JP4611626B2 - Antistatic composition - Google Patents
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- JP4611626B2 JP4611626B2 JP2003397363A JP2003397363A JP4611626B2 JP 4611626 B2 JP4611626 B2 JP 4611626B2 JP 2003397363 A JP2003397363 A JP 2003397363A JP 2003397363 A JP2003397363 A JP 2003397363A JP 4611626 B2 JP4611626 B2 JP 4611626B2
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- antistatic agent
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- antistatic
- quaternary ammonium
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- 239000000203 mixture Substances 0.000 title claims description 41
- 239000002216 antistatic agent Substances 0.000 claims description 35
- 239000007921 spray Substances 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 18
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 16
- 229920001296 polysiloxane Polymers 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 claims description 5
- 229960004670 didecyldimethylammonium chloride Drugs 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 3
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 claims 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 2
- MELGLHXCBHKVJG-UHFFFAOYSA-N dimethyl(dioctyl)azanium Chemical compound CCCCCCCC[N+](C)(C)CCCCCCCC MELGLHXCBHKVJG-UHFFFAOYSA-N 0.000 claims 2
- 235000019270 ammonium chloride Nutrition 0.000 claims 1
- 230000003068 static effect Effects 0.000 description 14
- 230000005611 electricity Effects 0.000 description 12
- 238000011156 evaluation Methods 0.000 description 12
- 238000002156 mixing Methods 0.000 description 10
- 230000000844 anti-bacterial effect Effects 0.000 description 9
- 239000000443 aerosol Substances 0.000 description 7
- 238000011049 filling Methods 0.000 description 7
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- 230000001580 bacterial effect Effects 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 230000007794 irritation Effects 0.000 description 5
- 210000003205 muscle Anatomy 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 235000015278 beef Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229940028444 muse Drugs 0.000 description 4
- GMVPRGQOIOIIMI-DWKJAMRDSA-N prostaglandin E1 Chemical compound CCCCC[C@H](O)\C=C\[C@H]1[C@H](O)CC(=O)[C@@H]1CCCCCCC(O)=O GMVPRGQOIOIIMI-DWKJAMRDSA-N 0.000 description 4
- 239000012209 synthetic fiber Substances 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- -1 phosphate compound Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 206010011224 Cough Diseases 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- FKUWPDMMGXHDOB-UHFFFAOYSA-M didecyl(dimethyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCC[N+](C)(C)CCCCCCCCCC FKUWPDMMGXHDOB-UHFFFAOYSA-M 0.000 description 2
- MLNXUQUBCWLPGQ-UHFFFAOYSA-M didecyl-ethyl-methylazanium ethyl sulfate Chemical compound S(=O)(=O)(OCC)[O-].C(CCCCCCCCC)[N+](C)(CC)CCCCCCCCCC MLNXUQUBCWLPGQ-UHFFFAOYSA-M 0.000 description 2
- NRLUCCYRQRCHIJ-UHFFFAOYSA-M ethyl-dimethyl-octadecylazanium;ethyl sulfate Chemical compound CCOS([O-])(=O)=O.CCCCCCCCCCCCCCCCCC[N+](C)(C)CC NRLUCCYRQRCHIJ-UHFFFAOYSA-M 0.000 description 2
- WYTNTFGZBBTWNR-UHFFFAOYSA-M methyl sulfate;trimethyl(octadecyl)azanium Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCCCC[N+](C)(C)C WYTNTFGZBBTWNR-UHFFFAOYSA-M 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 238000013112 stability test Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- QYWVQMLYIXYLRE-SEYXRHQNSA-N trimethyl-[(z)-octadec-9-enyl]azanium Chemical compound CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)C QYWVQMLYIXYLRE-SEYXRHQNSA-N 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- 108091003079 Bovine Serum Albumin Proteins 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- RIBVSPMYISMZGF-UHFFFAOYSA-N C(C)OS(=O)(=O)[O-].C(CCCCCCCCC)[NH+](C)CCCCCCCC Chemical compound C(C)OS(=O)(=O)[O-].C(CCCCCCCCC)[NH+](C)CCCCCCCC RIBVSPMYISMZGF-UHFFFAOYSA-N 0.000 description 1
- TTWLQNNBXFRNFC-UHFFFAOYSA-N C(C)OS(=O)(=O)[O-].C(CCCCCCCCC)[NH+](C)CCCCCCCCCCCC Chemical compound C(C)OS(=O)(=O)[O-].C(CCCCCCCCC)[NH+](C)CCCCCCCCCCCC TTWLQNNBXFRNFC-UHFFFAOYSA-N 0.000 description 1
- JMHWNJGXUIJPKG-UHFFFAOYSA-N CC(=O)O[SiH](CC=C)OC(C)=O Chemical compound CC(=O)O[SiH](CC=C)OC(C)=O JMHWNJGXUIJPKG-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 1
- 229920000433 Lyocell Polymers 0.000 description 1
- 229920001407 Modal (textile) Polymers 0.000 description 1
- 241000237536 Mytilus edulis Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 125000005376 alkyl siloxane group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229940098773 bovine serum albumin Drugs 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- KJFLMKNOGBSFEH-UHFFFAOYSA-M decyl-dimethyl-octylazanium methyl sulfate Chemical compound S(=O)(=O)(OC)[O-].C(CCCCCCCCC)[N+](C)(C)CCCCCCCC KJFLMKNOGBSFEH-UHFFFAOYSA-M 0.000 description 1
- SCXCDVTWABNWLW-UHFFFAOYSA-M decyl-dimethyl-octylazanium;chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCC SCXCDVTWABNWLW-UHFFFAOYSA-M 0.000 description 1
- HHLUPQQHMWJOFT-UHFFFAOYSA-M decyl-dodecyl-dimethylazanium methyl sulfate Chemical compound S(=O)(=O)(OC)[O-].C(CCCCCCCCC)[N+](C)(C)CCCCCCCCCCCC HHLUPQQHMWJOFT-UHFFFAOYSA-M 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- UMGXUWVIJIQANV-UHFFFAOYSA-M didecyl(dimethyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC UMGXUWVIJIQANV-UHFFFAOYSA-M 0.000 description 1
- WLCFKPHMRNPAFZ-UHFFFAOYSA-M didodecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCC WLCFKPHMRNPAFZ-UHFFFAOYSA-M 0.000 description 1
- PQKAOPIKNPTHNX-UHFFFAOYSA-M didodecyl(dimethyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCC PQKAOPIKNPTHNX-UHFFFAOYSA-M 0.000 description 1
- DMTBOUNPGRMCSU-UHFFFAOYSA-M didodecyl-ethyl-methylazanium ethyl sulfate Chemical compound S(=O)(=O)(OCC)[O-].C(CCCCCCCCCCC)[N+](C)(CC)CCCCCCCCCCCC DMTBOUNPGRMCSU-UHFFFAOYSA-M 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- FGEPMILYVLIUKV-UHFFFAOYSA-M dimethyl(dioctyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCC[N+](C)(C)CCCCCCCC FGEPMILYVLIUKV-UHFFFAOYSA-M 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- UUHBNESUDPIHCI-UHFFFAOYSA-M ethyl-hexadecyl-dimethylazanium;ethyl sulfate Chemical compound CCOS([O-])(=O)=O.CCCCCCCCCCCCCCCC[N+](C)(C)CC UUHBNESUDPIHCI-UHFFFAOYSA-M 0.000 description 1
- GXHOWLBSVJBVPK-UHFFFAOYSA-M ethyl-methyl-dioctylazanium ethyl sulfate Chemical compound S(=O)(=O)(OCC)[O-].C[N+](CCCCCCCC)(CCCCCCCC)CC GXHOWLBSVJBVPK-UHFFFAOYSA-M 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 229940068968 polysorbate 80 Drugs 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 1
- HVLUSYMLLVVXGI-USGGBSEESA-M trimethyl-[(z)-octadec-9-enyl]azanium;chloride Chemical compound [Cl-].CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)C HVLUSYMLLVVXGI-USGGBSEESA-M 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
本発明は衣料用の帯電防止剤組成物に関する。更に詳しくは帯電防止性に優れ、且つ優れた抗菌性を有し、使用時の安全性及び特に低温時における安定性にも優れた帯電防止剤組成物に関する。 The present invention relates to an antistatic agent composition for clothing. More particularly, the present invention relates to an antistatic agent composition having excellent antistatic properties, excellent antibacterial properties, and excellent safety in use and particularly stability at low temperatures.
