JP4797601B2 - High strength hot dip galvanized steel sheet manufacturing method and hot dip galvanized steel sheet manufacturing equipment - Google Patents

Description

  The present invention relates to a method for manufacturing a high-strength hot-dip galvanized steel sheet that is manufactured by performing hot-dip galvanization after heat treatment in an annealing furnace having a direct-fire heating type direct-fire zone and a reduction zone. Moreover, this invention relates to the manufacturing equipment of the hot dip galvanized steel plate suitable for manufacture of a high strength steel plate.

  Since steel plates are inexpensive metal materials, they are widely used in fields such as automobiles, home appliances, and building materials. In recent years, in the automobile industry, in addition to improving durability, the weight of automobiles has been reduced from the viewpoint of improving fuel efficiency and reducing exhaust gas, and the use of high-strength hot-dip galvanized steel sheets has increased rapidly. A high-strength hot-dip galvanized steel sheet is usually manufactured using continuous hot-dip galvanizing equipment, with Si, Mn, etc. added as elements in the steel. When a hot dip galvanizing is performed after annealing a steel sheet to which a large amount of Si and Mn are added using a continuous hot dip galvanizing facility, there is a problem in that plating defects occur due to Si and Mn oxides on the steel sheet surface. To solve this problem, after forming an Fe oxide film thicker than the oxide film normally formed of a steel sheet on the surface of the steel sheet, for example, an oxide film having a thickness of about 0.01 to 1 μm, and then reducing the Fe oxide film Hot dip galvanizing is effective.

  For example, in Patent Document 1, as a method of reducing the thickness of the Fe oxide film formed after forming an appropriate Fe oxide film on the steel sheet surface, a continuous hot dip galvanizing facility having no oxidation furnace is used, and a reduction furnace is provided. Divide into two or more zones to adjust the dew point of each zone. That is, in the first zone, water vapor is introduced into the furnace to adjust the dew point to form an appropriate Fe oxide film on the steel plate surface, and then in the second zone A method is described in which the dew point is adjusted to reduce the oxide film.

  Further, Patent Document 2 describes that a method using direct flame reduction is effective as a method for generating an oxide film. Further, Patent Document 3 shows that hot-dip galvanization can be performed on a high-strength steel sheet to which Si or Mn is added in a larger amount than Patent Document 1 if direct fire reduction is used. Here, the direct fire reduction is a method of reducing the steel plate surface after oxidizing the steel plate surface using a direct fire heating type direct flame.

FIG. 1 shows an essential part of a hot- dip galvanized steel sheet manufacturing facility in which an oxide film is generated by using direct-fire reduction in a direct-fire heating type direct-fire zone, and then this oxide film is reduced and then galvanized. It is a schematic side view which shows a structural example.

  In FIG. 1, 1 is a steel plate, 2 is a direct-fire heating type direct-fire zone (hereinafter also simply referred to as “direct-fire heating zone”), 3 is a reduction zone (a vertical reduction zone), 4 is a cooling zone, 5 is a snout, 6 is a hot dipping bath, and 7 is a gas wiping device. The direct fire heating zone 2 and the vertical reduction zone 3 are connected. The hot dip plating tank 6 holds hot galvanized metal.

  The direct-fired heating zone is (A) fast heating rate, (B) even if the steel plate temperature is low, the combustion gas temperature is high, and the radicals in the combustion gas reach the steel plate and participate in the reaction with the steel plate, so the reaction rate However, there is a feature that if the air ratio is high and the air ratio is high, the oxide film is formed earlier, and if a direct flame reduction zone is provided in which the air ratio is low and reduction is performed quickly, reduction can be performed. The fact that the oxidation is fast has an advantage that the formation of the Fe oxide can be advanced faster than the oxidizable elements such as Si and Mn are preferentially oxidized in the case of heating other than an open flame.

  The direct fire heating zone is divided into a plurality of heating zones, and a direct fire heating burner 103 is disposed in each heating zone, and fuel gas is supplied from the fuel supply system 101 and combustion air is supplied from the air supply system 102. The fuel gas flow rate, the combustion air flow rate, and the flow rate ratio of each heating zone can be controlled independently.

  The reduction zone 3 is provided with a plurality of in-furnace rolls arranged at a predetermined height at the upper and lower portions in the furnace. The steel plate 1 traveling in the reduction zone 3 has a plurality of vertical paths that are supported by the upper furnace roll and the lower furnace roll and travel in the vertical direction. The radial tube burner 8 faces the steel sheet between the vertical paths. Is arranged.

