JP4904730B2 - Separation and recovery of aromatic compounds and hydrogen chloride - Google Patents
Separation and recovery of aromatic compounds and hydrogen chloride Download PDFInfo
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本発明は、芳香族化合物と塩化水素の分離回収方法に関するものである。更に詳しくは、本発明は、芳香族化合物と塩素を反応させることにより、塩素化芳香族化合物と塩化水素を得る工程（塩素化工程）で得られる芳香族化合物を含有する塩化水素のガスから芳香族化合物と塩化水素を各々分離して回収する方法であって、工業的に有用な高品位の塩化水素ガスを得ると同時に芳香族化合物を効率的に回収するという優れた特徴を有する芳香族化合物と塩化水素の分離回収方法に関するものである。 The present invention relates to a method for separating and recovering an aromatic compound and hydrogen chloride. More specifically, the present invention relates to a method of reacting aromatics from a hydrogen chloride gas containing an aromatic compound obtained in a step of obtaining a chlorinated aromatic compound and hydrogen chloride (chlorination step) by reacting the aromatic compound with chlorine. A method for separating and recovering an aromatic compound and hydrogen chloride, each having an excellent feature of efficiently recovering an aromatic compound while obtaining industrially useful high-grade hydrogen chloride gas And hydrogen chloride separation and recovery method.
たとえばベンゼンのような芳香族化合物と塩素からクロルベンゼン（モノクロルベンゼンを意味する。以下、同じ。）のような塩素化芳香族化合物を製造する方法は公知である（たとえば、特許文献１参照。）。 For example, a method for producing a chlorinated aromatic compound such as chlorobenzene (monochlorobenzene means the same hereinafter) from an aromatic compound such as benzene and chlorine is known (for example, see Patent Document 1). .
ところで、芳香族化合物と塩素の反応では芳香族化合物及び塩素化芳香族化合物が含まれる塩化水素のガスが副生する。塩化水素ガスは酸素と反応させて塩素を得、該塩素を芳香族化合物との反応にリサイクル使用する等の有効利用が可能である。塩化水素ガスを有効利用するにあたっては、その中に含まれる芳香族化合物と塩化水素を分離回収する必要がある。 By the way, in the reaction between the aromatic compound and chlorine, hydrogen chloride gas containing the aromatic compound and the chlorinated aromatic compound is by-produced. Hydrogen chloride gas can be effectively used, for example, by reacting with oxygen to obtain chlorine and recycling the chlorine for reaction with an aromatic compound. In order to effectively use hydrogen chloride gas, it is necessary to separate and recover the aromatic compound and hydrogen chloride contained therein.
かかる状況において、本発明が解決しようとする課題は、芳香族化合物と塩素を反応させることにより、塩素化芳香族化合物と塩化水素を得る工程（塩素化工程）で得られる芳香族化合物を含有する塩化水素のガスから芳香族化合物と塩化水素を各々分離して回収する方法であって、工業的に有用な高品位の塩化水素ガスを得ると同時に芳香族化合物を効率的に回収するという優れた特徴を有する芳香族化合物と塩化水素の分離回収方法を提供する点にある。 In such a situation, the problem to be solved by the present invention includes an aromatic compound obtained in a step of obtaining a chlorinated aromatic compound and hydrogen chloride (chlorination step) by reacting the aromatic compound with chlorine. A method for separating and recovering an aromatic compound and hydrogen chloride from a hydrogen chloride gas, and obtaining an industrially useful high-grade hydrogen chloride gas and at the same time efficiently recovering an aromatic compound The object is to provide a method for separating and recovering an aromatic compound having characteristics and hydrogen chloride.