近年、ファッションの多様化に伴い様々な新素材を用いた衣料が登場してきている。これら新素材の大半は繊維断面を異形化することで新しい風合いを演出しようとするものである。これら新素材の素材としては加工のし易さから必然的にポリエステルやナイロンといった合成繊維が用いられている。また、衣料のカジュアル化も進み、それに伴いフリースといった新形態衣料も登場してきた。こちらも加工のし易さからポリエステルが用いられている。これらポリエステルを始めとする合成繊維を用いた衣類の欠点として帯電のし易さが挙げられる。衣類の帯電を防止する手段としては、古くから、ジ長鎖４級アンモニウム塩を主剤とした帯電防止剤組成物が知られている（例えば、特許文献１、特許文献４、特許文献７、及び特許文献８参照。）。更には、特殊リン酸エステル化合物を用いる方法も知られている（例えば、特許文献２参照。）。
一方で、昨今の消費者動向を見るとＯ−１５７やＳＡＲＳ等の影響から衛生嗜好が高まり、特にストッキング等にも使用する帯電防止剤組成物としても抗菌に対する要求が強まっている。抗菌を訴求する消臭抗菌剤の技術としては４級アンモニウム塩型抗菌剤を用いた技術がある（例えば、特許文献３、特許文献５、及び特許文献６参照。）。しかしながら、抗菌性と帯電防止性を兼ね備えた帯電防止剤組成物は未だ得られていないのが現状である。特に、帯電防止性として、静電気を除去する能力と共に、静電気の発生を防止する能力に優れた帯電防止剤組成物は得られていない。前者の能力に劣る場合には、静電気が発生した衣類にスプレー等で処理を行っても、静電気が除去できずにまとわり付き等の問題が解決されない。一方で後者の能力に劣る場合には、一旦、帯電防止剤組成物で処理を行い静電気が除去されても、着用中の摩擦により再び静電気が発生してしまい、何度となく処理を繰り返さなければならない煩わしさに繋がるといった問題が生じる。
更には、家庭用としての使用場面を想定すると、使用性の点でスプレーとして噴霧使用する形態が考えられる。ところが、有機溶媒を用いた帯電防止剤組成物をスプレー噴霧すると有機溶剤特有の臭気が部屋中にこもるといった問題点や、スプレー時に飛んだ微粒子のミストを吸引すると“ムセ”がおこり咳き込むといった問題点もある。これらを解決する為の手法として、溶媒として適度に水を含有したエタノールを使用する方法がある（例えば、特許文献８参照。）。しかしながら、本手法を用いても“ムセ”は軽減されるものの、特に低温での安定性の点で問題があり、長期保存で沈殿が生成するといった課題が残されている。
In recent years, with the diversification of fashion, clothing using various new materials has appeared. Most of these new materials try to produce a new texture by making the cross section of the fiber irregular. As these new materials, synthetic fibers such as polyester and nylon are inevitably used for ease of processing. In addition, as clothing has become more casual, new forms of clothing such as fleece have also appeared. Polyester is also used here for ease of processing. One of the disadvantages of clothing using synthetic fibers such as polyester is ease of charging. As means for preventing charging of clothes, antistatic agent compositions based on di-long-chain quaternary ammonium salts have been known for a long time (for example, Patent Document 1, Patent Document 4, Patent Document 7, and (See Patent Document 8). Furthermore, a method using a special phosphate compound is also known (see, for example, Patent Document 2).
On the other hand, looking at recent consumer trends, hygiene preference has increased due to the influence of O-157, SARS, and the like, and there has been an increasing demand for antibacterial properties, particularly as an antistatic agent composition used for stockings and the like. As a technique of a deodorizing antibacterial agent that promotes antibacterial activity, there is a technique using a quaternary ammonium salt type antibacterial agent (see, for example, Patent Document 3, Patent Document 5, and Patent Document 6). However, at present, an antistatic agent composition having both antibacterial properties and antistatic properties has not yet been obtained. In particular, as an antistatic property, an antistatic agent composition excellent in ability to remove static electricity and ability to prevent generation of static electricity has not been obtained. When the former ability is inferior, even if the clothes with static electricity are treated with a spray or the like, the static electricity cannot be removed and the problem of clinging is not solved. On the other hand, if the latter ability is inferior, once the static electricity is removed by treatment with the antistatic agent composition, static electricity is generated again due to friction during wearing, and the treatment must be repeated several times. There arises a problem that leads to troublesomeness.
Furthermore, assuming a use scene for home use, a form of spray use as a spray can be considered from the viewpoint of usability. However, when spraying an antistatic agent composition using an organic solvent, there is a problem that the odor peculiar to the organic solvent is trapped in the room, and when the mist of fine particles flying during the spraying is sucked, a problem occurs that "muscle" occurs and coughs. There is also. As a method for solving these problems, there is a method of using ethanol containing water appropriately as a solvent (see, for example, Patent Document 8). However, even though this method can reduce “mussel”, there is a problem in terms of stability particularly at low temperatures, and there remains a problem that precipitates are generated during long-term storage.
