JP4947466B2 - Decorative plate and method of manufacturing the decorative plate - Google Patents
Decorative plate and method of manufacturing the decorative plate Download PDFInfo
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- JP4947466B2 JP4947466B2 JP2007241102A JP2007241102A JP4947466B2 JP 4947466 B2 JP4947466 B2 JP 4947466B2 JP 2007241102 A JP2007241102 A JP 2007241102A JP 2007241102 A JP2007241102 A JP 2007241102A JP 4947466 B2 JP4947466 B2 JP 4947466B2
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- veneer
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- wood
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- 238000004519 manufacturing process Methods 0.000 title claims description 20
- 239000000853 adhesive Substances 0.000 claims description 170
- 230000001070 adhesive effect Effects 0.000 claims description 166
- 239000002023 wood Substances 0.000 claims description 115
- 239000000463 material Substances 0.000 claims description 98
- 238000000034 method Methods 0.000 claims description 64
- 239000012790 adhesive layer Substances 0.000 claims description 60
- 239000000758 substrate Substances 0.000 claims description 21
- 238000005422 blasting Methods 0.000 claims description 16
- 238000010030 laminating Methods 0.000 claims description 14
- 238000007731 hot pressing Methods 0.000 claims description 13
- 239000002537 cosmetic Substances 0.000 claims description 8
- 239000010410 layer Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 description 30
- 239000011347 resin Substances 0.000 description 30
- 238000001723 curing Methods 0.000 description 16
- 238000000576 coating method Methods 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 11
- 238000009408 flooring Methods 0.000 description 10
- 229920000877 Melamine resin Polymers 0.000 description 8
- 239000004640 Melamine resin Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000123 paper Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 230000007774 longterm Effects 0.000 description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 150000002513 isocyanates Chemical class 0.000 description 4
- 239000011120 plywood Substances 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- JZLWSRCQCPAUDP-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-triamine;urea Chemical compound NC(N)=O.NC1=NC(N)=NC(N)=N1 JZLWSRCQCPAUDP-UHFFFAOYSA-N 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 238000006124 Pilkington process Methods 0.000 description 3
- 229920002522 Wood fibre Polymers 0.000 description 3
- HNPDNOZNULJJDL-UHFFFAOYSA-N ethyl n-ethenylcarbamate Chemical compound CCOC(=O)NC=C HNPDNOZNULJJDL-UHFFFAOYSA-N 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000004606 Fillers/Extenders Substances 0.000 description 2
- 235000009137 Quercus alba Nutrition 0.000 description 2
- 241001531312 Quercus pubescens Species 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 235000011089 carbon dioxide Nutrition 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000011094 fiberboard Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000011121 hardwood Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 239000002025 wood fiber Substances 0.000 description 2
- 241000218631 Coniferophyta Species 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 241000758791 Juglandaceae Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 240000006413 Prunus persica var. persica Species 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- -1 for example Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
Landscapes
- Finished Plywoods (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
本発明は、床材として使用される化粧板及びその製造方法に関するものである。 The present invention relates to a decorative board used as a flooring and a manufacturing method thereof.
従来より、キャスター付きの家具を移動させるときや家具を置く際に凹みが生じないように、合板上に突板が貼着された床材としての化粧板は知られている。このような床材を製造する方法として、例えば、特許文献1に示すように、木質基材の表面に樹脂を含浸させたMDF(中密度繊維板)を貼着し、このMDFの表面に木質薄単板を貼着してなる床材が提案されている。 2. Description of the Related Art Conventionally, a decorative board is known as a flooring material in which a veneer is stuck on a plywood so that a dent does not occur when moving furniture with casters or placing furniture. As a method for producing such a flooring material, for example, as shown in Patent Document 1, MDF (medium density fiberboard) impregnated with resin is stuck on the surface of a woody base material, and woody material is put on the surface of this MDF. A flooring made by sticking a thin veneer has been proposed.
しかし、上記特許文献1の方法により製造された床材では、硬質プラスチック製や鉄製のキャスターを長期的に連続して摺動させて使用すると、固いキャスターにより硬質な木質薄単板がすり潰されて剪断破壊をおこしてしまい、木質薄単板が剥がれてしまうという問題が生じる。 However, in the floor material manufactured by the method of Patent Document 1, when a hard plastic or iron caster is slid continuously for a long period of time, a hard wooden thin veneer is ground by the hard caster. This causes a shear failure and causes a problem that the thin wood veneer is peeled off.
そこで、特許文献2に示すように、木質基材と木質薄単板との間にメラミン樹脂含浸紙等を介装させてホットプレスすることにより、耐傷性に優れた床材を得る方法が提案されている。この床材では、木質基材や樹脂含浸紙の上に塗布する接着剤としてSBR(スチレンブタジエンラバー)使用し、ホットプレスで接着剤に接着効果を発揮させることで、木質薄単板の剥離を抑制している。 Therefore, as shown in Patent Document 2, a method for obtaining a flooring material excellent in scratch resistance by hot pressing with a melamine resin impregnated paper or the like interposed between a wooden substrate and a thin wood veneer is proposed. Has been. This flooring uses SBR (Styrene Butadiene Rubber) as an adhesive to be applied onto a wood substrate or resin-impregnated paper, and the adhesive is exerted on the adhesive by hot pressing, thereby peeling off the thin wood veneer. Suppressed.
しかし、上記特許文献2の床材でも、熱硬化した樹脂含浸紙は極めて硬質であるため、通常の接着剤塗布量による製造条件においては、長期的なキャスターの使用により、やはり接着剤層の上の木質薄単板が層間剥離をおこして剥がれてしまうという問題が生じる。 However, even in the flooring of Patent Document 2 above, the thermoset resin-impregnated paper is extremely hard. Therefore, under the production conditions based on the normal adhesive application amount, the use of casters over the long term also causes the upper layer of the adhesive layer to remain. There arises a problem that the wood thin veneer peels off due to delamination.
一方、長期的なキャスターの使用等に対する耐傷性に考慮した床材として、特許文献3に示すように、柔軟性のある接着剤を用いることで、応力を分散させて木質薄単板の剥離を抑制しようとするものがある。
しかし、上記特許文献3のように柔軟性のある軟質の接着剤により接着層を形成する場合、ある程度の厚みを有する接着層を形成することが困難であるという問題がある。単純に接着剤の塗布量を増やして接着層を厚くしようとすると、木質基材と木質薄単板との間から接着剤が染み出てしまったり、木質薄単板に接着剤が染み上がり、表面から余分な接着剤が染み出てきてしまい意匠性が悪いという問題がある。 However, when the adhesive layer is formed with a flexible soft adhesive as in Patent Document 3, there is a problem that it is difficult to form an adhesive layer having a certain thickness. If you simply increase the amount of adhesive applied to make the adhesive layer thicker, the adhesive oozes out between the wood substrate and the wood thin veneer, or the wood ooze veneer oozes out the adhesive, There is a problem that excessive adhesive oozes out from the surface and the design is poor.
上記のように木質薄単板に接着剤が染み上がった化粧板(床材)に、ショットブラスト法による浮造り加工を施そうとすると、木質薄単板の接着剤が染み上がった部分を研削することができず、浮造り加工にムラが生じてしまい、化粧板の意匠性がよくないという問題がある。 If the decorative board (floor material) with the adhesive spread on the wood thin veneer as described above is subjected to float blasting by the shot blast method, the portion of the wood thin veneer with the adhesive spread will be ground. It is not possible to do so, and there is a problem in that unevenness occurs in the floating process, and the design of the decorative board is not good.
本発明は、かかる点に鑑みてなされたものであり、その目的とするところは、長期的なキャスターの使用に対する耐傷性と意匠性とに優れた化粧板を得ることにある。 This invention is made | formed in view of this point, The place made into the objective is to obtain the decorative board excellent in the scratch resistance with respect to long-term use of a caster, and designability.
