water repellency in the component (b) include dimethylpolysiloxane, methylhydrogenpolysiloxane, high-viscosity silicone, cross-linked silicone, fluorine-modified silicone, acrylic-modified silicone, and silicone resin. Silicone compounds, perfluoroalkylsilanes, anionic surfactants, cationic surfactants, surfactants such as nonionic surfactants, metal soaps such as zinc laurate and zinc stearate, polyisobutylene, wax, higher fatty acids, Oils such as higher alcohols, fluorine compounds such as N-acylamino acids, perfluoroalkyl phosphoric acid and salts thereof, perfluoropolyether, perfluoropolyether alkyl phosphoric acid and salts thereof, and polyvinyls such as polyvinylpyrrolidone-hexadecene copolymers Pyrrolidone-modified polymers, and the like, and these can be used singly or in combination.
[0011]
In the component (b), a method for treating the powder with the treating agent is usually a known method and is not particularly limited. For example, a wet method using a solvent, a gas phase method, a mechanochemical Law. Moreover, the treatment ratio of the treating agent and the powder in the component (b) is preferably 0.1 to 20: 99.9 to 80 as a mass ratio.
[0012]
The content of component (b) in the water-in-oil emulsified cosmetic of the present invention is preferably 0.1 to 60%. When used in this range, a water-in-oil emulsified cosmetic with better powder dispersibility can be obtained.
[0013]
The component (c) used in the present invention is used as an emulsifier in the water-in-oil emulsified cosmetic of the present invention. For example, a polyoxyalkylene-modified organopolysiloxane represented by the following general formula (1), The long-chain alkyl-containing polyoxyalkylene-modified organopolysiloxane represented by the following average composition formula (2) or (3) can be used, and one or more of them can be used. The component (c) preferably has an HLB of 6 or less from the viewpoint of emulsion stability.
[0014]
[Chemical 1]
[Wherein R1A hydrogen atom or a monovalent hydrocarbon group having 1 to 5 carbon atoms. R2;-( CH2)l-O- (C2H4O)x-(C3H6O)y-R3. R3A hydrogen atom and a lower alkyl group. a, b; a number selected from 0, 1, 2, 3; However, a + b = 3. m, n: 0 or a positive integer. l: a positive integer. x: 0 or a positive integer, y: 0 or a positive integer, and x and y are not 0 at the same time. However, n + b is an integer of 1 or more.
]
[0016]
Such polyoxyalkylene-modified organopolysiloxanes are commercially available products such as silicon KF-6011, KF6012, KF-6013, KF-6015, KF-6016, KF-6017, and X-22-4991 (all Shin-Etsu Chemical). Kogyo Kogyo Co., Ltd.), NUC silicon L7002 (Nihon Unicar Co., Ltd.), SH-3775C, SH-3775C (both manufactured by Toray Dow Corning Silicone Co., Ltd.) and the like. The component (c) preferably has an HLB of 6 or less from the viewpoint of emulsion stability.