解決しようとする課題は、優れた帯電防止性（特に、静電気を除去する能力と共に静電気の発生を防止する能力を併せ持つ）と優れた抗菌性を両立させ、且つスプレー噴霧時の“ムセ”を低減すべく、含水溶媒を使用しても長期保存安定性に優れた帯電防止剤組成物を提供することである。 The problem to be solved is to achieve both excellent antistatic properties (especially the ability to remove static electricity as well as the ability to prevent the generation of static electricity) and excellent antibacterial properties, and to reduce the mess when spraying Accordingly, it is an object to provide an antistatic agent composition having excellent long-term storage stability even when a water-containing solvent is used.
本発明者らは、上記課題を克服するために鋭意検討を行った結果、ポリエーテル変性シリコーン、特定の４級アンモニウム塩及び特定のポリエチレングリコールの3成分を組み合わせることで優れた帯電防止性と優れた抗菌性が両立することが明らかとなった。またこれらの混合基剤はスプレー噴霧時の“ムセ”を低減可能な含水溶媒中でも安定に存在することが明らかとなり、本発明に至った。
本発明は、下記成分（Ａ）及び成分（Ｂ）及び成分（Ｃ）を含有することを特徴とする帯電防止剤組成物を提供する。
（Ａ）ポリエーテル変性シリコーン：０．０５〜５質量％
（Ｂ）下記一般式〔Ｉ〕で示される４級アンモニウム塩：０．０１〜２質量％
（Ｃ）下記一般式〔II〕で示されるポリエチレングリコール：０．１〜５質量％
As a result of intensive studies to overcome the above problems, the present inventors have achieved excellent antistatic properties and excellent performance by combining three components of polyether-modified silicone, a specific quaternary ammonium salt and a specific polyethylene glycol. It was revealed that antibacterial properties were compatible. Further, these mixed bases were found to be stably present even in a water-containing solvent capable of reducing “musiness” during spraying, and the present invention was achieved.
The present invention provides an antistatic agent composition comprising the following component (A), component (B) and component (C).
(A) Polyether-modified silicone: 0.05 to 5% by mass
(B) Quaternary ammonium salt represented by the following general formula [I]: 0.01 to 2% by mass
(C) Polyethylene glycol represented by the following general formula [II]: 0.1 to 5% by mass
Ｒ2
｜+
Ｒ1−Ｎ−Ｒ4 Ｘ- …〔Ｉ〕
｜
Ｒ3
（式中、Ｒ1及びＲ2はそれぞれ炭素数１〜２２のアルキル基又はアルケニル基であり、Ｒ1とＲ2の炭素数の合計は１２〜２６である。Ｒ3及びＲ4はそれぞれ炭素数１〜２のアルキル基である。ＸはＣｌ、Ｂｒ、ＣＨ3ＳＯ3、ＣＨ3ＣＨ2ＳＯ3から選択される１種または２種以上である。）
R 2
｜ +
R 1 -N-R 4 X - ... [I]
｜
R 3
(In the formula, R 1 and R 2 are each an alkyl group or alkenyl group having 1 to 22 carbon atoms, and the total number of carbon atoms of R 1 and R 2 is 12 to 26. R 3 and R 4 are each carbon. X is an alkyl group having a number of 1 or 2. X is one or more selected from Cl, Br, CH 3 SO 3 and CH 3 CH 2 SO 3 .
ＨＯ−（ＣＨ2ＣＨ2Ｏ）ｎ−Ｈ …〔II〕
（式中、ｎはエチレンオキシドの付加モル数を示し、ｎ＝３〜７０の範囲である。）
HO- (CH 2 CH 2 O) n-H ... (II)
(In the formula, n represents the number of moles of ethylene oxide added, and n is in the range of 3 to 70.)
本発明の帯電防止剤組成物は、様々な繊維製品に対し優れた帯電防止性と優れた抗菌性を発現させるのみならず、使用時の“ムセ”を低減し、また低温での長期保存における安定性にも優れたものである。 The antistatic agent composition of the present invention not only exhibits excellent antistatic properties and excellent antibacterial properties for various textile products, but also reduces “muscles” during use, and is suitable for long-term storage at low temperatures. It is also excellent in stability.
以下、本発明を詳細に説明する。本発明における成分（Ａ）はポリエーテル変性シリコーンである。好ましいポリエーテル変性シリコーンとしては、例えば下記一般式（III）で示されるアルキルシロキサンとポリオキシアルキレンの共重合物が挙げられる。 Hereinafter, the present invention will be described in detail. Component (A) in the present invention is a polyether-modified silicone. Preferable polyether-modified silicone includes, for example, a copolymer of alkylsiloxane and polyoxyalkylene represented by the following general formula (III).
ＣＨ3 ＣＨ3 ＣＨ3 ＣＨ3
| ｜ ｜ ｜
ＣＨ3−ＳｉＯ−（ＳｉＯ）M−（ＳｉＯ）N−Ｓｉ−ＣＨ3 …（III）
| ｜ ｜ ｜
ＣＨ3 ＣＨ3 Ｃ3Ｈ6 ＣＨ3
｜
Ｏ（Ｃ2Ｈ4Ｏ）p（Ｃ3Ｈ6Ｏ）qＲ
（式中、Ｍ及びＮはそれぞれの繰り返し単位の重合度を示し、Ｍ：１０〜１００００、Ｎ：１〜１０００、Ｍ＞Ｎである。ｐ及びｑはそれぞれエチレンオキシド及びプロピレンオキシドの重合度を示し、ｐ：２〜１００、ｑ：０〜５０である。Ｒは水素又は炭素数１〜４のアルキル基である。）
CH 3 CH 3 CH 3 CH 3
| | | | |
CH 3 -SiO- (SiO) M - (SiO) N -Si-CH 3 ... (III)
| | | | |
CH 3 CH 3 C 3 H 6 CH 3
｜
O (C 2 H 4 O) p (C 3 H 6 O) q R
(In the formula, M and N represent the degree of polymerization of each repeating unit, M: 10 to 10,000, N: 1 to 1000, M> N. P and q represent the degree of polymerization of ethylene oxide and propylene oxide, respectively. P: 2 to 100, q: 0 to 50. R is hydrogen or an alkyl group having 1 to 4 carbon atoms.