第1の発明に係る化粧板は、少なくとも表面が硬質な木質基材の表面に、接着層を介して木質薄単板が積層一体化された化粧板であって、上記接着層は、半硬化状態において木質薄単板が積層されることで、厚みが30μm以上でかつ75μm以下であり、硬度がタイプAデュロメーターで30°以下となる基材側接着剤で構成されている。 A decorative board according to a first aspect of the present invention is a decorative board in which a thin wooden board is laminated and integrated through an adhesive layer on at least the surface of a wooden base material having a hard surface, and the adhesive layer is semi-cured In the state, the wood thin veneer is laminated to form a base material side adhesive having a thickness of 30 μm or more and 75 μm or less and a hardness of 30 ° or less with a type A durometer.
上記の構成によると、接着層が30〜75μmの厚みを有するとともに、硬度がタイプAデュロメーターで30°以下で弾性を有することで、柔軟でかつ充分な厚みの接着層が木質基材と木質薄単板との間に介装されるので、長期的にキャスターを使用しても、その応力が分散されて木質薄単板の剥離が抑制される。 According to the above configuration, the adhesive layer has a thickness of 30 to 75 μm and has a hardness of 30 ° or less with a type A durometer, so that the adhesive layer is flexible and has a sufficient thickness, so that the wooden substrate and the thin Since it is interposed between the veneers, even if casters are used for a long period of time, the stress is dispersed and peeling of the thin wood veneer is suppressed.
また、基材側接着剤を半硬化状態とした後に木質薄単板を積層することで、接着層の厚みを確保しつつ、木質薄単板への基材側接着剤の染み上がりが抑制される。 In addition, by laminating the thin wood veneer after making the substrate side adhesive semi-cured, the penetration of the substrate side adhesive to the wood thin veneer is suppressed while ensuring the thickness of the adhesive layer. The
第2の発明に係る化粧板は、第1の発明に係る化粧板において、上記接着層と木質薄単板とが単板側接着剤により接合一体化されている。 A decorative board according to a second invention is the decorative board according to the first invention, wherein the adhesive layer and the thin wood veneer are joined and integrated by a single-plate-side adhesive.
上記の構成によると、基材側接着剤による接着層と木質薄単板とが強固に接着される。 According to said structure, the contact bonding layer by a base material side adhesive agent and a wood thin veneer are adhere | attached firmly.
第3の発明に係る化粧板は、第2の発明に係る化粧板において、上記単板側接着剤の木質薄単板への染み上がりが、該木質薄単板の厚みの50%以下とされている。 A decorative board according to a third aspect of the invention is the decorative board according to the second aspect of the present invention, wherein the above-mentioned single-plate-side adhesive is soaked into the wood thin veneer by 50% or less of the thickness of the wood thin veneer. ing.
上記の構成によると、木質薄単板の表面にまで単板側接着剤が染み上がって意匠性が劣ってしまうことがなく、また、ショットブラスト法により浮造り加工を施した場合でも、少なくとも木質薄単板の厚みの上半分には単板側接着剤が染み上がっていないので、浮造り加工にムラが生じない。 According to the above configuration, the adhesive on the veneer side does not soak up to the surface of the thin wood veneer, and the design is not inferior, and at least even when the float blasting process is performed by the shot blast method Since the single plate side adhesive does not soak into the upper half of the thickness of the thin veneer, there is no unevenness in the floating process.
第4の発明に係る化粧板は、第2又は第3の発明に係る化粧板において、上記木質薄単板の表面に、単板側接着剤の該木質薄単板の裏面からの染み上がり部分に到る深さまで、ショットブラスト法による浮造り加工が施される。 A decorative board according to a fourth aspect of the invention is the decorative board according to the second or third aspect, wherein a portion of the adhesive on the surface of the wood thin veneer that oozes from the back surface of the wood thin veneer of the wood thin veneer Floating process by shot blast method is applied to the depth to reach.
上記の構成によると、ショットブラスト法により、木質薄単板の軟らかい部分を研削して凹部を形成する。このショットブラスト法とは、硬質で微細なブラスト研磨材を木質薄単板の表面に衝突させて、表面に微細な傷をつける加工のことであり、木質薄単板の軟らかい部分が少しずつ研削され、硬い部分が残る。 According to the above configuration, the concave portion is formed by grinding the soft portion of the thin wood veneer by shot blasting. This shot blasting is a process in which a hard and fine blasting abrasive is made to collide with the surface of a thin wood veneer to make fine scratches on the surface. The soft portion of the thin wood veneer is ground little by little. And the hard part remains.
このショットブラスト法による浮造り加工を施すとき、木質薄単板に接着剤が染み上がっている部分は研削されにくいが、木質薄単板への単板側接着剤の染み上がり部分まで浮造り加工を施すことで、単板側接着剤の染み上がり量を調整することにより浮造り加工の凹凸深さが決定される。 When this shot blasting method is used, the part where the adhesive is soaked into the thin wood veneer is difficult to grind, but the part where the adhesive is soaked into the wood thin veneer is floated. By adjusting the amount of permeation of the veneer-side adhesive, the unevenness depth of the float-making process is determined.
第5の発明に係る化粧板の製造方法は、少なくも表面が硬質な木質基材の表面に、硬化状態で弾性を有する基材側接着剤を塗布する基材側接着剤塗布工程と、上記基材側接着剤を半硬化させて接着層を形成する接着層形成工程と、上記接着層上に単板側接着剤を塗布する単板側接着剤塗布工程と、上記単板側接着剤が塗布された接着層上に木質薄単板を積層して積層体を得る積層工程と、上記積層体を熱圧プレスして積層一体化することで、上記接着層の厚みが30μm以上でかつ75μm以下であるとともに該接着層の硬度がタイプAデュロメーターで30°以下となる化粧基材を得る熱圧プレス工程と、上記化粧基材の表面に化粧加工を行う化粧加工工程とを含む。 According to a fifth aspect of the present invention, there is provided a method for producing a decorative board, comprising: applying a base material side adhesive having elasticity in a cured state to a surface of a wooden base material having a hard surface; An adhesive layer forming step of semi-curing the base material side adhesive to form an adhesive layer, a single plate side adhesive applying step of applying a single plate side adhesive on the adhesive layer, and the single plate side adhesive By laminating a thin wood sheet on the applied adhesive layer to obtain a laminate, and by laminating and integrating the laminate by hot pressing, the thickness of the adhesive layer is 30 μm or more and 75 μm. And a hot-pressing step for obtaining a decorative base material having a hardness of the adhesive layer of 30 ° or less with a type A durometer, and a cosmetic processing step for performing cosmetic processing on the surface of the decorative base material.
上記の構成によると、木質基材表面に塗布した基材側接着剤を半硬化させて接着層を形成した後に単板側接着剤を塗布し、さらに木質薄単板を積層する。基材側接着剤が半硬化状態であるため、基材側接着剤の木質薄単板への染み上がりが抑制されるとともに、接着層の厚みが確保される。また、単板側接着剤により、接着層と木質薄単板とが強固に接着される。 According to said structure, the base material side adhesive apply | coated to the wooden base material surface is semi-hardened, after forming a contact bonding layer, a veneer side adhesive is apply | coated and also a thin wood veneer is laminated | stacked. Since the base material side adhesive is in a semi-cured state, it is possible to prevent the base material side adhesive from spreading into the woody thin veneer and to secure the thickness of the adhesive layer. Further, the adhesive layer and the wood thin veneer are firmly bonded by the veneer side adhesive.