[0017]
R4 aR5 bR6 cSiO(4-abc) / 2 ... (2)
[Wherein R4They may be the same or different, and an alkyl group having 1 to 10 carbon atoms, a hydrogen atom, an aryl group, an aralkyl group, or a fluorine-substituted alkyl group. R5; -CmH2m-O- (C2HFourO)d-(CThreeH6O)e-R7Wherein m is an integer of 1 to 5, d and e are integers of 0 or more, and d + e ≧ 1 to 200, and R7; A hydrogen atom or a monovalent hydrocarbon group having 1 to 5 carbon atoms or-(CO) -R8An organic group represented by R8A monovalent hydrocarbon group having 1 to 5 carbon atoms). R6A monovalent hydrocarbon group having 10 to 30 carbon atoms; a, b, and c are 1.0 ≦ a ≦ 2.5, 0.001 ≦ b ≦ 1.5, and 0.001 ≦ c ≦ 1.5, respectively. ]
[0018]
R9 aR10 bR11 cSiO(4-abc) 2 ... (3)
[Wherein R9They may be the same or different, and an alkyl group having 1 to 10 carbon atoms, a hydrogen atom, an aryl group, an aralkyl group, a fluorine-substituted alkyl group. R10; -CmH2m-O- (C2HFourO)d-(CThreeH6O)e-R12(Wherein, m is an integer of 1 to 5, d and e are integers of 0 or more, and d + e ≧ 1 to 200, and R12Is a hydrogen atom or a monovalent hydrocarbon group having 1 to 5 carbon atoms or-(CO) -R13An organic group represented by R13Is a monovalent hydrocarbon group having 1 to 5 carbon atoms). R11; -CnH2n-O- (C2HFourO)f-(CThreeH6O)g-R14(In the formula, n is an integer of 1 to 5, f and g are integers of 0 or more, and f + g ≧ 0 to 200, R14Is a monovalent hydrocarbon group having 10 to 30 carbon atoms). a, b, and c are 1.0 ≦ a ≦ 2.5, 0.001 ≦ b ≦ 1.5, and 0.001 ≦ c ≦ 1.5, respectively. ]
[0019]
Such long-chain alkyl-containing polyoxyalkylene-modified organopolysiloxanes are commercially available products such as ABIL EM-90, ABIL B9806 (all manufactured by Goldschmidt), Silicon KF-6026 (manufactured by Shin-Etsu Chemical Co., Ltd.), etc. Can be mentioned.
[0020]
The content of the component (c) in the water-in-oil emulsified cosmetic of the present invention is preferably 0.1 to 10%. If it uses in this range, the water-in-oil type emulsified cosmetics which are excellent in emulsion stability can be obtained. In the water-in-oil emulsified cosmetic of the present invention, a surfactant other than the component (c) can be used in combination as an emulsification aid.
[0021]
The water-in-oil emulsified cosmetic of the present invention contains water in addition to the above components. The water content in the water-in-oil emulsified cosmetic of the present invention is preferably 5 to 80%, particularly preferably 10 to 70%. If it uses in this range, the water-in-oil type emulsified cosmetic which is more excellent in use feeling and emulsion stability can be obtained.
[0022]
The water-in-oil emulsified cosmetic of the present invention can further contain silicone oil as component (d). Silicone oil used in the present invention is usually used in cosmetics, for example, chain silicone such as dimethylpolysiloxane and methylphenylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and the like. Examples include cyclic silicones, fluorine-modified polysiloxanes, amino-modified polysiloxanes, fatty acid-modified polysiloxanes, higher alcohol-modified polysiloxanes, alkyl-modified polysiloxanes, and the like, and one or more of these can be used. Among these, when a volatile silicone oil such as low molecular weight chain silicone, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane or the like is selected as the component (d), a water-in-oil type emulsion makeup with particularly excellent makeup durability. You can get a fee. The content when the component (d) is contained in the water-in-oil emulsified cosmetic of the present invention is preferably 50 to 100% in the oil phase.
[0023]
In the water-in-oil emulsified cosmetic of the present invention, in addition to the above-mentioned components, oil agents other than the component (d) and components other than the component (c) in a quantitative and qualitative range depending on the purpose. Surfactant, oil gelling agent, untreated powder, aqueous component, water-soluble polymer, UV absorber, aqueous gelling agent such as bentonite, hectorite, smectite, antioxidant, paraoxybenzoic acid derivative, phenoxyethanol Preservatives such as vitamins A, B6, B12, C, E, etc. vitamins, chelating agents, rosemary extract, chamomile extract, carrot extract, assembly extract, catechin, catechin derivatives, licorice extract, Sakuha extract , Hop extract, collagen, hyaluronic acid, hyaluronic acid derivatives, trehalose, aloe extract and other cosmetic ingredients, menthol, camphor, sorbit Cooling agents such as Le, it can contain components that are generally used in ordinary cosmetics of perfumes.
