JP4719364B2 - Pack cosmetic - Google Patents

Description

【００２９】
参考例２
表２に示す色素について、水及びスクワランに対する０．０１重量％の溶解性を調べた。○が溶解し、×が溶解しないことを示す。
【００３０】
【表２】

【００３１】
実施例１
（成分） （重量％）
（１）多孔性ビニル系ポリマー ２５．２５
（特開昭63-316715号の合成例１）
（２）青色１号 ０．００５
（３）グリセリン ２５．８０
（４）ポリアクリル酸ナトリウム ５．５０
（５）ポリアクリル酸 ０．５０
（６）乾燥水酸化アルミニウムゲル ０．４０
（７）海藻エキス １．１０
（８）ハマメリス抽出液 ０．０１
（９）アルテアエキス １．００
（10）アスナロ抽出液 ０．５０
（11）グリチルリチン酸ジカリウム ０．２０
（12）メチルパラベン ０．１０
（13）無臭メントール ０．０５
（14）エタノール ０．２７５
（15）精製水 バランス
【００３２】
（製法）
ニーダーを用いて成分（３）に成分（４）、（５）及び（６）を均一に分散させ、これに成分（２）、（７）〜（１２）及び（１５）を添加して均一に練合した。次に成分（１３）、（１４）を添加して均一に練合した。更に成分（１）を加えて均一に練合して、化粧料を得た。この化粧料をポリエステルフィルム上に均一に塗工し（厚さ０．５mm）、ポリエステル製不織布を被せてシート状に整形した。
【００３３】
実施例２
実施例１において、青色１号の代わりに、紫色４０１号を用いる以外は同様にして、シート状パック化粧料を製造した。
【００３４】
実施例３
（成分） （重量％）
（１）多孔性ビニル系ポリマー ２５．０
（特開昭63-316715号の合成例１）
（２）青色１号 ０．００５
（３）ポリビニルアルコール １２．０
（４）ポリオキシエチレン硬化ヒマシ油 １．０
（エチレンオキサイド４０モル付加）
（５）１−イソステアロイル−３−ミリストイルグリセロール １．０
（６）グリセリン ５．０
（７）メチルパラベン ０．１０
（８）エタノール ７．００
（９）精製水 バランス
【００３５】
（製法）
上記組成の成分を、攪拌、混合することにより、ピールオフタイプのパック化粧料を製造した。
【００３６】
比較例１
実施例１において、青色１号を除いた以外は同様にして、シート状パック化粧料を製造した。
【００３７】
比較例２
実施例１において、多孔性ビニル系ポリマーの配合量を５．０重量％に代える以外は同様にして、シート状パック化粧料を製造した。
【００３８】
比較例３
実施例３において、青色１号を除いた以外は同様にして、ピールオフタイプのパック化粧料を製造した。
【００３９】
試験例１
前記実施例１及び比較例で得られた化粧料について、これを使用したときの脂っぽさの改善効果、化粧崩れ防止効果、化粧料の色の変化及び効果感を評価した。結果を表３に示す。
【００４０】
（評価方法）
（１）脂っぽさの改善効果、化粧崩れ防止効果：
女性パネラー１０名により、実施例１、実施例２、比較例１及び比較例２のシート状パック化粧料を顔に貼付し、６時間経過した後、剥離した。また、実施例３、比較例３のピールオフタイプのパック化粧料を顔に塗布し、３０分間乾燥後、剥離した。使用後の脂っぽさの改善効果及び化粧崩れ防止効果を官能評価し、以下の基準で判定した。
○；７名以上が「効果がある」と評価した。
△；４〜６名が「効果がある」と評価した。
×；３名以下が「効果がある」と評価した。
（２）パック化粧料の色の変化
使用後に剥離したパック化粧料を目視観察し、貼付していた面のシートの色が部分的な消失により変化していれば○、していなければ×と評価した。
（３）効果感
（１）と同様に、女性パネラー１０名により、使用後顔面から剥離してパック化粧料を観察し、皮脂が取れた効果を実感した度合いを評価し、以下の基準で判定した。 ○；７名以上が「効果が実感できる」と評価した。
△；４〜６名が「効果が実感できる」と評価した。
×；３名以下が「効果が実感できる」と評価した。
【００４１】
【表３】

【００４２】
実施例１〜３のパック化粧料は、いずれも脂っぽさの改善、化粧崩れ防止の効果に優れ、パック化粧料の色の変化が明確に認められ、効果感も実感も伴い良好であった。
【００４３】
【発明の効果】
本発明のパック化粧料は、皮脂を好適に吸収することができ、皮脂の脂っぽさや、化粧崩れを改善・防止する効果に優れ、しかも使用性が良好でかつ、使用者に皮脂が確実に取れたという効果の実感を与えるものである。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a pack cosmetic that is used by being applied to or applied to the skin such as the face, can absorb sebum, and changes color with the absorption of sebum.