  A steel sheet fed from a steel sheet feeding device (not shown) is directly heated using a fuel gas in the direct fire heating zone 2 to remove the rolling oil on the steel sheet surface, and Fe oxide (oxide film on the steel sheet surface). ).

  The front stage of the direct fire heating zone heats the steel sheet by increasing the air ratio, forms an oxide film on the surface of the steel sheet, and then the latter stage of the direct fire heating zone (hereinafter also referred to as the direct fire reduction zone). The oxide film formed in the previous stage is reduced by lowering the air ratio. Since the reduction is insufficient only with the direct reduction zone, the oxide film is further reduced in the next reduction zone.

  Next, the steel plate is passed through the reduction zone 3. Usually, as a reducing gas, a mixed gas of hydrogen and nitrogen having a hydrogen concentration of several percent to several tens of percent (vol%) is supplied from a gas supply pipe 105 to a plurality of locations in the cooling zone 4 and the reducing zone 3 and supplied. The gas flows to the inlet side of the reduction zone 3 and flows out to the direct flame heating zone 2 through the connecting portion 9 of the direct flame heating zone 2 and the reduction zone 3. By this gas, the atmosphere of the reduction zone 3 is maintained in a reducing property. The steel plate is heated and annealed at a predetermined temperature for a predetermined time by the high-temperature radiant tube 8 while the reduction zone 3 is passed through, and at the same time, the oxide film on the surface of the steel plate is reduced. The progress of the reduction is determined by the temperature pattern in the furnace, the feeding speed, the hydrogen concentration of the furnace gas, and the supply amount. Appropriate conditions are set so that the reduction of the steel sheet is completed in the reduction zone. The reducing gas supplied to the reduction zone 3 flows to the direct flame heating zone 2 through the connecting portion 9 between the reduction zone 3 and the direct flame heating zone 2.

The steel plate 1 with the oxide film reduced is adjusted to a steel plate temperature suitable for being immersed in the hot dipping bath 6 in the cooling zone 4, and then dipped in the hot dipping bath 6, pulled up from the hot dipping bath 6, and gas. The wiping device 7 is adjusted to a required plating adhesion amount, further subjected to spangle adjustment or alloying treatment, and then cooled, or cooled without being subjected to the above treatment, to obtain a required hot dip galvanized steel sheet.
Japanese Patent No. 3014529 Japanese Patent Laid-Open No. 5-195084 Japanese Patent No. 2530939

  When hot-dip galvanizing a steel sheet with high Si or Mn concentration, if the Fe-based oxide film formed in the direct flame heating zone is thickened and the formed Fe-based oxide film is sufficiently reduced in the next reduction step It should be possible to plate steel sheets with higher Si and Mn concentrations. However, if the oxide film is thick, the reduction of the Fe-based oxide film is insufficient in the reduction process, and stable and good plating cannot be obtained. There was a problem.

  An object of the present invention is to provide a high-strength hot-dip galvanized plate that can prevent the occurrence of poor plating properties when a high-strength hot-dip galvanized steel plate is manufactured by heat-annealing a steel plate having a high Si concentration and Mn concentration. It is providing the manufacturing method of a steel plate.

  Moreover, the subject of this invention is providing the manufacturing equipment of the hot dip galvanized steel plate suitable for manufacture of the high intensity | strength hot dip galvanized steel plate with high Si density | concentration and Mn density | concentration.

  The gist of the present invention for solving the above problems is as follows.

  (1) A steel sheet containing one or more of Si: 0.2 to 3% and Mn: 1 to 3% by mass% is heated in a direct flame heating type direct flame, and further reduced in a reduction zone. In the manufacturing method of high-strength hot-dip galvanized steel sheet, after reducing and annealing the surface in the atmosphere and then dipping in a hot-dip galvanizing bath and galvanizing, A method for producing a high-strength hot-dip galvanized steel sheet characterized by exhausting the gas inside.

  (2) In an annealing furnace having a direct-fired heating zone and a reduction zone, and a hot-dip galvanized steel plate equipped with a hot-dip galvanizing device downstream of the furnace, the connection between the direct-fire zone and the reduction zone or the vicinity thereof An apparatus for producing a hot dip galvanized steel sheet, characterized by having exhaust means for exhausting the gas in the furnace.

  According to the present invention, the high dew point gas in the reduction zone can be prevented from entering the direct fire reduction zone and / or the gas in the direct fire reduction zone can be prevented from entering the reduction zone. The reduction of the reduction capacity of the reduction zone is prevented, and the oxide film formed in the direct heating heating zone is reduced in the direct heating heating zone in the high-strength steel sheet with a large amount of Si and Mn added. It is possible to prevent the occurrence of defective plating during hot dip galvanizing.