[0024]
In the water-in-oil emulsified cosmetic of the present invention, in addition to the above components, in order to dilute the component (a) and to reduce the powderiness of the powder, Therefore, it can contain an oil agent usually used in cosmetics. Oils used here include hydrocarbons, fats and oils, waxes, hardened, regardless of the origin, such as animal oil, vegetable oil, synthetic oil, and the properties of solid oil, semi-solid oil, liquid oil, volatile oil, etc. Oils such as oils, ester oils, fatty acids, higher alcohols, fluorinated oils, lanolin derivatives and the like can be mentioned. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, paraffin wax, ceresin wax, microcrystalline wax, molasses, montan wax, Fischer-Tropsch wax, olive oil, castor oil, jojoba oil, mink oil, macadamian nut Fats and oils such as oil, beeswax, carnauba wax, candelilla wax, waxes such as gay wax, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, diglyceryl diisostearate, tri Diglyceryl isostearate, glyceryl tribehenate, rosin acid pentaerythritol ester, neopentyl glycol dioctanoate, cholesterol fatty acid ester, N- Esters such as uroyl-L-glutamate di (cholesteryl, behenyl, octyldodecyl), higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol, perfluoropolyether, perfluorodecane , Fluorinated oils such as perfluorooctane, lanolin derivatives such as lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin alcohol, and the like, and these can be used alone or in combination. The content of the oil agent in the oil-in-water cosmetic of the present invention is preferably 1 to 50% and more preferably 5 to 40% from the viewpoints of emulsion stability and usability.
[0025]
In addition to the above components, the water-in-oil emulsified cosmetic of the present invention may contain a surfactant as an emulsification aid and a dispersant. Examples of such surfactants include anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, and the like, and one or more of these can be used. . Specifically, as anionic surfactants, fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, 12-hydroxystearic acid and alkalis such as sodium, potassium, triethanolamine, etc. Examples include fatty acid soaps, acyl glutamates, alkyl phosphates, polyoxyalkylene-added alkyl phosphates and the like formed by the substance. Examples of the cationic surfactant include alkylamine salts and alkyl quaternary ammonium salts. Examples of amphoteric surfactants include N, N-dimethyl-N-alkyl-N-carboxylmethyl ammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine. N, N-dialkyl-N, N-bis (polyoxyethylene sulfate) ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine, lecithin, phospholipid and the like. Nonionic surfactants include glycerin fatty acid esters and alkylene glycol adducts thereof, polyglycerin fatty acid esters and alkylene glycol adducts thereof, propylene glycol fatty acid esters and alkylene glycol adducts thereof, sorbitan fatty acid esters and alkylene glycol adducts thereof. , Fatty acid ester of sorbitol and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, alkylene glycol of lanolin An adduct etc. are mentioned, These can be used 1 type, or 2 or more types. The content of the surfactant in the water-in-oil emulsified cosmetic of the present invention varies depending on the type of surfactant, the amount and quality of the oil, but is generally preferably 0.01 to 20%.
[0026]
In addition to the above components, the water-in-oil emulsified cosmetic of the present invention can contain an oil gelling agent as a stabilizer and a feel modifier. Examples of such oil gelling agents include dextrin fatty acid ester, sucrose fatty acid ester, starch fatty acid ester, aluminum isostearate, calcium stearate, partially crosslinked organopolysiloxane, organically modified bentonite, fumed silicic acid, and the like. One or more of these can be used. The content of the oil gelling agent in the water-in-oil emulsified cosmetic of the present invention is preferably about 0.1 to 10%.
[0027]
In addition to the above components, the water-in-oil emulsified cosmetic of the present invention may contain an aqueous component as a feel modifier, a moisturizer, a refreshing agent, a preservative, and the like. Examples of such aqueous components include polyhydric alcohols such as propylene glycol, 1,3-butylene glycol, and dipropylene glycol; glycerols such as glycerin, diglycerin, and polyglycerin; sorbitol, maltitol, sucrose, and starch sugar. Sugars such as guar gum, sclerotium gum, gellan gum, pectin, agar, chondroitin sulfate sodium, hyaluronic acid, gum arabic, sodium alginate, carrageenan, xanthan gum, locust bean gum, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, carboxyvinyl polymer, Water-soluble polymers such as alkyl-modified carboxyvinyl polymer, polyvinyl alcohol, polyvinyl pyrrolidone, sodium polyacrylate, sodium chloride Arm, magnesium chloride, salts such as sodium lactate, aloe vera, hamamelis, cucumber, lemon, lavender, plant extracts such as rose, and the like, and these can be used singly or in combination. The content of the aqueous component in the water-in-oil emulsified cosmetic of the present invention is preferably about 0.1 to 30%.
