JP4984202B2 - Secondary battery and portable device equipped with the same - Google Patents
Secondary battery and portable device equipped with the same Download PDFInfo
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- JP4984202B2 JP4984202B2 JP2001146942A JP2001146942A JP4984202B2 JP 4984202 B2 JP4984202 B2 JP 4984202B2 JP 2001146942 A JP2001146942 A JP 2001146942A JP 2001146942 A JP2001146942 A JP 2001146942A JP 4984202 B2 JP4984202 B2 JP 4984202B2
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- current collector
- negative electrode
- positive electrode
- secondary battery
- electrode body
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Sealing Battery Cases Or Jackets (AREA)
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Description
【0001】
【発明の属する技術分野】
本発明は、二次電池及びそれを搭載する携帯機器に関し、特に、積層タイプのラミネートフィルム二次電池及びそれを搭載する個人向け携帯型情報通信機器(Personal Digital Assistant:PDA)、携帯電話機、ノート型のパーソナルコンピュータなどの携帯機器に関する。
【0002】
【従来の技術】
従来、セパレータを介して交互に正極体と負極体とを積層した発電体をラミネートフィルムで覆った二次電池がある。
【0003】
(従来技術1)
図6は、従来の二次電池の分解斜視図である。図7は、従来の二次電池の断面図である。なお、図6には説明の都合上ラミネートフィルムを図示していない。
【0004】
図6等には、たとえば6枚のセパレータ3と、各セパレータ3の間に交互に位置する3枚の負極体1及び2枚の正極体2と、各負極体1及び各正極体2の一端に露出した電極集電部1a,2aと、電極集電部1a,2aと溶接などによって接続された負極リードタブ4及び正極リードタブ5とを示している。
【0005】
負極体1及び正極体2は、それぞれ金属箔に活物質が塗布されたものである。そして、これらと重ならないよう負極リードタブ4及び正極リードタブ5が接続されている。ラミネートフィルム6内には非水系電解液が注入されている。
【0006】
このような二次電池の発電体(セパレータ3、負極体1及び正極体2)部分は、ラミネートフィルム6でのみ覆われているだけであるので、衝撃や圧壊などの外力に弱かった。
【0007】
(従来技術2)
従来技術1に対し、たとえば特開昭60−65442号公報、特開昭60−117542号公報には、発電体を覆うラミネートフィルムを、紫外線硬化型樹脂で覆う二次電池が記載されている。
【0008】
【発明が解決しようとする課題】
しかし、従来技術2は、紫外線硬化型樹脂を備えるので、その分、二次電池が重くなるし、またその分、二次電池が厚くなる。これにより、二次電池が搭載される電気機器の軽量化、小型化を図るのが困難になる。そのため、PDAなどの携帯機器への搭載は不向きである。
【0009】
さらに、従来技術2は、紫外線硬化型樹脂をラミネートフィルムに塗布する工程と、塗布した紫外線硬化型樹脂を硬化させる工程とが必須となり、従来技術1に比して、製造工程が面倒になる。
【0010】
そこで、本発明は、面倒な製造工程や、製造工程の増加に伴う製造コストの増加を伴うことなく、強度がある二次電池の軽量化、小型化を図ることを課題とする。
【0011】
