JP4671392B2 - Full-color image forming method, full-color image forming apparatus, and full-color toner - Google Patents

Description

  The present invention relates to a full-color image forming method, a full-color image forming apparatus, and a full-color toner used for electrophotography for forming an image.

In recent years, high image quality and colorization have been advanced by electrophotographic technology, and as a result, toner having a smaller particle size has been used (for example, Patent Documents 1 to 3).
On the other hand, in order to obtain a full-color image, a method using an intermediate transfer member is often employed in an electrophotographic image forming apparatus (for example, Patent Document 4 and Patent Document 5).

  Further, when an intermediate transfer member is used, if background stains occur on the latent image carrier during development, there is an effect of preventing the background stains from being directly transferred to a recording medium such as paper. The method using an intermediate transfer member is transferred through two transfer steps: a transfer step from an electrostatic latent image holding member to an intermediate transfer member and a transfer step onto a transfer material for obtaining a final image from the intermediate transfer member. The efficiency is lowered, and in particular, when a toner having a small particle diameter of 5 μm or less is used, there is a problem that the image becomes rough.

  In order to improve the transferability, a technique for applying a substance that lowers the surface energy to the surface of the intermediate transfer member is known (for example, Patent Document 6, Patent Document 7). However, even if the transfer efficiency can be improved to a level where there is no problem using such a technique, when a transfer material with a rough surface is used, fixing properties such as cold offset and smearing properties are insufficient. It turns out that there is a problem.

  Furthermore, in order to solve the above fixing problem, for example, the nip pressure of the fixing machine can be made extremely high, but the fixing machine is increased in size for improving pressure resistance, and the wear of the fixing member is deteriorated due to high pressure, Another problem such as a decrease in the paper passing property of the transfer paper is not preferable.

JP 2000-098657 A JP 2000-098777 A Japanese Unexamined Patent Publication No. 07-092738 Japanese Patent Application Laid-Open No. 07-209952 JP 2000-077551 Japanese Patent Laid-Open No. 10-232571 JP 2002-268400 A

  The present invention makes it possible to obtain a high image quality and a high-resolution image without color misregistration, and using a full-color image forming apparatus using an intermediate transfer member, sufficient fixability can be achieved even on paper with a rough surface. Is.

As a result of intensive studies, the present inventors have come up with the following invention.
That is, the present invention is as described below.

(1) At least a step of charging the electrostatic latent image carrier to form an electrostatic charge image on the electrostatic latent image carrier, and developing the electrostatic image formed on the electrostatic latent image carrier with toner. Development process for forming a toner image on an electrostatic latent image carrier, a process for transferring the obtained toner image onto an intermediate transfer body, a process for transferring the toner image on the intermediate transfer body onto a transfer material, a transfer material In the full color image forming method including the step of fixing the above toner image with a heat and pressure fixing member, the toner contains at least a binder resin and a colorant, and the weight average particle diameter (D4) of the toner is 2 to 5 μm. A nip pressure during secondary transfer from the intermediate transfer member is 2 to 10 N / cm ² , a surface smoothness of the transfer material is 40 S or less, and a nip pressure of the fixing member is 10 to 50 N / cm ^2. Full-color image formation characterized by Method.
(2) The full color image forming method according to (1), wherein the toner has a shape factor SF-1 of 110 to 150.
(3) The full-color image forming method according to (1) or (2), wherein fine particles having an average particle size of 0.04 to 0.30 μm are adhered to the surface of the toner.
(4) The toner according to (1) to (3), wherein the toner further contains a release agent, and the content of the release agent is 3 to 10% by weight with respect to the weight of the toner. Full color image forming method.
(5) The full-color image forming method according to any one of (1) to (4) above, wherein the toner is prepared in an aqueous medium.
(6) The full-color image forming method according to any one of (1) to (5), which is performed using a tandem type electrophotographic image forming process.
(7) The full-color image forming method according to any one of (1) to (6), wherein the intermediate transfer member is composed of a single resin layer.
(8) The step of fixing with the pressure fixing member includes arranging a plurality of rotating bodies inside an endless belt having an elastic layer on the surface, and at least one of these rotating bodies is a heating roller, The endless belt is crushed by a pressure rotator positioned outside the endless belt, and an opposing rotator arranged to face the pressure rotator through the endless belt among the plurality of rotators. The full color image forming method according to any one of (1) to (7), wherein the toner image on the transfer material is heated and fixed by a nip portion formed by an endless belt and the pressure rotating body.
(9) The full-color image forming method according to (8), wherein the heating roller is made of a magnetic metal and is heated by electromagnetic induction by electromagnetic induction generating means, whereby the belt is heated.
(10) The above-mentioned (9), wherein the electromagnetic induction generating means is provided outside the heating roller via an endless belt, and is provided separately from the counter rotating body and the heating rotating body. Full color image forming method.
(11) The full-color image forming method according to any one of (1) to (10), wherein the electrostatic latent image carrier is an amorphous silicon photoconductor.
(12) The full color image forming method according to any one of (1) to (11), wherein an alternating electric field is applied when developing the latent image on the latent image carrier.
(13) The apparatus for charging the latent image carrier is a charging device that performs charging by bringing a charging member into contact with the latent image carrier and applying a voltage to the charging member. ) To (12).

  By using the image forming apparatus and the toner of the present invention, an image with high image quality and sufficient fixing ability can be obtained even when transfer paper having a rough surface is used.

Hereinafter, the present invention will be described in detail.
In a process using an intermediate transfer body using a color toner, a toner having a small particle diameter with a weight average particle diameter of 2 to 5 μm and a rough transfer paper having a surface smoothness of 40 S or less is used. A sufficient fixability was obtained by combining the nip pressure at the time of the next transfer of ² to 10 N / cm ² and the nip pressure of the fixing member of 10 to 50 N / cm ² .

  In the present invention, the reason why sufficient fixability can be obtained even with paper having a rough surface is not clear, but even with the same transfer efficiency and the same macro transfer state, the uniformity of the toner layer at the micro level This is considered to be because the phenomenon that the toner is damaged by the fixing member does not occur at the time of fixing, and the toner is sufficiently fixed under certain fixing conditions.

  In order to achieve the object of the present invention, the toner particle diameter is preferably 2 to 5 [mu] m in weight average particle diameter (D4), and if it is smaller than 2 [mu] m, especially when a transfer paper having large irregularities is used. However, if the thickness is larger than 5 μm, the dot reproducibility becomes insufficient, the graininess of the halftone part deteriorates, and a high-definition image cannot be obtained. When a large transfer paper is used, the fixability may deteriorate.

  As for the particle size distribution of the toner, a sharper distribution than a broad one is preferable for fixing properties, and in particular, the weight average particle size (D4) / number average particle size (Dn) is 1-1. .2 is preferable.

Further, since the nip pressure at the time of secondary transfer is ² to 10 N / cm ² , the uniformity of the toner layer on the transfer paper is ensured even when a small particle size toner is used and transfer paper with large irregularities is used. Improved and good fixability is obtained.
If the nip pressure at the time of secondary transfer is less than ² N / cm ² , sufficient fixability may not be obtained. Conversely, if the nip pressure is greater than 10 N / cm ² , offset may occur, Paper permeability may deteriorate.

In addition, when the nip pressure of the fixing member is 10 to 50 N / cm ² , sufficient fixability can be obtained under the condition of the transfer paper on which the toner is uniformly transferred.
When the nip pressure of the fixing member is smaller than 10 N / cm ² , sufficient fixing performance may not be obtained. Conversely, when the nip pressure is larger than 50 N / cm ² , an offset is generated or a transfer paper is passed. Sexuality may worsen.

The surface property of the transfer paper can be expressed by smoothness. The smoothness of the transfer paper is larger than 40S and up to about 150S in what is called normal plain paper, but in this range, sufficient fixing ability can be obtained even with a normal belt fixing device. However, in the case of a transfer paper having a rough surface such as a smoothness of 40 S or less, the fixability is insufficient.
Examples of transfer paper having a smoothness of 40S or less include some recycled paper and cotton paper, but are not limited thereto.
In addition, the measuring method of smoothness was performed according to JIS P 8119 (paper and paperboard-smoothness test method by Beck smoothness tester).

  Further, the toner having a shape factor SF-1 of 110 to 150 and a more nearly spherical shape is excellent in fixability. This is considered to be due to the fact that, in the case of a nearly spherical toner, in addition to the factor that heat is uniformly applied to the toner, the state of being transferred to the transfer paper is uniform. When SF-1 is smaller than 110, the toner may be scattered during development or transfer to disturb the image, or may remain on the photosensitive member without being transferred, and toner cleaning properties may deteriorate. In addition, a phenomenon in which toner is scattered may occur during fixing. On the other hand, if it is larger than 150, the image uniformity during development deteriorates, and the transfer efficiency of toner from the latent image carrier to the intermediate transfer member or transfer paper, or from the intermediate transfer member to the transfer paper decreases. In some cases, sufficient fixability cannot be obtained.

Further, fine particles having an average particle size of 0.04 to 0.30 μm are adhered to the surface of the color toner, so that the external additive is added to the toner by stirring in a developing device that obtains sufficient secondary transfer characteristics. Problems such as changes in charge amount and toner developability caused by embedding in the surface can be improved.
When the average particle diameter of the fine particles is smaller than 0.04 μm, the toner particles are easily embedded in the toner surface, and there is no problem in the initial stage. A phenomenon may occur. In this case, transferability may deteriorate and fixability may deteriorate. On the other hand, when the average particle size is larger than 0.30 μm, sufficient fixability of the toner may be hindered.

In addition, the color toner of the present invention preferably contains 3 to 10% by weight of a release agent with respect to the weight of the toner, and in this range, sufficient oilless fixability is imparted to the toner. Is possible.
When the amount is less than 3% by weight with respect to the weight of the toner, sufficient oilless fixability may not be obtained. On the other hand, when the amount is more than 10% by weight, the transferability of the toner becomes insufficient. Fixability may deteriorate.

The color toner of the present invention is preferably produced in an aqueous medium, and is particularly effective for obtaining a small particle size and shape in the toner of the present invention.
Examples of the production method include, but are not limited to, a suspension polymerization method, an emulsion association method, and a dissolution suspension method.

The full-color image forming apparatus preferably uses a tandem electrophotographic image forming process.
In a so-called tandem method in which a plurality of photoconductors are provided as a full-color recording method in the electrophotographic method and each color is developed at the time of each rotation, a latent image forming process and a developing / transfer process are performed for each color. Therefore, the difference between the single-color image formation speed and the full-color image formation speed is small, and there is an advantage that it can cope with high-speed printing. In order to form a full-color image by laminating (coloring) each color toner layer, if there are variations in characteristics such as different chargeability among the toner particles of each color, development with toner particles of each color A difference occurs in the toner amount, and the change in the hue of the secondary color due to color superposition increases, in other words, the color reproducibility decreases.

  In addition, since a color fixed image is formed by transferring and fixing the toner image formed on each of the plurality of latent image carriers to the image forming support, adhesion between the toner particles of each color to the image forming support If they are different, it becomes difficult to stabilize the image at the time of fixing, and there is a problem that the color reproducibility is lowered. In the conventionally known toner prepared by the pulverization method, since the material dispersed in the toner is non-uniformly present on the fracture surface, the surface property between the toner particles is difficult to be constant, and the toner developed between the toner particles of each color It becomes difficult to stabilize the amount and make the adhesion to the image forming support uniform. As a result, variations in developability and transferability tend to occur, and there is a problem that image quality as a color image is deteriorated. In particular, the transferability of each color is different, so that color reproducibility is deteriorated and partial transfer omission is likely to occur.