[0028]
In addition to the above components, the water-in-oil emulsified cosmetic of the present invention can contain an ultraviolet absorber. Examples of such UV absorbers include 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid sodium salt, 2,2 '-Dihydroxy-4,4'-dimethoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone-5-sulfonic acid sodium salt, 2,4-dihydroxybenzophenone, 2,2'4,4'-tetra Benzophenone series such as hydroxybenzophenone, 2,4,6-trianilino-para- (carbo-2'-ethylhexyl-1'-oxy) -1,3,5-triazine, 2-ethylhexyl salicylate, phenyl salicylate, homomenthyl salicylate Salicylic acid system such as PABA series such as perfume acid, ethyl paraaminobenzoate, glyceryl paraaminobenzoate, amyl paradimethylaminobenzoate, amyl-2-ethylhexyl paradimethylaminobenzoate, ethyl paradihydroxypropylbenzoate, p-methoxycinnamic acid-2- Cinnamates such as ethylhexyl and 4-methoxycinnamic acid-2-ethoxyethyl, dibenzoylmethanes such as 2- (2-hydroxy-5-methylphenyl) benzotriazole and 4-tert-4′-methoxydibenzoylmethane, Examples thereof include oxybenzone, dimethoxybenzylidene dioxoimidazolicin propionate-2-ethylhexyl, and the like, and one or more of them can be used.
[0029]
The water-in-oil emulsified cosmetic of the present invention can be applied to any cosmetics such as skin care cosmetics, makeup cosmetics, and hair cosmetics. Makeup cosmetics such as foundation, base material, control color, concealer, eye color, lipstick and sunscreen cosmetics. Further, the form of the water-in-oil emulsified cosmetic of the present invention may be any of liquid, emulsion, cream, gel, and solid.
[0030]
【Example】
Hereinafter, the present invention will be described in more detail with reference to examples. Note that these do not limit the present invention.
[0031]
Examples 1-9 and Comparative Examples 1-5: Creamy foundation
A cream-like foundation having the composition shown in Tables 1 to 3 was prepared by the following production method, and “dispersibility of powder”, “adhesion to skin”, “flexibility of cosmetic film”, “makeup persistence” Each item was evaluated by the following evaluation method and criteria, and the results are shown in Tables 1 to 3.
[0032]
[Table 1]
[Table 2]
[Table 3]
(Production method)
A: Components 1 to 12 are mixed and dissolved.
B: Components 13 to 24 are added to A and mixed and dispersed.
C: Components 25 to 27 are mixed and dissolved.
D: While stirring B, add C and emulsify.
E: D was filled in a container to obtain a creamy foundation.
[0036]
[Evaluation method: Dispersibility of powder]
The cream foundations of the above Examples and Comparative Examples were drawn on a glass plate using an applicator having a thickness of 25 μm, and the agglomeration property of the powder was observed, and judged according to the following criteria.
(Observation results): (Judgment)
Aggregation of powder is not observed: ◎
Slight aggregation of powder is observed: △
Clearly agglomeration of the powder is observed: ×
[0037]
[Evaluation method: Adhesion to skin, flexibility of cosmetic film, makeup sustainability]
The cream foundations of the above examples and comparative examples were used by 20 professional cosmetic panels, and each panel had the following evaluation criteria for “adhesion to skin” and “flexibility of cosmetic film” for each foundation. The average score of the scores of all the panels was calculated for each foundation and judged according to the following criteria. In addition, about "makeup sustainability", the state of 5 hours after foundation application was evaluated.