そして、木質基材と接着層と木質薄単板とが積層された積層体を熱圧プレスして積層一体化して化粧基材を得る。このとき、接着層は厚みが30μm以上でかつ75μm以下であり、硬度がタイプAデュロメーターで30°以下となる、すなわち、硬化物がこのような状態になる基材側接着剤が使用される。このため、充分な厚みと柔軟性を有した接着層が介装された化粧板を得ることができ、長期的なキャスターの使用に対しても、木質薄単板の剥離が抑制される。 And the laminated body by which the wooden base material, the contact bonding layer, and the wood thin single board were laminated | stacked is hot-pressed, laminated | stacked and integrated, and a decorative base material is obtained. At this time, the adhesive layer has a thickness of 30 μm or more and 75 μm or less, and has a hardness of 30 ° or less with a type A durometer, that is, a base material side adhesive in which the cured product is in such a state is used. For this reason, a decorative board in which an adhesive layer having sufficient thickness and flexibility is provided can be obtained, and peeling of the thin wood veneer is suppressed even when the caster is used for a long time.
第6の発明に係る化粧板の製造方法は、第5の発明に係る化粧板の製造方法において、上記単板側接着剤塗布工程の後に、上記単板側接着剤を半硬化させる半硬化工程をさらに含む。 A decorative plate manufacturing method according to a sixth aspect of the invention is a decorative plate manufacturing method according to the fifth aspect of the invention, wherein the single plate side adhesive is semi-cured after the single plate side adhesive coating step. Further included.
上記の構成によると、単板側接着剤を半硬化状態にした後に木質薄単板を積層することで、木質薄単板への単板側接着剤の染み上がりが抑制される。 According to said structure, after making a single board | plate side adhesive into a semi-hardened state, a wood thin single board is laminated | stacked, and the seepage of the single board side adhesive agent to a wood thin single board is suppressed.
第7の発明に係る化粧板の製造方法は、少なくとも表面が硬質な木質基材の表面に、硬化状態で弾性を有する基材側接着剤を塗布する基材側接着剤塗布工程と、上記基材側接着剤上に、該基材側接着剤よりも低粘度である単板側接着剤を塗布手段が接触しないように塗布する単板側接着剤塗布工程と、上記基材側接着剤及び単板側接着剤を半硬化させる半硬化工程と、上記単板側接着剤上に木質薄単板を積層して積層体を得る積層工程と、上記積層体を熱圧プレスして積層一体化することで、上記基材側接着剤で構成された接着層の厚みが30μm以上でかつ75μm以下であるとともに該接着層の硬度がタイプAデュロメーターで30°以下となる化粧基材を得る熱圧プレス工程と、上記化粧基材の表面に化粧加工を行う化粧加工工程とを含む。 According to a seventh aspect of the present invention, there is provided a method for manufacturing a decorative board comprising: a base material side adhesive applying step of applying a base material side adhesive having elasticity in a cured state to a surface of a wooden base material having a hard surface; On the material-side adhesive, a single-plate-side adhesive application step for applying a single-plate-side adhesive having a lower viscosity than the base-material-side adhesive so that the application means does not come into contact therewith; A semi-curing process for semi-curing the veneer side adhesive, a laminating process for laminating a thin wood veneer on the veneer side adhesive to obtain a laminated body, and laminating and integrating the laminated body by hot pressing By doing so, the thickness of the adhesive layer composed of the base material-side adhesive is 30 μm or more and 75 μm or less, and the hot pressure to obtain a decorative base material in which the hardness of the adhesive layer is 30 ° or less with a type A durometer A pressing process and a cosmetic processing process for performing cosmetic processing on the surface of the decorative base material. .
上記の構成によると、基材側接着剤を半硬化させる前に塗布手段が接触しないように単板側接着剤を塗布し、第1及び単板側接着剤の両方を同時に半硬化させる。 According to the above configuration, before the base material side adhesive is semi-cured, the single plate side adhesive is applied so that the coating means does not come in contact, and both the first and single plate side adhesives are semi-cured simultaneously.
第8の発明に係る化粧板の製造方法は、第5から第7のいずれか1つの発明に係る化粧板の製造方法において、上記熱圧プレス工程の後、ショットブラスト法により、上記木質薄単板の表面に上記単板側接着剤の木質薄単板の裏面からの染み上がり部分に到る深さまで浮造り加工を施す浮造り加工工程をさらに含む。 A method for manufacturing a decorative board according to an eighth invention is the method for manufacturing a decorative board according to any one of the fifth to seventh inventions, wherein the wood thin unit is formed by shot blasting after the hot-pressing step. A float processing step is further included in which the top surface of the board is floated to a depth that reaches a portion that penetrates from the back surface of the wood thin single plate of the single plate side adhesive.
すなわち、上記ショットブラスト法による浮造り加工では、木質薄単板の単板側接着剤が染み上がった部分は研削されにくくなる。上記の構成によると、木質薄単板に単板側接着剤が染み上がった部分まで浮造り加工を施すことで、単板側接着剤の染み上がり量を調整して浮造り加工の凹凸深さが決定される。 In other words, in the floating process by the shot blasting method, the portion where the single plate-side adhesive of the wood thin single plate has permeated becomes difficult to be ground. According to the above configuration, the depth of unevenness of the floating process is adjusted by adjusting the amount of soaking of the adhesive on the veneer side by applying the float process to the wood sheet veneer where the veneer side adhesive has soaked. Is determined.
本発明によれば、木質薄単板の剥離を効果的に抑制して、長期的なキャスターの使用に対する耐傷性を向上させることができるとともに、意匠性に優れた化粧板を得ることができる。 ADVANTAGE OF THE INVENTION According to this invention, peeling of a thin wood board | plate can be suppressed effectively, while being able to improve the scratch resistance with respect to long-term use of a caster, the decorative board excellent in the design property can be obtained.
以下、本発明の実施形態を図面に基づいて詳細に説明する。 Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
[化粧板]
本発明の実施形態に係る化粧板は、木質基材と、木質基材の表面に接着層を介して貼着される木質薄単板とを備え、床材として使用されるものである。
[Decorative board]
A decorative board according to an embodiment of the present invention includes a wood base material and a wood thin veneer adhered to the surface of the wood base material via an adhesive layer, and is used as a flooring material.
(木質基材)
木質基材は、少なくとも表面が硬質な木質基材で構成されていれば、例えば木材でもよいし、インシュレーションボードやMDF、ハードボード等の木質繊維板でもよいし、合板、パーティクルボードでもよい。
(Wood base)
The wood base material may be wood, for example, a wood fiber board such as an insulation board, MDF, or hard board, a plywood board, or a particle board, as long as the wood base material is composed of at least a hard wood base material.
木質基材の表面を硬く強化する強化方法としては、単純に、表層にメラミン系樹脂、フェノール系樹脂、エポキシ系樹脂、ウレタン系樹脂やイソシアネート系樹脂を含浸させてもよいし、メラミン樹脂含浸紙、フェノール樹脂含浸紙等の各種樹脂含浸紙による強化層を表層に設けてもよい。また、樹脂含浸紙に代えて、木粉や木質繊維、木質切片等を主体とし、これらを各種樹脂とともに混練成形した硬質の人工樹脂木材や、MDF、ハードボード等の木質繊維板等の硬質な木質基材で表面強化してもよい。 As a reinforcing method to harden the surface of the wooden substrate, the surface layer may simply be impregnated with melamine resin, phenol resin, epoxy resin, urethane resin or isocyanate resin, or melamine resin impregnated paper Further, a reinforcing layer made of various resin-impregnated paper such as phenol resin-impregnated paper may be provided on the surface layer. Also, instead of resin-impregnated paper, hard artificial resin wood mainly made of wood powder, wood fiber, wood slices, etc., and kneaded and molded with various resins, hard wood fiber boards such as MDF, hardboard, etc. The surface may be reinforced with a wooden substrate.