上述の課題を解決するために、本発明は、絶縁性を有するセパレータを介して交互に正極体と負極体とが積層された発電体をラミネートフィルムで覆った二次電池において、前記発電体の交互に積層された正極体と負極体から互いに反対方向に正極体の電極集電部と負極体の電極集電部とが引き出され、前記正極体の電極集電部が前記正極体から引き出された方向の反対側で正極リードタブに接続され、前記負極体の電極集電部が前記負極体から引き出された方向の反対側で負極リードタブに接続され、前記正極体の電極集電部と前記負極体の電極集電部とを、前記発電体の上面側と下面側から包み込むように引き回すことによって、前記正極体の電極集電部と前記負極体の電極集電部とが前記発電体を前記上面側と下面側の両側から挟み込んでいることを特徴とする。
また、本発明は、絶縁性を有するセパレータを介して交互に正極体と負極体とが積層された発電体をラミネートフィルムで覆った二次電池において、前記発電体の一端側では前記正極体の電極集電部として前記発電体から外側に露出し、前記正極体の電極集電部とは反対側の前記発電体の他端側では前記負極体の電極集電部として前記発電体の外側に露出し、前記正極体の電極集電部には正極リードタブが、前記負極体の電極集電部には負極リードタブがそれぞれ接続され、前記正極リードタブは前記正極体の電極集電部から前記負極体の電極集電部に向けて、前記負極リードタブは前記負極体の電極集電部から前記正極体の電極集電部に向けて互いに反対方向に引き出され、前記正極リードタブと負極リードタブとを、前記発電体の上面側と下面側から包み込むように引き回すことによって、前記正極リードタブと負極リードタブとが前記発電体を前記上面側と下面側の両側から挟み込んでいることを特徴とする。
【0012】
また、本発明の携帯機器は、上記二次電池を搭載することを特徴とする。
【0013】
【発明の実施の形態】
以下、本発明の実施形態について図面を参照して説明する。
【0014】
(実施形態1)
[構成の説明]
図1は、本発明の実施形態1の二次電池の斜視図である。図2は、図1の二次電池の分解断面図である。図3は、図1の二次電池の断面図である。なお、図2ではラミネートフィルム3の図示を省略している。
【0015】
図1等には、たとえば6枚のセパレータ3と、各セパレータ3の間に交互に位置する3枚の負極体1及び2枚の正極体2と、各負極体1及び各正極体2の一端に露出した電極集電部1a,2aと、電極集電部1a,2aと溶接などによって接続された負極リードタブ4及び正極リードタブ5と、電極集電部1aと正極リードタブ5との接続部及び電極集電部2aと負極リードタブ4との接続部に設けられた絶縁シート7とを示している。
【0016】
負極体1は、リチウムイオンなどを収集・放出するカーボンを含むハードカーボン系などの負極活物資を銅箔シートに塗布したものである。負極活物資の厚さは50μm程度、銅箔シートの厚さは15μm程度としている。また、負極体1の寸法は、70mm×125mmとしている。
【0017】
正極体2は、リチウムイオンなどを収集・放出するリチウムマンガン複合酸化物を含むリチウムイオン含有金属酸化物などの正極活物質をアルミニウム箔シートに塗布したものである。正極活物資の厚さは70μm程度、アルミニウム箔シートの厚さは20μm程度としている。正極体2の寸法は65mm×120mmとしている。
【0018】
セパレータ3は、多孔性で絶縁性を有する25μm程度の厚さのシート状の樹脂である。ここでは、ポリエチレンフィルムとポリプロピレンフィルムの積層型のセパレータを用いている。セパレータ3の寸法は、75mm×130mmとしている。
【0019】
負極体1、正極体2及びセパレータ3を有する発電体内部には、非水系電解液を注入した状態でラミネートフィルム6によって封止している。ここでは、非水系電解液は、プロピレンカーボネートとメチルエチルカーボネートとの非水系溶媒に六フッ化リン酸リチウムを溶解させたものを用いている。
【0020】
負極リードタブ4は、100μm程度の厚さのニッケルなどからなる。正極リードタブ5は、100μm程度の厚さのアルミニウムなどからなる。負極リードタブ4及び正極リードタブ5の寸法は、それぞれ160mm×65mmとしている。
【0021】
ラミネートフィルム6は、100μm程度の厚さのアルムニウム箔などからなる。
【0022】
図1等に示す二次電池の強度試験を行った。強度試験は、先端に半径0.5mmの鉄球を有する加圧棒を、図1等に示す二次電池の最も広い面の重心位置に荷重10kgf〜50kgfの範囲で押しあてた時の、電池の短絡可否を調査するものである。なお、比較のため、従来技術1の二次電池の強度試験も行った。
【0023】
荷重10kgfを加えた場合には、双方の二次電池は圧痕ができるものの短絡しなかった。但し、本実施形態の積層型ラミネートフィルム二次電池の圧痕に比して、従来技術1の二次電池の圧痕は大きなものであった。