本発明で用いるポリエーテル変性シリコーンの具体的な例としては東レ・ダウ コーニング・シリコーン（株）製のＳＨ３７７２Ｍ、ＳＨ３７７５Ｍ、ＳＨ３７４８、ＳＨ３７４９、ＳＦ８４１０、ＳＨ８７００、ＢＹ２２−００８、ＢＹ２２−０１２、ＳＦ８４２１、信越化学工業（株）製のＫＦ３５２Ａ、ＫＦ６００８、ＫＦ６１５Ａ、ＫＦ６０１６、ＫＦ６０１７、ＧＥ東芝シリコーン（株）製のＴＳＦ４４５０、ＴＳＦ４４５２、日本ユニカー（株）製のＳＩＬＷＥＴ Ｌ−７００１、ＳＩＬＷＥＴ Ｌ−７００２、ＳＩＬＷＥＴ Ｌ−７６０２、ＳＩＬＷＥＴ Ｌ−７６０４、ＳＩＬＷＥＴ ＦＺ−２１０４、ＳＩＬＷＥＴ ＦＺ−２１２０、ＳＩＬＷＥＴ ＦＺ−２１６１、ＳＩＬＷＥＴ ＦＺ−２１６２、ＳＩＬＷＥＴ ＦＺ−２１６４、ＳＩＬＷＥＴ ＦＺ−２１７１等が挙げられ、これらを１種単独で用いても良く、２種以上を組み合わせて用いても良い。
本発明で用いるポリエーテル変性シリコーンは帯電防止剤組成物中に０．０５〜５質量％配合される。ポリエーテル変性シリコーンの配合量が上記範囲内であれば優れた帯電防止性能が得られ、さらに衣類に噴霧した際のシミ発生や、衣類のベタツキ等が生じることもない。帯電防止性能等の観点から、ポリエーテル変性シリコーンの配合量は、好ましくは０．１〜４質量％、更に好ましくは０．２〜３質量％である。
Specific examples of the polyether-modified silicone used in the present invention include SH3772M, SH3775M, SH3748, SH3749, SF8410, SH8700, BY22-008, BY22-012, SF8421, Shin-Etsu Chemical, manufactured by Toray Dow Corning Silicone Co., Ltd. KF352A, KF6008, KF615A, KF6016, KF6017 manufactured by Kogyo Co., Ltd., TSF4450, TSF4452, manufactured by GE Toshiba Silicone Co., Ltd., SILWET L-7001, SILWET L-7002, SILWET L-7602 manufactured by Nippon Unicar Co., Ltd. SILWET L-7604, SILWET FZ-2104, SILWET FZ-2120, SILWET FZ-2161, SILWET FZ-2162, SILWET FZ-2164, S ILWET FZ-2171 and the like may be mentioned, and these may be used alone or in combination of two or more.
The polyether-modified silicone used in the present invention is blended in an amount of 0.05 to 5% by mass in the antistatic agent composition. If the blending amount of the polyether-modified silicone is within the above range, excellent antistatic performance can be obtained, and further, no generation of stains or stickiness of clothing will occur when sprayed on clothing. From the viewpoint of antistatic performance and the like, the blending amount of the polyether-modified silicone is preferably 0.1 to 4% by mass, and more preferably 0.2 to 3% by mass.
本発明における成分（Ｂ）は、下記一般式〔Ｉ〕で示される４級アンモニウム塩である。本発明の成分（Ｂ）は本来有している抗菌性能に加え、成分（Ａ）との混合により相乗的に帯電防止能（中でも発生した静電気を除去する能力）を向上させる効果を示す事が明らかとなった。 Component (B) in the present invention is a quaternary ammonium salt represented by the following general formula [I]. In addition to the inherent antibacterial performance, the component (B) of the present invention exhibits an effect of synergistically improving the antistatic ability (in particular, the ability to remove generated static electricity) by mixing with the component (A). It became clear.
Ｒ2
｜+
Ｒ1−Ｎ−Ｒ4 Ｘ- …〔Ｉ〕
｜
Ｒ3
（式中、Ｒ1及びＲ2はそれぞれ炭素数１〜２２のアルキル基又はアルケニル基であり、Ｒ1とＲ2の炭素数の合計は１２〜２６である。Ｒ3及びＲ4はそれぞれ炭素数１〜２のアルキル基である。ＸはＣｌ、Ｂｒ、ＣＨ3ＳＯ3、ＣＨ3ＣＨ2ＳＯ3から選択される１種または２種以上である。）
R 2
｜ +
R 1 -N-R 4 X - ... [I]
｜
R 3
(In the formula, R 1 and R 2 are each an alkyl group or alkenyl group having 1 to 22 carbon atoms, and the total number of carbon atoms of R 1 and R 2 is 12 to 26. R 3 and R 4 are each carbon. X is an alkyl group having a number of 1 or 2. X is one or more selected from Cl, Br, CH 3 SO 3 and CH 3 CH 2 SO 3 .
本発明で用いる４級アンモニウム塩は上記一般式〔Ｉ〕におけるＲ1とＲ2の炭素数合計が上記範囲内であれば皮膚に対する刺激を抑えることができ、組成物の劣化による臭気の発生を抑えることもできる。また、優れた帯電防止性能及び抗菌性が得られる。これらの観点から、Ｒ1とＲ2の炭素数合計は、好ましくは１４〜２４の範囲である。
本発明で用いる４級アンモニウム塩の具体的な例としては、牛脂アルキルトリメチルアンモニウムクロライド、牛脂アルキルトリメチルアンモニウムブロマイド、牛脂アルキルトリメチルアンモニウムメチルサルフェート、牛脂アルキルエチルジメチルアンモニウムエチルサルフェート、ステアリルトリメチルアンモニウムクロライド、ステアリルトリメチルアンモニウムブロマイド、ステアリルトリメチルアンモニウムメチルサルフェート、ステアリルエチルジメチルアンモニウムエチルサルフェート、オレイルトリメチルアンモニウムクロライド、オレイルトリメチルアンモニウムブロマイド、オレイルトリメチルアンモニウムメチルサルフェート、オレイルエチルジメチルアンモニウムエチルサルフェート、パルミチルオレイルトリメチルアンモニウムクロライド、パルミチルトリメチルアンモニウムブロマイド、パルミチルオレイルトリメチルアンモニウムメチルサルフェート、パルミチルエチルジメチルアンモニウムエチルサルフェート、ジデシルジメチルアンモニウムクロライド、ジデシルジメチルアンモニウムブロマイド、ジデシルジメチルアンモニウムメチルサルフェート、ジデシルメチルエチルアンモニウムエチルサルフェート、ジドデシルジメチルアンモニウムクロライド、ジドデシルジメチルアンモニウムメチルサルフェート、ジドデシルエチルメチルアンモニウムエチルサルフェート、ジオクチルジメチルアンモニウムクロライド、ジオクチルジメチルアンモニウムメチルサルフェート、ジオクチルエチルメチルアンモニウムエチルサルフェート、デシルドデシルジメチルアンモニウムクロライド、デシルドデシルジメチルアンモニウムメチルサルフェート、デシルドデシルエチルメチルアンモニウムエチルサルフェート、デシルオクチルジメチルアンモニウムクロライド、デシルオクチルジメチルアンモニウムメチルサルフェート、デシルオクチルエチルメチルアンモニウムエチルサルフェート等が挙げられる。上記４級アンモニウム塩の中でも、一般式〔Ｉ〕において、Ｒ1とＲ2とが同一である場合にはＲ1とＲ2の炭素数の合計は１２〜２０であり、Ｒ1とＲ2とが異なる場合にはＲ1とＲ2の炭素数の合計は１７〜２６である４級アンモニウム塩は帯電防止性能等の点で好ましい。さらに好ましくは、ジデシルジメチルアンモニウムクロライド、ジデシルジメチルアンモニウムメチルサルフェート、ジデシルメチルエチルアンモニウムエチルサルフェート、ステアリルトリメチルアンモニウムクロライド、ステアリルトリメチルアンモニウムメチルサルフェート、及びステアリルエチルジメチルアンモニウムエチルサルフェートである。
本発明で用いる４級アンモニウム塩は帯電防止剤組成物中に０．０１〜２質量％配合される。４級アンモニウム塩の配合量が上記範囲内であれば、優れた帯電防止性能が得られる。また、皮膚に対する刺激を抑えることができると共に、帯電防止剤組成物を噴霧した際の“ムセ”及び組成物の劣化による臭気の発生の抑制にも効果的である。４級アンモニウム塩の配合量は、帯電防止性能等の観点から、好ましくは０．０５〜１質量％、更に好ましくは０．０５〜０．５質量％である。
The quaternary ammonium salt used in the present invention can suppress irritation to the skin as long as the total carbon number of R 1 and R 2 in the general formula [I] is within the above range, and the generation of odor due to deterioration of the composition. It can also be suppressed. Further, excellent antistatic performance and antibacterial properties can be obtained. From these viewpoints, the total number of carbon atoms of R 1 and R 2 is preferably in the range of 14-24.