また、合板等の表面にMDFやハードボード等の硬質木質基材を貼着してもよい。この場合、MDFやハードボード等は樹脂含浸強化されたものでもよい。 Moreover, you may stick hard wooden base materials, such as MDF and a hard board, on the surface, such as a plywood. In this case, the MDF, the hard board and the like may be reinforced with resin impregnation.
いずれの場合でも、軟質な木質基材表面が長期的かつ連続的なキャスターの使用に耐え得るように強化されている必要がある。 In any case, the soft wooden substrate surface needs to be strengthened to withstand long-term and continuous use of casters.
(接着層)
上記接着層は、厚みが30〜75μmであって、硬度がタイプAデュロメーターで30°以下である、弾性を有する基材側接着剤の硬化物で構成されている。このように、接着層が充分な厚みと弾性とを有することにより、キャスターの長期的かつ連続的な荷重に対しても、木質薄単板の剥離を抑制することができる。
(Adhesive layer)
The adhesive layer has a thickness of 30 to 75 μm, and is made of a cured product of an elastic base material side adhesive having a hardness of 30 ° or less with a type A durometer. As described above, since the adhesive layer has sufficient thickness and elasticity, it is possible to suppress peeling of the thin wood veneer even for a long-term and continuous load of the caster.
また、基材側接着剤で構成される接着層と木質薄単板とを強固に接着させるために、これらは単板側接着剤により接合一体化されることが好ましい。単板側接着剤の塗布量は、木質薄単板への染み上がりを抑制するために必要最低限の量であることが好ましい。さらに、詳細は後述するように、単板側接着剤を半硬化状態にした後に木質薄単板を積層し、木質基材と木質薄単板とが積層された積層物を熱圧プレスして積層一体化する際に、単板側接着剤は所望の強度が実現できるものが好ましく、さらに染み上がりを抑制することができる。 Further, in order to firmly bond the adhesive layer composed of the base material side adhesive and the wood thin veneer, they are preferably joined and integrated by the veneer side adhesive. The application amount of the veneer-side adhesive is preferably the minimum amount necessary to suppress the stain on the thin wood veneer. Furthermore, as will be described in detail later, after the veneer side adhesive is made into a semi-cured state, the wood thin veneer is laminated, and the laminate in which the wood base material and the wood thin veneer are laminated is hot-pressed. When laminating and integrating, the single-plate-side adhesive is preferably one that can achieve a desired strength, and can further suppress bleeding.
上記基材側接着剤と単板側接着剤とは、同じ接着剤であってもよいし、異なる種類の接着剤であってもよいが、少なくとも基材側接着剤が、その硬化物の硬度がタイプAデュロメーターで30°以下となり、弾性を有するものであればよい。 The base material side adhesive and the veneer side adhesive may be the same adhesive or different types of adhesives, but at least the base material side adhesive has a hardness of the cured product. May be any type A durometer that is 30 ° or less and has elasticity.
上記基板側又は単板側接着剤の木質薄単板への染み上がりは、木質薄単板の厚みの50%以下であることが好ましい。染み上がり量をこのように抑えることにより、後述するショットブラスト法による浮造り加工を効果的に行うことができる。 It is preferable that the above-mentioned substrate side or veneer side adhesive has a stain of 50% or less of the thickness of the wood thin veneer. By suppressing the amount of permeation in this way, it is possible to effectively carry out a floating process by a shot blast method described later.
基材側接着剤としては、例えば、アクリル系樹脂、酢ビ系樹脂、ラテックス系樹脂、ゴム系樹脂、ビニルウレタン系樹脂、ウレタン系樹脂やこれらの変性樹脂、これらの樹脂と尿素メラミン系樹脂、エポキシ系樹脂、フェノール系樹脂、イソシアネート系樹脂等との混合物等が好適に用いられる。 Examples of the base-side adhesive include acrylic resins, vinyl acetate resins, latex resins, rubber resins, vinyl urethane resins, urethane resins and modified resins thereof, these resins and urea melamine resins, A mixture with an epoxy resin, a phenol resin, an isocyanate resin, or the like is preferably used.
さらに、基材側接着剤の塗布量を増やすために、各種増粘剤や増量剤を添加して高粘度にすることが好ましい。増粘剤としては、例えば小麦粉やポバール等が使用される。また増量剤としては、炭酸カルシウム、アルミナ、酸化チタン等が使用される。 Furthermore, in order to increase the application amount of the base-side adhesive, it is preferable to add various thickeners and extenders to increase the viscosity. As the thickener, for example, flour or poval is used. As the extender, calcium carbonate, alumina, titanium oxide or the like is used.
また、基材側接着剤には、木質基材の隠蔽性を向上させるために、各種顔料が添加されて着色されていてもよい。 Moreover, in order to improve the concealment property of a wooden base material, various pigments may be added and colored by the base material side adhesive.
単板側接着剤としては、例えば、アクリル系樹脂、酢ビ系樹脂、ラテックス系樹脂、ゴム系樹脂、ビニルウレタン系樹脂、ウレタン系樹脂やこれらの変性樹脂、尿素メラミン系樹脂、エポキシ系樹脂、フェノール系樹脂、イソシアネート系樹脂等及びこれらの樹脂の混合物等が好適に用いられる。 As the veneer side adhesive, for example, acrylic resin, vinyl acetate resin, latex resin, rubber resin, vinyl urethane resin, urethane resin and their modified resins, urea melamine resin, epoxy resin, Phenol resins, isocyanate resins and the like, and mixtures of these resins are preferably used.
単板側接着剤は弾性を有するものが好ましいが、その硬化物が著しく脆くて硬い性質のものではない限り、どのようなものでも使用することができる。好ましくは、酢ビ系樹脂やラテックス系樹脂にエポキシ系樹脂やメラミン系樹脂等を配合した強度と柔軟性とに考慮したものがよい。また、単板側接着剤は、基材側接着剤で構成された接着層と木質薄単板とを強固に接着するために、強接着性を有することが好ましい一方、基材側接着剤に比して低粘度のものであってもよい。 The veneer side adhesive preferably has elasticity, but any adhesive can be used as long as the cured product is not extremely brittle and hard. It is preferable to consider the strength and flexibility of an epoxy resin or a melamine resin blended with a vinyl acetate resin or a latex resin. In addition, the veneer side adhesive preferably has strong adhesiveness in order to firmly bond the adhesive layer composed of the base material side adhesive and the thin wood veneer, while the adhesive on the base material side It may have a lower viscosity.
上記接着剤には、適宜硬化剤を添加して硬化性を促進させる。硬化剤としては、熱反応型や紫外線硬化型等を適宜選択すればよく、これらを組み合わせてもよい。また、硬化剤は、接着剤を半硬化させる程度の比較的低温の熱で反応する硬化剤と、接着剤を半硬化させる工程では反応せず、熱圧プレス工程で反応するような硬化剤とを併用することが好ましい。 A curing agent is appropriately added to the adhesive to promote curability. As the curing agent, a thermal reaction type, an ultraviolet curing type, or the like may be appropriately selected, and these may be combined. Further, the curing agent includes a curing agent that reacts with relatively low-temperature heat that causes the adhesive to be semi-cured, and a curing agent that does not react in the process of semi-curing the adhesive but reacts in the hot press process. It is preferable to use together.
本発明の化粧板は、基材側接着剤で厚膜な接着層を形成し、木質基材に木質薄単板を積層する前に、基材側接着剤を半硬化状態とする。このため、接着層を熱硬化により半硬化状態にするためには、大掛かりなドライヤー設備が必要となるため、紫外線硬化型の硬化剤を添加し、紫外線照射により瞬時に半硬化状態とすることが好ましい。 The decorative board of the present invention forms a thick adhesive layer with the base material side adhesive, and puts the base material side adhesive into a semi-cured state before laminating the wood thin veneer on the wood base material. For this reason, in order to make the adhesive layer into a semi-cured state by heat curing, a large-scale dryer facility is required. Therefore, an ultraviolet curable curing agent can be added and instantaneously made into a semi-cured state by ultraviolet irradiation. preferable.