【0024】
荷重20kgfを加えた場合には、本実施形態の積層型ラミネートフィルム二次電池は短絡しなかった。これに対して、従来技術1の二次電池はおよそ7割がラミネートフィルムに亀裂が生じ短絡した。但し、従来技術1の二次電池で短絡しないものであっても、本実施形態の積層型ラミネートフィルム二次電池の圧痕に比して、大きな圧痕が形成されていた。
【0025】
荷重30kgfを加えた場合には、本実施形態の積層型ラミネートフィルム二次電池は短絡しなかった。これに対して、従来技術1の二次電池は全てがラミネートフィルムに亀裂が生じ短絡した。
【0026】
荷重40kgf,50kgfを加えても本実施形態の積層型ラミネートフィルムに次電池は短絡しなかった。このことから、本実施形態の二次電池は従来技術1の二次電池よりも2倍以上の局所的な衝撃に対する耐力を有していることがわかった。
【0028】
また、負極リードタブ4と正極リードタブ5とが対極するような構成の二次電池に限らず、負極リードタブ4と正極リードタブ5との幅をそれぞれ半分以下にして、これらを同じ側にした構成の二次電池においても適用が可能である。
【0029】
(実施形態2)
図4は、本発明の実施形態2の二次電池の断面図である。図5は、図4に示す二次電池の製造概略図である。なお、図4,図5において図1等と同様の部分には、同一符号を付している。
【0030】
本実施形態の二次電池は、電極集電部1a,2aを長くして、これらをそれぞれセパレータ6の下側で発電体の周囲を引き回しており、電極集電部1a,2aによって発電体を保護するようにしている。
【0031】
本実施形態に示すような構成の二次電池は、正電極2及び負電極1の数、すなわち電極集電部1a、2aの数が多くなるほど、発電体をより保護することができるようになる。なお、実際には最外層にのみ活物質を片面のみに塗布した電極体を用いている。
【0032】
以上説明したように、本発明の各実施形態の積層タイプのラミネートフィルム二次電池は、小型で軽く、また強度もあるので、これを個人向け携帯型情報通信機器、携帯電話機、ノート型のパーソナルコンピュータなどの携帯機器への搭載すると、携帯機器の携帯性が向上する。
【0033】
【発明の効果】
以上説明したように、本発明によると、リードタブの配置などを工夫して、リードタブ等によって発電体を保護するようにしているので、面倒な製造工程や、製造工程の増加に伴う製造コストの増加を伴うことなく、強度がある二次電池の軽量化、小型化を図ることができる。
【図面の簡単な説明】
【図1】本発明の実施形態1の二次電池の斜視図である。
【図2】図1の二次電池の分解断面図である。
【図3】図1の二次電池の断面図である。
【図4】本発明の実施形態2の二次電池の断面図である。
【図5】図4に示す二次電池の製造概略図である。
【図6】従来の二次電池の分解斜視図である。
【図7】従来の二次電池の断面図である。
【符号の説明】
1 負極体
1a 負極体の電極集電部
2 正極体
2a 正極体の電極集電部
3 セパレータ
4 負極リードタブ
5 正極リードタブ
6 ラミネートフィルム[0001]
BACKGROUND OF THE INVENTION
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a secondary battery and a portable device including the same, and more particularly, a laminated type laminated film secondary battery and a personal information assistant device (Personal Digital Assistant: PDA), a mobile phone, and a notebook. The present invention relates to a portable device such as a personal computer.
[0002]
[Prior art]
Conventionally, there is a secondary battery in which a power generation body in which positive and negative electrode bodies are alternately laminated via a separator is covered with a laminate film.
