JP4998716B2 - Manufacturing method of wear-resistant steel plate - Google Patents

Description

  The present invention relates to a method for manufacturing a wear-resistant steel plate used for industrial machines, transportation equipment, and the like.

  2. Description of the Related Art In recent years, steel plates for industrial machinery have been required to have higher strength and better wear resistance than ever, due to the reduction in weight of transportation equipment such as trucks, civil engineering, and mining machinery. In particular, industrial machinery, parts, and transportation equipment used in the fields of construction, civil engineering, mining, etc. (for example, power shovels, bulldozers, hoppers, buckets, etc.) A steel plate having excellent wear properties is used.

As such a wear-resistant steel plate, for example, a wear-resistant steel plate having excellent low-temperature toughness and low-temperature weld cracking properties is known, as described in Patent Document 1, for example, while ensuring strength and wear resistance. .
JP 2002-256382 A

  Abrasion-resistant steel plates are required to have high hardness by quenching because of their use, but shape correction after quenching is difficult because of the high hardness. Therefore, after quenching, a poorly shaped steel sheet cannot be made into a product, leading to a decrease in yield. On the other hand, even if shape correction is performed after quenching, the toughness deteriorates, which may cause a problem that the application is limited. In particular, in a thin steel plate having a thickness of 12 mm or less, it has been difficult to secure a flat shape and increase the yield.

  Even in the wear-resistant steel sheet described in Patent Document 1, the shape of the steel sheet having a small thickness is not always satisfactory.

  Accordingly, an object of the present invention is to solve such a problem of the prior art, particularly a thin wear-resistant steel plate having a plate thickness of 12 mm or less, which has been difficult to ensure a flat shape conventionally. However, an object of the present invention is to provide a method for producing a wear-resistant steel sheet that can easily ensure a good shape.

  As a result of intensive studies to achieve the above object, the present inventors ensure that the shape before quenching of the wear-resistant steel is secured and the residual stress is removed. The following findings (a) to (d) were obtained.

  (A) The shape after quenching depends on the shape before quenching. A thin material with a plate thickness of 12 mm or less, particularly a plate thickness of 8 mm or less, is less likely to have flatness during hot rolling. Furthermore, even when heated to the Ar3 point or higher during heating before quenching, it is less likely to become flat due to its own weight. It is important to flatten the shape of the original plate before quenching.

  (B) The cooling rate after hot rolling affects the shape before quenching. Since the steel plate manufactured by the thick plate mill is air-cooled as it is, it is likely to warp after hot rolling due to the difference in cooling rate between the edge portion and the center portion. This is particularly noticeable with thin materials having a large difference in cooling rate. In order to prevent this, after hot rolling, it is wound into a coil shape to form a hot rolled coil. The coil is cooled more slowly than the steel plate, and the difference in cooling rate depending on the position is small. In the case of a coil, the outermost periphery and the innermost periphery are usually discarded as defective parts when being cut into a steel plate, so that a position where cooling is fast is not a product. In order to lower the coil winding temperature, it is necessary to increase the amount of water injected at the run-out table, and the steel strip tends to be distorted. Further, when the coil winding temperature is lowered, a ferrite + bainite or martensite structure is formed, but the steel strip is easily deformed by transformation strain. Furthermore, the coiling temperature must be 600 ° C. or higher in order to coarsen the AlN so as not to hinder the crystal grain growth during quenching heating. When manufacturing a hot-rolled coil, it is preferable to use an edge heater to heat the edge of the steel strip before finish rolling because the temperature difference between the edge and the center is reduced.

  (C) As a reason why flatness does not appear, there is also an influence of strain during quenching. During quenching, warpage is likely to occur due to a cooling difference depending on the position of the steel sheet. If the austenite grain size at the time of quenching varies depending on the position of the steel sheet, warping increases because the martensitic transformation time at the time of quenching varies depending on the position of the steel sheet. In particular, since the thin material has a low mass with a low mass entering the heating furnace at the time of quenching, there is a circumstance that sufficient heating time cannot be taken. For this reason, warpage after quenching is likely to occur due to the difference in temperature history depending on the position. Further, since the thin material is rapidly heated at the time of quenching, it is difficult to achieve a uniform quenching temperature on the entire steel sheet, and warpage is likely to occur. When strain is applied to the steel sheet before quenching and heating, the austenite transformation is promoted during heating, and the entire steel sheet is easily quenched even when heated for a short time. As a method of introducing the strain before quenching, the tension leveler has a small effect because the strain is less introduced, and skin pass rolling is preferable.