In addition, in the toner used in the image forming method by the tandem method, the amount of development toner for controlling the balance of each color is stabilized (there is no variation between the toner particles of each color), and between the toner particles of each color Therefore, it is necessary that the adhesion to the latent image carrier and the image forming support is uniform.
In response to such a problem of the tandem method, even when a transfer paper having a rough surface is used, the process of the present invention effectively exhibits the above-described action, and uniform transferability and fixing property are obtained. It is done.

  Further, since the intermediate transfer member is a single resin layer, the transfer electric field at the time of transfer acts uniformly, and even when transfer paper having a rough surface is used, sufficient and uniform transfer properties can be obtained.

  In the fixing step, a plurality of rotating bodies are arranged inside an endless belt (fixing belt) having an elastic layer on the surface, and at least one rotating body of these rotating bodies is a heating roller, and the endless belt The endless belt is crushed by a pressure rotator located outside and a counter rotator arranged to face the pressure rotator through the endless belt among the plurality of rotators, and the endless belt Since the fixing unit heats and fixes the toner image on the transfer material by the nip formed by the pressure rotator, the temperature of the fixing belt rises in a short time, and stable temperature control becomes possible. Even when a transfer paper having a rough surface is used, the fixing belt acts in a state corresponding to the surface of the transfer paper to some extent at the time of fixing, so that sufficient fixability can be obtained.

  Furthermore, it is preferable that the surface of the pressure rotator is coated with a fluorine-based or silicon-based material, so that the toner rotates under pressure when an extremely small amount of toner is offset on the belt. There is an effect to prevent adhesion to the body. When the toner adheres to the pressure rotating body, there arises a problem that the back surface of the copy image on the transfer paper is stained with the toner.

  In particular, the counter rotating body has an elastic layer, and its rubber hardness is preferably smaller than the rubber hardness of the elastic layer of the pressure rotating body, which is sufficient even when uneven transfer paper is used. Fixability is obtained, and further, the nip is recessed toward the counter rotator and the nip shape of the fixing tends to face the pressure rotator, so the transfer paper faces away from the belt and transfers to the belt. It becomes possible to prevent the paper from being wrapped.

  Further, since the heating roller is made of an image forming apparatus that is made of a magnetic metal and is heated by electromagnetic induction, it is possible to heat the belt at high speed when electromagnetic induction is applied, and there are advantages such as high thermal efficiency.

  Further, the electromagnetic induction generating means and the heating roller are provided outside the pressure rotator and the counter rotator via an endless belt, so that the heating source is located inside the pressure rotator and the counter rotator. The heat efficiency applied to the belt increases, and uniform fixing becomes possible. That is, when the heating source is inside the rotating body, it is necessary to pressurize the rotating bodies, so it is necessary to provide a rubber layer or the like having a certain thickness around the heating source. There is a problem that a lot of heat is taken away. On the other hand, the heating roller does not need to have strong pressure resistance like the pressure rotating body and the counter rotating body, and it is not necessary to provide a thick layer for reducing the thermal efficiency around the heating source.

  Furthermore, it is preferable to provide the electromagnetic induction generating means outside for the following reasons. That is, when the electromagnetic induction generating means is provided inside the heating roller, it is necessary to extremely increase the diameter of the heating roller, and in accordance with this, it is necessary to improve pressure resistance for internal protection. It is necessary to thicken the layer. This thick layer around the periphery reduces thermal efficiency. In addition, by providing it outside the electromagnetic induction generating means, convenience such as temperature controllability and arrangement applicability is high.

  An example of a fixing device used in the fixing method of the present invention is shown in FIG. Here, R1 is a fixing roller in which a metal (aluminum, iron, etc.) cored bar is coated with an elastic body (silicon rubber, etc.), and R3 is a metallic (pipe made of aluminum, iron, copper, stainless steel, etc.) cored bar. And a heating roller having a heating source H inside. S is a temperature sensor for measuring the surface temperature of the fixing belt B in contact with the heating roller R3. A fixing belt B is stretched between the fixing roller R1 and the heating roller R3. The fixing belt B has a small heat capacity, and on a base (thickness of about 30 to 150 μm such as nickel or polyimide), a release layer (silicon rubber is 50 to 300 μm thick, or fluorine resin is 10 to 50 μm). Etc.). In the case of electromagnetic induction heating, a unit made of magnetic metal is also arranged inside the heating roller, and a layer such as silver foil is provided inside the belt to heat the belt surface.

  R2 is a pressure roller in which a metal core is covered with an elastic body or the like. By pressing the fixing roller R1 from below through the fixing belt B, the fixing roller B is pressed between the fixing belt B and the pressure roller R2. A nip is formed. If necessary, R4 is provided with an oil application roller impregnated with oil for applying oil (silicone oil or the like) to the fixing belt. G is a guide for supporting the print sheet P (paper or the like) carrying the unfixed toner image T. Moreover, the dimension of each member is set by various conditions required. These are only examples, and for example, it is possible to provide a heating source inside the fixing roller R1 or the pressure roller R2. In the present invention, a fixing device using a fixing belt with a configuration other than this example is also applied. Is done.

  In such a fixing device, in particular, an oil-less or oil minute coating type fixing device, it is preferable to fix a toner containing a release agent and further finely dispersed in the toner. The toner in which the release agent is finely dispersed easily oozes out during fixing, and even in the case of an oil-less fixing device or a case where the oil application effect is reduced by a minute amount of oil application fixing device, Transfer to the belt side can be suppressed.

  In order for the release agent to be present in a dispersed state in the toner, it is preferable that the release agent and the binder resin are not compatible. Further, in order to finely disperse the release agent in the toner, for example, there is a method using a shearing force of kneading at the time of toner production. The dispersion state of the release agent can be determined by observing a thin film section of the toner with a TEM. The dispersion diameter of the release agent is preferably small, but if it is too small, there may be insufficient bleeding at the time of fixing. Therefore, if the release agent can be confirmed at a magnification of 10,000, it is determined that the release agent exists in a dispersed state. If the size is 10,000 times and the release agent cannot be confirmed, even if finely dispersed, there is a case where the bleeding at the time of fixing is insufficient.

(Toner characteristic evaluation method)
<Shape factor SF-1>
SF-1 indicating a shape factor is obtained by randomly sampling 100 toner particle images of 2 μm or more magnified 1000 times using, for example, FE-SEM (S-800) manufactured by Hitachi, Ltd. The image information is introduced into, for example, an image analysis apparatus (Luxex III) manufactured by Nicole and analyzed, and the value obtained from the following equation is defined as the shape factor SF-1 (where MXLNG is the absolute maximum length of the particle) , AREA indicates the projected area of the particles).
The shape factor SF-1 indicates the degree of roundness of the toner particles, and is expressed by the following equation.
SF-1 = {(MXLNG) ² / AREA} × (100π / 4)

<Measurement method of weight average particle diameter (D4) and number average particle diameter (Dn)>
First, 0.1 to 5 ml of a surfactant (preferably alkylbenzene sulfonate) is added as a dispersant to 100 to 150 ml of the electrolytic aqueous solution. Here, the electrolytic solution is prepared as a 1% NaCl aqueous solution using primary sodium chloride, and for example, ISOTON-II (manufactured by Coulter) can be used. Here, 2 to 20 mg of a measurement sample is further added. The electrolyte in which the sample is suspended is subjected to a dispersion treatment with an ultrasonic disperser for about 1 to 3 minutes, and the weight and number of toner particles or toner are measured with the measuring device using a 50 μm aperture. Calculate distribution and number distribution.

As channels, 1.59 to less than 2.00 μm; 2.00 to less than 2.52 μm; 2.52 to less than 3.17 μm; 3.17 to less than 4.00 μm; 4.00 to less than 5.04 μm; 5 0.04 to less than 6.35 μm; 6.35 to less than 8.00 μm; 8.00 to less than 10.08 μm; 10.08 to less than 12.70 μm; 12.70 to less than 16.00 μm; Using 13 channels of less than 20 μm; less than 20.20 to less than 25.40 μm; less than 25.40 to less than 32.00 μm, particles having a particle size of 1.59 μm or more and less than 32.00 μm are targeted. The weight average weight average particle diameter (D4) determined from the weight distribution according to the present invention and the number average particle diameter (Dn) determined from the number distribution and the ratio D4 / Dn were determined.
Hereinafter, materials used for the toner of the present invention will be described.

(Binder resin)
Polymers of styrene such as polystyrene, poly p-chlorostyrene and polyvinyltoluene in addition to modified and unmodified polyester resins, and substituted polymers thereof; styrene-p-chlorostyrene copolymer, styrene-propylene copolymer, styrene-vinyl Toluene copolymer, styrene-vinylnaphthalene copolymer, styrene-methyl acrylate copolymer, styrene-ethyl acrylate copolymer, styrene-butyl acrylate copolymer, styrene-octyl acrylate copolymer, styrene -Methyl methacrylate copolymer, styrene-ethyl methacrylate copolymer, styrene-butyl methacrylate copolymer, styrene-α-chloromethyl methacrylate copolymer, styrene-acrylonitrile copolymer, styrene-vinyl methyl ketone Copolymer, styrene-butadiene Copolymers, styrene-isoprene copolymers, styrene-acrylonitrile-indene copolymers, styrene copolymers such as styrene-maleic acid copolymers, styrene-maleic acid ester copolymers; polymethyl methacrylate, polybutyl Methacrylate, polyvinyl chloride, polyvinyl acetate, polyethylene, polypropylene, polyester, epoxy resin, epoxy polyol resin, polyurethane, polyamide, polyvinyl butyral, polyacrylic resin, rosin, modified rosin, terpene resin, aliphatic or alicyclic Examples thereof include hydrocarbon resins, aromatic petroleum resins, chlorinated paraffins, and the like, which can be used alone or in combination.

(Release agent)
A well-known thing can be used as a mold release agent used by this invention. Examples of such include polyolefin wax (polyethylene wax, polypropylene wax, etc.); long chain hydrocarbons (paraffin wax, sasol wax, etc.); carbonyl group-containing wax. Of these, carbonyl group-containing waxes are preferred.
Carbonyl group-containing waxes include polyalkanoic acid esters (carnauba wax, montan wax, trimethylolpropane tribehenate, pentaerythritol tetrabehenate, pentaerythritol diacetate dibehenate, glycerin tribehenate, 1,18 -Octadecanediol distearate, etc.); polyalkanol esters (tristearyl trimellitic acid, distearyl maleate, etc.); polyalkanoic acid amides (ethylenediamine dibehenyl amide, etc.); And dialkyl ketones (such as distearyl ketone).

  The melting point of the release agent of the present invention is preferably 50 to 120 ° C, more preferably 60 to 90 ° C. A release agent having a melting point of less than 40 ° C. has an adverse effect on heat-resistant storage stability, and a release agent having a melting point of more than 160 ° C. tends to cause a cold offset during fixing at a low temperature. Further, the melt viscosity of the release agent is preferably 5 to 1000 cps, more preferably 10 to 100 cps, as a measured value at a temperature 20 ° C. higher than the melting point. A release agent exceeding 1000 cps is poor in improving the hot offset resistance and low temperature fixability. Further, at 5 cps or less, the heat resistant storage stability tends to deteriorate.