[0002]
[Prior art]
A thin sebum film is formed on the skin surface of the skin, which prevents the entry of foreign substances from the outside world, protects the skin from irritation of various substances, and suppresses moisture transpiration and lubricates the skin surface. have. On the other hand, if the sebum is excessive, it causes stickiness, lightness, makeup loss, and seborrheic diseases such as acne.
As a method for removing excessive sebum on the skin surface of the skin, there is a method using a degreased paper, which is a good first-aid measure, but has a problem in that the amount of sebum absorption is not sufficient. Further, for example, a pack containing lipophilic titanium dioxide or lipophilic silicon dioxide (Japanese Patent Laid-Open No. 57-112314), and a cosmetic containing barley stone powder having a median particle size of 5 to 15 μm (Japanese Patent Laid-Open No. 9-9 263528) and the like have been proposed, but the usability and sebum absorption ability are not sufficient, and the actual feeling that sebum has been absorbed is lacking even when compared with the above-mentioned degreased paper.
[0003]
On the other hand, in order to improve the actual feeling that sebum has been absorbed, for example, in a degreased paper, a technique (Japanese Patent Laid-Open No. 10-298030) has been proposed in which the pattern disappears or becomes clear when the sebum is absorbed. It is not widely applicable to pack cosmetics in the form.
[Problems to be solved by the invention]
[0004]
The object of the present invention is that sebum can be suitably absorbed, is excellent in the effect of improving and preventing sebum greasy and makeup loss, and has good usability, and the user can remove sebum. It is to provide a pack cosmetic that can realize the effect.
[0005]
[Means for Solving the Problems]
The present inventor is a pack cosmetic containing a specific oil-absorbing powder and a water-soluble pigment, can suitably absorb sebum, and is excellent in the effect of improving / preventing the greasyness of sebum and makeup loss, Moreover, it has been found that when the color of the part that has absorbed sebum changes during use, the user can feel the effect that the sebum has been reliably removed.
[0006]
The present invention provides a pack cosmetic containing oil-absorbing powder and changing the color of the part that has absorbed sebum.
The present invention also includes the following components (A) and (B):
(A) an oil-absorbing powder having an absorption amount of squalane of 1 mL / g or more,
(B) A pack cosmetic containing a water-soluble pigment is provided.
[0007]
The pack cosmetic containing the oil-absorbing powder and the water-soluble pigment of the present invention is used after being applied or applied to the skin. At this time, the oil-absorbing powder in the pack cosmetic has a stronger affinity for the oily sebum than the water-soluble pigment and the solvent such as water in which the water-soluble dye is dissolved. It is presumed that it is taken into the surroundings and the interior, and in turn, an aqueous component, that is, a water-soluble dye and a solvent such as water dissolving the same are released. For this reason, the pack cosmetic of the present invention is changed by the disappearance of the color of the pack cosmetic that has absorbed sebum after use, particularly the part corresponding to the position of the pores that secrete a large amount of sebum. The user can visually confirm the sebum removal effect very well.
[0008]
DETAILED DESCRIPTION OF THE INVENTION
Examples of the oil-absorbing powder used in the present invention include those in which sebum is sufficiently absorbed and the color change is clear, and the amount of squalane absorbed is 1 mL / g or more, preferably 1.5 mL. / G or more.
Here, the amount of squalane absorbed is a value measured in accordance with the method for measuring the amount of oil absorption of pigment defined in JIS K 5101 (1978). That is, 1 g of powder is taken on a glass plate, kneaded with a spatula while dripping squalane little by little, and when the powder is entirely pasty, the end point is the amount of squalane at that time (mL) Is the oil absorption (mL / g).