すなわち、本発明は、下記の塩素化工程で得られる芳香族化合物を含有する塩化水素のガスから芳香族化合物と塩化水素を各々分離して回収する方法であって、芳香族化合物を含有する塩化水素ガスを下記塩化水素精製工程に付すことにより塩素化芳香族化合物に溶解させて塩化水素、芳香族化合物及び塩素化芳香族化合物を含む溶液とし、該溶液を下記塩化水素回収工程に付すことにより塩化水素を主とするガスと芳香族化合物及び塩素化芳香族化合物を主とする留分を得、該芳香族化合物及び塩素化芳香族化合物を主とする留分を下記の芳香族化合物回収工程へ供給する塩化水素と芳香族化合物の分離回収方法に係るものである。
塩素化工程：芳香族化合物と塩素を反応させ、塩素化芳香族化合物と塩化水素を得る工程
塩化水素精製工程：芳香族化合物を含有する塩化水素ガスを塩素化芳香族化合物に溶解させて、塩化水素を主とするガスと、塩化水素、芳香族化合物及び塩素化芳香族化合物を含む溶液を得る工程
塩化水素回収工程：塩化水素、芳香族化合物、塩素化芳香族化合物を含む溶液から塩化水素を主とするガスを分離、回収する工程
芳香族化合物回収工程：芳香族化合物及び塩素化芳香族化合物を主とする留分から芳香族化合物を主とする留分を分離、回収する工程
That is, the present invention is a method for separating and recovering an aromatic compound and hydrogen chloride from a hydrogen chloride gas containing an aromatic compound obtained in the following chlorination step, wherein the chloride containing the aromatic compound is recovered. Hydrogen gas is subjected to the following hydrogen chloride purification step to be dissolved in the chlorinated aromatic compound to obtain a solution containing hydrogen chloride, the aromatic compound and the chlorinated aromatic compound, and the solution is subjected to the following hydrogen chloride recovery step. A gas mainly composed of hydrogen chloride and a fraction mainly composed of an aromatic compound and a chlorinated aromatic compound are obtained, and the fraction mainly composed of the aromatic compound and the chlorinated aromatic compound is recovered by the following aromatic compound recovery step. The present invention relates to a method for separating and recovering hydrogen chloride and an aromatic compound to be supplied to the vehicle.
Chlorination process: A process in which aromatic compound and chlorine are reacted to obtain chlorinated aromatic compound and hydrogen chloride. Hydrogen chloride purification process: Hydrogen chloride gas containing aromatic compound is dissolved in chlorinated aromatic compound and chlorinated. Step for obtaining a solution containing hydrogen gas, hydrogen chloride, aromatic compound and chlorinated aromatic compound Hydrogen chloride recovery step: Hydrogen chloride from a solution containing hydrogen chloride, aromatic compound and chlorinated aromatic compound Process for separating and recovering main gas Aromatic compound recovery process: A process for separating and recovering a fraction mainly composed of aromatic compounds from a fraction mainly composed of aromatic compounds and chlorinated aromatic compounds
本発明により、芳香族化合物と塩素を反応させることにより、塩素化芳香族化合物と塩化水素を得る工程（塩素化工程）で得られる芳香族化合物を含有する塩化水素のガスから芳香族化合物と塩化水素を各々分離して回収する方法であって、工業的に有用な高品位の塩化水素ガスを得ると同時に芳香族化合物を効率的に回収するという優れた特徴を有する芳香族化合物と塩化水素の分離回収方法を提供することができる。 According to the present invention, by reacting an aromatic compound and chlorine, the aromatic compound and chloride are obtained from the hydrogen chloride gas containing the aromatic compound obtained in the step of obtaining the chlorinated aromatic compound and hydrogen chloride (chlorination step). A method for separating and recovering hydrogen from each other, wherein an industrially useful high-grade hydrogen chloride gas is obtained, and at the same time, an aromatic compound and hydrogen chloride are efficiently recovered. A separation and recovery method can be provided.
本発明は、下記の塩素化工程で得られる芳香族化合物を含有する塩化水素のガスから芳香族化合物と塩化水素を各々分離して回収する方法である。
塩素化工程：芳香族化合物と塩素を反応させ、塩素化芳香族化合物と塩化水素を得る工程
The present invention is a method for separating and recovering an aromatic compound and hydrogen chloride from a hydrogen chloride gas containing the aromatic compound obtained in the following chlorination step.
Chlorination step: A step of reacting an aromatic compound and chlorine to obtain a chlorinated aromatic compound and hydrogen chloride.
芳香族化合物としては、ベンゼン、トルエン、キシレン等を上げることができる。塩素化芳香族化合物としては、クロルベンゼン等をあげることができる。芳香族化合物としてベンゼンを用い、塩素化芳香族化合物としてクロルベンゼンを得る方法が産業上の観点から特に重要である。 Examples of the aromatic compound include benzene, toluene, xylene and the like. Examples of the chlorinated aromatic compound include chlorobenzene. A method of obtaining chlorobenzene as a chlorinated aromatic compound using benzene as an aromatic compound is particularly important from an industrial viewpoint.