  Embodiments of the present invention will be described below.

  FIG. 2 is a schematic side view for explaining the structure of the flue provided at the joint of the direct heating zone and the reduction zone of the hot dip galvanized steel sheet manufacturing equipment according to the embodiment of the present invention. It is provided in the connection part 9 of the direct heating heating zone 2 and the reduction zone 3 of the manufacturing equipment for hot dip galvanized steel sheet. The direct-fired heating zone is divided into a first-stage direct-fired heating zone whose main function is heating, and a second-stage direct-fired reducing zone whose main function is reduction.

  Sealing rolls 10 and 11 are provided at the connecting part 9 of the direct heating zone 2 and the reduction zone 3, and the furnace gas is sucked from the exhaust port 13 between the sealing rolls 10 and 11, and the sucked gas is discharged outside the furnace. A flue 12 for exhausting is provided, and a damper 14 for adjusting the gas flow rate exhausted in the middle of the flue 12 is provided.

  In the reduction zone 3, the steel sheet is heated by a radiant tube burner 8 arranged in a large number between the longitudinal paths of the steel sheet, and the reducing gas flowing from the exit side to the entry side of the reduction zone 3 causes the direct fire heating zone 2. The Fe oxide layer produced by heating is reduced.

The atmosphere of the direct fire reduction zone of the direct fire heating zone 2 is a combustion component of fuel gas after directly hitting the steel plate, and therefore contains a large amount of water and has a high dew point. In the conventional apparatus, since the direct fire heating zone and the reduction zone are merely connected, the gas with a high dew point after the direct fire reduction in the direct fire heating zone 2 enters the reduction zone 3 along with the steel plate 1. Since the furnace wall of the reduction zone has a structure like a large box containing a radiant tube inside, the gas flows freely in the reduction zone 3. The gas with a high dew point that has entered the reduction zone easily diffuses into the reduction zone 3 and reduces the reducing ability of the gas in the reduction zone 3. Therefore, in high-strength steel sheets to which a large amount of Si or Mn formed a thick Fe oxide film compared to normal steel sheets in the direct heating zone, this oxide film is not sufficiently reduced in the reduction zone, A plating failure occurred. In addition, in the conventional apparatus, the total amount of gas with a high dew point in the reduction zone flows into the direct flame reduction zone, so that the plate that has been reduced by direct flame is oxidized again, or the reduction capability of the direct flame reduction zone is hindered. There was a problem.

  In the apparatus according to the embodiment of the present invention, the connection part 9 of the direct-fire heating zone 2 and the reduction zone 3 is provided with an exhaust port 13 for exhausting the in-furnace gas. The high dew point gas flowing from the direct heating zone 2 accompanying the steel plate 1 is exhausted to the outside through the flue 12 from the exhaust port 13 so that the high dew point gas in the direct heating zone 2 is reduced. 3 and the high dew point gas in the reduction zone is prevented from entering the direct flame reduction zone, and the high dew point gas in the direct fire heating zone 2 enters the reduction zone 3 to reduce the reduction zone. This eliminates the problem of lowering the gas, and the problem that the gas having a high dew point in the reduction zone enters the direct flame reduction zone and the reduction capability is reduced. Further, since the atmospheric gas in the reducing zone 3 is discharged to the outside from the exhaust port 13 through the flue 12, the reducing gas flow from the outlet side to the inlet side is stably formed in the reducing zone 3, and in the reducing zone, Good reduction ability is secured. As a result, the oxide film of the high-strength steel sheet to which a large amount of Si or Mn is added in the reduction zone is sufficiently reduced, and no plating failure occurs during hot dip galvanization.

  The displacement is preferably adjusted so that there is no gas movement in the direct-fire heating zone 2 and the reduction zone 3. If the exhaust from the exhaust port 13 is too strong, the gas flow in the direct-fired heating zone 2 and the reduction zone 3 is disturbed, so the amount of gas exhausted outside the furnace by providing an exhaust amount adjusting means 14 such as a damper in the flue 12 It is preferable to be able to adjust.

  The present invention is directed to a steel sheet containing 0.2 to 3% Si and 1 to 3% Mn by mass%. The reason for limiting the steel component composition will be described.

Si: 0.2-3 mass%
If Si is less than 0.2%, the effect of improving the strength is small, and if it exceeds 3%, good plating properties cannot be ensured even by the method of the present invention.

Mn: 1-3 mass%
If Mn is less than 1%, the effect of improving the strength is small, and if it exceeds 3%, good plating properties cannot be ensured even by the method of the present invention.