[0009]
Examples of such oil-absorbing powders include vinyl polymers obtained by polymerizing one or more monomers such as vinyl acetate, N-vinyl pyrrolidone, methacrylic acid ester, acrylic acid ester, styrene, divinylbenzene, nylon, Silicic anhydride etc. are mentioned. These are preferably porous powders, and can be made porous by an ordinary method to adjust the amount of squalane absorbed.
Of these, hydrophobic oil-absorbing powders such as vinyl polymers and nylon are preferred because the oil-absorbing ability is not lowered by water or sweat.
[0010]
The vinyl polymer is preferably a porous hydrophobic polymer obtained by polymerizing one or more vinyl monomers having a solubility parameter of 7 to 10. Examples of vinyl monomers having a solubility parameter of 7 to 10 include esters of (meth) acrylic acid and higher alcohols having 8 to 24 carbon atoms, styrene or styrene derivatives having a hydrocarbon substituent having 1 to 12 carbon atoms, and the number of carbon atoms. Examples thereof include vinyl esters of 8 to 20 saturated carboxylic acids, (meth) acrylic acid, and diolefins having 4 to 6 carbon atoms. When a monomer having a solubility parameter of 7 to 10 is used, the compatibility with sebum is excellent, and a higher sebum absorption ability is obtained.
The oil-absorbing powder preferably swells with sebum but does not dissolve, so that it is preferably crosslinked. Crosslinking can be performed by a method of adding a polyfunctional monomer during polymerization, post-crosslinking, self-crosslinking, or the like. Examples of the polyfunctional monomer include divinylbenzene, divinylpyridine, ethylene glycol di (meth) acrylate, triethylene glycol di (meth) acrylate, and the like.
[0011]
The vinyl monomer can be polymerized and made porous according to, for example, the method described in JP-A-63-331615. The monomer is dissolved in a non-polymerizable organic solvent, and this solution is suspended in water. Polymerization is preferably performed in a dispersed or emulsified state, and after completion of the polymerization, the organic solvent is preferably removed.
[0012]
Commercially available products of such oil-absorbing powder include porous nylon powders such as Organazole 2002 (manufactured by Elf Autochem); dimethyl silicone cross-linked elastomers such as Trefil E-506C (manufactured by Toray Dow Corning); Microsphere M Polymethylmethacrylate such as Microsphere M-100, Microsphere M-300, Microsphere M-400, Microsphere R-109 (manufactured by Matsumoto Yushi Co., Ltd.); Copolymerization of methacrylate such as polytrap (manufactured by Dow Corning) Examples include coalescence.
[0013]
As the oil-absorbing powder, those having an average particle diameter measured by a laser diffraction / scattering method of 0.005 to 30 μm, particularly 0.005 to 20 μm are preferable. Moreover, it is preferable that the particle | grains with a particle size of 0.005-30 micrometers are 90 weight% or more among oil absorption powder.
[0014]
Two or more kinds of oil-absorbing powder can be used, and it is preferably contained in the total composition in an amount of 10 to 60% by weight, particularly preferably 15 to 40% by weight. Within this range, sebum can be sufficiently absorbed, and uniform kneading is preferred.
Moreover, it is preferable that the hydrophobic oil-absorbing powder as described above is contained in the total composition in an amount of 5% by weight or more, particularly 10 to 40% by weight.
[0015]
The dye used in the present invention may be water-soluble and does not color or stain the component (A) oil-absorbing powder. The necessary water solubility may be a pigment having the following solubility in water and oil. That is, it has a solubility of 0.01% by weight or more, which is generally sufficient for color development, while it has a solubility of less than 0.01% by weight as a typical oil in squalane. That is, a dye that does not exhibit a uniform color even when 0.01% by weight of the dye is added to squalane and causes precipitation or separation of the dye is used.