芳香族化合物と塩素を反応させる方法については、特に制限はなく、公知の方法を使用することができる。具体的な方法の例を示すと、次のとおりである。芳香族化合物と塩素のモル比（芳香族化合物／塩素）は３以上であり、反応温度は２５〜１４０℃であり、反応圧力は０．０２〜１．０ＭＰａである。反応器としては、たとえば槽型反応器を用いることができる。反応には触媒としてＦｅＣｌ2を用いることができる。 There is no restriction | limiting in particular about the method of making an aromatic compound and chlorine react, A well-known method can be used. An example of a specific method is as follows. The molar ratio of aromatic compound to chlorine (aromatic compound / chlorine) is 3 or more, the reaction temperature is 25 to 140 ° C., and the reaction pressure is 0.02 to 1.0 MPa. As the reactor, for example, a tank reactor can be used. For the reaction, FeCl 2 can be used as a catalyst.
塩素化工程では副反応物として塩化水素が発生する。該塩化水素のガスを回収するには、たとえば反応器内に液相部と気相部を設け、塩素を液相に吹き込んで芳香族化合物と反応させ塩素化芳香族化合物を得、副生する塩化水素ガスを気相から抜き出せばよい。抜き出した塩化水素ガスは直接塩化水素精製工程に供給することもできるが、塩素化反応温度が常温より高い場合、塩素化精製工程までの間に熱交換器を設けて冷却することによりガス中の芳香族化合物の一部を凝縮、分離して含有量を低減させた後、塩化水素精製工程に供給することもできる。 In the chlorination process, hydrogen chloride is generated as a by-product. In order to recover the hydrogen chloride gas, for example, a liquid phase part and a gas phase part are provided in the reactor, and chlorine is blown into the liquid phase to react with the aromatic compound to obtain a chlorinated aromatic compound, which is by-produced. Hydrogen chloride gas may be extracted from the gas phase. The extracted hydrogen chloride gas can be directly supplied to the hydrogen chloride refining process. However, if the chlorination reaction temperature is higher than room temperature, a heat exchanger is provided and cooled until the chlorination refining process. A part of the aromatic compound may be condensed and separated to reduce the content, and then supplied to the hydrogen chloride purification step.
塩素化工程から回収される塩化水素のガス中には、未反応の芳香族化合物が含まれる。 The hydrogen chloride gas recovered from the chlorination step contains unreacted aromatic compounds.
本発明においては、上記の芳香族化合物を含有する塩化水素ガスを塩素化芳香族化合物に溶解させて塩化水素、芳香族化合物及び塩素化芳香族化合物を含む溶液とする。 In the present invention, the hydrogen chloride gas containing the aromatic compound is dissolved in the chlorinated aromatic compound to obtain a solution containing hydrogen chloride, the aromatic compound, and the chlorinated aromatic compound.
溶液を得る方法としては、充填塔あるいは棚段塔の下部より芳香族化合物を含む塩化水素ガスを供給し、上部より塩素化芳香族化合物を主として含む溶液を供給し向流接触させる塔方式、芳香族化合物を含む塩化水素ガスを管塔の上部から塩素化芳香族を主とする液と共に流下させて並流接触させ、下部で気液分離する濡れ壁方式などを例示することができる。 As a method for obtaining a solution, a tower system in which hydrogen chloride gas containing an aromatic compound is supplied from the lower part of a packed tower or a plate tower and a solution mainly containing a chlorinated aromatic compound is supplied from the upper part to make countercurrent contact, Examples include a wet wall system in which a hydrogen chloride gas containing an aromatic compound is caused to flow together with a liquid mainly composed of chlorinated aromatics from the upper part of the tube tower and contacted in parallel flow, and gas-liquid separation is performed at the lower part.
塩素化芳香族化合物としては、クロルベンゼン、ジクロルベンゼン等を挙げることができる。 Examples of the chlorinated aromatic compound include chlorobenzene and dichlorobenzene.
本発明においては、上記の溶液を塩化水素回収工程に付すことにより塩化水素を主とするガスと芳香族化合物及び塩素化芳香族化合物を主とする留分を得る。 In the present invention, the above solution is subjected to a hydrogen chloride recovery step to obtain a gas mainly composed of hydrogen chloride, a fraction mainly composed of an aromatic compound and a chlorinated aromatic compound.