単板側接着剤も、木質薄単板への染み上がりを効果的に制御するために、半硬化状態にした後に木質薄単板を積層することが望ましい。また単板側接着剤も紫外線硬化特性を有することで、紫外線照射により半硬化状態とし、化粧板を効率よく生産することができる。 In order to effectively control the permeation to the wood thin veneer, it is desirable to laminate the wood thin veneer after making it into a semi-cured state. Moreover, since the single-plate-side adhesive also has ultraviolet curing characteristics, it can be made into a semi-cured state by irradiation with ultraviolet rays, and a decorative plate can be produced efficiently.
(木質薄単板)
木質薄単板としては、天然木質材や、これらの積層物をスライスした薄切片を使用することができる。天然木質材は、針葉樹、広葉樹、いわゆる早生樹等、どのようなものでも使用することができる。また、天然木質材の積層物をスライスしたものとは、いわゆる人工突板といわれるものである。
(Woody thin veneer)
As the wood thin veneer, a natural wood material or a thin slice obtained by slicing these laminates can be used. As the natural wood material, any material such as conifers, broad-leaved trees, so-called fast-growing trees can be used. Moreover, what sliced the laminated body of natural wooden material is what is called an artificial veneer.
また、木質薄単板には、乾燥単板や生単板(いわゆる濡れ単板)を使用することができる。木質薄単板の厚みが厚すぎると、硬くなるだけでなく、単板自体の耐干割れ性が悪くなってしまうので、木質薄単板の厚みは、0.15〜1.0mm程度が好ましく、後の浮造り工程を考慮すると、より好ましくは、0.25〜0.6mm程度の厚みがよい。 Moreover, a dry veneer or a raw veneer (so-called wet veneer) can be used for the thin wood veneer. If the thickness of the wood thin veneer is too thick, not only will it become hard, but the resistance to dry cracking of the veneer itself will deteriorate, so the thickness of the wood thin veneer is preferably about 0.15 to 1.0 mm. In consideration of the subsequent floating process, the thickness of about 0.25 to 0.6 mm is more preferable.
[製造方法]
次に、上記化粧板の製造方法について説明する。
[Production method]
Next, the manufacturing method of the said decorative board is demonstrated.
(基材側接着剤塗布工程)
まず、上記木質基材に基材側接着剤を塗布する。基材側接着剤を塗布する手段としては、フローコーター又はロールコーターが好適に用いられる。この基材側接着剤によって、30〜75μmの厚みの接着層が形成されるように塗布する。
(Substrate side adhesive application process)
First, a base material side adhesive is applied to the wood base material. As a means for applying the substrate side adhesive, a flow coater or a roll coater is preferably used. The base material side adhesive is applied so that an adhesive layer having a thickness of 30 to 75 μm is formed.
(接着層形成工程)
次に、上記基材側接着剤を半硬化状態として接着層を形成する。
(Adhesive layer forming process)
Next, an adhesive layer is formed with the base material side adhesive in a semi-cured state.
基材側接着剤は、通風ドライヤー乾燥により半硬化状態とすることが一般的である。ドライヤーの温度は40〜60℃程度が好ましく、木質基材の盤面温度が80℃以上にならないようにする。木質基材の盤面が80℃以上になると、積層体を熱圧プレスする工程の前に接着剤が硬化してしまうからである。 In general, the base material side adhesive is semi-cured by drying with a ventilation dryer. The temperature of the dryer is preferably about 40 to 60 ° C., and the board surface temperature of the wooden base material is set not to exceed 80 ° C. This is because when the board surface of the wooden substrate is 80 ° C. or higher, the adhesive is cured before the step of hot-pressing the laminate.
紫外線照射により半硬化状態とする場合に使用する設備は、使用する光開始剤の種類により適宜選択する。具体的には、メタルハライドランプ、無電極方式のDランプ、Vバルブ、Qバルブ、Mバルブ、パルスUV方式等を使用する。 The equipment to be used in the semi-cured state by ultraviolet irradiation is appropriately selected depending on the type of photoinitiator used. Specifically, a metal halide lamp, an electrodeless D lamp, a V bulb, a Q bulb, an M bulb, a pulse UV method, or the like is used.
(単板側接着剤塗布工程)
上記接着層上に単板側接着剤を塗布する。なお、この単板側接着剤は、基材側接着剤を半硬化状態とする前に塗布してもよい。少なくとも木質薄単板を積層する前に基材側接着剤が半硬化状態となっていればよい。
(Single plate side adhesive application process)
A single plate side adhesive is applied on the adhesive layer. In addition, you may apply | coat this single-plate side adhesive, before making a base material side adhesive into a semi-hardened state. It is only necessary that the base material side adhesive is in a semi-cured state before at least laminating the wood thin veneer.
上記基材側接着剤を半硬化状態とした後に、単板側接着剤を塗布する場合には、塗布手段は特に限定されない。目的とする単板側接着剤の塗布量に応じた塗布方法を選択すればよく、例えば、ロールコーターやフローコーター、スプレー等が好適である。 When applying the veneer side adhesive after making the base material side adhesive semi-cured, the application means is not particularly limited. What is necessary is just to select the application | coating method according to the application quantity of the target single-plate side adhesive agent, for example, a roll coater, a flow coater, a spray etc. are suitable.
一方、基材側接着剤を乾燥させず半硬化状態となる前に単板側接着剤を塗布する場合には、塗布方法は塗布手段が接着層上に接触しない非接触方式に限定される。例えば、フローコーターやスプレー等の方式に限定される。 On the other hand, in the case where the single-plate adhesive is applied before the substrate-side adhesive is not dried and becomes a semi-cured state, the application method is limited to a non-contact method in which the application means does not contact the adhesive layer. For example, it is limited to a system such as a flow coater or a spray.
(半硬化工程)
上記基材側接着剤を半硬化させた後に単板側接着剤を塗布した場合、次に、単板側接着剤を半硬化状態とする。単板側接着剤を半硬化状態とする方法は、上述した基材側接着剤を半硬化状態とする方法と同じであるが、この際、基材側接着剤が硬化状態とならないようにする。
(Semi-curing process)
When the veneer side adhesive is applied after the base material side adhesive is semi-cured, the veneer side adhesive is then brought into a semi-cured state. The method for making the veneer side adhesive in a semi-cured state is the same as the method for making the base material side adhesive in a semi-cured state as described above. .
一方、上記基材側接着剤を半硬化状態とする前に単板側接着剤を塗布した場合には、基材側接着剤と単板側接着剤とを一緒に半硬化させる。これらを半硬化状態とする方法も上記基材側接着剤を半硬化状態とする方法と同じである。 On the other hand, when the single-plate-side adhesive is applied before the base-material-side adhesive is brought into a semi-cured state, the base-material-side adhesive and the single-plate-side adhesive are semi-cured together. The method for bringing these into a semi-cured state is also the same as the method for bringing the base material side adhesive into a semi-cured state.
なお、この単板側接着剤を半硬化させずに木質薄単板を載置してもよいが、木質薄単板への単板側接着剤の染み上がりを抑制するためには、単板側接着剤を半硬化状態としてから木質薄単板を載置することが好ましい。 In addition, the wood thin veneer may be placed without semi-curing the veneer side adhesive, but in order to suppress the penetration of the veneer side adhesive onto the wood thin veneer, It is preferable to place the thin wood veneer after the side adhesive is in a semi-cured state.