Specific examples of the quaternary ammonium salt used in the present invention include beef tallow alkyltrimethylammonium chloride, beef tallow alkyltrimethylammonium bromide, beef tallow alkyltrimethylammonium methyl sulfate, beef tallow alkylethyldimethylammonium ethyl sulfate, stearyltrimethylammonium chloride, stearyltrimethyl Ammonium bromide, stearyl trimethyl ammonium methyl sulfate, stearyl ethyl dimethyl ammonium ethyl sulfate, oleyl trimethyl ammonium chloride, oleyl trimethyl ammonium bromide, oleyl trimethyl ammonium methyl sulfate, oleyl ethyl dimethyl ammonium ethyl sulfate, palmityl oleyl trim Ruammonium chloride, palmityl trimethyl ammonium bromide, palmityl oleyl trimethyl ammonium methyl sulfate, palmityl ethyl dimethyl ammonium ethyl sulfate, didecyl dimethyl ammonium chloride, didecyl dimethyl ammonium bromide, didecyl dimethyl ammonium methyl sulfate, didecyl methyl ethyl ammonium Ethyl sulfate, didodecyl dimethyl ammonium chloride, didodecyl dimethyl ammonium methyl sulfate, didodecyl ethyl methyl ammonium ethyl sulfate, dioctyl dimethyl ammonium chloride, dioctyl dimethyl ammonium methyl sulfate, dioctyl ethyl methyl ammonium ethyl sulfate, decyl Decyl dimethyl ammonium chloride, decyl dodecyl dimethyl ammonium methyl sulfate, decyl dodecyl methyl ammonium ethylsulfate, decyl octyl dimethyl ammonium chloride, decyl octyl dimethyl ammonium methyl sulfate, decyl octyl methyl ammonium ethylsulfate and the like. Among the quaternary ammonium salts, in the general formula [I], when R 1 and R 2 are the same, the total number of carbon atoms of R 1 and R 2 is 12 to 20, and R 1 and R 2 Are different from each other, a quaternary ammonium salt in which the total number of carbon atoms of R 1 and R 2 is 17 to 26 is preferable in terms of antistatic performance and the like. More preferred are didecyl dimethyl ammonium chloride, didecyl dimethyl ammonium methyl sulfate, didecyl methyl ethyl ammonium ethyl sulfate, stearyl trimethyl ammonium chloride, stearyl trimethyl ammonium methyl sulfate, and stearyl ethyl dimethyl ammonium ethyl sulfate.
The quaternary ammonium salt used in the present invention is blended in an amount of 0.01 to 2% by mass in the antistatic agent composition. When the blending amount of the quaternary ammonium salt is within the above range, excellent antistatic performance can be obtained. In addition to being able to suppress irritation to the skin, it is also effective in suppressing the generation of odor due to “muscles” when the antistatic agent composition is sprayed and deterioration of the composition. The blending amount of the quaternary ammonium salt is preferably 0.05 to 1% by mass, more preferably 0.05 to 0.5% by mass, from the viewpoint of antistatic performance and the like.
本発明における成分（Ｃ）は、下記一般式〔II〕で示されるポリエチレングリコールである。本発明の成分（Ｃ）は、成分（Ｂ）との混合により相乗的に帯電防止能（中でも静電気の発生を防止する能力）を向上させる効果を示す事が明らかとなった。 Component (C) in the present invention is polyethylene glycol represented by the following general formula [II]. It became clear that the component (C) of the present invention has the effect of synergistically improving the antistatic ability (in particular, the ability to prevent the generation of static electricity) by mixing with the component (B).
ＨＯ−（ＣＨ2ＣＨ2Ｏ）ｎ−Ｈ …〔II〕
（式中、ｎはエチレンオキシドの付加モル数を示し、ｎ＝３〜７０の範囲である。）
HO- (CH 2 CH 2 O) n-H ... (II)
(In the formula, n represents the number of moles of ethylene oxide added, and n is in the range of 3 to 70.)
上記一般式〔II〕におけるエチレンオキシドの付加モル数が上記範囲内であれば、優れた帯電防止性能が得られる。エチレンオキシドの付加モル数は、帯電防止性能の観点から、好ましくは４〜５０の範囲である。
本発明で用いるポリエチレングリコールは帯電防止剤組成物中に０．１〜５質量％配合される。ポリエチレングリコールの配合量が上記範囲内であれば、優れた帯電防止性能が得ることができ、また衣類に噴霧した際のシミ発生や、衣類のベタツキ等が生じることもない。ポリエチレングリコールの配合量は、帯電防止性能の観点から、好ましくは０．２〜４質量％、更に好ましくは０．２〜３質量％である。
When the number of moles of ethylene oxide added in the general formula [II] is within the above range, excellent antistatic performance can be obtained. The number of moles of ethylene oxide added is preferably in the range of 4 to 50 from the viewpoint of antistatic performance.
The polyethylene glycol used in the present invention is blended in an amount of 0.1 to 5 mass% in the antistatic agent composition. If the blending amount of the polyethylene glycol is within the above range, excellent antistatic performance can be obtained, and no stains or stickiness of clothing will occur when sprayed on clothing. The blending amount of polyethylene glycol is preferably 0.2 to 4% by mass, more preferably 0.2 to 3% by mass, from the viewpoint of antistatic performance.