〔Evaluation criteria〕
Usability: Score
Very good: 5 points
Good: 4 points
Normal: 3 points
Slightly bad: 2 points
Defect: 1 point
[Criteria]
Average score of all panels: Judgment
4.5 or more: ◎
3.5 or more and less than 4.5: ○
2.0 or more and less than 3.5: △
Less than 2.0: ×
[0038]
As is apparent from the results of Tables 1 to 3, the cream-like foundations of Examples 1 to 9 according to the present invention are “dispersibility of powder”, “adhesion to skin”, and “flexibility of cosmetic film”. The water-in-oil type emulsified cosmetic excellent in all items of “makeup lasting”. On the other hand, in the comparative example 1 which does not contain a component (a), the dispersibility of powder and the adhesiveness to skin were inferior. Moreover, in the comparative example 2 which does not contain a component (b), the dispersibility of powder and makeup persistence were inferior. Furthermore, in the comparative example 3 which does not contain a component (c), the dispersibility of powder, the adhesiveness to skin, and makeup sustainability were inferior. And in the comparative example 4 containing the rosinic acid pentaerythritol instead of the component (a), the flexibility of the decorative film, and in the comparative example 5 containing the candelilla wax instead of the component (a), Dispersibility, flexibility of the decorative film, etc. were inferior.
[0039]
(Production method)
A: Components 1 to 6 are mixed.
B: Components 7 to 11 are added to A and mixed and dispersed.
C: Components 12 to 15 are mixed and dissolved.
D: While stirring B, add C and emulsify.
E: D was filled into a container to obtain an emulsion foundation.
The emulsion foundation of Example 10 is a water-in-oil emulsification excellent in all items of “dispersibility of powder”, “adhesion to skin”, “flexibility of cosmetic film”, and “persistence of makeup”. It was a cosmetic.
[0041]
(Production method)
A: Components 1 to 8 are mixed.
B: Components 9 to 11 are added to A and mixed and dispersed.
C: Components 12 to 15 are mixed and dissolved.
D: While stirring B, add C and emulsify.
E: D was filled into a container to obtain a shake dispersion type liquid sunscreen.
The shaking dispersion type liquid sunscreen of Example 11 was excellent in all items of “dispersibility of powder”, “adhesion to skin”, “flexibility of cosmetic film”, and “makeup sustainability”. It was a water-in-oil emulsified cosmetic.
[0043]
(Production method)
A: Components 1 to 10 are mixed and dissolved.
B: Components 11 to 15 are added to A and mixed and dispersed.
C: Components 16 to 18 are mixed and dissolved.
D: While stirring B, add C and emulsify.
E: D was melt-filled in a container to obtain a solid foundation.
The solid foundation of Example 12 is a water-in-oil emulsion makeup excellent in all items of “powder dispersibility”, “adhesion to skin”, “flexibility of cosmetic film”, and “makeup sustainability”. It was a fee.
[0045]
(Production method)
A: Components 1 to 9 are mixed and dissolved.
B: Components 10 to 14 are added to A and mixed and dispersed.
C: Components 15 to 18 are mixed and dissolved.
D: While stirring B, add C and emulsify.
E: D was melt-filled into a container to obtain a stick concealer.
The stick-type concealer of Example 13 is a water-in-oil emulsification excellent in all items of “dispersibility of powder”, “adhesion to skin”, “flexibility of cosmetic film”, and “persistence of makeup”. It was a cosmetic.
[0047]
(Production method)
A: Components 1 to 11 are mixed.
B: Components 12 to 14 are added to A and mixed and dispersed.
C: Components 15 to 17 are mixed and dissolved.
D: While stirring B, add C and emulsify.
E: D was filled into a container to obtain an emulsion control color.
The emulsion control color of Example 14 is a water-in-oil type excellent in all items of “dispersibility of powder”, “adhesion to skin”, “flexibility of cosmetic film”, and “makeup persistence”. It was an emulsified cosmetic.
[0049]
(Production method)
A: Components 1 to 8 are mixed.
B: Components 9 to 13 are added to A and mixed and dispersed.
C: Components 14 to 17 are mixed and dissolved.
D: While stirring B, add C and emulsify.