[0003]
(Prior art 1)
FIG. 6 is an exploded perspective view of a conventional secondary battery. FIG. 7 is a cross-sectional view of a conventional secondary battery. In FIG. 6, a laminate film is not shown for convenience of explanation.
[0004]
In FIG. 6 and the like, for example, six
[0005]
Each of the negative electrode body 1 and the
[0006]
Since the power generation body (
[0007]
(Prior art 2)
In contrast to the prior art 1, for example, Japanese Patent Application Laid-Open Nos. 60-65442 and 60-117542 describe secondary batteries in which a laminate film covering a power generator is covered with an ultraviolet curable resin.
[0008]
[Problems to be solved by the invention]
However, since the
[0009]
Furthermore, in the
[0010]
Therefore, an object of the present invention is to reduce the weight and size of a strong secondary battery without a troublesome manufacturing process and an increase in manufacturing cost accompanying an increase in the manufacturing process.
[0011]
In order to solve the above-described problems, the present invention provides a secondary battery in which a power generation body in which a positive electrode body and a negative electrode body are alternately laminated via an insulating separator is covered with a laminate film. From the alternately stacked positive and negative electrode bodies, an electrode current collector of the positive electrode and an electrode current collector of the negative electrode are drawn in opposite directions, and the electrode current collector of the positive electrode is drawn from the positive electrode. The negative electrode body is connected to the positive electrode lead tab on the opposite side to the negative electrode body, and the negative electrode body is connected to the negative electrode lead tab on the opposite side of the negative electrode body. an electrode current collector of the negative electrode body, by routed to wrap the upper and lower side of the power generating body, wherein the electrode current collector of the positive electrode and the negative electrode body of the electrode current collector is the power generating body Clamping from both sides of the upper and lower surfaces And wherein the Dale.
Further, the present invention provides a secondary battery in which a power generation body in which a positive electrode body and a negative electrode body are alternately laminated via an insulating separator is covered with a laminate film. As an electrode current collector, it is exposed to the outside from the power generator, and at the other end of the power generator opposite to the electrode current collector of the positive electrode, as an electrode current collector of the negative electrode, outside the power generator A positive electrode lead tab is connected to the electrode current collector portion of the positive electrode body, and a negative electrode lead tab is connected to the electrode current collector portion of the negative electrode body. The positive electrode lead tab is connected to the negative electrode body from the electrode current collector portion of the positive electrode body. The negative electrode lead tab is drawn from the electrode current collector portion of the negative electrode body in the opposite direction toward the electrode current collector portion of the positive electrode body, and the positive electrode lead tab and the negative electrode lead tab are Top side of power generator By routed to wrap from below, and the positive electrode lead tab and the negative electrode lead tab is characterized in that sandwich the power generating body from both sides of the upper and lower side.
[0012]
Moreover, the portable device of the present invention is equipped with the secondary battery.
[0013]
DETAILED DESCRIPTION OF THE INVENTION
Embodiments of the present invention will be described below with reference to the drawings.
[0014]
(Embodiment 1)
[Description of configuration]
FIG. 1 is a perspective view of a secondary battery according to Embodiment 1 of the present invention. FIG. 2 is an exploded cross-sectional view of the secondary battery of FIG. FIG. 3 is a cross-sectional view of the secondary battery of FIG. In addition, illustration of the
[0015]
In FIG. 1 and the like, for example, six
[0016]
The negative electrode body 1 is obtained by coating a copper foil sheet with a hard carbon-based negative electrode active material including carbon that collects and releases lithium ions and the like. The thickness of the negative electrode active material is about 50 μm, and the thickness of the copper foil sheet is about 15 μm. Moreover, the dimension of the negative electrode body 1 is 70 mm x 125 mm.