本発明の帯電防止剤組成物は、任意の溶媒に溶解して使用することができる。中でも、乾燥時間が短い上に、臭気が少なく使用時に周辺環境に悪影響を与える懸念がないことから、好ましくは、エタノールと水の質量比がエタノール：水＝８０：２０〜５：９５の範囲であるエタノール水溶液に溶解して使用することが望ましい。エタノールと水の質量比が上記範囲内であれば、さらに噴霧使用時の“ムセ”の発生を抑制することができる。
本発明の帯電防止剤組成物はスプレー容器に充填し、噴霧して使用することができる。具体的に使用されるスプレー容器としてはエアゾールスプレー容器、トリガースプレー容器（直圧型あるいは蓄圧型）、フィンガースプレー容器等が挙げられる。スプレー容器に充填して使用する場合には、噴射剤としてＬＰＧ（液化プロパンガス）、ＤＭＥ（ジメチルエーテル）、炭酸ガス等が使用され、これらは単独で使用しても良く、２種以上を混合して使用しても良い。トリガースプレー容器に充填して使用する場合、トリガースプレー容器の例としては特開平９−２６８４７３号公報、特開平９−２５６２７２号公報、特開平１０−７６１９６号公報等に記載のものが挙げられる。フィンガースプレー容器充填して使用する場合、フィンガースプレー容器の例としては特開平９−２５６２７２号公報等に記載のものが挙げられる。
本発明の帯電防止剤組成物は、前期必須成分以外に以下のような任意成分を本発明の効果を損なわない範囲で配合することが可能である。
１）エチレングリコール、プロピレングリコール等の多価アルコール
２）メチルパラベン等の防腐剤
３）香料
４）酸、アルカリ等のｐＨ調整剤
The antistatic agent composition of the present invention can be used by dissolving in an arbitrary solvent. Among them, since the drying time is short and there is no fear of adversely affecting the surrounding environment at the time of use, the mass ratio of ethanol and water is preferably in the range of ethanol: water = 80: 20 to 5:95. It is desirable to use by dissolving in a certain aqueous ethanol solution. If the mass ratio of ethanol and water is within the above range, it is possible to further suppress the occurrence of “muscles” during spray use.
The antistatic agent composition of the present invention can be used after being filled in a spray container and sprayed. Specific examples of spray containers that can be used include aerosol spray containers, trigger spray containers (direct pressure type or accumulator type), and finger spray containers. When used in a spray container, LPG (liquefied propane gas), DME (dimethyl ether), carbon dioxide, etc. are used as the propellant. These may be used alone or in combination of two or more. May be used. When filling the trigger spray container for use, examples of the trigger spray container include those described in JP-A-9-268473, JP-A-9-256272, JP-A-10-76196, and the like. When filling and using a finger spray container, examples of the finger spray container include those described in JP-A-9-256272.
The antistatic agent composition of the present invention can be blended with the following optional components in addition to the essential components in the previous period as long as the effects of the present invention are not impaired.
1) Polyhydric alcohols such as ethylene glycol and propylene glycol 2) Preservatives such as methylparaben 3) Fragrance 4) pH adjusters such as acids and alkalis
本発明の帯電防止剤組成物は、前期スプレー容器に充填して噴霧使用するだけではなく、保管を目的としてスタンディングパウチに充填して保管することも可能である。スタンディングパウチの本体及び注ぎ口の形状は問わず、構成材料としても公知の方法により製造されるプラスチックフィルムの多層積層構造のものが用いられる。
本発明の帯電防止剤組成物を使用する対象の繊維としては特に限定されるものではなくポリエステル、ナイロン、アクリル等の合成繊維、アセテート等の半合成繊維、レーヨン、テンセル、ポリノジック等の再生繊維、綿、ウール、絹等の天然繊維及びこれら各種繊維の混紡品、混織品、混編品等幅広い用途に用いることができる。
The antistatic agent composition of the present invention can be used not only for filling and spraying in a spray container in the previous period, but also for filling a standing pouch for storage. Regardless of the shape of the main body and spout of the standing pouch, a plastic film having a multilayer laminated structure manufactured by a known method is used as a constituent material.
The target fiber to be used for the antistatic agent composition of the present invention is not particularly limited, and synthetic fibers such as polyester, nylon, and acrylic, semi-synthetic fibers such as acetate, regenerated fibers such as rayon, tencel, and polynosic, It can be used for a wide range of applications such as natural fibers such as cotton, wool and silk, and blended products, blended fabrics and blended products of these various fibers.
下記に実施例及び比較例で使用した成分を示す。
下記に実施例及び比較例で使用した容器を示す。
トリガースプレー：吉野工業所（株）製、型番：ＹＴ−８７Ｌ（噴口径：０．６ｍｍ）
エアゾール容器：
缶：アルミニウム ＪＩＳ Ａ−３００４Ｐ内面コート缶（東洋製罐（株）製）
バルブ：２−ＧＤＥＳ−バルブ ＤＹ０２−Ｈ０４２２２ｘＣ９２Ｒ（東洋エ
アゾール製）
ボタン：ＧＤＥ−ボタン（キタノ製作（株）製）
ガラス瓶：広口規格瓶ＰＳ−Ｎｏ．１１（１１０ｍＬ容）
The container used by the Example and the comparative example is shown below.
Trigger spray: Yoshino Kogyo Co., Ltd., model number: YT-87L (nozzle diameter: 0.6 mm)
Aerosol container:
Can: Aluminum JIS A-3004P inner surface coated can (Toyo Seikan Co., Ltd.)
Valve: 2-GDES-Valve DY02-H04222xC92R (Toyoe
Made of azole)
Button: GDE-button (manufactured by Kitano Manufacturing Co., Ltd.)
Glass bottle: Wide-mouth standard bottle PS-No. 11 (110mL capacity)
〔帯電防止性評価方法Ａ：半減期測定（静電気を除去する能力）〕
試験布として市販のポリエステルサテンを用いた。この試験布を２０ｃｍ×３０ｃｍに裁断したものに対し、調整した帯電防止剤組成物をトリガースプレイヤーまたはエアゾールスプレーにて均一に３ｇ噴霧し、２０℃、４５％ＲＨにて２４時間調湿した。その後、ＳＴＡＴＩＣ ＨＯＮＥＳＴＭＥＴＥＲ ＴＹＰＥＳ−５１０９（宍戸商会製）を用いてＪＩＳ−Ｌ−１０９４、Ａ法に準じて半減期の測定を行った。
判定基準 ◎：半減期２秒未満
：半減期２秒以上、５秒未満
：半減期５秒以上、３０秒未満
×：半減期３０秒以上
[Antistatic evaluation method A: half-life measurement (ability to remove static electricity)]
A commercially available polyester satin was used as a test cloth. 3 g of the prepared antistatic agent composition was sprayed uniformly with a trigger sprayer or aerosol spray on the test cloth cut into 20 cm × 30 cm, and conditioned at 20 ° C. and 45% RH for 24 hours. Then, the half life was measured according to JIS-L-1094 and the A method using STATIC HONESTEMETER TYPES-5109 (made by Ashito Shokai).