E: D was filled in a container to obtain an emulsion base material.
The emulsion base material of Example 15 is a water-in-oil type excellent in all items of “dispersibility of powder”, “adhesion to skin”, “flexibility of cosmetic film”, and “makeup sustainability”. It was an emulsified cosmetic.
[0051]
(Production method)
A: Components 1 to 8 are mixed.
B: Components 9 to 11 are added to A and mixed and dispersed.
C: Components 12 to 14 are mixed and dissolved.
D: While stirring B, add C and emulsify.
E: D was melt-filled into a container to obtain a solid eye color.
The solid eye color of Example 16 is a water-in-oil emulsification excellent in all items of “powder dispersibility”, “adhesion to skin”, “flexibility of cosmetic film” and “makeup sustainability”. It was a cosmetic.
[0053]
(Production method)
A: Components 1 to 8 are mixed.
B: Component 9 is added to A and mixed and dispersed.
C: Components 10 to 14 are mixed and dissolved.
D: While stirring B, add C and emulsify.
E: D was filled into a container to obtain a skin cream.
The skin cream of Example 17 is a water-in-oil type excellent in all items of “dispersibility of powder”, “adhesion to skin”, “flexibility of cosmetic film”, and “sustainability of moisture”. It was an emulsified cosmetic.
[0055]
【The invention's effect】
As described above in detail, the water-in-oil emulsified cosmetic of the present invention is excellent in the adhesiveness to the skin, but also in the flexibility of the cosmetic film, in the makeup durability and powder dispersibility. It was water-type emulsification.
Claims (2)
（ａ）キャンデリラワックスより分別抽出して得られた樹脂分
（ｂ）疎水化処理粉体
（ｃ）下記平均組成式（２）又は（３）で示される長鎖アルキル含有ポリオキシアルキレン変性から選ばれる一種又は二種以上のシリコーン系界面活性剤
（ｄ）揮発性シリコーン油
Ｒ４ aＲ５ bＲ６ cＳｉＯ(4-a-b-c)/2 …（２）
［式中、Ｒ４；同一又は異なってもよく、炭素数１〜１０のアルキル基、水素原子、アリール基、アラルキル基、フッ素置換アルキル基。Ｒ５；−ＣmＨ2m−Ｏ−（Ｃ2Ｈ4Ｏ）d−（Ｃ3Ｈ6Ｏ）e−Ｒ７で示される基（式中、ｍ；１〜５の整数、ｄ、ｅは０以上の整数、且つ、ｄ＋ｅ≧１〜２００であり、Ｒ７；水素原子若しくは炭素数１〜５の一価炭化水素基又は−（ＣＯ）−Ｒ８で示される有機基、Ｒ８；炭素数１〜５の一価炭化水素基）。Ｒ６；炭素数１０〜３０の一価炭化水素基。ａ、ｂ、ｃはそれぞれ１．０≦ａ≦２．５、０．００１≦ｂ≦１．５、０．００１≦ｃ≦１．５である。］
Ｒ９ aＲ１０ bＲ１１ cＳｉＯ(4-a-b-c)2 …（３）
［式中、Ｒ９；同一又は異なってもよく、炭素数１〜１０のアルキル基、水素原子、アリール基、アラルキル基、フッ素置換アルキル基。Ｒ１０；−ＣmＨ2m−Ｏ−（Ｃ2Ｈ4Ｏ）d−（Ｃ3Ｈ6Ｏ）e−Ｒ１２で示される基（式中、ｍは１〜５の整数、ｄ、ｅは０以上の整数、且つ、ｄ＋ｅ≧１〜２００であり、Ｒ１２は水素原子若しくは炭素数１〜５の一価炭化水素基又は−（ＣＯ）−Ｒ１３で示される有機基、Ｒ１３は炭素数１〜５の一価炭化水素基）。Ｒ１１；−ＣnＨ2n−Ｏ−（Ｃ2Ｈ4Ｏ）f−（Ｃ3Ｈ6Ｏ）g−Ｒ１４（式中、ｎは１〜５の整数、ｆ、ｇは０以上の整数、且つ、ｆ＋ｇ≧０〜２００であり、Ｒ１４は炭素数１０〜３０の一価炭化水素基）。ａ、ｂ、ｃはそれぞれ１．０≦ａ≦２．５、０．００１≦ｂ≦１．５、０．００１≦ｃ≦１．５である。］
を含有することを特徴とする油中水型乳化化粧料。The following components (a) to (d) ;
(A) Candelilla resin component obtained by differential extraction from wax (b) hydrophobized powder (c) below SL average composition formula (2) or a long chain alkyl-containing polyoxyalkylene-modified represented by (3) one or two or more silicone-based surfactant selected from
(D) Volatile silicone oil
R 4 a R 5 b R 6 c SiO (4-abc) / 2 (2)
