JP4630153B2 - Manufacturing method of metal cord for tire and manufacturing method of pneumatic tire using the same - Google Patents

Description

The present invention enhances the rubber penetration into the cord, with omission resistant core in the layer twisting structure and a method of manufacturing a metal cord for a tire having improved corrosion resistance, and manufacturing of a pneumatic tire using the same Regarding the method .

  Metal cords used for pneumatic tires are usually a layer twist structure in which metal strands of the same diameter are arranged in close proximity to increase cord tensile strength per cord diameter and to obtain good fatigue resistance For example, a 3 + 9 structure (FIG. 7A) is widely adopted. However, in such a close-packed layer twist structure, the gap between the metal wires b and b in the sheath a is small, so that the rubber cannot sufficiently penetrate into the core c. For this reason, the adhesive force between the core c and the rubber is insufficient, and the core is pulled out of the cord due to repeated bending deformation of the cord that occurs when the tire travels, and the cord tends to be damaged. Further, due to insufficient penetration of rubber, there is a problem that rust is generated and moisture is easily propagated in the cord, and durability of the cord and the tire is lowered.

  Therefore, in Patent Document 1, as shown in FIG. 7B, for example, a 1 + 6 layer in which a sheath a composed of a plurality of metal strands b is formed around a core c composed of a single metal strand b. A cord having a twisted structure is disclosed, and as a metal wire b of the core c, a typed wire that is two-dimensionally wave-shaped before being twisted is used, and the sheathed wire is twisted while twisting the typed wire. It is matched. In this case, the mold is made three-dimensional by twisting the mold wire, and the diameter of the core c is increased moderately. Therefore, the gap between the metal wires b and b in the sheath a is increased, and the core c is formed. Can increase rubber penetration.

  However, since the core c is composed of one metal strand b, in order to form a relatively thick cord, for example, for a belt layer, the metal strand b itself of the core c has to be thickened, and the cord is not It tends to be stiff and supple. In Patent Document 2, as shown in FIG. 7C, for example, as shown in FIG. 7C, a cored wire b1 and a non-typed strand b2 that have already been two-dimensionally waved are bundled to form a strand of wire. Is disclosed in which a core is formed. However, in this case, each of the embedding strands b1 is individually three-dimensionalized by the twisting, so that the core diameter tends to be excessive, and the compactness of the cord is impaired.

Therefore, the present invention uses a typed bundle in which the metal strands are shaped in a two-dimensional wave shape or in a spiral shape while maintaining a bundled state in which the metal strands are aligned in parallel with each other. In addition, on the basis of forming the core, while ensuring the flexibility and compactness of the cord, it is possible to increase the rubber penetration into the core, and for tires that can improve the resistance to core removal and corrosion resistance. a method of manufacturing a metal cord, and to provide a manufacturing method of a pneumatic tire using the same are intended.

JP 2002-161487 A JP 2002-161489 A

The invention of claim 1 of the present application is a method of manufacturing a metal cord for a tire having a layer twist structure composed of 7 to 15 metal strands having a diameter D of greater than 0.25 mm and not greater than 0.40 mm,
Forming a core by twisting a single wire bundle in which 2 to 5 metal wires are aligned ; and
And forming a sheath by winding helically more metal wires than the number of metal strands of the core to the periphery of said core,
Moreover, the wire bundle is molded in a two-dimensional wave shape in which the bundle itself repeats a peak portion and a valley portion while maintaining the bundle state in which the metal strands are aligned in parallel with each other before the twist is applied. And is formed from an undulating mold bundle ,
The diameter D1 of the metal strand of the mold bundle, the mold pitch P of the mold bundle, and the mold height h of the mold bundle satisfy the following formulas (1) to (3).
10.0 × D1 ≦ P ≦ 50.0 × D1 (1)
0.1 × D1 ≦ h ≦ 2.5 × D1 (2)
0.5 ≦ (h / P) × 100 ≦ 13.0 −−− (3)
The invention of claim 2 of the present application is a method for producing a metal cord for a tire having a layer twist structure composed of 7 to 15 metal strands having a diameter D of greater than 0.25 mm and equal to or less than 0.40 mm. ,
Forming a core by twisting a single wire bundle in which 2 to 5 metal wires are aligned; and
Forming a sheath by spirally winding a metal wire more than the number of metal wires of the core around the core;
Moreover, the strand bundle is formed from a spirally shaped bundle in which the bundle itself is spirally shaped while maintaining the bundle state in which the metal strands are aligned in parallel to each other before the twist is applied. And
The diameter D1 of the metal strand of the mold bundle, the mold pitch P of the mold bundle, and the mold height h of the mold bundle satisfy the following expressions (1), (2 ′), and (3).
10.0 × D1 ≦ P ≦ 50.0 × D1 (1)
0.17 × D1 ≦ h ≦ 2.5 × D1 −−− (2 ′)
0.5 ≦ (h / P) × 100 ≦ 13.0 −−− (3)