(Coloring agent)
As the coloring agent of the present invention, all known dyes and pigments can be used. For example, carbon black, nigrosine dye, iron black, naphthol yellow S, Hansa yellow (10G, 5G, G), cadmium yellow, yellow iron oxide , Ocher, yellow lead, titanium yellow, polyazo yellow, oil yellow, Hansa yellow (GR, A, RN, R), pigment yellow L, benzidine yellow (G, GR), permanent yellow (NCG), Vulcan fast yellow ( 5G, R), Tartrazine Lake, Quinoline Yellow Lake, Anthrazan Yellow BGL, Isoindolinone Yellow, Bengala, Red Dan, Lead Zhu, Cadmium Red, Cadmium Mercury Red, Antimon Zhu, Permanent Red 4R, Para Red , Fais red, parachlorol Nitroaniline Red, Resol Fast Scarlet G, Brilliant Fast Scarlet, Brilliant Carmine B, Permanent Red (F2R, F4R, FRL, FRLL, F4RH), Fast Scarlet VD, Belkan Fast Rubin B, Brilliant Scarlet G, Resol Rubin GX, Permanent Red F5R, Brilliant Carmine 6B, Pigment Scarlet 3B, Bordeaux 5B, Tolujing Maroon, Permanent Bordeaux F2K, Helio Bordeaux BL, Bordeaux 10B, Bon Maroon Light, Bon Maroon Medium, Eosin Lake, Rhodamine Lake B, Rhodamine Lake Y, Alizarin Lake , Thioindigo red B, thioindigo maroon, oil red, quinacridone red, pyrazolone , Polyazo red, chrome vermillion, benzidine orange, perinone orange, oil orange, cobalt blue, cerulean blue, alkali blue rake, peacock blue rake, Victoria blue rake, metal free phthalocyanine blue, phthalocyanine blue, fast sky blue, in Dunslen Blue (RS, BC), Indigo, Ultramarine Blue, Bitumen, Anthraquinone Blue, Fast Violet B, Methyl Violet Lake, Cobalt Purple, Manganese Purple, Dioxane Violet, Anthraquinone Violet, Chrome Green, Zinc Green, Chrome Oxide, Pyridian, Emerald Green, Pigment Green B, Naphthol Green B, Green Gold, Acid Green Lake, Malachite Green Lake , Phthalocyanine green, anthraquinone green, titanium oxide, zinc white, lithopone and mixtures thereof can be used. The content of the colorant is usually 1 to 15% by weight, preferably 3 to 10% by weight, based on the toner.

The colorant used in the present invention can also be used as a master batch combined with a resin. As the resin kneaded together with the production of the master batch or the master batch, those selected from the binder resins are used.
This master batch can be obtained by mixing and kneading a resin for a master batch and a colorant under a high shear force to obtain a master batch. At this time, an organic solvent can be used to enhance the interaction between the colorant and the resin. Also, a so-called flushing method called watering paste containing water of colorant is mixed and kneaded with resin and organic solvent, and the colorant is transferred to the resin side to remove moisture and organic solvent components. Since it can be used as it is, it does not need to be dried and is preferably used. For mixing and kneading, a high shear dispersion device such as a three-roll mill is preferably used.

(Charge control agent)
In the present invention, in order to impart appropriate charging characteristics to the toner, all known charge control agents can be used. For example, nigrosine dyes, triphenylmethane dyes, chromium-containing metal complex dyes, molybdate chelate pigments. , Rhodamine dyes, alkoxy amines, quaternary ammonium salts (including fluorine-modified quaternary ammonium salts), alkylamides, phosphorus simple substances or compounds, tungsten simple substances or compounds, fluorine activators, salicylic acid metal salts, and salicylic acid And metal salts of derivatives. Specifically, Nitronine-based dye Bontron 03, quaternary ammonium salt Bontron P-51, metal-containing azo dye Bontron S-34, oxynaphthoic acid metal complex E-82, salicylic acid metal complex E- 84, phenol-condensate E-89 (above, manufactured by Orient Chemical Co., Ltd.), quaternary ammonium salt molybdenum complex TP-302, TP-415, and zirconium compound TN-105 (above, Hodogaya Chemical Co., Ltd.) Quaternary ammonium salt copy charge PSYVP2038, triphenylmethane derivative copy blue PR, quaternary ammonium salt copy charge NEGVP2036, copy charge NXVP434 (above, manufactured by Hoechst), LRA-901, boron complex LR-147 (made by Nippon Carlit), copper phthalocyan Emissions, perylene, quinacridone, azo pigments, sulfonate group, carboxyl group, and polymer compounds having a functional group such as a quaternary ammonium salt.

  A crystalline compound is preferable, and a compound that can be easily crushed into fine particles of 1 μm by stress or the like is more preferable. These charge control agent particles can also be placed in advance in resin particles containing a colorant for chargeability reinforcement. The amount of the charge control agent particles to be stirred together with the resin particles containing the colorant is preferably 0.01 to 2 parts by weight, more preferably 0.05 to 1 part by weight with respect to 100 parts by weight of the resin particles containing the colorant. Parts, most preferably from 0.1 to 0.5 parts by weight.

(External additive)
In addition to fine particles having an average particle size of 0.04 to 0.30 μm, inorganic fine particles are preferably used as an external additive for assisting fluidity, developability and chargeability of the colored particles obtained in the present invention. Can be used. In particular, hydrophobic silica and / or hydrophobic titanium oxide are preferred. The primary particle diameter of the inorganic fine particles is preferably 5 mμ to 2 μm, and particularly preferably 5 mμ to 500 mμ. Moreover, it is preferable that the specific surface area by BET method is 20-500 m <2> / g. The proportion of the inorganic fine particles used is preferably 0.01 to 5% by weight of the toner, and particularly preferably 0.01 to 2.0% by weight.

  Specific examples of other inorganic fine particles include, for example, alumina, barium titanate, magnesium titanate, calcium titanate, strontium titanate, zinc oxide, tin oxide, silica sand, clay, mica, wollastonite, diatomaceous earth, Examples thereof include chromium oxide, cerium oxide, pengala, antimony trioxide, magnesium oxide, zirconium oxide, barium sulfate, barium carbonate, calcium carbonate, silicon carbide, and silicon nitride.

  In addition, polymer fine particles such as polystyrene obtained by soap-free emulsion polymerization, suspension polymerization and dispersion polymerization, methacrylic acid ester and acrylic acid ester copolymer, polycondensation system such as silicone, benzoguanamine and nylon, thermosetting resin And polymer particles.

  Such a fluidizing agent can be surface-treated to increase hydrophobicity and prevent deterioration of flow characteristics and charging characteristics even under high humidity. For example, silane coupling agents, silylating agents, silane coupling agents having an alkyl fluoride group, organic titanate coupling agents, aluminum coupling agents, silicone oils, modified silicone oils and the like are preferable surface treatment agents. .

Examples of cleaning improvers for removing the developer after transfer remaining on the latent image carrier or intermediate transfer member include fatty acid metal salts such as zinc stearate, calcium stearate, and stearic acid, such as polymethyl methacrylate fine particles, polystyrene. Examples thereof include fine polymer particles produced by soap-free emulsion polymerization of fine particles and the like. The polymer fine particles preferably have a relatively narrow particle size distribution and an average particle size of 0.01 to 1 μm.
In the present invention, it is preferable to use the masterbatch colorant particles described above as the colorant, whereby the colorant can be uniformly dispersed efficiently.

As the electrostatic latent image carrier used in the present invention, an amorphous silicon photoreceptor is preferably used. Hereinafter, the amorphous silicon photoreceptor will be described.
(Amorphous silicon photoconductor)
As the electrophotographic photoreceptor in the present invention, a conductive support is heated to 50 ° C. to 400 ° C., and a vacuum deposition method, a sputtering method, an ion plating method, a thermal CVD method, a photo CVD method, An amorphous silicon photoconductor (hereinafter referred to as “a-Si photoconductor”) having a photoconductive layer made of a-Si can be used by a film forming method such as a plasma CVD method. Among them, a plasma CVD method, that is, a method in which a source gas is decomposed by direct current, high frequency or microwave glow discharge to form an a-Si deposited film on a support is preferably used.

<About layer structure>
The layer structure of the amorphous silicon photoconductor is, for example, as follows. FIG. 5 is a schematic configuration diagram for explaining a layer configuration. An electrophotographic photoreceptor 500 shown in FIG. 5A is provided with a photoconductive layer 502 made of a-Si: H, X and having photoconductivity on a support 501. An electrophotographic photoreceptor 500 shown in FIG. 5B includes a photoconductive layer 502 made of a-Si: H, X and having photoconductivity, and an amorphous silicon surface layer 503 on a support 501. It is configured. An electrophotographic photoreceptor 500 shown in FIG. 5C has a photoconductive layer 502 made of a-Si: H, X and having photoconductivity on a support 501, an amorphous silicon surface layer 503, And an amorphous silicon based charge injection blocking layer 504. In the electrophotographic photoreceptor 500 shown in FIG. 5D, a photoconductive layer 502 is provided on a support 501. The photoconductive layer 502 includes a charge generation layer 505 made of a-Si: H, X and a charge transport layer 506, and an amorphous silicon-based surface layer 503 is provided thereon.

<About the support>
The support for the photoreceptor may be conductive or electrically insulating. Examples of the conductive support include metals such as Al, Cr, Mo, Au, In, Nb, Te, V, Ti, Pt, Pd, and Fe, and alloys thereof such as stainless steel. Also, at least the surface on the side where the photosensitive layer is to be formed of an electrically insulating support such as polyester, polyethylene, polycarbonate, cellulose acetate, polypropylene, polyvinyl chloride, polystyrene, polyamide or other synthetic resin film or sheet, glass or ceramic. A conductively treated support can also be used.
The shape of the support can be a cylindrical or plate-like or endless belt with a smooth or uneven surface, and the thickness thereof is appropriately determined so that a desired photoreceptor for an image forming apparatus can be formed. When flexibility as a photoreceptor for an image forming apparatus is required, it can be made as thin as possible within a range where the function as a support can be sufficiently exhibited. However, the support is usually 10 μm or more from the viewpoints of manufacturing and handling, such as mechanical strength.

<Injection prevention layer>
In the amorphous silicon photoconductor that can be used in the present invention, a charge injection blocking layer that functions to block charge injection from the conductive support side is provided between the conductive support and the photoconductive layer as necessary. It is more effective to provide this (FIG. 5C). That is, the charge injection blocking layer has a function of blocking charge injection from the support side to the photoconductive layer side when the photosensitive layer is subjected to a charging process with a certain polarity on its free surface. When charged, it has a so-called polarity dependency that does not exhibit such a function. In order to provide such a function, the charge injection blocking layer contains a relatively large number of atoms for controlling conductivity as compared with the photoconductive layer.
The layer thickness of the charge injection blocking layer is preferably from 0.1 to 5 μm, more preferably from 0.3 to 4 μm, and most preferably from 0.5 to 0.5 in view of obtaining desired electrophotographic characteristics and economic effects. It is desirable to be 3 μm.

<About the photoconductive layer>
The photoconductive layer is formed on the undercoat layer as necessary, and the layer thickness of the photoconductive layer 502 is appropriately determined as desired from the viewpoint of obtaining desired electrophotographic characteristics and economic effects, preferably It is desirable that the thickness is 1 to 100 μm, more preferably 20 to 50 μm, and most preferably 23 to 45 μm.