塩化水素回収工程を実施する方法としては、たとえば塩化水素精製工程で得た溶液を、底部にリボイラーを備える蒸留塔に供給し、リボイラーで塔底液を加熱して溶解する塩化水素を放散させればよい。塔底から得られる芳香族化合物及び塩素化芳香族化合物を主とする留分中の塩化水素のモル濃度は０．５％以下が好ましく、更に好ましくは１〜１０００ｐｐｍである。該濃度が高すぎると、次の芳香族化合物回収工程で回収される芳香族化合物に混入した塩化水素による塔頂での凝縮温度低下などの問題を引き起こすことがある。一方１ｐｐｍ以下にするのは大きな設備やエネルギーが必要になり経済的でない。蒸留塔の操作圧力は減圧、常圧、加圧いずれでもよいが、該圧力を塩化水素精製工程の圧力より高く保ち、塩素化精製工程で得た液をポンプを用いて塩化水素回収工程に送入することで、蒸留塔の塔頂から得た塩化水素ガスを圧縮することなく塩化水素精製工程に供給し、精製することができる。この際、塔頂から得たガスを一旦熱交換器で冷却し、ガス中に含まれる芳香族化合物及び塩素化芳香族化合物の一部を凝縮させて塔に還流させることもできる。 As a method for carrying out the hydrogen chloride recovery step, for example, the solution obtained in the hydrogen chloride purification step is supplied to a distillation tower equipped with a reboiler at the bottom, and the bottom liquid is heated by the reboiler to dissolve dissolved hydrogen chloride. That's fine. The molar concentration of hydrogen chloride in the fraction mainly composed of aromatic compounds and chlorinated aromatic compounds obtained from the bottom of the column is preferably 0.5% or less, more preferably 1-1000 ppm. If the concentration is too high, problems such as a reduction in the condensation temperature at the top of the column due to hydrogen chloride mixed in the aromatic compound recovered in the subsequent aromatic compound recovery step may occur. On the other hand, to make it 1 ppm or less is not economical because large equipment and energy are required. The operation pressure of the distillation column may be any of reduced pressure, normal pressure, and pressurized pressure, but the pressure is kept higher than the pressure in the hydrogen chloride purification process, and the liquid obtained in the chlorination purification process is sent to the hydrogen chloride recovery process using a pump. By entering, the hydrogen chloride gas obtained from the top of the distillation column can be supplied to the hydrogen chloride purification step without being compressed and purified. At this time, the gas obtained from the top of the tower can be once cooled by a heat exchanger, and a part of the aromatic compound and chlorinated aromatic compound contained in the gas can be condensed and refluxed to the tower.
本発明においては、上記の塩化水素回収工程で得られた芳香族化合物及び塩素化芳香族化合物を主とする留分を下記の芳香族化合物回収工程へ供給する。
芳香族化合物回収工程：芳香族化合物及び塩素化芳香族を主とする留分から、芳香族化合物を主とする留分を分離、回収する工程
In the present invention, a fraction mainly comprising the aromatic compound and the chlorinated aromatic compound obtained in the hydrogen chloride recovery step is supplied to the following aromatic compound recovery step.
Aromatic compound recovery step: A step of separating and recovering a fraction mainly composed of aromatic compounds from a fraction mainly composed of aromatic compounds and chlorinated aromatics.
芳香族化合物回収工程を実施する具体例をあげると次のとおりである。 Specific examples for carrying out the aromatic compound recovery step are as follows.