  (D) Since winding is performed at a temperature of 600 ° C. or higher, a thick scale is formed on the surface of the steel strip after winding. When annealing is performed for improving the structure before quenching in this state, the surface hardness is difficult to develop due to scale decarburization. Therefore, it is preferable not to perform heat treatment such as spheroidizing annealing before quenching.

The present invention has been completed based on these findings, and the features thereof are as follows.
(1) By mass% in steel, C: 0.1 to 0.4%, Si: 0.01 to 1.0%, Mn: 0.6 to 2.0%, P ≦ 0.04%, S ≦ 0.04%, Sol. Al: 0.005 to 0.1% only contains a steel the balance being Fe and unavoidable impurities, after Tsu taken up into a coil at 600 ° C. or higher temperatures after hot rolling, the strain in the skin pass rolling After the addition, a method for producing a wear-resistant steel sheet, which is cut into a steel sheet, heated to a temperature of Ar3 or higher, and quenched.
(2) Furthermore, steel is mass%, Cu: 0.03-2.0%, Ni: 0.03-2.0%, Cr: 0.03-2.0%, Mo: 0.03- 2.0%, Nb: 0.005 to 0.1%, V: 0.010 to 0.5%, Ti: 0.005 to 0.05%, B: 0.0005 to 0.003% The method for producing a wear-resistant steel sheet according to (1), comprising one or more selected from the group consisting of:

  ADVANTAGE OF THE INVENTION According to this invention, even if it is a thin abrasion-resistant steel plate, a favorable shape can be ensured easily and the abrasion-resistant steel plate excellent in the shape can be provided.

  Hereinafter, regarding a wear-resistant steel sheet that can ensure a good shape even if it is a thin wear-resistant steel sheet with a thickness of 12 mm or less, particularly 8 mm or less, the reason for limiting the chemical components and the manufacturing conditions are specifically described. explain.

  First, chemical components of the wear-resistant steel plate used in the present invention will be described. In the following description of chemical components, all units shown in% are mass%.

C: 0.1-0.4%
C is an important element for increasing the hardness of steel and improving wear resistance. If the C content is less than 0.1%, sufficient hardness cannot be obtained. On the other hand, if it exceeds 0.4%, when a hot-rolled coil is manufactured, coil collapse tends to occur. Although it is necessary to perform high temperature winding so that baking does not occur at the stage of the hot rolled coil, the high temperature strength decreases when the winding temperature is high. Preferably, C: 0.2 to 0.3%.

Si: 0.01 to 1.0%
Si is added from the viewpoint of hardenability. The effect is not sufficiently obtained if it is less than 0.01%. On the other hand, if the amount of Si is too large, a red scale is generated, and the red scale portion is rapidly cooled on a hot-run runout table to form a fine structure. This variation in structure affects the shape at the time of quenching, so the Si content is 1.0% or less. Preferably, it is 0.01 to 0.5%.

Mn: 0.6-2.0%
Mn is added from the viewpoint of hardenability. If the content is less than 0.6%, the effect cannot be obtained, and if the content exceeds 2.0%, the shape deteriorates due to structural variation due to Mn segregation. A preferable Mn content is 0.6 to 1.5%.

P ≦ 0.04%
If the P content exceeds 0.04%, the toughness deteriorates. Therefore, 0.04% or less. Desirably, it is 0.02% or less.

S ≦ 0.04%
S combines with Mn and degrades toughness. For this reason, the smaller the content, the better. For the above reasons, S is preferably 0.005% or less.

Sol.Al: 0.005-0.1%
Sol.Al is added to fix N contained inevitably. Solid solution N or fine AlN inhibits crystal grain growth, and austenite grains become fine during quenching heating (during reheating), thereby inhibiting quenchability. For that effect, that is, to prevent hardenability inhibition by these solid solution N or fine AlN, the amount of Sol.Al is made 0.005% or more. If the amount of Al is too large, the oxide in the steel increases and the inhibition of crystal grain growth by the oxide becomes obvious, so the amount of Sol.Al is made 0.1% or less. A preferred range is 0.02 to 0.07%.

  The steel used for this invention needs to be limited to the said component composition range.

  Moreover, in order to improve hardenability, it is preferable to contain the 1 type (s) or 2 or more types chosen from the elements of Cu, Ni, Cr, Mo, Nb, V, Ti, and B in the following ranges. In addition, the content level of each element as an impurity is Cu <0.03%, Ni <0.03%, Cr <0.03%, Mo <0.03%, Nb <0.005%, V <0.010%, Ti <0.005%, B < 0.0005%.

Cu: 0.03-2.0%
If Cu is less than 0.03%, the hardenability effect is not sufficient, while if it exceeds 2.0%, hot workability deteriorates. Preferably, it is 0.03 to 0.2%.