<Charge transport layer>
The charge transport layer is a layer mainly having a function of transporting charges when the photoconductive layer is functionally separated. The charge transport layer includes at least silicon atoms, carbon atoms, and fluorine atoms as constituent elements, and is formed of a-SiC (H, F, O) including hydrogen atoms and oxygen atoms as required. It has conductive properties, particularly charge retention properties, charge generation properties, and charge transport properties. In the present invention, it is particularly preferable to contain an oxygen atom.
The layer thickness of the charge transport layer is appropriately determined as desired from the viewpoint of obtaining desired electrophotographic characteristics and economic effects. The charge transport layer is preferably 5 to 50 μm, more preferably 10 to 40 μm, Optimally, the thickness is desirably 20 to 30 μm.

<Charge generation layer>
The charge generation layer is a layer mainly having a function of generating charges when the photoconductive layer is functionally separated. This charge generation layer is composed of a-Si: H containing at least silicon atoms as components and substantially no carbon atoms and, if necessary, hydrogen atoms, and has desired photoconductive properties, particularly charge generation properties. , Has charge transport properties.
The layer thickness of the charge generation layer is appropriately determined as desired from the viewpoint of obtaining desired electrophotographic characteristics and economic effects, etc., preferably 0.5 to 15 μm, more preferably 1 to 10 μm, optimally 1 ˜5 μm.

<About the surface layer>
If necessary, the amorphous silicon photoconductor that can be used in the present invention can be provided with a surface layer on the photoconductive layer formed on the support as described above. It is preferable to form a surface layer. This surface layer has a free surface, and is provided to achieve the object of the present invention mainly in moisture resistance, continuous repeated use characteristics, electrical pressure resistance, use environment characteristics, and durability.
The layer thickness of the surface layer in the present invention is usually 0.01 to 3 μm, preferably 0.05 to 2 μm, and most preferably 0.1 to 1 μm. If the layer thickness is less than 0.01 μm, the surface layer is lost due to wear or the like during use of the photoreceptor, and if it exceeds 3 μm, electrophotographic characteristics such as an increase in residual potential are observed.

(Development of latent image on electrostatic latent image carrier)
In developing the latent image on the electrostatic latent image carrier in the present invention, it is preferable to apply an alternating electric field.
In the developing device 1 shown in FIG. 6, during development, a vibration bias voltage in which an AC voltage is superimposed on a DC voltage is applied to the developing sleeve 2 as a developing bias by the power source 3. The background portion potential and the image portion potential are located between the maximum value and the minimum value of the vibration bias potential. As a result, an alternating electric field whose direction changes alternately is formed in the developing unit 4. In this alternating electric field, the developer toner and the carrier vibrate vigorously, and the toner flies off the electrostatic binding force on the developing sleeve 2 and the carrier and flies to the photosensitive drum 5 to correspond to the latent image on the photosensitive drum. Adhere.
The difference between the maximum value and the minimum value of the vibration bias voltage (voltage between peaks) is preferably 0.5 to 5 KV, and the frequency is preferably 1 to 10 KHz. As the waveform of the vibration bias voltage, a rectangular wave, a sine wave, a triangular wave, or the like can be used. As described above, the DC voltage component of the vibration bias is a value between the background part potential and the image part potential, but the value closer to the background part potential than the image part potential is more likely to cover the background part potential region. This is preferable for preventing toner adhesion.

  When the vibration bias voltage waveform is a rectangular wave, the duty ratio is preferably 50% or less. Here, the duty ratio is a ratio of time during which the toner is directed to the photosensitive member during one period of the vibration bias. By doing so, the difference between the peak value at which the toner is directed to the photoreceptor and the time average value of the bias can be increased, so that the movement of the toner is further activated and the potential of the latent image surface is increased. It can adhere to the distribution and improve the roughness and resolution. In addition, since the difference between the peak value of the carrier having a charge opposite to that of the toner and the time average value of the bias toward the photosensitive member can be reduced, the movement of the carrier is reduced, and the background portion of the latent image is reduced. The probability of carriers adhering to the substrate can be greatly reduced.

(Charging method)
As the charging device used in the image forming method of the present invention, the charging device shown in FIGS. 7 and 8 can be used.

<Roller electrification>
FIG. 7 shows a schematic configuration of an example of an image forming apparatus using a contact-type charging device. A photosensitive member as an object to be charged and an image carrier is rotationally driven in the direction of an arrow at a predetermined speed (process speed). The charging roller, which is a charging member brought into contact with the photosensitive drum, is basically composed of a cored bar and a conductive rubber layer formed on the roller concentrically with the outer periphery of the cored bar. In addition, the charging roller is pressed against the photosensitive drum with a predetermined pressure by a pressurizing unit (not shown). In this case, the charging roller rotates following the rotation of the photosensitive drum. . The charging roller is formed to have a diameter of 16 mm by coating a medium resistance rubber layer of about 100,000 Ω · cm on a core metal having a diameter of 9 mm.

The core roller of the charging roller and the illustrated power source are electrically connected, and a predetermined bias is applied to the charging roller by the power source. As a result, the peripheral surface of the photoreceptor is uniformly charged to a predetermined polarity and potential.
The shape of the charging member used in the present invention may take any form such as a magnetic brush or a fur brush in addition to the roller, and can be selected according to the specifications and form of the electrophotographic apparatus. When the magnetic brush is used, the magnetic brush is made up of various ferrite particles such as Zn-Cu ferrite as a charging member, a nonmagnetic conductive sleeve for supporting the ferrite member, and a magnet roll included in the nonmagnetic conductive sleeve. In addition, when using a fur brush, for example, as a material of the fur brush, a fur treated with carbon, copper sulfide, metal, and metal oxide is used, and this is wound around a metal or other conductive core metal. By charging or pasting, it becomes a charger.

<Fur brush charging>
FIG. 8 shows a schematic configuration of an example of an image forming apparatus using a contact-type charging device. A photosensitive member as an object to be charged and an image carrier is rotationally driven in the direction of an arrow at a predetermined speed (process speed). A brush roller constituted by a fur brush is brought into contact with the photosensitive member with a predetermined nip width with a predetermined pressing force against the elasticity of the brush portion.

  The fur brush roller as a contact charging member in this example spirals a tape having a pile of conductive rayon fiber REC-B manufactured by Unitika Co., Ltd. as a brush portion on a metal core metal having a diameter of 6 mm which also serves as an electrode. The roll brush has an outer diameter of 14 mm and a longitudinal length of 250 mm. The brush of the brush part has a density of 300 denier / 50 filaments and 155 per square millimeter. This roll brush was inserted into a pipe having an inner diameter of 12 mm while rotating in one direction, and the brush and the pipe were set to be concentric, and left in a high-temperature and high-humidity atmosphere to bend and bevel.

The resistance value of the fur brush roller is 1 × 10 5 Ω at an applied voltage of 100V. This resistance value was converted from the current that flows when a fur brush roller is brought into contact with a metal drum having a diameter of φ30 mm with a nip width of 3 mm and a voltage of 100 V is applied.
The resistance value of the fur brush charger is such that, even when a low-voltage defective part such as a pinhole occurs on the photosensitive member that is the object to be charged, an excessive leakage current flows into this part and the charging nip part becomes poorly charged. In order to prevent image defects, 10 4 Ω or more is required, and in order to sufficiently inject charges onto the surface of the photoreceptor, it is necessary to have 10 7 Ω or less.

  In addition to REC-B manufactured by Unitika Ltd., the brush material is REC-C, REC-M1, REC-M10, SA-7 manufactured by Toray Industries, Inc., Nippon Kashiwa Co., Ltd. It is possible to use Sanderlon manufactured by Kanebo, Beltron manufactured by Kanebo, Kuraray Co., Ltd., Krabobo, carbon dispersed in rayon, Mitsubishi Rayon Co., Ltd. global, etc. One brush is 3 to 10 denier, and preferably has a density of 10 to 100 filaments / bundle and 80 to 600 brushes / mm. The hair foot is preferably 1 to 10 mm.

  The fur brush roller is rotationally driven at a predetermined peripheral speed (surface speed) in a direction (counter) opposite to the rotation direction of the photoconductor, and contacts the photoconductor surface with a speed difference. A predetermined charging voltage is applied to the fur brush roller from a power source, so that the surface of the rotating photoconductor is uniformly contact-charged to a predetermined polarity and potential. In this example, the contact charging of the photosensitive member by the fur brush roller is performed by direct injection charging, and the surface of the rotating photosensitive member is charged to a potential substantially equal to the charging voltage applied to the fur brush roller.

  In addition to the fur brush roller, the charging member used in the present invention may take any form such as a charging roller or a fur brush, and can be selected according to the specifications and form of the electrophotographic apparatus. When a charging roller is used, it is generally used by coating a medium resistance rubber layer of about 100,000 Ω · cm on a cored bar. In the case of using a magnetic brush, the magnetic brush is composed of various ferrite particles such as Zn—Cu ferrite as a charging member, a non-magnetic conductive sleeve for supporting it, and a magnet roll included therein.

<In case of magnetic brush charging>
FIG. 8 shows a schematic configuration of an example of an image forming apparatus using a contact-type charging device. A photosensitive member as an object to be charged and an image carrier is rotationally driven in the direction of an arrow at a predetermined speed (process speed). A brush roller composed of a magnetic brush is brought into contact with the photosensitive member with a predetermined nip width with a predetermined pressing force against the elasticity of the brush portion.

  As a magnetic brush as a contact charging member in this example, Zn—Cu ferrite particles having an average particle diameter of 25 μm and Zn—Cu ferrite particles having an average particle diameter of 10 μm are mixed at a weight ratio of 1: 0.05, Magnetic particles were used in which ferrite particles having an average particle diameter of 25 μm and having a peak at the position of each average particle diameter were coated with a medium resistance resin layer. The contact charging member is composed of the coated magnetic particles prepared above, a nonmagnetic conductive sleeve for supporting the coated magnetic particles, and a magnet roll included therein, and the coated magnetic particles are formed on the sleeve with a thickness. Coating was performed at 1 mm to form a charging nip having a width of about 5 mm between the photosensitive member and the photosensitive member. The gap between the magnetic particle holding sleeve and the photosensitive member was about 500 μm. Further, the magnet roll is rotated so that the sleeve surface rubs in the opposite direction at twice as fast as the peripheral speed of the surface of the photoconductor, and the photoconductor and the magnetic brush are in uniform contact with each other. I did it.

  The shape of the charging member used in the present invention may take any form such as a charging roller or a fur brush in addition to the magnetic brush, and can be selected according to the specifications and form of the electrophotographic apparatus. When a charging roller is used, it is generally used by coating a medium resistance rubber layer of about 100,000 Ω · cm on a cored bar. In addition, when using a fur brush, for example, as a material of the fur brush, a fur treated with carbon, copper sulfide, metal, and metal oxide is used, and this is wound around a metal or other conductive core metal. By charging or pasting, it becomes a charger.

(Process cartridge)
The developer of the present invention can be used in, for example, an image forming apparatus provided with a process cartridge as shown in FIG.
In the present invention, a plurality of components such as the above-described photosensitive member, charging unit, developing unit, and cleaning unit are integrally combined as a process cartridge, and this process cartridge is formed. It is configured to be detachable from the image forming apparatus main body such as a copying machine or a printer.