頂部にコンデンサー、底部にリボイラーを備える蒸留塔の中段部に塩化水素回収工程で得られた芳香族化合物及び塩素化芳香族化合物を主とする留分を供給する。リボイラーでの加熱により塔頂から得られる蒸気をコンデンサーで液化し、その一部を蒸留塔の頂部に還流させることにより、塔頂から芳香族化合物に富む留分が得られる。蒸留塔には塩化水素回収工程で得られた芳香族化合物および塩素化芳香族化合物を主とする留分のみを供給してもよいが、たとえば塩素化工程から得られる、未反応の芳香族化合物と反応で生成した塩素化芳香族からなる液を併せて供給し、芳香族化合物を回収することもできる。本発明においては、芳香族化合物回収工程で得られた芳香族化合物を主とする留分を塩素化工程へ供給することができる。このことにより芳香族化合物を有用にリサイクル利用できる。 A fraction mainly composed of the aromatic compound and the chlorinated aromatic compound obtained in the hydrogen chloride recovery step is supplied to the middle part of the distillation column having a condenser at the top and a reboiler at the bottom. The vapor obtained from the top of the column by heating in the reboiler is liquefied in a condenser, and a part thereof is refluxed to the top of the distillation column, whereby a fraction rich in aromatic compounds is obtained from the top. The distillation column may be supplied only with a fraction mainly composed of the aromatic compound and chlorinated aromatic compound obtained in the hydrogen chloride recovery step. For example, an unreacted aromatic compound obtained from the chlorination step And a liquid composed of chlorinated aromatics produced by the reaction can be supplied together to recover the aromatic compound. In the present invention, a fraction mainly composed of the aromatic compound obtained in the aromatic compound recovery step can be supplied to the chlorination step. As a result, the aromatic compound can be effectively recycled.
本発明においては、塩化水素精製工程で得られた塩化水素を主とするガスを下記の酸化工程へ供給することができる。このことにより、塩化水素を塩素に変換し、該塩素を有効利用することができる。
酸化工程：塩化水素を酸素と反応させ、塩素を得る工程
In the present invention, a gas mainly composed of hydrogen chloride obtained in the hydrogen chloride purification step can be supplied to the following oxidation step. As a result, hydrogen chloride can be converted to chlorine, and the chlorine can be used effectively.
Oxidation process: Process of reacting hydrogen chloride with oxygen to obtain chlorine
酸化工程は、塩素化工程で得た塩化水素を酸素と反応させ、塩素を得る工程である。塩化水素と酸素を反応させる方法については、特に制限はなく、公知の方法を使用することができる。具体的な方法の例を示すと、次のとおりである。塩化水素と酸素のモル比（塩化水素／酸素）は０．５〜２であり、反応温度は２００〜５００℃、好ましくは２００〜３８０℃であり、反応圧力は０．１〜５ＭＰａであり、空塔速度は０．７〜１０ｍ／ｓである。反応器としては、固定床反応器、流動床反応器、移動床反応器を用いることができる。反応には触媒として酸化クロム触媒、酸化ルテニウム触媒を用いることができる。 The oxidation step is a step of obtaining chlorine by reacting hydrogen chloride obtained in the chlorination step with oxygen. There is no restriction | limiting in particular about the method of making hydrogen chloride and oxygen react, A well-known method can be used. An example of a specific method is as follows. The molar ratio of hydrogen chloride to oxygen (hydrogen chloride / oxygen) is 0.5 to 2, the reaction temperature is 200 to 500 ° C., preferably 200 to 380 ° C., the reaction pressure is 0.1 to 5 MPa, The superficial velocity is 0.7-10 m / s. As the reactor, a fixed bed reactor, a fluidized bed reactor, or a moving bed reactor can be used. In the reaction, a chromium oxide catalyst or a ruthenium oxide catalyst can be used as a catalyst.
酸化工程で得られた塩素の少なくとも一部は塩素化工程へリサイクルされ、塩素化工程の原料として有効利用される。 At least a portion of the chlorine obtained in the oxidation process is recycled to the chlorination process and is effectively used as a raw material for the chlorination process.
上記の態様を採用することにより、芳香族炭化水素（たとえば、ベンゼン）と塩素とから最終目的物としての塩素化芳香族炭化水素（たとえば、クロルベンゼン）を効率的に製造することができる。 By adopting the above embodiment, a chlorinated aromatic hydrocarbon (for example, chlorobenzene) as an end product can be efficiently produced from an aromatic hydrocarbon (for example, benzene) and chlorine.