Ni: 0.03-2.0%
If Ni is less than 0.03%, the hardenability effect is not sufficient. On the other hand, even if added over 2.0%, the effect is saturated and the cost is increased. Preferably, it is 0.03 to 0.5%.

Cr: 0.03-2.0%
If the Cr content is less than 0.03%, the hardenability effect is not sufficient. On the other hand, if the Cr content exceeds 2.0%, the amount of carbide increases, and conversely the hardenability decreases. Preferably, it is 0.03 to 0.5%.

Mo: 0.03-2.0%
If the Mo content is less than 0.03%, the hardenability effect is not sufficient. On the other hand, if the Mo content exceeds 2.0%, the hot-rolled coil is baked, which not only makes coil cutting difficult, but also deteriorates the shape. To do. Preferably, it is 0.03 to 0.5%.

Nb: 0.005-0.1%
If Nb is less than 0.005%, the hardenability effect is not sufficient. On the other hand, even if added over 0.1%, the effect is saturated, resulting in high costs. Preferably, it is 0.01 to 0.05%.

V: 0.010 to 0.5%
If V is less than 0.010%, the hardenability effect is not sufficient. On the other hand, even if added over 0.5%, the effect is saturated, resulting in high costs. Preferably, it is 0.03 to 0.5%.

Ti: 0.005-0.05%
If Ti is less than 0.005%, the hardenability effect is not sufficient. On the other hand, even if added over 0.05%, the effect is saturated and the cost is increased. Preferably, it is 0.03 to 0.05%.

B: 0.0005-0.003%
If B is less than 0.0005%, the hardenability effect is not sufficient. On the other hand, if it exceeds 0.003%, it will be burned at the stage of hot-rolled coil, and not only will coil cutting become difficult, but the shape will also deteriorate. To do. Preferably, it is 0.0005 to 0.002%.

  In the steel used in the present invention, the balance other than the above-described component composition is preferably Fe and inevitable impurities.

  Next, the manufacturing method of the wear-resistant steel plate of this invention is demonstrated.

  Regarding the heating conditions before hot rolling, it is necessary to heat to a temperature at which hot rolling is possible, and 1150 ° C. or higher is preferable. On the other hand, if the heating temperature is too high, surface flaws are likely to occur. Regarding the heating before hot rolling, the heating may be performed without cooling the slab.

  Next, hot rolling is performed. The hot rolling is preferably performed in a hot rolling mill having a roughing mill and a finishing mill used for manufacturing a thin plate material.

  It is preferable to make the structure uniform in the width direction by performing the finishing temperature (finishing finishing temperature) at Ar3 or higher. Further, the wear-resistant steel plate according to the method of the present invention is easily baked, and the amount of cooling water at the run-out table needs to be controlled to be small in order to prevent tempering during hot rolling. For this purpose, the finishing temperature is preferably Ar3 or higher and 900 ° C or lower.

  It is effective to perform accelerated rolling in order to ensure the finishing temperature. Here, accelerated rolling is a technique for increasing the rolling speed during finish rolling to equalize the temperature for the purpose of preventing a drop in the finish temperature at the tail end of the steel strip. Not only that, the rough bar (the semi-finished product before the hot rough rolling is finished and before the finish rolling) is heated by a method such as electromagnetic induction heating before the finish rolling, or the coarse bar is wound once around the coil and roughed. Since it is easier to maintain the finishing temperature by using a method in which the temperature distribution in the width direction or the length direction of the bar is made uniform and then finish rolling is performed at a constant speed or acceleration, these methods are preferable. Further, from the viewpoint of the hot rolled coil shape before quenching, it is preferable to use an edge heater for the purpose of uniformizing the material of the edge portion in the plate width direction before hot finish rolling. When using an edge heater, it is preferable that the difference in the finish rolling temperature between the edge part (position from the center of the steel sheet in the width direction and 20 mm from the edge of the steel sheet) and the center part (center part in the width direction of the steel sheet) is 20 ° C. or less.

  In hot-rolled coil manufacturing, in order to lower the coil winding temperature, it is necessary to increase the amount of water injected at the run-out table installed between the finish rolling mill exit side and the winding machine. Easily distorted. Further, when the coiling temperature is lowered, the steel structure becomes a ferrite + bainite or martensite structure, but the steel strip is easily deformed by transformation strain. Furthermore, the coiling temperature is set to 600 ° C. or higher so that AlN is coarsened and does not hinder crystal grain growth during quenching heating. On the other hand, if the coiling temperature is too high, coil crushing is likely to occur due to a decrease in high-temperature strength. From the viewpoint of AlN coarse precipitation, 650 to 750 ° C. is preferable.