  The process cartridge shown in FIG. 9 includes a photoreceptor, a charging unit, a developing unit, and a cleaning unit. Explaining the operation, the photosensitive member is rotationally driven at a predetermined peripheral speed. In the rotation process, the photosensitive member is uniformly charged with a predetermined positive or negative potential on its peripheral surface by the charging unit, and then image exposure light from an image exposure unit such as slit exposure or laser beam scanning exposure. In this way, an electrostatic latent image is sequentially formed on the circumferential surface of the photosensitive member, and the formed electrostatic latent image is then toner developed by the developing means, and the developed toner image is exposed from the paper feeding unit. The transfer unit sequentially transfers the image to the transfer material fed in synchronization with the rotation of the photosensitive member between the transfer unit and the transfer unit. The transfer material that has received the image transfer is separated from the surface of the photosensitive member, introduced into the image fixing means, and fixed on the image, and printed out as a copy (copy). The surface of the photoconductor after the image transfer is cleaned by removing the transfer residual toner by a cleaning means, and after being further discharged, it is repeatedly used for image formation.

Embodiment 1
An embodiment in which the present invention is applied to an image forming apparatus will be described below, but the present invention is not limited to this. FIG. 1 is a schematic configuration diagram of an image forming apparatus using the toner and developer of the present invention.
In FIG. 1, a main body 100 mainly includes an image writing unit 120Bk, C, M, Y, an image forming unit 130Bk, C, M, Y, and a paper feeding unit 140 for performing color image formation by an electrophotographic method. Has been. Based on the image signal, an image processing unit (not shown) performs image processing, and converts it into black (Bk), cyan (C), magenta (M), and yellow (Y) color signals for image formation, It transmits to the image writing unit 120Bk, C, M, Y. The image writing unit 120Bk, C, M, Y is a laser scanning optical system including, for example, a laser light source, a deflector such as a rotary polygon mirror, a scanning imaging optical system, and a mirror group (none of which are shown). There are four writing optical paths corresponding to the respective color signals described above, and the respective color signals are supplied to the photoreceptors 210Bk, C, M, and Y as image carriers provided for the respective colors of the image forming units 130Bk, C, M, and Y. The image writing according to is performed.

  The image forming units 130Bk, C, M, and Y include the photosensitive members 210BBk, C, M, and Y for black, cyan, magenta, and yellow. The photosensitive members 210Bk, C, M, and Y for these colors are included in the photosensitive members 210Bk, C, M, and Y for the respective colors. Usually, an OPC photoreceptor is used. Around each of the photoreceptors 210Bk, C, M, and Y, there are charging devices 215Bk, C, M, and Y, an exposure unit for the laser beam from the image writing unit 120Bk, C, M, and Y, and a developing device for each color. 200Bk, C, M, Y, primary transfer devices 230Bk, C, M, Y, cleaning devices 300Bk, C, M, Y, a static eliminator (not shown), and the like are arranged. The developing devices 200Bk, C, M, and Y use a two-component magnetic brush developing method. Further, an intermediate transfer belt 220 is interposed between the photosensitive members 210BBk, C, M, and Y and the primary transfer devices 230Bk, C, M, and Y. The toner images of the respective colors are transferred from the photosensitive members to the intermediate transfer belt 220. Are sequentially superimposed and transferred to carry a toner image on each photoconductor.

  Conductive rollers 241, 242, and 243 are provided between the primary transfer devices 230Bk, C, M, and Y. The transfer sheet is fed from the sheet feeding unit 140 and then carried on the transfer belt 500 via the registration roller pair 160. When the intermediate transfer belt 220 and the transfer belt 500 come into contact with each other, the secondary transfer roller 600 causes the intermediate transfer belt 600 to contact the transfer sheet. The toner image on 220 is transferred to transfer paper, and a color image is formed.

  Then, the transfer paper after the image transfer is conveyed to the fixing device 150 by the transfer belt 500, and the image is fixed to obtain a color image. The toner on the intermediate transfer belt 220 remaining without being transferred is removed from the belt by the intermediate transfer belt cleaning device 260.

  Since the toner polarity on the intermediate transfer belt 220 before transfer onto the transfer paper is the same negative polarity as during development, a positive transfer bias voltage is applied to the secondary transfer roller 600 and the toner is transferred onto the transfer paper. The nip pressure at this portion affects the transferability and greatly affects the fixability. Further, the toner on the intermediate transfer belt 220 remaining without being transferred is discharged and charged to the positive polarity side and charged to 0 to the positive side at the moment when the transfer paper and the intermediate transfer belt 220 are separated. Note that the toner image formed when the transfer paper is jammed or in the non-image area is not affected by the secondary transfer, and thus remains of negative polarity.

  The thickness of the photosensitive layer is 30 μm, the beam spot diameter of the optical system is 50 × 60 μm, and the light quantity is 0.47 mW. The developing process is performed by setting the charging (pre-exposure) potential V0 of the photoreceptor (black) 210Bk to −700V, the post-exposure potential VL to −120V, and the development bias voltage to −470V, that is, the development potential 350V. A visible image of the toner (black) 6Bk formed on the photoreceptor (black) 210Bk is then transferred (intermediate transfer belt and transfer paper) and a fixing process to complete an image. In the transfer, all colors are transferred from the color photoreceptors 210Bk, C, M, and Y to the intermediate transfer belt 220 by applying a bias to the primary transfer devices 230Bk, C, M, and Y, and then another secondary transfer. The image is transferred to a transfer sheet by applying a bias to the roller 600.

  Next, the photoconductor cleaning device will be described in detail. In FIG. 1, the developing devices 200Bk, C, M, and Y are connected to the cleaning devices 300Bk, C, M, and Y by toner transfer tubes 250Bk, C, M, and Y, respectively (broken lines in FIG. 1). ). Each of the toner transfer pipes 250Bk, C, M, and Y includes a screw (not shown), and the toner collected by each of the cleaning devices 300Bk, C, M, and Y is stored in the developing devices 200Bk, It is transferred to C, M, and Y.

  In the conventional direct transfer method using a combination of four photosensitive drums and belt conveyance, paper dust adheres when the photoreceptor and the transfer paper come into contact with each other. Image deterioration such as omission occurred and could not be used. Furthermore, in a conventional system combining a single photoconductor drum and an intermediate transfer member, the use of the intermediate transfer member eliminates the adhesion of paper dust to the photoconductor during paper transfer, but the remaining toner is recycled to the photoconductor. When trying to do so, it is practically impossible to separate the mixed color toner. There is also a proposal to use a mixed color toner as a black toner, but even if all the colors are mixed, it does not become black, and the color changes depending on the print mode. Therefore, it is impossible to recycle the toner with one photoconductor configuration.

  On the other hand, in the printer according to the present embodiment, since the intermediate transfer belt 220 is used, paper dust is less mixed, and adhesion of paper dust to the intermediate transfer belt 220 during paper transfer is prevented. Since each of the photoconductors 210Bk, C, M, and Y uses an independent color toner, it is possible to reliably collect only the toner without having to contact or separate the photoconductor cleaning devices 300BBk, C, M, and Y.

The positively charged toner remaining on the intermediate transfer belt 220 is cleaned by a conductive fur brush 262 to which a negative voltage is applied. The method for applying a voltage to the conductive fur brush 262 is exactly the same as the conductive fur brush 261 except that the polarity is different. The toner remaining without being transferred is also almost cleaned by the two conductive fur brushes 261 and 262. Here, toner, paper powder, talc, and the like remaining without being cleaned by the conductive fur brush 262 are negatively charged by the negative voltage of the conductive fur brush 262.
The next black primary transfer is a transfer with a positive voltage, and negatively charged toner or the like is attracted to the intermediate transfer belt 220 side, so that the transfer to the photoreceptor (black) 210Bk side can be prevented.

  Next, the intermediate transfer belt 220 used in the image forming apparatus of this embodiment will be described. As described above, the intermediate transfer belt is preferably a single resin layer, but may have an elastic layer or a surface layer as necessary.

  As the resin material constituting the resin layer 220a, polycarbonate, fluororesin (ETFE, PVDF), polystyrene, chloropolystyrene, poly-α-methylstyrene, styrene-butadiene copolymer, styrene-vinyl chloride copolymer, Styrene-vinyl acetate copolymer, styrene-maleic acid copolymer, styrene-acrylic acid ester copolymer (styrene-methyl acrylate copolymer, styrene-ethyl acrylate copolymer, styrene-butyl acrylate copolymer) Styrene-octyl acrylate copolymer and styrene-phenyl acrylate copolymer), styrene-methacrylic acid ester copolymer (styrene-methyl methacrylate copolymer, styrene-ethyl methacrylate copolymer, styrene) -Phenyl methacrylate copolymer, etc.) Styrenic resins (monopolymer or copolymer containing styrene or styrene-substituted product) such as styrene-α-chloromethyl acrylate copolymer, styrene-acrylonitrile-acrylate ester copolymer, methyl methacrylate resin, methacryl Acid butyl resin, ethyl acrylate resin, butyl acrylate resin, modified acrylic resin (silicone modified acrylic resin, vinyl chloride resin modified acrylic resin, acrylic / urethane resin, etc.), vinyl chloride resin, styrene-vinyl acetate copolymer, chloride Vinyl-vinyl acetate copolymer, rosin-modified maleic acid resin, phenol resin, epoxy resin, polyester resin, polyester polyurethane resin, polyethylene, polypropylene, polybutadiene, polyvinylidene chloride, ionomer resin, polyurethane resin, silica Over down resin, ketone resin, ethylene - can be used ethyl acrylate copolymer, xylene resin and polyvinyl butyral resin, polyamide resin, one kind or two kinds or more selected from the group consisting of modified polyphenylene oxide resin. However, it is a matter of course that the material is not limited to the above materials.

  In addition, as the elastic material (elastic material rubber, elastomer) constituting the elastic layer 220b, butyl rubber, fluorine rubber, acrylic rubber, EPDM, NBR, acrylonitrile-butadiene-styrene rubber natural rubber, isoprene rubber, styrene-butadiene rubber , Butadiene rubber, Ethylene-propylene rubber, Ethylene-propylene terpolymer, Chloroprene rubber, Chlorosulfonated polyethylene, Chlorinated polyethylene, Urethane rubber, Syndiotactic 1,2-polybutadiene, Epichlorohydrin rubber, Ricone rubber, Fluoro rubber , Polysulfide rubber, polynorbornene rubber, hydrogenated nitrile rubber, thermoplastic elastomer (eg polystyrene, polyolefin, polyvinyl chloride, polyurethane, polyamide, polyurea, polyester Ether-based, it may be used one kind or two kinds or more selected from the group consisting of fluorocarbon resin) or the like. However, it is a matter of course that the material is not limited to the above materials.

  The material of the surface layer 220c is not particularly limited, but a material that reduces the adhesive force of the toner to the surface of the intermediate transfer belt 220 and increases the secondary transfer property is required. For example, materials that use one or more of polyurethane, polyester, epoxy resin, etc. to reduce surface energy and improve lubricity, such as fluorine resin, fluorine compound, fluorocarbon, titanium dioxide, silicon carbide, etc. One kind or two or more kinds of powders and particles or particles having different particle diameters can be dispersed and used. Further, it is also possible to use a material having a reduced surface energy by forming a fluorine-rich layer on the surface by heat treatment, such as a fluorine-based rubber material.