次に本発明を実施例により説明する。
実施例１
本発明はたとえば図１のフローと表１の物質収支により最適に実施することができる。
ベンゼンと塩素を反応させてクロルベンゼンと塩化水素を得た。ここで反応温度は１１７℃、反応圧力は０．６ＭＰａとし、外部から供給されるベンゼン／塩素のモル比は８／１とした。反応で発生したベンゼンと塩化水素を含むガスは３０℃まで冷却して凝縮したベンゼンは戻し、ベンゼンと塩化水素を０．０３／１で含む混合ガス（流体番号−６）を取り出した。［塩素化工程］
上記の混合ガスとクロルベンゼンを圧力０．５５ＭＰａ、温度が−３５℃の下で接触させ、ベンゼン、クロルベンゼンの濃度が低減された塩化水素ガス（流体番号―９）と、塩化水素水素、ベンゼン、クロルベンゼンからなる溶液（流体番号−８）を得た。［塩化水素精製工程］
塩化水素精製工程で得られた溶液を、塩素化反応で得られた塩化水素、ベンゼン、クロルベンゼンを含む液と共に圧力０．６ＭＰａ下で加熱して液中に溶解している塩化水素を放散させ、塔頂からベンゼンと塩化水素を０．０２／１で含む混合ガス（流体番号―１４）を、塔底から塩化水素のモル濃度が低減されたベンゼンおよびクロルベンゼンの混合液（流体番号−１３）を得た。［塩化水素回収工程］
塩化水素回収工程で得られた混合ガスは塩化水素精製工程に戻し、再精製した。塩化水素回収工程から得られたベンゼンおよびクロルベンゼンの混合液は通常の蒸留によりベンゼン（流体番号−１６）とクロルベンゼン（流体番号―１５）に分離した。［芳香族化合物回収工程］
芳香族化合物回収工程で分離、回収されたベンゼンは塩素化工程の原料としてリサイクルした。また、塩化水素精製工程で得られた塩化水素ガスは酸素と反応させ、塩素と水に変換した。［酸化工程］
得られた塩素（流体番号−１２）は塩素化工程の原料としてリサイクルした。
Next, the present invention will be described with reference to examples.
Example 1
The present invention can be optimally implemented, for example, by the flow shown in FIG. 1 and the material balance shown in Table 1.
Benzene and chlorine were reacted to obtain chlorobenzene and hydrogen chloride. Here, the reaction temperature was 117 ° C., the reaction pressure was 0.6 MPa, and the molar ratio of benzene / chlorine supplied from the outside was 8/1. The gas containing benzene and hydrogen chloride generated by the reaction was cooled to 30 ° C. and condensed benzene was returned, and a mixed gas containing 0.03 / 1 of benzene and hydrogen chloride (fluid number -6) was taken out. [Chlorination process]
The above mixed gas and chlorobenzene are contacted at a pressure of 0.55 MPa and at a temperature of −35 ° C. to reduce the concentration of benzene and chlorobenzene, hydrogen chloride gas (fluid number -9), hydrogen chloride hydrogen, benzene A solution (fluid number -8) consisting of chlorobenzene was obtained. [Hydrogen chloride purification process]
The solution obtained in the hydrogen chloride purification step is heated with a liquid containing hydrogen chloride, benzene and chlorobenzene obtained in the chlorination reaction under a pressure of 0.6 MPa to dissipate the hydrogen chloride dissolved in the liquid. From the top of the column, a mixed gas (fluid number -14) containing benzene and hydrogen chloride at 0.02 / 1, and from the bottom of the column, a mixed liquid of benzene and chlorobenzene (fluid number -13 with reduced hydrogen chloride molarity) ) [Hydrogen chloride recovery process]
The mixed gas obtained in the hydrogen chloride recovery step was returned to the hydrogen chloride purification step and re-purified. The mixed solution of benzene and chlorobenzene obtained from the hydrogen chloride recovery step was separated into benzene (fluid number -16) and chlorobenzene (fluid number -15) by ordinary distillation. [Aromatic compound recovery process]
The benzene separated and recovered in the aromatic compound recovery process was recycled as a raw material for the chlorination process. Moreover, the hydrogen chloride gas obtained in the hydrogen chloride purification process was reacted with oxygen and converted into chlorine and water. [Oxidation process]
The obtained chlorine (fluid number -12) was recycled as a raw material for the chlorination step.