  Steel components other than Si and Mn are not particularly limited. The thing of the component composition used for manufacture of a high strength steel plate can be used.

  In the apparatus of FIG. 1, the apparatus for manufacturing a hot dip galvanized steel sheet according to the embodiment of the present invention in which the connecting portion 9 of the direct heating zone 2 and the reduction zone 3 has the structure of FIG. 2 is used as follows. A high-strength hot-dip galvanized steel sheet is produced.

  A steel sheet having a composition defined by the present invention sent from a steel sheet feeding device not shown is set according to the steel composition composition and material standards by direct fire heating using a fuel gas in the direct fire heating zone 2. The heating temperature is raised to a predetermined temperature in accordance with the heat pattern, and at the same time, the rolling oil on the steel sheet surface is removed and an oxide film is formed on the steel sheet surface. In the direct-fired heating zone, the oxide film is operated so as to generate an amount capable of sufficiently securing the plating property by subsequent reduction. In the steel plate targeted by the present invention, the oxide film is preferably formed so that its thickness is 0.01 to 1 μm. Direct-fire heating suppresses the oxidation of easily oxidizable elements such as Si and Mn because Fe oxide is generated quickly. The operating conditions in the direct-fired heating zone are set to a higher temperature than the normal steel plate temperature in the direct-fired heating zone outlet side zone, and the amount of air used during combustion is higher than the theoretical air ratio. Combustion control is performed so that the oxygen partial pressure increases.

  Next, the steel plate is passed through the reduction zone 3. Usually, as a reducing gas, a mixed gas of hydrogen and nitrogen having a hydrogen concentration of several percent to several tens of percent (vol%) and a low dew point is supplied from the gas supply pipe 105 to a plurality of locations in the cooling zone 4 and the reduction zone 3. . By this gas, the atmosphere of the reduction zone 3 is maintained in a reducing property. While the steel sheet is passed through the reduction zone 3, the steel sheet is heat-annealed at a predetermined temperature and at a predetermined time by a high-temperature radiant tube burner 8 according to a heat pattern set in accordance with the steel sheet component composition and material standards. The oxide film on the steel sheet surface is reduced by the reducing atmosphere gas. The reduction is performed until the sufficiently generated Fe oxide is reduced as Fe. The reduction rate depends on the temperature of the reduction zone and the amount of hydrogen. Although the temperature of the reduction zone is determined by the annealing conditions, the annealing temperature cannot be changed greatly. Therefore, the adjustment of reduction is mainly the adjustment of the amount of hydrogen, specifically the flow rate of reducing gas supplied into the furnace and / or hydrogen gas. The concentration is adjusted to an appropriate condition.

  In addition, the gas in the furnace is discharged from the flue 12 provided in the connecting portion 9 of the direct fire heating zone 2 and the reduction zone 3. Exhaust of the gas in the furnace from the flue 12 not only prevents gas movement in the direct heating heating zone 2 and the reduction zone 3, but also prevents disturbance of the gas flow in the direct heating heating zone 2 and the reduction zone 3. It is preferable. From such a viewpoint, the gas flow rate exhausted from the flue 12 to the outside of the furnace is preferably 30% or more and 120% or less, more preferably 50% or more and 100% or less of the gas flow rate based on the reducing gas flow rate supplied into the furnace. preferable. Here, the lower limit is defined by the influence on the direct flame heating zone, and the upper limit is defined by preventing the gas in the direct flame heating zone from flowing backward.

  The steel plate 1 with the oxide film reduced is adjusted to a steel plate temperature suitable for immersing in the hot dipping bath 6 in the cooling zone 4 according to a conventional method, and is then dip plated in the hot dipping bath 6, from the hot dipping bath 6. The steel sheet is pulled up and adjusted to the required coating amount by the gas wiping device 7 and further cooled after being subjected to spangle adjustment or alloying treatment, or cooled without being subjected to the above-described treatment, to obtain a required hot-dip galvanized steel sheet. .

  In the hot-dip galvanized steel sheet produced above, the oxidation of easily oxidizable elements such as Si and Mn is suppressed in the direct flame heating zone 2 and the Fe oxide is sufficiently reduced in the reduction zone 3. Good plating properties are exhibited.

  In the above-described apparatus, the exhaust means for exhausting the gas in the furnace is provided at the connection portion between the direct fire zone and the reduction zone, but the exhaust means may be provided near the connection portion between the direct fire zone and the reduction zone. Further, although the reduction zone is a saddle type reduction zone, the reduction zone may be a horizontal type.