  A resistance value adjusting conductive agent is added to the resin layer 220a and the elastic layer 220b. The conductive agent for adjusting the resistance value is not particularly limited. For example, carbon black, graphite, metal powder such as aluminum and nickel, tin oxide, titanium oxide, antimony oxide, indium oxide, potassium titanate, antimony oxide-tin oxide Conductive metal oxides such as composite oxide (ATO), indium oxide-tin oxide composite oxide (ITO), and conductive metal oxides are coated with insulating fine particles such as barium sulfate, magnesium silicate, and calcium carbonate. It may be a thing. Of course, the conductive agent is not limited thereto.

The intermediate transfer belt 220 according to this embodiment has a volume resistivity of 10 ¹² [Ωcm] or more and 10 ¹⁴ [Ωcm] or less. If the volume resistivity of the intermediate transfer belt 220 is too smaller than 10 ¹² [Ωcm], the toner holding force is insufficient on the belt surface in the range from the primary transfer position to the secondary transfer position, and toner dust occurs. On the other hand, if it is larger than 10 ¹⁴ [Ωcm], the neutralization by the ground supporting roller is insufficient, and charges due to secondary transfer accumulate on the belt surface in the range from the secondary transfer position to the primary transfer position. As a result, primary transfer unevenness occurs, causing image unevenness. In order to prevent this image unevenness, it is necessary to provide a dedicated static eliminator, leading to an increase in cost. Therefore, if the volume resistivity of the intermediate transfer belt 220 is 10 ¹² [Ωcm] or more and 10 ¹⁴ [Ωcm] or less, generation of toner dust and cost increase due to installation of a dedicated static eliminator can be prevented.

  Examples of the method for manufacturing the intermediate transfer belt 220 include a centrifugal molding method in which a material is poured into a rotating cylindrical mold to form a belt, a spray coating method in which a thin film is formed on the surface layer, and a cylindrical mold as a material solution. There are a dipping method in which it is soaked in a mold, a casting method in which it is injected into an inner mold and an outer mold, and a method in which a compound is wound around a cylindrical mold and vulcanized and polished. Of course, belts can be manufactured by combining manufacturing methods.

An example of a method for manufacturing the intermediate transfer belt 220 by the casting method will be described.
A cylindrical mold is immersed in a dispersion in which 18 parts by weight of carbon black, 3 parts by weight of a dispersant, and 400 parts by weight of toluene are uniformly dispersed with respect to 100 parts by weight of PVDF, gently lifted at 10 mm / sec, and dried at room temperature. A uniform film of 75 μm PVDF is formed. A mold having a 75 μm film is repeatedly immersed in the dispersion under the above conditions, and the mold is gently lifted at 10 mm / sec and dried at room temperature to form a resin layer 220a of a 150 μm PVDF belt.

  The 150 μm PVDF resin layer 220a is formed in a dispersion obtained by uniformly dispersing 100 parts by weight of a polyurethane prepolymer, 3 parts by weight of a curing agent (isocyanate), 20 parts by weight of carbon black, 3 parts by weight of a dispersant, and 500 parts by weight of MEK. The cylindrical mold is dipped and pulled up at 30 mm / sec to perform natural drying. The drying is repeated after drying to form a target elastic layer 220b of 150 μm urethane polymer layer on the surface of the resin layer 220a.

  Further, 100 parts by weight of polyurethane prepolymer, 3 parts by weight of curing agent (isocyanate), 50 parts by weight of PTFE fine powder, 4 parts by weight of dispersant, and 500 parts by weight of MEK are uniformly dispersed for the surface layer 220c. The dispersion is immersed in a cylindrical mold in which the PVDF resin layer 220a and the urethane prepolymer elastic layer 220b are formed, and is naturally dried by pulling it up at 30 mm / sec. After drying, the above operation is repeated to form a urethane polymer surface layer 220c in which 5 μm of PTFE is uniformly dispersed. After drying at room temperature, crosslinking was performed at 130 ° C. for 2 hours to obtain an intermediate transfer belt having a three-layer structure of resin layer 220a; 150 μm, elastic layer 220b; 150 μm, surface layer 220c;

  As a method of preventing the elongation of the intermediate transfer belt 220, a method of forming the rubber elastic layer 220b on the resin layer 220a of the core body having a small elongation as in the above manufacturing method, or a material for preventing the elongation of the core body layer is added. Although there are methods, various production methods can be used. Examples of the material for preventing the core layer from stretching include natural fibers such as cotton and silk, polyester fibers, nylon fibers, acrylic fibers, polyolefin fibers, polyvinyl alcohol fibers, polyvinyl chloride fibers, polyvinylidene chloride fibers, and polyurethanes. 1 or 2 types selected from the group consisting of synthetic fibers such as fibers, polyacetal fibers, polyfluoroethylene fibers and phenol fibers, inorganic fibers such as carbon fibers, glass fibers and boron fibers, and metal fibers such as iron fibers and copper fibers By using the above, a woven fabric or a yarn can be obtained. Of course, the material is not limited to the above.

  The yarn may be twisted by one or a plurality of filaments, one twisted yarn, various twisted yarns, twin yarn, or the like. Further, for example, fibers of a material selected from the above material group may be blended. Of course, the yarn can be used after being subjected to an appropriate conductive treatment. On the other hand, the woven fabric can be any woven fabric such as knitted fabric, and of course, a woven fabric that is interwoven can also be used, and naturally conductive treatment can be applied.

  The production method for providing the core layer is not particularly limited. For example, a method of providing a woven fabric woven in a cylindrical shape on a mold and providing a coating layer thereon, the woven fabric woven in a cylindrical shape is a liquid rubber And a method of providing a coating layer on one side or both sides of the core layer, and a method of winding a thread spirally around a mold at an arbitrary pitch and providing a coating layer thereon.

The thickness of the elastic layer 220b depends on the hardness of the elastic layer 220b, but if it is too thick, the surface expands and contracts and cracks are likely to occur in the surface layer. In addition, it is not preferable that the thickness is too large because the amount of expansion / contraction increases and the expansion / contraction of the image increases. Therefore, the thickness of the elastic layer 220b is desirably thinner than about 1 mm.

  The appropriate range of the hardness (HS) of the intermediate transfer belt 220 is 10 ° ≦ HS ≦ 60 ° (JIS K7215 (A type)). Although the optimum hardness varies depending on the layer thickness of the intermediate transfer belt 220, in this embodiment, when the hardness is within the above range, the transfer rate can be improved, the amount of recycled toner can be reduced, and image deterioration can be further avoided to prevent image deterioration. Quality can be maintained. If the hardness is less than 10 ° (JIS K7215 (A type)), it is very difficult to mold with high dimensional accuracy. This is due to the fact that it is susceptible to shrinkage and expansion during molding. Moreover, when making it soft, it is a general method to contain an oil component in the base material, but there is a drawback that the oil component oozes out when continuously operated under pressure.

  It has been found that when the oil component that has oozed out adheres to each of the photoreceptors 210Bk, C, M, and Y that are in contact with the intermediate transfer belt 220, the photoreceptor is deteriorated and horizontal band-like unevenness is generated. In general, the surface layer 220c is provided to improve releasability. However, in order to completely prevent the seepage, the durability of the surface layer 220c is improved, and it is difficult to select materials and secure characteristics. Become. On the other hand, when the hardness is larger than 60 ° (JIS K7215 (A type)), it can be molded with high accuracy because of the increased hardness, and the oil content can be suppressed to a low level. Therefore, deterioration of the photoconductor can be reduced.

  In the above-described embodiment, the configuration of the intermediate transfer belt has been described. However, not only the intermediate transfer belt but also a drum-shaped intermediate transfer member can be cleaned. Further, the present invention can be applied to a cleaning device that cleans the photosensitive member.

(Description of fixing device)
Fixing device A
The fixing device shown in FIG. 2 is set under the following conditions. The standard fixing set temperature of the fixing belt is 130 ° C., but the fixing temperature can be changed.
Belt speed ... 150mm / sec
Fixing nip pressure: Variable by pressing on both sides. (Example values are listed in Table 1)
Fixing roller (opposite rotating body) Roller diameter: Φ40 mm (inner layer (center): stainless steel cored bar φ24 mm, surface layer: elastic layer of silicon foam, thickness 8 mm)
Pressure roller: Roller outer diameter: Φ40 mm (inner layer (center part): cavity (diameter of the cavity part φ37 mm), outward, iron core metal having a thickness of 1 mm, Si rubber layer: thickness 0.5 mm, Furthermore, the surface layer is PFA tube layer; thickness 30μm)
Heating roller: Roller outer diameter: Φ30 mm, halogen heater in the center. The outer layer is made of aluminum and has a thickness of 2 mm. Fixing belt: belt diameter: Φ60 mm, the following two layers are formed from the inner layer (substrate) to the surface layer.
・ Substrate: Nickel layer of about 40 μm thickness
Surface layer: Silicon rubber of about 150 μm, surface roughness Rz: 3.3 μm
Belt width: 310mm
Oil application roller: Oil application amount: 2mg / A4 per size

Fixing device B
The following two changes are made from the fixing device A.
(1) Oil application amount: per 0.5 mg / A4 size (2) Change the release layer of the fixing belt to about 50 μm fluororesin and surface roughness 6.0 μm

Fixing device C
FIG. 3 shows an example of a belt induction heating fixing device related to the present invention.
The fixing device shown in FIG. 3 includes a heating roller 1 heated by electromagnetic induction of induction heating means 6, a fixing roller 2 (opposite rotating body) arranged in parallel with the heating roller 1, and the heating roller 1 and the fixing roller 2. And an endless belt-like heat-resistant belt (toner heating medium) 3 that is heated by the heating roller 1 and rotated in the direction of arrow A by at least one of these rollers, and fixing via the belt 3 A pressure roller 4 (pressure rotator) that is pressed against the roller 2 and rotates in the forward direction with respect to the belt 3 is configured.

  The heating roller 1 is made of a hollow cylindrical magnetic metal member such as iron, cobalt, nickel, or an alloy of these metals, and has a low heat capacity with an outer diameter of 20 to 40 mm and a thickness of 0.3 to 1.0 mm, for example. The temperature rises quickly.

  The fixing roller 2 (opposing rotating body) includes a metal core 2a made of, for example, stainless steel, and an elastic member 2b covered with the core 2a in a solid or foamed heat-resistant silicone rubber. In order to form a contact portion having a predetermined width between the pressure roller 4 and the fixing roller 2 by the pressing force from the pressure roller 4, the outer diameter is set to about 20 to 40 mm, which is larger than that of the heating roller 1. . The elastic member 2b has a thickness of about 4 to 6 mm. With this configuration, the heat capacity of the heating roller 1 is smaller than the heat capacity of the fixing roller 2, so that the heating roller 1 is rapidly heated and the warm-up time is shortened.

  The belt 3 stretched between the heating roller 1 and the fixing roller 2 is heated at the contact portion W1 with the heating roller 1 heated by the induction heating means 6. The inner surface of the belt 3 is continuously heated by the rotation of the rollers 1 and 2, and as a result, the entire belt is heated.