Criteria ◎: Half-life less than 2 seconds: Half-life 2 seconds or more, less than 5 seconds: Half-life 5 seconds or more, less than 30 seconds ×: Half-life 30 seconds or more
〔帯電防止性評価方法Ｂ：摩擦帯電圧（静電気の発生を防止する能力）〕
試験布として市販のポリエステルサテンを用いた。この試験布を２０ｃｍ×３０ｃｍに裁断したものに対し、調整した帯電防止剤組成物をトリガースプレイヤーまたはエアゾールスプレーにて均一に３ｇ噴霧し、２０℃、４５％ＲＨにて２４時間調湿した。その後、ＲＯＴＡＲＹ ＳＴＡＴＩＣ ＴＥＳＴＥＲ（興亜商会製）を用いてＪＩＳ−Ｌ−１０９４、Ｂ法に準じて摩擦帯電圧の測定を行った。尚、摩擦布としては綿金巾３号を用いた。
判定基準 ◎：摩擦帯電圧２００Ｖ未満
：摩擦帯電圧２００Ｖ以上、５００Ｖ未満
：摩擦帯電圧５００Ｖ以上、１０００Ｖ未満
×：摩擦帯電圧１０００Ｖ以上
[Antistatic Evaluation Method B: Friction Voltage (Ability to Prevent Generation of Static Electricity)]
A commercially available polyester satin was used as a test cloth. 3 g of the prepared antistatic agent composition was sprayed uniformly with a trigger sprayer or aerosol spray on the test cloth cut into 20 cm × 30 cm, and conditioned at 20 ° C. and 45% RH for 24 hours. Thereafter, the frictional voltage was measured according to JIS-L-1094, Method B, using ROTARY STATIC TESTER (manufactured by Koa Shokai). In addition, as the friction cloth, a cotton gold no. 3 was used.
Judgment criteria A: Friction band voltage less than 200V: Friction band voltage 200V or more, less than 500V: Friction band voltage 500V or more, less than 1000V
X: Friction band voltage 1000V or more
〔抗菌力評価方法〕
調整した帯電防止剤組成物：８ｍＬ、ＢＳＡ０．３％水溶液（牛血清アルブミン Ｎｏ．Ａ−４３７８ ＡＬＢＭＩＮ，ＢＯＶＩＮＥ Ｃｒｙｓｔａｌｌｉｚｅｄ ａｎｄ ｌｙｏｐｈｉｌｉｚｅｄ：ＳＩＧＭＡ ＣＨＭＩＣＡＬ ＣＯＭＰＡＮＹ製）：１ｍＬ、菌液（大腸菌 Ｅ．ｃｏｌｉ ＩＦ０３３０１ 菌数が１０の９乗個となるように調整）：１ｍＬを試験管内で調整し、２５℃にて５分間放置した。この菌液を菌数が１０の６乗個になるまで希釈した後、希釈菌液０．５ｍＬをサンプリングした。サンプリングした希釈菌液をＳＣＤＬＰ培地（Ｓｏｙｂｅｅｎ−ｃａｓｅｉｎ Ｄｉｇｅｓｔ Ａｇａｒ ｗｉｔｈ Ｌｅｃｉｔｈｉｎ ＆ Ｐｏｌｙｓｏｒｂａｔｅ ８０ ＤＡＩＧＯ ：日本製薬（株）製）：４．５ｍＬと混合した。更にこの混合菌液１ｍＬとＳＣＤＬＰ培地２０ｍＬを混合し、シャーレにて３７℃で２４時間培養し、菌数を測定した。
判定基準 ○：初期菌数より１０の５乗個／ｍＬ以上減少
△：初期菌数より１０の３乗個／ｍＬ以上、１０の５乗個／ｍＬ未満減少
×：初期菌数より１０の３乗個／ｍＬ未満の減少
[Antimicrobial evaluation method]
Adjusted antistatic agent composition: 8 mL, BSA 0.3% aqueous solution (bovine serum albumin No. A-4378 ALBMIN, BOVINE Crystallized and lyophilized: manufactured by SIGMA CHMICAL COMPANY): 1 mL, bacterial solution (E. coli IF03301 1 mL was adjusted in the test tube and left at 25 ° C. for 5 minutes. After diluting this bacterial solution until the number of bacteria reached 10 6, 0.5 mL of the diluted bacterial solution was sampled. The sampled diluted bacterial solution was mixed with SCDLP medium (Soybean-casein Digest Agar with Lecithin & Polysorbate 80 Daigo: manufactured by Nippon Pharmaceutical Co., Ltd.): 4.5 mL. Further, 1 mL of this mixed bacterial solution and 20 mL of SCDLP medium were mixed and cultured in a petri dish at 37 ° C. for 24 hours, and the number of bacteria was measured.
Judgment criteria ○: Decrease by 10 5 cells / mL or more from the initial number of bacteria
Δ: Decreased from 10 3 cells / mL or more to less than 10 5 cells / mL from the initial number of bacteria
×: Decrease by less than 10 3 / mL from the initial number of bacteria
〔安定性試験評価方法〕
調整した帯電防止剤組成物１００ｍＬを１１０ｍＬ容のガラス瓶に充填後、密栓した後−５℃にて２週間保存した。保存後の外観を下記基準にて判定した。
判定基準 ○：透明均一
：僅かに沈澱が生成
×：多量の沈澱が生成
[Stability test evaluation method]
The prepared antistatic agent composition (100 mL) was filled into a 110 mL glass bottle, sealed, and stored at -5 ° C. for 2 weeks. The appearance after storage was judged according to the following criteria.
Judgment criteria ○: Transparent uniform: Slight precipitation is generated ×: Large amount of precipitation is generated
〔“ムセ”の評価方法〕
直径３０ｃｍの半球状ボウルにエアゾール型帯電防止剤では５秒間、トリガースプレイヤーでは３ストローク噴霧し、反射してきた霧に口や鼻を近づけて“ムセ”の程度を判定した。
判定基準 ◎：全く“ムセ”がない
○：僅かに刺激を感じるが“ムセ”はない
×：刺激を感じ、“ムセ”る
××：強い刺激を感じ、咳き込む
[Evaluation method of “Muse”]
A 30 cm diameter hemispherical bowl was sprayed with an aerosol type antistatic agent for 5 seconds and with a trigger sprayer for 3 strokes, and the mouth and nose were brought close to the reflected mist to determine the degree of “muse”.