[0016]
Examples of such water-soluble pigments of component (B) are legal pigments that are recognized as cosmetics and are water-soluble Blue No. 1 (CI 42090) and Blue No. 2 (C.I. .73015), Blue No. 202 (C.I. 42052), Blue No. 203 (C.I. 42052), Blue No. 205 (C.I. 42090), Red No. 2 (C.I. 16185), Red 3 No. (CI. 45430), Red No. 102 (C.I. 16255), Red No. 104 (C.I. 45410), Red No. 105 (C.I. 45440), Red No. 106 (C.I. 45100), Red 201 (C.I. 15850), Red 213 (C.I. 45170), Red 214 (C.I. 45170), Red 227 (C.I. 17200), Red 228 (C.I. 12085), Color 230 (C.I. 45380), Red 231 (C.I. 45410), Red 232 (C.I. 45440), Red 401 (C.I. 45190), Red 502 (C.I. I.16155), red 504 (C.I. 14700), red 506 (C.I. 15620), yellow 4 (C.I. 19140), yellow 5 (C.I. 15985), yellow 202 (C.I. 45350), Yellow 203 (C.I. 47005), Yellow 402 (C.I. 18950), Yellow 403 (C.I. 10316), Yellow 406 (C.I 13065), yellow 407 (C.I. 18820), green 3 (C.I. 42053), green 201 (C.I. 61570), green 204 (C.I. 59040), green 205 No. (C.I. 4209 ), Green 401 (C.I. 10020), green 402 (C.I. 42085), orange color 205 (C.I. 15510), orange color 207 (C.I. 45425), orange color No. 402 (C.I. 14600), brown 201 (C.I. 20170), purple 401 (C.I. 60730), black 401 (C.I. 20470), etc. Flavin (such as riboflavin), quinone (such as lacaic acid, carminic acid (costule), and kermesic acid), betacyanin (such as betanin), and flavonoid (such as safrole yellow, shisonin, and rutin).
[0017]
The water-soluble pigment is 0.000001 to 1% by weight, particularly 0.0001 to 0.1% by weight in the total composition because it is easy to confirm that the sebum has been removed from the skin due to the change in color accompanying sebum absorption. % Content is preferable.
[0018]
The pack cosmetic of the present invention is used by being applied to or applied to the skin such as the face, and the dosage form is, for example, a pack cosmetic such as a clay pack that is applied and washed away after absorbing sebum, and dried after application and sebum Peel-off type pack cosmetics that absorb and peel off, sheet-like packs that remove sebum at the same time as sebum at the time of peeling, and sheet-like pack cosmetics that absorb and remove sebum after application. In particular, it is preferable to use a sheet-shaped pack cosmetic from the viewpoint of the effect that the oil-absorbing effect can be clearly recognized by the color change.
[0019]
In order to make the pack cosmetic of the present invention into a sheet-shaped pack cosmetic, it is preferable to use a hydrogel comprising component (C) a water-soluble polymer and a crosslinking agent.
[0020]
Examples of the water-soluble polymer include polyacrylic acid, polymethacrylic acid, alginate, starch, agar, gelatin, pectin, casein, polyvinyl alcohol, polyvinyl pyrrolidone, polyethylene oxide and the like.
Two or more kinds of these water-soluble polymers can be used, and it is preferable to contain 1 to 30% by weight, particularly 2 to 15% by weight in the total composition.
In order to form a hydrous gel, examples of the water-soluble polymer crosslinking agent include water-soluble salts such as calcium chloride, aluminum chloride, potassium alum, and aluminum sulfate, and calcium hydroxide, aluminum hydroxide, calcium carbonate, and calcium phosphate. And polyvalent metal salts such as poorly water-soluble or slightly water-soluble salts such as aluminum stearate and calcium citrate.
These crosslinking agents are preferably blended in an amount of 0.01 to 5 equivalents, particularly 0.1 to 2 equivalents, relative to the crosslinking point of the water-soluble polymer.
[0021]
The sheet-shaped pack cosmetic is, for example, impregnated or coated on a base fabric with a composition obtained by mixing the components (A), (B), (C) and other components used as appropriate. It can manufacture by shape | molding to a polyethylene film, and can further face a polyethylene film etc. as needed. Moreover, it can manufacture also by cutting the raw material obtained by apply | coating a composition on the film for facing and covering a base fabric etc. to a predetermined dimension.
[0022]
Examples of the base fabric include knitted fabrics such as flanks and sufumos, woven fabrics; nonwoven fabrics such as felts and spunlaces; papers and plastic sheets.
The thickness of the base fabric is 0.1 to 1.0 mm, particularly 0.1 to 0.5 mm, and the coating thickness of the composition is 0.1 to 1.0 mm, particularly 0.1 to 0.5 mm. preferable. The overall thickness is preferably 0.1 to 2.0 mm, particularly preferably 0.1 to 1.0 mm.
The shape and size of the sheet can be any of, for example, covering the entire face or partially pasting and using.