[In formula, R < 4 > may be same or different and is a C1-C10 alkyl group, a hydrogen atom, an aryl group, an aralkyl group, and a fluorine-substituted alkyl group. R 5 ; —C m H 2m —O— (C 2 H 4 O) d — (C 3 H 6 O) e —R 7 (wherein, m: an integer of 1 to 5, d, e Is an integer of 0 or more and d + e ≧ 1 to 200, R 7 ; a hydrogen atom or a monovalent hydrocarbon group having 1 to 5 carbon atoms or an organic group represented by — (CO) —R 8 , R 8 ; A monovalent hydrocarbon group having 1 to 5 carbon atoms). R 6 ; a monovalent hydrocarbon group having 10 to 30 carbon atoms. a, b, and c are 1.0 ≦ a ≦ 2.5, 0.001 ≦ b ≦ 1.5, and 0.001 ≦ c ≦ 1.5, respectively. ]
R 9 a R 10 b R 11 c SiO (4-abc) 2 ... (3)
[Wherein, R 9 may be the same or different, and an alkyl group having 1 to 10 carbon atoms, a hydrogen atom, an aryl group, an aralkyl group, or a fluorine-substituted alkyl group. R 10 ; —C m H 2m —O— (C 2 H 4 O) d — (C 3 H 6 O) e —R 12 (wherein, m is an integer of 1 to 5, d, e Is an integer of 0 or more and d + e ≧ 1 to 200, R 12 is a hydrogen atom or a monovalent hydrocarbon group having 1 to 5 carbon atoms or an organic group represented by — (CO) —R 13 , R 13 is A monovalent hydrocarbon group having 1 to 5 carbon atoms). R 11; -C n H 2n -O- (C 2 H 4 O) f - (C 3 H 6 O) g -R 14 ( wherein, n an integer of 1 to 5, f, g is 0 or more An integer, and f + g ≧ 0 to 200, and R 14 is a monovalent hydrocarbon group having 10 to 30 carbon atoms). a, b, and c are 1.0 ≦ a ≦ 2.5, 0.001 ≦ b ≦ 1.5, and 0.001 ≦ c ≦ 1.5, respectively. ]
A water-in-oil type emulsified cosmetic comprising:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001163883A JP4919543B2 (en) | 2001-05-31 | 2001-05-31 | Water-in-oil emulsified cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001163883A JP4919543B2 (en) | 2001-05-31 | 2001-05-31 | Water-in-oil emulsified cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002363029A JP2002363029A (en) | 2002-12-18 |
| JP4919543B2 true JP4919543B2 (en) | 2012-04-18 |
Family
ID=19006772
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001163883A Expired - Lifetime JP4919543B2 (en) | 2001-05-31 | 2001-05-31 | Water-in-oil emulsified cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4919543B2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4812423B2 (en) * | 2005-12-27 | 2011-11-09 | 花王株式会社 | Water-in-oil emulsified cosmetic |
| FR2915101B1 (en) * | 2007-04-23 | 2011-07-29 | Fabre Pierre Dermo Cosmetique | DERMATOLOGICAL COMPOSITION FOR THE PREVENTION AND / OR TREATMENT OF ROSACEAE, CUPPEROSIS OR SKINS WITH DIFFUSED REDNESS OR SMALL DILATED VESSELS |
| JP4902752B2 (en) * | 2009-01-27 | 2012-03-21 | 株式会社 資生堂 | Water-in-oil emulsified sunscreen cosmetics |
| WO2012172622A1 (en) * | 2011-06-13 | 2012-12-20 | 株式会社 資生堂 | Solid water-in-oil-type emulsion cosmetic |
| JP6533087B2 (en) * | 2015-04-08 | 2019-06-19 | 株式会社伊勢半 | Water-in-oil emulsion cosmetic |
| US20200129390A1 (en) * | 2017-05-30 | 2020-04-30 | Kao Corporation | Water-in-oil emulsion composition |
| JP7565141B2 (en) * | 2017-05-30 | 2024-10-10 | 花王株式会社 | Water-in-oil emulsion composition |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3890547B2 (en) * | 1997-08-21 | 2007-03-07 | 株式会社伊那貿易商会 | Cosmetics |
| JPH11106310A (en) * | 1997-09-30 | 1999-04-20 | Shiseido Co Ltd | W/o emulsion composition |