According to a fourth aspect of the present invention, there is provided a carcass comprising a series of ply turn-up portions that fold around the bead core from the inner side to the outer side in the tire axial direction on the ply body portion extending from the tread portion through the sidewall portion to the bead core. carcass made of plies, and the belt layer to a manufacturing method of a pneumatic tire having a belt layer disposed radially outward of the carcass of the tread portion, the metal cord according to claim 1 It is characterized by using.

  Since the present invention is configured as described above, the rubber penetration into the core can be enhanced while ensuring the flexibility and compactness of the cord, and the core removal resistance and corrosion resistance can be improved. Can do.

Hereinafter, an embodiment of the present invention will be described with reference to the drawings. FIG. 1 is a cross-sectional view showing an example of a pneumatic tire using the metal cord of the present invention.
As shown in FIG. 1, a pneumatic tire 1 is a heavy-duty tire for trucks and buses in this example, and includes a carcass 6 extending from a tread portion 2 to a sidewall portion 3 to a bead core 5 of a bead portion 4. And a belt layer 7 disposed on the inner side of the tread portion 2 and on the outer side in the radial direction of the carcass 6.

  The carcass 6 is formed of one or more, in this example, one carcass ply 6A in which carcass cords are arranged at an angle of 70 to 90 ° with respect to the tire circumferential direction. The carcass ply 6A includes a series of ply turn-up portions 6b that are turned back from the inside in the tire axial direction around the bead core 5 on both sides of the ply main body portion 6a straddling the bead cores 5 and 5. A bead apex rubber 8 for bead reinforcement extending radially outward from the bead core 5 is disposed between the main body portion 6a and the ply turn-up portion 6b.

  The belt layer 7 is formed of two or more belt plies (usually 3 to 4 in the case of a heavy duty tire). In this example, the belt layer 7 includes a first belt ply 7A on the innermost side in the radial direction in which belt cords are arranged at an angle of, for example, 60 ± 15 ° with respect to the tire circumferential direction, A case of a four-sheet structure with second to fourth belt plies 7B to 7D arranged at a small angle of 35 ° is illustrated. The belt plies 7 </ b> A to 7 </ b> D are provided with one or more places where the belt cords cross each other between the plies, and are superposed to enhance belt rigidity and reinforce the tread portion 2 with a tagging effect.

  The bead portion 4 is provided with a bead reinforcing layer 9 made of one or more reinforcing plies in which reinforcing cords are arranged at an angle of 10 to 50 ° with respect to the tire circumferential direction.

  The bead reinforcing layer 9 includes an inner portion 9i that rises along an inner side surface in the tire axial direction of the ply body portion 6a and an outer portion 9o that rises along an outer side surface in the tire axial direction of the ply folded portion 6b. In this example, the inner portion 9i and the outer portion 9o are terminated at the inner side in the tire radial direction than the ply turn-up portion 6b. This bead reinforcing layer 9 increases the bending rigidity of the bead portion 4 and also improves the bead durability by relaxing the compressive stress acting on the ply folding portion 6b and the tensile stress acting on the ply main body portion 6a during load loading. Can be made.

  And in the tire 1 of this embodiment, as a belt cord used for the said belt layer 7, as shown in FIG. 2, 7-15 metal strand F which has the diameter D larger than 0.25 mm and below 0.40 mm. The metal cord 10 of the layer twist structure which consists of is employ | adopted. Specifically, the metal cord 10 includes a core 12 obtained by twisting a single wire bundle 11 in which n (2 to 5) metal wires Fc are aligned, and m more metals than the n wires. An n + m structure comprising a strand 13 and a sheath 13 formed by spirally winding the metal strand Fs around the core 12 is formed. In this example, a 3 + 9 structure in which n = 3 and m = 9 is used. The thing is illustrated.