FIG. 4 shows the configuration of the belt 3. The configuration of the belt 2 is as follows.
The following four layers are formed from the inner layer to the surface layer.
・ Substrate (resin layer: polyimide (PI) resin, etc.)
・ Heat generation layer (Ni, Ag, SUS, etc. as conductive material): 3a
・ Intermediate layer (Aiming for uniform fixing with an elastic layer): 3b
・ Surface layer (release layer) (Aimed at release effect and oil-less with fluororesin material): 3c

  The thickness of the release layer 3c is preferably about 10 μm to 300 μm, particularly about 200 μm. By doing so, the toner image T formed on the recording material 11 is sufficiently wrapped by the surface layer portion of the belt 3, so that the toner image T can be uniformly heated and melted.

The thickness of the release layer c, that is, the surface release layer, is required to be at least 10 μm in order to ensure wear resistance over time.
Further, when the thickness of the release layer 3c is larger than 300 μm, the heat capacity of the belt 3 is increased and the time required for warm-up is increased. In addition, in the toner fixing process, the belt surface temperature is difficult to decrease, the agglomeration effect of the melted toner at the fixing portion outlet cannot be obtained, the belt releasability is reduced, and the toner adheres to the belt. Hot offset occurs.

  As a base material for the belt 3, a heat-resistant resin layer such as a fluorine resin, a polyimide resin, a polyamide resin, a polyamideimide resin, a PEEK resin, a PES resin, or a PPS resin is used instead of the heat generating layer 3a made of the metal. May be used.

The pressure roller 4 includes a cored bar 4a made of a cylindrical member made of a metal having high thermal conductivity such as copper or aluminum, and an elastic member having high heat resistance and toner releasability provided on the surface of the cored bar 4a. 4b. In addition to the above metal, SUS may be used for the core metal 4a.
The pressure roller 4 presses the fixing roller 2 via the belt 3 to form the fixing nip portion N, but in this embodiment, the pressure roller 4 is harder than the fixing roller 2. As a result, the pressure roller 4 bites into the fixing roller 2 (and the belt 3), and the recording material 11 follows the circumferential shape of the surface of the pressure roller 4 by this biting. Has the effect of facilitating. The outer diameter of the pressure roller 4 is about 20 to 40 mm, which is the same as that of the fixing roller 2, but the wall pressure is about 0.5 to 2.0 mm, which is thinner than the fixing roller 2.

As shown in FIG. 3, the induction heating means 6 for heating the heating roller 1 by electromagnetic induction has an exciting coil 7 as a magnetic field generating means and a coil guide plate 8 around which the exciting coil 7 is wound. Yes. The coil guide plate 8 has a semi-cylindrical shape that is disposed close to the outer peripheral surface of the heating roller 1, and the exciting coil 7 is formed by passing a long exciting coil wire along the coil guide plate 8 in the axial direction of the heating roller 1. It is one that is wound around alternately. The exciting coil 7 is connected to a driving power source (not shown) whose oscillation circuit has a variable frequency.
Outside the excitation coil 7, a semi-cylindrical excitation coil core 9 made of a ferromagnetic material such as ferrite is fixed to the excitation coil core support member 10 and is disposed close to the excitation coil 7.

In the above configuration, the following conditions were set as specific examples.
Fixing roller; outer diameter φ38 mm (inner layer (center): stainless steel core metal φ28 mm, outer layer: elastic layer of silicone rubber foam layer thickness 5 mm, rubber hardness: 25 Hs))
Pressure roller; outer diameter φ40 mm (inner layer (center): aluminum core metal φ37 mm, iron core bar 1.0 mm thick toward the outside, and Si rubber layer: thickness 0.5 mm (rubber hardness: 60 Hs) ) Furthermore, the surface layer is a PFA tube layer; thickness 30 μm)
Heating roller; outer diameter φ30mm (inside hollow, surrounding is 0.8mm thick magnetic iron oxide layer)
Fixing conditions: belt speed: 289 mm / sec, nip pressure: variable on both sides. (Example values are listed in Table 1)
Fixing belt: The following four layers from the inner layer to the surface layer (inner layer side) PI (50 μm) + Ni (40 μm) + Si rubber (150 μm) + fluorine resin (20 μm) (surface layer side)

Example of toner production [toner]
Constituent material of toner a Binder resin: polyol resin (1/2 outflow start temperature 118 ° C.) 100 parts by weight Colorant For yellow toner: benzimidazolone yellow pigment
(C.I. Pigment Yellow 180) 5 parts by weight
For magenta toner: Quinacridone magenta pigment
(C.I. Pigment Red122) 4 parts by weight
For cyan toner: Copper phthalocyanine blue pigment
(C.I. Pigment Blue 15) 2 parts by weight
For black kutner: Carbon black 6 parts by weight Charge control agent: Salicylic acid derivative zinc salt 2 parts by weight

Constituent material for toner b Binder resin: polyester resin (1/2 outflow start temperature 118 ° C.) 97 parts by weight Release agent: 3 parts by weight carnauba wax Colorant, charge control agent: same as toner a

Toner c Constituent material Binder resin: 100 parts by weight of polyester resin (1/2 outflow start temperature: 106 ° C.) Colorant, charge control agent: similar to toner a

The toner constituent materials a to c were sufficiently mixed with a blender for each color, and then melt-kneaded with a biaxial extruder heated to 100 to 110 ° C. The kneaded product was allowed to cool and then coarsely pulverized by a cutter mill, pulverized by a fine pulverizer using a jet stream, and each color base color particle of each toner was obtained using an air classifier. The weight average particle diameter of the obtained particles is shown in Table 1.
In addition, the shape factor SF-1 of each toner was as follows.
Toner a: 160, Toner b: 165, Toner c: 163

Toner d constituent material Same as toner a. Toner a was obtained by using a surffusion system apparatus (manufactured by Hosokawa Micron Industry Co., Ltd .: air flow set temperature: 270 ° C., feed amount: 1 kg / Hr) to obtain roughly spherical base colored particles. The shape factor SF-1 of the matrix coloring particles was 112.
Furthermore, 1.5 parts by weight of hydrophobic silica having an average particle diameter of 0.12 μm and 1.0 part by weight of titanium oxide having an average particle diameter of 0.02 μm are added to 100 parts by weight of the matrix-colored particles a to d. Were mixed to obtain yellow, magenta, cyan, and black toners.

Preparation of toner e (synthesis of toner binder resin)
724 parts of bisphenol A ethylene oxide 2-mole adduct, 276 parts of isophthalic acid and 2 parts of dibutyltin oxide are placed in a reaction vessel equipped with a cooling tube, a stirrer and a nitrogen introduction tube, and reacted at 230 ° C. for 8 hours at normal pressure. Further, the mixture was reacted at a reduced pressure of 10 to 15 mmHg for 5 hours, then cooled to 160 ° C., 32 parts of phthalic anhydride was added thereto and reacted for 2 hours. Subsequently, it cooled to 80 degreeC and reacted with 188 parts of isophorone diisocyanate in ethyl acetate for 2 hours, and the isocyanate containing prepolymer (1) was obtained. Next, 267 parts of prepolymer (1) and 14 parts of isophoronediamine were reacted at 50 ° C. for 2 hours to obtain a urea-modified polyester resin (1) having a weight average molecular weight of 64,000. In the same manner as above, 724 parts of bisphenol A ethylene oxide 2-mole adduct and 276 parts of terephthalic acid were polycondensed at 230 ° C. for 8 hours under normal pressure, and then reacted for 5 hours at a reduced pressure of 10 to 15 mmHg. An unfinished polyester resin (a) was obtained. 200 parts of the urea-modified polyester resin (1) and 800 parts of the unmodified polyester resin (a) are dissolved and mixed in 2000 parts of an ethyl acetate / MEK (1/1) mixed solvent to mix the ethyl acetate of the toner binder resin (1). / MEK solution was obtained. Part of the mixture was dried under reduced pressure to isolate the toner binder resin (1). The Tg was 62 ° C. and the acid value was 10 mgKOH / g.

(Production of toner)
In a beaker, 240 parts of the ethyl acetate / MEK solution of the toner binder resin (1), 20 parts of pentaerythritol tetrabehenate (melting point: 81 ° C., melt viscosity: 25 cps), and 4 parts of copper phthalocyanine blue pigment were placed at 60 ° C. Then, the mixture was stirred at 12000 rpm with a TK homomixer, and uniformly dissolved and dispersed. In a beaker, 706 parts of ion-exchanged water, 294 parts of hydroxyapatite 10% suspension (Superite 10 manufactured by Nippon Chemical Industry Co., Ltd.) and 0.8 part of sodium dodecylbenzenesulfonate were uniformly dissolved. Next, the temperature was raised to 60 ° C., and the toner material solution was added and stirred for 10 minutes while stirring at 12000 rpm with a TK homomixer. Next, this mixed solution was transferred to a Kolben equipped with a stir bar and a thermometer, heated to 98 ° C. to partially remove the solvent, returned to room temperature, stirred at 12000 rpm with the same homomixer, and the solvent was completely removed. Removed. Then, after filtering, washing and drying, air classification was performed to obtain base toner particles. The weight average particle diameter was 4.0 μm, and the shape factor SF-1 of the toner e was 110.
Further, 1.5 parts by weight of hydrophobic silica and 1.0 part by weight of titanium oxide were mixed with 100 parts by weight of the base colored particles e by a Henschel mixer to obtain a toner.

[Evaluation of fixability]
Two-component development of yellow, magenta, cyan, and black by mixing with a tumbler mixer at a ratio of 5 parts by weight to 100 parts by weight of carrier having silicon particles coated on ferrite particles with an average particle size of 50 μm An agent was used. These developers are loaded into the developing unit of a Ricoh copier Ipsio 8200, and the transfer paper is Gilbert Lancaster bond paper (surface smoothness: 18S) or resource type A of Ricoh recycled paper (surface smoothness: 34S). A full color image was obtained. The obtained images are solid images and halftone images of yellow, magenta, cyan, and black, and solid images of green, blue, and red as intermediate colors. Note The copier is adjusted so that the solid portion of the monochromatic 1.0 toner ± 0.1 mg / cm ² is monochromatic halftone portions of 0.4 ± 0.1mg / cm ² toner is developed Has been. In addition, the original fixing device is removed and another fixing device can be attached. For the evaluation of fixability, the lower limit fixing temperature is used. The lower limit fixing temperature is the fixing belt temperature at which the residual ratio of the image density after rubbing the obtained fixed image with a pad becomes 70% or more. did.

Example 1
The image forming apparatus of the present invention (the secondary transfer nip pressure of the image forming apparatus shown in FIG. 1 is set to 5.5 N / cm ² ). Further, the fixing device A is used as the fixing device, and the fixing setting temperature is set to the standard fixing temperature (130). And a fixed image of toner a was obtained. As a result, the lower limit fixing temperature was 110 ° C., and the fixed image at the time of printing 10,000 sheets at the standard fixing temperature was a clear image with no occurrence of offset. Thereafter, the fixing portion was disassembled and the belt surface and the oil application pad were examined, but no contamination with toner was observed. The evaluation results are shown in Table 1.

(Example 2)
The image forming apparatus of the present invention (the nip pressure of the secondary transfer of the image forming apparatus shown in FIG. 1 is set to 4.5 N / cm ² ) Further, the fixing device B is used as the fixing device, and the fixing setting temperature is set to the standard fixing temperature (130 And a fixed image of toner b was obtained. The lower limit fixing temperature was 115 ° C., and then the fixing setting temperature was returned to the standard fixing temperature, and 10,000 sheets were printed. Similar to Example 1, an image with no offset was also obtained as a fixed image when printing 10,000 sheets. Further, the state where the belt surface was contaminated with toner was not observed. The evaluation results are shown in Table 1.