[0017]
The
[0018]
The
[0019]
The power generation body having the negative electrode body 1, the
[0020]
The negative
[0021]
The
[0022]
The strength test of the secondary battery shown in FIG. The strength test was performed when a pressure rod having an iron ball with a radius of 0.5 mm at the tip was pressed against the center of gravity of the widest surface of the secondary battery shown in FIG. 1 or the like in a load range of 10 kgf to 50 kgf. This is to investigate the possibility of short circuit. For comparison, the strength test of the secondary battery of Prior Art 1 was also conducted.
[0023]
When a load of 10 kgf was applied, both the secondary batteries were indented but did not short-circuit. However, the indentation of the secondary battery of the prior art 1 was larger than the indentation of the laminated laminate film secondary battery of this embodiment.
[0024]
When a load of 20 kgf was applied, the laminated laminate film secondary battery of this embodiment was not short-circuited. On the other hand, about 70% of the secondary batteries of the prior art 1 were short-circuited due to cracks in the laminate film. However, even if the secondary battery of Prior Art 1 is not short-circuited, a large impression was formed as compared with the impression of the laminated laminate film secondary battery of this embodiment.
[0025]
When a load of 30 kgf was applied, the laminated laminate film secondary battery of this embodiment was not short-circuited. On the other hand, all the secondary batteries of Prior Art 1 were short-circuited due to cracks in the laminate film.
[0026]
Even when loads of 40 kgf and 50 kgf were applied, the secondary battery did not short-circuit the laminated laminate film of this embodiment. From this, it was found that the secondary battery of the present embodiment has a resistance to local impacts that is twice or more that of the secondary battery of Prior Art 1.
[0028]
In addition, the secondary battery is not limited to a secondary battery having a configuration in which the negative
[0029]
(Embodiment 2)
FIG. 4 is a cross-sectional view of the secondary battery according to
[0030]
In the secondary battery of this embodiment, the electrode
[0031]
The secondary battery configured as shown in the present embodiment can further protect the power generator as the number of
[0032]
As described above, the laminate-type laminated film secondary battery according to each embodiment of the present invention is small, light, and strong, so that it can be used as a portable information communication device for personal use, a mobile phone, and a notebook personal computer. When mounted on a portable device such as a computer, the portability of the portable device is improved.
[0033]
【Effect of the invention】
As described above, according to the present invention, the arrangement of the lead tabs is devised to protect the power generation body with the lead tabs, etc., so the troublesome manufacturing process and the increase in the manufacturing cost accompanying the increase in the manufacturing process are required. Therefore, the secondary battery having strength can be reduced in weight and size.
[Brief description of the drawings]
FIG. 1 is a perspective view of a secondary battery according to Embodiment 1 of the present invention.
2 is an exploded cross-sectional view of the secondary battery of FIG.
3 is a cross-sectional view of the secondary battery of FIG.
FIG. 4 is a cross-sectional view of a secondary battery according to
5 is a manufacturing schematic diagram of the secondary battery shown in FIG. 4. FIG.
FIG. 6 is an exploded perspective view of a conventional secondary battery.
FIG. 7 is a cross-sectional view of a conventional secondary battery.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1
Claims (5)
前記発電体の交互に積層された正極体と負極体から互いに反対方向に正極体の電極集電部と負極体の電極集電部とが引き出され、前記正極体の電極集電部が前記正極体から引き出された方向の反対側で正極リードタブに接続され、前記負極体の電極集電部が前記負極体から引き出された方向の反対側で負極リードタブに接続され、前記正極体の電極集電部と前記負極体の電極集電部とを、前記発電体の上面側と下面側から包み込むように引き回すことによって、前記正極体の電極集電部と前記負極体の電極集電部とが前記発電体を前記上面側と下面側の両側から挟み込んでいることを特徴とする二次電池。In a secondary battery in which a power generation body in which a positive electrode body and a negative electrode body are alternately laminated via a separator having an insulating property is covered with a laminate film,
An electrode current collector of the positive electrode body and an electrode current collector of the negative electrode body are drawn out from the alternately stacked positive and negative electrode bodies in opposite directions , and the electrode current collector of the positive electrode body is Connected to the positive electrode lead tab on the opposite side of the direction drawn from the positive electrode body, and connected to the negative electrode lead tab on the opposite side of the negative electrode body in the direction drawn from the negative electrode body. The electrode current collector of the positive electrode body and the electrode current collector of the negative electrode body are drawn by routing the electric part and the electrode current collector of the negative electrode body so as to be wrapped from the upper surface side and the lower surface side of the power generator. A secondary battery, wherein the power generator is sandwiched from both the upper surface side and the lower surface side.