Judgment criteria A: There is no “muscle”
○: Slight irritation but no “muse” ×: I feel irritation and “muse”
XX: Feel strong irritation and cough
〔帯電防止剤組成物の調整〕
トリガースプレイヤーでの評価やガラス瓶での安定性試験は、表−２〜４に準じて常温にて攪拌混合により調整した帯電防止剤組成物を充填して評価を行った。
エアゾールでの評価は、表−５に準じて常温にて攪拌混合により調整した帯電防止剤組成物を充填、クリンチ（閉缶）後、噴射ガスを所定量充填して評価を行った。尚、噴射ガスとしてはＬＰＧ：ＤＭＥ＝６０：４０（質量比）の混合ガスを使用し、質量比で帯電防止剤組成物６５に対し混合ガス３５の割合で充填した。
(Adjustment of antistatic agent composition)
The evaluation with a trigger sprayer and the stability test with a glass bottle were evaluated by filling an antistatic composition prepared by stirring and mixing at room temperature according to Tables 2 to 4.
The evaluation with aerosol was performed by filling with an antistatic agent composition adjusted by stirring and mixing at room temperature according to Table-5, clinching (closing can), and then filling with a predetermined amount of injection gas. Note that a mixed gas of LPG: DME = 60: 40 (mass ratio) was used as the propellant gas, and the mixture was filled at a ratio of the mixed gas 35 to the antistatic agent composition 65 at a mass ratio.
〔トリガースプレイヤーでの評価〕
〔トリガースプレイヤーでの評価〕
〔トリガースプレイヤーでの評価〕
〔トリガースプレイヤーでの評価〕
〔エアゾールスプレイヤーでの評価〕
香料組成物（表中の配合量は香料組成物中の質量％）
Fragrance composition (the amount in the table is mass% in the fragrance composition)
Claims (5)
０．０１〜２質量％の４級アンモニウム塩（Ｂ）と、
０．１〜５質量％の下記一般式〔II〕で示されるポリエチレングリコール（Ｃ）とを含有することを特徴とする帯電防止剤組成物であって、４級アンモニウム塩（Ｂ）がステアリルトリメチルアンモニウムクロライド、パルミチルトリメチルアンモニウムブロマイド、ジデシルジメチルアンモニウムクロライド又はジオクチルジメチルアンモニウムメトサルフェートである、帯電防止剤組成物。
ＨＯ−（ＣＨ2ＣＨ2Ｏ）ｎ−Ｈ …〔II〕
（式中、ｎはエチレンオキシドの付加モル数を示し、ｎ＝４〜５０の範囲である。） 0.05 to 5% by mass of polyether-modified silicone (A),
0.01-2% by mass of a quaternary ammonium salt (B),
An antistatic agent composition comprising 0.1 to 5% by mass of polyethylene glycol (C) represented by the following general formula [II], wherein the quaternary ammonium salt (B) is stearyltrimethyl An antistatic agent composition which is ammonium chloride, palmityl trimethyl ammonium bromide, didecyl dimethyl ammonium chloride or dioctyl dimethyl ammonium methosulfate.
HO- (CH 2 CH 2 O) n-H ... (II)
(In the formula, n represents the number of moles of ethylene oxide added, and n is in the range of 4 to 50.)
ＣＨ3 ＣＨ3 ＣＨ3 ＣＨ3
| ｜ ｜ ｜
ＣＨ3−ＳｉＯ−（ＳｉＯ）M−（ＳｉＯ）N−Ｓｉ−ＣＨ3 …（III）
| ｜ ｜ ｜
ＣＨ3 ＣＨ3 Ｃ3Ｈ6 ＣＨ3
｜
Ｏ（Ｃ2Ｈ4Ｏ）p（Ｃ3Ｈ6Ｏ）qＲ
（式中、Ｍ及びＮはそれぞれの繰り返し単位の重合度を示し、Ｍ：１０〜１００００、Ｎ：１〜１０００、Ｍ＞Ｎである。ｐ及びｑはそれぞれエチレンオキシド及びプロピレンオキシドの重合度を示し、ｐ：２〜１００、ｑ：０〜５０である。Ｒは水素又は炭素数１〜４のアルキル基である。） The antistatic composition according to claim 1, wherein the component (A) is a polyether-modified silicone represented by the following general formula (III).
CH 3 CH 3 CH 3 CH 3
| | | | |
CH 3 -SiO- (SiO) M - (SiO) N -Si-CH 3 ... (III)
| | | | |
CH 3 CH 3 C 3 H 6 CH 3
｜
O (C 2 H 4 O) p (C 3 H 6 O) q R
(In the formula, M and N represent the degree of polymerization of each repeating unit, M: 10 to 10,000, N: 1 to 1000, M> N. P and q represent the degree of polymerization of ethylene oxide and propylene oxide, respectively. P: 2 to 100, q: 0 to 50. R is hydrogen or an alkyl group having 1 to 4 carbon atoms.
ＨＯ−（ＣＨ 2 ＣＨ 2 Ｏ）ｎ−Ｈ …〔II〕
（式中、ｎはエチレンオキシドの付加モル数を示し、ｎ＝４〜５０の範囲である。） 0.05 to 5% by mass of a polyether-modified silicone, 0.01 to 2% by mass of a quaternary ammonium salt, and 0.1 to 5% by mass of polyethylene glycol represented by the general formula [II] are mixed with ethanol and water. A method for preparing an antistatic agent composition comprising dissolving in a solvent having a mass ratio of ethanol: water = 80: 20 to 5:95, comprising a quaternary ammonium salt (B) Is a method for preparing an antistatic agent composition, wherein is stearyltrimethylammonium chloride, palmityltrimethylammonium bromide, didecyldimethylammonium chloride or dioctyldimethylammonium methosulfate.
HO- (CH 2 CH 2 O) n-H ... (II)
(In the formula, n represents the number of moles of ethylene oxide added, and n is in the range of 4 to 50.)
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| JP4807945B2 (en) * | 2004-11-18 | 2011-11-02 | ライオン株式会社 | Aerosol-type antistatic agent in a container |
| KR101227761B1 (en) | 2010-09-16 | 2013-01-29 | 영남대학교 산학협력단 | Anti-static and anti-microbial surface treating agent comprising quaternary ammonium salt compound and anti-static method of polymer fiber using the same |
| WO2012036382A2 (en) * | 2010-09-16 | 2012-03-22 | 영남대학교 산학협력단 | Anti-microbial and anti-static surface treatment agent with quaternary ammonium salt as active ingredient and method for preventing static electricity in polymer fibers using same |
| CN105463836A (en) * | 2016-01-08 | 2016-04-06 | 湖州市千金丝织厂 | Novel antibacterial finishing agent suitable for cotton fabric and preparation method of novel antibacterial finishing agent |
| JP7164073B2 (en) * | 2017-07-04 | 2022-11-01 | 白元アース株式会社 | Fiber treatment composition |
| CN111040171A (en) * | 2019-11-20 | 2020-04-21 | 威海诺葳信和新材料有限公司 | Antistatic agent for spandex oil agent and preparation method thereof |
| CN118388866A (en) * | 2024-05-23 | 2024-07-26 | 殷建东 | Preparation process of antibacterial and mildew-proof polyethylene plastic |
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