(Example 3)
The image forming apparatus of the present invention (the nip pressure of the secondary transfer of the image forming apparatus shown in FIG. 1 is set to 7.0 N / cm ² ). Further, the fixing device C is used as the fixing device, and the fixing setting temperature is set to the standard fixing temperature (130 And a fixed image of toner b was obtained. The minimum fixing temperature was 110 ° C., and a clear image was obtained. Thereafter, the fixing set temperature was returned to the standard fixing temperature, and 10,000 sheets were printed. Similar to Example 1, an image with no occurrence of offset was obtained as a fixed image when printing 10,000 sheets. Further, the state where the belt surface was contaminated with toner was not observed. The evaluation results are shown in Table 1.

Example 4
The image forming apparatus of the present invention (the nip pressure of the secondary transfer of the image forming apparatus shown in FIG. 1 is set to 9.5 N / cm ² ). Further, the fixing device C is used as the fixing device, and the fixing setting temperature is set to the standard fixing temperature ( 130 ° C.), and a fixed image of toner c was obtained. The minimum fixing temperature was 105 ° C., and a clear image was obtained. Thereafter, the fixing set temperature was returned to the standard fixing temperature, and 10,000 sheets were printed. Similar to Example 1, an image with no occurrence of offset was obtained as a fixed image when printing 10,000 sheets. In addition, the state where the belt surface and the oil application roller were contaminated with toner was not observed. The evaluation results are shown in Table 1.

(Example 5)
The image forming apparatus of the present invention (the secondary transfer nip pressure of the image forming apparatus shown in FIG. 1 is set to ^2.5 N / cm ² ). Further, the fixing device A is used as the fixing device, and the fixing set temperature is set to the standard fixing temperature (130 And a fixed image of toner d was obtained. The minimum fixing temperature was 105 ° C., and a clear image was obtained. Thereafter, the fixing set temperature was returned to the standard fixing temperature, and 10,000 sheets were printed. Similar to Example 1, an image with no occurrence of offset was obtained as a fixed image when printing 10,000 sheets. In addition, the state where the belt surface and the oil application roller were contaminated with toner was not observed. The evaluation results are shown in Table 1.

(Example 6)
The image forming apparatus of the present invention (the secondary transfer nip pressure of the image forming apparatus shown in FIG. 1 is set to 5.5 N / cm ² ). Further, the fixing device A is used as the fixing device, and the fixing setting temperature is set to the standard fixing temperature (130). And a fixed image of toner e was obtained. The minimum fixing temperature was 105 ° C., and a clear image was obtained. Thereafter, the fixing set temperature was returned to the standard fixing temperature, and 10,000 sheets were printed. Similar to Example 1, an image with no occurrence of offset was obtained as a fixed image when printing 10,000 sheets. Further, the state where the belt surface was contaminated with toner was not observed. The evaluation results are shown in Table 1.

(Example 7)
The image forming apparatus of the present invention (the secondary transfer nip pressure of the image forming apparatus shown in FIG. 1 is set to 5.5 N / cm ² ). Further, the fixing device A is used as the fixing device, and the fixing setting temperature is set to the standard fixing temperature (130). And a fixed image of toner a was obtained. The fixing minimum temperature was 115 ° C., and a clear image was obtained. Thereafter, the fixing set temperature was returned to the standard fixing temperature, and 10,000 sheets were printed. Similar to Example 1, an image with no occurrence of offset was obtained as a fixed image when printing 10,000 sheets. In addition, the state where the belt surface and the oil application roller were contaminated with toner was not observed. The evaluation results are shown in Table 1.

(Example 8)
The image forming apparatus of the present invention (the nip pressure of the secondary transfer of the image forming apparatus shown in FIG. 1 is set to 5.5 N / cm ² ) Further, the fixing device C is used as the fixing device, and the fixing setting temperature is set to the standard fixing temperature (130 And a fixed image of toner c was obtained. The minimum fixing temperature was 105 ° C., and a clear image was obtained. Thereafter, the fixing set temperature was returned to the standard fixing temperature, and 10,000 sheets were printed. As in Example 1,
An image with no offset was also obtained as a fixed image when printing 10,000 sheets. In addition, the state where the belt surface and the oil application roller were contaminated with toner was not observed. The evaluation results are shown in Table 1.

(Comparative Example 1)
A fixed image of toner a was obtained in the same manner as in Example 1 except that the nip pressure of the secondary transfer of the image forming apparatus shown in FIG. 1 of the image forming apparatus of the present invention was changed to 1.5 N / cm ² . The minimum fixing temperature rose to 155 ° C. The evaluation results are shown in Table 1.

(Comparative Example 2)
A fixed image of toner a was obtained in the same manner as in Example 1 except that the nip pressure of the secondary transfer of the image forming apparatus of the present invention shown in FIG. 1 was changed to 10.6 N / cm ² . The minimum fixing temperature was 105 ° C. As in Example 1, when a fixed image at the time of printing 10,000 sheets was confirmed, contamination due to an offset corresponding to a solid image occurred on the image surface. The evaluation results are shown in Table 1.

(Comparative Example 3)
Evaluation similar to Example 1 was performed except that the fixing nip pressure was changed from Example 1. The nip pressure and evaluation results are shown in Table 1.

(Comparative Example 4)
Evaluation similar to Example 1 was performed except that the fixing nip pressure was changed from Example 1. The nip pressure and evaluation results are shown in Table 1.

(Comparative Example 5)
Evaluation was performed in the same manner as in Example 1 except that the weight average particle diameter of the toner a used in Example 1 was changed to 5.8 μm by changing the pulverization classification conditions to obtain toner f. The shape factor SF-1 of the toner f was 168. The evaluation results are shown in Table 1.

(Comparative Example 6)
Evaluation was performed in the same manner as in Example 1 except that the weight average particle diameter of the toner a used in Example 1 was changed to 1.8 μm by changing the pulverization classification conditions to obtain toner g. The shape factor SF-1 of the toner g was 150. The evaluation results are shown in Table 1.

1 is a diagram illustrating a configuration of an image forming apparatus used as an embodiment of the present invention. 1 is a diagram illustrating an example of a fixing device used in an image forming apparatus of the present invention. 1 is a diagram illustrating an example of a fixing device used in an image forming apparatus of the present invention. FIG. 3 is a diagram illustrating an example of a layer configuration of a belt used in a fixing device. It is a figure which shows the example of a layer structure of the amorphous silicon photoreceptor used in the image forming apparatus of this invention. FIG. 2 is a schematic diagram illustrating an example of a developing device used in the image forming apparatus of the present invention. FIG. 2 is a schematic view showing an example of a contact charging device (roller type) used in the image forming apparatus of the present invention. FIG. 2 is a schematic diagram illustrating an example of a contact charging device (brush type) used in the image forming apparatus of the present invention. 2 is a schematic view of a process cartridge used in the image forming apparatus of the present invention. FIG.

Explanation of symbols

1 Heating roller 2 Fixing roller (opposite rotating body)
2a Core 2b Elastic member 3 Heat resistant belt (toner heating medium)
4 Pressure roller (Pressure rotating body)
4a Core 4b Elastic member 5 Temperature detection member 6 Induction heating means 7 Excitation coil 8 Coil guide plate 9 Excitation coil core 10 Excitation coil core support member 11 Recording material 100 Main body 120 Image writing unit 120Bk, C, M, Y
130 Image forming unit 130Bk, C, M, Y
140 Paper Feed Unit 150 Fixing Device 160 Registration Roller Pair 200 Developing Device 200Bk, C, M, Y
210 photoconductor 210Bk, C, M, Y
215 Charging device 215BBk, C, M, Y
220 Intermediate transfer belt 230 Primary transfer device 230Bk, C, M, Y
241 conductive roller 242 conductive roller 243 conductive roller 250 toner transfer tube 250Bk, C, M, Y
260 Intermediate transfer belt cleaning device 261 Conductive fur brush 262 Conductive fur brush 300 Cleaning device 300Bk, C, M, Y
500 Transfer belt 600 Secondary transfer roller 200Bk Developing device (black)
200C Developer (Cyan)
200M Developer (Magenta)
200Y Development device (yellow)
210Bk photoconductor (black)
220 Intermediate transfer belt N1 Magnetic pole N2 Magnetic pole S1 Magnetic pole S2 Magnetic pole S3 Magnetic pole R1: Fixing roller (opposite rotating body)
R2: Pressure roller (Pressure rotating body)
R3: Heating roller R4: Oil application roller B Fixing belt (endless belt)
T Unfixed toner image P Print sheet (transfer paper)
S Temperature sensor G Guide H Heating source N Fixing nip W1 Contact area

Claims (13)

At least a step of charging the electrostatic latent image carrier to form an electrostatic charge image on the electrostatic latent image carrier, and developing the electrostatic image formed on the electrostatic latent image carrier with toner to form a toner image Developing on the electrostatic latent image carrier, transferring the obtained toner image onto the intermediate transfer member, transferring the toner image on the intermediate transfer member onto the transfer material, toner on the transfer material In a full color image forming method including a step of fixing an image with a heat and pressure fixing member, the toner contains at least a binder resin and a colorant, and the toner has a weight average particle diameter (D4) of 2 to 5 μm, The nip pressure during secondary transfer from the intermediate transfer member is 2 to 10 N / cm ² , the surface smoothness of the transfer material is 40 S or less, and the nip pressure of the fixing member is 10 to 50 N / cm ^2. A full color image forming method.   2. The full color image forming method according to claim 1, wherein the toner has a shape factor SF-1 of 110 to 150.   The full-color image forming method according to claim 1, wherein fine particles having an average particle diameter of 0.04 to 0.30 μm are attached to the surface of the toner.   The full color according to any one of claims 1 to 3, wherein the toner further contains a release agent, and the content of the release agent is 3 to 10% by weight based on the weight of the toner. Image forming method.   The full-color image forming method according to claim 1, wherein the toner is produced in an aqueous medium.   6. The full-color image forming method according to claim 1, wherein the full-color image forming method is performed using a tandem type electrophotographic image forming process.   The full-color image forming method according to claim 1, wherein the intermediate transfer member is composed of a single resin layer.   The step of fixing with the pressure fixing member includes arranging a plurality of rotating bodies inside an endless belt having an elastic layer on the surface, and at least one of the rotating bodies is a heating roller, and the endless belt The endless belt is crushed by a pressure rotator located outside and a counter rotator arranged to face the pressure rotator through the endless belt among the plurality of rotators, and the endless belt 8. The full color image forming method according to claim 1, wherein the toner image on the transfer material is heated and fixed by a nip portion formed by the pressure rotating body.   9. The full-color image forming method according to claim 8, wherein the heating roller is made of a magnetic metal and is heated by electromagnetic induction by electromagnetic induction generating means, whereby the belt is heated.   The full-color image according to claim 9, wherein the electromagnetic induction generating means is provided outside the heating roller via an endless belt, and is provided separately from the opposing rotating body and the heating rotating body. Forming method.   The full-color image forming method according to claim 1, wherein the electrostatic latent image carrier is an amorphous silicon photoconductor.   The full-color image forming method according to claim 1, wherein an alternating electric field is applied when the latent image on the latent image carrier is developed.   The charging device for charging the latent image carrier is a charging device that performs charging by bringing a charging member into contact with the latent image carrier and applying a voltage to the charging member. The full color image forming method according to any one of the above.

Images