Ａ：塩素化工程
Ｂ：塩化水素精製工程
Ｃ、Ｆ：ポンプ
Ｄ：塩化水素回収工程
Ｅ：芳香族化合物回収工程
Ｇ：酸化工程
A: Chlorination process B: Hydrogen chloride refining process C, F: Pump D: Hydrogen chloride recovery process E: Aromatic compound recovery process G: Oxidation process
Claims (5)
塩素化工程：芳香族化合物と塩素を反応させ、塩素化芳香族化合物と塩化水素を得る工程
塩化水素精製工程：芳香族化合物を含有する塩化水素ガスを塩素化芳香族化合物に溶解させて、塩化水素を主とするガスと、塩化水素、芳香族化合物及び塩素化芳香族化合物を含む溶液を得る工程
塩化水素回収工程：塩化水素、芳香族化合物、塩素化芳香族化合物を含む溶液から塩化水素を主とするガスを分離、回収する工程
芳香族化合物回収工程：芳香族化合物及び塩素化芳香族化合物を主とする留分から、芳香族化合物を主とする留分を分離、回収する工程 A method for separating and recovering an aromatic compound and hydrogen chloride from a hydrogen chloride gas containing an aromatic compound obtained in the following chlorination step, wherein the hydrogen chloride gas containing an aromatic compound is A solution containing hydrogen chloride, an aromatic compound and a chlorinated aromatic compound is dissolved in a chlorinated aromatic compound by subjecting it to a purification step, and hydrogen chloride is mainly produced by subjecting the solution to the following hydrogen chloride recovery step. A gas, a fraction mainly composed of an aromatic compound and a chlorinated aromatic compound, and hydrogen chloride which supplies the fraction mainly composed of the aromatic compound and the chlorinated aromatic compound to the following aromatic compound recovery step; A method for separating and recovering aromatic compounds.
Chlorination process: A process in which aromatic compound and chlorine are reacted to obtain chlorinated aromatic compound and hydrogen chloride. Hydrogen chloride purification process: Hydrogen chloride gas containing aromatic compound is dissolved in chlorinated aromatic compound and chlorinated. Step for obtaining a solution containing hydrogen gas, hydrogen chloride, aromatic compound and chlorinated aromatic compound Hydrogen chloride recovery step: Hydrogen chloride from a solution containing hydrogen chloride, aromatic compound and chlorinated aromatic compound Process of separating and recovering main gas Aromatic compound recovery process: A process of separating and recovering a fraction mainly composed of aromatic compounds from a fraction mainly composed of aromatic compounds and chlorinated aromatic compounds
酸化工程：塩化水素を酸素と反応させ、塩素を得る工程 The method according to claim 1, wherein a gas mainly comprising hydrogen chloride obtained in the hydrogen chloride purification step is supplied to the following oxidation step.
Oxidation process: Process of reacting hydrogen chloride with oxygen to obtain chlorine
The process according to claim 1, wherein the aromatic compound is benzene and the chlorinated aromatic compound is chlorobenzene.
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| ATE485284T1 (en) | 2003-11-20 | 2010-11-15 | Solvay | METHOD FOR PRODUCING ORGANIC COMPOUNDS FROM GLYCEROL, FROM RENEWABLE RAW MATERIALS |
| KR20080037615A (en) | 2005-05-20 | 2008-04-30 | 솔베이(소시에떼아노님) | Method for making a chlorohydrin |
| JP2008545643A (en) | 2005-05-20 | 2008-12-18 | ソルヴェイ（ソシエテ アノニム） | Process for the preparation of chlorohydrin by reaction of polyhydroxylated aliphatic hydrocarbons with chlorinating agents. |
| WO2007054505A2 (en) | 2005-11-08 | 2007-05-18 | Solvay (Société Anonyme) | Process for the manufacture of dichloropropanol by chlorination of glycerol |
| CA2654717A1 (en) | 2006-06-14 | 2007-12-21 | Solvay (Societe Anonyme) | Crude glycerol-based product, process for its purification and its use in the manufacture of dichloropropanol |
| FR2913421B1 (en) | 2007-03-07 | 2009-05-15 | Solvay | PROCESS FOR PRODUCING DICHLOROPROPANOL |
| FR2913684B1 (en) | 2007-03-14 | 2012-09-14 | Solvay | PROCESS FOR PRODUCING DICHLOROPROPANOL |
| TWI500609B (en) | 2007-06-12 | 2015-09-21 | Solvay | Product containing epichlorohydrin, its preparation and its use in various applications |
| JP2011502032A (en) | 2007-10-02 | 2011-01-20 | ソルヴェイ（ソシエテ アノニム） | Use of silicon-containing compositions to improve the corrosion resistance of containers |
| FR2925045B1 (en) | 2007-12-17 | 2012-02-24 | Solvay | GLYCEROL-BASED PRODUCT, PROCESS FOR OBTAINING THE SAME AND USE THEREOF IN THE MANUFACTURE OF DICHLOROPROPANOL |
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