  In addition, the present invention is characterized in that the wire bundle 11 is formed from a wave-like mold bundle 11A (shown in FIG. 3) or a spiral mold bundle 11B (shown in FIG. 4). In the wavy mold bundle 11A, the bundle itself repeats the peak portion 15 and the valley portion 16 while maintaining a bundle state in which n metal strands Fc are aligned in parallel with each other in a state before twisting. It is shaped like a two-dimensional wave. That is, as shown in FIG. 5, n metal strands Fc unwound from the bobbin 20 are arranged in parallel with each other to form a bundle 21, and the bundle 21 itself is molded into a two-dimensional wave shape. As a result, the corrugated mold bundle 11A is formed like a single wire. In addition, in the spiral shaped bundling bundle 11B (shown in FIG. 4), the bundle itself is formed in a spiral shape while maintaining a bundled state in which n metal strands Fc are aligned in parallel with each other before being twisted. It is typed. That is, the spirally shaped bundle 11B is formed by performing spiral molding on the bundle 21 itself. In addition, in the above-mentioned mold-binding bundles 11A and 11B, the metal strands Fc are in close contact with each other over the entire length thereof.

  Then, as shown in FIG. 5, the core 12 is formed by twisting the wire bundle 11 composed of the above-mentioned die-molded bundles 11A and 11B, and the sheath 13 is formed by winding m metal wires Fs around the core 12. . In addition, although the thing which wound the metal strand Fs after adding a twist in this figure is illustrated, the winding of the metal strand Fs can also be performed simultaneously with twist.

  Here, when the wire bundle 11 is a wave-like mold bundle 11A, the two-dimensional typing of the wire bundle 11 is made three-dimensional by applying the twist. At this time, since the mold bundle 11A is formed like a single wire, the metal wires Fc are kept in close contact with each other even in the twisted core 12 state. Therefore, the apparent diameter K1 of the core 12 can be appropriately increased as compared with the diameter K0 of the strand bundle 11. As a result, a gap between the metal strands Fs and Fs in the sheath 13 is widened, rubber permeability to the core 12 is increased, and rubber can be filled in a space where the core 12 has a large diameter. Therefore, the adhesive force between the core 12 and the rubber can be increased, the resistance to pulling out of the core can be increased, the cord damage can be suppressed, and the occurrence of rust can be suppressed. Moreover, since the metal wires Fc are in close contact with each other in the core 12, the cord can be kept compact. In addition, since the core 12 can be formed of a plurality of metal wires Fc, it is possible to prevent the cord from being stiffened and to ensure flexible flexibility. In addition, when a core is formed by twisting a plurality of two-dimensionally-molded metal strands as in the past, each metal strand is individually three-dimensional, so the apparent diameter of the core becomes excessive. , Disadvantageous to code compactization.

  Further, in the case where the strand bundle 11 is a spiral typed bundle 11B, the same effect can be obtained because the typed mold itself has already been made three-dimensional.

Moreover, in order to effectively exhibit the above-mentioned effects, it is important to satisfy the following formulas (1) to (3) when the molding is a two-dimensional wave, and when the molding is a spiral, Let (2) be (2 ') .
10.0 × D1 ≦ P ≦ 50.0 × D1 (1)
0.1 × D1 ≦ h ≦ 2.5 × D1 (2)
0.17 × D1 ≦ h ≦ 2.5 × D1 −−− (2 ′)
0.5 ≦ (h / P) × 100 ≦ 13.0 −−− (3)
In the formula, D1 is the diameter of the metal strand Fc of the mold bundle 11; P is the mold pitch of the mold bundle 11, and h is the mold height of the mold bundle. As shown in FIGS. 3 and 4, the embossing pitch P means the length of the wave in the longitudinal direction between the crests 15 and 15 or between the troughs 16 and 16 in the case of the corrugated embossing bundle 11A. In the case of the spiral shaped bundle 11B, it means a helical pitch. In the case of the wave-like mold bundle 11A, the mold height h means the amplitude of the wave, and in the case of the spiral mold bundle 11B, it means the diameter of the pitch circle.

  When the molding pitch P is larger than 50.0 times the diameter D1 and the molding height h is smaller than 0.1 times the diameter D1, the molding is too small to sufficiently increase the rubber permeability. The effect of improving the resistance to core removal and corrosion resistance is insufficient. On the other hand, when the molding pitch P is less than 10.0 times the diameter D1 and the molding height h is greater than 2.5 times the diameter D1, the molding process rate is excessive and the metal element Fc is greatly damaged. As a result, the strength of the cord is reduced, and the strength reduction rate is increased to reduce the durability.

  Further, even when the molding pitch P and the molding height h are within the above ranges, if the ratio (h / P) × 100 is less than 0.5, the rubber permeability cannot be sufficiently increased. If h / P) × 100 exceeds 13.0, the damage caused by the molding process becomes large, the strength reduction rate becomes large, and the durability is lowered.