(積層工程)
少なくとも基材側接着剤が半硬化状態で、次の木質薄単板の載置が行われる。
(Lamination process)
At least the base material side adhesive is in a semi-cured state, and the next wood thin veneer is placed.
半硬化状態の基材側接着剤、半硬化状態又は未硬化状態の単板側接着剤上に木質薄単板を載置して積層体を得る。載置した木質薄単板は仮固定してもよい。仮固定の方法としては、高周波等で仮固定部分の水分を飛ばし、単板側接着剤を固化させる方法が好適に用いられる。 A thin laminate of wood is placed on the base-side adhesive in a semi-cured state, the single-plate-side adhesive in a semi-cured state or an uncured state, and a laminate is obtained. The placed wood thin veneer may be temporarily fixed. As a method for temporary fixing, a method in which moisture in the temporarily fixed portion is blown off by high frequency or the like and the single plate side adhesive is solidified is preferably used.
(熱圧プレス工程)
次に、上記積層体を積層一体化して化粧基材を得るために、積層体を熱圧プレスする。熱圧プレスの方法は、一般的なロールプレスや平板プレス等、様々な方法があるが、好ましくは平板プレスが使用される。熱圧プレスは、100〜130℃でかつ0.2〜1.0MPaの条件下で、30〜90秒程度行われる。これにより、基材側接着剤及び単板側接着剤が完全に硬化され、接着層の厚みが30μm以上でかつ75μm以下であるとともに、接着層の硬度がタイプAデュロメーターで30°以下となり、積層体が積層一体化される。
(Hot press process)
Next, in order to obtain a decorative base material by stacking and integrating the laminate, the laminate is hot-pressed. There are various hot pressing methods such as a general roll press and a flat plate press, and a flat plate press is preferably used. The hot press is performed at a temperature of 100 to 130 ° C. and 0.2 to 1.0 MPa for about 30 to 90 seconds. Thereby, the base material side adhesive and the single plate side adhesive are completely cured, the thickness of the adhesive layer is not less than 30 μm and not more than 75 μm, and the hardness of the adhesive layer is not more than 30 ° with a type A durometer. The body is laminated and integrated.
このとき、単板側接着剤の木質薄単板への染み上がりは、木質薄単板の厚みの50%以下となっている。 At this time, the stain on the wood thin veneer on the veneer side adhesive is 50% or less of the thickness of the wood thin veneer.
(浮造り加工工程)
次に、上記化粧基材の表面に、ショットブラスト法による浮造り加工を施す。ショットブラスト法とは、硬質で微細なブラスト用研磨材を木質薄単板の表面に衝突させて表面に微細な傷をつける加工である。これにより、木質薄単板の軟らかい部分が研削され、硬い部分が残り、表面に凹凸を有する化粧基材を得ることができる。
(Floating process)
Next, the surface of the decorative base material is floated by a shot blast method. The shot blasting process is a process in which a hard and fine blasting abrasive is made to collide with the surface of a thin wood veneer to cause fine scratches on the surface. Thereby, the soft part of a wood thin veneer is ground, a hard part remains, and the decorative base material which has an unevenness | corrugation on the surface can be obtained.
ブラスト用研磨材としては、ガラスビーズ、ガラスパウダー、ケイ素質等の無機質粒子、アルミナ等の金属粒子、胡桃や桃の種等を粉砕した硬質有機粒子、あるいはドライアイスを細かく粉砕したドライアイス粒子等が用いられる。このようなブラスト用研磨材をノズルから噴出させ、化粧基材の表面に衝突させて浮造り加工を施す。なお、化粧基材には浮造り加工を施さなくてもよい。 Abrasives for blasting include glass beads, glass powder, inorganic particles such as silicon, metal particles such as alumina, hard organic particles obtained by pulverizing walnuts and peach seeds, or dry ice particles obtained by finely pulverizing dry ice. Is used. Such an abrasive for blasting is ejected from a nozzle and is made to collide with the surface of the decorative base material to carry out a floating process. In addition, it is not necessary to give a floating process to a decorative base material.
(化粧加工工程)
最後に、上記浮造り加工が施された化粧基材や、面均一に研削された化粧基材の表面に透明性樹脂塗料を塗布し、これを硬化させて透明性樹脂塗膜を形成する化粧加工を施して化粧板を得る。
(Makeup process)
Lastly, a makeup is applied by applying a transparent resin paint to the surface of the decorative base that has been subjected to the above-described floating process or a surface of the base that has been uniformly ground, and then curing the same to form a transparent resin coating film. A decorative board is obtained by processing.
[実施形態の効果]
このように、本発明の実施形態に係る化粧板は、接着層が30μm以上でかつ75μm以下の厚みを有し、タイプAデュロメーターで30°以下の硬度となり弾性を有するので、柔軟でかつ充分な厚みを有する接着層が木質基材と木質薄単板との間に介装されることになり、長期的かつ連続的にキャスターを使用しても、その応力が分散されて木質薄単板の剥離を効果的に抑制することができる。
[Effect of the embodiment]
Thus, the decorative board according to the embodiment of the present invention is flexible and sufficient because the adhesive layer has a thickness of 30 μm or more and 75 μm or less, has a hardness of 30 ° or less with a type A durometer and has elasticity. A thick adhesive layer is interposed between the wood substrate and the wood thin veneer, and even if casters are used continuously for a long time, the stress is dispersed and the wood thin veneer is Separation can be effectively suppressed.
また、基材側接着剤を半硬化状態とした後に木質薄単板を積層するので、接着層の厚みを確保しつつ、木質薄単板への基材側接着剤の染み上がりを抑制することができる。 In addition, since the thin wood veneer is laminated after the base material side adhesive is made semi-cured, it suppresses the spread of the base material side adhesive to the thin wood veneer while ensuring the thickness of the adhesive layer. Can do.
また、接着層と木質薄単板とを単板側接着剤により接合一体化するので、接着層と木質薄単板とが強固に接着されて、化粧板の凹み等をより効果的に抑制することができる。 In addition, since the adhesive layer and the wood thin veneer are joined and integrated with the veneer side adhesive, the adhesive layer and the wood thin veneer are firmly bonded to more effectively suppress the dent of the decorative board. be able to.
また、基材側接着剤の木質薄単板への染み上がりを抑制するとともに、単板側接着剤の木質薄単板への染み上がりの抑制も考慮することで、この化粧板にショットブラスト法により浮造り加工を施した場合に、ムラが生じにくくなり、意匠性に優れた化粧板を得ることができる。 In addition to suppressing the spread of the base material side adhesive to the wood thin veneer and taking into account the suppression of the veneer of the veneer side adhesive to the wood thin veneer, the shot blast method is applied to this decorative board. When a floating process is performed, unevenness is less likely to occur, and a decorative board with excellent design can be obtained.
また、単板側接着剤の木質薄単板への染み上がりを木質薄単板の厚みの50%以下とすることで、木質薄単板の表面への単板側接着剤の染み上がりがないだけでなく、ショットブラスト法による浮造り加工の際、より確実にムラの発生を抑制することができ、意匠性により一層優れた化粧板を得ることができる。 In addition, the amount of the single plate side adhesive that permeates the wood thin veneer is 50% or less of the thickness of the wood thin veneer so that the surface of the wood thin veneer does not bleed. In addition, the occurrence of unevenness can be more reliably suppressed during the floating process by the shot blasting method, and a decorative board that is more excellent in design can be obtained.
さらに、木質薄単板への単板側接着剤の染み上がり部分まで浮造り加工を施すことによって、単板側接着剤の染み上がり量を調整することで浮造り加工の凹凸深さを決定することができるので、効果的に浮造り加工を施すことができる。 Furthermore, the depth of unevenness of the float process is determined by adjusting the amount of soaking of the adhesive on the veneer side by applying the float process to the part where the veneer side adhesive penetrates the thin wood veneer. Therefore, it is possible to effectively carry out floating processing.