[0023]
When the pack cosmetic of the present invention is a peel-off type pack cosmetic, the component (D) film-forming water-soluble polymer is used.
Examples of film-forming water-soluble polymers include synthetic polymers such as polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl acetate, poly (meth) acrylic acid ester, polystyrene, polyalkylene oxide, and silicone, and natural systems such as cellulose, starch, and proteins. Polymers can be used.
[0024]
Two or more kinds of film-forming water-soluble polymers can be used, and the total composition preferably contains 0.01 to 70% by weight, particularly 5 to 40% by weight.
The peel-off type pack cosmetic is produced, for example, by mixing the components (A), (B), (D) and other components used as appropriate according to a conventional method.
[0025]
Examples of the components used as appropriate here include solid / semi-solid oil, fluid oil, hydrocarbon, higher alcohol, higher fatty acid, esters, silicones, lower alcohol, polyhydric alcohol, saccharides, amino acids, vitamins, Organic amines, synthetic resin emulsions, surfactants, humectants, thickeners, pH adjusters, antibacterial agents, flame retardants, antioxidants, fragrances, water and the like can be mentioned.
[0026]
The pack cosmetic of the present invention is used, for example, after being stuck or applied to the face, left for about 15 minutes to 10 hours, and then peeled off or washed away. For example, it is possible to apply a method in which a sheet-shaped pack cosmetic is attached before going to bed and peeled off after waking up.
When sebum is absorbed by the oil-absorbing powder in the pack cosmetic applied or applied, the color of the part changes (for example, the color disappears and gradually becomes white). Recognize and feel the degree of removal of sebum.
[0027]
【Example】
Reference example 1
With respect to the oil-absorbing powder shown in Table 1, the amount of squalane absorbed was measured by a method according to the JIS K 5101 method. In addition, the average particle size of the powder was determined using a laser diffraction / scattering particle size distribution analyzer manufactured by Horiba.
[0028]
[Table 1]

[0029]
Reference example 2
About the pigment | dye shown in Table 2, the solubility of 0.01 weight% with respect to water and squalane was investigated. ○ indicates that it is dissolved, and × indicates that it does not dissolve.
[0030]
[Table 2]

[0031]
Example 1
(Ingredient) (wt%)
(1) Porous vinyl polymer 25.25
(Synthesis Example 1 of JP-A-63-316715)
(2) Blue No. 1 0.005
(3) Glycerin 25.80
(4) Sodium polyacrylate 5.50
(5) Polyacrylic acid 0.50
(6) Dry aluminum hydroxide gel 0.40
(7) Seaweed extract 1.10
(8) Hamelis extract 0.01
(9) Altea extract 1.00
(10) Asunaro extract 0.50
(11) Dipotassium glycyrrhizinate 0.20
(12) Methylparaben 0.10
(13) Odorless menthol 0.05
(14) Ethanol 0.275
(15) Purified water balance [0032]
(Manufacturing method)
Components (4), (5) and (6) are uniformly dispersed in component (3) using a kneader, and components (2), (7) to (12) and (15) are added uniformly to this. Kneaded into. Next, components (13) and (14) were added and kneaded uniformly. Furthermore, component (1) was added and kneaded uniformly to obtain a cosmetic. This cosmetic was uniformly coated on a polyester film (thickness 0.5 mm) and covered with a non-woven fabric made of polyester and shaped into a sheet.
[0033]
Example 2
A sheet-shaped pack cosmetic was produced in the same manner as in Example 1 except that purple 401 was used instead of blue 1.
[0034]
Example 3
(Ingredient) (wt%)
(1) Porous vinyl polymer 25.0
(Synthesis Example 1 of JP-A-63-316715)
(2) Blue No. 1 0.005
(3) Polyvinyl alcohol 12.0
(4) Polyoxyethylene hydrogenated castor oil 1.0
(40 mol addition of ethylene oxide)
(5) 1-isostearoyl-3-myristoylglycerol 1.0
(6) Glycerin 5.0
(7) Methylparaben 0.10
(8) Ethanol 7.00
(9) Purified water balance [0035]
(Manufacturing method)
Peel-off type pack cosmetics were produced by stirring and mixing the components having the above composition.
[0036]
Comparative Example 1
A sheet-shaped pack cosmetic was produced in the same manner as in Example 1 except that Blue No. 1 was omitted.