  The diameter D1 of the metal strand Fc is in the range of 0.25 to 0.40 mm, and if it is less than 0.25 mm, it is too thin to obtain a sufficient cord strength as a belt cord, particularly as a belt cord for heavy duty tires. Can not be. On the other hand, if it exceeds 0.40 mm, the bending rigidity becomes excessive, leading to the rigidity of the cord, and the shape retaining property of the cord is deteriorated. The diameter D2 of the metal strand Fs of the sheath 13 is also in the range of 0.25 to 0.40 mm. In this example, a preferable case where the metal strand Fc and the metal strand Fs have the same diameter is illustrated. However, D1> D2 or D1 <D2 may be satisfied. Further, the number n of the metal wires Fc in the core 12 is required to be 5 or less from the viewpoint of the stability of the wire bundle 11, and 3 (n = 3) from the viewpoint of the stability and the bending rigidity. Is most desirable.

  Further, as the metal strands Fc and Fs, for example, a hard steel wire having a carbon content of 0.65 to 0.88 wt% is preferable, and when the carbon content is less than 0.65%, the strength of the metal strands Conversely, when it exceeds 0.88 wt%, the hardness of the metal wire tends to be too high, and the strength reduction tends to increase during molding.

  The twist pitch Pc of the core 12 is 5.0 to 100.0 mm, and the winding pitch Ps of the metal strand Fs in the sheath 13 is 1.5 to 2.5 times the twist pitch Pc. preferable. If the twist pitch Pc is less than 5.0 mm, the strength of the cord is greatly reduced, and if it exceeds 100.0 mm, the fatigue property of the cord is reduced. When the winding pitch Ps is less than 1.5 times the twist pitch Pc, both pitches approach each other, the sheath twist easily falls between the core twist valleys, and the rubber permeability deteriorates. If exceeded, the contact angle between the core wire and the sheath wire becomes large, and the strength reduction after running due to the rubbing of the strands becomes large.

  As described above, the particularly preferred embodiment of the present invention has been described in detail. However, the present invention is not limited to the illustrated embodiment, and for example, on the outside of the metal cord 10, for the purpose of preventing the metal wire F from being scattered. The present invention can be carried out with various modifications such as one known wrapping filament thinner than the metal strand F can be wound in a spiral.

  Metal cords having the specifications shown in Tables 1 and 2 were prototyped, and the cord characteristics (cord strength, cord bending rigidity, shape retention) of each metal cord were tested. A heavy-duty tire (size 11R22.5) having the structure of FIG. 1 using this metal cord as a belt cord was manufactured and tested for rubber permeability, resistance to core removal, corrosion resistance, and strength retention after running. . The results are shown in Table 1. Each tire has the same specifications except for the metal cord. Note that a hard steel wire having a carbon content of 0.82 wt% is used for the metal strand F, and one wrapping filament having a diameter of 0.15 mm is attached to the outer periphery of the cord at a winding pitch of 3.5 mm.

(1) Code strength:
In accordance with JIS G3510 “steel tire cord test method”, the load (unit: N / mm ² ) at the time of cutting the cord at a tensile speed of 50 mm / min was measured.

(2) Cord bending stiffness:
Using a V-5 stiffness tester model 150-D manufactured by TABER (USA), as shown in FIG. 6, a force is applied to the tip of a metal cord extending 5 cm from the fixed end, and the opening angle θ of the tip is The value (N · cm) of the bending moment when the angle reached 15 ° was measured.

(3) Rubber permeability:
Remove the metal cord from the tire with the topping rubber attached, remove the rubber from the surface of the cord with rubber as much as possible, insert a knife from the cross section, and remove the two adjacent strands of the sheath strands. Remove. Then, the length of the portion in which the rubber is completely filled in the gap formed between the two removed wires and the remaining core is measured over about 10 cm, and the rubber is filled. The ratio of the length of the part to the total length is the rubber penetration rate. The above measurement is performed on ten cords, and the average value is taken as the cord measurement value.

(4) Core removal resistance:
A total of five of the metal cord to be measured and the two metal cords before and after it are taken out from the tire in a ply state with a topping rubber attached. For the metal cord to be measured, only the sheath is cut off at the upper end side to protrude only the core, and only the core is cut off and removed at the lower end side. Then, only the protruding core portion is sandwiched by the upper chuck, and the lower end portion of the ply (the range where the core is removed) is sandwiched by the lower chuck, and the core is pulled up and down. Then, the tensile force (unit N) when the core loss occurred was measured. The depth at which the core was buried in the ply (in the topping rubber) was 15 mm, and the pulling speed by the chuck was 50 mm / min.