| JP3510106B2 (en) * | 1998-06-03 | 2004-03-22 | 株式会社コーセー | Eye makeup cosmetics |
| JP2000044429A (en) * | 1998-08-03 | 2000-02-15 | Kose Corp | Water-in-oil type emulsion cosmetic |
| JP2000053554A (en) * | 1998-08-10 | 2000-02-22 | Kao Corp | Water-in-oil emulsion cosmetics |
| JP3619981B2 (en) * | 1998-10-16 | 2005-02-16 | 株式会社コーセー | Eye makeup cosmetics |
| JP2000327524A (en) * | 1999-05-17 | 2000-11-28 | Nippon Nachiyuraru Prod:Kk | Cosmetic |
| JP3907351B2 (en) * | 1999-08-20 | 2007-04-18 | 株式会社コーセー | Powder composition for cosmetic preparation and powder dispersion in oil for cosmetic preparation |
-
2001
- 2001-05-31 JP JP2001163883A patent/JP4919543B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2002363029A (en) | 2002-12-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3535389B2 (en) | External composition | |
| JP2000063233A (en) | Water-in-oil cosmetic | |
| JP3727901B2 (en) | Oil-in-water emulsified cosmetic | |
| JP2003063919A (en) | Water-in-oil type solid cosmetic | |
| JP2000281532A (en) | Oily solid cosmetic material | |
| JP2004203788A (en) | Solid water-in-oil type emulsified cosmetic | |
| JP5769913B2 (en) | Water-in-oil emulsified makeup cosmetics | |
| JP2000119134A (en) | Oily solid cosmetic | |
| WO2020100573A1 (en) | Water-in-oil composition | |
| JP4919543B2 (en) | Water-in-oil emulsified cosmetic | |
| JP6920168B2 (en) | Powder cosmetics | |
| JP2003095874A (en) | Eyelash cosmetics | |
| JP2002128628A (en) | Powder cosmetic | |
| JP2002348214A (en) | Oil-in-water emulsified cosmetic for covering up hair follicles | |
| JP2018168134A (en) | Oil-in-water type cosmetic | |
| JP3312679B2 (en) | Water-in-oil emulsion composition | |
| JP4047512B2 (en) | Solid oil-in-water cosmetic | |
| JP2001072532A (en) | O/w-type emulsion cosmetic | |
| JP3633820B2 (en) | Water-in-oil emulsion composition | |
| JP4837838B2 (en) | Oil-in-water cosmetic | |
| JP2021161115A (en) | Water-in-oil emulsified cosmetic | |
| JP2002087929A (en) | Gel-like composition and cosmetic product comprising the same | |
| JP2001072533A (en) | W/o-type cosmetic | |
| JP4965145B2 (en) | Oil-in-water cosmetic for cosmetics | |
| JP2003113034A (en) | Oil-in-water type cosmetic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080513 |
|
| RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20080513 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20100713 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100727 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100826 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110329 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110518 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20120105 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20120131 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4919543 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150210 Year of fee payment: 3 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| EXPY | Cancellation because of completion of term |