  The shape after the heat treatment depends on the shape before the heat treatment. Therefore, it is preferable to perform shape correction by skin pass rolling (also referred to as temper rolling) or a leveler at the hot rolling coil stage. In the case of a leveler, the elongation rate is preferably about 0.1% to 0.4%, which is the range that is usually performed. Further, skin pass rolling is preferable because the elongation rate can be higher than that of the leveler. In skin pass rolling, considering the shape after quenching, the elongation is preferably 0.7% or more. In addition, if the elongation rate becomes too large, the crystal grains are locally enlarged due to strained grain growth during quenching heating, and quenching tends to be non-uniform, so the elongation rate is preferably 2.0% or less. However, it is effective to perform shape correction with a leveler after skin pass rolling (including before and after coil cutting).

  The hot-rolled coil is coil-cut into a steel plate having a predetermined length for heat treatment.

  The coil-cut steel sheet is quenched after being reheated to the Ar3 point or higher. For thin materials, the reheating temperature is usually 1000 ° C. or less because of the efficiency of the heating furnace. If necessary, cooling can be stopped at a temperature below the Ar3 point during quenching.

  In the manufacturing method of the present invention, the surface of the steel sheet is oxidized by quenching after coil cutting, and pickling is required after the quenching. Therefore, pickling is not performed at the stage of hot rolling coils. On the other hand, since the scale is hardened, if the scale is too thick, the steel plate surface is decarburized due to scale decarburization, and a predetermined hardness is hardly obtained. Therefore, heat treatment that causes scale growth should be avoided as much as possible after hot rolling, and heat treatment is not performed prior to the reheating for quenching described above.

  Steels having the chemical components shown in Table 1 (steel types A to I) were melted to produce wear-resistant steel plates under the production conditions shown below.

  A slab produced by continuous casting is heated to 1250 ° C and hot rolled using a hot rolling mill with or without an edge heater, and a finishing temperature of 860 ° C or higher at an Ar3 point or higher. A hot rolled coil with a plate width of 1829 mm was produced by winding it into a coil with a plate thickness of 6.0 mm and a winding temperature of 700 ° C. All the structures after winding were ferrite-pearlite structures. After that, it was subjected to skin pass rolling at an elongation rate of 1.0% or a tension leveler at an elongation rate of 0.3%, and then cut to a length of 12220 mm. For comparison, a steel plate of the same size was produced in a thick plate mill at the same finishing temperature without being wound into a coil. The steel plate by the thick plate mill was air-cooled to room temperature after finishing.

  These steel sheets were reheated to 900 ° C., which is a temperature higher than the Ar 3 point of each steel sheet, and the shape after quenching was measured. The shape was evaluated by pressing a straight ruler against an adjacent convex portion on a steel plate after quenching and after quenching, and measuring a gap generated between the ruler and the steel plate. The gap was measured three times for each of the rolling direction and the direction perpendicular to the rolling, and the average value was used as the shape. The results are shown in Table 2. In addition, all the steel plates using the production method of the present invention had a surface Brinell hardness HBS (10/3000) of 320 or more, and had sufficient surface hardness as wear-resistant steel.

  In addition, No. of steel grade A FIG. 1 shows a comparison of the shapes after winding of the wear-resistant steel sheets in the case of Nos. 1 to 5 with and without coil winding and when using an edge heater and skin pass rolling. According to FIG. 1, it can be seen that the shape of the steel sheet is flattened by using the manufacturing method of the present invention that is wound in a coil shape.

The graph which shows the relationship of the shape after hardening by the presence or absence of coil winding. The shape when using edge heater and skin pass rolling is also shown.

Claims (2)

In steel, by mass%, C: 0.1 to 0.4%, Si: 0.01 to 1.0%, Mn: 0.6 to 2.0%, P ≦ 0.04%, S ≦ 0 .04%, Sol. Al: 0.005 to 0.1% only contains a steel the balance being Fe and unavoidable impurities, after Tsu taken up into a coil at 600 ° C. or higher temperatures after hot rolling, the strain in the skin pass rolling After the addition, a method for producing a wear-resistant steel sheet, which is cut into a steel sheet, heated to a temperature of Ar3 or higher, and quenched.   Furthermore, steel is mass%, Cu: 0.03-2.0%, Ni: 0.03-2.0%, Cr: 0.03-2.0%, Mo: 0.03-2.0 %, Nb: 0.005-0.1%, V: 0.010-0.5%, Ti: 0.005-0.05%, B: 0.0005-0.003% It contains 1 type (s) or 2 or more types, The manufacturing method of the abrasion-resistant steel plate of Claim 1 characterized by the above-mentioned.

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