(5) Corrosion resistance:
After running the tire for about 200,000 km, the tire was disassembled and the occurrence of rust on the metal cord was observed. The evaluation is shown by an index with Comparative Example 1 being 100, and the smaller the numerical value, the less the occurrence of rust and the better.

(6) Strength retention after running:
After running the tire about 200,000 km, the tire is disassembled and the metal cord is taken out, and the strength of the cord before running (cord strength) is indicated by an index of 100. The larger the value, the better.

  As shown in the table, it was confirmed that the metal cords of the examples can improve the rubber penetration into the core while ensuring the flexibility and compactness of the cord, and can improve the resistance to core removal and corrosion resistance. it can. Also, it can be confirmed that the strength retention after running is secured high and can contribute to the improvement of durability.

It is sectional drawing which shows one Example of the pneumatic tire using the metal cord of this invention. It is sectional drawing which shows the metal cord. (A) is a perspective view schematically showing a wavy mold bundle, and (B) is a sectional view. (A) is a perspective view schematically showing a spiral shaped bundle, and (B) is a sectional view. It is drawing which shows schematically the formation process of a metal cord. It is drawing explaining the measuring method of the bending rigidity of a cord. (A)-(C) are sectional drawing of the metal cord explaining a prior art.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Pneumatic tire 2 Tread part 3 Side wall part 4 Bead part 5 Bead core 6 Carcass 6A Carcass ply 6a Ply main-body part 6b Ply folding | turning part 9 Bead reinforcement layer 9i Inner part 9o Outer part 10 Metal cord 11 Strand bundle 11A Wavy die bundle 11B Spiral mold bundling 12 Core 13 Sheath 15 Mountain part 16 Valley part F, Fc, Fs Metal strand

Claims (4)

A method for producing a metal cord for a tire having a layer twist structure composed of 7 to 15 metal strands having a diameter D greater than 0.25 mm and equal to or less than 0.40 mm,
Forming a core by twisting a single wire bundle in which 2 to 5 metal wires are aligned ; and
And forming a sheath by winding helically more metal wires than the number of metal strands of the core to the periphery of said core,
Moreover, the wire bundle is shaped in a two-dimensional wave shape in which the bundle itself repeats a peak portion and a valley portion while maintaining the bundle state in which the metal strands are aligned parallel to each other before the twist is applied. And is formed from an undulating mold bundle ,
The diameter D1 of the metal wire of the mold bundle, the mold pitch P of the mold bundle, and the mold height h of the mold bundle satisfy the following formulas (1) to (3) : Manufacturing method .
10.0 × D1 ≦ P ≦ 50.0 × D1 --- (1)
0.1 × D1 ≦ h ≦ 2.5 × D1 (2)
0.5 ≦ (h / P) × 100 ≦ 13.0 −−− (3) A method for producing a metal cord for a tire having a layer twist structure composed of 7 to 15 metal strands having a diameter D greater than 0.25 mm and equal to or less than 0.40 mm,
Forming a core by twisting a single wire bundle in which 2 to 5 metal wires are aligned; and
Forming a sheath by spirally winding a metal wire more than the number of metal wires of the core around the core;
Moreover, the strand bundle is formed from a spirally shaped bundle in which the bundle itself is spirally shaped while maintaining the bundle state in which the metal strands are aligned in parallel to each other before the twist is applied. And
The diameter D1 of the metal strands of the mold with the bundle, typing pitch P of typed bundle of typing bundle typed height h of the following (1), tire characterized by satisfying the (2 ') and (3) Method for manufacturing metal cords for use in a car.
10.0 × D1 ≦ P ≦ 50.0 × D1 (1)
0.17 × D1 ≦ h ≦ 2.5 × D1 −−− (2 ′)
0.5 ≦ (h / P) × 100 ≦ 13.0 −−− (3) Twist pitch Pc of said core is 5.0～100.0Mm, and the pitch Ps winding of the sheath claim 1, characterized in that 1.5 to 2.5 times the twist pitch Pc or 3. A method for producing a metal cord for tire according to 2. A carcass composed of a carcass ply having a series of ply turn-up portions that fold the bead core from the inner side to the outer side in the tire axial direction on the ply body portion extending from the tread portion to the bead core from the sidewall portion to the bead core, and the tread A method for manufacturing a pneumatic tire comprising a belt layer disposed inward of a portion and radially outward of the carcass,
The belt layer is composed of two or more belt plies in which metal cords are inclined with respect to the tire circumferential direction,
And the manufacturing method of the pneumatic tire characterized by using the metal cord in any one of Claims 1 thru | or 3 for the said metal cord .

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