Steel composed of the composition shown in Table 1, the balance Fe and inevitable impurities was hot-rolled, pickled, and cold-rolled to prepare a plating original plate having a thickness of 1 mm and a width of 1 m. This steel plate is annealed in an annealing furnace equipped with a direct heat heating zone, a reduction zone, and a cooling zone, and provided with a gas exhaust mechanism having the structure shown in FIG. Hot dip galvanizing was performed, and the amount of plating adhered was adjusted to 40 g / m ² per side with a gas wiping apparatus. The direct fire heating zone includes a direct fire pre-tropical zone, a direct fire oxidation zone, and a direct fire reduction zone.

The manufacturing conditions are as follows.
・ Line speed: 80 mpm
・ Direct fire heating zone:
After preheating in the direct fire pre-tropical zone, the steel plate was directly heated and oxidized in the direct fire oxidation zone, and then directly reduced in the direct fire reduction zone so that the steel plate temperature was 600-630 ° C. after direct fire reduction. The air ratio in the direct fire oxidation zone was 1.30, and the air ratio in the direct fire reduction zone was 0.80.
・ Reduction zone:
Annealing conditions: Steel plate heating temperature was 800 ° C.
・ Hot galvanizing:
Bath temperature: 470 ° C
Atmosphere _{Gas: H 2: 8vol% -N 2} : 92vol% ( dew point: about -50 ° C.), flow rate 1000 Nm ³ / H
The appearance of the hot-dip galvanized steel sheet thus produced was visually observed and the presence or absence of non-plating was evaluated. The evaluation results are shown in Table 2.

  As shown in Table 2, by exhausting the gas from the connection portion of the direct heating heating zone and the reduction zone, the occurrence of non-plating is reduced compared to the conventional example in which the gas is not discharged from the connection portion. The effect is more excellent at 50% or more.

  The method for producing a high-strength hot-dip galvanized steel sheet according to the present invention is a method for producing a high-strength hot-dip galvanized steel sheet containing Si 0.2 to 3% and Mn 1 to 3% by mass% without causing poor plating properties. Can be used.

  The equipment for producing a hot-dip galvanized steel sheet of the present invention can be used as an apparatus for producing a high-strength hot-dip galvanized steel sheet containing 0.2 to 3% Si and 1 to 3% Mn by mass%.

It is a schematic side view which shows the principal part structural example of the manufacturing equipment of a hot dip galvanized steel plate. It is a schematic side view which shows the structure of the connection part of the direct-fired heating zone and reduction zone of the manufacturing equipment of the hot dip galvanized steel plate which concerns on embodiment of this invention.

Explanation of symbols

1 Steel plate 2 Direct flame heating type (direct flame heating zone)
3 Vertical type reduction zone (reduction zone)
4 Cooling zone 5 Snout 6 Hot dipping bath 7 Gas wiping device 8 Radiant tube burner 9 Direct heating heating zone and reduction zone connecting part 10, 11 Seal roll 12 Flue 13 Exhaust port 14 Exhaust amount adjustment means (damper)
DESCRIPTION OF SYMBOLS 101 Fuel supply system 102 Air supply system 103 Direct fire heating burner 105 Gas supply piping

Claims (4)

A steel sheet containing at least one of Si: 0.2 to 3% and Mn: 1 to 3% by mass% is heated in a direct flame heating type direct flame, and further in a reducing atmosphere in the reduction zone. After performing the reduction and annealing of the surface, high in strength method for manufacturing a galvanized steel sheet, the furnace gas of the connecting portion or et furnace reduction zone with an open flame zone to perform the allowed galvanized immersed in the molten zinc plating bath A method for producing a high-strength hot-dip galvanized steel sheet, characterized by exhausting outside . 2. The high-strength melting according to claim 1, wherein the gas flow rate exhausted outside the furnace from the joint of the direct flame zone and the reduction zone is 30% or more and 120% or less of the flow rate of the reducing gas supplied into the furnace. Manufacturing method of galvanized steel sheet. In an annealing furnace having a direct-fired heating zone and a reduction zone, and a hot-dip galvanized steel sheet manufacturing facility equipped with a hot-dip galvanizing device downstream of it, the gas in the furnace is connected to the joint between the direct-fire zone and the reduction zone. A facility for producing a hot-dip galvanized steel sheet, characterized by having exhaust means for exhausting outside the furnace . The said exhaust means is equipped with the exhaust amount adjustment means which adjusts the gas amount exhausted outside a furnace, The manufacturing equipment of the hot dip galvanized steel sheet of Claim 3 characterized by the above-mentioned.

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