前記発電体の一端側では前記正極体の電極集電部として前記発電体から外側に露出し、前記正極体の電極集電部とは反対側の前記発電体の他端側では前記負極体の電極集電部として前記発電体の外側に露出し、
前記正極体の電極集電部には正極リードタブが、前記負極体の電極集電部には負極リードタブがそれぞれ接続され、
前記正極リードタブは前記正極体の電極集電部から前記負極体の電極集電部に向けて、前記負極リードタブは前記負極体の電極集電部から前記正極体の電極集電部に向けて互いに反対方向に引き出され、
前記正極リードタブと負極リードタブとを、前記発電体の上面側と下面側から包み込むように引き回すことによって、前記正極リードタブと負極リードタブとが前記発電体を前記上面側と下面側の両側から挟み込んでいることを特徴とする二次電池。In a secondary battery in which a power generation body in which a positive electrode body and a negative electrode body are alternately laminated via a separator having an insulating property is covered with a laminate film,
One end of the power generator is exposed to the outside of the power generator as an electrode current collector of the positive electrode, and the other end of the power generator opposite to the electrode current collector of the positive electrode Exposed to the outside of the power generator as an electrode current collector,
A positive electrode lead tab is connected to the electrode current collector portion of the positive electrode body, and a negative electrode lead tab is connected to the electrode current collector portion of the negative electrode body, respectively.
The positive electrode lead tab is directed from the electrode current collector portion of the positive electrode body toward the electrode current collector portion of the negative electrode body, and the negative electrode lead tab is directed from the electrode current collector portion of the negative electrode body toward the electrode current collector portion of the positive electrode body. Pulled in the opposite direction,
The positive electrode lead tab and the negative electrode lead tab are routed so as to be wrapped from the upper surface side and the lower surface side of the power generator, so that the positive electrode lead tab and the negative electrode lead tab sandwich the power generator from both the upper surface side and the lower surface side. A secondary battery characterized by that.
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KR101621591B1 (en) | 2013-01-03 | 2016-05-16 | 주식회사 엘지화학 | asymmetric electrode plate, asymmetric electrode assembly having asymmetric electrode plate, and asymmetric secondary battery having asymmetric electrode assembly |
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JP3789438B2 (en) | 2003-03-03 | 2006-06-21 | Necラミリオンエナジー株式会社 | Film outer battery |
JP4304304B2 (en) * | 2003-05-15 | 2009-07-29 | 日本電気株式会社 | Film outer battery |
EP1995816B1 (en) * | 2006-03-20 | 2015-08-12 | Citic Guoan Mengguli New Energy Technology Co., Ltd. | A soft packaged and high capacity lithium ion battery and the manufacture method of the same |
JP5256589B2 (en) * | 2006-07-07 | 2013-08-07 | 日本電気株式会社 | An assembled battery in which a plurality of film-clad batteries are arranged adjacent to each other |
JP5422378B2 (en) * | 2007-03-14 | 2014-02-19 | パナソニック株式会社 | Electrochemical element with terminal and mounting structure including the same |
JP5472284B2 (en) * | 2011-12-26 | 2014-04-16 | 日本電気株式会社 | Film outer battery and battery pack |
CN107851771B (en) * | 2015-08-31 | 2021-07-09 | 松下知识产权经营株式会社 | Battery with a battery cell |
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