(実施例1)
厚さ9mmの針葉樹合板の表面に、厚さ2.7mmのMDFをビニルウレタン系接着剤で、コールドプレスによって貼着し、木質基材を得た。
Example 1
A 2.7 mm thick MDF was stuck to the surface of a 9 mm thick softwood plywood with a vinyl urethane adhesive by a cold press to obtain a wooden substrate.
上記木質基材のMDFの表面に、基材側接着剤として変性酢ビ系接着剤95重量部に対してイソシアネート系接着剤5重量部を混合したものを塗布した。基材側接着剤の樹脂分率は約50%とし、その塗布量は15g/尺2とした。この基材側接着剤を硬化させた硬化物の硬度をショア硬度計(タイプA)で測定すると25°であった。 What mixed 5 weight part of isocyanate adhesives with respect to 95 weight part of modified vinyl acetate adhesives as a base material side adhesive agent was apply | coated to the surface of MDF of the said wooden base material. The resin fraction of the base-side adhesive was about 50%, and the coating amount was 15 g / scale 2 . The hardness of the cured product obtained by curing the substrate-side adhesive was 25 ° when measured with a Shore hardness meter (type A).
上記基材側接着剤を塗布した木質基材を80℃で1分間通風乾燥させ、常温になるまで通風冷却し、基材側接着剤を半硬化状態とした接着層を形成した。 The woody base material coated with the base material side adhesive was dried by ventilation at 80 ° C. for 1 minute and cooled by ventilation until reaching room temperature, thereby forming an adhesive layer in which the base material side adhesive was semi-cured.
そして、接着層の上に、単板側接着剤としてアクリル系樹脂40重量部に対して、メラミン系樹脂59重量部及び増粘剤1重量部を混合したものを塗布し、80℃で10分間通風乾燥させ、常温になるまで通風冷却した。単板側接着剤の樹脂分率は約50%とし、その塗布量は10g/尺2とした。 On the adhesive layer, a mixture of 59 parts by weight of melamine resin and 1 part by weight of thickener is applied to 40 parts by weight of the acrylic resin as the single-plate-side adhesive, and the mixture is applied at 80 ° C. for 10 minutes. Ventilated and dried and cooled by cooling to room temperature. The resin fraction of the veneer side adhesive was about 50%, and the coating amount was 10 g / scale 2 .
上記単板側接着剤を塗布した接着層の上に、厚さ0.35mmの木質薄単板としてのホワイトオーク生単板を積層して積層体を得た。そして、この積層体を120℃で0.8MPa圧力下で60秒のプレススケジュールで熱圧プレスして化粧基材を得た。 A white oak raw veneer as a wood thin veneer having a thickness of 0.35 mm was laminated on the adhesive layer coated with the veneer side adhesive to obtain a laminate. The laminate was hot-pressed at 120 ° C. under a 0.8 MPa pressure with a press schedule of 60 seconds to obtain a decorative base material.
上記のようにして得た化粧基材の表面には、全く接着剤の染み上がりがなかった。 The surface of the decorative base material obtained as described above had no adhesive oozing.
そして、化粧基材の表面を均一に厚さ0.05mmだけワイドベルトサンダーで研削し、透明性樹脂塗料を塗布して透明性樹脂塗膜を形成し、化粧板を得た。 Then, the surface of the decorative substrate was uniformly ground with a wide belt sander by a thickness of 0.05 mm, and a transparent resin coating was formed by applying a transparent resin paint to obtain a decorative board.
上記のようにして得た化粧板の断面を顕微鏡観察すると、接着層の厚さは約30μmであった。 When the cross section of the decorative board obtained as described above was observed with a microscope, the thickness of the adhesive layer was about 30 μm.
上記化粧板に対して耐キャスター試験を行った。耐キャスター試験とは、直径50mmの鉄製の単輪キャスター上に25kgの荷重を載せ、300m長さを500回往復させる試験である。キャスターの移動速度は、約2秒/往復とし、試験後の化粧板表面の凹み量の測定と、状態の目視確認とを行う。 A caster resistance test was performed on the decorative board. The caster resistance test is a test in which a load of 25 kg is placed on an iron single wheel caster having a diameter of 50 mm and a 300 m length is reciprocated 500 times. The moving speed of the caster is about 2 seconds / reciprocation, and the dent amount on the decorative board surface after the test is measured and the state is visually confirmed.
上記耐キャスター試験の試験結果は、化粧板表面の凹み量は最大で0.1mmであり、木質薄単板の剥離も確認されなかった。 The test results of the caster resistance test showed that the dent amount on the decorative plate surface was 0.1 mm at the maximum, and peeling of the thin wood veneer was not confirmed.
(実施例2)
上記実施例1で得られた化粧基材の表面に、ショットブラスト法により浮造り加工を施した。この浮造り加工により、柔らかい導管以外の部分が優先的に研削され、硬い導管部分が残り、凹凸感に優れた外観を持つ化粧基材を得ることができた。この化粧基材の表面を研磨剤が含まれたスポンジで研磨した後、透明樹脂塗料を塗布して透明樹脂塗膜を形成し、美麗な化粧板を得た。
(Example 2)
The surface of the decorative base material obtained in Example 1 was floated by the shot blast method. By this floating process, a portion other than the soft conduit was preferentially ground, a hard conduit portion remained, and a decorative base material having an excellent appearance with an uneven feeling could be obtained. After polishing the surface of this decorative substrate with a sponge containing an abrasive, a transparent resin coating was applied to form a transparent resin coating film to obtain a beautiful decorative board.
上記のようにしてられた化粧板に対しても耐キャスター試験を行った。500回往復させた後には、木質薄単板の剥離等の問題は確認されなかった。 A caster resistance test was also performed on the decorative board made as described above. After reciprocating 500 times, problems such as peeling of the thin wood veneer were not confirmed.
(比較例1)
比較例1の化粧板は、基材側接着剤が尿素メラミン樹脂系接着剤60重量部に対して、変性酢ビ系接着剤40重量部を混合したものである点で上記実施例1の化粧板と異なり、他は実施例1と同じ構成であり、同じ製造方法により化粧板を得た。接着層の強度を測定すると80°であった。
(Comparative Example 1)
The decorative board of Comparative Example 1 is the makeup of Example 1 in that the base-side adhesive is a mixture of 60 parts by weight of urea melamine resin adhesive and 40 parts by weight of modified vinyl acetate adhesive. Unlike the board, the rest was the same as in Example 1, and a decorative board was obtained by the same manufacturing method. The strength of the adhesive layer was measured and found to be 80 °.
上記耐キャスター試験を行った結果、300回往復させた時点で、木質薄単板の剪断破壊が確認され、MDFと木質薄単板との間の接着層が界面剥離をおこしていた。 As a result of performing the caster resistance test, when the wood was reciprocated 300 times, shear failure of the wood thin veneer was confirmed, and the adhesive layer between the MDF and the wood thin veneer was subjected to interfacial peeling.
(比較例2)
比較例2の化粧板は、上記比較例1において、基材側接着剤の塗布量を35g/尺2とし、この基材側接着剤を乾燥させずに、つまり半硬化状態とせず、また単板側接着剤を使用せずに、0.35mmのホワイトオーク生単板を積層して積層体を得た。この積層体を120℃で0.8MPaの圧力下で60秒のプレススケジュールで熱圧プレスして化粧基材を得た。
(Comparative Example 2)
The decorative board of Comparative Example 2 is the same as that of Comparative Example 1 except that the coating amount of the base-side adhesive is 35 g / scale 2, and this base-side adhesive is not dried, that is, not semi-cured. Without using the plate-side adhesive, a 0.35 mm white oak veneer was laminated to obtain a laminate. This laminate was hot-pressed at 120 ° C. under a pressure of 0.8 MPa for 60 seconds to obtain a decorative base material.