[0037]
Comparative Example 2
A sheet-shaped pack cosmetic was produced in the same manner as in Example 1, except that the amount of the porous vinyl polymer was changed to 5.0% by weight.
[0038]
Comparative Example 3
In Example 3, a peel-off type pack cosmetic was manufactured in the same manner except that Blue No. 1 was removed.
[0039]
Test example 1
The cosmetics obtained in Example 1 and Comparative Example were evaluated for the effect of improving greasyness, the effect of preventing makeup collapse, the color change of the cosmetics, and the feeling of effectiveness when using the cosmetics. The results are shown in Table 3.
[0040]
(Evaluation methods)
(1) The effect of improving greasyness, the effect of preventing makeup collapse:
The sheet-shaped pack cosmetics of Example 1, Example 2, Comparative Example 1 and Comparative Example 2 were applied to the face by 10 female panelists, and after 6 hours, they were peeled off. Moreover, the peel-off type pack cosmetics of Example 3 and Comparative Example 3 were applied to the face, dried for 30 minutes, and then peeled off. Sensory evaluation of the effect of improving greasyness after use and the effect of preventing makeup collapse was made and judged according to the following criteria.
○: Seven or more people evaluated it as “effective”.
(Triangle | delta); 4-6 persons evaluated that it was "effective."
X: Three or less people evaluated it as "effective".
(2) Change in color of pack cosmetics When the pack cosmetic peeled after use is visually observed, ○ if the color of the sheet on the attached surface has changed due to partial disappearance, and x otherwise. evaluated.
(3) Like the effect (1), 10 female panelists peeled from the face after use, observed the pack cosmetics, evaluated the degree of feeling that the sebum was removed, and judged according to the following criteria did. ○: Seven or more people evaluated that “the effect can be realized”.
(Triangle | delta); 4-6 persons evaluated that "the effect can be actually felt."
X: Three or less persons evaluated that "the effect is realizable".
[0041]
[Table 3]

[0042]
Each of the pack cosmetics of Examples 1 to 3 was excellent in the effect of improving greasy and preventing makeup collapse, the color change of the pack cosmetic was clearly recognized, and both the effect and the feeling were good. It was.
[0043]
【The invention's effect】
The pack cosmetic of the present invention can absorb sebum suitably, is excellent in the effect of improving and preventing the sebum's greasyness and makeup collapse, has good usability, and ensures sebum to the user. It gives a real sense of the effect of being removed.

Claims (3)

The following components (A), (B) and (C):
(A) Esters of (meth) acrylic acid and higher alcohols having 8 to 24 carbon atoms, styrene, styrene derivatives having a hydrocarbon substituent having 1 to 12 carbon atoms, vinyl esters of saturated carboxylic acids having 8 to 20 carbon atoms A porous vinyl polymer obtained by polymerizing a vinyl monomer selected from (meth) acrylic acid and a diolefin having 4 to 6 carbon atoms and having a mean particle size of 0. 10 to 60% by weight of a porous oil-absorbing powder having 0.005 to 30 μm and an absorption amount of squalane of 1 to 3.35 mL / g ,
(B) Water-soluble dye 0.000001 to 1% by weight,
(C) A pack cosmetic containing a hydrogel comprising a water-soluble polymer and a crosslinking agent. The following components (A), (B) and (D):
(A) Esters of (meth) acrylic acid and higher alcohols having 8 to 24 carbon atoms, styrene, styrene derivatives having a hydrocarbon substituent having 1 to 12 carbon atoms, vinyl esters of saturated carboxylic acids having 8 to 20 carbon atoms A porous vinyl polymer obtained by polymerizing a vinyl monomer selected from (meth) acrylic acid and a diolefin having 4 to 6 carbon atoms and having a mean particle size of 0. 10 to 60% by weight of a porous oil-absorbing powder having 0.005 to 30 μm and an absorption amount of squalane of 1 to 3.35 mL / g ,
(B) Water-soluble dye 0.000001 to 1% by weight,
(D) Film-forming water-soluble polymer 0.01 to 70% by weight
Pack cosmetic containing. The pack cosmetic according to claim 1 or 2 , wherein the polyfunctional monomer is selected from divinylbenzene, divinylpyridine, ethylene glycol di (meth) acrylate and triethylene glycol di (meth) acrylate.