この場合、木質基材と木質薄単板との間から接着剤がはみ出ただけでなく、木質薄単板の表面に、かなりの量の接着剤の染み上がりが確認された。 In this case, not only the adhesive protruded from between the wood substrate and the wood thin veneer, but also a considerable amount of adhesive soaking was confirmed on the surface of the wood thin veneer.
上記化粧基材の表面を均一に0.05mmだけワイドベルトサンダーで研削し、透明性樹脂塗料を塗布して透明性樹脂塗膜を形成し、化粧板を得た。 The surface of the decorative substrate was uniformly ground with a wide belt sander by 0.05 mm, and a transparent resin coating was formed by applying a transparent resin paint to obtain a decorative board.
上記化粧板の表面を顕微鏡で観察したところ、接着層は厚みが均等でなく、また平均した厚みは7μmであった。 When the surface of the decorative board was observed with a microscope, the thickness of the adhesive layer was not uniform, and the average thickness was 7 μm.
また、上記化粧板に対して耐キャスター試験を行った。試験結果は500回往復させた後で、表面の凹みは最大で0.15mm程度であった。また、接着層と透明性樹脂塗膜との間の木質薄単板の剪断破壊が発生していた。 Moreover, the caster-proof test was done with respect to the said decorative board. As a result of the test, the surface dent was about 0.15 mm at the maximum after 500 reciprocations. Moreover, the shear failure of the thin wood single board between the contact bonding layer and the transparent resin coating film had generate | occur | produced.
(比較例3)
上記比較例2で得られた化粧基材の表面に、ショットブラスト法により浮造り加工を施した。木質薄単板の接着剤が染み上がっている部分がほとんど研削されず、浮造り加工にムラが生じていた。
(Comparative Example 3)
The surface of the decorative base material obtained in Comparative Example 2 was floated by a shot blast method. The portion of the wood thin veneer where the adhesive oozed out was hardly ground, and unevenness occurred in the floating process.
以上説明したように、本発明は、床材として利用される化粧板及びその製造方法について有用である。 As described above, the present invention is useful for a decorative board used as a flooring and a method for producing the same.
Claims (8)
上記接着層は、半硬化状態において木質薄単板が積層されることで、厚みが30μm以上でかつ75μm以下であり、硬度がタイプAデュロメーターで30°以下となる基材側接着剤で構成されていることを特徴とする化粧板。 It is a decorative board in which a wooden thin veneer is laminated and integrated via an adhesive layer on the surface of a wooden base material having at least a hard surface,
The adhesive layer is composed of a base-side adhesive that has a thickness of 30 μm or more and 75 μm or less and a hardness of 30 ° or less with a type A durometer, by laminating wood thin veneers in a semi-cured state. A decorative board characterized by
上記接着層と木質薄単板とが単板側接着剤により接合一体化されていることを特徴とする化粧板。 The decorative board according to claim 1,
A decorative board, wherein the adhesive layer and the wood thin veneer are joined and integrated by a veneer side adhesive.
上記単板側接着剤の木質薄単板への染み上がりが、該木質薄単板の厚みの50%以下とされていることを特徴とする化粧板。 The decorative board according to claim 2,
A decorative board, characterized in that the above-mentioned single board side adhesive has a stain of 50% or less of the thickness of the wood thin single board.
上記木質薄単板の表面に、単板側接着剤の該木質薄単板裏面からの染み上がり部分に到る深さまでショットブラスト法による浮造り加工が施されていることを特徴とする化粧板。 The decorative board according to claim 2 or 3,
A decorative board characterized in that the surface of the wood thin veneer is subjected to a float blasting process by a shot blasting method to a depth reaching a portion where the veneer side adhesive penetrates from the back surface of the wood thin veneer. .
上記基材側接着剤を半硬化させて接着層を形成する接着層形成工程と、
上記接着層上に単板側接着剤を塗布する単板側接着剤塗布工程と、
上記単板側接着剤が塗布された接着層上に木質薄単板を積層して積層体を得る積層工程と、
上記積層体を熱圧プレスして積層一体化することで、上記接着層の厚みが30μm以上でかつ75μm以下であるとともに該接着層の硬度がタイプAデュロメーターで30°以下となる化粧基材を得る熱圧プレス工程と、
上記化粧基材の表面に化粧加工を行う化粧加工工程とを含むことを特徴とする化粧板の製造方法。 A base material side adhesive applying step of applying a base material side adhesive having elasticity in a cured state to the surface of a wooden base material having a hard surface at least;
An adhesive layer forming step of semi-curing the base material side adhesive to form an adhesive layer;
A single plate side adhesive application step of applying a single plate side adhesive on the adhesive layer;
A laminating step of laminating a thin wood veneer on the adhesive layer to which the veneer side adhesive is applied;
A decorative base material in which the thickness of the adhesive layer is 30 μm or more and 75 μm or less and the hardness of the adhesive layer is 30 ° or less with a type A durometer by hot-pressing the laminated body and integrating the layers. A hot pressing process to obtain;
A method for producing a decorative board, comprising: a cosmetic processing step of performing cosmetic processing on the surface of the decorative base material.
上記単板側接着剤塗布工程の後に、上記単板側接着剤を半硬化させる半硬化工程をさらに含むことを特徴とする化粧板の製造方法。 In the manufacturing method of the decorative board of Claim 5,
The method for producing a decorative board, further comprising a semi-curing step of semi-curing the single-plate side adhesive after the single-plate side adhesive applying step.
上記基材側接着剤上に、該基材側接着剤よりも低粘度である単板側接着剤を塗布手段が接触しないように塗布する単板側接着剤塗布工程と、
上記基材側接着剤及び単板側接着剤を半硬化させる半硬化工程と、
上記単板側接着剤上に木質薄単板を積層して積層体を得る積層工程と、
上記積層体を熱圧プレスして積層一体化することで、上記基材側接着剤で構成された接着層の厚みが30μm以上でかつ75μm以下であるとともに該接着層の硬度がタイプAデュロメーターで30°以下となる化粧基材を得る熱圧プレス工程と、
上記化粧基材の表面に化粧加工を行う化粧加工工程とを含むことを特徴とする化粧板の製造方法。 A base material side adhesive application step of applying a base material side adhesive having elasticity in a cured state to the surface of a wooden base material having a hard surface at least;
On the substrate side adhesive, a single plate side adhesive application step for applying a single plate side adhesive having a lower viscosity than the base material side adhesive so that the application means does not come in contact with it,
A semi-curing step of semi-curing the base material side adhesive and the veneer side adhesive;
A laminating step of laminating a thin wood veneer on the veneer side adhesive to obtain a laminate;
The thickness of the adhesive layer composed of the base material side adhesive is 30 μm or more and 75 μm or less and the hardness of the adhesive layer is a type A durometer by hot pressing the laminate and integrating the laminates. A hot-pressing step for obtaining a decorative substrate of 30 ° or less;
A method for producing a decorative board, comprising: a cosmetic processing step of performing cosmetic processing on the surface of the decorative base material.
上記熱圧プレス工程の後、ショットブラスト法により、上記木質薄単板の表面に上記単板側接着剤の木質薄単板裏面からの染み上がり部分に到る深さまで浮造り加工を施す浮造り加工工程をさらに含むことを特徴とする化粧板の製造方法。 In the manufacturing method of the decorative board of any one of Claim 5 to 7,
After the hot-pressing process, the float is made by shot blasting to the surface of the wood thin veneer up to the depth that reaches the part of the wood veneer from the back of the wood thin veneer. A method for producing a decorative board, further comprising a processing step.
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